Sampling Guide: Sampling Agency Standard Vol. (Liter) Rate (Ml/min) Time

Sampling Guide
SAMPLING∞ www.skcinc.com for updates

Agency Standard Vol. (liter) Rate (ml/min) Time
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
TWA CLG/STEL TWA (hrs)
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number A
Abietic acid OSHA CSI 200 2000 1.6 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Absidia species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Absidia species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Acenaphthene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Acenaphthene (polynuclear aromatic hydrocarbons) NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Acenaphthene (polynuclear aromatic hydrocarbons) NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Acenaphthylene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Acenaphthylene (polynuclear aromatic hydrocarbons) NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Acenaphthylene (polynuclear aromatic hydrocarbons) NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Acetaldehyde  ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 39
Acetaldehyde  NIOSH 2538 LFC 10 20 8 GC-FID ST 226-27 37
Acetaldehyde  NIOSH 3507 LFC 60 125 8 HPLC IMP 225-36-2 61 IT 225-22 61
Acetaldehyde  OSHA 68 1007 200 3 0.75 50 50 1 15 GC-NPD ST 226-27 37
Acetaldehyde (aldehydes, screening)  NIOSH 2539 LFC 5 10 8 GC-FID & GC-MS ST 226-118 39
Acetamide OSHA PV2084 10 20(50) 8(3.3) GC-NPD ST 226-10 37
Acetates (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 40
Acetic acid  NIOSH 1603 10 15 24 50 8 GC-FID ST 226-01 37
Acetic acid  OSHA ID 186SG 10 48 200 4 IC or GC-FID ST 226-01 37
Acetic acid  OSHA PV2119 48 200 4 IC or GC-FID ST 226-01 37
Acetic anhydride  NIOSH 3506 5 90 1000 1.5 VAS IMP 225-36-2 61 IT 225-22 61
Acetic anhydride  OSHA 102 1392 5 7.5 7.5 50 500 2.5 15 GC-NPD CF/CST 225-9010π 59 C/HLD 225-1 78
Acetic anhydride  OSHA 82 1391 5 0.75 50 15 min GC-NPD CF/CST 225-9009 59 C/HLD 225-1 78
Acetoin (Acetyl methyl carbinol) NIOSH 2558 1-10 10-200 varies GC-FID ST 226-121 39
Acetoin (Acetyl methyl carbinol) OSHA 1012 0.05 9 3 50 200 3 15 GC-FID ST 226-183 40
Acetoin (Acetyl methyl carbinol) OSHA 1013 0.05 9 3 50 200 3 15 GC-FID ST 226-183 40
Acetone  ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
Acetone  OSHA 69 1059 1000 3 50 1 GC-FID ST 226-121 39
Acetone (ketones I)  NIOSH 1300 250 2 0.75 20 50 100 min 15 GC-FID ST 226-01 37
Acetone (ketones I)  NIOSH 2555 0.5-3 10-200 varies GC-FID ST 226-121 39
Acetonitrile  NIOSH 1606 20 10 20(50) 8(3.3) GC-FID ST 226-09 37
Acetophenone OSHA PV2003 12 100 2 GC-FID ST 226-35 37
Acetyl methyl carbinol (acetoin) NIOSH 2558 1-10 10-200 varies GC-FID ST 226-121 39
Acetyl methyl carbinol (acetoin) OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-121 39
2-Acetylaminofluorene OSHA CSI 240 1000 4 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Acetylene OSHA CSI DET TB DT 810-171
Acetylene tetrabromide OSHA CSI 1 96 200 8 GC-FID ST 226-10 37
Acetylene tetrabromide (1,1,2,2-tetrabromoethane) NIOSH 2003 96 200 8 GC-FID ST 226-10 37
Acetylsalicylic acid OSHA CSI 120 1000 2 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Acid black 128 OSHA CSI 200 1000 3.3 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Acid blue 9 OSHA CSI 100 1000 100 min HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Acid orange 74 OSHA CSI 200 1000 3.3 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Acid red 114 OSHA CSI 120 1000 2 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Acid yellow 34 OSHA CSI 100 1000 100 min HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Acid yellow 42 OSHA CSI 100 1000 100 min HPLC-FD F/CST 225-706 74 C/HLD 225-1 78
Acid/base (skin) CI PCH 769-3006 or W 769-1036 or
TK 769-1006 110
Acid/base (surface) CI W 769-1024 or TK 769-1006 110
Acids, inorganic (see specific compounds) NIOSH 7903 1016 48 200 4 IC ST 226-10-03 37
Acremonium species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Acremonium species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Acridine OSHA 58 1077 0.2 mg/m3 960 2000 8 GR, HPLC- FLT 225-7 74 CST 225-2LF 79
FD, -UV C/HLD 225-1 78
Acrolein NIOSH 2501 0.1 0.3 24 3 50 200 8 15 GC-NPD ST 226-118 39
Acrolein OSHA 52 0.1 48 3 100 200 8 15 GC-NPD ST 226-117 39
Acrolein (aldehydes, screening) NIOSH 2539 0.1 0.3 5 10 8 GC-FID & GC-MS ST 226-118 39
Acrylamide OSHA 21 0.3 mg/m3 120 1000 2 GC-NPD ST 226-10 37 FLT 225-16 74
CST 225-32 78 C/HLD 225-1 78
Acrylic acid NON 10 48 100 8 GC ST 226-70A 38
Acrylic acid OSHA 28 24 100 4 HPLC-UV ST 226-30-08 37
Acrylonitrile  NIOSH 1604 1266 1 10 (15 min) 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Acrylonitrile  OSHA 37 1265 2 10 20 6 200 400 100 min 15 GC-NPD ST 226-01 37
Actinomycetes, thermophilic NIOSH 0800 varies 28300 varies varies BI 225-9611 94
Adipic acid OSHA CSI 96 200 8 GC-FID ST 226-30-16 37
Adiponitrile OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Aerobic bacteria by GC-FAME NIOSH 0801 50-300 28300 varies GC-FID BI 225-9611 94
Alcohols (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 40
Alcohols combined NIOSH 1405 varies varies varies varies 10-200 10-200 varies varies GC-FID ST 226-01 37
Alcohols I (see specific compounds) NIOSH 1400 varies varies varies varies GC-FID ST 226-01 37
Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Symbols, references, and abbreviations are found on pages 190-191.
SKC Inc. Phone: +1-724-941-9701 www.skcinc.com 145

Sampling Guide
www.skcinc.com for updates SAMPLING∞
A Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number
Alcohols II (see specific compounds) NIOSH 1401 varies varies varies 8 GC-FID ST 226-01 37
Alcohols III (see specific compounds) NIOSH 1402 varies varies varies 8 GC-FID ST 226-01 37
Alcohols IV (see specific alcohol) NIOSH 1403 varies varies varies varies GC-FID ST 226-01 37
Aldehydes (screening)  NIOSH 2539 varies 5 20 4 GC-FID & GC-MS ST 226-118 39
Aldehydes (screening)  NIOSH 2549 5 20 4 GC-MS ST 226-330 40
Aldehydes (see Environmental Sampling Guide) EPA TO-5
Aldicarb (organonitrogen pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Aldicarb (Temik) OSHA 74 1399 480 1000 8 GC-NPD ST 226-30-16 37
Aldrin ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Aldrin NIOSH 5502 0.25 mg/m3 240 500 8 GC-ECN F/CST 225-709 74 IMP 225-36-2 61
IT 225-22 61 C/HLD 225-1 78
Aldrin OSHA CSI 0.25 mg/m 3
240 1000 4 GC-ECN F/CST 225-709 74 IMP 225-36-2 61
IT 225-22 61 C/HLD 225-1 78
Aliphatic hydrocarbons (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 40
Alkaline dusts NIOSH 7401 30 2000 15 TITRA FLT 225-17-01 75 CST 225-3LF 79
C/HLD 225-1 78
Allethrin ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Allyl alcohol  OSHA CSI 2 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Allyl alcohol  OSHA PV2140 2 (skin) 10 50 200 min GC-FID ST 226-01 37
Allyl alcohol (alcohols combined)  NIOSH 1405 2 4 (skin) 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 37
Allyl alcohol (alcohols III)  NIOSH 1402 2 4 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Allyl chloride  NIOSH 1000 1 2 15 1000 15 GC-FID ST 226-01 37
Allyl chloride  OSHA 07 1126 1 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Allyl glycidyl ether (AGE) NIOSH 2545 5 10 6 3 50 200 2 15 GC-FID ST 226-35-03 37
Allyl propyl disulfide OSHA PV2086 2 10 20(50) 8(3.3) GC-FPD ST 226-110 39
Allyll amine  HPLC-UV PS 500-400 64
Alternaria species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Alternaria species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Alumina (aluminum & compounds [total dust as Al]) NIOSH 7013 10 mg/m3 360 1000 6 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Alumina (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR CYC 225-01-02 73 C/HLD 225-1 78
FLT 225-8-01 85 CST 225-3LF 79
Alumina (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
alpha-Alumina (respirable fraction) OSHA CSI 5 mg/m3 varies varies varies GR CYC 225-105 84 FLT 225-8-01 73
C/HLD 225-1 78 CST 225-3LF 79
alpha-Alumina (total dust) OSHA CSI 15 mg/m3 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Aluminum (elements by ICP Aqua Regia ashing) NIOSH 7301 10 mg/m3 5-100 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
(total dust) C/HLD 225-1 78
Aluminum (elements by ICP HNO3 digestion) NIOSH 7303 10 mg/m3 (total dust) 2-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
5 mg/m3 (resp. fume)
Aluminum (elements) NIOSH 7300 1455 10 mg/m3 (total) 5-100 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
5 mg/m3 (dust)
Aluminum (respirable fraction) OSHA CSI 5 mg/m 3
varies varies varies GR FLT 225-8-01 73 CYC 225-105 84
C/HLD 225-1 78
Aluminum (total dust) OSHA CSI 15 mg/m 3
960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Aluminum & compounds (total dust as Al) NIOSH 7013 10 mg/m 3
360 1000 6 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Aluminum soluble salts OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Aluminum welding fumes OSHA CSI 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Aluminum, pyro powders OSHA CSI 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Alupent OSHA CSI 720 2000 6 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Amiben OSHA CSI 240 1000 4 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Amines NIOSH 2002 varies 20 40 8 GC-FID or ST 226-10 37
GC-NSD
Amines, aliphatic NIOSH 2010 varies 24 50 8 GC-FID ST 226-10 37
Amines, aliphatic (skin) CI PCH 769-3005 or W 769-1035 or
TK 769-1005 110 110
Amines, aliphatic (surface) CI W 769-1025 or TK 769-1005 110
Amines, aromatic (skin) CI PCH 769-3001 or W 769-1031 or
TK 769-1001 110 110
Amines, aromatic (surface) CI W 769-1021 or TK 769-1001 110
2-Amino-2-methy-1-propanol OSHA CSI 9 100 90 min GC-NPD ST 226-10 37
2-Amino-2-methy-1-propanol OSHA PV2145 10 100 100 min HPLC-UV ST 226-30-16 37
4-Aminobiphenyl OSHA 93 1233 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
2-Aminoethanol NIOSH 2007 3 6 10 20 8 GC-FID ST 226-10-04 37
2-Aminoethanol NIOSH 3509 3 6 240 1000 4 IC IMP 225-36-1 61 IT 225-22 61
2-Aminoethanol OSHA PV2111 3 10 1.5 100 100 100 min 15 HPLC-UV ST 226-30-18 37
Aminoethanol compounds I (see specific compounds) NIOSH 2007 varies varies varies 8 GC-FID ST 226-10-04 37
Aminoethanol compounds II (see specific compounds) NIOSH 3509 varies 240 1000 4 IC IMP 225-36-1 61 IT 225-22 61
Aminoethylethanolamine OSHA PV2116 10 100 HPLC-UV ST 226-30-18 37
N-Aminoethylpiperazine OSHA CSI 9 100 90 min GC-NPD ST 226-98 39
p-Aminophenylarsonic acid (arsenic, organo-) NIOSH 5022 960 2000 8 IC-AA FLT 225-17-01 75 CST 225-3LF 79
C/HLD 225-1 78
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Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number A
2-Aminopyridine OSHA CSI 0.5 12 200 1 GC-FID ST 226-35-02 37
2-Aminopyridine OSHA PV2143 0.5 240 1000 4 GC-NPD CF/CST 225-9004 59 C/HLD 225-1 78
3-Aminopyridine OSHA PV2143 240 1000 4 GC-NPD CF/CST 225-9004 59 C/HLD 225-1 78
4-Aminopyridine OSHA PV2143 240 1000 4 GC-NPD CF/CST 225-9004 59 C/HLD 225-1 78
Amitrole OSHA PV2006 60 1000 1 HPLC-UV IMP 225-36-1 61 IT 225-22 61
Ammonia  NIOSH 6015 25 35 72 3 150 200 8 15 VAS ST 226-10-06 37 F/CST 225-3-01** 71
Ammonia  NON 41 18 5 75 500 4 10 CLR ST 226-61 38
Ammonia  OSHA ID 188 1008 50 24 7.5 100 500 4 15 IC-ECN ST 226-29 37
Ammonia by IC NIOSH 6016 25 35 48 3 100 200 8 15 IC ST 226-10-06 37 F/CST 225-3-01** 71
Ammonium chloride (fume) OSHA ID 188 960 30 2000 2000 8 15 GR, IC-ECN F/CST 225-803 73 C/HLD 225-1 78
Ammonium hydroxide (see ammonia)
Ammonium metavanadate (see vanadium oxides) NIOSH 7504
Ammonium nitrate OSHA CSI 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Ammonium sulfamate (respirable dust) OSHA CSI 5 mg/m 3
varies varies varies GR CYC 225-105 84 C/HLD 225-1 78
FLT 225-8-01 85 CST 225-3LF 79
Ammonium sulfamate (total dust) OSHA CSI 15 mg/m 3
960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Ammonium sulfamate (total dust) OSHA ID 188 15 mg/m 3
960 2000 8 GR, IC F/CST 225-3-01 71 C/HLD 225-1 78
n-Amyl acetate  OSHA 07 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
sec-Amyl acetate (2-pentyl acetate)  OSHA 07 125 10 20(50) 8(3.3) GC-FID ST 226-01 37
n-Amyl acetate (esters I)  NIOSH 1450 100 1-10 10-200 varies GC-FID ST 226-01 37
n-Amyl alcohol  GC-FID PS 575-002 63
t-Amyl methyl ether (methyl tert-amyl ether)  GC-FID PS 575-001 63
Amyl nitrite OSHA CSI 8 50 2.5 HPLC-UV ST 226-01 37
Aniline  NIOSH 2017 LFC 24 200 2 GC-FID CF/CST 225-9004 59 ST 226-15 37
Aniline  OSHA PV2079 5 24 50 8 GC-FID ST 226-98 39
Aniline (amines, aromatic) NIOSH 2002 1058 LFC 24 50 8 GC-FID or ST 226-10 37
GC-NSD
o-Anisaldehyde OSHA CSI 96 200 8 HPLC-UV ST 226-30 37
Anisidine NIOSH 2514 0.5 mg/m3 240 1000 4 HPLC-UV ST 226-30-05 37
Anisidine (o- & p-isomers) OSHA CSI 0.5 mg/m3 240 1000 4 HPLC-UV ST 226-30-05 37
Anthophyllite fibers (see asbestos fibers) NIOSH 7400
Anthracene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Anthracene OSHA 58 1075 0.2 mg/m3 960 2000 8 GR, HPLC- FLT 225-7 74 CST 225-2LF 79
FD, -UV C/HLD 225-1 78
Anthracene (polynuclear aromatic hydrocarbons) NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Anthracene (polynuclear aromatic hydrocarbons) NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Anthrax NIOSH F/CST 225-1723 75 PUMP 110-100 20
Antimony (ICP analysis of metal/metalloid OSHA ID 206 0.5 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
particulates from solder operations)
Antimony (elements by ICP Aqua Regia ashing) NIOSH 7301 0.5 mg/m3 50-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Antimony (elements by ICP HNO3 digestion) NIOSH 7303 0.5 mg/m 3
3-100,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Antimony (elements) NIOSH 7300 1455 0.5 mg/m3 50-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Antimony & compounds (as Sb) OSHA ID 121 0.5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Antimony & compounds (as Sb) OSHA ID 125G 0.5 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
ANTU (alphanaphthyl thiourea) OSHA CSI 0.3 mg/m3 480 2000 4 HPLC-UV FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Apron OSHA PV2102 60 1000 1 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Aqua fortis (acids, inorganic) NIOSH 7903 2 4 48 200 4 IC ST 226-10-03 37
Aroclor ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Aroclor NIOSH 5602 480 1000 8 GC-ECD ST 226-58 38
Aroclor 1242 ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Aroclor 1242 (42% Cl) (see polychlorobiphenyls) NIOSH 5503
Aroclor 1254 (54% Cl) (see polychlorobiphenyls) NIOSH 5503
Aromatic hydrocarbons (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 40
Arsenic & compounds (as As) NIOSH 7900 2 µg/m3 (15 min) 30 2000 15 AA, FLAG F/CST 225-3-01 71 C/HLD 225-1 78
Arsenic (elements by ICP Aqua Regia ashing) NIOSH 7301 0.002 mg/m3 5-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Arsenic (elements by ICP HNO3 digestion) NIOSH 7303 0.002 mg/m3 8-5,000,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Arsenic (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Arsenic (elements) NIOSH 7300 1040 0.002 mg/m3 C 5-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Arsenic (inorganic compounds as As) OSHA ID 105 0.01 mg/m3 960 2000 8 AAS-HGA F/CST 225-3-01 71 C/HLD 225-1 78
Arsenic trioxide as AS NIOSH 7901 2 mg/m3 (15 min) 30 2000 15 FLT 225-5‡ 70 CST 225-2LF 79
C/HLD 225-1 78
Arsenic, inorganic (volatile compounds as As) OSHA ID 105 0.01 mg/m3 960 2000 8 AAS-HGA CF/CST 225-9001 59 C/HLD 225-1 78
Arsenic, organo- NIOSH 5022 960 2000 8 IC-AA FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78

Sampling Guide
A Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Arsine NIOSH 6001 1278 2 µg/m3 (15 min) 10 3 20 200 8 15 AAS-GF ST 226-01 37
Arylam (see carbaryl)
Asbestos OSHA ID 160 1301 0.1 fbr/cc 1 fbr/cc EL 25-1200 25-1200 500-2500 500-2500 varies varies PCM FLT/CL 225-321 or FLT/CL 225-326 or
FLT/CL 225-321A or FLT/CL 225-327 71
Asbestos (bulk) by PLM NIOSH 9002 1% (bulk) bulk PLM
Asbestos (mass concentrations) ASTM D 5756 1440 varies 2000 2 min (minimum) TEM MVC 225-322 113
Asbestos (structure number concentrations) ASTM D 5755 1440 varies 2000 2 min (minimum) TEM MVC 225-322 113
Asbestos by TEM NIOSH 7402 0.1 fbr/cc/400L 960 2000 8 TEM FLT/CL 225-327 71
Asbestos fibers NIOSH 7400 1033 0.1 fbr/cc/400L varies varies varies PCM FLT/CL 225-321 or FLT/CL 225-326 or
FLT/CL 225-321A or FLT/CL 225-327 71
Asbestos, chrysotile NIOSH 9000 bulk XRD
Aspartame NIOSH 5031 480 1000 8 HPLC-UV FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Aspergillus flavipes species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Aspergillus flavipes species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Aspergillus flavus species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Aspergillus flavus species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Aspergillus fumigatus species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Aspergillus fumigatus species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Aspergillus glaucus species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Aspergillus glaucus species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Aspergillus nidulans species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Aspergillus nidulans species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Aspergillus niger species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Aspergillus niger species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Aspergillus ochraceus (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Aspergillus ochraceus (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Aspergillus versicolor (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Aspergillus versicolor (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Asphalt fume (benzene-soluble & total particulate) NIOSH 5042 5 mg/m3 360 60 1000 4000 6 15 GR FLT 225-27-07 75 SP 225-27 78
(15 min) (C) CST 225-2LF 79
Asphalt fume particulate ASTM D 6494 960 2000 8 GR F/CST 225-1713 75 C/HLD 225-1 78
Asphalt fumes (petroleum) OSHA 58 1078 960 2000 8 GR, HPLC- FLT 225-7 74 CST 225-2LF 79
FD, -UV C/HLD 225-1 78
Atrazine ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 42
Atrazine NIOSH 5602 5 480 1000 8 GC-ECD ST 226-58 38
Atrazine OSHA CSI 240 1000 4 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Auramine OSHA CSI 100 1000 100 min HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Aureobasidium pullulans (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Aureobasidium pullulans (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Aureobasidium species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Aureobasidium species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Azelaic acid NIOSH 5019 960 2000 8 GC-FID F/CST 225-803 73 C/HLD 225-1 78
Azinphos-ethyl OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Azinphos-methyl OSHA PV2087 0.2 mg/m3 480 1000 8 GC-FPD ST 226-30-16 37
Azinphos-methyl (organophosphorus pesticides) NIOSH 5600 0.2 mg/m3 240 1000 4 GC-FPD ST 226-58 38
1,1’-Azobisformamide OSHA CSI 90 1000 1.5 HPLC-UV ST 226-30-16 37
Bacillus anthracis NIOSH F/CST 225-1723 75 PUMP 110-100 20
Bacteria NIOSH 0800 varies 28300 varies varies BI 225-9611 94
Bacteria by GC-FAME NIOSH 0801 50-300 28300 varies GC-FID BI 225-9611 94
Bacteria in air NON 48 62.5-375 12500 + 5-30 varies BS 225-9595 93 VT 225-9598A◊ 93
Barium (elements by ICP Aqua Regia ashing) NIOSH 7301 0.5 mg/m3 50-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Barium (elements by ICP HNO3 digestion) NIOSH 7303 1-100,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Barium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Barium (insoluble compounds) OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Barium (soluble compounds) NIOSH 7056 0.5 mg/m3 960 2000 8 AA F/CST 225-3-01 71 C/HLD 225-1 78
Barium (soluble compounds) OSHA ID 121 0.5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Barium chloride (barium, soluble compounds) NIOSH 7056 0.5 mg/m3 960 2000 8 AA F/CST 225-3-01 71 C/HLD 225-1 78
Barium sulfate (respirable fraction) OSHA ID 204 1216 5 mg/m3 varies varies varies
Bendiocarb ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92
Bendiocarb (Ficam ) OSHA PV2008 240 1000 4 HPLC-UV ST 226-30-16 37
Benomyl (organonitrogen pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Benomyl (respirable dust) OSHA CSI 5 mg/m3 varies varies varies HPLC-UV ST 226-30-16 37 CYC 225-105 84
Benomyl (total dust) OSHA PV2107 15 mg/m3 60 1000 1 HPLC-UV ST 226-30-16 37
Bentonite (see dust, total and respirable nuisance)
Benz(a)anthracene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Benz(a)anthracene OSHA CSI 960 2000 8 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Benz(a)anthracene (polynuclear aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 75 ST 226-30-04 37
hydrocarbons) C/HLD 225-1 78
Benz(a)anthracene (polynuclear aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
Benzaldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number B
Benzene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Benzene  OSHA 1005 1749 1 5 12 0.75 50 50 4 15 GC-FID ST 226-01 37
Benzene  OSHA 12 1009 1 5 10 3 200 200 50 min 15 GC-FID ST 226-01 37
Benzene (hydrocarbons, aromatic)  NIOSH 1501 0.1 1 5-30 5-30 10-200 10-200 varies varies GC-FID ST 226-01 37
Benzene by portable GC NIOSH 3700 1029 0.1 1 (15 min) varies varies varies P GC-PID SB 232 Series 52
alpha-Benzene hexachloride ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
beta-Benzene hexachloride ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
gamma-Benzene hexachloride ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Benzene-soluble & total particulate (asphalt fume) NIOSH 5042 5 mg/m3 360 60 1000 4000 6 15 GR FLT 225-27-07 75 SP 225-27 78
(15 min) (C) CST 225-2LF 79
Benzene-soluble particulate matter ASTM D 4600 1416 960 2000 8 GR FLT 225-7 74 SP 225-27 78
CST 225-2LF 79 C/HLD 225-1 78
1,2-Benzenedicarboxylic acid OSHA CSI 240 1000 4 GC-FID ST 226-56 38
Benzidine NIOSH 5509 LFC 96 200 8 HPLC-UV FLT 225-16 74 CST 225-32 78
Benzidine OSHA 65 1239 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
Benzidine dyes (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
Benzidine-based dyes OSHA CSI 480 1000 8 HPLC-UV FLT 225-17-04 75 CST 225-3LF 79
C/HLD 225-1 78
Benzo(a)pyrene ASTM D 6209 350 m (max)
3
225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
PEM 761-200 88
Benzo(a)pyrene (polynuclear aromatic hydrocarbons) NIOSH 5506
Benzo(a)pyrene (polynuclear aromatic hydrocarbons) NIOSH 5515 0.1 mg/m3 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Benzo(b)fluoranthene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
PEM 761-203B 88 FLT 225-1709 75
Benzo(b)fluoranthene (polynuclear aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 75 ST 226-30-04 37
Benzo(b)fluoranthene (polynuclear aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
Benzo(e)pyrene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Benzo(e)pyrene OSHA CSI 960 2000 8 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Benzo(e)pyrene (polynuclear aromatic hydrocarbons) NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Benzo(e)pyrene (polynuclear aromatic hydrocarbons) NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Benzo(g,h,i)perylene ASTM D 6209 350 m (max)
3
225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Benzo(g,h,i)perylene (polynuclear aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 75 ST 226-30-04 37
Benzo(g,h,i)perylene (polynuclear aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
Benzo(k)fluoranthene (polynuclear aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 75 ST 226-30-04 37
Benzo(k)fluoranthene (polynuclear aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
Benzoalphapyrene (BAP) OSHA 58 0.2 mg/m3 960 2000 8 GR, HPLC- FLT 225-7 74 CST 225-2LF 79
FD, -UV C/HLD 225-1 78
2,3-Benzofuran OSHA CSI 96 200 8 HPLC-UV ST 226-30 37
Benzoic acid OSHA CSI 24 100 4 GC-FID ST 226-115 39
Benzophenone NON 39 480 1000 8 GC-FID ST 226-56 38
Benzophenone OSHA PV2130 0.5 mg/m3 48 200 4 GC-FID ST 226-110 37
Benzophenonetetracarboxylic acid dianhydride OSHA CSI 100 1000 100 min HPLC FLT 225-17-04 75 CST 225-2LF 79
C/HLD 225-1 78
Benzothiazole in asphalt fume NIOSH 2550 480 1000 8 GC-SCD F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
2-Benzothiazolethiol OSHA CSI 240 2000 2 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Benzotrichloride  OSHA ID 216SG 12 200 1 GC-FID ST 226-35-03 37
Benzotrifluoride (trifluoromethylbenzene, OXSOL 2000)  100 GC-FID PS 575-001 or PS 575-002 63
Benzoyl chloride OSHA CSI 90 1000 1.5 GC-ECD IMP 225-36-1 61 IT 225-22 61
Benzoyl peroxide NIOSH 5009 5 mg/m3 90 1500 1 HPLC-UV F/CST 225-3-01 71 C/HLD 225-1 78
Benzyl acetate  OSHA PV2124 10 20(50) 8(3.3) GC-FID ST 226-01 37
Benzyl alcohol OSHA PV2009 24 100 4 GC-FID ST 226-95 39
Benzyl bromide OSHA CSI DET TB DT 810-136L
Benzyl chloride  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Benzyl chloride  OSHA 07 1187 1 10 20(50) 8(3.3) GC-FID ST 226-01 37
Benzyl chloride (hydrocarbons, halogenated)  NIOSH 1003 1 10 10-200 varies GC-FID ST 226-01 37
Beryllium (elements by ICP Aqua Regia ashing) NIOSH 7301 0.0005 mg/m3 1250-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Beryllium (elements by ICP HNO3 digestion) NIOSH 7303 35-25,000,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Beryllium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Beryllium (elements) NIOSH 7300 1455 0.0005 mg/m3 1250-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Beryllium (ICP analysis of metal/metalloid OSHA ID 206 2 mg/m3 5 mg/m3 (C) 480 10 2000 2000 4 5 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Beryllium & compounds OSHA ID 125G 2 µg/m 3
5 µg/m 3
480 60 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Beryllium & compounds (as Be) NIOSH 7102 0. 5 µg/m 9603
2000 8 AA-GF F/CST 225-3-01 71 C/HLD 225-1 78

Sampling Guide
B Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Betasan OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37

BHC (alpha-, beta-, gamma-) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Bioaerosol sampling NIOSH 0800 varies 28.3 L/min varies varies BI 225-9611 94
Bioaerosols 15-150 15 L/min 1-10 min varies STC 225-9820 77
Bioaerosols NON 48 62.5-375 12500 + 5-30 varies BS 225-9595 93 VT 225-9598A◊ 93
Biphenyl (diphenyl) NIOSH 2530 0.2 10 20(50) 8(3.3) GC-FID ST 226-35-01 37
Bipolaris species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Bipolaris species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
4,4’-Bipyridine (vapor & aerosol) NON 26 96 2 200 200 8 10 HPLC ST 226-30-05 37 F/CST 225-706 74
C/HLD 225-1 78
Bis (tributyltin) oxide (tin, organic compounds [as Sn]) OSHA CSI 960 2000 8 AA-GF F/CST 225-709 74 C/HLD 225-1 78
Bismuth OSHA CSI 960 2000 8 AA F/CST 225-3-01 71 C/HLD 225-1 78
Bismuth (elements by ICP HNO3 digestion) NIOSH 7303 1-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Bismuth telluride, Se-doped OSHA ID 121 5 mg/m3 960 2000 8 AA or AES FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Bismuth telluride, undoped (respirable dust) OSHA ID 121 5 mg/m3 varies varies varies AA or AES CYC 225-105 84 C/HLD 225-1 78
FLT 225-8-01 85 CST 225-3LF 79
Bismuth telluride, undoped (total dust) OSHA CSI 15 mg/m3 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Bisphenol A OSHA CSI 360 1500 4 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Bladex OSHA CSI 100 1000 100 min HPLC-UV IMP 225-36-1 61 IT 225-22 61
Borates tetrasodium salts (anhydrous, decahy- OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
drate & pentahydrate) C/HLD 225-1 78
Boric acid OSHA CSI 960 2000 8 GR, ICP- FLT 225-8-01 73 C/HLD 225-1 78
DCP CST 225-2LF 79
Boron OSHA CSI 960 2000 8 GR, ICP- FLT 225-8-01 73 C/HLD 225-1 78
DCP CST 225-2LF 79
Boron (elements by ICP HNO3 digestion) NIOSH 7303 1-3300 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Boron carbide NIOSH 7506 600 2500 4 XRD F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Boron oxide (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Boron oxide (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Boron oxide (total dust) OSHA CSI 15 mg/m 3
480 2000 4 ICP-AES FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Boron tribromide OSHA CSI 5 1000 5 IC IMP 225-36-2 61 IT 225-22 61
Boron trifluoride OSHA CSI 1 (C) 15 1000 15 ISE IMP 225-36-2 61 IT 225-22 61
Botran OSHA CSI 400 1000 6.7 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Bromacil OSHA CSI 50 1000 50 min HPLC-UV IMP 225-36-1 61 IT 225-22 61
Bromine NIOSH 6011 1329 0.1 0.3 240 15 1000 1000 4 15 IC CF/CST 225-9006 59 C/HLD 225-1 78
Bromine OSHA ID 108 0.1 120 7.5 500 500 4 15 IC IMP 225-36-2 61 IT 225-22 61
Bromine pentafluoride OSHA CSI 48 200 4 IC ST 226-10-03 37
Bromoethane (ethyl bromide)  NIOSH 1011 4 20(50) 3.3(1.3) GC-FID ST 226-01 37
Bromoform  OSHA 07 1127 0.5 10 20(50) 8(3.3) GC-FID ST 226-01 37
Bromoform (hydrocarbons, halogenated) NIOSH 1003 0.5 (skin) 10 10-200 varies GC-FID ST 226-01 37
1-Bromopropane  NIOSH 1025 0.1-12 10-200 varies GC-FID ST 226-01 or ST 226-121 39
1-Bromopropane  OSHA PV2061 12 100 2 GC-FID ST 226-01 37
2-Bromopropane NIOSH 1025 0.1-12 10-200 varies GC-FID ST 226-01 or ST 226-121 39
2-Bromopropane OSHA PV2062 12 100 2 GC-FID ST 226-01 37
Bromotrifluoromethane (trifluorobromomethane) NIOSH 1017 1000 0.3 20 15 min GC-FID ST 226-09 37 ST 226-01 37
Bromoxynil NIOSH 5010 240 1000 4 HPLC-UV F/CST 225-1713 75 C/HLD 225-1 78
Bromoxynil octanoate NIOSH 5010 240 1000 4 HPLC-UV F/CST 225-1713 75 C/HLD 225-1 78
Bronkosol OSHA CSI 480 1000 8 HPLC F/CST 225-706 74 C/HLD 225-1 78
Brucine OSHA CSI 180 1000 3 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
1,3-Butadiene  NIOSH 1024 1010 LFC 10 20 8 GC-FID ST 226-37 38
1,3-Butadiene  OSHA 56 1011 1 5 3 50 1 GC-FID ST 226-73 38
Butane OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
1,3-Butanediol OSHA CSI 60 2000 30 min GC-FID ST 226-57 38
1-Butanethiol (butyl mercaptan) NIOSH 2525 0.5 1 50 15 GC-FPD ST 226-109 39
n-Butanol (alcohols combined)  NIOSH 1405 50 (skin) 2-10 10-200 varies GC-FID ST 226-01 37
2-Butanone OSHA 1004 1745 200 12 50 4 GC-FID ST 226-121 39
2-Butanone (ketones I) NIOSH 2555 1-10 10-200 varies GC-FID ST 226-121 39
2-Butanone (methyl ethyl ketone, MEK)  NIOSH 2500 1012 200 300 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-81A or ST 226-121 39
2-Butanone (methyl ethyl ketone, MEK)  OSHA 16 1282 200 3 1.5 100 100 30 min 15 GC-FID ST 226-10 37
2-Butanone (methyl ethyl ketone, MEK)  OSHA 84 1288 200 3 0.75 50 50 1 15 GC-FID ST 226-121 39
Butene OSHA CSI 1 20 50 min GC-FID ST 226-01 37
2-Butoxyethanol (alcohols IV)  NIOSH 1403 1275 5 (skin) 2-10 10-50 varies GC-FID ST 226-01 37
2-Butoxyethanol (butyl CELLOSOLVE solvent)  OSHA 83 50 48 100 8 GC-FID ST 226-01 37
2-Butoxyethanol acetate (butyl CELLOSOLVE acetate)  OSHA 83 48 100 8 GC-FID ST 226-01 37
n-Butyl acetate  OSHA 07 150 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
n-Butyl acetate  OSHA 1009 1750 150 12 0.75 50 50 4 15 GC-FID ST 226-01 37
n-Butyl acetate  OSHA 1009 1750 150 13.07 13.07 8 15 GC-FID PS 575-002 63
sec-Butyl acetate  OSHA 07 200 10 20(50) 8(3.3) GC-FID ST 226-01 37

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number B
sec-Butyl acetate  OSHA 1009 1750 200 12 0.75 50 50 4 15 GC-FID ST 226-01 37
sec-Butyl acetate  OSHA 1009 1750 200 12.74 12.74 8 15 GC-FID PS 575-002 63
t-Butyl acetate  OSHA 07 200 10 20(50) 8(3.3) GC-FID ST 226-01 37
t-Butyl acetate  OSHA 1009 1750 200 12 0.75 50 50 4 15 GC-FID ST 226-01 37
t-Butyl acetate  OSHA 1009 1750 200 13.09 13.09 8 15 GC-FID PS 575-002 63
n-Butyl acetate (esters I)  NIOSH 1450 1272 150 200 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 37
sec-Butyl acetate (esters I)  NIOSH 1450 200 1-10 10-200 varies GC-FID ST 226-01 37
t-Butyl acetate (esters I)  NIOSH 1450 200 1-10 10-200 varies GC-FID ST 226-01 37
Butyl acrylate  OSHA PV2011 12 50 4 GC-FID ST 226-73 38
n-Butyl acrylate  NON 54 5 15 10 3 20 200 8 15 GC-FID ST 226-81A 38
n-Butyl alcohol  OSHA 07 100 10 1 20 200 8 5 GC-FID ST 226-01 37
sec-Butyl alcohol  OSHA 07 150 10 20(50) 8(3.3) GC-FID ST 226-01 37
t-Butyl alcohol  OSHA 07 100 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
n-Butyl alcohol (alcohols combined)  NIOSH 1405 50 (skin) 2-10 10-200 varies GC-FID ST 226-01 37
sec-Butyl alcohol (alcohols combined)  NIOSH 1405 100 150 2-10 2-10 10-200 10-200 varies varies GC-FID ST 226-01 37
t-Butyl alcohol (alcohols I)  NIOSH 1400 100 150 10 20(50) 8(3.3) GC-FID ST 226-01 37
n-Butyl alcohol (alcohols II)  NIOSH 1401 50 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
sec-Butyl alcohol (alcohols II)  NIOSH 1401 100 150 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Butyl benzyl phthalate OSHA CSI 180 1000 3 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Butyl butryrate OSHA PV2090 10 200 50 min GC-FID ST 226-01 37
Butyl carbitol OSHA PV2095 10 200 50 min GC-FID ST 226-01 37
Butyl carbitol acetate OSHA PV2095 10 200 50 min GC-FID ST 226-01 37
Butyl CELLOSOLVE acetate (see 2-butoxyethanol acetate)  OSHA 83
Butyl CELLOSOLVE solvent (see 2-butoxyethanol)  OSHA 83
t-Butyl chromate OSHA ID 215 0.005 mg/m3 960 2000 15 IC-UV F/CST 225-802 73 C/HLD 225-1 78
t-Butyl ethyl ether (ethyl tert-butyl ether)  GC-FID PS 575-001 63
n-Butyl glycidyl ether  NIOSH 1616 5.6 (15 min) 3 200 15 GC-FID ST 226-01 37
t-Butyl glycidyl ether OSHA CSI 10 200 50 min GC-FID ST 226-01 37
n-Butyl glycidyl ether (BGE)  OSHA 07 1125 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
Butyl isocyanate OSHA CSI 15 50 5 HPLC-UV ST NA SKC 39
n-Butyl lactate OSHA PV2080 10 200 50 min GC-FID ST 226-01 37
n-Butyl mercaptan NIOSH 2525 0.5 1 50 15 GC-FPD ST 226-109 39
Butyl mercaptan (butanethiol) OSHA CSI 10 1.5 25 1 GC-FPD ST 226-109 39
n-Butyl mercaptan (mercaptans) NIOSH 2542 1330 0.5 (15 min) 48 12 100 200 8 60 GC-FPD CF/CST 225-9007 59 C/HLD 225-1 78
t-Butyl methyl ether  OSHA CSI 96 200 8 GC-FID ST 226-37 38
Butyl ziram OSHA PV2065 180 1000 3 HPLC-UV ST 226-30-16 37
N-t-Butyl-2-benzothiazolesulfenamide OSHA CSI 120 1000 2 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Butylamine  OSHA CSI 5 (C) 5 1000 5 GC-FID ST 226-53 38
n-Butylamine  NIOSH 2012 5 15 1000 15 GC-FID ST 226-53 38
Butylated hydroxytoluene OSHA PV2108 100 1000 100 min GC-FID ST 226-57 38
sec-Butylbenzene OSHA CSI 6 100 1 GC-FID ST 226-01 37
1,3-Butylene glycol (glycols) NIOSH 5523 1404 60 1000 1 GC-FID ST 226-57 38
o-sec-Butylphenol OSHA CSI 10 100 1.6 HPLC-UV ST 226-95 39
p-tert-Butylphenol OSHA PV2085 20 200 100 min GC-FID ST 226-95 39
Butyltin trichloride OSHA ID 217SG 240 1000 4 AA-GF ST 226-30-16 37
p-tert-Butyltoluene  OSHA 07 1129 10 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
p-tert-Butyltoluene (hydrocarbons, aromatic)  NIOSH 1501 10 20 1-29 1-29 10-200 10-200 varies varies GC-FID ST 226-01 37
Butyraldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
Butyraldehyde (aldehydes, screening) NIOSH 2539 5 20 4 GC-FID & GC-MS ST 226-118 39
Butyric acid OSHA CSI 18 100 3 GC-FID ST 226-15 37
beta-Butyrolactone  OSHA CSI 9.6 20 8 GC-FID ST 226-01 37
gamma-Butyrolactone  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Cadmium OSHA ID 189 1456 5 µg/m3 960 2000 8 AA F/CST 225-3-01 71 C/HLD 225-1 78
Cadmium (elements by ICP Aqua Regia ashing) NIOSH 7301 LFC 13-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Cadmium (elements by ICP HNO3 digestion) NIOSH 7303 3-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Cadmium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Cadmium (elements) NIOSH 7300 1280 LFC 13-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Cadmium & compounds (as Cd) NIOSH 7048 1467 LFC 480 30 1000 2000 8 15 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Cadmium dust (as Cd) OSHA ID-121 0.2 mg/m3 0.5 mg/m3 960 30 2000 2000 8 15 AA F/CST 225-3-01 71 C/HLD 225-1 78
Cadmium dust (as Cd) OSHA ID-206 0.2 mg/m3 0.5 mg/m3 960 30 2000 2000 8 15 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Cadmium fume (ICP analysis of metal/metalloid OSHA ID 206 0.1 mg/m3 0.3 mg/ 480 2000 4 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
particulates from solder operations) m3 (C)
Calcium (elements by ICP Aqua Regia ashing) NIOSH 7301 varies 5-200 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Calcium (elements by ICP HNO3 digestion) NIOSH 7303 2-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Calcium (elements) NIOSH 7300 1455 varies 5-200 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Calcium (see specific compounds) NIOSH 7020 varies varies varies varies AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Calcium & compounds (as Ca) NIOSH 7020 varies 240 1000 4 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Calcium arsenate (as As) OSHA CSI 600 2000 5 AA-GF F/CST 225-3-01 71 C/HLD 225-1 78
Calcium bromide (see dust, total & respirable nuisance) OSHA CSI

Sampling Guide
C Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Calcium carbonate OSHA ID 121 15 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Calcium carbonate (calcium) NIOSH 7020 2 mg/m3 240 1000 4 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Calcium carbonate (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Calcium carbonate (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Calcium carbonate (see dust, total & respirable nuisance)
Calcium cyanamide OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Calcium hydroxide OSHA ID 121 5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Calcium hydroxide (calcium) NIOSH 7020 2 mg/m3 240 1000 4 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Calcium hydroxide (see dust, total & respirable nuisance)
Calcium oxide OSHA ID 121 5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Calcium oxide (calcium) NIOSH 7020 2 mg/m3 240 1000 4 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Calcium oxide (elements by ICP HNO3 digestion) NIOSH 7303 2 mg/m3 3-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Calcium silicate (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Calcium silicate (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Calcium sulfate (see dust, total & respirable nuisance)
Camphor  OSHA 07 1130 2 mg/m3 10 20(50) 8(3.3) GC-FID ST 226-01 37
Camphor (ketones II )  NIOSH 2553 2 1-25 10-200 varies GC-FID ST 225-121 39
Camphor (ketones II)  NIOSH 1301 2 10 20(50) 8(3.3) GC-FID ST 226-01 37
Caprolactam OSHA PV2012 100 1000 100 min HPLC-UV ST 226-57 38
Capsaicin NIOSH 5041 480 15 1 1 8 15 HPLC-FD FLT 225-16 74 CST 225-32 78
Captafol (difolatan) OSHA CSI 240 1000 4 GC-ECD ST 226-30-16 37
Captan ASTM D 4861 240-7200 1000- 5000 4- 24 GC-ECD PUF 226-92 42
Captan OSHA PV2093 60 1000 1 HPLC-UV ST 226-30-16 37
Captan (organonitrogen pesticides) NIOSH 5601 5 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Carbadox OSHA CSI 120 1000 2 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Carbaryl ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Carbaryl (organonitrogen pesticides) NIOSH 5601 5 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Carbaryl (Sevin) NIOSH 5006 5 mg/m3 240 1000 4 VAS F/CST 225-706 74 C/HLD 225-1 78
Carbaryl (Sevin) OSHA 63 5 mg/m3 60 1000 1 HPLC-UV ST 226-30-16 37
Carbazol OSHA CSI 120 1000 2 GC-FID ST 226-56 38
Carbendazim (organonitrogen pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Carbitol OSHA PV2013 10 200 50 min GC-FID ST 226-01 37
Carbitol acetate OSHA PV2013 10 200 50 min GC-FID ST 226-01 37
Carbofuran ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Carbofuran (organonitrogen pesticides) NIOSH 5601 0.1 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Carbon black NIOSH 5000 3.5 mg/m3 360 1500 4 GR FLT 225-8-01 73 CST 225-3LF 79
SCN 225-26 78 C/HLD 225-1 78
Carbon black OSHA ID 196 3.5 mg/m 3
960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Carbon dioxide  NIOSH 6603 1027 5000 30,000 5 0.75 varies varies 1.5 15 P GC-TCD SB 231-05 53 SB 232-05 52
Carbon dioxide  OSHA ID 172 1026 5000 5 4.5 50 300 100 min 15 GC-TCD SB 231-05 or SB 232-05 or
SB 245-03A 52
Carbon disulfide NIOSH 1600 1 10 10 3 20(50) 200 8(3.3) 15 GC-FPD ST 226-01 37 DRT 226-44 38
Carbon monoxide  NIOSH 6604 35 200 varies varies varies ELCHM DRI 805-43846
Carbon monoxide  OSHA ID 209 50 DRI DRI 805-30011 ..
Carbon monoxide  OSHA ID 210 1021 50 5 5 50 1000 100 min 5 GC-DID SB 245-05 or SB 245-25 52
Carbon tetrabromide OSHA CSI 9 3 50 200 3 15 GC-ECD ST 226-93 39
Carbon tetrachloride  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Carbon tetrachloride  OSHA 07 1131 10 25 15 3 50 200 5 15 GC-FID ST 226-01 37
Carbon tetrachloride (hydrocarbons, halogenated)  NIOSH 1003 2 (1 hr) 15 10-200 varies GC-FID ST 226-01 37
Carbon, activated (see dust, total nuisance)
Carbonyl fluoride OSHA CSI 480 2000 4 ISE IMP 225-36-2 61 IT 225-22 61
Carboxin OSHA CSI 200 1000 3.3 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
3-Carene (terpenes)  NIOSH 1552 24 50 8 GC-FID ST 226-01 37
Catechol (pyrocatechol) OSHA PV2014 100 1000 100 min HPLC-UV ST 226-57 39
Cell fragments (bioaerosols) 15-150 15 L/min 1-10 min varies STC 225-9820 77
CELLOSOLVE acetate (see 2-ethoxyethyl acetate) 
CELLOSOLVE solvent (see 2-ethoxyethanol) (alcohols IV)  NIOSH 1403 1273
Cellulose (paper fiber) (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Cellulose (paper fiber) (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Cellulose (see dust, total or respirable nuisance)
Cellulose insulation NIOSH 7404 varies 1000 varies SEM FLT/CL 225-1604 73
Cerium OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Cesium hydroxide OSHA CSI 960 2000 8 AA F/CST 225-3-01 71 C/HLD 225-1 78
Chaetomium species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Chaetomium species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Chloramphenicol OSHA CSI 60 1000 1 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number C
Chlordane NIOSH 5510 0.5 mg/m3 150 1000 2.5 GC-ECD ST 226-107 39 FLT 225-5
CST 225-2LF 79 SCN 225-26 78
C/HLD 225-1 78
Chlordane OSHA 67 1013 0.5 mg/m3 480 1000 8 GC-ECD ST 226-30-16 37
Chlordane (non-occupational exposure) ASTM D 4947 1417 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Chlordane (technical) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Chlorinated & organonitrogen herbicides NIOSH 5602 480 1000 8 GC-ECD ST 226-58 38
Chlorinated & organonitrogen herbicides (hand wash) NIOSH 9200 GC-ECD NA SKC
Chlorinated camphene (Toxaphene) NIOSH 5039 LFC 30 15 1000 1000 0.5 15 GC-ECD F/CST 225-3-01 71 C/HLD 225-1 78
Chlorinated diphenyl ether (chlorinated diphenyl oxide) NIOSH 5025 0.5 mg/m3 180 1000 3 GC-ECD F/CST 225-3-01 71 C/HLD 225-1 78
Chlorinated diphenyl oxide NIOSH 5025 0.5 mg/m3 90 1000 1.5 GC-ECD F/CST 225-3-01 71 C/HLD 225-1 78
Chlorinated hydrocarbons (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 40
Chlorinated terphenyl (60% chlorine) NIOSH 5014 720 1500 8 GC-ECD F/CST 225-706 74 C/HLD 225-1 78
Chlorine  NIOSH 6011 1332 0.5 1 90 15 1000 1000 1.5 15 IC CF/CST 225-9006 59 C/HLD 225-1 78
Chlorine  OSHA ID 101 1052 1 (C) 240 15 1000 1000 4 15 ISE IMP 225-36-2 61 IT 225-22 61
Chlorine (prefiltered) OSHA ID 101 1289 1 (C) 240 15 1000 1000 4 15 ISE IMP 225-36-2 61 IT 225-22 61
CST 225-3-23** 79 SP 225-2901** 78
FLT 225-2708** 75
Chlorine dioxide OSHA ID 202 1462 0.1 120 7.5 500 500 4 15 IC-ECN IMP 225-36-2 61 IT 225-22 61
Chlorine trifluoride OSHA CSI 0.1 15 1000 15 ISE IMP 225-36-2 61 IT 225-22 61
1-Chloro-1-nitropropane OSHA CSI 20 12 50 4 GC-FID ST 226-113 39
5-Chloro-2-methyl-4-isothiazolin-3-one (Kathon 886) NON 55 0.75 mg/m3 0.23 mg/m3 50 7.5 200 500 4 15 HPLC-UV ST 226-99 39
1-Chloro-4-(trifluoromethyl)benzene  OSHA CSI 6 100 1 GC-FID ST 226-01 37
(parachlorobenzotrifluoride)
2-Chloro-6-trichloromethyl pyridine (respirable dust) OSHA CSI 15 mg/m3 480 1000 8 HPLC-UV ST 226-30-16 37 CYC 225-105 84
2-Chloro-6-trichloromethyl pyridine (total dust) OSHA CSI 5 mg/m3 varies varies varies HPLC-UV ST 226-30-16 37
Chloroacetaldehyde NIOSH 2015 1 3 200 15 GC-ECD ST 226-15GWS 37
Chloroacetaldehyde OSHA 76 1 (C) 2.5 500 5 GC-ECD ST 226-15GWS 37
Chloroacetic acid NIOSH 2008 48 100 8 IC-ECN ST 226-47-01 38
alpha-Chloroacetophenone (phenacylchloride) OSHA CSI 0.05 12 200 1 HPLC-UV ST 226-35-02 37
Chloroacetyl chloride OSHA CSI 10 50 3.3 HPLC-UV ST NA SKC 39
o-Chloroaniline OSHA CSI 5 20 4 HPLC-UV ST 226-10 37
p-Chloroaniline OSHA PV2109 6 100 1 HPLC-UV ST 226-10 37
Chlorobenzene (monochlorobenzene)  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Chlorobenzene (monochlorobenzene)  OSHA 07 1132 75 10 20(50) 8(3.3) GC-FID ST 226-01 37
Chlorobenzene (monochlorobenzene)  NIOSH 1003 10 10-200 varies GC-FID ST 226-01 37
(hydrocarbons, halogenated)
4-Chlorobenzotrifluoride  NIOSH 1026 0.1-10.0 10-200 varies GC-FID ST 226-01 37
4-Chlorobenzotrifluoride  OSHA CSI 6 100 1 GC-FID ST 226-01 37
p-Chlorobenzotrifluoride  NIOSH 1026 0.1-10.0 10-200 varies GC-FID ST 226-01 37
p-Chlorobenzotrifluoride  OSHA CSI 6 100 1 GC-FID ST 226-01 37
Chlorobiphenyl NIOSH 5503 0.001 mg/m3 48 100(200) 8(4) GC-ECD FLT 225-16 74 CST 225-32 78
(10 hr) ST 226-39 38
Chlorobromomethane  OSHA CSI 200 5 20 4 GC-FID ST 226-01 37
Chlorobromomethane (hydrocarbons, halogenated)  NIOSH 1003 200 5 10-200 varies GC-FID ST 226-01 37
Chlorodifluoromethane OSHA CSI 1 50 20 min GC-FID ST 226-121 39
Chlorodiphenyl OSHA CSI 60 1000 1 GC-ECD ST 226-30-16 37
Chlorodiphenyl (21% Cl) (see polychlorinated biphenyls) OSHA CSI
Chlorodiphenyl (42% Cl) OSHA PV2089 1 60 1000 1 GC-ECD ST 226-30-16 37
Chlorodiphenyl (42% Cl) (see polychlorinated biphenyls) NIOSH 5503
Chlorodiphenyl (54% Cl) OSHA PV2088 0.5 60 1000 1 GC-ECD ST 226-30-16 37
Chlorodiphenyl (54% Cl) (see polychlorinated biphenyls) NIOSH 5503
Chloroethane (ethyl chloride) NIOSH 2519 3 50 1 GC-FID ST 226-09 37
2-Chloroethanol (ethylene chlorohydrin) NIOSH 2513 1 10 20(50) 8(3.3) GC-FID ST 226-81A 38
Chloroform (trichloromethane)  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Chloroform (trichloromethane)  OSHA 05 1062 50 (C) 10 200 50 min GC-FID ST 226-01 37
Chloroform (trichloromethane)  NIOSH 1003 1269 2 15 10-200 varies GC-FID ST 226-01 37
bis-Chloromethyl ether OSHA 10 50 500 100 min GC-ECD IMP 225-36-2 61 IT 225-22 61
Chloromethyl methyl ether (CMME) NON 29 1251 2.4 0.3 10 20 4 15 GC-ECD ST 226-125 39
Chloromethyl methyl ether (CMME) OSHA 10 50 500 100 min GC-ECD IMP 225-36-2 61 IT 225-22 61
4-Chloronitrobenzene (nitrobenzenes) NIOSH 2005 0.1 ppm 96 200 8 GC-FID ST 226-10 37
Chloropentafluoroethane OSHA CSI 2.5 50 50 min GC-FID ST 226-01 37
Chlorophene OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-35 37
o-Chlorophenol OSHA CSI 40 200 3.3 HPLC-UV ST 226-10 37
p-Chlorophenol NIOSH 2014 24 50 8 HPLC-UV ST 226-10 37
Chloropicrin NON 51 0.1 144 100 24 GC-ECD, ST 226-175 40
GC-MSD
Chloropicrin OSHA PV2103 0.1 3 200 15 min GC-ECD ST 226-93 39
beta-Chloroprene NIOSH 1002 1 (15 min) 1.5 100 15 GC-FID ST 226-01 37

Sampling Guide
C Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
beta-Chloroprene OSHA 07 1133 25 10 20(50) 8(3.3) GC-FID ST 226-01 37

beta-Chloroprene OSHA 112 25 6 50 2 GC-ECD ST 226-111A 39
o-Chlorostyrene  OSHA CSI 20 3 200 200 100 min 15 GC-FID ST 226-01 37
Chlorothalonil ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Chlorothalonil OSHA CSI 180 1000 3 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
o-Chlorotoluene  OSHA CSI 20 200 100 min GC-FID ST 226-01 37
Chlorotoluron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Chlorotrifluoroethylene OSHA CSI 10 200 50 min GC-FID ST 226-01 37
Chlorpropham (organonitrogen pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Chlorpyrifos (Dursban) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Chlorpyrifos (Dursban) OSHA 62 1394 480 1000 8 GC-FPD ST 226-30-16 37
Chlorpyrifos (organophosphorus pesticides) NIOSH 5600 0.2 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Chromic acid & chromates OSHA ID 215 1439 0.005 mg/m3 960 2000 8 15 IC-UV F/CST 225-802 73 C/HLD 225-1 78
Chromic acid & chromates (chromium hexavalent) NIOSH 7600 1 µg/m3 (10 hr) 240 1000 4 VAS F/CST 225-803 73 C/HLD 225-1 78
Chromic acid & chromates (chromium hexavalent) NIOSH 7604 1 µg/m3 (10 hr) 960 2000 8 IC-ECN F/CST 225-803 73 C/HLD 225-1 78
Chromium & compounds (as Cr) NIOSH 7024 1457 0.5 mg/m3 480 1000 8 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Chromium (elements by ICP Aqua Regia ashing) NIOSH 7301 0.5 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Chromium (elements by ICP HNO3 digestion) NIOSH 7303 0.5 mg/m3 8-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Chromium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Chromium (elements) NIOSH 7300 1455 0.5 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Chromium acetate OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Chromium carbonate OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Chromium metal & insoluble compounds OSHA ID 121 1043 1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Chromium metal & insoluble compounds OSHA ID 1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
125G C/HLD 225-1 78
Chromium phosphate OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Chromium soluble salts (except hexavalent) OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Chromium trioxide (CR(VI)) OSHA ID 215 0.005 mg/m3 960 2000 8 IC-UV F/CST 225-802‡ or FLT 225-1827‡ 74
(V2) CST 225-2LF 79 C/HLD 225-1 78
Chromium, hexavalent ASTM D 6832 varies 1000-5000 varies IC F/CST 225-802 or F/CST 225-1713 or
F/CST 225-709 or F/CST 225-401 74
Chromium, hexavalent NIOSH 7600 1032 1 µg/m (10 hr)
3
240 1000 4 VAS F/CST 225-802 73 C/HLD 225-1 78
Chromium, hexavalent NIOSH 7604 1032 1 µg/m3 (10 hr) 240 1000 4 IC-ECN F/CST 225-802 73 C/HLD 225-1 78
Chromium, hexavalent NIOSH 7605 0.001 mg/m3 1-400 1000-4000 varies IC-PCD-UV F/CST 225-802 73 C/HLD 225-1 78
(10 hr)
Chromium, hexavalent NIOSH 7703 0.001 mg/m3 10-1200 1000-4000 varies P VAS F/CST 225-802 73 C/HLD 225-1 78
(10 hr)
Chromium, hexavalent OSHA ID 103 1439 0.005 mg/ 960 30 2000 2000 8 15 DPP F/CST 225-802 73 C/HLD 225-1 78
m3 (C)
Chromium, hexavalent OSHA ID 215 1439 0.005 mg/m3 960 2000 8 15 IC-UV F/CST 225-802 73 C/HLD 225-1 78
Chromium, hexavalent OSHA W4001 0.005 mg/ IC-UV FLT 225-8-01-1 or FLT 225-1822 74
m3 (C)
Chromium, hexavalent (CR(VI)) OSHA ID 215 0.005 mg/m3 960 2000 8 IC-UV F/CST 225-802‡ or FLT 225-1827‡ 74
(V2) CST 225-2LF 79 C/HLD 225-1 78
Chromium, hexavalent (in settled dust) NIOSH 9101 bulk bulk CLR or VAS
or IC
Chrysene ASTM D 6209 350 m (max)
3
225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Chrysene OSHA 58 0.2 mg/m3 960 2000 8 GR, HPLC- FLT 225-7 74 CST 225-2LF 79
FD, -UV C/HLD 225-1 78
Chrysene (polynuclear aromatic hydrocarbons) NIOSH 5506 LFC 480 2000 4 HPLC-UV F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Chrysene (polynuclear aromatic hydrocarbons) NIOSH 5515 LFC 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Chrysosporium species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Chrysosporium species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Chrysotile (see asbestos fibers) NIOSH 9000 bulk XRD
Chrysotile fibers (see asbestos fibers) NIOSH 7400
Cladosporium species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Cladosporium species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Clopidol (respirable fraction) OSHA CSI 5 mg/m3 varies varies varies HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
CYC 225-105 84
Clopidol (total dust) OSHA CSI 15 mg/m3 120 1000 2 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Co-Ral (coumaphos) OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Coal dust (< 5% SiO2) OSHA CSI 2.4 mg/m3/ varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
(%SiO2+2) CYC 225-105 84 CST 225-3LF 79
Coal dust (> 5% SiO2) OSHA ID 142 (10 mg/m )/3
varies varies varies XRD F/CST 225-803 73 C/HLD 225-1 78
(%SiO2+2) CYC 225-105 84 CST 225-3LF 79
Coal tar naphtha (naphthas) NIOSH 1550 100 3 20 2.5 GC-FID ST 226-01 37
Coal tar pitch volatiles OSHA 58 1076 0.2 mg/m3 960 2000 8 GR, HPLC- FLT 225-7 74 CST 225-2LF 79
FD, -UV C/HLD 225-1 78
Cobalt OSHA ID 213 0.1 mg/m3 480 2000 6 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Cobalt (elements by ICP Aqua Regia ashing) NIOSH 7301 0.5 mg/m3 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
(dust, fume) C/HLD 225-1 78
Cobalt (elements by ICP HNO3 digestion) NIOSH 7303 0.5 mg/m3 3-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
(dust, fume)

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number C
Cobalt (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Cobalt (elements) NIOSH 7300 1455 0.05 mg/m3 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
(dust, fume)
Cobalt & compounds (as Co) NIOSH 7027 0.05 mg/m3 960 2000 8 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Cobalt acetate OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Cobalt carbonyl OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Cobalt hydrocarbonyl OSHA ID 121 1193 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
(as Co)
Cobalt metal, dust & fume OSHA ID 125G 0.1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Cobalt metal, dust & fume (as Co) OSHA ID 121 1210 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Coke oven emissions OSHA 58 0.15 mg/m3 960 2000 8 GR, HPLC- FLT 225-7 74 CST 225-2LF 79
FD, -UV C/HLD 225-1 78
Command (dimethazone) OSHA PV2066 60 1000 1 GC-ECD ST 226-30-16 37
Copper (dust [elements]) NIOSH 7300 1455 1 mg/m3 (dust) 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
0.1 mg/m3 (fume)
Copper (elements by ICP Aqua Regia ashing) NIOSH 7301 1 mg/m (dust)
3
5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
0.1 mg/m3 (fume) C/HLD 225-1 78
Copper (elements by ICP HNO3 digestion) NIOSH 7303 1 mg/m (dust)
3
15-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
0.1 mg/m3 (fume)
Copper (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Copper dust NIOSH 7029 1 mg/m3 480 1000 8 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Copper dusts & mists OSHA ID 125G 1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Copper dusts & mists (as Cu) OSHA ID 121 1205 1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Copper fume NIOSH 7029 0.1 mg/m3 480 1000 8 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Copper fume OSHA ID 121 1206 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Copper fume OSHA ID 125G 0.1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Copper fume (ICP analysis of metal/metalloid OSHA ID 206 0.1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Corn starch (see dust, respirable nuisance)
Coronene OSHA CSI 960 2000 8 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Corundum (Al2O3) (see alpha-alumina [total dust])
Corundum (emery) (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Corundum (emery) (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Corynebacterium species (bacteria) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Cotton dust (raw) OSHA CSI 1 mg/m3 2664 7.4 6 GR FLT 225-8-01 73 VERT. NA SKC
ELUTRIATOR
CST 225-3LF 79
Coumarin OSHA CSI 96 200 8 HPLC-UV ST 226-30-04 37
Crag herbicide (respirable dust) OSHA CSI 5 mg/m3 varies varies varies CLR F/CST 225-803 73 C/HLD 225-1 78
CYC 225-105 84
Crag herbicide (total dust) OSHA CSI 15 mg/m 3
90 1500 1 CLR F/CST 225-3-01 71 C/HLD 225-1 78
p-Cresidine (see 5-methyl-o-anisidine) OSHA CSI
di-tert-butyl-p-Cresol OSHA PV2108 100 1000 100 min GC-FID ST 226-57 38
Cresol (all isomers) NIOSH 2546 10 mg/m3 24 100 4 GC-FID ST 226-95 39
Cresol (all isomers) OSHA 32 5 mg/m3 24 100 4 HPLC-UV ST 226-95 39
Cresols (see Environmental Sampling Guide) EPA TO-8
Cresylil acid (see cresol, all isomers) OSHA CSI
Cristobalite OSHA ID 142 varies varies varies XRD F/CST 225-803 73 C/HLD 225-1 78
CYC 225-105 84
Cristobalite (silica, crystalline [respirable] by XRD ) NIOSH 7500 1370 0.05 mg/m 3
400-1000 2500 varies XRD F/CST 225-803 73 CYC 225-01-02 85
C/HLD 225-1 78
Cristobalite (silica, crystalline by IR) NIOSH 7602 0.05 mg/m 3
400-800 2500 varies IR F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Cristobalite (silica, crystalline by VAS) NIOSH 7601 1041 0.05 mg/m 3
400-800 2500 varies VAS F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Crocidolite fibers (see asbestos fibers) NIOSH 7400
Crotonaldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
Crotonaldehyde NIOSH 3516 2 48 200 4 DPP IMP 225-36-2 61 IT 225-22 61
Crotonaldehyde OSHA 81 2 6 100 1 HPLC-UV CF/CST 225-9019 59 C/HLD 225-1 78
Crotonaldehyde (aldehydes, screening) NIOSH 2539 2 5 20 4 GC-FID & GC-MS ST 226-118 39
Crufomate OSHA PV2015 60 1000 1 GC-FPD ST 226-30-16 37
Cryolite (fluorides) NIOSH 7902 2.5 mg/m3 480 1000 8 ISE CF/CST 225-9001 59 C/HLD 225-1 78
Cumene (isopropyl benzene)  OSHA 07 1065 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
Cumene (isopropyl benzene)  OSHA PV2137 50 24 200 2 GC-FID ST 226-01 37
Cumene (isopropyl benzene) (hydrocarbons, aromatic)  NIOSH 1501 50 (skin) 1-30 10-200 8(3.3) GC-FID ST 226-01 37
Cumene hydroperoxide OSHA CSI 120 1000 2 HPLC-UV IMP 225-36-1 61 IT 225-22 61
Cunninghamella species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Cunninghamella species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Cupric carbonate as Cu (elements) NIOSH 7300 1455 960 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Curvularia species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78

Sampling Guide
C Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Curvularia species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Cyanamide OSHA CSI 10 100 100 min HPLC-UV ST 226-30-18 37
Cyanazine NIOSH 5602 480 1000 8 GC-ECD ST 226-58 38
Cyanide (as Cn) OSHA ID 120 5 mg/m3 120 1000 2 ISE F/CST 225-3-01 71 IMP 225-36-2 61
IT 225-22 61
Cyanides, aerosol & gas NIOSH 7904 5 mg/m3 120 500 4 ISE FLT 225-2705∆ 75 CST 225-2LF 79
(10 min) IMP 225-36-2 61 IT 225-22 61
C/HLD 225-1 78
Cyanogen OSHA PV2104 12 200 1 GC-NPD ST 226-117 39
Cyanogen chloride OSHA CSI 1 200 5 GC-NPD ST 226-117 39
Cyanuric acid NIOSH 5030 480 1000 8 HPLC-UV F/CST 225-802 73 C/HLD 225-1 78
Cyclohexane  OSHA 07 1134 300 10 20(50) 8(3.3) GC-FID ST 226-01 37
Cyclohexane (hydrocarbons, BP 36 to 216 C)  NIOSH 1500 1268 300 2.5-5 10-200 varies GC-FID ST 226-01 37
Cyclohexanol  OSHA 07 1135 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
Cyclohexanol (alcohols combined)  NIOSH 1405 50 (skin) 1-10 10-200 varies GC-FID ST 226-01 37
Cyclohexanol (alcohols III)  NIOSH 1402 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
Cyclohexanone  OSHA 01 1073 50 10 20(50) 8(3.3) GC-FID ST 226-110 39
Cyclohexanone (ketones I)  NIOSH 1300 25 10 20(50) 8(3.3) GC-FID ST 226-01 37
Cyclohexanone (ketones I)  NIOSH 2555 1-10 10-200 varies GC-FID ST 226-121 39
Cyclohexene  OSHA 07 1124 300 10 20(50) 8(3.3) GC-FID ST 226-01 37
Cyclohexene (hydrocarbons, BP 36 to 216 C)  NIOSH 1500 300 5-7 10 - 200 varies GC-FID ST 226-01 37
N-Cyclohexyl-2-benzothiazolesulfenamide OSHA CSI 480 2000 4 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Cyclohexylamine OSHA PV2016 20 200 100 min GC-FID ST 226-98 39
Cyclonite (RDX) OSHA CSI 1.5 mg/m3 (skin) 120 1000 2 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Cyclopentane OSHA CSI 5 200 25 min GC-FID ST 226-01 37
Cyhexatin OSHA ID 197SG 480 2000 4 AA-GF F/CST 225-709 74 C/HLD 225-1 78
ST 226-30 37
Cypermethrin OSHA PV2063 60 1000 60 min GC-ECD ST 226-30-16 37
2,4-D (2-butoxyethyl ester) NIOSH 5602 480 1000 8 GC-ECD ST 226-58 38
2,4-D (2-butoxyethyl ester) NIOSH 5602 480 1000 8 GC-ECD ST 226-58 38
2,4-D (2,4-dichlorophenoxyacetic acid) NIOSH 5001 10 mg/m3 180 1000 3 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
2,4-D (2,4-dichlorophenoxyacetic acid) OSHA CSI 10 mg/m3 180 3000 1 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
D & C red #19 OSHA CSI 240 1000 4 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
2,4-D acid NIOSH 5602 10 480 1000 8 GC-ECD ST 226-58 38
2,4-D, BE NIOSH 5602 480 1000 8 GC-ECD ST 226-58 38
2,4-D, EH NIOSH 5602 480 1000 8 GC-ECD ST 226-58 38
2,4-D, ME (2,4-dichlorophenoxyacetic acid) NIOSH 5602 480 1000 8 GC-ECD ST 226-58 38
Dacthal ASTM D 4861 240-7200 1000- 5000 4- 24 GC-ECD PUF 226-92 42
DAP (diallyl phthalate) OSHA CSI 60 1000 1 GC-FID ST 226-30-16 37
DBP (see dibutyl phthalate) OSHA 104
p,p-DDE ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
DDT OSHA CSI 1 mg/m3 90 1500 1 GC-ECD F/CST 225-709 74 C/HLD 225-1 78
p,p-DDT ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
DDVP (dichlorvos) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Decaborane OSHA CSI 0.05 480 30 2000 2000 4 15 ICP F/CST 225-3-01 71 C/HLD 225-1 78
Decabromodiphenyl oxide NIOSH 2559 48-960 2000 varies HPLC-UV FLT 225-1822 74 SP 225-27 78
CST 225-2LF 79
Decabromodiphenyl oxide OSHA CSI 200 1000 3 GC-ECD F/CST 225-709 74 C/HLD 225-1 78
n-Decane (hydrocarbons, BP 36 to 216 C)  NIOSH 1500 2 10-50 varies GC-FID ST 226-01 37
Decyl alcohol  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
DEHP (see di-2-ethylhexyl phthalate) OSHA 104
Dehydroabietic acid OSHA CSI 180 2000 1.5 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Dehydroisoandrosterone OSHA CSI 240 1000 4 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Demeton NIOSH 5514 0.1 mg/m3 480 1000 8 GC-FPD FLT 225-5 70 SCN 225-26 78
CST 225-2LF 79 ST 226-30-05 37
C/HLD 225-1 78
Demeton (Systox) OSHA CSI 0.1 mg/m3 480 1000 8 GC-FPD ST 226-30-16 37
Demosan OSHA CSI 960 2000 8 GC-ECD F/CST 225-709 74 C/HLD 225-1 78
DEP (see diethyl phthalate) OSHA 104
Desflurane  OSHA 106 3 50 1 GC-FID ST 226-81A 38
Di-(2-ethylhexyl) adipate OSHA CSI 180 1000 3 GC-FID FLT 225-17-04 75 CST 225-3LF 79
C/HLD 225-1 78
Di-(2-ethylhexyl) phthalate OSHA CSI 5 mg/m 3
60 15 1000 1000 1 15 GC-FID ST 226-30-16 37
Di-(2-ethylhexyl) phthalate (DEHP) NIOSH 5020 180 1000 3 GC-FID F/CST 225-3-01 71 C/HLD 225-1 78
Di-n-hexyl phthalate OSHA PV2076 240 1000 4 GC-FID ST 226-56 38
Di-n-octyl phthalate (DNOP) OSHA 104 240 1000 4 GC-FID ST 226-56 38
Di-n-octyl-phthalate (DNOP) OSHA CSI 90 1000 1.5 GC-ECD ST 226-56 38
Di-sec-octyl phthalate (see di-[2-ethylhexy] phthalate)
Di(ethyleneglycol) ethyl ether acrylate OSHA PV2132 1 mg/m3 48 200 4 GC-FID ST 226-110 39
Diacetone alcohol  OSHA 07 1123 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
Diacetone alcohol (alcohols combined)  NIOSH 1405 50 1-10 10-200 varies GC-FID ST 226-01 37
Diacetone alcohol (alcohols III)  NIOSH 1402 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
Diacetyl NIOSH 2557 6 100 1 GC ST 226-121 39
Diacetyl OSHA 1012 0.05 9 3 50 200 3 15 GC-FID ST 226-183 40

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number D
Diacetyl OSHA 1013 0.05 9 3 50 200 3 15 GC-FID ST 226-183 40
Diallyl disulfide OSHA PV2086 10 20(50) 8(3.3) GC-FPD ST 226-110 39
Diallyl phthalate OSHA CSI 60 1000 1 GC-FID ST 226-30-16 37
1,2-Diaminoethane NIOSH 2540 10 100 1.7 HPLC-UV ST 226-30-18 37
o-Dianisidine OSHA 71 1235 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
o-Dianisidine dyes (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC-UV FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
o-Dianisidine-based dyes OSHA CSI 480 1000 8 HPLC-UV FLT 225-17-04 75 CST 225-3LF 79
C/HLD 225-1 78
Diazinon ASTM D 4861 1000-5000 4-24 GC-NPD PUF 226-92 42

Diazinon OSHA 62 1396 480 1000 8 GC-FPD ST 226-30-16 37
Diazinon (organophosphorus pesticides) NIOSH 5600 0.1 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Diazomethane NIOSH 2515 0.2 10 200 50 min GC-FID ST 226-23 37
Diazomethane OSHA CSI 0.2 10 200 50 min GC-FID ST 226-23 37
Dibenz(a,h)anthracene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Dibenz(a,h)anthracene OSHA CSI 960 2000 8 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Dibenz(a,h)anthracene (polynuclear aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 75 ST 226-30-04 37
Dibenz(a,h)anthracene (polynuclear aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
Diborane NIOSH 6006 0.1 120 1000 2 PES ST 226-151 40 FLT NA SKC
CST 225-32 78
Dibrom OSHA CSI 3 mg/m 3
60 1000 1 GC-FPD ST 226-30-16 37
1,2-Dibromo-3-chloropropane (DBCP) OSHA CSI 1 ppb 10 20(50) 8(3.3) GC-ECD ST 226-81A 38
Dibromodifluoromethane (difluorodibromomethane) NIOSH 1012 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
1,2-Dibromoethane (ethylene dibromide)  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
1,2-Dibromoethane (ethylene dibromide)  NIOSH 1008 0.045 0.13 24 3 50 200 8 15 GC-ECD ST 226-01 37
Dibutyl amine OSHA CSI 120 1000 2 GC-NPD IMP 225-36-2 61 IT 225-22 61
2-Dibutyl aminoethanol (aminoethanol compounds I) NIOSH 2007 2 10 20(50) 8(3.3) GC-FID ST 226-10-04 37
Dibutyl phosphate NIOSH 5017 1 2 240 2000 2 GC-FPD FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Dibutyl phthalate NIOSH 5020 5 mg/m 3
100 1000 100 min GC-FID F/CST 225-3-01 71 C/HLD 225-1 78
Dibutyl phthalate (DBP) OSHA 104 5 mg/m3 240 1000 4 GC-FID ST 226-56 38
Dibutyltin bis (isooctyl mercaptoacetate) (organo- NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC, ST 226-30 37 F/CST 225-709 74
tin compounds as Sn) AA-GF C/HLD 225-1 78
Dibutyltin dilaurate (as Sn) OSHA ID218SG 500 1000 500 min AA F/CST 225-3-01 71 C/HLD 225-1 78
Dibutyltin maleate (as Sn) OSHA ID224SG 200 1000 200 min AA-GF F/CST 225-3-01 71 C/HLD 225-1 78
Dicamba OSHA CSI 200 1000 3.3 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Dicamba sodium salt OSHA CSI 200 1000 3.3 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
1,1-Dichloro-1-fluoroethane OSHA 113 1 50 20 min GC-FID ST 226-121 39
1,1-Dichloro-1-nitroethane NIOSH 1601 2 10 20(50) 8(3.3) GC-FID ST 226-81A 38
1,1-Dichloro-1-nitroethane OSHA 07 10 15 1000 15 GC-FID ST 226-81A 38
1,1-Dichloro-1-nitroethane OSHA CSI 10 10 20 8 GC-FID ST 226-81A 38
2,2-Dichloro-1,1,1-trifluoroethane NON 50 9 50 3 GC-FID ST 226-09 37
3,3-Dichloro-1,1,1,2,2-pentafluoropropane OSHA CSI 9 50 3 GC-FID ST 226-01 37
1,3-Dichloro-1,1,2,2,3-pentafluoropropane OSHA CSI 9 50 3 GC-FID ST 226-01 37
Dichloroacetylene OSHA CSI 1 200 5 GC-FID ST 226-01 37
3,4-Dichloroaniline OSHA CSI 100 1000 1.5 HPLC F/CST 225-803 73 C/HLD 225-1 78
m-Dichlorobenzene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
m-Dichlorobenzene  OSHA CSI 10 200 50 min GC-FID ST 226-01 37
o-Dichlorobenzene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
o-Dichlorobenzene  OSHA 07 1122 50 (C) 3 200 15 GC-FID ST 226-01 37
p-Dichlorobenzene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
p-Dichlorobenzene  OSHA 07 1121 75 3 0.75 20 50 2.5 15 GC-FID ST 226-01 37
o-Dichlorobenzene (hydrocarbons, halogenated)  NIOSH 1003 50 3 10-200 varies GC-FID ST 226-01 37
p-Dichlorobenzene (hydrocarbons, halogenated)  NIOSH 1003 1.7 (LOQ) 3 10-200 varies GC-FID ST 226-01 37
3,3’-Dichlorobenzidine OSHA 65 1238 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
Dichlorodifluoroethane OSHA CSI 3 100 30 min GC-FID ST 226-01 37
Dichlorodifluoromethane NIOSH 1018 1000 3 20 2.5 GC-FID ST 226-01 37 ST 226-09 37
1,1-Dichloroethane (ethylene dichloride) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
1,1-Dichloroethane (ethylene dichloride) OSHA 07 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
1,2-Dichloroethane (ethylene dichloride)  OSHA 07 1119 50 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
1,1-Dichloroethane (hydrocarbons, halogenated) NIOSH 1003 1267 100 10 10-200 varies GC-FID ST 226-01 37
Dichloroethyl ether  NIOSH 1004 5 10 10 20(50) 8(3.3) GC-FID ST 226-01 37
Dichloroethyl ether  OSHA 07 15 10 15 20 1000 8 15 GC-FID ST 226-01 37
1,2-Dichloroethylene  OSHA 07 1118 200 3 20 2.5 GC-FID ST 226-01 37
cis-1,2-Dichloroethylene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
1,2-Dichloroethylene (hydrocarbons, halogenated)  NIOSH 1003 200 3 10-200 varies GC-FID ST 226-01 37
trans-1,2-Dichloroethylene  DT 810-174D
Dichlorofluoromethane NIOSH 2516 10 3 20 2.5 GC-FID ST 226-25 37
Dichloromethane  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Dichloromethane (see methylene chloride) 
Dichloromonofluoromethane (dichlorofluoromethane) NIOSH 2516 10 3 20 2 GC-FID ST 226-09 37

Sampling Guide
D Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Dichloromonofluoromethane (dichlorofluoromethane) OSHA CSI 1000 3 20 2.5 GC-FID ST 226-09♠ 37

2,4-Dichlorophenoxyacetic acid (2,4-D) NIOSH 5001 10 mg/m3 180 1000 3 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
1,2-Dichloropropane (propylene dichloride)  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
1,2-Dichloropropane (propylene dichloride)  NIOSH 1013 LFC 3 20 2.5 GC-ECN ST 226-81A 38
1,3-Dichloropropene OSHA CSI 5 200 25 min GC-FID ST 226-01 37
cis-1,3-Dichloropropene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
trans-1,3-Dichloropropene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
3,4-Dichloropropionanilide OSHA CSI W FLT 225-7 74
2,2-Dichloropropionic acid OSHA PV2017 10 200 50 min HPLC-UV ST 226-10 37
Dichlorotetrafluoroethane OSHA CSI 3 50 1 GC-FID ST 226-09 37 ST 226-01 37
1,1-Dichlorotetrafluoroethane OSHA CSI 2 50 40 min GC-FID ST 226-01 37 ST 226-09 37
1,2-Dichlorotetrafluoroethane (dichlorodifluoromethane) NIOSH 1018 1000 3 20 2.5 GC-FID ST 226-01 37 ST 226-09 37
Dichlorotrifluoroethane NON 50 9 50 3 GC-FID ST 226-09 37
Dichlorvos (DDVP) ASTM D 4861 240-7200 1000- 5000 4-24 GC-ECD PUF 226-92 42
Dichlorvos (DDVP) OSHA 62 1395 1 mg/m3 480 1000 8 GC-FPD ST 226-30-16 37
Dicloran ASTM D 4861 240-7200 1000- 5000 4-24 GC-ECD PUF 226-92 42
Dicofol ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Dicofol OSHA CSI W SM TB 225-24 112
Dicrotophos ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Dicrotophos (Bidrin) OSHA PV2099 480 1000 8 GC-FPD ST 226-30-16 37
Dicrotophos (organophosphorus pesticides) NIOSH 5600 0.25 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Dicyclopentadiene  OSHA PV2098 10 100 100 min GC-FID ST 226-01 37
Dicyclopentadienyl iron (respirable dust) OSHA CSI 5 mg/m3 varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Dicyclopentadienyl iron (total dust) OSHA CSI 15 mg/m3 960 2000 8 AA F/CST 225-3-01 71 C/HLD 225-1 78
Dieldrin ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Dieldrin OSHA CSI 0.25 mg/m3 180 1500 2 GC-ECD F/CST 225-709 74 C/HLD 225-1 78
Diesel emissions (see elemental carbon) NIOSH 5040 TOA-FID
Diesel exhaust particles (see elemental carbon) NIOSH 5040 TOA-FID
Diesel particulate matter ASTM D 6877 varies 1000-4000 varies EGA-TOS DPM 225-317 or F/CST 225-401 74
Diesel particulate matter MSHA 30CFR57 350 µg/m3 varies 2000 varies TOA-FID F/CST 225-317 74 CYC 225-100 84
(total carbon) C/HLD 225-1 78
Diesel particulate matter MSHA 30CFR57 350 µg/m3 varies varies varies TOA-FID F/CST 225-401 74 CYC 225-100 84
(total carbon) C/HLD 225-1 78
Diethanolamine OSHA PV2018 10 100 100 min HPLC-UV ST 226-30-18 37
Diethanolamine (DEA) (aminoethanol compounds II) NIOSH 3509 1006 3 240 1000 4 IC IMP 225-36-1 61 IT 225-22 61
Diethyl ether (ethyl ether)  NIOSH 1610 0.25-3 10-200 varies GC-FID ST 226-01 37
Diethyl ketone (3-pentanone)  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-121 39
Diethyl phthalate (DEP) OSHA 104 240 1000 4 GC-FID ST 226-56 38
Diethyl sulfate OSHA CSI 15 1000 15 min GC-FID ST 226-10 37
Diethylamine  OSHA 41 1697 25 10 3 200 200 50 min 15 min HPLC ST 226-96 39
Diethylamine (amines, aliphatic)  NIOSH 2010 10 25 24 3 50 200 8 15 GC-FID ST 226-10 37
2-Diethylaminoethanol OSHA CSI 10 24 200 2 GC-FID ST 226-10-04 37
2-Diethylaminoethanol (aminoethanol compounds I) NIOSH 2007 10 10 20(50) 8(3.3) GC-FID ST 226-10-04 37
Diethylaminopropylamine (DEP) OSHA CSI 100 1000 100 min GC-NPD IMP 225-36-1 61 IT 225-22 61
Diethylene dioxide (see dioxane)
Diethylene ether (see dioxane)
Diethylene glycol (glycols) NIOSH 5523 1387 60 1000 1 GC-FID ST 226-57 38
Diethylene glycol methyl ether OSHA CSI 10 100 100 min GC-FID ST 226-01 37
Diethylene glycol monobutyl ether acetate OSHA CSI 9.6 100 1.6 GC-FID ST 226-01 37
Diethylene glycol monoethyl ether OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Diethylenetriamine (DETA) OSHA 60 1285 10 100 100 min HPLC-UV ST 226-30-18 37
Difluorodibromomethane NIOSH 1012 100 6 50 2 GC-FID ST 226-01 37
Difluorodibromomethane OSHA 07 100 10 20 8 GC-FID ST 226-01 37
Diglycidyl ether of bisphenol A OSHA CSI 240 1000 4 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Diglycolamine OSHA CSI 20 100 3 GC-NPD IMP 225-36-1 61 IT 225-22 61
Diglyme OSHA CSI 20 200 100 min GC-FID ST 226-01 37
Dihexyl phthalate OSHA PV2076 240 1000 4 GC-FID ST 226-56 38
Dihydrocapsaicin NIOSH 5041 480 15 1 1 8 15 HPLC-FD FLT 225-16 74 CST 225-32 78
Diisobutyl ketone  OSHA 07 1116 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
Diisobutyl ketone (ketones I)  NIOSH 1300 25 10 20(50) 8(3.3) GC-FID ST 226-01 37
Diisobutyl ketone (ketones I)  NIOSH 2555 1-10 10-200 varies GC-FID ST 226-121 39
Diisocyanates OSHA 42 1458 240 15 1000 1000 4 15 HPLC-UV, CF/CST 225-9002 or CF/CST 225-9013 59
or FD C/HLD 225-1 78
Diisopropylamine OSHA CSI 5 120 1000 2 GC-FID IMP 225-36-1 61 IT 225-22 61
Dimethazone OSHA PV2066 60 1000 1 GC-ECD ST 226-30-16 37
Dimethoate OSHA PV2113 480 1000 8 GC-FPD ST 226-30-16 37
2,5-Dimethoxyaniline OSHA CSI 17 50 5.7 HPLC-UV ST 226-30-04 37
Dimethoxymethane (methylal)  NIOSH 1611 1000 2 20 1.5 GC-FID ST 226-01 37
Dimethoxymethane (methylal)  OSHA 07 1115 1000 2 20 1.5 GC-FID ST 226-01 37
Dimethyl adipate OSHA PV2019 20 200 100 min GC-FID ST 226-01 37
Dimethyl arsenic acid (arsenic, organo-) NIOSH 5022 960 2000 8 IC-AA FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number D
Dimethyl disulfide NON 42 1413 12 1000 12 min GC-FPD SB 240-08B 53
Dimethyl disulfide OSHA CSI 6 100 1 GC-FID ST 226-01 37
Dimethyl glutarate OSHA PV2020 20 200 100 min GC-FID ST 226-01 37
Dimethyl phthalate (DMP) OSHA 104 5 mg/m3 240 1000 4 GC-FID ST 226-56 38
Dimethyl succinate OSHA PV2021 20 200 100 min GC-FID ST 226-01 37
Dimethyl sulfate NIOSH 2524 1284 0.1 (8 h) 12 50 4 GC-ECN ST 226-114 39
Dimethyl sulfate OSHA PV2147 1 10 100 100 min GC-FPD ST 226-115 39
Dimethyl sulfide NON 42 1413 12 1000 12 min GC-FPD SB 240-08B 53
Dimethyl sulfide OSHA CSI 5 20 4 GC-FPD ST 226-01 37
Dimethyl sulfoxide OSHA CSI 10 100 100 min GC-FID ST 226-01 37
Dimethyl-1,2-dibromo-2,2-dichloroethyl phosphate OSHA CSI 3 mg/m3 60 1000 1 GC-FPD ST 226-30-16 37
2,3-Dimethyl-2,3-dinitrobutane NON 44 0.15 mg/m3 OEL 10 200 50 min GC-ECD ST 226-35-03 37
N,N-Dimethyl-p-toluidine (amines, aromatic) NIOSH 2002 1055 96 200 8 GC-FID or ST 226-10 37
GC-NSD
Dimethylacetamide NIOSH 2004 1695 10 48 100 8 GC-FID ST 226-10 37
Dimethylacetamide OSHA CSI 10 60 1000 1 GC-FID ST 226-10 37
Dimethylamine  NIOSH 2010 10 24 50 8 GC-FID ST 226-10 37
Dimethylamine  OSHA 34 1696 10 10 20 8 HPLC ST 226-96 39
2-Dimethylamino ethanol NIOSH 2561 10-24 20-100 varies GC-FID ST 226-94 39
1-Dimethylamino-2-propanol NIOSH 2561 10-24 20-100 varies GC-FID ST 226-94 39
4-Dimethylaminoazobenzene OSHA CSI 60 1000 1 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
IMP 225-36-1 61 IT 225-22 61
Dimethylaminobenzene OSHA CSI 5 24 50 8 GC-FID ST 226-10 37
2,4-Dimethylaminobenzene (amines, aromatic) NIOSH 2002 2 24 50 8 GC-FID or ST 226-10 37
GC-NSD
N,N-Dimethylaniline  OSHA 07 5 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
N,N-Dimethylaniline  OSHA PV2064 5 30 200 2.5 GC-FID ST 226-98 39
N,N-Dimethylaniline (amines, aromatic)  NIOSH 2002 1054 5 10 24 3 50 200 8 15 GC-FID or ST 226-10 37
GC-NSD
2,5-Dimethylbenzaldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
trans-1,4-Dimethylcyclohexane  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
trans-1,2-Dimethylcyclohexane  GC-FID PS 575-001 63
N,N-Dimethylethanolamine NIOSH 2561 10-24 20-100 varies GC-FID ST 226-94 39
N,N-Dimethylethanolamine OSHA CSI 24 50 8 GC-FID ST 226-10-04 37
N,N-Dimethylethylamine OSHA PV2096 40 100 40 min GC-NPD ST 226-18 37
N,N-Dimethylformamide (DMF)  NIOSH 2004 10 24 50 8 GC-FID ST 226-10 37
N,N-Dimethylformamide (DMF)  OSHA 66 1271 10 9.6 3 20 200 8 15 GC-NPD ST 226-01 37
1,1-Dimethylhydrazine NIOSH 3515 0.06 (120 min) 60 1000 1 VAS IMP 225-36-2 61 IT 225-22 61
1,1-Dimethylhydrazine OSHA CSI 0.5 96 200 8 CLR IMP 225-36-2 61 IT 225-22 61
Dimethyltin dichloride NIOSH 5526 0.1 mg/m3 60 60 250 1000 4 60 GC-FPD ST 226-30-16 37
Dinitolmide OSHA CSI 240 1000 4 HPLC F/CST 225-706 74 C/HLD 225-1 78
Dinitro-o-cresol OSHA CSI 0.2 mg/m3 180 1.5 2 HPLC-UV F/CST 225-3-01 71 IMP 225-36-1 61
IT 225-22 61
4,6-Dinitro-o-sec-butyl phenol OSHA CSI 24 50 8 HPLC-UV ST 226-95 39
Dinitrobenzene (all isomers) OSHA CSI 1 mg/m3 60 1000 1 HPLC-UV ST 226-30-16 37
2-(2,4-Dinitrophenoxy)ethanol OSHA CSI 10 20(50) 8(3.3) HPLC-UV ST 226-10 37
Dinitrotoluene (DNT) OSHA 44 1.5 mg/m3 60 1000 1 GC-TEA ST 226-56 38
n-Dioctyl phthalate (DNOP) OSHA 104 240 1000 4 GC-FID ST 226-56 38
Dioxane (diethylene dioxide)  NIOSH 1602 1 (30 min) 10 20(50) 8(3.3) GC-FID ST 226-01 37
Dioxane (diethylene dioxide)  OSHA 07 1114 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
Dioxathion (Delnav) OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Dioxins (including PHDDs, PCDDs, PBDDs) (see EPA TO-9A
Environmental Sampling Guide)
Diphenyl NIOSH 2530 0.2 30 100 5 GC-FID ST 226-35-01 37
Diphenyl ether OSHA PV2022 0.2 20 200 100 min GC-FID ST 226-95 39
p,p-Diphenyl methane diisocyanate (MDI) (see OSHA 47
methylene bisphenyl isocyanate)
2-Diphenylacetyl-1,3-indandione OSHA CSI 480 2000 4 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Diphenylamine OSHA 78 1229 100 1000 100 min HPLC-UV CF/CST 225-9004 59 C/HLD 225-1 78
5,5-Diphenylhydantoin OSHA CSI 60 1000 1 HPLC-UV FLT 225-7‡ 74 CST 225-3LF 79
C/HLD 225-1 78
Diphenylmethane-4,4’-diisocyanate (MDI) NIOSH 5521 1001 50 µg/m3 200 µg/m3 480 10 1000 1000 8 10 HPLC-UV IMP 225-36-1 61 IT 225-22 61
(4,4-methylene bisphenyl isocyanate) (isocyanates) (10 min) C
Dipropyl disulfide OSHA PV2086 10 20(50) 8(3.3) GC-FPD ST 226-110 39
Dipropyl ketone (4-heptanone)  OSHA CSI 10 20 8 GC-FID ST 226-121 39
Dipropylene glycol methyl ether  OSHA 07 1113 100 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Dipropylene glycol methyl ether  OSHA 101 100 10 100 100 min GC-FID ST 226-01 37
Dipropylene glycol methyl ether (glycol ethers)  NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 38
Dipropylene glycol monomethyl ether (glycol ethers)  NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 38
Diquat OSHA CSI 120 1000 2 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Direct black 38 OSHA CSI 100 1000 100 min HPLC F/CST 225-706 74 C/HLD 225-1 78
Direct black 38 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
Direct blue OSHA CSI 60 1000 1 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78

Sampling Guide
D Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Direct blue 2 OSHA CSI 100 1000 100 min HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Direct blue 6 OSHA CSI 100 1000 100 min HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Direct blue 6 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
Direct blue 8 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
Direct blue 98 OSHA CSI 180 1000 3 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Direct brown 31 OSHA CSI 180 1000 3 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Direct brown 95 OSHA CSI 100 1000 100 min HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Direct brown 95 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
Direct red 2 OSHA CSI 120 1000 2 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Direct red 2 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
Direct red 28 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
Direct red 81 OSHA CSI 100 1000 100 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Disperse yellow 3 OSHA CSI 100 1000 100 min HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Disulfiram (tetraethylthiuram disulfide) OSHA CSI 120 1000 2 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Disulfoton OSHA PV2105 480 1000 8 GC-FPD ST 226-30-16 37
Disulfoton (organophosphorus pesticides) NIOSH 5600 0.1 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Disyston OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
2,2’-Dithiobis(benzothiazole) OSHA CSI 480 2000 4 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Diuron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Diuron (organonitrogen pesticides) NIOSH 5601 10 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Divinyl benzene OSHA 89 12 50 4 GC-FID ST 226-73 38
Divinyl sulfide OSHA CSI 2.5 20 2 GC ST 226-01 37
DMP (see dimethyl phthalate) OSHA 104
DNOP (see di-n-octyl phthalate) OSHA 104
DNT (dinitrotoluene) OSHA 44 1.5 mg/m3 60 1000 1 GC-TEA ST 226-56 38
n-Dodecane  TD, GC PS 590-259 and SV 590-260 or
SV 590-262 67
Dodecyl alcohol (lauryl alcohol)  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Dodine OSHA CSI 240 1000 2 HPLC-UV ST 226-30 37
Dursban (chlorpyrifos)(organophosphorus pesticides) NIOSH 5600 0.2 mg/m3 0.6 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Dust, inorganic 15-150 15 L/min 1-10 min varies STC 225-9820 77
Dust, respirable (in workplace atmospheres) ASTM D 4532 1418 varies 2500 varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Dust, respirable nuisance OSHA CSI 5.0 mg/m3 varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Dust, respirable nuisance (particulates) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Dust, total nuisance OSHA CSI 15 mg/m3 720 1500 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Dust, total nuisance (particulates) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Dust, total, particulates not otherwise regulated NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Dyes, benzidine, o-tolidine, o-dianisidine NIOSH 5013 LFC 480 1000 8 HPLC-UV FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
Dyfonate OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Elemental carbon (diesel exhaust) MSHA varies varies varies EGA-TOS DPM 225-317 77 CYC 225-105 84
Elemental carbon (diesel exhaust) NIOSH 5040 varies varies varies TOA-FID F/CST 225-401 74 CYC 225-100 84
C/HLD 225-1 78
Elements (see specific compounds) NIOSH 7300 1455 varies varies 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Elements by ICP Aqua Regia ashing (see specific NIOSH 7301 varies varies 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
element) C/HLD 225-1 78
Elements by ICP HNO3 digestion (see specific element) NIOSH 7303 varies varies 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Elements on wipes (see specific element) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Elements qualitative OSHA ID 204 480 2000 8 XRF F/CST 225-3-01 71 C/HLD 225-1 78
Emery (corundum) (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Emery (corundum) (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Emery (respirable dust) OSHA CSI 5 mg/m3 varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Emery (total dust) OSHA CSI 15 mg/m3 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Endosulfan (Thiodan) OSHA PV2023 60 1000 1 GC-ECD ST 226-30-16 37
Endotoxins (bacteria in air) NON 48 62.5-375 12500 + 5-30 varies BS 225-9595 93 VT 225-9598A◊ 93
Endrin NIOSH 5519 0.1 mg/m3 240 1000 4 GC-ECD CST 225-2LF 79 FLT 225-5 70
SCN 225-26 78 ST 226-104 39
C/HLD 225-1 78
Enflurane (ethrane)  OSHA 103 1348 12 50 4 GC-FID ST 226-121 or ST 226-81A 38
Enflurane (ethrane)  OSHA 29 10 20 8 GC-FID ST 226-01 37
Environmental tobacco smoke (nicotine & 3-ethenylpyridine) NON 49 90-720 1500 1-8 GC-NSD ST 226-170 40

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number E
Environmental tobacco smoke (respirable particles) ASTM D 5955 1419 varies varies varies GR, HPLC- FLT 225-2705 75 C/HLD 225-1 78
UV, FD CYC 225-01-02 85 CST 225-3LF 79
Environmental tobacco smoke (solanesol, ASTM D 6271 150-3600 2500 1-24 HPLC-UV FLT 225-2705 75 CST 225-3LF 79
respirable particles) CYC 225-01-02 85 C/HLD 225-1 78
Epichlorohydrin  NIOSH 1010 LFC 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Epichlorohydrin  OSHA 07 1112 5 20 100 3.3 GC-FID ST 226-01 37
Epicoccum species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Epicoccum species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
EPN NIOSH 5012 0.5 mg/m3 480 1000 8 GC-FPD F/CST 225-709 74 C/HLD 225-1 78
EPN OSHA CSI 0.5 mg/m3 480 1000 8 GC-FPD ST 226-30-16 37
1,2-Epoxyethylbenzene OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-35 37
1,2-Epoxypropane (see propylene oxide) 
2,4,D-Esters ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Esters I (see specific compounds) NIOSH 1450 varies 1-10 varies varies GC-FID ST 226-01 37
Estradiol OSHA PV2001 240 1000 4 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Estriol OSHA PV2001 60 1000 1 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Estrone OSHA PV2001 60 1000 1 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
1,2-Ethanediol (ethylene glycol) (glycols) NIOSH 5523 1401 24 100 4 GC-FID ST 226-57 38
1,2-Ethanediol dinitrate OSHA 43 0.2 (C) 15 1000 15 HPLC-TEA ST 226-35-03 37
2-(2-methoxyethoxy) Ethanol OSHA CSI 6 100 1 GC-FID ST 226-01 37
Ethanolamine OSHA PV2111 3 10 1.5 100 100 100 min 15 HPLC-UV ST 226-30-18 37
3-Ethenylpyridine NON 49 90-720 1500 1-8 GC-NSD ST 226-170 40
3-Ethenylpyridine & nicotine ASTM D 5075 1427 90-2160 1500 1-24 GC-NPD ST 226-93 39
Ethion (nialate) OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Ethion (organophosphorus pesticides) NIOSH 5600 0.4 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Ethoprop (organophosphorus pesticides) NIOSH 5600 240 1000 4 GC-FPD ST 226-58 38
1-Ethoxy-2-propanol OSHA CSI 48 100 8 GC-FID ST 226-01 37
2-Ethoxyethanol (alcohols IV)  NIOSH 1403 1273 0.5 (skin) 1-6 10-50 varies GC-FID ST 226-01 37
2-Ethoxyethanol (CELLOSOLVE solvent)  OSHA 79 1277 200 48 15 100 1000 8 15 GC-FID ST 226-01 37
2-Ethoxyethanol (CELLOSOLVE solvent) (alcohols IV)  NIOSH 1403 1273 0.5 (skin) 1-6 10-50 varies GC-FID ST 226-01 37
2-Ethoxyethyl acetate (CELLOSOLVE acetate)  OSHA 79 1277 100 48 15 100 1000 8 15 GC-FID ST 226-01 37
2-Ethoxyethyl acetate (esters I)  NIOSH 1450 0.5 (skin) 1-10 10-200 varies GC-FID ST 226-01 37
Ethrane (enflurane)  OSHA 29 10 100 1.6 GC-FID ST 226-01 37
Ethyl 2-cyanoacrylate OSHA 55 12 100 2 HPLC-UV ST 226-98 39
Ethyl acetate  NIOSH 1457 400 10 20 8 GC-FID ST 226-01 37
Ethyl acetate  OSHA 07 1111 400 5 20 4 GC-FID ST 226-01 37
Ethyl acrylate  NON 54 5 15 10 3 20 200 8 15 GC-FID ST 226-81A 38
Ethyl acrylate  OSHA 92 25 12 0.75 50 50 4 15 GC-FID ST 226-73 38
Ethyl acrylate (esters I)  NIOSH 1450 4 LOQ 1-10 10-200 varies GC-FID ST 226-01 37
Ethyl alcohol (ethanol)  OSHA 07 1109 1000 1 50 20 min GC-FID ST 226-01 37
Ethyl alcohol (ethanol)  OSHA 100 1283 1000 12 50 4 GC-FID ST 226-82 38
Ethyl alcohol (ethanol) (alcohols I)  NIOSH 1400 1000 1 50 20 min GC-FID ST 226-01 37
Ethyl amyl ketone  OSHA 07 1158 25 10 20(50) 8(3.3) GC-FID ST 226-01 37
Ethyl benzene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Ethyl benzene  OSHA 07 1108 100 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Ethyl benzene  OSHA 1002 1746 100 12 50 4 GC-FID ST 226-01 37
Ethyl benzene (hydrocarbons, aromatic)  NIOSH 1501 1053 100 125 1-24 1-24 10-200 10-200 varies varies GC-FID ST 226-01 37
Ethyl bromide (bromoethane)  NIOSH 1011 4 20 3.3 GC-FID ST 226-01 37
Ethyl bromide (bromoethane)  OSHA 07 1107 200 5 3 20 200 4 15 GC-FID ST 226-01 37
Ethyl butyl ketone (3-heptanone)  OSHA 07 1106 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
Ethyl butyl ketone (3-heptanone) (ketones II )  NIOSH 2553 50 1-25 10-200 varies GC-FID ST 225-121 39
Ethyl butyl ketone (3-heptanone) (ketones II)  NIOSH 1301 50 24 200 2 GC-FID ST 226-01 37
Ethyl chloride ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Ethyl chloride NIOSH 2519 3 50 1 GC-FID ST 226-25 37
Ethyl chloride OSHA 07 1000 3 50 1 GC-FID ST 226-01 37
Ethyl ether (Diethyl ether)  OSHA 07 1105 400 3 3 20 200 2.5 15 GC-FID ST 226-01 37
Ethyl ether (ethyl ether)  NIOSH 1610 0.25-3 10-200 varies GC-FID ST 226-01 37
Ethyl formate  NIOSH 1452 100 10 20 8 GC-FID ST 226-01 37
Ethyl formate  OSHA 07 1104 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
Ethyl lactate OSHA PV2081 10 200 50 min GC-FID ST 226-01 37
Ethyl mercaptan OSHA CSI 10 (C) 120 1000 120 GC-FPD CF/CST 225-9007 59 C/HLD 225-1 78
Ethyl mercaptan (mercaptans) NIOSH 2542 1330 0.5 (15 min) 48 12 100 200 8 60 GC-FPD CF/CST 225-9007 59 C/HLD 225-1 78
Ethyl methacrylate  NIOSH 2537 1-8 10-50 varies GC-FID ST 226-30-06 37
Ethyl methacrylate  OSHA PV2100 10 20(50) 8(3.3) GC-FID ST 226-01 37
Ethyl O-(p-nitrophenyl) phenylphosphonothionate (EPN) NIOSH 5012 0.5 mg/m3 480 1000 8 GC-FPD F/CST 225-709 74 C/HLD 225-1 78
Ethyl parathion ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 42
Ethyl propionate  OSHA CSI 10 20(50) 8(3.3) GC ST 226-01 37
Ethyl silicate OSHA CSI 100 9 50 3 GC-FID ST 226-30-04 37
Ethyl tert-butyl ether (tert-butyl ethyl ether)  GC-FID PS 575-001 63
2-Ethyl toluene  TD, GC PS 590-259 and SV 590-260 or
SV 590-262 67

Sampling Guide
E Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method

SV 590-262 67
SV 590-262 67
Ethyl vinyl benzene OSHA 89 12 50 4 GC-FID ST 226-73 38
Ethyl-3-ethoxypropionate OSHA PV2025 10 100 100 min GC-FID ST 226-01 37
Ethylamine OSHA 36 10 10 200 50 min HPLC-UV ST 226-96 39
Ethylene  OSHA CSI DET TB DT 800-28051 or DT 810-172 or
DT 800-01331 or DT 810-172L
Ethylene chlorohydrin NIOSH 2513 1 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-81A 38
Ethylene chlorohydrin OSHA 07 1159 5 20 40 8 GC-FID ST 226-81A 38
Ethylene dibromide (1,2-dibromoethane)  NIOSH 1008 0.045 0.13(15min) 10 3 20(50) 200 8(3.3) 15 GC-ECD ST 226-01 37
Ethylene dibromide (1,2-dibromoethane)  OSHA 02 1072 20 30 10 1 20(50) 200 8(3.3) 5 GC-ECD ST 226-01 37
Ethylene dichloride (1,2-dichloroethane)  OSHA 03 1063 50 100 10 3 200 200 1 15 GC-ECD ST 226-01GWS 37
Ethylene dichloride (1,2-dichloroethane) (hydro-  NIOSH 1003 1 2 3 3 10-200 10-200 varies varies GC-FID ST 226-01 37
carbons, halogenated)
Ethylene glycol (glycols) NIOSH 5523 1401 60 1000 1 GC-FID ST 226-57 38
Ethylene glycol dinitrate OSHA 43 0.2 (C) 15 1000 15 HPLC-TEA ST 226-35-03 37
Ethylene glycol dinitrate (nitroglycerine) NIOSH 2507 0.1 mg/m3 15 1000 15 GC-ECD ST 226-35-03 37
Ethylene glycol isopropyl ether (isopropyl OSHA CSI 9 100 1.5 GC-FID ST 226-01 37
CELLOSOLVE solvent)
Ethylene glycol monohexyl ether  OSHA CSI 10 200 50 min GC-FID ST 226-01 37
Ethylene oxide  ASTM D 4413 6 3 100 200 1 15 GC-FID ST 226-16 or ST 226-36 38
Ethylene oxide  ASTM D 5578 9.6 1.5 20 100 8 15 GC-ECD ST 226-178 37
Ethylene oxide  NIOSH 1614 0.1 5 (10 min) 24 1.5 100 150 4 10 GC-ECD ST 226-178 37
Ethylene oxide  OSHA 1010 1751 1 5.0 EL 12 0.75 50 50 4 15 GC-ECD ST 226-178 37
Ethylene oxide (Qazi-Ketcham) NON 14 10 20(50) 8(3.3) GC ST 226-36 38
Ethylene oxide by portable GC NIOSH 3702 1031 0.1 5 (10 min) varies varies varies varies varies varies P GC-PID SB 232 Series 52
Ethylene thiourea NIOSH 5011 LFC 480 2000 4 VAS F/CST 225-802 73 C/HLD 225-1 78
Ethylene thiourea OSHA 95 480 2000 4 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Ethylenediamine NIOSH 2540 10 10 100 1.7 HPLC-UV ST 226-30-18 37
Ethylenediamine (EDA) OSHA 60 1287 10 10 100 100 min HPLC-UV ST 226-30-18 37
Ethylenimine NIOSH 3514 48 200 4 HPLC-UV IMP 225-36-2 61 IT 225-22 61
2-Ethylhexanol  OSHA CSI 48 200 4 GC-FID ST 226-01 37
Ethylhexyl acetate  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
2-Ethylhexyl acrylate OSHA PV2026 12 100 2 GC-FID ST 226-73 38
di-2-Ethylhexyl phthalate (DEHP) OSHA 104 5 mg/m3 240 1000 4 GC-FID ST 226-56 38
N-Ethylmorpholine OSHA CSI 20 10 20(50) 8(3.3) GC-FID ST 226-10 37
ETS (see environmental tobacco smoke) NON 49
Exserohilum species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Exserohilum species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Fenamiphos OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Fenamiphos (organophosphorus pesticides) NIOSH 5600 0.1 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Fenarimol OSHA CSI 30 1000 30 min HPLC-UV ST 226-30-16 37
Fensulfothion (Dansanit) OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Fenthion OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Fenvalerate ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Ferbam OSHA CSI 15 mg/m3 480 1000 8 HPLC-UV ST 226-30-16 37
Ferric chloride (see iron salts, soluble as Fe) OSHA ID 121
Ferrovanadium dust OSHA ID 125G 1218 1 mg/m3 480 30 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Fibers (bioaerosols) 15-150 15 L/min 1-10 min varies STC 225-9820 77
Fibers (see specific compounds)
Fibrous glass (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Fibrous glass (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Fibrous glass dust OSHA CSI 15 mg/m3 960 2000 8 GR F/CST 225-8204 73 C/HLD 225-1 78
Flax dust (see dust, total and respirable nuisance) OSHA CSI
Fluoboric acid OSHA CSI 120 1000 2 ISE IMP 225-36-2 61 IT 225-22 61
Fluometuron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Fluoranthene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Fluoranthene OSHA CSI 960 2000 8 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Fluoranthene (polynuclear aromatic hydrocarbons) NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Fluoranthene (polynuclear aromatic hydrocarbons) NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Fluorene ASTM D 6209 350 m (max)
3
225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Fluorene OSHA CSI 960 2000 8 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Fluorene (polynuclear aromatic hydrocarbons) NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Fluorene (polynuclear aromatic hydrocarbons) NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Fluorides ASTM D 4765 1421 varies 2000 varies ISE CF/CST 225-9001 59 C/HLD 225-1 78

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number F
Fluorides (as F) OSHA ID 110 1227 2.5 mg/m3 90 22.5 1500 1500 1 15 ISE CF/CST 225-9001 59 C/HLD 225-1 78
Fluorides, aerosol & gas by ISE NIOSH 7902 1226 2.5 mg/m3 6 (HF) 480 22.5 1000 1500 8 15 ISE CF/CST 225-9001 59 C/HLD 225-1 78
Fluorine OSHA CSI 0.1 480 1000 8 ISE IMP 225-36-2 61 IT 225-22 61
Fluorotrichloromethane (trichlorofluoromethane) NIOSH 1006 1000 5 20 240 GC-FID ST 226-09 37
5-Fluorouracil OSHA CSI 180 1000 3 HPLC-UV ST 226-30-16 37
Folpet ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Fonofos (Dyfonate) OSHA PV2027 480 1000 8 GC-FPD ST 226-30-16 37
Fonofos (organophosphorus pesticides) NIOSH 5600 0.1 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Formaldehyde  ASTM D 5197 1442 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
Formaldehyde  NIOSH 2016 0.016 0.1 (C) 1-<15 1-<15 30-500 30-500 varies HPLC-UV ST 226-119♠ 39
Formaldehyde  NIOSH 2541 1015 0.016 0.1 (C) 24 1 100 100 4 10 GC-FID ST 226-118 39
Formaldehyde  NIOSH 3500 0.016 0.1 96 15 200 1000 8 15 VAS FLT 225-17-01 75 IT 225-22 61
IMP 225-36-1 61 CST 225-2LF 79
C/HLD 225-1 78
Formaldehyde  OSHA 1007 0.75 2 13.8 0.43 28.6 28.6 8 15 HPLC-UV PS 500-100 64
Formaldehyde  OSHA 52 1020 0.75 2 24 3 100 200 4 15 GC-NPD ST 226-117 or ST 226-54 38
Formaldehyde (aldehydes, screening)  NIOSH 2539 0.016 0.1 5 20 4 GC-FID & GC-MS ST 226-118 39
Formaldehyde (see Environmental Sampling Guide) EPA IP-11A
Formaldehyde (see Environmental Sampling Guide) EPA IP-6A
Formaldehyde (see Environmental Sampling Guide) EPA IP-6C
Formaldehyde on dust (textile or wood) NIOSH 5700 0.016 0.1 240 2000 4 HPLC-UV IOM 225-70A 87 FLT 225-8-04 73
Formamide OSHA CSI 10 1.5 100 100 100 min GC-NPD ST 226-10 37
Formetanate (organonitrogen pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Formic acid  NIOSH 2011 5 24 200 2 IC-ECN FLT 225-2708 75 CST 225-3-25LF 79
ST 226-10-03 37 C/HLD 225-1 78
Formic acid  OSHA ID 186SG 5 48 100 8 IC ST 226-09 37
Freon 11 ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Freon 113 (1,1,2-Trichloro-1,2,2-trifluoroethane) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Freon 113 (1,1,2-Trichloro-1,2,2-trifluoroethane) OSHA 113 1000 1 50 20 min GC-FID ST 226-121 39
Freon 123 NON 50 9 50 3 GC-FID ST 226-09 37
Freon 141b OSHA 113 1000 1 50 20 min GC-FID ST 226-121 39
Fumarin OSHA CSI 180 1000 3 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Fungi NIOSH 0800 varies 28300 varies varies BI 225-9611 94
Fungi (in air) 15-150 15 L/min 1-10 min varies STC 225-9820 77
Fungi (in air) (BioSampler method) NON 48 62.5-375 12500 + 5-30 varies BS 225-9595 93 VT 225-9598A◊ 93
Furans (including PHDFs, PCDFs, PBDFs) (see EPA TO-9A
Furfural  NIOSH 2529 5 20 4 GC-FID ST 226-118 39
Furfural  OSHA 72 5 180 1000 3 GC-FID ST 226-81A 38
Furfural (aldehydes, screening)  NIOSH 2539 5 20 4 GC-FID & GC-MS ST 226-118 39
Furfuryl alcohol NIOSH 2505 10 15 5 20 4 GC-FID ST 226-115 39
Fusarium species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Fusarium species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Gallium OSHA CSI 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Gallium (elements by ICP HNO3 digestion) NIOSH 7303 1-3300 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Gasoline OSHA PV2028 10 1.5 20(50) 100 8(3.3) 15 GC-FID ST 226-01 37
Gentian violet OSHA CSI 180 1000 3 HPLC-UV FLT 225-7‡ 74 CST 225-2LF 79
C/HLD 225-1 78
Germanium oxide OSHA CSI 960 2000 8 AA-GF F/CST 225-3-01 71 C/HLD 225-1 78
Germanium tetrahydride OSHA CSI 48 200 4 AA-GF ST 226-01 37
Glass, fibrous (see asbestos fibers) NIOSH 7400
Glass, fibrous dust OSHA CSI 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Gliocladium species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Gliocladium species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Glutaraldehyde NIOSH 2532 1346 0.2 3 200 15 HPLC-UV ST 226-119 39
Glutaraldehyde NON 43 30 15 250 1000 2 15 GC-FID ST 226-10 37
Glutaraldehyde OSHA 64 1241 15 1000 15 HPLC-UV CF/CST 225-9003 59 C/HLD 225-1 78
Glycerin mist (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Glycerin mist (respirable) OSHA CSI 5 mg/m 3
varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Glycerin mist (total dust) OSHA CSI 15 mg/m 3
96 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Glycidol  NIOSH 1608 25 10 20(50) 8(3.3) GC-FID ST 226-01 37
Glycidol (2,3-epoxy-1-propanol)  OSHA 07 1157 50 48 100(200) 8(4) GC-FID ST 226-01 37
Glycol chlorohydrin (see ethylene chlorohydrin)
Glycol ethers NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 38
Glycols NIOSH 5523 1402 60 1000 1 GC-FID ST 226-57 38
Glyphosate OSHA PV2067 100 1000 100 min HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Gold OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78

Sampling Guide
G Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Gold (elements by ICP HNO3 digestion) NIOSH 7303 1-3300 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Grain dust (oats, wheat, barley) OSHA CSI 10 mg/m3 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Graphite (natural) (respirable dust) OSHA ID 142 15 mppcf varies varies varies GR , XRD FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Graphite (synthetic) (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Graphite (synthetic) (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Graphite (synthetic) (respirable dust) OSHA CSI 5 mg/m 3
CYC 225-105 84 CST 225-3LF 79
Graphite (synthetic) (total dust) OSHA CSI 15 mg/m 3
960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Graphium species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Graphium species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Grunerite fibers (see asbestos) OSHA ID 160
Gypsum (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Gypsum (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Hafnium OSHA ID 121 0.5 mg/m 3
960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Halothane OSHA 103 1347 12 50 4 GC-FID ST 226-121 or ST 226-81A 38
Halothane OSHA 29 9 100 1.5 GC-FID ST 226-01 37
Haloxon OSHA CSI W W 225-2401A 112
HDI (see hexamethylene diisocyanate)
Heptachlor ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Heptachlor OSHA PV2029 0.5 mg/m3 60 1000 1 GC-ECD ST 226-30-16 37
Heptachlor (non-occupational exposure) ASTM D 4947 1417 240-7200 250 1000-5000 4-24 GC-ECD PUF 226-92 42
Heptachlor epoxide ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Heptanal (aldehydes, screening) NIOSH 2539 5 20 4 GC-FID & GC-MS ST 226-118 39
n-Heptane  OSHA 07 1156 500 5 3 20 200 4 15 GC-FID ST 226-01 37
3-Heptanone (ethyl butyl ketone) (ketones II )  NIOSH 2553 50 1-25 10-200 varies GC-FID ST 225-121 39
2-Heptanone (methyl-n-amyl ketone) (ketones II ) NIOSH 2553 100 1-25 10-200 varies GC-FID ST 225-121 39
1-Heptene  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Hexachloro-1,3-cyclopentadiene NIOSH 2518 0.01 24 50 8 GC-ECD ST 226-116 39
Hexachlorobenzene ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Hexachlorobenzene (HCB) OSHA CSI 480 2000 4 GC-ECD F/CST 225-706 74 C/HLD 225-1 78
Hexachlorobutadiene NIOSH 2543 0.02 48 100 8 GC-ECD ST 226-30-04 37
Hexachlorocyclopentadiene ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-124 42
Hexachlorocyclopentadiene (hexachloro- NIOSH 2518 0.01 48 100 8 GC-ECD ST 226-116 39
1,3-cyclopentadiene)
Hexachloroethane  OSHA 07 1155 1 30 100 5 GC-FID ST 226-01 37
Hexachloroethane (hydrocarbons, halogenated)  NIOSH 1003 1 10 10-200 varies GC-FID ST 226-01 37
Hexachloronaphthalene OSHA CSI 0.2 mg/m3 30 1000 30 min GC-ECD F/CST 225-3-01 71 C/HLD 225-1 78
Hexamethylene diisocyanate (HDI) NIOSH 5522 35 µg/m3 140 µg/m3 360 20 1000 2000 6 10 HPLC-FD IMP 225-36-1 61 IT 225-22 61
1,6-Hexamethylene diisocyanate (HDI) OSHA 42 1458 15 1000 15 min HPLC-UV, CF/CST 225-9002 or CF/CST 225-9013 59
Hexamethylene diisocyanate (HDI) (isocyanates) NIOSH 5521 35 µg/m3 140 µg/m3 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 61 IT 225-22 61
(10 min) (C) ELCHM, UV
1,6-Hexamethylene diisocyanate (isocyanates, NIOSH 5525 35 µg/m3 140 µg/ 1-500 1000-2000 varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
total [MAP]) m3 /10 SP 225-27 or IOM 225-76A 87
min C FLT 225-702 74
Hexamethylene diisocyanate (monomeric aerosol) ASTM D 6561 15 1000 15 min HPLC-UV CF/CST 225-9023 or CF/CST 225-9022 59
C/HLD 225-1 78
Hexamethylene diisocyanate (monomeric gaseous) ASTM D 6561 15 1000 15 min HPLC-UV CF/CST 225-9023 or CF/CST 225-9022 59
C/HLD 225-1 78
Hexamethylene diisocyanate (monomeric gaseous) ASTM D 6562 15 1000 15 min HPLC-UV, CF/CST 225-9023 or CF/CST 225-9022 59
-FD C/HLD 225-1 78
Hexamethylene diisocyanate (oligomeric aerosol) ASTM D 6561 15 1000 15 min HPLC-UV CF/CST 225-9023 or CF/CST 225-9022 59
C/HLD 225-1 78
Hexamethylene diisocyanate biuret OSHA PV2030 15 1000 15 min HPLC-UV FLT 225-7‡ 74 CST 225-3LF 79
C/HLD 225-1 78
Hexamethylenediamine OSHA CSI 12 100 2 HPLC-UV ST 226-30-18 37
Hexamethylenetetramine (HMTA) NON 52 15 1000 15 min GC-NPD or ST 226-57 38
GC-FID
Hexamethylenetetramine (HMTA) OSHA CSI 15 1000 15 min GC-NPD F/CST 225-3-01 71 IMP 225-36-1 61
IT 225-22 61
Hexanal ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
Hexanal (aldehydes, screening) NIOSH 2539 5 20 4 GC-FID & GC-MS ST 226-118 39
n-Hexane  OSHA 07 1154 500 5 20 4 GC-FID ST 226-01 37
Hexane (isomers other than n-hexane) OSHA CSI 4 3 20 200 3.3 15 GC-FID ST 226-01 37
1,6-Hexanediol OSHA CSI 6 100 1 GC-FID ST 226-09 37
1,6-Hexanediol diacrylate OSHA CSI 10 20(50) 8(3.3) HPLC ST 226-95 39
1,6-Hexanediol diacrylate OSHA PV2133 1 mg/m3 48 200 4 GC-FID ST1409 226-110 39
Hexanediol diacrylate (HDDA) NON 39 480 1000 8
2-Hexanone (methyl butyl ketone, MBK)  OSHA 07 1153 100 10 20(50) 8(3.3) GC-FID ST 226-01 37

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number H
2-Hexanone (methyl butyl ketone, MBK) (ketones I)  NIOSH 1300 1 10 20(50) 8(3.3) GC-FID ST 226-01 37
2-Hexanone (methyl butyl ketone, MBK) (ketones I)  NIOSH 2555 1-10 10-200 varies GC-FID ST 226-121 39
Hexavalent chromium ASTM D 6832 varies 1000-5000 varies IC F/CST 225-802 or F/CST 225-1713 or
F/CST 225-709 or F/CST 225-401 74
Hexavalent chromium NIOSH 7600 1032 1 µg/m3 (10 hr) 240 1000 4 VAS F/CST 225-802 73 C/HLD 225-1 78
Hexavalent chromium NIOSH 7604 1032 1 µg/m3 (10 hr) 240 1000 4 IC-ECN F/CST 225-802 73 C/HLD 225-1 78
Hexavalent chromium NIOSH 7605 0.001 mg/m3 1-400 1000-4000 varies IC-PCD-UV F/CST 225-802 73 C/HLD 225-1 78
(10 hr)
Hexavalent chromium NIOSH 7703 0.001 mg/m 3
10-1200 1000-4000 varies P VAS F/CST 225-802 73 C/HLD 225-1 78
(10 hr)
Hexavalent chromium OSHA ID 103 1439 0.005 mg/ 960 30 2000 2000 8 15 DPP F/CST 225-802 73 C/HLD 225-1 78
m3 (C)
Hexavalent chromium OSHA ID 215 1439 0.005 mg/m 3
960 2000 8 15 IC-UV F/CST 225-802 73 C/HLD 225-1 78
Hexavalent chromium OSHA W4001 0.005 mg/m3 (C) IC-UV FLT 225-8-01-1 or FLT 225-1822 74
Hexavalent chromium (CR(VI)) OSHA ID 215 0.005 mg/m3 960 2000 8 IC-UV F/CST 225-802 or FLT 225-1827‡ 74
(V2) CST 225-2LF 79 C/HLD 225-1 78
Hexavalent chromium(in settled dust) NIOSH 9101 bulk bulk CLR or VAS
or IC
Hexone (methyl isobutyl ketone, MIBK)  OSHA 07 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
Hexone (methyl isobutyl ketone, MIBK)  OSHA 1004 1745 100 12 50 4 GC-FID ST 226-121 39
Hexone (methyl isobutyl ketone, MIBK) (ketones I)  NIOSH 1300 50 75 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Hexone (methyl isobutyl ketone, MIBK) (ketones I)  NIOSH 2555 50 1-10 10-200 varies GC-FID ST 226-121 39
n-Hexyl acetate  OSHA CSI 6 200 30 min GC-FID ST 226-01 37
sec-Hexyl acetate  OSHA 07 1152 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
Hexyl alcohol  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Hexyl carbitol OSHA CSI 6 200 30 min GC-FID ST 226-01 37
Hexylene glycol  OSHA PV2101 3 200 15 GC-FID ST 226-01 37
HMX OSHA PV2032 480 1000 8 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Hydramethylnon (AMDRO) OSHA CSI 90 1000 1.5 HPLC-UV F/CST 225-3-01 71 C/HLD 225-1 78
Hydrazine  NIOSH 3503 0.03 (120 min) 90 1000 1.5 VAS IMP 225-36-2 61 IT 225-22 61
Hydrazine  NON 22 96 200 8 CLR ST 226-42-02 38
Hydrazine  OSHA 108 1 240 1000 4 IC-UV CF/CST 225-9012 59 C/HLD 225-1 78
Hydrazine  OSHA 20 1281 1 20 100 3.3 HPLC-UV ST 226-42-02 38
Hydrazine (skin) CI PCH 769-3004 or W 769-1034 110
Hydrazine (surface) CI W 769-1024 110
Hydrazoic acid NON 25 15 1000 15 HPLC-UV ST 226-55 38
Hydrazoic acid OSHA ID 211 5 1000 5 IC-UV ST 226-55 38 FLT 225-8-01 73
CST 225-2LF 79 SPC 225-23 78
C/HLD 225-1 78
Hydrobromic acid (acids, inorganic) NIOSH 7903 3 48 4.5 200 300 4 15 IC ST 226-10-03 37
Hydrocarbons BP 36 to 216 C (see specific compounds) NIOSH 1500 varies varies varies varies GC-FID ST 226-01 37
Hydrocarbons, aromatic (see specific compounds) NIOSH 1501 1453 varies varies varies varies GC-FID ST 226-01 37
Hydrocarbons, halogenated (see specific compounds) NIOSH 1003 1454 varies varies varies varies GC-FID ST 226-01 37
Hydrocyanic acid  DT 800-33221
Hydrofluoric acid (fluorides) NIOSH 7906 3 6 480 15 1000 1000 8 15 IC-ECN CF/CST 225-9001 59 C/HLD 225-1 78
Hydrogen OSHA CSI DET TB DT 810-30
Hydrogen bromide OSHA ID 165SG 3 97 3 200 200 8 15 IC ST 226-10-03 37
Hydrogen bromide (acids, inorganic) NIOSH 7903 3 48 4.5 200 300 4 15 IC ST 226-10-03 37
Hydrogen chloride (Hydrochloric acid, acids, inorganic)  NIOSH 7903 5 48 4.5 200 300 4 15 IC ST 226-10-03 37
Hydrogen chloride (Hydrochloric acid)  OSHA ID 174SG 5 7.5 500 15 IC ST 226-10-03 37
Hydrogen cyanide  NIOSH 6010 4.7 2-90 50-200 varies VAS ST 226-28 37
Hydrogen cyanide  OSHA ID 120 10 120 15 1000 1000 2 15 ISE CST 225-3LF 79 IMP 225-36-2 61
IT 225-22 61 FLT 225-5 70
SP 225-2902 78
Hydrogen cyanide (cyanides)  NIOSH 7904 5 mg/m3 15 1000 15 ISE FLT 225-2705∆ 75 CST 225-2LF 79
(10 min) IMP 225-36-2 61 IT 225-22 61
C/HLD 225-1 78
Hydrogen fluoride  NIOSH 7906 3 6 480 15 1000 1000 8 15 IC-ECN CF/CST 225-9001 59 C/HLD 225-1 78
Hydrogen fluoride (acids, inorganic)  NIOSH 7903 3 6 48 4.5 200 300 4 15 IC ST 226-10-03 37
Hydrogen fluoride (as F)  OSHA ID 110 3 90 22 1500 1500 1 15 ISE CF/CST 225-9001 59 C/HLD 225-1 78
Hydrogen fluoride (fluorides)  NIOSH 7902 3 6 480 30 1000 2000 8 15 ISE CF/CST 225-9001 59 C/HLD 225-1 78
Hydrogen fluoride (fluorides)  NIOSH 7906 2.5 mg/m3 480 1000 8 IC-ECN CF/CST 225-9001 59 C/HLD 225-1 78
Hydrogen peroxide (90%)  OSHA ID 126SG 1005 1 100 1000 100 min DPP IMP 225-36-2 61 IT 225-22 61
Hydrogen selenide (as Se) OSHA CSI 0.05 480 1000 8 AA IMP 225-36-2 61 IT 225-22 61
Hydrogen sulfide  NIOSH 6013 10 (10 min) 24 3 100 300 4 10 IC ST NA SKC
Hydrogen sulfide  NON 42 1414 12 1000 12 min GC-FPD SB 240-08B 53
Hydrogen sulfide  OSHA 1008 10 20 12 7.5 50 500 4 15 IC ST 226-177 40
Hydrogenated terphenyls OSHA CSI 30 1000 30 GC-FID FLT 225-17-04 75 CST 225-2LF 79
C/HLD 225-1 78
Hydroquinone NIOSH 5004 2 mg/m3 30 2000 15 HPLC-UV F/CST 225-3-01 71 C/HLD 225-1 78
(15 min)
Hydroquinone OSHA PV2094 2 mg/m3 20 200 100 min HPLC-UV ST 226-98 39
2-Hydroxy-4-methoxyacetophenone OSHA CSI 10 200 50 min HPLC-UV ST 226-30 37
4-Hydroxy-4-methyl-2-pentanone (see diacetone alcohol)
4-Hydroxy-4-methyl-2-petanone (alcohols combined) NIOSH 1405 50 1-10 10-200 varies GC-FID ST 226-01 37

Sampling Guide
H Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
m-Hydroxyacetophenone OSHA CSI 10 200 50 min HPLC-UV ST 226-30-04 37

m-Hydroxybenzoic acid OSHA CSI 180 1000 3 HPLC-UV F/CST 225-3-01 71 C/HLD 225-1 78
4-Hydroxycoumarin OSHA CSI 10 200 50 min HPLC-UV ST 226-30-04 37
Hydroxyethyl acrylate OSHA CSI 12 200 2 GC-FID ST 226-15GWS 37
2-Hydroxyethyl methacrylate OSHA CSI 10 200 50 min GC-FID ST 226-01 37
2-Hydroxypropyl acrylate OSHA PV2078 10 100 100 min GC-FID ST 226-73 38
2-Imidazolidinethione (ethylene thiourea) NIOSH 5011 LFC 480 1000 8 VAS F/CST 225-803 73 C/HLD 225-1 78
Indene OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-110 39
Indeno(1,2,3-cd)pyrene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Indeno(1,2,3-cd)pyrene (polynuclear aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
Indeno(1,2,3-cd)pyrene (polynuclear aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 75 ST 226-30-04 37
Indium OSHA ID 121 0.1 mg/m 3
Indium (elements by ICP HNO3 digestion) NIOSH 7303 15-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Indium & compounds (as In) OSHA CSI 0.1 mg/m3 960 2000 8 ICP-DCP F/CST 225-3-01 71 C/HLD 225-1 78
Inorganic acids (acids, inorganic) NIOSH 7903 1016 IC ST 226-10-03 37
Iodine NIOSH 6005 0.1 15 1000 15 IC ST 226-67 38
Iodine NON 16 48 100 8 IC ST 226-67 38
Iodine OSHA ID 212 0.1 (C) 2.5 500 5 IC ST 226-80 38
Iodine (particulates) OSHA ID 212 0.1 2.5 500 5 IC ST 226-142 39
Iodine (vapor) OSHA ID 212 0.1 2.5 500 5 IC ST 226-80 38
Iodoform OSHA CSI 10 100 100 min GC-ECD F/CST 225-706 74 C/HLD 225-1 78
ST 226-93 39
Iridium OSHA CSI 960 2000 8 AA F/CST 225-3-01 71
Iron OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Iron (bulk) OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Iron (elements by ICP Aqua Regia ashing) NIOSH 7301 5 mg/m3 5-100 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
(dust, fume) C/HLD 225-1 78
Iron (elements by ICP HNO3 digestion) NIOSH 7303 0.5 mg/m 3
1-5000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
(dust, fume)
Iron (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Iron (elements) NIOSH 7300 1455 5 mg/m3 5-100 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
(dust, fume)
Iron & compounds (as Fe) OSHA ID 121 1209 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Iron oxide (elements by ICP HNO3 digestion) NIOSH 7303 1-5000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Iron oxide fume OSHA ID 121 1045 10 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Iron oxide fume OSHA ID 10 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
125G C/HLD 225-1 78
Iron pentacarbonyl (as Fe) OSHA CSI 480 30 2000 2000 4 15 CLR IMP 225-36-2 61 IT 225-22 61
Iron salts, soluble (as Fe) OSHA ID 121 1208 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Isoamyl acetate  OSHA 07 1151 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
Isoamyl acetate (esters I)  NIOSH 1450 100 1-10 10-200 varies GC-FID ST 226-01 37
Isoamyl alcohol  OSHA CSI 100 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Isoamyl alcohol (alcohols combined)  NIOSH 1405 100 125 (skin) 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 37
Isoamyl alcohol (alcohols III)  NIOSH 1402 100 125 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Isoamyl nitrite OSHA CSI 5 20 4 HPLC-UV ST 226-01 37
Isobutyl acetate  OSHA 07 1150 150 10 20(50) 8(3.3) GC-FID ST 226-01 37
Isobutyl acetate  OSHA 1009 1750 150 12 0.75 50 50 4 15 GC-FID ST 226-01 37
Isobutyl acetate  OSHA 1009 1750 150 13.16 13.16 8 15 GC-FID PS 575-002 63
Isobutyl acetate (esters I)  NIOSH 1450 150 1-10 10-200 varies GC-FID ST 226-01 37
Isobutyl acrylate  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Isobutyl alcohol  OSHA 07 1149 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
Isobutyl alcohol (alcohols combined)  NIOSH 1405 50 2-10 10-200 varies GC-FID ST 226-01 37
Isobutyl alcohol (alcohols II)  NIOSH 1401 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
Isobutyl isobutyrate OSHA PV2090 10 200 50 min GC-FID ST 226-01 37
Isobutyl nitrite OSHA CSI 5 20 4 HPLC-UV ST 226-01 37
Isobutylbenzene OSHA CSI 6 200 30 min GC-FID ST 226-01 37
Isobutyraldehyde (aldehydes, screening) NIOSH 2539 5 20 4 GC-FID & GC-MS ST 226-118 39
Isobutyric acid OSHA CSI 6 100 1 GC-FID ST 226-110 39
Isobutyronitrile OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Isocyanates NIOSH 5521 1459 varies 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 61 IT 225-22 61
ELCHM, UV
Isocyanates NIOSH 5522 1460 varies varies 360 20 1000 2000 6 10 HPLC-FD IMP 225-36-1 61 IT 225-22 61
Isocyanates (see specific isocyanate)
Isocyanates, aromatic (surface) CI W 769-1022 or TK 769-1002 110
Isocyanates, aliphatic (skin) CI PCH 769-3003 or W 769-1033 or
TK 769-1003 110
Isocyanates, aliphatic (surface) CI W 769-1023 or TK 769-1003 110
Isocyanates, aromatic (skin) CI PCH 769-3002 or W 769-1032 or
TK 769-1002 110

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number I
Isocyanates, total (MAP) (see specific isocyanate) NIOSH 5525 varies varies 1-500 1-500 1000-2000 1000-2000 varies varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
SP 225-27 or IOM 225-76A 87
FLT 225-702‡ 74
Isofenphos OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Isoflurane  OSHA 103 1349 12 50 4 GC-FID ST 226-121 or ST 226-81A 38
Isooctane OSHA CSI DET TB DT 810-101
Isooctyl alcohol  OSHA PV2033 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
Isophorone  NIOSH 2508 4 10 20(50) 8(3.3) GC-FID ST 226-81A 38
Isophorone  NIOSH 2556 4 2-25 10-100 varies GC-FID ST 226-93 39
Isophorone  OSHA 07 1160 25 10 20(50) 8(3.3) GC-FID ST 226-81A 38
Isophorone diisocyanate OSHA PV2034 60 15 1000 1000 1 15 HPLC-UV CF/CST 225-9002 59 C/HLD 225-1 78
Isophorone diisocyanate (isocyanates, total NIOSH 5525 45 µg/m3 180 µg/m3 1-500 1000-2000 varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
[MAP]) /10 min C SP 225-27 or IOM 225-76A 87
FLT 225-702‡ 74
Isophthalic acid OSHA CSI bulk HPLC-UV
Isoprene  DT 810-174D
Isopropyl acetate  NIOSH 1454 9 50 3 GC-FID ST 226-01 37
Isopropyl acetate  NIOSH 1460 0.1-9.0 20-200 varies GC-FID ST 226-01 37
Isopropyl acetate  OSHA 07 1148 250 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Isopropyl alcohol  OSHA 07 1147 400 3 1.5 20 100 2.5 15 GC-FID ST 226-01 37
Isopropyl alcohol  OSHA 109 400 18 3 50 200 6 15 GC-FID ST 226-82 38
Isopropyl alcohol (alcohols I)  NIOSH 1400 400 500 3 3 20 200 2.5 15 GC-FID ST 226-01 37
Isopropyl amine  OSHA CSI 5 90 15 1000 1000 1.5 15 GC-FID IMP 225-36-2 61 IT 225-22 61
N-Isopropyl aniline OSHA 78 1228 100 1000 100 min HPLC-UV CF/CST 225-9004 59 C/HLD 225-1 78
Isopropyl bromide OSHA CSI 12 100 2 GC-FID ST 226-01 37
Isopropyl CELLOSOLVE solvent (see ethylene OSHA CSI
glycol isopropyl ether)
Isopropyl ether  NIOSH 1618 500 0.1-3 10-50 varies GC-FID ST 226-01 37
Isopropyl ether  OSHA 07 1146 500 3 0.75 20 50 2.5 15 GC-FID ST 226-01 37
Isopropyl glycidyl ether (IGE)  NIOSH 1620 50 (15 min) 3 200 15 GC-FID ST 226-01 37
Isopropyl glycidyl ether (IGE)  OSHA 07 1145 50 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Isopropyl m-chlorocarbanilate OSHA CSI 30 1000 30 min HPLC-UV IMP 225-36-1 61 IT 225-22 61
Isovaleraldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
Isovaleraldehyde (aldehydes, screening) NIOSH 2539 5 20 4 GC-FID & GC-MS ST 226-118 39
Jet fuel OSHA CSI 3 200 15 GC-FID ST 226-01 37
Kaolin (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Kaolin (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Kaolin (respirable dust) OSHA CSI 5 mg/m3 varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Kaolin (total dust) OSHA CSI 15 mg/m3 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Kathon 886 (kathon biocide) NON 55 50 7.5 200 500 4 15 HPLC-UV ST 226-99 39
Kepone NIOSH 5508 1 µg/m3 480 1000 8 GC-ECD F/CST 225-3-01 71 IMP 225-36-1 61
IT 225-22 61
Kepone OSHA CSI 480 1000 8 GC-ECD F/CST 225-3-01 71 IMP 225-36-1 61
IT 225-22 61
Kerosene OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Kerosene OSHA PV2139 20 100 200 min GC-FID ST 226-01 37
Kerosene (naphthas) NIOSH 1550 100 mg/m3 10 20(50) 8(3.3) GC-FID ST 226-01 37
Ketene OSHA CSI 0.5 50 15 1000 1000 50 min 15 CLR IMP 225-36-2 61 IT 225-22 61
Ketones (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 40
Ketones (see Environmental Sampling Guide) EPA TO-5
Ketones I (see specific compounds) NIOSH 1300 varies varies 10-200 varies GC-FID ST 226-01 37
Ketones I (see specific compounds) NIOSH 2555 varies varies varies GC-FID ST 226-121 39
Ketones II (see specific compounds) NIOSH 1301 varies varies varies 8 GC-FID ST 226-01 37
Ketones II (see specific ketone) NIOSH 2553 varies varies 1-25 1-25 10-200 10-200 varies varies GC-FID ST 225-121 39
Lactic acid powder NON 53 F/CST 225-1725 or FLT 225-2714 and
CST 225-2257 and SP 225-2901 78
Lake Red C OSHA CSI 300 2000 2.5 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Landrin OSHA CSI 60 1000 1 HPLC-UV ST 226-30-16 37
Lanthanum (elements by ICP Aqua Regia ashing) NIOSH 7301 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Lanthanum (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Lanthanum (elements) NIOSH 7300 1455 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Lasso (aroclor) OSHA PV2035 100 1000 100 min HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Lead NIOSH 7082 1034 < 0.1 mg/m3 720 1500 8 AAS-F F/CST 225-3-01 71 C/HLD 225-1 78
Lead NIOSH 7105 1034 < 0.1 mg/m3 720 1500 8 AAS-GF F/CST 225-3-01 71 C/HLD 225-1 78
Lead (elements by ICP Aqua Regia ashing) NIOSH 7301 0.05 mg/m3 50-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Lead (elements by ICP HNO3 digestion) NIOSH 7303 0.5 mg/m3 35-100,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Lead (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112

Sampling Guide
L Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Lead (elements) NIOSH 7300 1034 0.05 mg/m3 50-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Lead (ICP analysis of metal/metalloid particulates OSHA ID 206 480 2000 4 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
from solder operations)
Lead (in air by chemical spot test) NIOSH 7700 1369 < 0.1 mg/m 3
240 2000 2 SPOT W 225-2404 112 F/CST 225-3-01 71
Lead (in dust wipes) NIOSH 9105 SPOT W 550-001 or W 550-002 109
Lead (in surface dust) ASTM E 1792 bulk Varies W 225-2414 112 TMP 225-2403 112
Lead (in surface dust) OSHA ID 125G wipe ICP-AES W 225-2414 112 TMP 225-2403 112
Lead (in workplace air) ASTM D 6785 varies varies varies AAS-F IOM 225-70A 87 FLT 225-1930 70
Lead (on surfaces) NIOSH 9100 AA, AA-GF W 225-2401A 112
or ICP
Lead by field portable XRF NIOSH 7702 < 0.1 mg/m3 960 2000 8 XRF F/CST 225-3-01 71
Lead by portable ultrasound extraction/ASV NIOSH 7701 0.05 mg/m3 20-1500 1000-4000 varies PASV F/CST 225-3-01 71 C/HLD 225-1 78
Lead chromate (as Pb) OSHA CSI 50 µg/m3 960 2000 8 AA F/CST 225-3-01 71 C/HLD 225-1 78
Lead chromate (as Pb) (see lead, inorganic fumes OSHA CSI
& dusts or chromic acid & chromates)
Lead chromate (CR(VI)) OSHA ID 215 (V2) 0.005 mg/m3 960 2000 8 IC-UV F/CST 225-802 or FLT 225-1827‡ 74
CST 225-2LF 79 C/HLD 225-1 78
Lead oxide (as lead) NIOSH 7082 1034 < 0.1 mg/m 3
720 1500 8 AAS-F F/CST 225-3-01 71 C/HLD 225-1 78
Lead oxide (as Pb) NIOSH 7105 1034 < 0.1 mg/m3 720 1500 8 AAS-GF F/CST 225-3-01 71 C/HLD 225-1 78
Lead oxide by field portable XRF NIOSH 7702 < 0.1mg/m3 960 2000 8 XRF F/CST 225-3-01 71
Lead oxide by portable ultrasound extraction/ASV NIOSH 7701 0.05 mg/m3 20-1500 1000-4000 varies PASV F/CST 225-3-01 71 C/HLD 225-1 78
Lead sulfide (as Pb) NIOSH 7505 < 0.1 mg/m3 750 2500 5 XRD F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Lead, inorganic fumes & dusts (as Pb) OSHA ID 121 1196 0.05 mg/m3 960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Lead, inorganic fumes & dusts (as Pb) OSHA ID 125G 0.05 mg/m3 480 30 2000 15 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Lead, inorganic surface dusts (as Pb) OSHA ID 121 1179 AA or AES W 225-2401A 112
Limestone (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Limestone (see calcium carbonate)
Limestone (see dust, total & respirable nuisance)
Limonene  OSHA PV2036 10 20(50) 8(3.3) GC-FID ST 226-01 37
Limonene (terpenes)  NIOSH 1552 24 50 8 GC-FID ST 226-01 37
Lindane OSHA CSI 0.5 mg/m3 240 1000 4 GC-ECD F/CST 225-706 74 C/HLD 225-1 78
IMP 225-36-1 61 IT 225-22 61
Lindane (gamma-BHC) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Linuron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Linuron OSHA CSI 240 1000 4 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Lithium OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Lithium (elements by ICP Aqua Regia ashing) NIOSH 7301 100-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Lithium (elements) NIOSH 7300 1455 100-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Lithium hydride (as Li) OSHA ID 121 0.025 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Lithium hydroxide (alkaline dust) NIOSH 7401 960 2000 8 TITRA FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Lithium hydroxide (as Li) OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
LPG (liquified petroleum gas) OSHA CSI 1000 DET TB DT 810-100A
Machette OSHA CSI 100 1000 100 min HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Magnesite (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Magnesite (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Magnesite (see dust, total & respirable nuisance)
Magnesite (see dust, total & respirable nuisance) OSHA CSI
Magnesium OSHA ID 121 1192 960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Magnesium (elements by ICP Aqua Regia ashing) NIOSH 7301 10 mg/m3 5-67 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
(fume, as oxide) C/HLD 225-1 78
Magnesium (elements by ICP HNO3 digestion) NIOSH 7303 1-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Magnesium (elements) NIOSH 7300 1455 10 mg/m3 5-67 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
(fume, as oxide)
Magnesium oxide (as Mg, elements by ICP) NIOSH 7303 10 5-33000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Magnesium oxide fume (respirable dust) OSHA ID 121 1214 5 mg/m3 960 2000 8 AA or AES, F/CST 225-3-01 71 C/HLD 225-1 78
GR CYC 225-105 84
Magnesium oxide fume (total dust) OSHA ID 121 1213 15 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Malathion ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 42
Malathion OSHA 62 1397 15 mg/m3 60 1000 1 GC-FPD ST 226-30-16 37
Malathion (organophosphorus pesticides) NIOSH 5600 10 mg/m3 60 1000 1 GC-FPD ST 226-58 38
Malbranchea species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Malbranchea species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Maleic anhydride  NIOSH 3512 0.25 360 1000 6 HPLC-UV IMP 225-36-2 61 IT 225-22 61
Maleic anhydride  OSHA 25 0.25 20 100 3.3 HPLC-UV ST 226-30-07 37 ST 226-30 37
Maleic anhydride  OSHA 86 0.25 60 500 2 HPLC-UV CF/CST 225-9021†† 59 C/HLD 225-1 78
Maneb OSHA 107 500 2000 250 HPLC-UV F/CST 225-3-01 71 C/HLD 225-1 78
Maneb OSHA CSI W W 225-2401A 112
Manganese (elements by ICP Aqua Regia ashing) NIOSH 7301 1 mg/m3 3 mg/m3 5-200 5-200 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number M
Manganese (elements by ICP HNO3 digestion) NIOSH 7303 1 mg/m3 3 mg/m3 0.05- 0.05- 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
10,000 10,000
Manganese (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Manganese (elements) NIOSH 7300 1455 1 mg/m3 3 mg/m3 5-200 5-200 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Manganese & compounds (as Mn) OSHA ID 121 1194 5 mg/m3 (C) 960 10 2000 2000 8 5 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Manganese & compounds (as Mn) OSHA ID 125G 5 mg/m3 10 2000 5 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Manganese cyclopentadienyl tricarbonyl (as Mn) OSHA CSI 480 1000 8 AA F/CST 225-3-01 71 IMP 225-36-2 61
IT 225-22 61
Manganese fume OSHA ID 125G 5 mg/m3 480 30 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Manganese fume (as Mn) OSHA ID 121 1195 5 mg/m3 (C) 960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Manganese tetroxide (as Mn) OSHA ID 121 1191 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Manganese tetroxide (as Mn) OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Marble (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Marble (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Marble (see dust, total and respirable nuisance)
MCPA (2-methyl-4-chlorophenoxyacetic acid) OSHA CSI 240 500 8 HPLC F/CST 225-706 74 C/HLD 225-1 78
MCPP OSHA CSI 240 1000 4 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
MDI (4,4-methylene bisphenyl isocyanate) OSHA 47 50 µg/m3 200 µg/m3 10 1000 10 HPLC-UV CF/CST 225-9002 or CF/CST 225-9013 59
C/HLD 225-1 78
MDI (4,4-methylenebis[phenyl isocyanate]) NIOSH 5525 50 µg/m3 200 µg/ 1-500 1000- varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
(isocyanates, total [MAP]) m3 /10 2000 SP 225-27 or IOM 225-76A 87
min C FLT 225-702‡ 74
MDI (4,4’-methylenebisphenyl isocyanate) NIOSH 5521 1001 50 µg/m3 200 µg/m3 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 61 IT 225-22 61
(isocyanates) (10 min) C ELCHM, UV
Melamine OSHA CSI 40 1000 40 min HPLC F/CST 225-709 74 C/HLD 225-1 78
Melengestrol acetate OSHA CSI 120 1000 2 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Menadione OSHA CSI 10 20(50) 8(3.3) HPLC-UV ST 226-30 37
Mercaptans (see specific compounds) NIOSH 2542 1330 0.5 (15 min) 48 12 100 200 8 60 GC-FPD CF/CST 225-9007 59 C/HLD 225-1 78
Mercaptoethanol OSHA CSI 10 20(50) 8(3.3) GC-FPD ST 226-10 37
Mercury NIOSH 6009 0.05 mg/m3 48 200 4 AA ST 226-17-1A 37 F/CST 225-3-01 71
Mercury (Rathje & Marcero) NON 17 48 100 8 AA ST 226-17-1A 37
Mercury (Rathje & Marcero) NON 17 varies 1000-3000 varies AA ST 226-17-3A 37
Mercury (vapor) OSHA ID 140 1677 0.1 mg/m3 3-100 200 varies AA ST 226-17-1A 37 F/CST 225-3-01 71
Mercury (vapor) OSHA ID 140 1677 0.1 mg/m3 9.6 20 8 AA PS 520-03 66 C 520-02A 66
Mercury, aryl & inorganic (particulate Hg) OSHA ID 145 0.01 mg/m3 30 2000 15 AA F/CST 225-3-01 71 C/HLD 225-1 78
Mesityl oxide  OSHA 07 1144 25 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Mesityl oxide (ketones II )  NIOSH 2553 10 1-25 10-200 varies GC-FID ST 225-121 39
Mesityl oxide (ketones II)  NIOSH 1301 10 10 20(50) 8(3.3) GC-FID ST 226-01 37
Mestranol OSHA PV2068 480 2000 4 HPLC F/CST 225-802 73 C/HLD 225-1 78
Metal & metalloid particulates OSHA ID 121 1177 varies varies 960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Metal & metalloid particulates OSHA ID 125G 1371 varies varies 480 30 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Metal removal fluid (aerosol) ASTM D 7049 960 2000 8 GR FLT 225-27-07 75 CST 225-2LF 79
C/HLD 225-1 78
Metal working fluids (aerosols) ASTM D 7049 960 2000 8 GR FLT 225-27-07 75 CST 225-2LF 79
C/HLD 225-1 78
Metals (in settled dust) ASTM D 6966 wipe wipe wipe Varies W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Metals in workplace atmospheres ASTM D 4185 1426 varies 2000 varies AAS F/CST 225-3-01 71 C/HLD 225-1 78
Metals, trace (elements) NIOSH 7300 1455 varies varies varies varies 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Metalworking fluids (thoracic particulates) NIOSH 5524 0.4 mg/m3 2000 varies varies GR PPI 225-381 83 FLT 225-27-07 83
(thoracic IS 225-388 83 SP 225-27 or
particulates) SCRN 225-26 83
Metalworking fluids (total particulates) NIOSH 5524 1726 0.5 mg/m3 (total 1000 (min) 2000 varies GR FLT 225-27-07 75 CST 225-4 79
particulates) C/HLD 225-1 78
Methacrylic acid OSHA PV2005 24 100 4 HPLC-UV ST 226-30-08 37
Metham sodium OSHA CSI 40 1000 40 min HPLC-UV ST 226-58 38
Methamidophos OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Methamidophos (organophosphorus pesticides) NIOSH 5600 240 1000 4 GC-FPD ST 226-58 38
Methane OSHA CSI DET TB DT 800-20001
Methanol (methyl alcohol) NIOSH 2000 200 250 5 3 20 200 4 15 GC-FID ST 226-51 38
Methidathion OSHA PV2074 60 1000 1 GC-ECD ST 226-58 38
Methiocarb (organonitrogen pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Methomyl OSHA PV2114 60 1000 1 HPLC-UV ST 226-30-16 37
Methomyl (organonitrogen pesticides) NIOSH 5601 2.5 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Methotrexate OSHA PV2146 120 1000 2 HPLC-UV ST 226-30-16 37
2-Methoxy-1-propanol  OSHA 99 10 100 100 min GC-FID ST 226-01 37
2-Methoxy-1-propyl acetate  OSHA 99 10 100 100 min GC-FID ST 226-01 37
1-Methoxy-2-propanol  OSHA 99 10 100 100 min GC-FID ST 226-01 37
1-Methoxy-2-propanol (glycol ethers)  NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 38

Sampling Guide
M Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
1-Methoxy-2-propyl acetate  OSHA 99 10 100 100 min GC-FID ST 226-01 37

1-Methoxy-2-propyl acetate (glycol ethers)  NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 38
Methoxychlor ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Methoxychlor OSHA PV2038 15 mg/m3 60 1000 1 GC-ECD ST 226-30-16 37
2-Methoxyethanol (methyl CELLOSOLVE solvent)  OSHA 79 1277 25 48 15 100 1000 8 15 GC-FID ST 226-01 37
2-Methoxyethanol (methyl CELLOSOLVE solvent)  NIOSH 1403 1274 0.1 (skin) 6-50 10-50 varies GC-FID ST 226-01 37
(alcohols IV)
2-Methoxyethyl acetate (methyl CELLOSOLVE acetate)  OSHA 79 1277 25 48 15 100 1000 8 15 GC-FID ST 226-01 37
Methoxyflurane OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
2-Methoxyphenol OSHA PV2039 20 200 100 min GC-FID ST 226-95 39
Methoxypropanol  TD, GC PS 590-259 and SV 590-260 or
SV 590-261 or SV 590-262 67
6-Methoxytetralone OSHA CSI 10 20(50) 8(3.3) HPLC-UV ST 226-30 37
Methyl acetate  NIOSH 1458 200 250 5 3 20 200 4 15 GC-FID ST 226-01 37
Methyl acetate  OSHA 07 1143 200 5 3 20 200 4 15 GC-FID ST 226-01 37
Methyl acetylene-propadiene mixture (MAPP) OSHA 07 1142 1000 2 0.75 20 50 100 min 15 min GC-FID ST 226-01 37
Methyl acrylate  NIOSH 1459 10 5 20 4 GC-FID ST 226-01 37
Methyl acrylate  NIOSH 2552 10 1-5 10-200 varies GC-FID ST 226-121 39
Methyl acrylate  NON 54 5 15 10 3 20 200 8 15 GC-FID ST 226-81A 38
Methyl acrylate  OSHA 92 10 12 50 4 GC-FID ST 226-73 38
Methyl acrylonitrile OSHA 37 20 200 100 min GC-NPD ST 226-01 37
Methyl alcohol (methanol) NIOSH 2000 200 250 5 3 20 200 4 15 GC-FID ST 226-51 38
Methyl alcohol (RH < 50% at 25 C) OSHA 91 1328 200 3 0.75 50 50 1 15 GC-FID ST 226-82 38
Methyl alcohol (RH > 50% at 25 C) OSHA 91 1328 200 5 0.75 50 50 100 min 15 GC-FID ST 226-82 38
Methyl amine  OSHA 40 10 10 20 8 HPLC-UV ST 226-96 39
Methyl arsonic acid (arsenic, organo-) NIOSH 5022 480 1000 8 IC-AA FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Methyl bromide ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Methyl bromide OSHA PV2040 20 3 200 15 GC-FID ST 226-83 38
Methyl butyl ketone (MBK, 2-hexanone) (ketones I)  NIOSH 1300 1 10 20(50) 8(3.3) GC-FID ST 226-01 37
Methyl butyl ketone (MBK, 2-hexanone) (MBK) (ketones I)  NIOSH 2555 1-10 10-200 varies GC-FID ST 226-121 39
Methyl CELLOSOLVE acetate (2-methoxyethyl acetate)  NIOSH 1451 0.1 12 50 4 GC-FID ST 226-01 37
Methyl CELLOSOLVE acetate (2-methoxyethyl acetate)  OSHA 79 1277 25 48 15 100 1000 8 15 GC-FID ST 226-01 37
Methyl CELLOSOLVE solvent (2-methoxyethanol)  OSHA 79 1277 25 48 15 100 1000 8 15 GC-FID ST 226-01 37
Methyl CELLOSOLVE solvent (2-methoxyetha-  NIOSH 1403 1274 0.1 (skin) 6-50 10-50 varies GC-FID ST 226-01 37
nol) (alcohols IV)
Methyl chloride ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Methyl chloride NIOSH 1001 LFC 0.5 100 5 GC-FID ST 226-09 37 ST 226-01 37
Methyl chloroform  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Methyl chloroform (1,1,1-trichloroethane)  OSHA 14 350 3 3 20 200 2.5 15 GC-FID ST 226-01 37
Methyl chloroform (1,1,1-trichloroethane) (hydro-  NIOSH 1003 350 3 10-200 varies GC-FID ST 226-01 37
Methyl cyclohexane  OSHA 07 1069 500 5 20 4 GC-FID ST 226-01 37
Methyl cyclohexane (hydrocarbons, BP 36 to 216 C)  NIOSH 1500 400 4 10-200 varies GC-FID ST 226-01 37
Methyl demeton OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
N-Methyl dicyclohexylamine OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-10 37
Methyl ethyl ketone (ketones I)  NIOSH 2555 1-10 10-200 varies GC-FID ST 226-121 39
Methyl ethyl ketone (MEK)  OSHA 1004 1745 200 12 50 4 GC-FID ST 226-121 39
Methyl ethyl ketone (MEK) (see 2-butanone) 
Methyl ethyl ketone (MEK) (see 2-butanone)  NIOSH 2500 1012 200 300 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-81A or ST 226-121 39
Methyl ethyl ketone peroxide NIOSH 3508 1002 0.2 (15 min) 120 1000 120 VAS IMP 225-36-1 61 IT 225-22 61
Methyl ethyl ketone peroxide OSHA 77 15 1000 15 HPLC-UV ST 226-93 39
Methyl formate OSHA PV2041 100 3 50 1 GC-FID ST 226-83 38
Methyl iodide  NIOSH 1014 2 48 100 8 GC-FID ST 226-01 37
Methyl iodide  OSHA CSI 5 50 200 4 GC-FID ST 226-01 37
Methyl isoamyl acetate (esters I) NIOSH 1450 50 1-10 10-200 varies GC-FID ST 226-01 37
Methyl isoamyl ketone  OSHA PV2042 100 24 50 8 GC-FID ST 226-01 37
Methyl isobutyl carbinol (methyl amyl alcohol)  OSHA 07 1068 25 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Methyl isobutyl carbinol (methyl amyl alcohol)  NIOSH 1405 25 40 (skin) 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 37
(alcohols combined)
Methyl isobutyl carbinol (methyl amyl alcohol)  NIOSH 1402 25 40 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
(alcohols III)
Methyl isobutyl ketone (MIBK, hexone)  OSHA 07 1070 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
Methyl isobutyl ketone (MIBK, hexone)  OSHA 1004 1745 100 12 50 4 GC-FID ST 226-121 39
Methyl isobutyl ketone (MIBK, hexone) (ketones I)  NIOSH 1300 50 75 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Methyl isobutyl ketone (MIBK, hexone) (ketones I)  NIOSH 2555 50 1-10 10-200 varies GC-FID ST 226-121 39
Methyl isocyanate (MIC) OSHA 54 0.02 15 50 5 HPLC-FD ST NA SKC 39
Methyl isopropyl ketone  OSHA CSI 10 20 8 GC-FID ST 226-01 37
Methyl isothiocyanate OSHA CSI 120 1000 2 GC-FID ST 226-16 37
Methyl mercaptan NIOSH 2542 1330 0.5 (15 min) 48 12 100 200 8 60 GC-FPD CF/CST 225-9007 59 C/HLD 225-1 78
Methyl mercaptan NON 42 1412 12 1000 12 min GC-FPD SB 240-08B 53

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number M
Methyl mercaptan OSHA 26 10 20 200 100 min GC-FPD CF/CST 225-9007 59 C/HLD 225-1 78
Methyl methacrylate  NIOSH 2537 100 1-8 10-50 varies GC-FID ST 226-30-06 37
Methyl methacrylate  NON 54 50 75 10 3 20 200 8 15 GC-FID ST 226-81A 38
Methyl methacrylate  OSHA 94 100 3 50 1 GC-FID ST 226-73 38
4-Methyl morpholine OSHA CSI 30 100 5 GC-FID ST 226-98 39
Methyl parathion ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 42
Methyl parathion OSHA PV2112 480 1000 8 GC-FPD ST 226-30-16 37
Methyl parathion (organophosphorus pesticides) NIOSH 5600 0.2 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Methyl propyl ketone (2-pentanone)  OSHA 07 200 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Methyl propyl ketone (2-pentanone) (ketones I) NIOSH 2555 1-10 10-200 varies GC-FID ST 226-121 39
Methyl silicate OSHA CSI 9 50 3 GC-FID ST 226-30-04 37
alpha-Methyl styrene  OSHA 07 1066 100 (C) 30 3 200 200 2.5 15 GC-FID ST 226-01 37
alpha-Methyl styrene (hydrocarbons, aromatic)  NIOSH 1501 50 100 1-30 1-30 10-200 10-200 varies varies GC-FID ST 226-01 37
beta-Methyl styrene (hydrocarbons, aromatic) NIOSH 1501 50 100 1-30 1-30 10-200 10-200 varies varies GC-FID ST 226-01 37
17-a-Methyl testosterone OSHA PV2001 60 1000 1 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Methyl-2-cyanoacrylate (MCA) OSHA 55 12 100 2 HPLC-UV ST 226-98 39
3-Methyl-2-cyclopentene-2-ol-one OSHA CSI 10 200 50 min HPLC-UV ST 226-30-04 37
1-Methyl-2-ethyl benzene  TD, GC PS 590-259 and SV 590-260 or
SV 590-262 67
1-Methyl-2-pyrrolidinone OSHA PV2043 10 200 50 min ST 226-01 37
N-Methyl-2-pyrrolidinone NIOSH 1302 96 200 8 GC-NPD, FID ST 226-01 37
N-Methyl-2-pyrrolidinone OSHA PV2043 10 200 50 min GC-FID ST 226-01 37
SV 590-262 67
5-Methyl-3-heptanone (ketones II)  NIOSH 1301 25 10 20(50) 8(3.3) GC-FID ST 226-01 37
5-Methyl-3-heptanone (ketones II)  NIOSH 2553 25 1-25 10-200 varies GC-FID ST 225-121 39
SV 590-262 67
2-Methyl-4-isothiazolin-3-one (Kathon 886) NON 55 1.5 mg/m 4.5 mg/m 50
3 3
7.5 200 500 4 15 HPLC-UV ST 226-99 39
Methyl-n-amyl ketone (2-heptanone)  OSHA CSI 100 24 200 2 GC-FID ST 226-01 37
Methyl-n-amyl ketone (2-heptanone) (ketones II )  NIOSH 2553 100 1-25 10-200 varies GC-FID ST 225-121 39
Methyl-n-amyl ketone (2-heptanone) (ketones II)  NIOSH 1301 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
5-Methyl-o-anisidine OSHA CSI 60 1000 1 HPLC-UV ST 226-30-04 37
Methyl-tert-amyl ether (tert-amyl methyl ether)  GC-FID PS 575-001 63
Methyl-tert-butyl ether (MTBE)  NIOSH 1615 1017 96 200 8 GC-FID ST 226-37 38
Methylacetylene (propyne) OSHA CSI 1000 2 50 40 min GC-FID ST 226-01 37
Methylal (dimethoxymethane)  NIOSH 1611 1000 1.8 20 1.5 GC-FID ST 226-01 37
Methylal (see dimethoxymethane) 
6-Methylcoumarin OSHA CSI 10 20(50) 8(3.3) HPLC-UV ST 226-30 37
Methylcyclohexanol  NIOSH 1404 50 12 25 8 GC-FID ST 226-01 37
Methylcyclohexanol  OSHA CSI 100 12 25 8 GC-FID ST 226-01 37
Methylcyclohexanone NIOSH 2521 50 75 3 50 1 GC-FID ST 226-115 39
o-Methylcyclohexanone OSHA CSI 100 6 0.75 50 50 2 15 GC-FID ST 226-115 39
Methylcyclopentadienyl manganese tricarbonyl (as Mn) OSHA CSI 5 (C) 10 200 1 AA ST 226-30 37
N-Methyldiethanolamine OSHA CSI 20 100 3.3 GC-NPD ST 226-42-02 38
4,4-Methylene bisphenyl isocyanate (MDI) OSHA 47 1242 200 µg/m3 15 1000 15 HPLC-UV CF/CST 225-9002 or CF/CST 225-9013 59
C/HLD 225-1 78
4,4-Methylene bisphenyl isocyanate (MDI) NIOSH 5521 1001 50 µg/m 3
200 µg/m 480
3
10 1000 1000 8 10 HPLC- IMP 225-36-1 61 IT 225-22 61
(isocyanates) (10 min) C ELCHM, UV
Methylene chloride  NIOSH 1005 1018 LFC 2 1.5 20 100 1.6 15 GC-FID ST 226-01 37
Methylene chloride  OSHA 59 1358 25 125 10 0.25 50 50 3.3 5 GC-FID ST 226-09-02 37
Methylene chloride  OSHA 80 1333 25 125 3 0.25 50 50 1 5 GC-FID ST 226-121 39
Methylene-bis-(4-cyclohexylisocyanate) OSHA PV2092 15 1000 15 HPLC-UV CF/CST 225-9013 59 C/HLD 225-1 78
Methylene-bis-(4-cyclohexylisocyanate) (isocya- NIOSH 5525 110 µg/m3 / 1-500 1000-2000 varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
nates, total [MAP]) 10 min C SP 225-27 or IOM 225-76 87
FLT 225-702‡ 74
2,2’-Methylene-bis(4-chlorophenol) OSHA CSI 750 2000 6.25 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
4,4’-Methylenebis(2-chloroaniline) (MOCA) OSHA 71 1234 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
4,4-Methylenebisphenyl isocyanate (MDI) NIOSH 5525 50 µg/m3 200 µg/m3 1-500 1000-2000 varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
(isocyanates, total [MAP]) /10min C SP 225-27 or IOM 225-76A 87
FLT 225-702‡ 74
4,4’-Methylenedianiline (MDA) NIOSH 5029 LFC 480 1000 8 HPLC-UV CF/CST 225-9004 59 C/HLD 225-1 78
4,4’-Methylenedianiline (MDA) OSHA 57 1240 100 1000 100 GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
4,4-Methylenediphenyl isocyanate (MDI) NIOSH 5522 50 µg/m3 200 µg/m3 360 20 1000 2000 6 10 HPLC-FD IMP 225-36-1 61 IT 225-22 61
(10 min) C
2-Methylpentane  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
3-Methylpentane  OSHA CSI 5 20 4 GC ST 226-01 37
Methylphenols (see Environmental Sampling Guide) EPA TO-8
Methyltetrahydrophthalic anhydride NON 28 200 20 40 1000 8 20 GC-FID ST 226-30 37
Methyltin dichloride NIOSH 5526 0.1 mg/m3 60 60 250 1000 4 60 GC-FPD ST 226-30-16 37
Methyltin mercaptide (tin, organic compounds [as Sn]) OSHA CSI 480 1000 8 AA-GF ST 226-30-16 37
Metolachlor ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Metolachlor NIOSH 5602 480 1000 8 GC-ECD ST 226-58 38
Metribuzin OSHA PV2044 240 1000 4 GC-FPD ST 226-30-16 37

Sampling Guide
M Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Mevinphos (phosdrin) OSHA CSI 0.1 mg/m3 480 15 1000 1000 8 15 GC-FPD ST 226-30-16 37
Mevinphos (phosdrin) (organophosphorus pesticides) NIOSH 5600 0.01 240 1000 4 GC-FPD ST 226-58 38
Mexacarbate ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
MIC (methyl isocyanate) OSHA 54 0.02 15 50 5 HPLC-FD ST NA SKC 39
Mica OSHA ID 142 20 mppcf varies varies varies GR , XRD CYC 225-105 84 F/CST 225-803 73
C/HLD 225-1 78
Mineral spirits (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 3 1 20 200 2.5 5 GC-FID ST 226-01 37
Mineral wool fiber OSHA CSI 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Mineral wool fiber (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Mineral wool fiber (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Mirex ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
MOCAP OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Mold spores (in air) 15-150 15 L/min 1-10 min varies STC 225-9820 77
Molybdenum (elements by ICP Aqua Regia ashing) NIOSH 7301 5 mg/m3 (sol) 5-67 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
10 mg/m3 (insoluble) C/HLD 225-1 78
Molybdenum (elements by ICP HNO3 digestion) NIOSH 7303 5 mg/m (soluble)
3
0.5-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
10 mg/m3 (insoluble)
Molybdenum (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Molybdenum (elements) NIOSH 7300 1455 5 mg/m (sol)
3
10 mg/m3 (insoluble)
Molybdenum insolubles (as Mo) OSHA ID 125G 15 mg/m 3
480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Molybdenum insolubles (as Mo), respirable fraction OSHA ID 121 1212 15 mg/m 3
960 2000 8 AA or AES, F/CST 225-3-01 71 C/HLD 225-1 78
(total dust) GR CYC 225-105 84
Molybdenum solubles (as Mo) OSHA ID 121 1211 5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Monensin OSHA CSI 960 2000 8 CLR F/CST 225-706 74 C/HLD 225-1 78
Monilia species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Monilia species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Monochloroacetic acid OSHA CSI 96 200 8 IC ST 226-47-01 38
Monochloroacetic acid (chloroacetic acid) NIOSH 2008 48 100 8 IC-ECN ST 226-47-01 38
Monocrotophos (Azodrin) OSHA PV2045 480 1000 8 GC-FPD ST 226-30-16 37
Monocrotophos (organophosphorus pesticides) NIOSH 5600 0.25 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Monoethanolamine (MEA) NIOSH 3509 3 6 240 1000 4 IC IMP 225-36-1 61 IT 225-22 61
Monoethanolamine (see 2-aminoethanol)
Monomethyl aniline NIOSH 3511 0.5 100 1000 100 min GC-FID IMP 225-36-2 61 IT 225-22 61
Monomethyl aniline OSHA CSI 2 100 1000 100 min GC-FID IMP 225-36-2 61 IT 225-22 61
Monomethyl hydrazine NIOSH 3510 0.04 (120 min) 15 1000 15 VAS IMP 225-36-2 61 IT 225-22 61
Monomethyl hydrazine OSHA 20 0.2 4.5 300 15 HPLC-UV ST 226-42-02 38
Monuron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Morpholine OSHA PV2123 20 10 100 100 min GC-FID ST 226-98 39
Mortierella species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Mortierella species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Mucor (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Mucor (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Mycobacteria NIOSH 0801 50-300 28300 varies GC-FID BI 225-9611 94
Mycobacterium tuberculosis (airborne) NIOSH 0900 1920 4000 8 PCR FLT 225-2705 75 SP 225-27 78
CST 225-3LF 79 C/HLD 225-1 78
Mycotoxins (fungi in air) NON 48 62.5-375 12500 + 5-30 varies BS 225-9595 93 VT 225-9598A◊ 93
Naphtha (coal tar) NIOSH 1550 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
Naphtha (coal tar) OSHA 48 100 3 200 15 min GC-FID ST 226-01 37
Naphthalene  ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Naphthalene  OSHA 35 1060 10 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-110 39
Naphthalene (polynuclear aromatic hydrocarbons)  NIOSH 5506 10 15 480 2000 4 HPLC-UV F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Naphthalene (polynuclear aromatic hydrocarbons)  NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
1,5-Naphthalene diisocyanate OSHA PV2046 60 1000 1 HPLC-UV, -FD CF/CST 225-9013 59 C/HLD 225-1 78
1,5-Naphthalene diisocyanate (isocyanates, NIOSH 5525 40 µg/m3 70 µg/m3 1-500 1-500 1000-2000 1000-2000 varies varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
total [MAP]) /10 min C SP 225-27 or IOM 225-76A 87
FLT 225-702‡ 74
Naphthas (see specific compounds) NIOSH 1550 varies varies varies 8 GC-FID ST 226-01 37
beta-Naphthol OSHA CSI 60 1000 1 HPLC-UV IMP 225-36-1 61 IT 225-22 61
alpha-Naphthylamine OSHA 93 1232 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
beta-Naphthylamine OSHA 93 1232 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
Naphthylamines (alpha- & beta-) NIOSH 5518 96 200 8 GC-FID FLT 225-16 74 CST 225-32 78
ST 226-51 38
Naphthylene diisocyanate (NDI) (isocyanates) NIOSH 5521 40 µg/m3 70 µg/m3 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 61 IT 225-22 61
(10 min) C ELCHM, UV
Naphthylthiourea (see ANTU)
Neurospora species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Neurospora species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number N
Nickel (elements by ICP Aqua Regia ashing) NIOSH 7301 0.015 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Nickel (elements by ICP HNO3 digestion) NIOSH 7303 0.012 mg/m3 1-50,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Nickel (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Nickel (elements) NIOSH 7300 1455 0.15 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Nickel (metal & insoluble compounds as Ni) OSHA ID 125G 1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Nickel (metal, soluble, & insoluble compounds as Ni) OSHA ID 121 1044 1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Nickel (soluble compounds as Ni) OSHA ID 121 1197 1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Nickel (soluble compounds as Ni) OSHA ID 125G 1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Nickel carbonyl NIOSH 6007 0.001 72 150 8 AA-GF ST NA SKC F/CST 225-3-01 71
Nickel carbonyl OSHA CSI 0.001 480 1000 8 AA-GF F/CST 225-709 74 C/HLD 225-1 78
IMP 225-36-2 61 IT 225-22 61
Nicotine NIOSH 2544 0.5 mg/m 3
360 1000 6 GC-NPD ST 226-30-04 37
Nicotine NIOSH 2551 0.5 mg/m3 480 1000 8 GC-NPD ST 226-93 39
Nicotine NON 19 120 1000 2 GC ST 226-93 39
Nicotine NON 49 90-720 1500 1- 8 GC-NSD ST 226-170 40
Nicotine & 3-ethenylpyridine ASTM D 5075 1427 varies 1500 varies GC-NPD ST 226-93 39
Nigrospora species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Nigrospora species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Niobium (elements by ICP HNO3 digestion) NIOSH 7303 0.012 mg/m3 0.1-3300 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Nitric acid  OSHA ID 165SG 2 96 7.5 200 500 8 15 IC ST 226-10-03 37
Nitric acid (acids, inorganic)  NIOSH 7903 2 4 48 3 200 200 4 15 IC ST 226-10-03 37
Nitric oxide OSHA ID 190 25 6 25 4 IC ST 226-40 38
Nitric oxide & nitrogen dioxide NIOSH 6014 1390 25 (NO) 1 (NO2) 1.5-6 25 1-4 VAS ST 226-40 38
5-Nitro-2-furaldehyde semicarbazone OSHA CSI 240 1000 24 min HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
p-Nitroaniline NIOSH 5033 3 mg/m3 240 1000 4 HPLC-UV F/CST 225-3-01 71 C/HLD 225-1 78
p-Nitroaniline OSHA CSI 1 mg/m3 90 1.5 1 HPLC-UV F/CST 225-3-01 71 C/HLD 225-1 78
Nitrobenzene  NIOSH 2005 1 48 100 8 GC-FID ST 226-10 37
Nitrobenzene  NIOSH 2017 1 24 200 2 GC-FID CF/CST 225-9004 59 ST 226-15 37
4-Nitrobiphenyl OSHA CSI 240 500 8 GC-FID ST 226-30-16 37
p-Nitrochlorobenzene OSHA CSI 1 mg/m3 150 1000 2.5 GC-FID ST 226-10 37
p-Nitrochlorobenzene (nitrobenzenes) NIOSH 2005 0.1 96 200 8 GC-FID ST 226-10 37
Nitrochloroform NON 51 0.1 144 100 24 GC-ECD, ST 226-175 40
GC-MSD
Nitrochloromethane NON 51 0.1 144 100 24 GC-ECD, ST 226-175 40
GC-MSD
4-Nitrodiphenyl OSHA PV2082 240 500 8 GC-FID ST 226-30-16 37
Nitroethane NIOSH 2526 100 2.4 20 2 GC-FID ST 226-3002A 37
Nitrofurazone OSHA PV2069 240 1000 4 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Nitrogen dioxide  NIOSH 6014 1 (NO2) 1.5-6 25-200 varies VAS ST 226-40-02 38
Nitrogen dioxide  OSHA ID 182 1406 5 (C) 3 200 15 IC ST 226-40 or ST 226-40-02 38
Nitrogen dioxide & nitric oxide NIOSH 6014 1390 25 (NO) 1 (NO2) 1.5-6 25 1-4 VAS ST 226-40 38
Nitrogen dioxide & nitric oxide NON 11 0.75 50 15 CLR ST 226-40 38
Nitrogen dioxide & nitric oxide OSHA ID 182 1389 25 (NO) 5 (NO2) 6 3 25 200 4 15 IC ST 226-40 38
Nitroglycerin NIOSH 2507 0.1 mg/m3 3 200 15 GC-ECD ST 226-35-03 37
Nitroglycerin OSHA 43 0.1 mg/m3 15 1000 15 HPLC ST 226-35-03 37
Nitromethane NIOSH 2527 2.4 20 2 GC-NSD ST 226-111A 39
Nitromethane OSHA CSI 100 3 50 1 GC-NPD ST 226-111A 39
p-Nitrophenol OSHA CSI 100 1000 100 min HPLC-UV IMP 225-36-1 61 IT 225-22 61
1-Nitropropane OSHA 46 25 3 100 30 min GC-FID ST 226-93 39
2-Nitropropane NIOSH 2528 LFC 2 20 1.5 GC-FID ST 226-110 39
2-Nitropropane OSHA 46 25 3 100 30 min GC-FID ST 226-93 39
1-Nitropyrene OSHA CSI 960 2000 8 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
1-Nitropyrene in diesel particulates NIOSH 2560 480-960 1000-2000 varies GC-NCD FLT 225-7 74 SP 225-27 78
SPC 225-23 78
N-Nitrosodiethanolamine OSHA 31 480 2000 4 GC-TEA F/CST 225-706 74 C/HLD 225-1 78
N-Nitrosodiphenylamine OSHA 23 240 1000 4 HPLC-UV IMP 225-36-2 61 IT 225-22 61
Nitrotoluene (m-isomer) OSHA CSI 5 30 200 2.5 GC-FID ST 226-10 37
m-Nitrotoluene (nitroaromatic compounds) NIOSH 2005 2 ppm 96 200 8 GC-FID ST 226-10 37
o-Nitrotoluene (nitroaromatic compounds) NIOSH 2005 2 ppm 96 200 8 GC-FID ST 226-10 37
p-Nitrotoluene (nitroaromatic compounds) NIOSH 2005 2 ppm 96 200 8 GC-FID ST 226-10 37
Nitrotoluene (nitrobenzenes) NIOSH 2005 2 ppm 96 200 8 GC-FID ST 226-10 37
Nitrous oxide  NIOSH 6600 1028 25 3 varies varies P IR SB 231-05 53
Non-sporulating fungi OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Non-sporulating fungi OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
trans-Nonachlor ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Nonane  OSHA CSI 3 50 1 GC-FID ST 226-01 37
n-Nonane (hydrocarbons, BP 36 to 216 C)  NIOSH 1500 200 4 10-200 varies GC-FID ST 226-01 37
Nonpolar organic compounds NON 38 varies varies varies GC PUF 226-129 43
Nonyl alcohol  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Nonylphenol OSHA CSI 24 100 4 HPLC-UV ST 226-95 39

Sampling Guide
N Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Norethindrone OSHA PV2070 480 2000 4 HPLC-UV F/CST 225-802 73 C/HLD 225-1 78
Nuisance dust (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Nuisance dust (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Nuisance dust (see dust, respirable nuisance)
Octachloronaphthalene OSHA CSI 0.1 mg/m3 30 15 1000 1000 0.5 15 GC-ECD F/CST 225-3-01 71 C/HLD 225-1 78
Octadecanol OSHA CSI 10 100 100 min GC-FID ST 226-01 37
Octane  OSHA 07 1141 500 5 3 20 200 4 15 GC-FID ST 226-01 37
n-Octane  OSHA PV2138 500 4 50 80 min GC-FID ST 226-01 37
n-Octane (hydrocarbons, BP 36 to 216 C)  NIOSH 1500 75 385 4 4 0-200 0-200 varies varies GC-FID ST 226-01 37
1-Octanethiol NIOSH 2510 0.5 (15 min) 3 200 15 GC-FPDS ST 226-35-03 37
Octanol (Octyl alcohol)  TD, GC PS 590-259 and SV 590-260 67
Octyl alcohol (Octanol)  TD, GC PS 590-259 and SV 590-260 67
di-n-Octyl phthalate (DNOP) OSHA 104 240 1000 4 GC-FID ST 226-56 38
Oil mist (mineral) NIOSH 5026 1526 5 mg/m3 10 mg/m3 480 30 1000 2000 8 15 IR F/CST 225-3-01 or F/CST 225-802 73
C/HLD 225-1 78
Oil mist (mineral) OSHA ID 128 5 mg/m 3
960 2000 8 GR, FLUOR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Oil mist (mineral) OSHA ID 178SG 5 mg/m 3
960 2000 8 GR,IR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Oil mist (total aerosol) NON 46 5 mg/m 3
varies 2000 varies GR IOM 225-70A 87 FLT 225-8-04 73
Oil mist (vegetable) (see dust, total & respirable nuisance)
Oil of vitriol (acids, inorganic) NIOSH 7903 1 mg/m3 48 200 4 IC ST 226-10-03 37
Organic vapors (charcoal tube method) ASTM D 3686 varies varies varies varies varies varies GC ST 226-01 37
Organic vapors (diffusive sampler method) ASTM D 4597 varies varies varies varies varies varies GC PS 575-001 or PS 575-002 or
PS 575-003 63
Organonitrogen pesticides (see specific compounds) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Organophosphorus pesticides (see specific compounds) NIOSH 5600 varies varies varies 8 GC-FPD ST 226-58 38
Organotin compounds as Sn (see specific compounds) NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC, ST 226-30 37 F/CST 225-709 74
AA-GF C/HLD 225-1 78
Organotincompounds as Sn (see specific compounds) NIOSH 5526 0.1 mg/m3 60 60 250 1000 4 60 GC-FPD ST 226-30-16 37
Orthene (acephate) OSHA CSI 240 1000 4 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Oryzalin OSHA CSI 120 1000 2 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
IMP 225-36-1 61 IT 225-22 61
Osmium tetroxide (as Os) OSHA CSI 0.002 480 15 1000 1000 8 15 ICP F/CST 225-3-01 71 IMP 225-36-1 61
IT 225-22 61
Oxalic acid OSHA PV2115 1 mg/m3 100 1000 100 min IC F/CST 225-3-01 71 C/HLD 225-1 78
Oxamyl (organonitrogen pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Oxamyl (Vydate) OSHA CSI 60 1000 1 HPLC ST 226-30-16 37
Oxychlordane ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Oxydemeton methyl OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Oxygen NIOSH 6601 19.5-25% 1000 DRI DRI 805-43848
Oxygen OSHA CSI DET TB or DT 800-28081 or DRI 805-10499 or
DRI DT 810-31B
Ozone  OSHA CSI 0.1 DET TB DT 800-33181 or DT 800-21001 or
DT 810-18L
Ozone  OSHA ID-214 0.1 90 500 3 IC CF/CST 225-9014 59 C/HLD 225-1 78
ST Special order∑
Paecilomyces species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Paecilomyces species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
PAHs ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Palladium (elements by ICP HNO3 digestion) NIOSH 7303 0.1-3.300 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Palladium (see dust, total nuisance) OSHA CSI
Pancreatin OSHA CSI 480 2000 4 IRA F/CST 225-1713 75 C/HLD 225-1 78
Papain OSHA CSI 60,000 1000 L/min 1 GC-FID FLT 225-7-07 74
Paper fiber (cellulose) (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Paper fiber (cellulose) (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
PAPI OSHA CSI 15 1000 15 min HPLC-UV FLT 225-7‡ 74 CST 225-3LF 79
C/HLD 225-1 78
Paraffin wax fume OSHA PV2047 100 1000 100 min GC-FID F/CST 225-706 74 C/HLD 225-1 78
Paraquat NIOSH 5003 0.1 mg/m3 480 1000 8 HPLC-UV FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Paraquat (respirable dust) OSHA CSI 0.5 mg/m3 960 4000 4 HPLC-UV FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Parathion OSHA 62 1398 0.1 mg/m3 480 1000 8 GC-FPD ST 226-30-16 37
Parathion (organophosphorus pesticides) NIOSH 5600 0.05 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Particulates not otherwise regulated (total dust) OSHA CSI 15 mg/m3 720 1500 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Particulates not otherwise regulated, respirable NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Particulates not otherwise regulated, respirable fraction OSHA CSI 5 mg/m3 varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Particulates, inorganic (bioaerosols) 15-150 15 L/min 1-10 min varies STC 225-9820 79

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number P
Particulates, respirable NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Particulates, total (see specific compounds) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
PCBs (42% CI) (see polychlorobiphenyls) NIOSH 5503
PCBs (54% CI) (see polychlorobiphenyls) NIOSH 5503
PCBs (polychlorinated biphenyls) (see Environ- EPA TO-4A
mental Sampling Guide)
Penicillium species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Penicillium species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Pentaborane OSHA CSI 0.005 480 15 1000 1000 8 15 ICP IT 225-22 61 IMP 225-36-2 61
Pentac (bis [pentachloro-2,4-cyclopentadien-1-yl]) OSHA CSI 120 1000 2 HPLC-UV FLT 225-9 70 CST 225-3LF 79
IMP 225-36-1 61 IT 225-22 61
C/HLD 225-1 78
Pentachlorobenzene ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Pentachlorobenzene (polychlorobenzenes) NIOSH 5517 12 25 8 GC-ECD FLT 225-17-03 75 CST 225-33 78
ST 226-30-04 37
Pentachloroethane NIOSH 2517 10 20 8 GC-ECD ST 226-59-04 38
Pentachloroethane OSHA CSI 10 20 8 GC-ECD ST 226-59-04 38
Pentachloronaphthalene OSHA CSI 0.5 mg/m3 90 1000 1.5 GC-ECD ST 226-30-16 37
Pentachlorophenol ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Pentachlorophenol NIOSH 5512 0.5 mg/m3 480 1000 8 HPLC-UV CST 225-3LF 79 SCN 225-26 78
IMP 225-36-2 61 IT 225-22 61
FLT 225-5 70
Pentachlorophenol OSHA 39 0.5 mg/m3 48 200 4 HPLC-UV ST 226-97 39
Pentaerythritol (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Pentaerythritol (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Pentaerythritol (respirable dust) OSHA CSI 5 mg/m3 varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Pentaerythritol (total dust) OSHA CSI 15 mg/m3 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Pentamethyldiethylenetriamine OSHA CSI 480 1000 8 GC-NPD IMP 225-36-1 61 IT 225-22 61
Pentamidine isethionate NIOSH 5032 960 2000 8 HPLC-FD CST 225-4 79 FLT 225-8-01 73
C/HLD 225-1 78
Pentane  OSHA 07 1140 1000 2 0.75 20 50 1.6 15 GC-FID ST 226-01 37
n-Pentane (hydrocarbons, BP 36 to 216 C)  NIOSH 1500 120 610 4 4 10-200 10-200 varies varies GC-FID ST 226-01 37
2-Pentanone (methyl propyl ketone)  OSHA 07 1139 200 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
2-Pentanone (methyl propyl ketone) (ketones I)  NIOSH 1300 150 10 20(50) 8(3.3) GC-FID ST 226-01 37
2-Pentanone (methyl propyl ketone) (ketones I)  NIOSH 2555 1-10 10-200 varies GC-FID ST 226-121 39
1-Pentene  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Perchloric acid OSHA ID 115SG 120 500 4 CLR IMP 225-36-2 61 IT 225-22 61
Perchloroethylene (tetrachloroethylene)  OSHA 1001 100 200 (C) 12 0.75 50 50 4 5 GC-FID ST 226-01 37
Perchloroethylene (tetrachloroethylene) (hydro-  NIOSH 1003 LFC 3 10-200 varies GC-FID ST 226-01 37
Perchloroethylene (tetrachloroethylene) (portable GC) NIOSH 3704 LFC 1 varies varies P GC SB 232-01 or SB 233-01 52
Perchloryl fluoride OSHA CSI 3 240 15 1000 1000 4 15 ISE IMP 225-36-2 61 IT 225-22 61
Perlite (< 1% Quartz) (see dust, total & respirable
nuisance)
cis-Permethrin ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
trans-Permethrin ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Pesticides (see Environmental Sampling Guide) EPA IP-8
Pesticides (see Environmental Sampling Guide) EPA TO-10A
Pesticides, carbamate ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Pesticides, organochlorine ASTM D 4861 1253 240-7200 1000-5000 4-24 varies PUF 226-92 or PUF 226-124 42
Pesticides, organochlorine (see Environmental EPA TO-4A
Sampling Guide)
Pesticides, organonitrogen (see specific compounds) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Pesticides, organophosphorus ASTM D 4861 1253 240-7200 1000-5000 4-24 varies PUF 226-92 or PUF 226-124 42
Pesticides, pyrethrin ASTM D 4861 240- 7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Pesticides, triazine ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
or GC-ECD
Petroleum distillate (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 3.6 1.5 20 100 3 15 GC-FID ST 226-01 37
Petroleum distillate fractions (PDF) OSHA 48 500 3 20 2.5 GC-FID ST 226-01 37
Petroleum ether (benzin) (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 3 1.5 20(50) 100 2.5(1) 15 GC-FID ST 226-01 37
Petroleum naphtha (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 3 1.5 20(50) 100 2.5(1) 15 GC-FID ST 226-01 37
Peziza species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Peziza species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Phenanthrene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Phenanthrene OSHA 58 960 2000 8 GR, HPLC- FLT 225-7 74 CST 225-2LF 79
FD, -UV C/HLD 225-1 78
Phenanthrene (polynuclear aromatic hydrocarbons) NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Phenanthrene (polynuclear aromatic hydrocarbons) NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78

Sampling Guide
P Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Phenol  OSHA 32 1019 5 24 100 4 HPLC-UV ST 226-95 39

Phenol (cresols)  NIOSH 2546 5 15.6(15min) 24 3 100 200 4 15 GC-FID ST 226-95 39
Phenol (see Environmental Sampling Guide) EPA TO-8
Phenolics (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 40
Phenothiazine OSHA PV2048 100 1000 1 GC-NPD F/CST 225-706 74 C/HLD 225-1 78
2-Phenoxyethanol OSHA CSI 10 200 50 min GC-FID ST 226-01 37
2-Phenoxyethyl acrylate OSHA CSI 24 100 4 GC-FID ST 226-22 37
1-Pheny-1-cyclohexene OSHA CSI 10 200 50 min GC-FID ST 226-01 37
Phenyl ether  NIOSH 1617 1 48 100 8 GC-FID ST 226-01 37
Phenyl ether  OSHA 07 1138 1 10 20(50) 8(3.3) GC-FID ST 226-01 37
Phenyl ether  OSHA PV2022 1 20 200 100 min GC-FID ST 226-95 39
Phenyl ether-biphenyl mix NIOSH 2013 1 24 50 8 GC-FID ST 226-10 37
Phenyl ether-biphenyl mix OSHA CSI 1 10 20(50) 8(3.3) GC-FID ST 226-95 39
Phenyl glycidyl ether  NIOSH 1619 1 (15 min) 80 1000 80 GC-FID ST 226-01 37
Phenyl glycidyl ether  OSHA 07 1137 10 48 100 8 GC-FID ST 226-01 37
Phenyl hydrazine NIOSH 3518 0.14 (120 min) 120 1000 120 VAS IMP 225-36-2 61 IT 225-22 61
Phenyl hydrazine OSHA CSI 5 100 15 1000 1000 100 min 15 CLR IMP 225-36-2 61 IT 225-22 61
Phenyl mercaptan OSHA PV2075 20 200 100 min GC-FID CF/CST 225-9007 59 C/HLD 225-1 78
N-Phenyl-1-naphthylamine OSHA 96 240 2000 4 HPLC-FD FLT 225-703‡ 74 CST 225-309 79
C/HLD 225-1 78
N-Phenyl-2-naphthylamine OSHA 96 240 1000 4 HPLC-FD FLT 225-703‡ 74 CST 225-309 79
C/HLD 225-1 78
N-Phenyl-2-naphthylamine OSHA CSI W W 225-2401A 112
4-Phenylcyclohexene OSHA CSI 10 200 50 min GC-FID ST 226-01 37
m-Phenylenediamine OSHA 87 1231 100 1000 100 min HPLC-UV CF/CST 225-9004 59 C/HLD 225-1 78
o-Phenylenediamine OSHA 87 1231 100 1000 100 min HPLC-UV CF/CST 225-9004 59 C/HLD 225-1 78
p-Phenylenediamine OSHA 87 1231 0.1 mg/m3 100 1000 100 min HPLC-UV CF/CST 225-9004 59 C/HLD 225-1 78
Phenyloxirane (see styrene oxide) OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-35 37
o-Phenylphenol ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
o-Phenylphenol OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-35 37
Phoma species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Phoma species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Phorate ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 42
Phorate (organophosphorus pesticides) NIOSH 5600 0.05 mg/m3 0.2 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Phorate (Thimet) OSHA CSI 480 15 1000 1000 8 15 GC-FPD ST 226-30-16 37
Phosdrin (mevinphos) OSHA CSI 0.1 mg/m3 480 15 1000 1000 8 15 GC-FPD ST 226-30-16 37
Phosdrin (mevinphos) (organophosphorus pesticides) NIOSH 5600 0.01 0.03 120 15 1000 1000 2 15 GC-FPD ST 226-58 38
Phosgene OSHA 61 0.1 240 1000 4 GC-NPD ST 226-117 39
Phosgene (see Environmental Sampling Guide) EPA TO-6
Phosgene & chloroformates NON 40 24 50 8 GC-FPD ST 226-153 40
Phosmet (Imidan) OSHA CSI 120 1000 2 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Phosphine NIOSH 6002 0.3 1 12 3 100 200 8 15 UV-VAS ST 226-165A†† 40
Phosphine OSHA 1003 1698 0.3 240 30 1000 2000 4 15 ICP-AES CF/CST 225-9018†† 59 C/HLD 225-1 78
Phosphoric acid OSHA ID 111 1466 1 mg/m3 960 30 2000 2000 8 15 IC F/CST 225-3-01 71 C/HLD 225-1 78
Phosphoric acid OSHA ID 165SG 1 mg/m3 960 30 2000 2000 8 15 IC ST 226-10-03 37
o-Phosphoric acid NIOSH 7903 1 mg/m3 3 mg/m3 48 3 200 200 4 15 IC ST 226-10-03 37
m-Phosphoric acid (acids, inorganic) NIOSH 7903 1 mg/m3 3 mg/m3 48 3 200 200 4 15 IC ST 226-10-03 37
Phosphorous (elements by ICP HNO3 digestion) NIOSH 7303 0.1 mg/m3 250-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Phosphorus NIOSH 7905 0.1 mg/m3 12 200 1 GC-FPD ST 226-35-03 37
Phosphorus (elements by ICP Aqua Regia ashing) NIOSH 7301 0.1 mg/m3 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Phosphorus (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Phosphorus (elements) NIOSH 7300 1455 0.1 mg/m 3
Phosphorus (yellow) OSHA CSI 0.1 mg/m3 96 200 8 GC-FPD ST 226-35-03 37
Phosphorus oxychloride OSHA CSI 240 1000 4 IC IMP 225-36-2 61 IT 225-22 61
Phosphorus pentachloride OSHA CSI 1 mg/m3 48 200 4 CLR F/CST 225-803 73 IMP 225-36-2 61
IT 225-22 61 SCN 225-26 78
Phosphorus pentasulfide OSHA ID 128SG 1 mg/m 3
960 30 2000 2000 8 15 IC F/CST 225-802 73 C/HLD 225-1 78
Phosphorus pentoxide OSHA ID 111 480 1000 8 IC F/CST 225-3-01 71 C/HLD 225-1 78
Phosphorus trichloride NIOSH 6402 0.2 0.5 24 200 2 VAS IMP 225-36-2 61 IT 225-22 61
Phosphorus trichloride OSHA CSI 0.5 96 3 200 200 8 15 CLR IMP 225-36-2 61 IT 225-22 61
Phosvel OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Phthalic acid OSHA CSI 10 200 50 min HPLC ST 226-01 37
Phthalic anhydride OSHA 90 2 75 1000 1.25 HPLC-UV FLT 225-7‡ 74 CST 225-3LF 79
C/HLD 225-1 78
m-Phthalodinitrile OSHA CSI 20 200 100 min GC-NPD ST 226-01 37
Picloram (tordon) ( total dust) OSHA PV2049 15 mg/m3 60 1000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Picloram (tordon) (respirable dust) OSHA CSI 5 mg/m 3
CYC 225-105 84 CST 225-3LF 79
Picric acid OSHA CSI 0.1 mg/m 3
180 1500 2 HPLC-UV F/CST 225-3-01 71 C/HLD 225-1 78
Pindone OSHA CSI 0.1 mg/m3 180 1000 3 HPLC-UV FLT 225-17-01 75 CST 225-2LF 79
ST 226-35-03 37 C/HLD 225-1 78

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number P
alpha-Pinene  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
beta-Pinene  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
alpha-Pinene (terpenes) NIOSH 1552 24 50 8 GC-FID ST 226-01 37
beta-Pinene (terpenes)  NIOSH 1552 24 50 8 GC-FID ST 226-01 37
Piperazine dihydrochloride OSHA CSI 96 200 8 GC-NPD F/CST 225-709 74 C/HLD 225-1 78
Piperidine OSHA CSI 6 200 30 min GC-FID ST 226-01 37
Piperonyl butoxide OSHA PV2110 30 1000 30 min HPLC-UV ST 226-30-16 37
Pipron OSHA CSI 90 1000 1.5 GC-ECD F/CST 225-706 74 C/HLD 225-1 78
IMP 225-36-1 61 IT 225-22 61
Pirimiphos methyl OSHA PV2071 120 1000 2 GC-ECD ST 226-30-16 37
Pithomyces species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Pithomyces species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Plaster of Paris (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Plaster of Paris (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Plaster of Paris (see dust, respirable nuisance) OSHA CSI
Platinum OSHA ID 130SG 90 1000 1.5 AA F/CST 225-3-01 71 C/HLD 225-1 78
Platinum (elements by ICP HNO3 digestion) NIOSH 7303 200-25,000,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Platinum (as Pt), metal OSHA CSI 960 2000 8 AA-GF F/CST 225-3-01 71 C/HLD 225-1 78
Platinum (as Pt), metal OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Platinum (as Pt), soluble salts OSHA ID 121 2 µg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
PM2.5 (see Environmental Sampling Guide) EPA IP-10A
PNAs (see specific compounds) NIOSH 5506 1464 480 2000 4 HPLC-UV F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
PNAs (see specific compounds) NIOSH 5515 1464 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
PNAs selected OSHA 58 960 2000 8 GR, HPLC- FLT 225-7 74 CST 225-2LF 79
FD, -UV C/HLD 225-1 78
Pollen (in air) 15-150 15 L/min 1-10 min varies STC 225-9820 79
Pollen (in air) NON 48 62.5-375 12500 + 5-30 varies BS 225-9595 93 VT 225-9598A◊ 93
Polychlorinated biphenyls ASTM D 4861 1252 240-7200 1000-5000 4-24 varies PUF 226-92 or PUF 226-124 42
Polychlorinated biphenyls NIOSH 5503 0.001 mg/m3 48 100(200) 8(4) GC-ECD FLT 225-16 74 CST 225-32 78
(10 hr) ST 226-39 38
Polychlorinated biphenyls OSHA CSI 60 1000 1 GC-ECD ST 226-30-16 37
Polychlorobenzenes (see specific compounds) NIOSH 5517 varies varies varies 8 GC-ECD FLT 225-17-03 75 ST 226-30-04 37
CST 225-33 78 C/HLD 225-1 78
Polychlorobiphenyls (42% Cl) NIOSH 5503 0.001 mg/m3 48 100(200) 8(4) GC-ECD FLT 225-16 74 CST 225-32 78
(10 hr) ST 226-39 38
Polychlorobiphenyls (54% Cl) NIOSH 5503 0.001 mg/m 3
48 100(200) 8(4) GC-ECD FLT 225-16 74 CST 225-32 78
(10 hr) ST 226-39 38
Polycyclic aromatic compounds (PACs), total NIOSH 5800 960 30 2000 2000 8 15 FLUOR F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Polyfunctional aziridine OSHA CSI 100 1000 100 min GC-FID ST 226-57 38
Polynuclear aromatic hydrocarbons ASTM D 6209 varies 350 m3 (max) 225 L/min 4-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Polynuclear aromatic hydrocarbons (see specific NIOSH 5506 1464 varies 480 2000 4 HPLC-UV F/CST 225-1713 75 ST 226-30-04 37
compounds) C/HLD 225-1 78
Polynuclear aromatic hydrocarbons (see specific NIOSH 5515 1464 varies 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
Portland cement (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Portland cement (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Portland cement (respirable dust) OSHA ID 142 5 mg/m3 varies varies varies GR, XRD FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Portland cement (total dust) OSHA ID 142 15 mg/m3 960 2000 8 GR, XRD FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Portland cement (total dust) OSHA ID 207 15 mg/m 3
240 1000 4 XRD, XRF FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Potassium (elements by ICP Aqua Regia ashing) NIOSH 7301 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 73
C/HLD 225-1 78
Potassium (elements) NIOSH 7300 1455 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Potassium & compounds OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Potassium chromate (CR(VI)) OSHA ID 215 (V2) 0.005 mg/m3 960 2000 8 IC-UV F/CST 225-802‡ or FLT 225-1827 74
CST 225-2LF 79 C/HLD 225-1 78
Potassium cyanide (cyanides) NIOSH 7904 5 mg/m3 (10 min) 15 1000 15 ISE FLT 225-2705∆ 75 CST 225-2LF 79
IMP 225-36-2 61 IT 225-22 61
C/HLD 225-1 78
Potassium hydroxide (alkaline dust) NIOSH 7401 960 2000 8 TITRA FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Potassium hydroxide (as K) OSHA ID 121 1199 10 2000 5 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Pramitol OSHA CSI 100 1000 100 min HPLC-UV ST 226-30-16 37
Progesterone OSHA PV2001 60 1000 1 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Propane OSHA CSI 1000 5 100 50 min GC-FID ST 226-121 39
1,2,3-Propanetriol trinitrate OSHA 43 15 1000 15 min HPLC-UV ST 226-35-03 37
Propargyl alcohol OSHA 97 6 50 2 GC-ECD ST 226-178 37
Propazine ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 42

Sampling Guide
P Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Propham (organonitrogen pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
Propionaldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
Propionaldehyde (aldehydes, screening) NIOSH 2539 5 20 4 GC-FID & GC-MS ST 226-118 39
Propionic acid  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-15 37
Propionitrile  TD, GC PS 590-259 and SV 590-262 67
Propoxur (Baygon) ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Propoxur (Baygon) OSHA PV2007 60 1000 1 HPLC-UV ST 226-30-16 37
Propoxur (organonitrogen pesticides) NIOSH 5601 0.5 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
2-Propoxyethanol OSHA CSI 6 200 30 min GC-FID ST 226-01 37
n-Propyl acetate  OSHA 07 1136 200 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
n-Propyl acetate (esters I)  NIOSH 1450 200 250 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 37
Propyl alcohol  OSHA 07 200 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
n-Propyl alcohol (alcohols combined)  NIOSH 1405 200 250 (skin) 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 37
n-Propyl alcohol (alcohols II)  NIOSH 1401 200 250 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
n-Propyl benzene  TD, GC PS 590-259 and SV 590-260 or
SV 590-262 67
Propyl bromide  OSHA CSI 12 100 2 GC-FID ST 226-01 37
n-Propyl nitrate OSHA 07 25 40 48 100 8 GC-FID ST 226-81A 38
Propyl paraben OSHA CSI HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Propylene dichloride (1,2-dichloro propane)  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Propylene dichloride (1,2-dichloro propane)  NIOSH 1013 LFC 3 20 2.5 GC-ECN ST 226-81A 38
Propylene dichloride (1,2-dichloro propane)  OSHA 07 75 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Propylene glycol NIOSH 5523 1403 60 1000 1 GC-FID ST 226-57 38
1,2-Propylene glycol dinitrate OSHA CSI 15 1000 15 min HPLC ST 226-35-03 37
Propylene glycol monomethyl ether  OSHA CSI 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Propylene glycol monomethyl ether (glycol ethers)  NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 38
Propylene glycol monomethyl ether acetate  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Propylene glycol monomethyl ether acetate  NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 38
(glycol ethers)
Propylene oxide (1, 2-epoxypropane)  NIOSH 1612 LFC 5 20 4.2 GC-FID ST 226-01 37
Propylene oxide (1, 2-epoxypropane)  OSHA 88 1325 100 5 5 100 1000 50 min 5 GC-FID ST 226-81A 38
Propyleneimine OSHA CSI 2 48 200 4 HPLC-UV IMP 225-36-2 61 IT 225-22 61
Pyrene ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 43 FLT 225-1821 74
Pyrene OSHA 58 960 2000 8 GR, HPLC- FLT 225-7 74 CST 225-2LF 79
FD, -UV C/HLD 225-1 78
Pyrene (polynuclear aromatic hydrocarbons) NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Pyrene (polynuclear aromatic hydrocarbons) NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 75 ST 226-30-04 37
C/HLD 225-1 78
Pyrethrin pesticides (see specific compounds) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Pyrethrum ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Pyrethrum NIOSH 5008 5 mg/m3 100 1000 2 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
SP 225-27 78
Pyrethrum OSHA 70 1400 5 mg/m 3
60 1000 1 GC-ECD ST 226-30-16 37
Pyridine  NIOSH 1613 5 48 100 8 GC-FID ST 226-01 37
Pyridine  OSHA 07 1180 5 48 100 8 GC-FID ST 226-01 37
1-(2-Pyridyl)piperazine OSHA CSI W W 225-2401A 112
Pyrimethamine OSHA CSI 10 1000 100 min HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Quartz (respirable) in coal dust, (silica in coal NIOSH 7603 0.05 mg/m3 300-1000 2500 varies IR FLT 225-8-01 73 C/HLD 225-1 78
mine dust) CYC 225-01-02 85 CST 225-3LF 79
Quartz (silica, crystalline [respirable]) by XRD NIOSH 7500 1370 0.05 mg/m3 400-1000 2500 varies XRD F/CST 225-803 73 CYC 225-01-02 85
C/HLD 225-1 78
Quartz (silica, crystalline by IR) NIOSH 7602 0.05 mg/m3 400-800 2500 varies IR F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Quartz (silica, crystalline by VAS) NIOSH 7601 1041 0.05 mg/m3 400-800 2500 varies VAS F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Quinone OSHA CSI 0.1 24 100 4 HPLC-UV ST 226-30-04 37
Rabon OSHA CSI 480 1000 8 GC-ECD ST 226-30-16 37
Ramrod (propachlor) OSHA CSI 120 1000 2 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Resmethrin ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Resmethrin OSHA PV2052 60 1000 1 HPLC-UV ST 226-30-16 37
Resorcinol NIOSH 5701 10 120 500 4 GC-FID ST 226-57 38
Rhizopus species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Rhizopus species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Rhodamine B OSHA PV2072 240 1000 4 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Rhodium metal fume & dust (as Rh) OSHA CSI 0.1 mg/m3 960 2000 8 AA-GF F/CST 225-3-01 71 C/HLD 225-1 78
Rhodium soluble salts (as Rh) OSHA CSI 1 µg/m3 960 2000 8 AA-GF F/CST 225-3-01 71 C/HLD 225-1 78
Rhodotorula species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Rhodotorula species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Ribavirin NIOSH 5027 480 1000 8 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Ronnel ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 42
Ronnel OSHA PV2054 15 mg/m3 60 1000 1 GC-FPD ST 226-30-16 37
Ronnel (organophosphorus pesticides) NIOSH 5600 10 mg/m3 60 1000 1 GC-FPD ST 226-58 38
Rosaniline OSHA CSI bulk HPLC

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number R
Rotenone NIOSH 5007 5 mg/m3 120 1000 2 HPLC-UV FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Rotenone (commercial) OSHA CSI 5 mg/m3 240 2000 2 HPLC-UV FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Rouge (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Rouge (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Rouge (respirable dust) OSHA CSI 5 mg/m 3
CYC 225-105 84 CST 225-3LF 79
Rouge (total dust) OSHA CSI 15 mg/m 3
960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Roundup OSHA CSI 90 1000 1.5 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Rozol OSHA CSI 120 1000 2 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Rubber solvent (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 10 1.5 20(50) 100 8(3.3) 15 GC-FID ST 226-01 37
Rubidium OSHA CSI 480 1000 8 AA-GF F/CST 225-709 74 C/HLD 225-1 78
IMP 225-36-2 61 IT 225-22 61
Safrotin OSHA PV2050 60 1000 1 GC-ECD F/CST 225-709 74 C/HLD 225-1 78
Saphrophyte (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Saphrophyte (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Sarin OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
SARS virus NIOSH PCR F/CST 225-1723 75 PUMP 110-100 20
Scopolamine methyl nitrate OSHA PV2144 120 1000 2 HPLC-UV F/CST 225-709 or F/CST 225-706 74
C/HLD 225-1 78
Scopulariopsis species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Scopulariopsis species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Selenium OSHA ID 121 0.2 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Selenium (elements by ICP Aqua Regia ashing) NIOSH 7301 0.2 mg/m3 13-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Selenium (elements by ICP HNO3 digestion) NIOSH 7303 0.2 mg/m3 8-250,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Selenium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Selenium (elements) NIOSH 7300 1455 0.2 mg/m3 13-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Selenium compounds (as Se) OSHA CSI 0.2 mg/m3 960 2000 8 AA-GF F/CST 225-3-01 71 C/HLD 225-1 78
Sevin (see carbaryl)
Sevoflurane  OSHA CSI 3 50 1 GC-FID ST 226-81A 37
Silica (quartz, non-respirable) (see dust, total nuisance) OSHA CSI
Silica (quartz) in coal dust (quartz in coal mine dust by IR) NIOSH 7603 0.05 mg/m3 300-1000 2500 varies IR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Silica, amorphous OSHA CSI 20 mppcf 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Silica, amorphous (respirable) NIOSH 7501 6 mg/m 3
50-400 2500 varies XRD F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Silica, crystalline (respirable) by XRD NIOSH 7500 1370 0.05 mg/m 3
C/HLD 225-1 78
Silica, crystalline by IR NIOSH 7602 0.05 mg/m 3
400-800 2500 varies IR F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Silica, crystalline by VAS NIOSH 7601 1041 0.05 mg/m 3
400-800 2500 varies VAS F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Silica, crystalline cristobalite (respirable dust) OSHA ID 142 [(10 mg/m )/ 3
varies varies varies XRD, GR FLT 225-8-01 73 C/HLD 225-1 78
(%SiO2+2)]/2 CYC 225-105 84 CST 225-3LF 79
Silica, crystalline quartz (respirable dust) OSHA ID 142 1003 (10 mg/m )/ 3
varies varies varies XRD, GR FLT 225-8-01 73 C/HLD 225-1 78
(%SiO2+2) CYC 225-105 84 CST 225-3LF 79
Silica, crystalline tridymite (respirable dust) OSHA ID 142 [(10 mg/m )/ 3
varies varies varies XRD, GR FLT 225-8-01 73 CST 225-3LF 79
(%SiO2+2)]/2 CYC 225-105 84 C/HLD 225-1 78
Silica, crystalline tripoli (respirable dust) OSHA ID 142 (10 mg/m3)/ varies varies varies XRD FLT 225-8-01 78 C/HLD 225-1 73
(%SiO2+2) CYC 225-105 84 CST 225-3LF 79
Silica, fused (respirable dust) OSHA ID 142 varies varies varies GR FLT 225-8-01 78 C/HLD 225-1 73
CYC 225-105 84 CST 225-3LF 79
Silicon OSHA CSI 15 mg/m3 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Silicon (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Silicon (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Silicon (respirable dust) OSHA CSI 5 mg/m3 varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Silicon carbide (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Silicon carbide (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Silicon carbide (respirable dust) OSHA CSI 5 mg/m3 varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Silicon carbide (total dust) OSHA CSI 15 mg/m 3
960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Silicon tetrahydride (silane) OSHA CSI 480 1000 8 AA-GF IMP 225-36-2 61 IT 225-22 61
Silver (Ag) (elements) NIOSH 7300 1455 0.01 mg/m3 250-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
(metal, sol)

Sampling Guide
S Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Silver (elements by ICP Aqua Regia ashing) NIOSH 7301 250-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Silver (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Silver, metal & soluble compounds (as Ag) OSHA ID 121 1198 0.01 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Silver, metal & soluble compounds (ICP analysis of OSHA ID 206 1279 0.01 mg/m3 960 2000 8 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
metal/metalloid particulates from solder operations)
Silvex OSHA CSI W W 225-2401A 112
Simazine ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Simazine NIOSH 5602 480 1000 8 GC-ECD ST 226-58 38
Simazine OSHA CSI 120 1000 2 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Soapstone (respirable dust) OSHA CSI 20 mppcf varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Soapstone (total dust) OSHA CSI 20 mppcf 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Sodium azide OSHA ID 211 5 1000 5 IC-UV ST 226-55 38 FLT 225-8-01 73
CST 225-2LF 79 SPC 225-23 78
C/HLD 225-1 78
Sodium bisulfite OSHA ID 121 1203 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Sodium carbonate (see dust, respirable nuisance) OSHA CSI
Sodium fluoride (fluorides) NIOSH 7902 2.5 mg/m3 480 30 1000 2000 8 15 ISE CF/CST 225-9001 59 C/HLD 225-1 78
Sodium fluoride (fluorides) NIOSH 7906 2.5 mg/m3 480 1000 8 IC-ECN CF/CST 225-9001 59 C/HLD 225-1 78
Sodium fluoroacetate OSHA CSI 0.05 mg/m3 960 30 2000 2000 8 15 AA F/CST 225-3-01 71 C/HLD 225-1 78
Sodium hexafluoroaluminate (fluorides) NIOSH 7902 2.5 mg/m3 480 30 1000 2000 8 15 ISE CF/CST 225-9001 59 C/HLD 225-1 78
Sodium hexafluoroaluminate (fluorides) NIOSH 7906 2.5 mg/m3 480 1000 8 IC-ECN CF/CST 225-9001 59 C/HLD 225-1 78
Sodium hydroxide OSHA ID 121 1042 2 mg/m3 960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Sodium hydroxide (alkaline dust) NIOSH 7401 2 mg/m3 360 1500 4 TITRA FLT 225-17-01 75 CST 225-3LF 79
(15 min) C/HLD 225-1 78
Sodium metabisulfite OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Sodium metasilicate OSHA CSI NVM F/CST 225-3-01 71 C/HLD 225-1 78
Sodium nitrate OSHA CSI 960 2000 8 AA or IC F/CST 225-3-01 71 C/HLD 225-1 78
Sodium nitrite OSHA CSI 960 2000 8 AA or IC F/CST 225-3-01 71 C/HLD 225-1 78
Sodium o-phenyl phenate OSHA CSI 10 20(50) 8(3.3) GC-FID F/CST 225-706 74 C/HLD 225-1 78
ST 226-35 37
Sodium polyacrylate (see super absorbent polymer)
Solanesol (environmental tobacco smoke, ASTM D 6271 150-3600 2500 1-24 HPLC-UV FLT 225-2705 75 CST 225-3LF 79
respirable particles) CYC 225-01-02 85 C/HLD 225-1 78
Solder fume (ICP analysis of metal/metalloid OSHA ID 206 480 2000 4 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Solvents (skin) CI PCH 769-3050 110
Soot (see elemental carbon) NIOSH 5040 TOA-FID
Spores (bacterial, fungal) (in air) 15-150 15 L/min 1-10 min varies STC 225-9820 77
Spores (bacterial, fungal) (in air) NON 48 62.5-375 12500 + 5-30 varies BS 225-9595 93 VT 225-9598A◊ 93
Sporothrix species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Sporothrix species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Stachybotrys chartarum (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Stachybotrys chartarum (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Stachybotrys species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Stachybotrys species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Stannous-2-ethyl hexanoate (tin, organic OSHA CSI 480 1000 8 AA-GF ST 226-30-16 37
compounds [as Sn])
Starch (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Starch (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Starch (see dust, total and respirable nuisance)
Stoddard solvent OSHA 48 500 12 200 1 GC-FID ST 226-01 37
Stoddard solvent (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 10 1.5 20(50) 100 8(3.3) 15 GC-FID ST 226-01 37
Strontium OSHA CSI 480 1000 8 AA F/CST 225-3-01 71 C/HLD 225-1 78
Strontium (elements by ICP Aqua Regia ashing) NIOSH 7301 10-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Strontium (elements by ICP HNO3 digestion) NIOSH 7303 300-100,000,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Strontium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Strontium (elements) NIOSH 7300 1455 0.5 mg/m3 10-1000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Strychnine NIOSH 5016 0.15 mg/m3 180 1500 2 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
(10 hr)
Strychnine OSHA CSI 0.15 mg/m 3
1000 3000 5.5 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Styrene (phenylethylene)  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Styrene (phenylethylene)  NON 54 25 15 10 3 20 200 8 15 GC-FID ST 226-81A 38
Styrene (phenylethylene)  OSHA 09 100 200 (C) 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Styrene (phenylethylene)  OSHA 89 1368 100 200 (C) 12 0.75 50 50 4 15 GC-FID ST 226-73 38
Styrene (phenylethylene) (hydrocarbons, aromatic)  NIOSH 1501 50 100 1-14 1-14 10-1000 10-1000 varies varies GC-FID ST 226-01 37
Styrene oxide OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-35 37
Subtilisins (proteolytic enzymes) OSHA CSI Bulk

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number S
Sucrose (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Sucrose (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Sucrose (see dust, total or dust, respirable nuisance) OSHA CSI
Sudan I OSHA CSI 90 1000 2 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Sudan III OSHA CSI 90 1000 1.5 HPLC F/CST 225-709 74 C/HLD 225-1 78
Sulfamethazine OSHA CSI 100 1000 1.5 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Sulfamic acid OSHA CSI 100 1000 100 min IC F/CST 225-709 74 C/HLD 225-1 78
m-Sulfobenzoic acid OSHA CSI 180 1000 3 HPLC-UV F/CST 225-3-01 71 C/HLD 225-1 78
Sulfur (see dust, total & respirable nuisance)
Sulfur dioxide  NIOSH 6004 1331 2 5 180 15 1000 1000 3 15 IC CF/CST 225-9005 59 C/HLD 225-1 78
Sulfur dioxide OSHA 1011 5 ppm 12 7.5 50 500 4 15 IC ST 226-179 40
Sulfur dioxide  OSHA ID 104 5 60 15 1000 1000 1 15 IC F/CST 225-3-01 71 IMP 225-36-2 61
IT 225-22 61
Sulfur dioxide  OSHA ID 200 1461 5 12 1.5 100 100 2 15 IC ST 226-80 38
Sulfur dioxide (using prefilter) OSHA ID 200 1622 5 12 1.5 100 100 2 15 IC ST 226-80 38 FLT 225-2708 75
CST 225-3-23 79 C/HLD 225-1 78
Sulfur hexafluoride by portable GC NIOSH 6602 1023 1000 varies varies varies P GC-ECD SB 232-03 or SB 231-03 53
Sulfur monochloride OSHA CSI 1 5 1000 5 IC IMP 225-36-2 61 IT 225-22 61
Sulfur tetrafluoride OSHA ID 110 5 1000 5 ISE IMP 225-36-2 61 IT 225-22 61
Sulfuric acid OSHA ID 113 1465 1 mg/m3 480 2000 4 IC F/CST 225-3-01 71 C/HLD 225-1 78
Sulfuric acid OSHA ID 165SG 1 mg/m3 96 200 8 IC ST 226-10-03 37
Sulfuric acid (acids, inorganic) NIOSH 7903 1 mg/m3 48 200 4 IC ST 226-10-03 37
Sulfuric acid mist ASTM D 4856 1431 40 1000 40 min IC F/CST 225-3-01 71 C/HLD 225-1 78
Sulfuryl fluoride NIOSH 6012 5 10 10 20 8 IC-ECN ST 226-16 37
Sulfuryl fluoride OSHA CSI 5 24 1.5 100 100 4 15 IC ST 226-16 37
Sulprofos OSHA PV2037 240 1000 4 GC-FPD ST 226-30-16 37
Sulprofos (organophosphorus pesticides) NIOSH 5600 1 mg/m3 240 1000 4 GC-FPD ST 226-58 38
Super absorbent polymers NIOSH 5035 960 2000 8 ICP-AES or AA F/CST 225-802 73 C/HLD 225-1 78
Syncephalastrum species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Syncephalastrum species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Systox (see demeton)
2,4,5-T OSHA CSI 10 mg/m3 200 3000 1 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Talc (containing asbestos) (see asbestos) OSHA ID 160
Talc (respirable, with no asbestos) OSHA CSI 20 mppcf varies varies varies GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-105 84 CST 225-3LF 79
Tannin OSHA CSI 60 1000 1 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Tantalum (metal, oxide dusts) OSHA CSI 5 mg/m3 960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
2,4-TDI (toluene diisocyanate) ASTM D 5932 15 1000 15 HPLC-UV, -FD CF/CST 225-9022 59 C/HLD 225-1 78
2,4-TDI (toluene diisocyanate) NIOSH 5522 LFC 360 20 1000 2000 6 10 HPLC-FD IMP 225-36-1 61 IT 225-22 61
2,4-TDI (toluene diisocyanate) OSHA 42 1458 0.02 (C) 240 15 1000 1000 4 15 HPLC-UV, CF/CST 225-9002 or CF/CST 225-9013 59
2,6-TDI (toluene diisocyanate) ASTM D 5932 15 1000 15 HPLC-UV, -FD CF/CST 225-9022 59 C/HLD 225-1 78
2,6-TDI (toluene diisocyanate) NIOSH 5522 LFC 360 20 1000 2000 6 10 HPLC-FD IMP 225-36-1 61 IT 225-22 61
2,6-TDI (toluene diisocyanate) OSHA 42 1458 15 2000 15 HPLC-UV, CF/CST 225-9002 or CF/CST 225-9013 59
2, 4-TDI (toluene diisocyanate) (isocyanates, NIOSH 5525 LFC 1-500 1000-2000 varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
total [MAP]) SP 225-27 or IOM 225-76A 87
FLT 225-702 74
2, 6-TDI (toluene diisocyanate) (isocyanates, NIOSH 5525 LFC 1-500 1000-2000 varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
FLT 225-702 74
TEDP OSHA CSI 0.2 mg/m3 480 1000 8 GC-FPD ST 226-30-16 37
Tellurium OSHA ID 121 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Tellurium OSHA ID 132SG 0.1 mg/m3 100 to 1000 1500 to 2000 varies AA-GF F/CST 225-3-01 71 C/HLD 225-1 78
Tellurium (elements by ICP Aqua Regia ashing) NIOSH 7301 0.1 mg/m3 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Tellurium (elements by ICP HNO3 digestion) NIOSH 7303 0.1 mg/m3 125-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Tellurium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Tellurium (elements) NIOSH 7300 1455 0.1 mg/m3 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Tellurium hexafluoride (as Te) OSHA CSI 0.02 480 1000 8 AA ST 226-01 37 F/CST 225-3-01 71
Temephos (respirable dust) OSHA PV2056 5 mg/m3 varies varies varies GC-FPD F/CST 225-706 74 C/HLD 225-1 78
Temephos (total dust) OSHA CSI 15 mg/m3 480 1000 8 GC-FPD ST 226-30-16 37
TEPP OSHA CSI 0.05 mg/m3 480 1000 8 GC-FPD ST 226-30-16 37
Terbufos OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37
Terbufos (organophosphorus pesticides) NIOSH 5600 240 1000 4 GC-FPD ST 226-58 38
Terbuthiuron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 42
Tergitol NP-33 OSHA CSI 100 1000 1.6 HPLC-UV ST 226-57 38
Terpenes (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 40
Terpenes (see specific compounds) NIOSH 1552 1463 24 50 8 GC-FID ST 226-01 37
o-Terphenyl NIOSH 5021 0.5 30 2000 15 GC-FID F/CST 225-1713 75 C/HLD 225-1 78
o-Terphenyl (see terphenyls) OSHA CSI

Sampling Guide
T Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Terphenyls OSHA CSI 1 (C) 8.5 1700 5 HPLC-FD F/CST 225-709 74 C/HLD 225-1 78
Terpineol  OSHA CSI 10 200 50 min GC-FID ST 226-01 37
Testosterone OSHA PV2001 60 1000 1 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Tetrabromobisphenol A OSHA CSI 100 1000 100 min HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
1,1,2,2-Tetrabromoethane NIOSH 2003 96 200 8 GC-FID ST 226-10 37
Tetrabutyltin (organotin compounds as Sn) NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC, AA-GF ST 226-30 37 F/CST 225-709 74
C/HLD 225-1 78
1,1,2,2-Tetrachloro-1,2-difluoroethane NIOSH 1016 500 2 20 1.5 GC-FID ST 226-01 37
1,1,2,2-Tetrachloro-1,2-difluoroethane OSHA 07 1182 500 2 50 40 min GC-FID ST 226-01 37
1,1,1,2-Tetrachloro-2,2-difluoroethane NIOSH 1016 500 2 20 1.5 GC-FID ST 226-01 37
1,1,1,2-Tetrachloro-2,2-difluoroethane OSHA 07 1181 500 2 50 40 min GC-FID ST 226-01 37
1,2,3,4-Tetrachlorobenzene ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-124 42
1,2,3,5-Tetrachlorobenzene OSHA CSI 12 100 2 GC-ECD FLT 225-17-03 75 CST 225-33 78
ST 226-30-04 37 C/HLD 225-1 78
1,2,4,5-Tetrachlorobenzene (polychlorobenzenes) NIOSH 5517 12 25 8 GC-ECD FLT 225-17-03 75 CST 225-33 78
2,3,7,8-Tetrachlorodibenzo-p-dioxin OSHA CSI 30 1000 0.5 NVM IMP 225-36-1 61 IT 225-22 61
2,3,7,8-Tetrachlorodibenzofuran OSHA CSI 30 1000 0.5 NVM IMP 225-36-1 61 IT 225-22 61
1,1,2,2-Tetrachloroethane  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
1,1,2,2-Tetrachloroethane  NIOSH 1019 1 24 50 8 GC-FID ST 226-81A 38
1,1,2,2-Tetrachloroethane  NIOSH 2562 1 3-30 10-200 varies GC-FID ST 226-121 39
1,1,2,2-Tetrachloroethane  OSHA 07 5 30 200 2.5 GC-FID ST 226-81A 38
1,1,1,2-Tetrachloroethane  TD, GC PS 590-259 and SV 590-260 or
SV 590-261 or SV 590-262 67
Tetrachloroethylene (hydrocarbons, halogenated)  NIOSH 1003 LFC 3 10-200 varies GC-FID ST 226-01 37
Tetrachloroethylene (perchloroethylene)  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Tetrachloroethylene (perchloroethylene)  OSHA 07 100 200 24 50 8 GC-FID ST 226-01 37
Tetrachloroethylene (perchloroethylene)  OSHA 1001 1747 100 200 (C) 12 0.75 50 50 4 5 GC-FID ST 226-01 37
Tetrachloroethylene (perchloroethylene) (portable GC) NIOSH 3704 LFC 1 varies varies P GC SB 232-01 or SB 233-01 52
Tetrachloronaphthalene OSHA CSI 2 mg/m3 90 1000 1.5 GC-FID ST 226-30-16 37
2,3,4,6-Tetrachlorophenol OSHA 45 48 200 4 HPLC-UV ST 226-97 39
Tetraethyl lead (as Pb) NIOSH 2533 0.075 mg/m3 120 1000 2 GC-PID ST 226-30-04 37
Tetraethyl lead (as Pb) OSHA CSI 75 µg/m3 480 1000 8 AA ST 226-01 37 F/CST 225-706 74
C/HLD 225-1 78
Tetraethyl pyrophosphate NIOSH 2504 0.05 mg/m 3
24 50 8 GC-FPD ST 226-105 39
Tetraethyl tin OSHA 110 0.1 mg/m3 48 3 200 200 4 15 GC-FID ST 226-95 39
Tetraethylene glycol NIOSH 5523 60 1000 1 GC-FID ST 226-57 38
Tetraethylene glycol diacrylate OSHA CSI 10 20(50) 8(3.3) HPLC-UV ST 226-95 39
Tetraethylene glycol dimethacrylate OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-95 39
Tetraethylenepentamine OSHA CSI 15 1000 15 HPLC-UV FLT 225-7 74 CST 225-2LF 79
C/HLD 225-1 78
Tetrahydrofuran  NIOSH 1609 200 250 9 1.5 20(50) 100 7(3) 15 GC-FID ST 226-01 37
Tetrahydrofuran  OSHA 07 1064 200 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Tetrahydrofurfuryl acrylate OSHA PV2131 1 mg/m3 48 200 4 GC-FID ST 226-110 39
Tetrakis(hydroxymethyl)phosphonium chloride NIOSH 5046 1-480 1000-1700 varies HPLC-UV CF/CST 225-9003 59
Tetramethyl lead (as Pb) NIOSH 2534 75 µg/m3 96 200 8 GC-PID ST 226-30-06 37
Tetramethyl lead (as Pb) OSHA CSI 75 µg/m3 480 1000 8 AA F/CST 225-709 74 C/HLD 225-1 78
ST 226-01 37
Tetramethyl succinonitrile OSHA 07 1183 0.5 10 20 8 GC-FID ST 226-01 37
Tetramethyl thiouram disulfide (see thiram, 2427)
Tetramethyl thiourea NIOSH 3505 96 200 8 VAS IMP 225-36-1 61 IT 225-22 61
Tetramethyl tin OSHA PV2057 0.1 mg/m3 20 200 100 min GC-FID ST 226-01 37
1,2,3,4-Tetramethylbenzene  OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Tetramethylbenzidine  TD, GC PS 590-200 or PS 590-259 and
SV 590-261 67
Tetramethyldiaminobenzophenone OSHA CSI 180 1000 3 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
N,N,N’,N’-Tetramethylethylenediamine OSHA CSI 480 1000 8 GC-NPD IMP 225-36-1 61 IT 225-22 61
Tetranitromethane NIOSH 3513 1 240 1000 4 GC-NPD IMP 225-36-1 61 IT 225-22 61
Tetranitromethane OSHA CSI 1 240 1000 4 GC-NPD IMP 225-36-1 61 IT 225-22 61
Tetrasodium pyrophosphate OSHA ID 111 960 2000 8 GR,IC FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Tetrasodium pyrophosphate OSHA ID 121 960 2000 8 AA or AES FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Tetryl (2,4,6-trinitrophenyl-methylnitramine) OSHA CSI 1.5 mg/m 3
90 1500 1 CLR F/CST 225-3-01 71 C/HLD 225-1 78
Thalium (elements by ICP Aqua Regia ashing) NIOSH 7301 0.1 mg/m3 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
(skin, sol) C/HLD 225-1 78
Thallium (elements by ICP HNO3 digestion) NIOSH 7303 0.1 mg/m3 35-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
(skin, sol)
Thallium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Thallium (elements) NIOSH 7300 1455 0.1 mg/m3 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
(skin, sol)
Thallium (soluble compounds) (as Tl) OSHA ID 121 1202 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Thimet (phorate) OSHA CSI 480 15 1000 1000 8 15 GC-FPD ST 226-30-16 37

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number T
Thiobencarb (organonitrogen pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 37
4,4’-Thiobis(6-tert-butyl-m-cresol) (respirable dust) OSHA CSI 5 mg/m3 varies varies varies HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
CYC 225-105 84
4,4’-Thiobis(6-tert-butyl-m-cresol) (total dust) OSHA CSI 15 mg/m 3
60 1000 1 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Thioglycolic acid OSHA CSI 120 1000 2 HPLC-UV IMP 225-36-1 61 IT 225-22 61
Thionyl chloride OSHA CSI 15 1000 15 IC IMP 225-36-2 61 IT 225-22 61
Thiophanate OSHA CSI 180 1000 3 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Thiophanate-methyl OSHA PV2058 240 1000 4 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Thiophanate-methyl in air NIOSH 5606 20-480 10-1000 varies HPLC-UV ST 226-58 38
Thiophene OSHA CSI 48 100 8 GC-FPD ST 226-01 37
Thiourea OSHA PV2059 480 2000 4 HPLC-UV F/CST 225-706 74 C/HLD 225-1 78
Thiram NIOSH 5005 5 mg/m3 120 1000 2 HPLC-UV FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Thorium OSHA CSI 960 2000 8 N ACT F/CST 225-3-01 71 C/HLD 225-1 78
L-Thyroxine OSHA PV2117 240 1000 4 HPLC-UV F/CST 225-709 74 C/HLD 225-1 78
Tin (elements by ICP Aqua Regia ashing) NIOSH 7301 2 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Tin (elements by ICP HNO3 digestion) NIOSH 7303 2 mg/m3 1-25,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Tin (elements) NIOSH 7300 1455 2 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Tin (ICP analysis of metal/metalloid particulates OSHA ID 206 2 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
from solder operations)
Tin (inorganic compounds, except oxides) (as Sn) OSHA ID 121 1201 2 mg/m 3
Tin (organic compounds, see specific OSHA CSI
compounds) (as Sn)
Tin (organic compounds) (as Sn) (organotin NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC, AA-GF ST 226-30 37 F/CST 225-706 74
Tin oxide (as Sn) OSHA ID 121 1200 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Titanium (elements by ICP Aqua Regia ashing) NIOSH 7301 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Titanium (elements by ICP HNO3 digestion) NIOSH 7303 0.1-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Titanium (elements) NIOSH 7300 1455 5-100 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Titanium (see titanium dioxide) OSHA CSI
Titanium dioxide (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Titanium dioxide (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Titanium dioxide (total dust) OSHA CSI 15 mg/m 3
960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
TNT (2,4,6-trinitrotoluene) OSHA 44 1.5 mg/m 3
60 1000 1 GC-TEA-EAP ST 226-56 38
o-Tolidine OSHA 71 1236 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
o-Tolidine based dyes OSHA CSI 480 1000 8 HPLC-UV FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
o-Tolidine dyes (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC-UV FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
m-Tolualdehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
o-Tolualdehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
p-Tolualdehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 39
o-Toluamide OSHA CSI 5 mg/m3 240 1000 4 HPLC F/CST 225-709 74 C/HLD 225-1 78
Toluene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Toluene  NIOSH 4000 100 150 7 0.2 14.5 14.5 8 15 GC-FID PS 575-001 63
Toluene  OSHA 07 200 300 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Toluene  OSHA 111 1748 200 300 (C) 12 0.5 50 50 4 10 GC-FID ST 226-81A or ST 226-01 37
Toluene (hydrocarbons, aromatic)  NIOSH 1501 100 150 1-8 1-8 10-200 10-200 varies varies GC-FID ST 226-01 37
2,4-Toluene diisocyanate (2,4-TDI) ASTM D 5836 1432 15 1000 15 HPLC-UV, -FD CF/CST 225-9002 59 C/HLD 225-1 78
2,4-Toluene diisocyanate (2,4-TDI) ASTM D 5932 15 1000 15 HPLC-UV, -FD CF/CST 225-9022 59 C/HLD 225-1 78
2,4-Toluene diisocyanate (2,4-TDI) OSHA 42 1458 0.02 (C) 240 15 1000 1000 4 15 HPLC-UV, CF/CST 225-9002 or CF/CST 225-9013 59
2,4-Toluene diisocyanate (2,4-TDI) (isocyanates, NIOSH 5525 LFC 1-500 1000-2000 varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
FLT 225-702‡ 74
2,4-Toluene diisocyanate (2,4-TDI) (isocyanates) NIOSH 5521 LFC 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 61 IT 225-22 61
ELCHM, UV
2,6-Toluene diisocyanate (2,6-TDI) ASTM D 5836 1432 15 1000 15 HPLC-UV, -FD CF/CST 225-9002 59 C/HLD 225-1 78
2,6-Toluene diisocyanate (2,6-TDI) ASTM D 5932 15 1000 15 HPLC-UV, -FD CF/CST 225-9022 59 C/HLD 225-1 78
2,6-Toluene diisocyanate (2,6-TDI) OSHA 42 1458 240 1000 4 HPLC-UV, CF/CST 225-9002 or CF/CST 225-9013 59
2,6-Toluene diisocyanate (2,6-TDI) (isocyanates, NIOSH 5525 LFC 1-500 1000-2000 varies HPLC-UV FLT 225-7‡ 74 CST 225-4 79
FLT 225-702‡ 74
2,6-Toluene diisocyanate (2,6-TDI) (isocyanates) NIOSH 5521 LFC 480 1000 8 HPLC- IMP 225-36-1 61 IT 225-22 61
ELCHM, UV
p-Toluene sulfonic acid NIOSH 5043 960 45 2000 3000 8 15 HPLC-UV FLT 225-16 74 CST 225-32 78
p-Toluene sulfonic acid OSHA CSI 120 1000 2 HPLC-UV IMP 225-36-1 61 IT 225-22 61
2,4-Toluenediamine NIOSH 5516 LFC 480 1000 8 HPLC-UV IMP 225-36-1 61 IT 225-22 61
2,4-Toluenediamine OSHA 65 1237 0.02 (C) 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
2,4-Toluenediamine OSHA 65 1237 0.02 (C) 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78

Sampling Guide
T Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
2,6-Toluenediamine NIOSH 5516 LFC 480 1000 8 HPLC-UV IMP 225-36-1 61 IT 225-22 61
2,6-Toluenediamine OSHA 65 1237 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
2,6-Toluenediamine OSHA 65 1237 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
m-Toluidine OSHA 73 1230 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
o-Toluidine NIOSH 2017 LFC 24 200 2 GC-FID CF/CST 225-9004 59 ST 226-15 37
o-Toluidine OSHA 73 1230 5 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
p-Toluidine OSHA 73 1230 100 1000 100 min GC-ECD CF/CST 225-9004 59 C/HLD 225-1 78
o-Toluidine (amines, aromatic) NIOSH 2002 1057 LFC 48 100 8 GC-FID or ST 226-10 37
GC-NSD
o-Toluidine based dyes OSHA CSI 480 1000 8 HPLC-UV FLT 225-17-04 75 CST 225-3LF 79
C/HLD 225-1 78
Torak OSHA CSI W W 225-2401A 112
Torula species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Torula species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Toxaphene
Tremolite (see asbestos fibers) NIOSH 7400
Tremolite fibers (see asbestos) OSHA ID 160
Trially isocyanurate OSHA CSI 10 20(50) 8(3.3) GC-NPD ST 226-01 37
Triazine pesticides ASTM D 4861 960 2000 8 GC-ECD PUF 226-92 42
Tributyl phosphate NIOSH 5034 0.2 90 1500 1 GC-FPD F/CST 225-3-01 71 C/HLD 225-1 78
Tributyl phosphate OSHA CSI 5 mg/m3 90 1500 1 GC-FPD F/CST 225-3-01 71 C/HLD 225-1 78
Tributyl phosphorotrithioate OSHA CSI 480 1000 8 GC-FID IMP 225-36-1 61 IT 225-22 61
Tributyl phosphorotrithioate (DEF) OSHA CSI 480 1000 8 GC-FPD IMP 225-36-1 61 IT 225-22 61
Tributyltin benzoate {tin, organic compounds (as Sn)} OSHA ID222SG 200 2000 100 min AA-GF F/CST 225-803 73 C/HLD 225-1 78
Tributyltin chloride (organotin compounds as Sn) NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC, AA-GF ST 226-30 37 F/CST 225-709 74
C/HLD 225-1 78
Tributyltin fluoride {tin, organic compounds (as Sn)} OSHA ID223SG 200 2000 100 min AA-GF F/CST 225-803 73 C/HLD 225-1 78
Tributyltin neodecanoate (see tin, organic compounds)
Trichlorfon OSHA CSI 390 1000 6.5 GC-FPD ST 226-30-16 37
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)  NIOSH 1020 1061 1000 1250 2.4 0.3 20 20 2 15 GC-FID ST 226-01 37
1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113)  OSHA 113 1000 1 50 20 min GC-FID ST 226-121 39
1,1,1-Trichloro-2,2,2-trifluoroethane OSHA CSI 3 20 2.5 GC-FID ST 226-01 37
Trichloroacetic acid OSHA PV2017 10 200 50 HPLC-UV ST 226-10 37
1,2,3-Trichlorobenzene ASTM D 4861 240-7200 1000- 5000 4 to 24 GC-ECD PUF 226-124 42
1,2,3-Trichlorobenzene OSHA CSI 12 50 4 GC-ECD FLT 225-17-03 75 CST 225-33 78
ST 226-30-04 37 C/HLD 225-1 78
1,2,4-Trichlorobenzene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
1,2,4-Trichlorobenzene OSHA CSI 5 1000 5 GC-ECD FLT 225-17-03 75 CST 225-33 78
ST 226-30-04 37 C/HLD 225-1 78
1,2,4-Trichlorobenzene (polychlorobenzenes) NIOSH 5517 5 12 3 25 200 8 15 GC-ECD FLT 225-17-03 75 CST 225-33 78
ST 226-30-04 37 C/HLD 225-1 78
1,1,2-Trichloroethane  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
1,1,2-Trichloroethane  OSHA 11 1071 10 10 200 1 GC-FID ST 226-01 37
1,1,2-Trichloroethane (hydrocarbons, halogenated)  NIOSH 1003 10 (skin) 10 10-200 varies GC-FID ST 226-01 37
1,1,1-Trichloroethane (methyl chloroform)  NIOSH 1003 350 3 10-200 varies GC-FID ST 226-01 37
Trichloroethylene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Trichloroethylene  NIOSH 1022 25 2 (1 hr) 10 2 20(50) 200 8(3.3) 10 GC-FID ST 226-01 37
Trichloroethylene  OSHA 07 1184 100 200 (C) 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Trichloroethylene  OSHA 1001 1747 100 200 (C) 12 0.75 50 50 4 5 GC-FID ST 226-01 37
Trichloroethylene (hydrocarbons, halogenated) NIOSH 1003 10 10-200 varies GC-FID ST 226-01 37
Trichloroethylene by portable GC NIOSH 3701 1030 25 2 (1 hr) varies varies varies varies varies varies P GC-PID SB 232 Series 52
Trichlorofluoromethane (fluorotrichloromethane) NIOSH 1006 1000 5 20 240 GC-FID ST 226-09 37
Trichloromethylbenzene (benzotrifluoride,  100 GC-FID PS 575-001 or PS 575-002 63
OXSOL 2000)
Trichloronaphthalene OSHA CSI 5 mg/m 3
90 1000 1.5 GC-ECD ST 226-30-16 37
Trichloronitromethane NON 51 0.1 144 100 24 GC-ECD, ST 226-175 40
GC-MSD
2,4,5-Trichlorophenol ASTM D 4861 240-7200 1000- 5000 4 to 24 GC-ECD PUF 226-92 42
2,4,5-Trichlorophenoxyacetic acid (see 2,4,5-T)
1,2,3-Trichloropropane  OSHA 07 1185 50 10 20(50) 8(3.3) GC-FID ST 226-01 37
1,2,3-Trichloropropane (hydrocarbons, halogenated)  NIOSH 1003 10 (skin) 0.6-60 10-200 varies GC-FID ST 226-01 37
2,3,6-Trichlorotoluene OSHA CSI 10 20(50) 8(3.3) GC-FID ST 226-01 37
Trichoderma species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Trichoderma species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Tricyclohexyltin hydroxide (organotin compounds as Sn) NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC, AA-GF ST 226-30 37 F/CST 225-709 74
C/HLD 225-1 78
Tridymite (silica, crystalline (respirable)) by XRD NIOSH 7500 1370 0.05 mg/m 3
C/HLD 225-1 78
Tridymite (Silica, crystalline by IR) NIOSH 7602 0.05 mg/m3 400-800 2500 varies IR F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Triethanolamine (TEA) OSHA PV2141 120 1000 2 GC-FID F/CST 225-709 74 C/HLD 225-1 78
Triethanolamine (TEA) (aminoethanol compounds II) NIOSH 3509 240 1000 4 IC IMP 225-36-1 61 IT 225-22 61
Triethylamine  OSHA PV2060 25 5 3 100 200 50 min 15 GC-FID ST 226-98 39
Triethylene glycol NIOSH 5523 60 1000 1 GC-FID ST 226-57 38

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number T
Triethylenetetramine (TETA) OSHA 60 1286 10 100 100 min HPLC-UV ST 226-30-18 37
Trifluorobromomethane NIOSH 1017 1000 1 20 50 min GC-FID ST 226-01 37 ST 226-09 37
2,2,2-Trifluoroethanol OSHA CSI 5 20 4 GC-FID ST 226-01 37
Trifluoromonobromomethane OSHA 07 1000 1 20 50 min GC-FID ST 226-01 37 ST 226-09 37
Trifluoromonobromomethane (trifluorobromomethane) NIOSH 1017 1000 1 20 50 min GC-FID ST 226-01 37 ST 226-09 37
Trifluralin ASTM D 4861 240-7200 1000- 5000 4 to 24 GC-ECD PUF 226-92 42
Trifluralin OSHA CSI 48 100 8 HPLC-UV ST 226-56 38
1,3,5-Triglycidyl isocyanurate OSHA PV2055 60 1000 1 GC-ECD FLT 225-7‡ 74 CST 225-2LF 79
C/HLD 225-1 78
Trimellitic anhydride (TMA) NIOSH 5036 0.005 (10 hr) 960 2000 8 GC-FID F/CST 225-802 73 C/HLD 225-1 78
Trimellitic anhydride (TMA) OSHA 98 480 2000 4 HPLC-UV CF/CST 225-9010 59 C/HLD 225-1 78
2,2,4-Trimethyl-1,3-pentanediol diisobutyrate OSHA PV2002 10 100 100 min GC-FID ST 226-110 39
Trimethylamine OSHA CSI 10 1.5 100 100 100 min 15 GC-NPD ST 226-98 39
1,2,3-Trimethylbenzene  OSHA PV2091 10 100 100 min GC-FID ST 226-01 37
1,2,4-Trimethylbenzene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
1,2,4-Trimethylbenzene  OSHA PV2091 10 100 100 min GC-FID ST 226-01 37
1,3,5-Trimethylbenzene (mesitylene)  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
1,3,5-Trimethylbenzene (mesitylene)  OSHA PV2091 10 100 100 min GC-FID ST 226-01 37
Trimethylolethane trinitrate OSHA CSI 15 1000 15 min HPLC-UV ST 226-35-03 37
Trimethylolpropane triacrylate OSHA CSI 10 20(50) 8(3.3) HPLC-UV ST 226-95 39
Trimethyltin dichloride NIOSH 5526 0.1 mg/m3 60 60 250 1000 4 60 GC-FPD ST 226-30-16 37
2,4,7-Trinitro-9-fluorenone OSHA CSI 480 1000 8 HPLC-UV FLT 225-17A 75 CST 225-3LF 79
C/HLD 225-1 78
2,4,7-Trinitrofluoren-9-one NIOSH 5018 480 3000 2.7 HPLC-UV FLT 225-17-04 75 CST 225-3LF 79
C/HLD 225-1 78
2,4,6-Trinitrotoluene (TNT) OSHA 44 1.5 mg/m 3
60 1000 1 GC-TEA-EAP ST 226-56 38
Triorthocresyl phosphate NIOSH 5037 0.1 mg/m3 90 1000 1.5 GC-FPD F/CST 225-3-01 71 C/HLD 225-1 78
Triphenyl phosphate NIOSH 5038 3 mg/m3 240 1000 4 GC-FPD F/CST 225-3-01 71 C/HLD 225-1 78
Triphenyl tin chloride (as Sn) NIOSH 5527 0.1 mg/m3 (skin) 100-2000 1000-4000 varies HPLC/ICP- FLT 225-8-01-1 73 SP 225-27 78
AES C/HLD 225-1 78
Triphenylamine OSHA CSI 240 1000 4 HPLC-UV IMP 225-36-2 61 IT 225-22 61
Triphenyltin fluoride (tin, organic compounds [as Sn]) OSHA CSI 0.1 mg/m3 960 2000 8 AA-GF F/CST 225-709 74 C/HLD 225-1 78
Triphenyltin hydroxide {tin, organic compounds (as Sn)} OSHA ID225SG 0.1 mg/m3 200 2000 100 min AA-GF F/CST 225-709 74 C/HLD 225-1 78
Tripropylene glycol diacrylate OSHA CSI 10 20(50) 8(3.3) HPLC-UV ST 226-95 39
Tripropylene glycol diacrylate (TPGDA) NON 39 480 1000 8 GC-FID ST 226-56 38
Trydymite (silica, crystalline by VAS) NIOSH 7601 1041 0.05 mg/m3 400-800 2500 varies VAS F/CST 225-803 73 C/HLD 225-1 78
CYC 225-01-02 85
Trypsin OSHA CSI 480 2000 4 IRA F/CST 225-1713 75 C/HLD 225-1 78
Tuberculosis (mycobacterium tuberculosis), airborne NIOSH 0900 1920 4000 8 PCR FLT 225-2705 75 SP 225-27 78
CST 225-3LF 79 C/HLD 225-1 78
Tungsten (elements) NIOSH 7300 1455 5 mg/m3 10 mg/m3 5-1000 5-1000 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Tungsten (elements by ICP Aqua Regia ashing) NIOSH 7301 5 mg/m3 10 mg/m3 50-1000 50-1000 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Tungsten & compounds (insoluble) (as W) OSHA ID 213 480 30 2000 2000 4 15 ICP F/CST 225-3-01 71 C/HLD 225-1 78
Tungsten & compounds (soluble) (as W) OSHA ID 213 480 30 2000 2000 4 15 ICP F/CST 225-3-01 71 C/HLD 225-1 78
Tungsten insoluble NIOSH 7074 5 mg/m3 10 mg/m3 480 1000 8 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Tungsten soluble NIOSH 7074 1 mg/m3 3 mg/m3 480 1000 8 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
Turpentine NIOSH 1551 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
n-Undecane (hydrocarbons, BP 36 to 216 C)  NIOSH 1500 2 2 10 - 50 varies GC-FID ST 226-01 37
Uranium (as U) soluble compounds OSHA CSI 0.05 mg/m3 960 2000 8 DPCSP F/CST 225-803 73 C/HLD 225-1 78
Uranium (insoluble compounds) OSHA CSI 0.25 mg/m3 960 30 2000 2000 8 15 ICP F/CST 225-3-01 71 C/HLD 225-1 78
Uranium (soluble compounds) OSHA ID 170SG 0.05 mg/m3 240 2000 2 POL F/CST 225-803 73 C/HLD 225-1 78
Urea pesticides ASTM D 4861 240-7200 1000- 5000 4 to 24 GC-ECD PUF 226-92 42
Valeraldehyde ASTM D 5197 varies 500-1200 5 min to 24 hrs HPLC-UV ST 226-120 or ST 226-119 39
Valeraldehyde NIOSH 2536 50 10 20 8 GC-FID ST 226-118 39
n-Valeraldehyde OSHA 85 3 50 1 HPLC-UV CF/CST 225-9020 59 C/HLD 225-1 78
n-Valeraldehyde (aldehydes, screening) NIOSH 2539 50 5 20 4 GC-FID & GC-MS ST 226-118 39
Vanadium (elements by ICP HNO3 digestion) NIOSH 7303 0.05 mg/m3 2.5-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Vanadium (elements) NIOSH 7300 1455 0.05 mg/m3 5-2000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Vanadium (elements by ICP Aqua Regia ashing) NIOSH 7301 0.05 mg/m3 5-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 73
C/HLD 225-1 78
Vanadium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Vanadium fume (V2O5) OSHA ID 125G 0.05 mg/m3 0.1 480 20 2000 1000 4 20 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Vanadium oxides NIOSH 7504 0.05 mg/m3 600 2600 4 XRD F/CST 225-803 73 C/HLD 225-1 78
(15 min) CYC 225-01-02 85
Vanadium pentoxide (confirmation of) OSHA ID 185 0.05 mg/m3 0.05 mg/m3 varies varies varies XRD F/CST 225-803 73 CYC 225-105 84
C/HLD 225-1 78
Vanadium pentoxide (see vanadium oxides) NIOSH 7504
Vanadium respirable dust (V2O5) OSHA ID 125G 0.5 mg/m3 varies varies varies ICP-AES F/CST 225-3-01 71 CYC 225-105 84
C/HLD 225-1 78
Vanadium trioxide (see vanadium oxides) NIOSH 7504
Vegetable oil mist (see dust, respirable & total nuisance) OSHA CSI
Vermiculite (see dust, total & respirable nuisance)

Sampling Guide
V Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
Verticillium species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Verticillium species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Vinyl acetate  NON 21 24 50 8 GC ST 226-68 38
Vinyl acetate  OSHA 51 24 3 100 200 4 15 GC-FID ST NA SKC
Vinyl bromide  NIOSH 1009 LFC 10 20(50) 8(3.3) GC-FID ST 226-09 37
Vinyl bromide  OSHA 08 1074 5 20 4 GC-FID ST 226-01 37
Vinyl chloride  ASTM D 4766 1434 24 100 or 50 4 or 8 GC-FID ST 226-16 37
Vinyl chloride  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Vinyl chloride  NIOSH 1007 LFC 5 50 1.6 GC-FID ST 226-01 37
Vinyl cyclohexene dioxide OSHA PV2083 10 20(50) 8(3.3) GC-FID ST 226-30 37
Vinyl toluene  OSHA 07 100 10 20(50) 8(3.3) GC-FID ST 226-01 37
N-Vinyl-2-pyrrolidinone OSHA PV2106 10 100 100 min GC-FID ST 226-01 37
Vinylidene chloride  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
Vinylidene chloride  NIOSH 1015 LFC 5 20 4 GC-FID ST 226-01 37
Vinylidene chloride  OSHA 19 3 3 200 200 15 min 15 GC-FID ST 226-01 37
Viruses (in air) NON 48 62.5-375 12500 + 5 to 30 varies BS 225-9595 93 VT 225-9598A◊ 93
VM&P naphtha OSHA 48 3 3 20 200 2.5 15 GC-FID ST 226-01 37
VM&P naphtha (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
VOCs (Volatile Organic Compounds) (canister) EPA IP-1A
(see Environmental Sampling Guide)
VOCs (Volatile Organic Compounds) (canister) EPA TO-14A
VOCs (Volatile Organic Compounds) (canister) EPA TO-15
VOCs (Volatile Organic Compounds) (passive EPA IP-1B
sampler) (see Environmental Sampling Guide)
VOCs (Volatile Organic Compounds) (passive EPA TO-17
sampler) (see Environmental Sampling Guide)
VOCs (volatile organic compounds) (sample bag) EPA 0040
VOCs (volatile organic compounds) (sorbent EPA IP-1B
tube) (see Environmental Sampling Guide)
VOCs (volatile organic compounds) (sorbent EPA TO-17
tube) (see Environmental Sampling Guide)
VOCs (volatile organic compounds) (VOST) (see EPA 0031
Volatile organic compounds ASTM D 6196 varies varies varies varies GC ST 226-332 or ST 226-330 40
Volatile organic compounds (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 40
Volatile organics NON 32 24 50 8 GC-PID-ECN ST 226-127 39
Vydate (oxamyl) OSHA CSI 60 1000 1 HPLC ST 226-30-16 37
Wallemia species (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Wallemia species (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Warfarin NIOSH 5002 0.1 mg/m3 360 1500 4 HPLC-UV FLT 225-17-01 75 CST 225-2LF 79
C/HLD 225-1 78
Welding fumes (total particulate) OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Wemicide CW 104 OSHA CSI 480 1000 8 HPLC-UV ST 226-30-16 37
Wollastonite (see dust, total and respirable nuisance) OSHA CSI
Wood alcohol (methanol) NIOSH 2000 200 250 5 3 20 200 4 15 GC-FID ST 226-51 38
Wood dust (except western red cedar) OSHA CSI 960 30 2000 2000 8 30 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Wood dust (western red cedar) OSHA CSI 2.5 mg/m 3
960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Wood dust, hardwood OSHA CSI 15 mg/m 3
960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Wood dust, softwood OSHA CSI 15 mg/m 3
960 2000 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Wood spirit (methanol) NIOSH 2000 200 250 5 3 20 200 4 15 GC-FID ST 226-51 38
m-Xylene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
o-Xylene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
p-Xylene  ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series
m-Xylene (hydrocarbons, aromatic)  NIOSH 1501 100 2-23 10-200 varies GC-FID ST 226-01 37
o-Xylene (hydrocarbons, aromatic)  NIOSH 1501 100 150 2-23 2-23 10-200 10-200 varies varies GC-FID ST 226-01 37
p-Xylene (hydrocarbons, aromatic)  NIOSH 1501 100 2-23 10-200 varies GC-FID ST 226-01 37
Xylene (o-, m-, & p-isomers)  OSHA 07 1186 100 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 37
Xylene (o-, m-, & p-isomers)  OSHA 1002 1746 100 12 50 4 GC-FID ST 226-01 37
m-Xylenediamine (mXDA) OSHA 105 1405 15 1000 15 HPLC-UV CF/CST 225-9004 59 C/HLD 225-1 78
p-Xylenediamine (pXDA) OSHA 105 1405 15 1000 15 HPLC-UV CF/CST 225-9004 59 C/HLD 225-1 78
Xylidine OSHA CSI 5 24 50 8 GC-FID ST 226-10 37
2,4-Xylidine (amines, aromatic) NIOSH 2002 1056 2 10 20(50) 8(3.3) GC-FID or ST 226-10 37
GC-NSD
Yeast (fungi, molds, spores) OSHA CSI 120 1000 2 varies F/CST 225-3-01 71 C/HLD 225-1 78
Yeast (fungi, molds, spores) OSHA CSI 141.5 28.3 L/min 5 min varies BI 225-9611 94
Yttrium OSHA ID 121 1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Yttrium (elements by ICP HNO3 digestion) NIOSH 7303 0.1-50,000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78

Sampling Guide
Chemical Hazards
Passive
Guide
Agency
Reference
Chem
F File
TWA (ppm)
CLG/STEL
(ppm)
TWA
CLG/
STEL
CLG/STEL
(min)
Analytical
Method
SKC Collecting Equipment and Page Number X
Yttrium (elements by ICP Aqua Regia ashing) NIOSH 7301 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Yttrium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Yttrium (elements) NIOSH 7300 1455 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Zectran OSHA CSI W W 225-2401A 112
Zinc OSHA ID 121 1204 960 2000 8 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Zinc OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Zinc (elements by ICP Aqua Regia ashing) NIOSH 7301 5-200 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Zinc (elements by ICP HNO3 digestion) NIOSH 7303 5 mg/m3 15 mg/m3 0.5- 0.5- 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
(ZnO) (ZnO) 10,000 10,000
Zinc (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Zinc (elements) NIOSH 7300 1455 5 mg/m3 10 mg/m3 5-200 5-200 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
(ZnO) (ZnO)
Zinc & compounds (as Zn) NIOSH 7030 5 mg/m 3
15 mg/m 240
3
30 1000 2000 4 15 AA-F F/CST 225-3-01 71 C/HLD 225-1 78
(ZnO) (ZnO)
Zinc bromide (see dust, total and nuisance)
Zinc chloride fume OSHA ID 121 1207 1 mg/m3 960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 71 C/HLD 225-1 78
Zinc chloride fume OSHA ID 125G 1 mg/m3 480 30 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Zinc chromate (CR(VI)) OSHA ID 215 (V2) 0.005 mg/m3 960 2000 8 IC-UV F/CST 225-802 or FLT 225-1827‡ 74
CST 225-2LF 79 C/HLD 225-1 78
Zinc chromates (as CrO3) OSHA ID 215 0.005 mg/m3 960 2000 15 IC-UV F/CST 225-802 73 C/HLD 225-1 78
Zinc dibutyldithiocarbamate OSHA PV2065 180 1000 3 HPLC-UV ST 226-30-16 37
Zinc oxide NIOSH 7502 5 mg/m3 15 mg/m3 240 30 1000 2000 4 15 XRD FLT 225-807 73 CST 225-3-23 79
(15 min)
Zinc oxide (elements by ICP HNO3 digestion) NIOSH 7303 5 mg/m 3
15 mg/m 0.5-10,000 0.5-10,000 1000-4000 1000-4000 varies
3
varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Zinc oxide (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Zinc oxide (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Zinc oxide dust (see dust, total & respirable) OSHA CSI
Zinc oxide fume OSHA ID 121 5 mg/m3 960 30 2000 2000 8 15 AA or AES FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Zinc oxide fume OSHA ID 125G 5 mg/m 3
480 30 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 79
Zinc oxide fume OSHA ID 143 5 mg/m 3
960 30 2000 2000 8 15 GR, XRD FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Zinc oxide fume (ICP analysis of metal/metalloid OSHA ID 206 5 mg/m 3
480 2000 4 ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Zinc stearate (particulates, respirable) NIOSH 0600 1038 375 2500 2.5 GR FLT 225-8-01 73 C/HLD 225-1 78
CYC 225-01-02 85 CST 225-3LF 79
Zinc stearate (particulates, total) NIOSH 0500 1035 120 2000 1 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-2LF 79
Zinc stearate (respirable dust) OSHA CSI 5 mg/m 3
912 1900 8 GR FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79
Zinc stearate (total dust) OSHA ID 121 15 mg/m 3
Zinc stearate (total dust) OSHA ID 125G 15 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 71
C/HLD 225-1 78
Zineb OSHA 107 500 2000 250 min HPLC-UV F/CST 225-3-01 71 C/HLD 225-1 78
Ziram OSHA PV2073 120 1000 2 HPLC-UV ST 226-30-16 37
Zirconium (elements by ICP Aqua Regia ashing) NIOSH 7301 5 mg/m3 10 mg/m3 5-200 5-200 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 or F/CST 225-803¥ 73
C/HLD 225-1 78
Zirconium (elements on wipes) NIOSH 9102 wipe ICP-AES W 225-2414 112 TMP 225-2403 or
TMP 225-2415 112
Zirconium (elements) NIOSH 7300 1455 5 mg/m 3
10 mg/m 5-200
3
5-200 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 71 C/HLD 225-1 78
Zirconium compounds (as Zr) OSHA ID 121 5 mg/m3 960 30 2000 2000 8 15 AA or AES FLT 225-8-01 73 C/HLD 225-1 78
CST 225-3LF 79

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SAMPLING∞ www.skcinc.com for updates

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Betasan OSHA CSI 480 1000 8 GC-FPD ST 226-30-16 37

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beta-Chloroprene OSHA 07 1133 25 10 20(50) 8(3.3) GC-FID ST 226-01 37

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Diazinon ASTM D 4861 1000-5000 4-24 GC-NPD PUF 226-92 42

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Dichloromonofluoromethane (dichlorofluoromethane) OSHA CSI 1000 3 20 2.5 GC-FID ST 226-09♠ 37

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3-Ethyl toluene  TD, GC PS 590-259 and SV 590-260 or

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m-Hydroxyacetophenone OSHA CSI 10 200 50 min HPLC-UV ST 226-30-04 37

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1-Methoxy-2-propyl acetate  OSHA 99 10 100 100 min GC-FID ST 226-01 37

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Phenol  OSHA 32 1019 5 24 100 4 HPLC-UV ST 226-95 39

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