Supplemental Instruction CHEM 105a: Exam 2 Review Dr. Prezhdo & Dr.

Bertolini
Nicole, Allen & Lindsay [email protected] 10/1/17

Topics on Exam 2: Chapter 4, Chapter 5, and Chapter 6 (6.1-6.4)

Percent yield Limiting reactant Precipitation Acid-base reactions Molarity

Redox reactions Concentrations/Dilutions Properties of gases Ideal gas law Partial pressure
Real vs. ideal gas Kinetic molecular theory Thermochemistry System vs. surroundings State functions
Calorimetry Exothermic/Endothermic Pressure-volume work

Chapter 4:

1. Adipic acid (C6H10O4, molar mass = 146.14 g/mol) is used to make nylon fabric. Reaction of cyclohexane (C6H12,
molar mass = 84.16 g/mol) and molecular oxygen produces adipic acid via the following reaction:

C6H12 + O2 → C6H10O4 + H2O

If a chemist reacts 25.0 g of cyclohexane with 115 g of molecular oxygen and obtains 33.5 g of adipic acid, what is the
percent yield?

2. A solution is prepared by dissolving 10.8 g ammonium sulfate in enough water to make 100.0 mL of stock solution. A
10.00 mL sample of this stock solution is added to 50.00 mL of water. Calculate the concentration of ammonium and
sulfate ions in the final solution.

3. A 230. mL sample of 0.275 M CaCl2 is left on a hot plate overnight; the following morning, the solution is 1.10 M.
What volume of water evaporated from the CaCl2 solution?
Supplemental Instruction CHEM 105a: Exam 2 Review Dr. Prezhdo & Dr. Bertolini
Nicole, Allen & Lindsay [email protected] 10/1/17

4. When the following solutions are mixed together, what precipitate (if any) will form? Don’t forget to balance your
equations. Then, write the complete ionic and net ionic equations for reaction (a).

a. Al(NO3)3 (aq) + Ba(OH)2 (aq) →

b. FeSO4 (aq) + KCl (aq) →

c. CaCl2 (aq) + Na2SO4 (aq) →

d. K2S (aq) + Ni(NO3)2 (aq) →

e. Fe(NO3)3 (aq) + NaOH (aq) →

Complete and Net Ionic Equations:

a.

5. What volume of 0.155 M HCl is needed to neutralize 35.0 mL of 0.101 M Ba(OH)2 solution?

6. What mass of silver chloride can be prepared by reaction of 100.0 mL of 0.20 M silver nitrate with 100.0 mL of
0.15 M calcium chloride? Calculate the concentration of each ion remaining in solution after the precipitation is
complete.

7. For the reaction below, assign oxidation states to each element and fill out the following chart.

a. H2O (l) + As (s) + KClO3 (aq) → H3AsO4 (aq) + KClO (aq)

Oxidized Reduced Oxidizing Agent Reducing Agent

Supplemental Instruction CHEM 105a: Exam 2 Review Dr. Prezhdo & Dr. Bertolini
Nicole, Allen & Lindsay [email protected] 10/1/17

Chapter 5:
8. What is the pressure -- in atm -- of gas inside the flask? What if the tube was open, and the atmospheric pressure
was 760 mmHg?

9. Find the volume, in mL, when 7.00 g of O2 and 1.50 g of Cl2 are mixed in a container, at a pressure of 482 atm,
and a temperature of 22°C.

10. A sample of methane gas at 0.949 atm and 40.0°C occupies a volume of 7.52 L. What volume will the gas
occupy if the pressure is increased to 1.58 atm, and the temperature is increased to 92.2°C?

11. Air has a density of 1.185 g/L at 25°C and 760. torr. What is the average molar mass of the air?
Supplemental Instruction CHEM 105a: Exam 2 Review Dr. Prezhdo & Dr. Bertolini
Nicole, Allen & Lindsay [email protected] 10/1/17

12. Consider a mixture of two gases, A and B, sealed within a flask. A third gas, C, is added to the same flask at the
same temperature. How does the addition of gas C affect the following?
a. The partial pressure of gas A increase decrease no change
b. The total pressure in the flask increase decrease no change

c. The mole fraction of gas B increase decrease no change

13. What is the average speed of a chlorine molecule at 650. K? What about a helium molecule?

14. At a certain temperature, the ratio of effusion rates for an unknown diatomic gas to chlorine gas is 1.5907.
Calculate the molar mass and propose an identity for the unknown gas.

15. A 12.0 g sample of gas occupies 19.2 L at STP. What is the molecular weight of this gas?

Real vs. Ideal Gases

● Ideal gas particles are…

○
○
○
● Real gases behave like ideal gases at…
○
○
Supplemental Instruction CHEM 105a: Exam 2 Review Dr. Prezhdo & Dr. Bertolini
Nicole, Allen & Lindsay [email protected] 10/1/17

Chapter 6:

Definitions:
When a change in a value is the same regardless of the steps that happened: ______________________

When the path and steps taken affects the change in value: ______________________________

Elevation of 2 hikers who climbed the same mountain on different paths State Path

Potential energy S P

Distance traveled taking a long road vs a shortcut to the same location S P

Change in temperature S P

Heat and work S P

Density S P

If a variable can be expressed as a value in both states and as a change S P

Heat and the MCAT

16. How much heat does it take to raise 0.610 moles of solid iron (specific heat = 0.444 J/goC) from 25.00 oC to
41.5 oC?

17. If a heat blanket uses 80.0 watts of power, how much does a 55.0 kg human heat up in 1 hour? Assume the
human is mostly water and water has heat capacity 4.18 J/goC
Supplemental Instruction CHEM 105a: Exam 2 Review Dr. Prezhdo & Dr. Bertolini
Nicole, Allen & Lindsay [email protected] 10/1/17

Variable Equation When Positive When negative

Heat q = mcΔT Heat flows from __________ to Heat flows from __________ to
______________ ______________

Work W = -PΔV Work is done _____ the system Work is done _____ the system

Energy ΔE/U = q + w Energy flows _________ the Energy flows _________ the
system system

18. 1.50 moles of ideal gas is kept in a container at a pressure of 2.00 atm. At constant pressure, the gas is
compressed to half its original volume. If temperature remains constant at 315 K (ΔE = 0), how much heat leaves
the system?

19. A 30.0 g piece of Aluminum (C = 0.900 J/moloC) is placed in a sealed 1.00L container of gas. The aluminum
cools from 40.6oC to 28.1oC releasing all heat into the container, which expands at constant pressure of 2.00 atm
to a final volume of 1.82 L. What is the change in energy?
Supplemental Instruction CHEM 105a: Exam 2 Review Dr. Prezhdo & Dr. Bertolini
Nicole, Allen & Lindsay [email protected] 10/1/17