AP Chemistry 2013-2014 Lab #13 Hot Pack/Cold Pack Design Challenge

AP Standard: Science Practices 1.4, 2.2, 2.3, 4.2, 5.1, 5.3, 6.4, 7.2; Primary Learning Objective 5.7; Secondary Learning Objective 5.6 Central Challenge Use chemistry to design an effective, safe, environmentally benign, and inexpensive hand warmer. The ideal hand warmer increases in temperature by 20C (but no more) as quickly as possible, has a volume of about 50 mL, costs as little as possible to make, and uses chemicals that are as safe and environmentally friendly as possible. Design and carry out an experiment to determine which substances, in what amounts, to use in order to make a hand warmer that meets these criteria. Substances to choose from are assigned below in Materials Assigned section. Prelab Reference Lab #6 and Chapter 13 in hour textbook. Breaking bonds and particulate attractions absorb energy from the surroundings, while forming new bonds and particulate attractions release energy to the surroundings. When an ionic solid dissolves in water, ionic bonds between cations and anions in the ionic solid and hydrogen bonds between water molecules are broken, and new attractions between water molecules and anions and water molecules and cations are formed. The amount of energy required to break these bonds and form new ones depends on the chemical properties of the particular anions and cations. Therefore, when some ionic solids dissolve, more energy is required to break the cation-anion bonds than is released in forming the new water-ion attractions, and the overall process absorbs energy in the form of heat. When other ionic compounds dissolve, the converse is true, and the bond making releases more energy than the bond breaking absorbs, and therefore the process overall releases heat. When heat is absorbed, the enthalpy change, q, is endothermic, and the enthalpy change is positive. When heat is released the change is exothermic, and the value of q, is negative. The entropy change of solution formation is always positive, regardless of whether it is endothermic or exothermic, because solutions are much more disordered than are the pure solute and solvent from which they are made. The positive entropy change is thermodynamically favorable.

Prelab Guiding Questions 1. When sodium chloride is dissolved in water, the temperature of the resulting solution is lower than the temperature of the water before the salt dissolves. How can this result be explained based on the bond breaking and bond making that is occurring? 2. Why do some salts, such as sodium chloride, dissolve spontaneously even though the process in endothermic overall? 3. When some ionic salts are dissolved in water, the temperature of the resulting solution is higher than the temperature of the water before the salt dissolves. What do you think determines whether the resulting solution is cooler or warmer than the starting water?

Procedure Guidlines 1. Safety and Environmental Impact: Obtain the MSDS for your solids from Flinn. Review each one making notes about safety concerns, necessary precautions, and disposal. 2. Cost: Rank the solid you are given from least to most expensive. Use Flinn to determine cost per 500 g/container. 3. Heat of Solution: Work with your group to design a procedure to compare the solids in terms of the heat released or absorbed when they dissolve and include what materials and equipment you will use. You must include the safety precautions you will take. 4. Be sure to keep detailed records of the amounts of substances used and the starting and ending temperature as you will need it later to determine the amount of solid to use in your hand warmer. 5. You will receive a maximum of 10 g of each solid (suggest total mass for each solution to be 50.0 g). 6. Minimum of two trials for each solid. 7. Teacher approval of your procedure required prior to beginning. Materials Assignment Lab Tables 1-2; NH4NO3, Na2CO3, CaCl2 Lab Tables 3-4; NaCl, LiCl, NaC2H3O2 Lab Tables 5-6; NH4NO3, LiCl, NaC2H3O2, Lab Tables 7-9; NaCl, Na2CO3, CaCl2 Calorimeter Calibration Procedure 1. Place a 100.0 mL sample of tap water in a clean, dry 150 mL beaker. Heat with Bunsen burner, occasional stirring to approximately 50C. Meanwhile, place exactly 100.0 mL of cool water (approximately 20C) in the clean dry calorimeter. Measure the temperature of the hot water (Thot) and the cold water (Tcold) and record, then immediately pout the entire hot water sample into the calorimeter and quickly put on the cover. Wait 15 seconds then take a temperature reading (Tmix). Repeat this determination twice. Calorimeter Constant Determination: According to the law of conservation of energy, energy cannot be created or destroyed, only changed from one form to another or transferred from one system to another. The temperature change observed when water or any substance changes temperature can be a result of a transfer of energy from the substance to the surroundings (in which case the temperature of the substance decreases) or the surroundings to the substance (in which case the temperature of the substance increases). When hot and cold water are mixed, the hot water transfers some of its thermal energy to the cool water. The law of conservation of energy dictates that the amount of thermal energy lost (or the enthalpy change) by the hot water, qhot, is equal to the enthalpy change of the cool water, qcold, but opposite in sign, so qhot = - qcold. The enthalpy change for nay substance is directly related to the mass of substance, m, the specific hat capacity (a substance specific constant) c; and the temperature change, !T;. The relationship is express mathematically in the equation q = mc!T. 2. Calculate the enthalpy change of the cool water using the equation qhot = mhotc!Thot. Assume that the density of waster is exactly 1 g/mL. 3. Calculate the enthalpy change of hot water using the equation qcold = mcoldc!Tcold. Assume that the density of waster is exactly 1 g/mL.

4. The amounts are not equal because the calorimeter absorbs some of the thermal energy transferred by the hot water. Thus under the real conditions observed in the laboratory the law of conservation of energy equation becomes qhot = -( qcold + qcal), where qcal is the enthalpy change of the calorimeter. Use this equation to calculate the enthalpy change of the calorimeter. 5. The calorimeter constant, C, is the heat absorbed by the calorimeter per degree of temperature change, C = qcal/!Tcal. Assuming the starting temperature of the calorimeter is the same as the cold water, calculate the calorimeter constant in units of joules per degree Celsius. The solid and water, considered together, have a certain amount of internal energy as a function of the bonds that exist in the solid and in the water. The solution that is produced as a result of the dissolving has a different amount of internal energy than the solid and water did because the arrangement of particles and the bonds and attractions between the particles in the solution are different bonds and particulate attractions than the arrangement of particles and the bonds and attractions between the particles in the solid and water. The difference in energy, qsoln, is the reason for the difference in the thermal energy of the two systems (solid and pure water versus solution), with symbol qrxn. Just as with the hot and cold water in the calorimeter constant determination, qsoln and qrxn are equal in magnitude and opposite in sign, qrxn = - qsoln. And just as in that case of the cold and hot water mixing, the calorimeter will also experience an enthalpy change during the solution formation process. To account for this enthalpy change, the relationship is adjusted to qsoln = -( qrxn + C!T) where C is the calorimeter constant determined above. This difference in thermal energy of the system before and after solution formation, qsoln, can be calculated using the relationship qrxn = mc2T, where m is the total mass of the solution and c is the specific heat capacity for the solution and !T is the temperature change of the solution. It is important to note that we will assume that the heat capacity of the solutions is the same as pure water but in reality the solutions do not have exactly the same heat capacity, and this assumption affects the accuracy of this determination. Calculation Summary 1. For each compound you will need the following calculations summarized in a data table. a. Temperature change, !T (C) b. Thermal energy change in calorimeter contents, qrxn (J) c. Thermal energy of calorimeter, qcal (J) d. Internal energy change, qsoln (J) e. Molar Mass (g/mol) f. Moles used (mol) g. Enthalpy of dissolution, !Hsoln (kJ/mol) Discussion Hints Describe all the factors you considered as well as explain your rationale for choosing once chemical and not each of the other chemicals studied in this experiment. Start with a claim sentence (conclusion statement) that clearly states your choice and the amount of substance to use. The claim should be followed by evidence from your experiment and cost and safety analysis. Conclude with reasoning, explaining how your evidence supports your claim.