Nitofill Eplv Uae

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Revision date: 19/04/2021 Revision: 3 Supersedes date: 17/08/2015

SAFETY DATA SHEET


NITOFILL EPLV BASE

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name NITOFILL EPLV BASE

Product number A1802040AE1

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Base component of low viscosity epoxy injection resin system.

1.3. Details of the supplier of the safety data sheet


Supplier Al Gurg Fosroc LLC
PO Box 657
Dubai
United Arab Emirates
+ 971 4 2858606

1.4. Emergency telephone number


Emergency telephone +97142039699 (08:00 to 16:30) // +971506258232 (16:30 to 08:00)GMT+4

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Skin Irrit. 2 - H315 Eye Irrit. 2 - H319 Skin Sens. 1 - H317 Muta. 2 - H341

Environmental hazards Aquatic Chronic 2 - H411

2.2. Label elements

Hazard pictograms

Signal word Warning

Hazard statements H315 Causes skin irritation.


H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H411 Toxic to aquatic life with long lasting effects.

Precautionary statements P261 Avoid breathing vapour/ spray.


P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P501 Dispose of contents/ container in accordance with national regulations.

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Contains reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight
≤ 700), GLYCIDYL ESTER OF VERSATIC 10

Supplementary precautionary P201 Obtain special instructions before use.


statements P202 Do not handle until all safety precautions have been read and understood.
P264 Wash contaminated skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P302+P352 IF ON SKIN: Wash with plenty of water.
P308+P313 IF exposed or concerned: Get medical advice/ attention.
P321 Specific treatment (see medical advice on this label).
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P391 Collect spillage.
P405 Store locked up.

2.3. Other hazards


This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin 60-100%


(number average molecular weight ≤ 700)
CAS number: 25068-38-6 EC number: 500-033-5 REACH registration number: 01-
2119456619-26-XXXX

Classification
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Aquatic Chronic 2 - H411

GLYCIDYL ESTER OF VERSATIC 10 10-30%


CAS number: 26761-45-5

Classification
Skin Sens. 1 - H317
Muta. 2 - H341
Aquatic Chronic 2 - H411

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


Inhalation Move affected person to fresh air at once. Rinse nose and mouth with water. Get medical
attention if any discomfort continues.

Ingestion Never give anything by mouth to an unconscious person. Do not induce vomiting. Rinse
mouth thoroughly with water. Get medical attention if any discomfort continues.

Skin contact Remove affected person from source of contamination. Remove contaminated clothing. Wash
skin thoroughly with soap and water. Get medical attention if any discomfort continues.

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Eye contact Remove affected person from source of contamination. Remove any contact lenses and open
eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information Get medical attention promptly if symptoms occur after washing.

Inhalation May cause irritation.

Ingestion May cause discomfort if swallowed.

Skin contact Causes skin irritation. May cause an allergic skin reaction.

Eye contact May cause eye irritation.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide or dry powder.

5.2. Special hazards arising from the substance or mixture


Hazardous combustion Oxides of carbon.
products

5.3. Advice for firefighters


Special protective equipment Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
for firefighters clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions


Environmental precautions Do not discharge into drains or watercourses or onto the ground.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Stop leak if possible without risk. Absorb in vermiculite, dry sand or earth and place into
containers. Flush contaminated area with plenty of water. Avoid the spillage or runoff entering
drains, sewers or watercourses.

6.4. Reference to other sections


Reference to other sections For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions Avoid spilling. Avoid contact with skin and eyes.

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Chemical storage.

7.3. Specific end use(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.2.

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SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Ingredient comments WEL = Workplace Exposure Limits

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) (CAS:
25068-38-6)

DNEL Workers - Inhalation; Short term systemic effects: 12.25 mg/m³


Workers - Inhalation; Long term systemic effects: 12.25 mg/m³

PNEC - Fresh water; 0.006 mg/l

GLYCIDYL ESTER OF VERSATIC 10 (CAS: 26761-45-5)

DNEL Workers - Inhalation; Long term systemic effects: 2.7 mg/m³


Workers - Dermal; Long term systemic effects: 1.9 mg/kg bw/day
General population - Inhalation; Long term systemic effects: 1.6 mg/m³
General population - Dermal; Long term systemic effects: 1.15 mg/kg bw/day

PNEC Aqua - Fresh water; 0.001 mg/L

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate ventilation. Avoid inhalation of vapours. Observe any occupational
controls exposure limits for the product or ingredients.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles or
face shield.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible. Wear protective gloves made of the
following material: Neoprene. Butyl rubber. Nitrile rubber.

Other skin and body Wear appropriate clothing to prevent any possibility of skin contact.
protection

Hygiene measures Provide eyewash station. Do not smoke in work area. Wash at the end of each work shift and
before eating, smoking and using the toilet. Promptly remove any clothing that becomes
contaminated. Use appropriate skin cream to prevent drying of skin. Do not eat, drink or
smoke when using this product.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Appearance Liquid.

Colour Colourless.

Odour Mild.

Odour threshold Not applicable.

pH Not applicable.

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Melting point Not determined.

Initial boiling point and range >200°C @

Flash point >150°C

Evaporation rate Not determined.

Evaporation factor Not determined.

Flammability (solid, gas) Not determined.

Other flammability Not determined.

Vapour density Not determined.

Relative density 1.05 @ 20°C

Solubility(ies) Insoluble in water.

Partition coefficient Not determined.

Auto-ignition temperature No information available.

Viscosity 8 P @ 20°C

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.


of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information


Other information No data available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Stable under recommended transport or storage conditions.

10.2. Chemical stability


Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions


Possibility of hazardous Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

10.4. Conditions to avoid


Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials


Materials to avoid acids, oxidizing materials.

10.6. Hazardous decomposition products


Hazardous decomposition Fire creates: Carbon monoxide (CO). Carbon dioxide (CO2).
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

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Inhalation Irritating to respiratory system.

Ingestion May cause stomach pain or vomiting.

Skin contact Irritating to skin. May cause an allergic skin reaction.

Eye contact Irritating to eyes.

Toxicological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 5,000.0


mg/kg)

Species Rat

Notes (oral LD₅₀) NOAEL 750 mg/kg, Oral, Rat

ATE oral (mg/kg) 5,000.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 20,000.0


mg/kg)

Species Rabbit

Notes (dermal LD₅₀) LD₅₀ >1600 mg/kg, Dermal, Rat

ATE dermal (mg/kg) 20,000.0

Skin corrosion/irritation

Animal data Rabbit Moderately irritating.

Skin sensitisation

Skin sensitisation May cause sensitisation by skin contact.

GLYCIDYL ESTER OF VERSATIC 10

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 2,000.0


mg/kg)

Species Rat

Notes (oral LD₅₀) LD₅₀ > 2 000 mg/kg bw, Oral, Rat

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 3,900.0


mg/kg)

Species Rat

Notes (dermal LD₅₀) LD₅₀ > 2 000 mg/kg bw, Dermal, Rat

ATE dermal (mg/kg) 3,900.0

Acute toxicity - inhalation

Acute toxicity inhalation 240.0


(LC₅₀ vapours mg/l)

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Species Rat

Notes (inhalation LC₅₀) LC50 > 240 mg/m³, Inhalation, Rat

ATE inhalation (vapours 240.0


mg/l)

SECTION 12: Ecological information

Ecotoxicity The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

12.1. Toxicity
Toxicity The product contains a substance which is toxic to aquatic organisms.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Toxicity Ecotoxic to fish / daphnia / algae

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 3.6 mg/l, Leuciscus idus (Golden orfe)
LC₅₀, 96 hours: 2 mg/l, Oncorhynchus mykiss (Rainbow trout)

Acute toxicity - aquatic EC₅₀, 48 hours: 1.8 mg/l, Daphnia magna


invertebrates

Acute toxicity - aquatic EC50, 72 hours: 11 mg/l, Scenedesmus capricornutum (fresh water algae)
plants

GLYCIDYL ESTER OF VERSATIC 10

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 5 mg/l, Salmo gairdneri

Acute toxicity - aquatic EC₅₀, 48 hours: 4.8 mg/l, Daphnia magna


invertebrates

Acute toxicity - aquatic EC₅₀, 72 hours: 2.9 mg/L, Selenastrum capricornutum


plants

Acute toxicity - NOEC, 3 hour: 500 mg/L, Activated sludge


microorganisms

12.2. Persistence and degradability


Persistence and degradability The product is not readily biodegradable.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Persistence and The product is not readily biodegradable.


degradability

12.3. Bioaccumulative potential


Bioaccumulative potential No data vailable.

Partition coefficient Not determined.

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Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Partition coefficient log Pow: 3.242

12.4. Mobility in soil


Mobility The product is immiscible with water and will sediment in water systems.

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Mobility The product has poor water-solubility.

Adsorption/desorption Water - Koc: 445 @ °C


coefficient

12.5. Results of PBT and vPvB assessment


Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

Ecological information on ingredients.

reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700)

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects


Other adverse effects Not determined.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 3082

UN No. (IMDG) 3082

UN No. (ICAO) 3082

UN No. (ADN) 3082

14.2. UN proper shipping name


Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS reaction
(ADR/RID) product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700),
GLYCIDYL ESTER OF VERSATIC 10)

Proper shipping name (IMDG) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS reaction
product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700),
GLYCIDYL ESTER OF VERSATIC 10)

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Proper shipping name (ICAO) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS reaction
product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700),
GLYCIDYL ESTER OF VERSATIC 10)

Proper shipping name (ADN) ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (CONTAINS reaction
product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700),
GLYCIDYL ESTER OF VERSATIC 10)

14.3. Transport hazard class(es)


ADR/RID class 9

ADR/RID classification code M6

ADR/RID label 9

IMDG class 9

ICAO class/division 9

ADN class 9

Transport labels

14.4. Packing group


ADR/RID packing group III

IMDG packing group III

ICAO packing group III

ADN packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

14.6. Special precautions for user


EmS F-A, S-F

ADR transport category 3

Emergency Action Code •3Z

Hazard Identification Number 90


(ADR/RID)

Tunnel restriction code (-)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

15.2. Chemical safety assessment


No chemical safety assessment has been carried out.

SECTION 16: Other information

General information Only trained personnel should use this material.

Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 19/04/2021

Revision 3

Supersedes date 17/08/2015

Hazard statements in full H315 Causes skin irritation.


H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H341 Suspected of causing genetic defects.
H411 Toxic to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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SAFETY DATA SHEET


NITOFILL EPLV HARDENER

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier


Product name NITOFILL EPLV HARDENER

Product number A1802042AE1

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Hardener component of low viscosity epoxy injection resin system.

1.3. Details of the supplier of the safety data sheet


Supplier Al Gurg Fosroc LLC
PO Box 657
Dubai
United Arab Emirates
+ 971 4 2858606

1.4. Emergency telephone number


Emergency telephone +97142039699 (08:00 to 16:30) // +971506258232 (16:30 to 08:00)GMT+4

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture


Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Acute Tox. 4 - H302 Skin Corr. 1B - H314 Eye Dam. 1 - H318 Skin Sens. 1 - H317

Environmental hazards Aquatic Chronic 3 - H412

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H302 Harmful if swallowed.


H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.

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Precautionary statements P260 Do not breathe vapour/ spray.


P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of contents/ container in accordance with national regulations.

Contains ISOPHORONEDIAMINE, TRIMETHYLENE HEXAMETHYLENE DIAMINE

Supplementary precautionary P261 Avoid breathing vapour/ spray.


statements P264 Wash contaminated skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P272 Contaminated work clothing should not be allowed out of the workplace.
P301+P312 IF SWALLOWED: Call a POISON CENTRE/doctor if you feel unwell.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P310 Immediately call a POISON CENTER/ doctor.
P321 Specific treatment (see medical advice on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/ attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.

2.3. Other hazards


This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

TRIMETHYLENE HEXAMETHYLENE DIAMINE 30-60%


CAS number: 25620-58-0 EC number: 247-134-8

Classification
Acute Tox. 4 - H302
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Chronic 3 - H412

ISOPHORONEDIAMINE 30-60%
CAS number: 2855-13-2 EC number: 220-666-8 REACH registration number: 01-
2119514687-32-xxxx

Classification
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Skin Corr. 1B - H314
Eye Dam. 1 - H318
Skin Sens. 1 - H317
Aquatic Chronic 3 - H412

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The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures


Inhalation Move affected person to fresh air at once. Rinse nose and mouth with water. Never give
anything by mouth to an unconscious person. Do not induce vomiting. Keep affected person
warm and at rest. Get medical attention immediately.

Ingestion Do not induce vomiting. Never give anything by mouth to an unconscious person. Do not
induce vomiting. Rinse mouth thoroughly with water. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. Get medical attention
immediately.

Skin contact Remove affected person from source of contamination. Rinse immediately with plenty of
water. Get medical attention promptly if symptoms occur after washing.

Eye contact Remove affected person from source of contamination. Remove any contact lenses and open
eyelids wide apart. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation May cause irritation.

Ingestion Harmful if swallowed.

Skin contact Causes severe burns. May cause an allergic skin reaction.

Eye contact May cause chemical eye burns.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media


Suitable extinguishing media Extinguish with alcohol-resistant foam, carbon dioxide or dry powder.

5.2. Special hazards arising from the substance or mixture


Specific hazards Oxides of carbon. Oxides of nitrogen.

5.3. Advice for firefighters


Protective actions during Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective
firefighting clothing.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures


Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet.

6.2. Environmental precautions


Environmental precautions Prevent from entering into ditches, sewers, waterways and groundwater.

6.3. Methods and material for containment and cleaning up


Methods for cleaning up Absorb in vermiculite, dry sand or earth and place into containers. Containers with collected
spillage must be properly labelled with correct contents and hazard symbol. Avoid
contamination of ponds or watercourses with washing down water. Dispose of
contents/container in accordance with local regulations.

6.4. Reference to other sections

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Reference to other sections For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling


Usage precautions Avoid skin and eye contact.

7.2. Conditions for safe storage, including any incompatibilities


Storage precautions Store in tightly-closed, original container in a dry, cool and well-ventilated place.

Storage class Corrosive storage.

7.3. Specific end use(s)


Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

ISOPHORONEDIAMINE (CAS: 2855-13-2)

DNEL Workers - Inhalation; : 0,073 mg/m³

PNEC - marine water; 0.006 mg/l


- Fresh water; 0.06 mg/l
- Soil; 1.121 mg/kg

8.2. Exposure controls

Protective equipment

Appropriate engineering Provide adequate general and local exhaust ventilation.


controls

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles.

Hand protection Wear protective gloves made of the following material: Nitrile rubber. Butyl rubber. Neoprene.

Other skin and body Wear appropriate clothing to prevent skin contamination. Provide eyewash station.
protection

Hygiene measures Wash at the end of each work shift and before eating, smoking and using the toilet. Wash
promptly with soap and water if skin becomes contaminated. Promptly remove any clothing
that becomes wet or contaminated.

Respiratory protection Use an approved air purifying respirator with replaceable filter cartage comply with EN 140and
filter EN 141: Organic Vapour cartridge type A1

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties


Appearance Liquid.

Colour Clear liquid.

Odour Mild.

Odour threshold Not applicable.

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Melting point Not determined.

Initial boiling point and range >230°C @

Flash point 110°C

Evaporation rate Not determined.

Flammability (solid, gas) Not determined.

Upper/lower flammability or Not determined.


explosive limits

Vapour pressure 0.002 kPa @ 20°C

Relative density 0.85 @ 20°C

Solubility(ies) Slightly soluble in water.

Auto-ignition temperature 350°C

Decomposition Temperature Not determined.

Viscosity Not determined.

Explosive properties Not considered to be explosive.

Explosive under the influence Not considered to be explosive.


of a flame

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information


Other information No data available.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity The reactivity data for this product will be typical of those for the following class of materials:
Amines.

10.2. Chemical stability


Stability Stable at normal ambient temperatures.

10.3. Possibility of hazardous reactions


Possibility of hazardous Will not polymerise.
reactions

10.4. Conditions to avoid


Conditions to avoid Avoid excessive heat for prolonged periods of time.

10.5. Incompatible materials


Materials to avoid Strong oxidising agents.

10.6. Hazardous decomposition products


Hazardous decomposition Oxides of nitrogen. Oxides of carbon.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects


Acute toxicity - oral

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ATE oral (mg/kg) 673.2

Acute toxicity - dermal


ATE dermal (mg/kg) 2,200.0

Inhalation May cause respiratory system irritation.

Ingestion May cause chemical burns in mouth and throat. Harmful if swallowed.

Skin contact Product has a defatting effect on skin. May cause an allergic skin reaction. Causes burns.

Eye contact Severe irritation, burning and tearing. Causes burns.

Toxicological information on ingredients.

ISOPHORONEDIAMINE

Acute toxicity - oral

Acute toxicity oral (LD₅₀ 1,030.0


mg/kg)

Species Rat

ATE oral (mg/kg) 10,300.0

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 1,840.0


mg/kg)

Species Rabbit

ATE dermal (mg/kg) 1,100.0

SECTION 12: Ecological information

Ecotoxicity Dangerous for the environment. May cause long-term adverse effects in the aquatic
environment.

12.1. Toxicity
Toxicity The product contains a substance which is harmful to aquatic organisms.

Ecological information on ingredients.

ISOPHORONEDIAMINE

Acute aquatic toxicity

Acute toxicity - fish LC₅₀, 96 hours: 110 mg/l, Fish

Acute toxicity - aquatic EC₅₀, 48 hours: 23 mg/l, Daphnia magna


invertebrates

Acute toxicity - aquatic IC₅₀, 72 hours: 50 mg/l, Algae


plants

12.2. Persistence and degradability


Persistence and degradability Not expected to be readily biodegradable.

Ecological information on ingredients.

ISOPHORONEDIAMINE

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Persistence and The product is not readily biodegradable.


degradability

12.3. Bioaccumulative potential


Bioaccumulative potential No data vailable.

Ecological information on ingredients.

ISOPHORONEDIAMINE

Bioaccumulative potential The product does not contain any substances expected to be bioaccumulating.

Partition coefficient log Kow: 0.99

12.4. Mobility in soil


Mobility The product is partly miscible with water and may spread in the aquatic environment.

12.5. Results of PBT and vPvB assessment


Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects


Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods


Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 2735

UN No. (IMDG) 2735

UN No. (ICAO) 2735

UN No. (ADN) 2735

14.2. UN proper shipping name


Proper shipping name AMINES, LIQUID, CORROSIVE, N.O.S. (CONTAINS ISOPHORONEDIAMINE,
(ADR/RID) TRIMETHYLENE HEXAMETHYLENE DIAMINE)

Proper shipping name (IMDG) AMINES, LIQUID, CORROSIVE, N.O.S. (CONTAINS ISOPHORONEDIAMINE,
TRIMETHYLENE HEXAMETHYLENE DIAMINE)

Proper shipping name (ICAO) AMINES, LIQUID, CORROSIVE, N.O.S. (CONTAINS ISOPHORONEDIAMINE,
TRIMETHYLENE HEXAMETHYLENE DIAMINE)

Proper shipping name (ADN) AMINES, LIQUID, CORROSIVE, N.O.S. (CONTAINS ISOPHORONEDIAMINE,
TRIMETHYLENE HEXAMETHYLENE DIAMINE)

14.3. Transport hazard class(es)


ADR/RID class 8

ADR/RID classification code C7

ADR/RID label 8

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IMDG class 8

ICAO class/division 8

ADN class 8

Transport labels

14.4. Packing group


ADR/RID packing group II

IMDG packing group II

ICAO packing group II

ADN packing group II

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant


No.

14.6. Special precautions for user


IMDG Code segregation 18. Alkalis
group

EmS F-A, S-B

ADR transport category 2

Emergency Action Code 2X

Hazard Identification Number 80


(ADR/RID)

Tunnel restriction code (E)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations No data

EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).

15.2. Chemical safety assessment


No chemical safety assessment has been carried out.

SECTION 16: Other information

General information Only trained personnel should use this material.

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Revision comments NOTE: Lines within the margin indicate significant changes from the previous revision.

Revision date 19/04/2021

Revision 3

Supersedes date 18/08/2015

SDS number 11172

Hazard statements in full H302 Harmful if swallowed.


H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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