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Revision Date: 08.10.2019

SAFETY DATA SHEET

According to Regulation (EC) No. 1907/2006 (REACH) Article 31, Annex II as amended.

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name: EMKARATE™ RL 32-3MAF

1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: Refrigeration Lubricants.
Uses advised against: None identified.

1.3 Details of the supplier of the safety data sheet

Supplier
Company Name: LUBRIZOL LIMITED
Address: THE KNOWLE, NETHER LANE
HAZELWOOD, DERBYSHIRE, DE56 4AN
GB
Telephone: (44) 01332-842211
E-mail contact: [email protected] {Lubrizol Safety Data Sheets can be obtained at
www.mylubrizol.com}

1.4 Emergency telephone number:

FOR TRANSPORT EMERGENCY CALL CHEMTREC (+1) 703 527 3887

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

This product does not meet the classification requirements of the current European legislation.

Classification according to Regulation (EC) No 1272/2008 as amended.

Not classified

2.2 Label elements according to Regulation (EC) No 1272/2008 as amended

Not applicable

2.3 Other hazards: None identified.

SECTION 3: Composition/information on ingredients

3.2 Mixtures
Regulation No. 1272/2008.
This material has no known hazards under applicable laws.

See Section 15 for Regulation (EC) No. 1907/2006 REACH Article 59(1). Candidate List (Substances of Very High Concern (SVHC))

SECTION 4: First aid measures

4.1 Description of first aid measures

Inhalation: Remove exposed person to fresh air if adverse effects are observed.

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Eye contact: Any material that contacts the eye should be washed out immediately with
water. If easy to do, remove contact lenses.

Skin Contact: Wash with soap and water. If skin irritation occurs, get medical attention.
Launder contaminated clothing before reuse.

Ingestion: Treat symptomatically. Get medical attention.

4.2 Most important symptoms See section 11.

and effects, both acute and
delayed:

4.3 Indication of any immediate medical attention and special treatment needed
Hazards: No data available.

Treatment: Treat symptomatically.

SECTION 5: Firefighting measures

General Fire Hazards: No unusual fire or explosion hazards noted. No unusual fire or explosion
hazards noted.

5.1 Extinguishing media

Suitable extinguishing CO2, Dry chemical or Foam. Water can be used to cool and protect
media: exposed material. CO2, dry chemical, foam, water spray, water fog.

Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire.
media:

5.2 Special hazards arising See section 10 for additional information. Keep away from heat, sparks and
from the substance or open flame. Water may cause splattering. Container may rupture on
mixture: heating.

5.3 Advice for firefighters

Special fire fighting No data available.
procedures:

Special protective Wear full protective firegear including self-containing breathing apparatus
equipment for fire-fighters: operated in the positive pressure mode with full facepiece, coat, pants,
gloves and boots. Recommend wearing self-contained breathing apparatus.

SECTION 6: Accidental release measures

6.1 Personal precautions, Personal Protective Equipment must be worn, see Personal Protection
protective equipment and Section for PPE recommendations. Ventilate area if spilled in confined
emergency procedures: space or other poorly ventilated areas.

6.2 Environmental Avoid release to the environment. Do not contaminate water sources or
Precautions: sewer. Environmental manager must be informed of all major spillages.
Prevent further leakage or spillage if safe to do so.

6.3 Methods and material for Dike far ahead of larger spill for later recovery and disposal. Pick up free
containment and cleaning liquid for recycle and/or disposal. Residual liquid can be absorbed on inert
up: material.

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6.4 Reference to other See sections 8 and 13 for additional information.

sections:

SECTION 7: Handling and storage:

7.1 Precautions for safe Keep away from ignition sources such as heat, sparks and open flame. No
handling: smoking. Keep containers closed when not in use. Wash thoroughly after
handling. Launder contaminated clothing before reuse. Empty container
contains product residue which may exhibit hazards of product.

Observe good industrial hygiene practices. Provide adequate ventilation.

Wear appropriate personal protective equipment.

Maximum Handling Not determined.

Temperature:

7.2 Conditions for safe Store away from incompatible materials. See section 10 for incompatible
storage, including any materials.
incompatibilities:

Maximum Storage Not determined.

Temperature:

7.3 Specific end use(s): End uses are listed in an attached exposure scenario when one is required.

SECTION 8: Exposure controls/personal protection

8.1 Control Parameters

Occupational Exposure Limits
None of the components have assigned exposure limits.

8.2 Exposure controls

Appropriate engineering Use material in well ventilated area only. Adequate ventilation should be
controls: provided so that exposure limits are not exceeded. Mechanical ventilation
or local exhaust ventilation may be required.

Individual protection measures, such as personal protective equipment

General information: Please follow the recommended personal protective equipment (PPE)
guidelines below and refer to the appropriate EN standard where
applicable. Use personal protective equipment as required.

Eye/face protection: If contact is likely, safety glasses with side shields are recommended. Eye
protection should meet the standards set out in EN 166.

Skin protection
Hand Protection: Rubber (natural, latex). Suitable gloves can be recommended by the glove
supplier. Polyvinyl chloride (PVC). Nitrile.

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General: Because specific work environments and material handling practices vary,
safety procedures should be specific for each intended application. The
correct choice of protective gloves depends upon the chemicals being
handled, and the conditions of work and use. Most gloves provide
protection for only a limited time before they must be discarded and
replaced (even the best chemically resistant gloves will break down after
repeated chemical exposures). Gloves should be chosen in consultation
with the supplier / manufacturer and taking account of a full assessment of
the working conditions. For typical use and handling of chemical
substances, gloves should meet the standards set out in EN 374. For
applications involving mechanical risks with potential for abrasion or
puncture, the standards set out in EN 388 should be considered. For tasks
involving thermal hazards, the standards set out in EN 407 should be
considered.

Break-through time: Breakthrough time data are generated by glove manufacturers under
laboratory test conditions and represent how long a glove can be expected
to provide effective permeation resistance. It is important when following
breakthrough time recommendations that actual workplace conditions are
taken into account. Always consult with your glove supplier for up-to-date
technical information on breakthrough times for the recommended glove
type.
For continuous contact, we suggest gloves with a minimum breakthrough
time of 240 minutes, or > 480 minutes if suitable gloves can be obtained. If
suitable gloves are not available to offer that level of protection, gloves with
shorter breakthrough times may be acceptable as long as appropriate glove
maintenance and replacement regimes are determined and adhered to.
For short-term, transient exposures and splash protection, gloves with
shorter breakthrough times may commonly be used. Therefore, appropriate
maintenance and replacement regimes must be determined and rigorously
followed.

Glove thickness: For general applications, we recommend gloves with a thickness typically
greater than 0.35 mm.
It is important to note that glove thickness is not the only predictor of glove
resistance to a specific chemical, as the permeation efficiency of the glove
will be dependent on the exact composition of the glove material.
Therefore, glove selection should also be based on consideration of the
task requirements and knowledge of breakthrough times.
Glove thickness may also vary depending on the glove manufacturer, the
glove type and the glove model. Therefore, the manufacturers’ technical
data should always be taken into account to ensure selection of the most
appropriate glove for the task.
Note: Depending on the activity being conducted, gloves of varying
thickness may be required for specific tasks. For example: Thinner gloves
(down to 0.1 mm or less) may be required where a high degree of manual
dexterity is needed. However, these gloves are only likely to give short
duration protection and would normally be just for single use applications,
before being disposed of. Thicker gloves (up to 3 mm or more) may be
required where there is a mechanical (as well as a chemical) risk i.e. where
there is abrasion or puncture potential.

Other: Long sleeve shirt is recommended. Wear apron or protective clothing in

case of contact.

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Respiratory Protection: Use respirator with an organic vapor cartridge if exposure limit is
exceeded. Use self-contained breathing apparatus for entry into confined
space, for other poorly ventilated areas and for large spill clean-up sites.
Consult with an industrial hygienist to determine the appropriate
respiratory protection for your specific use of this material. A respiratory
protection program compliant with all applicable regulations must be
followed whenever workplace conditions require the use of a respirator.

Respiratory Protective Equipment (RPE) is not normally required where

there is adequate natural or local exhaust ventilation to control exposure.
In case of insufficient ventilation, wear suitable respiratory equipment.
The correct choice of respiratory protection depends upon the chemicals
being handled, the conditions of work and use, and the condition of the
respiratory equipment.
Safety procedures should be developed for each intended application.
Respiratory protection equipment should therefore be chosen in
consultation with the supplier/manufacturer and with a full assessment of
the working conditions.
Please refer to the relevant EN standards for the RPE selected.

Hygiene measures: Always observe good personal hygiene measures, such as washing after
handling the material and before eating, drinking, and/or smoking. Routinely
wash work clothing to remove contaminants. Discard contaminated
footwear that cannot be cleaned.

Environmental No data available.

Controls: See section 6 for details.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance
Physical state: liquid
Form: liquid
Color: Colorless to yellow
Odor: Mild
Odor Threshold: No data available.
pH: No data available.
Freezing point: No data available.
Boiling Point: No data available.
Flash Point: 240 °C (Cleveland Open Cup)
Evaporation Rate: No data available.
Flammability (solid, gas): No data available.
Upper/lower limit on flammability or explosive limits
Flammability Limit - Upper (%): No data available.
Flammability Limit - Lower (%): No data available.
Vapor pressure: No data available.
Vapor density (air=1): No data available.
Relative density: 0.981 (20 °C)
Solubility(ies)
Solubility in Water: Slightly Soluble
Solubility (other): No data available.
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Partition coefficient (n-octanol/water): No data available.

Autoignition Temperature: No data available.
Decomposition Temperature: No data available.
Viscosity: 31.2 mm2/s (40 °C); 5.6 mm2/s (100 °C )
Explosive properties: No data available.
Oxidizing properties: No data available.
VOC Content: No data available.

Other information
Pour Point Temperature: -56 °C

SECTION 10: Stability and reactivity

10.1 Reactivity: No data available.

10.2 Chemical Stability: Material is stable under normal conditions.

10.3 Possibility of hazardous Will not occur.

reactions:

10.4 Conditions to avoid: Do not expose to excessive heat, ignition sources, or oxidizing materials.

10.5 Incompatible Materials: Strong oxidizing agents. Strong acids. Oxidizing agents. Strong bases.

10.6 Hazardous Thermal decomposition or combustion may generate smoke, carbon

Decomposition Products: monoxide, carbon dioxide, and other products of incomplete combustion.

SECTION 11: Toxicological information

Information on likely routes of exposure

Inhalation: No data available.

Ingestion: No data available.

Skin Contact: No data available.

Eye contact: No data available.

11.1 Information on toxicological effects

Acute toxicity
Oral
Product: Not classified for acute toxicity based on available data.

Dermal
Product: Not classified for acute toxicity based on available data.

Inhalation
Product: Not classified for acute toxicity based on available data.

Skin Corrosion/Irritation:
Product: Remarks: Prolonged or repeated contact may cause irritation. Not
classified as a primary skin irritant.

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Serious Eye Damage/Eye Irritation:

Product: Remarks: Not classified as a primary eye irritant.

Respiratory sensitization:
No data available

Skin sensitization:
No data available

Specific Target Organ Toxicity - Single Exposure:

No data available

Aspiration Hazard:
No data available

Chronic Effects
Carcinogenicity:
No data available

Germ Cell Mutagenicity:

No data available

Reproductive toxicity:
No data available

Specific Target Organ Toxicity - Repeated Exposure:

No data available

SECTION 12: Ecological information

12.1 Ecotoxicity
Fish
No data available

Aquatic Invertebrates
No data available

Toxicity to Aquatic Plants

No data available

Toxicity to soil dwelling organisms

No data available

Sediment Toxicity
No data available

Toxicity to Terrestrial Plants

No data available

Toxicity to Above-Ground Organisms

No data available

Toxicity to microorganisms
No data available

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12.2 Persistence and Degradability

Biodegradation
No data available

BOD/COD Ratio
No data available

12.3 Bioaccumulative potential

Bioconcentration Factor (BCF)
No data available

Partition Coefficient n-octanol / water (log Kow)

No data available

12.4 Mobility:
No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Other adverse effects

No data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Disposal methods: Treatment, storage, transportation, and disposal must be in accordance

with applicable Federal, State/Provincial, and Local regulations.
Since emptied containers retain product residue, follow label warnings even
after container is emptied.

Contaminated Packaging: Container packaging may exhibit hazards.

SECTION 14: Transport information

ADR
Not regulated.

IMDG
Not regulated.

IATA
Not regulated.

14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
None known.

Shipping descriptions may vary based on mode of transport, quantities, temperature of the material, package size, and/or
origin and destination. It is the responsibility of the transporting organization to follow all applicable laws, regulations and
rules relating to the transportation of the material. For transportation, steps must be taken to prevent load shifting or materials
falling, and all relating legal statutes should be obeyed. Review classification requirements before shipping materials at
elevated temperatures.

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SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture:

EU Regulations
Regulation (EC) No. 2037/2000 Substances that deplete the ozone layer:
None present or none present in regulated quantities.

Regulation (EC) No. 850/2004 on persistent organic pollutants:

None present or none present in regulated quantities.

Regulation (EC) No. 649/2012 Import and export of dangerous chemicals:

None present or none present in regulated quantities.

Regulation (EC) No. 1907/2006, REACH Article 59(1). Candidate List:

None present or none present in regulated quantities.

Regulation (EC) No. 1907/2006, REACH Annex XIV Substances subject to authorisation, as amended:
None present or none present in regulated quantities.

Regulation (EC) No. 1907/2006 Annex XVII Substances subject to restriction on marketing and use:
None present or none present in regulated quantities.

Directive 2004/37/EC on the protection of workers from the risks related to exposure to carcinogens
and mutagens at work.:
None present or none present in regulated quantities.

Directive 92/85/EEC: on the safety and health of pregnant workers and workers who have recently
given birth or are breast feeding.:
None present or none present in regulated quantities.

Directive 2012/18/EU (Seveso III): on the control of major accident hazards involving dangerous
substances:
None present or none present in regulated quantities.

EU. Regulation No. 166/2006 PRTR (Pollutant Release and Transfer Registry), Annex II: Pollutants:
None present or none present in regulated quantities.

Directive 98/24/EC on the protection of workers from the risks related to chemical agents at work:
None present or none present in regulated quantities.

Inventory Status

Australia (AICS)
All components are in compliance with chemical notification requirements in Australia.

Canada (DSL/NDSL)
All substances contained in this product are in compliance with the Canadian Environmental
Protection Act and are present on the Domestic Substances List (DSL) or are exempt.

China (IECSC)
All components of this product are listed on the Inventory of Existing Chemical Substances in
China.

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European Union (REACh)

To obtain information on the REACH compliance status of this product, please e-mail
[email protected].

Japan (ENCS)
All components are in compliance with the Chemical Substances Control Law of Japan.

Korea (ECL)
All components are in compliance in Korea.

New Zealand (NZIoC)

All components are in compliance with chemical notification requirements in New Zealand.

Philippines (PICCS)
All components are in compliance with the Philippines Toxic Substances and Hazardous and
Nuclear Wastes Control Act of 1990 (R.A. 6969).

Switzerland (SWISS)
All components are in compliance with the Environmentally Hazardous Substances Ordinance in
Switzerland.

Taiwan (TCSCA)
All components of this product are listed on the Taiwan inventory.

United States (TSCA)

All substances contained in this product are listed on the TSCA inventory or are exempt.

The information that was used to confirm the compliance status of this product may deviate from the chemical
information shown in Section 3.

15.2 Chemical safety No Chemical Safety Assessment has been carried out.
assessment:

SECTION 16: Other information

Key literature references and Internal company data and other publically available resources.
sources for data:

Wording of the H-statements in section 2 and 3: none

Other information:

Abbreviations and acronyms:

ACGIH – American Conference of Governmental Industrial Hygienist
ADR - International Carriage of Dangerous Goods by Road
AICS - Australian Inventory of Chemical Substances
ATEmix - Acute Toxicity Estimate for the mixture
BCF - Bio concentration factor
DMSO - Dimethyl sulfoxide
DSL - Domestic Substance List
EC50 - Effective concentration that gives a response in 50% of the population
ECHA - European Chemical Agency
ECL - Existing Chemical List
ENCS - Existing and New Chemical Substances
EPA – Environmental Protection Agency
IARC - International Agency for Research on Cancer

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IATA - International Air Transport Association

IECSC - Inventory of Existing Chemical Substances
IMDG - International Maritime Dangerous Goods
IP 346 – A gravimetric assay used to determine the percentage weight of polycyclic aromatics in oil, via
a DMSO extraction technique
LC50 - Lethal concentration required to kill 50% of the population
MARPOL - International Conventions for the Prevention of Pollution from Ships
NDSL - Non Domestic Substance List
NOAEC - No observed adverse effect concentration
NOAEL - No observed adverse effect level
NOEC - No observed effective concentration
NTP - National Toxicology Program
NZloc - New Zealand Inventory of chemicals
OECD TG - Organization for Economic Cooperation and Development Test Guidelines
OSHA – Occupational, Safety, and Health Administration
PBT – Persistent bioaccumulative toxic chemical
PEL – Permissible Exposure Level
PICCS - Philippine Inventory of Chemicals and Chemical Substances
PPE - Personal Protective Equipment
PRTR - Pollutant Release and Transfer Register
REACH - Registration, Evaluation, Authorization & restriction of Chemicals
SVHC - Substance of Very High Concern
SWISS - Switzerland chemical ordinance
TCSCA - Toxic Chemical Substance Control Act
TLV – Threshold Limit Value
TSCA - Toxic Substances Control Act
TWA – Time Weighted Average
vPvB – very Persistent very Bioaccumulative

Issue Date: 08.10.2019

Disclaimer: As the conditions or methods of use are beyond our control, we do not
assume any responsibility and expressly disclaim any liability for any use of
this product. Information contained herein is believed to be true and accurate
but all statements or suggestions are made without warranty, expressed or
implied, regarding accuracy of the information, the hazards connected with
the use of the material or the results to be obtained from the use thereof.
Compliance with all applicable federal, state, and local regulations remains
the responsibility of the user.

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