OSHA NIOSH ASTM Sampling-Methods Guide

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Sampling Guide

skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Acenaphthene (Polynuclear Aromatic ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Hydrocarbons by GC-MS) (max)

Acenaphthene (Polynuclear Aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Acenaphthene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Acenaphthylene (Polynuclear Aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Acenaphthylene (Polynuclear Aromatic ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Hydrocarbons by GC-MS) (max)

Acenaphthylene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Acetaldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

Acetaldehyde NIOSH 2538 LFC 10 20 8 GC-FID ST 226-27 48

Acetaldehyde NIOSH 3507 LFC 60 125 8 HPLC IMP 225-36-2 70 IT 225-22 70

Acetaldehyde OSHA 68 200 3 0.75 50 50 1 15 GC-NPD ST 226-27 48

Acetaldehyde (Aldehydes, Screening) NIOSH 2539 LFC 5 10 8 GC-FID & ST 226-118 50


GC-MS

Acetamide OSHA PV2084 10 20(50) 8(3.3) GC-NPD ST 226-10 48

Acetates (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 52

Acetic acid EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Acetic acid NIOSH 1603 10 15 24 50 8 GC-FID ST 226-01 48

Acetic acid OSHA PV2119 48 200 4 IC or GC- ST 226-01 48


FID

Acetic anhydride NIOSH 3506 5 90 1000 1.5 VAS IMP 225-36-2 70 IT 225-22 70

Acetic anhydride OSHA 102 5 7.5 7.5 50 500 2.5 15 GC-NPD CF/CST 225-9010 68 C/HLD 225-1 116

Acetoin NIOSH 2558 1-10 10-200 varies GC-FID ST 226-183 51

Acetoin (acetyl methyl carbinol) OSHA 1012 0.05 9 3 50 200 3 15 GC-FID ST 226-183 51

Acetone ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

Acetone Internal 15.2 ml/min 8-24 hrs SE, GC PS 690-105 96

Acetone OSHA 69 1000 3 50 1 GC-FID ST NA SKC

Acetone (Ketones I) NIOSH 1300 250 2 0.75 20 50 100 min 15 GC-FID ST 226-01 48

Acetone (Ketones I) NIOSH 2555 0.5 - 3 10-200 varies GC-FID ST NA SKC

Acetonitrile EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Acetonitrile NIOSH 1606 20 10 20(50) 8(3.3) GC-FID ST 226-09 48

Acetophenone OSHA PV2003 12 100 2 GC-FID ST 226-35 48

Acetyl methyl carbinol (acetoin) NIOSH 2558 1-10 10-200 varies GC-FID ST NA SKC

Acetylene tetrabromide (1,1,2,2-tetrabromoethane) NIOSH 2003 96 200 8 GC-FID ST 226-10 48

Acid blue 9 OSHA PV2129 100 1000 100 min HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

Acridine OSHA 58 0.2 mg/m 3


960 2000 8 GR & HPLC- FLT 225-7 110 CST 225-2LF 115
FD, or GR & C/HLD 225-1 116
HPLC-UV

Acrolein NIOSH 2501 0.1 0.3 24 3 50 200 8 15 GC-NPD ST 226-118 50

Acrolein OSHA 52 0.1 48 3 100 200 8 15 GC-NPD ST 226-117 50

Acrolein (Aldehydes, Screening) NIOSH 2539 0.1 0.3 5 10 8 GC-FID & ST 226-118 50
GC-MS

Acrylamide OSHA PV2004 0.3 mg/m3 120 1000 2 HPLC-UV ST 226-57 49

Acrylic acid NON 10 48 100 8 GC ST 226-70A 49

Acrylic acid NON 60 24 100 4 HPLC-UV ST 226-30-08 48

Acrylic acid OSHA PV2005 2 20 100 4 LC-UV ST 226-30-08 48

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 187


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Acrylonitrile EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Acrylonitrile Internal 20.4 ml/min 8-24 hrs TD, GC PS 690-101 96

Acrylonitrile Internal 20.4 ml/min 8-24 hrs SE, GC PS 690-105 96

Acrylonitrile NIOSH 1604 1 10 (15 min) 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 48

Acrylonitrile OSHA 37 2 10 20 6 200 400 100 min 15 GC-NPD ST 226-01 48

Actinomycetes, thermophilic NIOSH 0800 varies 28,300 varies varies BI 225-9611 136

Aerobic bacteria (by GC-FAME) NIOSH 0801 50-300 28300 varies GC-FID BI 225-9611 136

Alcohols (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 52

Alcohols combined NIOSH 1405 varies varies varies varies 10-200 10-200 varies varies GC-FID ST 226-01 48

Alcohols I (see specific compounds) NIOSH 1400 varies varies varies varies GC-FID ST 226-01 48

Alcohols II (see specific compounds) NIOSH 1401 varies varies varies 8 GC-FID ST 226-01 48

Alcohols III (see specific compounds) NIOSH 1402 varies varies varies 8 GC-FID ST 226-01 48

Alcohols IV (see specific alcohol) NIOSH 1403 varies varies varies varies GC-FID ST 226-01 48

Aldehydes EPA TO-5 < 80 L 100-1000 ml/min HPLC-UV IMP 225-36-1 70 IT 225-22 70

Aldehydes (screening) NIOSH 2539 varies 5 20 4 GC-FID & ST 226-118 50


GC-MS

Aldehydes (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 52

Aldicarb (Organonitrogen Pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Aldicarb (Temik) OSHA 74 480 1000 8 GC-NPD ST 226-30-16 48

Aldrin ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Aldrin NIOSH 5502 0.25 mg/m3 240 500 8 GC-ECN F/CST 225-709 110 IMP 225-36-2 70
IT 225-22 70 C/HLD 225-1 116

Aliphatic hydrocarbons (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 52

Alkaline dusts NIOSH 7401 30 2000 15 TITRA F/CST 225-1715 108 C/HLD 225-1 116

Allethrin ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Allyl alcohol OSHA PV2140 2 (skin) 10 50 200 min GC-FID ST 226-01 48

Allyl alcohol (Alcohols Combined) NIOSH 1405 2 4 (skin) 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 48

Allyl alcohol (Alcohols III) NIOSH 1402 2 10 3 200 200 GC-FID ST 226-01 48

Allyl chloride NIOSH 1000 1 2 15 1000 15 GC-FID ST 226-01 48

Allyl glycidyl ether NIOSH 2545 5 10 6 3 50 200 2 15 GC-FID ST 226-35-03 48

Allyl propyl disulfide OSHA PV2086 2 10 20(50) 8(3.3) GC-FPD ST 226-110 50

Alumina (aluminum & compounds [total dust as Al]) NIOSH 7013 10 mg/m3 360 1000 6 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Alumina (particulates, respirable) NIOSH 0600 375 2500 2.5 GR CYC 225-01-02 127 C/HLD 225-1 116
F/CST 225-803 107

Alumina (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

alpha-Alumina (respirable fraction) OSHA PV2121 5 mg/m3 varies varies varies GR CYC 225-105 126 F/CST 225-803 107
C/HLD 225-1 116

alpha-Alumina (total dust) OSHA PV2121 15 mg/m3 960 2000 4-8 GR F\CST 225-802 107 C/HLD 225-1 116
CST 225-2LF 115

Aluminum (Elements by Cellulosic Internal NIOSH 7306 10 mg/m3 5 mg/m3 1-330 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Capsule Sampler) (total dust) (respirable)

Aluminum & compounds (total dust as Al) NIOSH 7013 10 mg/m3 360 1000 6 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Aluminum (Elements by ICP Aqua Regia Ashing) NIOSH 7301 10 mg/m 3


5-100 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 107
(total dust) C/HLD 225-1 116

Aluminum (Elements by ICP HNO3 Digestion) NIOSH 7303 10 mg/m3 (total dust) 2-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
5 mg/m3 (respirable fume)

Aluminum (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 10 mg/m3 (total dust) 5-100 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
5 mg/m3 (respirable dust)

Aluminum (respirable fraction) OSHA PV2121 5 mg/m3 varies varies varies GR F/CST 225-803 107 CYC 225-105 126
C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

188 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Aluminum (total dust) OSHA PV2121 15 mg/m3 480-960 2000 4-8 GR F/CST 225-802 107 C/HLD 225-1 116
CST 225-2LF 115

Aluminum soluble salts OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Amines NIOSH 2002 varies 20 40 8 GC-FID or ST 226-10 48


GC-NSD

Amines, aliphatic NIOSH 2010 varies 24 50 8 GC-FID ST 226-10 48

2-Amino-2-methy-1-propanol OSHA PV2145 10 100 100 min HPLC-UV ST 226-30-16 48

4-Aminobiphenyl OSHA 93 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

2-Aminoethanol NIOSH 2007 3 6 10 20 8 GC-FID ST 226-10-04 48

2-Aminoethanol NIOSH 3509 3 6 240 1000 4 IC IMP 225-36-1 70 IT 225-22 70

2-Aminoethanol OSHA PV2111 3 10 1.5 100 100 100 min 15 HPLC-UV ST 226-30-18 48

Aminoethanol compounds I (see specific NIOSH 2007 varies varies varies 8 GC-FID ST 226-10-04 48
compounds)

Aminoethanol compounds II (see specific NIOSH 3509 varies 240 1000 4 IC IMP 225-36-1 70 IT 225-22 70
compounds)

Aminoethylethanolamine OSHA PV2116 10 100 HPLC-UV ST 226-30-18 48

p-Aminophenylarsonic acid (arsenic, organo-) NIOSH 5022 960 2000 8 IC-AA FLT 225-17-01 108 CST 225-3LF 115
C/HLD 225-1 116

2-Aminopyridine OSHA PV2143 0.5 240 1000 4 GC-NPD CF/CST 225-9004 68 C/HLD 225-1 116

3-Aminopyridine OSHA PV2143 240 1000 4 GC-NPD CF/CST 225-9004 68 C/HLD 225-1 116

4-Aminopyridine OSHA PV2143 240 1000 4 GC-NPD CF/CST 225-9004 68 C/HLD 225-1 116

Amitrole OSHA PV2006 60 1000 1 HPLC-UV IMP 225-36-1 70 IT 225-22 70

Ammonia NIOSH 6015 25 35 72 3 150 200 8 15 VAS ST 226-10-06 48 F/CST 225-3-01 102

Ammonia NON 41 18 5 75 500 4 10 CLR ST 226-61 49

Ammonia OSHA ID 188 50 24 7.5 100 500 4 15 IC-CD ST 226-29 48

Ammonia (by IC) NIOSH 6016 25 35 48 3 100 200 8 15 IC ST 226-10-06 48 F/CST 225-3-01** 102

Ammonium chloride (fume) OSHA ID 188 960 30 2000 2000 8 15 IC-CD F/CST 225-3-01 102 C/HLD 225-1 116

Ammonium hydroxide (see ammonia)

Ammonium metavanadate (see vanadium oxides) NIOSH 7504

sec-Amyl acetate (2-pentyl acetate) NIOSH 1450 125 10 200 50 (min) GC-FID ST 226-01 48

n-Amyl acetate (Esters I) NIOSH 1450 100 1-10 10-200 varies GC-FID ST 226-01 48

t-Amyl methyl ether (methyl tert-amyl ether) Internal 13.1 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

t-Amyl methyl ether (methyl tert-amyl ether) Internal 13.1 ml/min 8-24 hrs SE, GC PS 690-105 96

Aniline NIOSH 2017 LFC 24 200 2 GC-FID CF/CST 225-9004 68 ST 226-15 48

Aniline OSHA PV2079 5 24 50 8 GC-FID ST 226-98 50

Aniline (Amines, Aromatic) NIOSH 2002 LFC 24 50 8 GC-FID or ST 226-10 48


GC-NSD

Anisidine NIOSH 2514 0.5 mg/m3 240 1000 4 HPLC-UV ST 226-30-05 48

Anthophyllite fibers (see asbestos fibers) NIOSH 7400

Anthracene OSHA 58 0.2 mg/m3 960 2000 8 GR & HPLC- FLT 225-7 110 CST 225-2LF 115
FD, or GR & C/HLD 225-1 116
HPLC-UV

Anthracene (Polynuclear Aromatic Hydrocarbons ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
by GC-MS) (max)

Anthracene (Polynuclear Aromatic Hydrocarbons NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
by GC) C/HLD 225-1 116

Anthracene (Polynuclear Aromatic Hydrocarbons NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 108 ST 226-30-04 48
by HPLC) C/HLD 225-1 116

Antimony & compounds (as Sb) OSHA ID 121 0.5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Antimony & compounds (as Sb) OSHA ID 125G 0.5 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 189


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Antimony (Elements by Cellulosic Internal Capsule NIOSH 7306 0.05 mg/m3 1-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Antimony (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.5 mg/m3 50-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Antimony (Elements by ICP HNO3 Digestion) NIOSH 7303 0.5 mg/m3 3-100,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Antimony (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.5 mg/m3 50-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Antimony (ICP Analysis of Metal/metalloid OSHA ID 206 0.5 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
Particulates from Solder Operations)

Apron OSHA PV2102 60 1000 1 HPLC-UV F/CST 225-709 110 C/HLD 225-1 116

Aroclor ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Aroclor NIOSH 5602 480 1000 8 GC-ECD ST 226-58 49

Aroclor 1242 ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Aroclor 1242 (42% Cl) (see polychlorobiphenyls) NIOSH 5503

Aroclor 1254 ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Aroclor 1254 (54% Cl) (see polychlorobiphenyls) NIOSH 5503

Aroclor 1260 ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Aromatic hydrocarbons (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 52

Arsenic (Elements by Cellulosic Internal Capsule NIOSH 7306 0.002 mg/m 3


32-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Arsenic & compounds (as As) NIOSH 7900 2 µg/m3 (15 min) 30 2000 15 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Arsenic (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.002 mg/m3 5-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Arsenic (Elements by ICP HNO3 Digestion) NIOSH 7303 0.002 mg/m3 8-5,000,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Arsenic (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.002 mg/ 5-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
m3 (C)

Arsenic (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Arsenic (inorganic compounds as As) OSHA 1006 0.01 mg/m3 480 2000 4 ICP-MS F/CST 225-3-01 102 C/HLD 225-1 116

Arsenic trioxide as AS NIOSH 7901 2 mg/m3 30 2000 15 AAS-GF FLT 225-5 ‡ 102 CST 225-2LF 115
(15 min) C/HLD 225-1 116

Arsenic, inorganic (volatile compounds as As) OSHA 1006 0.01 mg/m3 480 2000 4 ICP-MS CF/CST 225-9001 68 C/HLD 225-1 116

Arsenic, organo NIOSH 5022 960 2000 8 IC-AA FLT 225-17-01 108 CST 225-2LF 115
C/HLD 225-1 116

Arsine NIOSH 6001 2 µg/m3 (15 min) 10 3 20 200 8 15 AAS-GF ST 226-01 48

Arylam (see carbaryl)

Asbestos OSHA ID 160 0.1 fbr/cc 1 fbr/cc EL 25-1200 25-1200 500-2500 500-2500 varies varies PCM FLT/CL 225-321 or FLT/CL 225-326 or
FLT/CL 225-321A or FLT/CL 225-327 104

Asbestos ([bulk] by PLM) NIOSH 9002 1% (bulk) bulk PLM

Asbestos (by TEM) NIOSH 7402 0.1 fbr/ 960 2000 8 TEM FLT/CL 225-327 104
cc/400L

Asbestos (chrysotile) NIOSH 9000 bulk XRD

Asbestos (structure number concentrations) ASTM D 5755 varies 2000 2 min TEM MVC 225-322 173
(minimum)

Asbestos fibers NIOSH 7400 0.1 fbr/ varies varies varies PCM FLT/CL 225-321 or FLT/CL 225-326 or
cc/400L FLT/CL 225-321A or FLT/CL 225-327 104

Aspartame NIOSH 5031 480 1000 8 HPLC-UV FLT 225-17-01 108 CST 225-2LF 115
C/HLD 225-1 116

Asphalt fume (benzene-soluble & total particulate) NIOSH 5042 5 mg/m3 360 60 1000 4000 6 15 GR FLT 225-37-07 108 SP 225-27 117
(15 min) (C) CST 225-2LF 115 C/HLD 225-1 116

Asphalt fume particulate ASTM D 6494 960 2000 8 GR F/CST 225-1713 108 C/HLD 225-1 116

Asphalt fumes (petroleum) OSHA 58 960 2000 8 GR & HPLC- FLT 225-7 110 CST 225-2LF 115
FD, or GR & C/HLD 225-1 116
HPLC-UV

Atrazine ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 54

Atrazine NIOSH 5602 5 480 1000 8 GC-ECD ST 226-58 49

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

190 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Azelaic acid NIOSH 5019 960 2000 8 GC-FID F/CST 225-803 107 C/HLD 225-1 116

Azinphos-methyl OSHA PV2087 0.2 mg/m3 480 1000 8 GC-FPD ST 226-30-16 48

Azinphos-methyl (Organophosphorus Pesticides) NIOSH 5600 0.2 mg/m3 240 1000 4 GC-FPD ST 226-58 49

Bacteria NIOSH 0800 varies 28,300 varies varies BI 225-9611 136

Bacteria (by GC-FAME) NIOSH 0801 50-300 28300 varies GC-FID BI 225-9611 136

Bacteria (in air) NON 48 62.5-375 12,500 + 5-30 varies BS 225-9595 138 VT 225-9598A ◊ 138

Barium (Elements by Cellulosic Internal Capsule NIOSH 7306 3-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Barium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.5 mg/m3 50-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Barium (Elements by ICP HNO3 Digestion) NIOSH 7303 1-100,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Barium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172


TMP 225-2415 172

Barium (insoluble compounds) OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Barium (soluble compounds) NIOSH 7056 0.5 mg/m3 960 2000 8 AA F/CST 225-3-01 102 C/HLD 225-1 116

Barium (soluble compounds) OSHA ID 121 0.5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Barium chloride (barium, soluble compounds) NIOSH 7056 0.5 mg/m3 960 2000 8 AA F/CST 225-3-01 102 C/HLD 225-1 116

Barium sulfate (total dust) OSHA ID 121 15 mg/m 3


960 2000 8 AA or AES F/CST 225-802 107 C/HLD 225-1 116

Baygon (propoxur) ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Baygon (propoxur) OSHA PV2007 48 100 8 HPLC-UV ST 226-30-16 48

Bendiocarb ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Bendiocarb (Ficam ) OSHA PV2008 240 1000 4 HPLC-UV ST 226-30-16 48

Benomyl (Organonitrogen Pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Benomyl (respirable dust) OSHA PV2107 5 mg/m3 varies varies varies HPLC-UV ST 226-30-16 48 CYC 225-105 126

Benomyl (total dust) OSHA PV2107 15 mg/m3 60 1000 1 HPLC-UV ST 226-30-16 48

Bentonite (see Particulates Not Otherwise


Regulated, total and respirable)

Benz(a)anthracene OSHA In 960 2000 HPLC-UV F/CST 225-709 110 C/HLD 225-1 116
House File

Benz(a)anthracene (Polynuclear Aromatic ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Hydrocarbons by GC-MS) (max)

Benz(a)anthracene (Polynuclear Aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Benz(a)anthracene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Benzaldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

Benzene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Benzene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Benzene Internal 16.0 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Benzene Internal 0.78 ml/min 24 hrs to 7 TD, GC PS 690-101 or PS 690-103 with


days RR 690-300 96

Benzene Internal 16.0 ml/min 8 hrs-30 SE, GC PS 690-105 96


days

Benzene OSHA 1005 1 5 8 15 GC-FID PS 575-002 82

Benzene OSHA 1005 1 5 12 0.75 50 50 4 15 GC-FID ST 226-01 48

Benzene OSHA 1005 1 5 12 0.5 50 50 240 min 10 GC-FID ST 226-01 48

Benzene (by portable GC) NIOSH 3700 0.1 1 (15 min) varies 20-5000 varies P GC-PID SB 232 Series 61

Benzene (Hydrocarbons, Aromatic) NIOSH 1501 0.1 1 5-30 5-30 10-200 10-200 varies varies GC-FID ST 226-01 48

alpha-Benzene hexachloride ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

beta-Benzene hexachloride ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

gamma-Benzene hexachloride ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

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Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Benzene-soluble & total particulate (asphalt fume) NIOSH 5042 5 mg/m3 360 60 1000 4000 6 15 GR FLT Contact SKC 108 SP 225-27 117
(15 min) (C) CST 225-2LF 115

Benzene-soluble particulate matter ASTM D 4600 960 2000 8 GR FLT 225-7 110 SP 225-27 117
CST 225-2LF 115 C/HLD 225-1 116

Benzidine NIOSH 5509 LFC 96 200 8 HPLC-UV FLT 225-16 110 CST 225-32 116

Benzidine OSHA 65 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

Benzidine dyes (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17P 108 CST 225-3LF 115
C/HLD 225-1 116

Benzidine-based dyes OSHA 65 100 15 1000 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

Benzo(a)pyrene (Polynuclear Aromatic NIOSH 5515 0.1 mg/m3 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Benzo(a)pyrene (Polynuclear Aromatic ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Hydrocarbons by GC-MS) (max) PEM 761-200B 132 FLT 225-1709 108

Benzo(a)pyrene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Benzo(b)fluoranthene (Polynuclear Aromatic ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Hydrocarbons by GC-MS) PEM 761-203B 132 FLT 225-1709 108

Benzo(b)fluoranthene (Polynuclear Aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Benzo(b)fluoranthene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Benzo(e)pyrene (Polynuclear Aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Benzo(e)pyrene (Polynuclear Aromatic ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Hydrocarbons by GC-MS)

Benzo(e)pyrene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Benzo(g,h,i)perylene (Polynuclear Aromatic ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Hydrocarbons by GC-MS)

Benzo(g,h,i)perylene (Polynuclear Aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Benzo(g,h,i)perylene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Benzo(k)fluoranthene (Polynuclear Aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Benzo(k)fluoranthene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Benzoalphapyrene OSHA 58 0.2 mg/m3 960 2000 8 GR & HPLC- FLT 225-7 110 CST 225-2LF 115
FD, or GR & C/HLD 225-1 116
HPLC-UV

Benzophenone NON 39 480 1000 8 GC-FID ST 226-56 49

Benzophenone OSHA PV2130 0.5 mg/m3 48 200 4 GC-FID ST 226-110 50

Benzothiazole in asphalt fume NIOSH 2550 480 1000 8 GC-SCD F/CST 225-1713 108 ST 226-30-04 48
C/HLD 225-1 116

Benzoyl peroxide NIOSH 5009 5 mg/m3 90 1500 1 HPLC-UV F/CST 225-3-01 102 C/HLD 225-1 116

Benzyl acetate OSHA PV2124 10 100 100 min GC-FID ST 226-73 49

Benzyl alcohol OSHA PV2009 24 100 4 GC-FID ST 226-95 50

Benzyl chloride ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Benzyl chloride (hydrocarbons, halogenated) NIOSH 1003 1 10 10-200 varies GC-FID ST 226-01 48

Beryllium & compounds OSHA ID 125G 0.2 µg/m3 2.0 µg/m3 480 60 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Beryllium & compounds (as Be) NIOSH 7102 0. 5 µg/m3 960 2000 8 AA-GF F/CST 225-3-01 102 C/HLD 225-1 116

Beryllium & compounds (as Be) OSHA 1023 0.2 µg/m3 2.0 µg/m3 480 30 2000 2000 4 15 ICP-AES FLT 225-5 102 CST 225-2LF 115
SM TB 225-24 172

Beryllium (Elements by Cellulosic Internal Capsule NIOSH 7306 0.0005 0.005 mg/ 10-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler) mg/m3 m3

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

192 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Beryllium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.0005 1250-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 107
mg/m3 C/HLD 225-1 116

Beryllium (Elements by ICP HNO3 Digestion) NIOSH 7303 35- 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
25,000,000

Beryllium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.0005 1250-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
mg/m3

Beryllium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Beryllium (ICP analysis of metal/metalloid OSHA ID 206 0.2 µg/m3 2.0 µg/m3 480 10 2000 2000 4 5 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
particulates from solder operations)

Beryllium (in air by portable fluorometry) NIOSH 7704 2 mg/m3 5 mg/m3 (C) 240-2000 1000-4000 P FLUOR F/CST 225-3-01 or F/CST 225-3100 102
UV/VIS C/HLD 225-1 116

BHC (alpha-, beta-, gamma-) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Bioaerosol sampling NIOSH 0800 varies 28,300 varies varies BI 225-9611 136

Bioaerosols 15-150 15000 1-10 min varies STC 225-9820 114

Bioaerosols NON 48 62.5-375 12,500 + 5-30 varies BS 225-9595 138 VT 225-9598A 138

Biphenyl (diphenyl) NIOSH 2530 0.2 10 20(50) 8(3.3) GC-FID ST 226-35-01 48

4,4’-Bipyridine (vapor & aerosol) NON 26 96 2 200 200 8 10 HPLC ST 226-30-05 48 F/CST 225-706 110
C/HLD 225-1 116

Bismuth OSHA ID 121 480-960 2000 4-8 AAS/AES F/CST 225-3-01 102 C/HLD 225-1 116

Bismuth (Elements by ICP HNO3 Digestion) NIOSH 7303 1-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Bismuth telluride, Se-doped OSHA ID 121 5 mg/m 3


960 2000 8 AA or AES FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Bismuth telluride, undoped (respirable dust) OSHA ID 121 5 mg/m3 varies varies varies GR & AA or CYC 225-105 126 C/HLD 225-1 116
GR & AES F/CST 225-803 107

Bisphenol A OSHA 1018 240 1000 240 (min) HPLC-UV/ F/CST 225-709 110 C/HLD 225-1 116
PDA

Borates tetrasodium salts (anhydrous, decahydrate OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
& pentahydrate) F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Boron (Elements by ICP HNO3 Digestion) NIOSH 7303 1-3,300 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Boron carbide NIOSH 7506 600 2500 4 XRD F/CST 225-803 107 C/HLD 225-1 116
CYC 225-01-02 127

Boron oxide (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Boron oxide (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Bromine NIOSH 6011 0.1 0.3 240 15 1000 1000 4 15 IC CF/CST 225-9006 68 C/HLD 225-1 116

Bromine OSHA ID 108 0.1 120 7.5 500 500 4 15 IC IMP 225-36-2 70 IT 225-22 70

Bromoethane (ethyl bromide) NIOSH 1011 4 20(50) 3.3(1.3) GC-FID ST 226-01 48

Bromoform (hydrocarbons, halogenated) NIOSH 1003 0.5 (skin) 10 10-200 varies GC-FID ST 226-01 48

1-Bromopropane Internal 14.4 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

1-Bromopropane Internal 14.4 ml/min 8-24 hrs SE, GC PS 690-105 96

1-Bromopropane NIOSH 1025 0.1-12 10-200 varies GC-FID ST 226-01 48

1-Bromopropane OSHA 1017 12 50 240 (min) GC-FID ST 226-01 48

1-Bromopropane OSHA PV2061 12 100 2 GC-FID ST 226-01 48

2-Bromopropane NIOSH 1025 0.1-12 10-200 varies GC-FID ST 226-01 48

2-Bromopropane OSHA 1017 12 50 240 (min) GC-FID ST 226-01 48

2-Bromopropane OSHA PV2062 12 100 2 GC-FID ST 226-01 48

Bromotrifluoromethane (trifluorobromomethane) NIOSH 1017 1000 0.3 20 15 min GC-FID ST 226-09 48 ST 226-01 48

Bromoxynil NIOSH 5010 240 1000 4 HPLC-UV F/CST 225-1713 108 C/HLD 225-1 116

Bromoxynil octanoate NIOSH 5010 240 1000 4 HPLC-UV F/CST 225-1713 108 C/HLD 225-1 116

BTEX (hydrocarbons, aromatic. See benzene, NIOSH 1501 varies varies varies varies GC-FID ST 226-01 48
toluene, ethylbenzene, and xylene)

1,3-Butadiene NIOSH 1024 LFC 10 20 8 GC-FID ST 226-37 49

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 193


Sampling Guide
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SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
1,3-Butadiene OSHA 56 1 5 3 50 1 GC-FID ST 226-73 49

Butane OSHA PV2010 3 50 1 GC-FID ST NA SKC

1-Butanethiol (butyl mercaptan) NIOSH 2525 0.5 1 50 15 GC-FPD ST 226-109 50

n-Butanol (alcohols combined) NIOSH 1405 50 (skin) 2-10 10-200 varies GC-FID ST 226-01 48

2-Butanone EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

2-Butanone Internal 16.9 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

2-Butanone Internal 16.9 ml/min 8-24 hrs SE, GC PS 690-105 96

2-Butanone OSHA 1004 200 12 50 4 GC-FID ST 575-002 82

2-Butanone (methyl ethyl ketone) NIOSH 2500 200 300 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-81A 49

2-Butanone (methyl ethyl ketone) OSHA 1004 200 16.88 8 GC-FID PS 575-002 82

2-Butoxyethanol (alcohols IV) NIOSH 1403 5 (skin) 2-10 10-50 varies GC-FID ST 226-01 48

2-Butoxyethanol (butyl CELLOSOLVE solvent) OSHA 83 50 48 100 8 GC-FID ST 226-01 48

2-Butoxyethanol acetate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

2-Butoxyethanol acetate (butyl CELLOSOLVE OSHA 83 48 100 8 GC-FID ST 226-01 48


acetate)

n-Butyl acetate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

n-Butyl acetate Internal 12.3 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or
PS 690-104 96

n-Butyl acetate Internal 12.3 ml/min 8-24 hrs SE, GC PS 690-105 96

n-Butyl acetate OSHA 1009 150 13.07 13.07 8 15 GC-FID PS 575-002 82

n-Butyl acetate OSHA 1009 150 12 0.75 50 50 4 15 GC-FID ST 226-01 48

sec-Butyl acetate OSHA 1009 200 12.74 12.74 8 15 GC-FID PS 575-002 82

sec-Butyl acetate OSHA 1009 200 12 0.75 50 50 4 15 GC-FID ST 226-01 48

t-Butyl acetate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

t-Butyl acetate OSHA 1009 200 13.09 13.09 8 15 GC-FID PS 575-002 82

t-Butyl acetate OSHA 1009 200 12 0.75 50 50 4 15 GC-FID ST 226-01 48

n-Butyl acetate (Esters I) NIOSH 1450 150 200 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 48

sec-Butyl acetate (Esters I) NIOSH 1450 200 1-10 10-200 varies GC-FID ST 226-01 48

t-Butyl acetate (Esters I) NIOSH 1450 200 1-10 10-200 varies GC-FID ST 226-01 48

Butyl acrylate Internal 11.7 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Butyl acrylate Internal 11.7 ml/min 8-24 hrs SE, GC PS 690-105 96

Butyl acrylate OSHA PV2011 12 50 4 GC-FID ST 226-73 49

n-Butyl acrylate NON 54 5 15 10 3 20 200 8 15 GC-FID ST 226-81A 49

n-Butyl alcohol EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

n-Butyl alcohol OSHA 5001 200 12 4 GC-FID ST 226-82 50

sec-Butyl alcohol OSHA 5001 200 12 4 GC-FID ST 226-82 50

n-Butyl alcohol (alcohols combined) NIOSH 1405 50 (skin) 2-10 10-200 varies GC-FID ST 226-01 48

sec-Butyl alcohol (alcohols combined) NIOSH 1405 100 150 2-10 2-10 10-200 10-200 varies varies GC-FID ST 226-01 48

t-Butyl alcohol (Alcohols I) NIOSH 1400 100 150 10 20(50) 8(3.3) GC-FID ST 226-01 48

n-Butyl alcohol (alcohols II) NIOSH 1401 50 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 48

sec-Butyl alcohol (alcohols II) NIOSH 1401 100 150 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 48

Butyl butryrate OSHA PV2090 10 200 50 min GC-FID ST 226-01 48

Butyl carbitol (diethylene glycol monobutyl ether) OSHA PV2095 10 200 50 min GC-FID ST 226-01 48

Butyl carbitol acetate OSHA PV2095 10 200 50 min GC-FID ST 226-01 48

Butyl CELLOSOLVE acetate (see 2-butoxyethanol OSHA 83


acetate)

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

194 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Butyl CELLOSOLVE solvent (see 2-butoxyethanol) OSHA 83

t-Butyl chromate (as CrO3) OSHA ID 215 0.005 mg/ 960 2000 15 IC-UV F/CST 225-802 107 C/HLD 225-1 116
(V2) m3

t-Butyl ethyl ether (ethyl tert-butyl ether) Internal 13.1 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96
PS 690-104 96

t-Butyl ethyl ether (ethyl tert-butyl ether) Internal 13.1 ml/min 8-24 hrs SE, GC PS 690-105 96

n-Butyl glycidyl ether NIOSH 1616 5.6 (15 min) 3 200 15 GC-FID ST 226-01 48

n-Butyl lactate OSHA PV2080 10 200 50 min GC-FID ST 226-01 48

n-Butyl mercaptan NIOSH 2525 0.5 1 50 15 GC-FPD ST 226-109 50

n-Butyl mercaptan (mercaptans) NIOSH 2542 0.5 (15 min) 48 12 100 200 8 60 GC-FPD CF/CST 225-9007 68 C/HLD 225-1 116

t-Butyl methyl ether (MTBE) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

t-Butyl methyl ether (MTBE) Internal 13.6 ml/min 8 hrs-30 SE, GC PS 690-105 96
days

Butyl ziram OSHA PV2065 180 1000 3 HPLC-UV ST 226-30-16 48

n-Butylamine NIOSH 2012 5 15 1000 15 GC-FID ST 226-53 49

Butylated hydroxytoluene OSHA PV2108 100 1000 100 min GC-FID ST 226-57 49

1,3-Butylene glycol (glycols) NIOSH 5523 60 1000 1 GC-FID ST 226-57 49

o-sec-Butylphenol OSHA PV2128 20 200 1.6 HPLC-UV ST 226-95 50

p-tert-Butylphenol OSHA PV2085 20 200 100 min GC-FID ST 226-95 50

Butyltin trichloride OSHA ID 240 1000 4 AA-GF ST 226-30-16 48


217SG

p-tert-Butyltoluene Internal 10.4 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

p-tert-Butyltoluene Internal 10.4 ml/min 8-24 hrs SE, GC PS 690-105 96

p-tert-Butyltoluene (Hydrocarbons, Aromatic) NIOSH 1501 10 20 1-29 1-29 10-200 10-200 varies varies GC-FID ST 226-01 48

Butyraldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

Butyraldehyde (Aldehydes, Screening) NIOSH 2539 5 20 4 GC-FID & ST 226-118 50


GC-MS

Cadmium & compounds (as Cd) NIOSH 7048 LFC 480 30 1000 2000 8 15 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Cadmium (Elements by Cellulosic Internal Capsule NIOSH 7306 LFC 3-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Cadmium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 LFC 13-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Cadmium (Elements by ICP HNO3 Digestion) NIOSH 7303 3-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Cadmium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 LFC 13-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Cadmium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Cadmium dust (as Cd) OSHA ID 121 0.2 mg/m3 0.5 mg/m3 960 30 2000 2000 8 15 AA F/CST 225-3-01 102 C/HLD 225-1 116

Cadmium OSHA 1006 0.2 mg/m3 0.5 mg/m3 480 2000 4 ICP-MS F/CST 225-3-01 102 C/HLD 225-1 116

Cadmium OSHA 5003 0.2 mg/m3 0.5 mg/m3 480 2000 4 ICP-MS F/CST 225-3-01 102 C/HLD 225-1 116

Cadmium OSHA ID125G 0.1 mg/m3 0.3 mg/m3 480 30 2000 2000 4 15 ICP F/CST 225-3-01 102 C/HLD 225-1 116
(fume) (fume)
0.2 mg/m3 0.6 mg/m3
(dust) (dust)

Cadmium dust (as Cd) OSHA ID 206 0.2 mg/m3 0.5 mg/m3 960 30 2000 2000 8 15 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Cadmium fume (ICP analysis of metal/metalloid OSHA ID 206 0.1 mg/m3 0.3 mg/m3 (C) 480 2000 4 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
particulates from solder operations)

Calcium & compounds (as Ca) NIOSH 7020 varies 240 1000 4 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Calcium (Elements by Cellulosic Internal Capsule NIOSH 7306 Varies 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Calcium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 varies 5-200 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Calcium (Elements by ICP HNO3 Digestion) NIOSH 7303 2-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Calcium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 varies 5-200 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 195


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Calcium (see specific compounds) NIOSH 7020 varies varies varies varies AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Calcium carbonate OSHA ID 121 15 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Calcium carbonate (calcium) NIOSH 7020 2 mg/m3 240 1000 4 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Calcium carbonate (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Calcium carbonate (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Calcium carbonate (see Particulates Not Otherwise


Regulated, total and respirable)

Calcium cyanamide OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Calcium hydroxide OSHA ID 121 5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Calcium hydroxide (calcium) NIOSH 7020 2 mg/m3 240 1000 4 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Calcium hydroxide (see Particulates Not Otherwise


Regulated, total and respirable)

Calcium oxide OSHA ID 121 5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Calcium oxide (calcium) NIOSH 7020 2 mg/m3 240 1000 4 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Calcium oxide (Elements by ICP HNO3 Digestion) NIOSH 7303 2 mg/m3 3-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Calcium silicate (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Calcium silicate (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Calcium sulfate (Particulates Not Otherwise


Regulated, total and respirable)

Camphor (Ketones II ) NIOSH 2553 2 1-25 10-200 varies GC-FID ST NA SKC

Camphor (Ketones II) NIOSH 1301 2 10 20(50) 8(3.3) GC-FID ST 226-01 48

Caprolactam OSHA PV2012 100 1000 100 min HPLC-UV ST 226-57 49

Capsaicin NIOSH 5041 480 15 1000 1000 8 15 HPLC-FD FLT 225-16 110 CST 225-32 116

Captan ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Captan OSHA PV2093 60 1000 1 HPLC-UV ST 226-30-16 48

Captan (Organonitrogen Pesticides) NIOSH 5601 5 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Carbaryl ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Carbaryl (Organonitrogen Pesticides) NIOSH 5601 5 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Carbaryl (Sevin) NIOSH 5006 5 mg/m3 240 1000 4 VAS F/CST 225-706 110 C/HLD 225-1 116

Carbaryl (Sevin) OSHA 63 5 mg/m3 60 1000 1 HPLC-UV ST 226-30-16 48

Carbendazim (Organonitrogen Pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Carbitol OSHA PV2013 10 200 50 min GC-FID ST 226-01 48

Carbitol acetate OSHA PV2013 10 200 50 min GC-FID ST 226-01 48

Carbofuran ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Carbofuran (Organonitrogen Pesticides) NIOSH 5601 0.1 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Carbon black NIOSH 5000 3.5 mg/m 3


360 1500 4 GR FLT 225-5-37-P 107 CST 225-3LF 115
SCN 225-26 117 C/HLD 225-1 116

Carbon black OSHA ID 196 3.5 mg/m3 960 2000 8 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Carbon dioxide OSHA ID 172 5000 30000 2-5 2-5 10-50 300 4-8 15 GC-TCD SB 253 Series or SB 263 Series 62

Carbon dioxide (by portable GC) NIOSH 6603 5000 30000 varies varies 20-100 20-100 varies varies P GC-TCD SB 232 Series 61

Carbon disulfide NIOSH 1600 1 10 10 3 20(50) 200 8(3.3) 15 GC-FPD ST 226-01 48 DRT 226-44 49

Carbon monoxide OSHA ID 210 50 2-5 2-5 10-50 1000 varies varies GC-DID SB 252 Series or SB 253 Series or
SB 262 Series or SB 263 Series 62

Carbon tetrachloride ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Carbon tetrachloride EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Carbon tetrachloride Internal 0.59 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 with
RR 690-300 96

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

196 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Carbon tetrachloride Internal 14.1 ml/min 8 hrs-7 SE, GC PS 690-105 96
days

Carbon tetrachloride (hydrocarbons, halogenated) NIOSH 1003 2 (1 hrs) 15 10-200 varies GC-FID ST 226-01 48

Carbon, activated (Particulates Not Otherwise


Regulated, total)

3-Carene (terpenes) NIOSH 1552 24 50 8 GC-FID ST 226-01 48

Catechol (pyrocatechol) OSHA PV2014 100 1000 100 min HPLC-UV ST 226-57 49

Cell fragments (bioaerosols) 15-150 15000 1-10 min varies STC 225-9820 114

CELLOSOLVE acetate (see 2-ethoxyethyl acetate)

CELLOSOLVE solvent (see 2-ethoxyethanol) NIOSH 1403


(alcohols IV)

Cellulose (paper fiber) (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Cellulose (paper fiber) (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Cellulose (see Particulates Not Otherwise


Regulated, total and respirable)

Cellulose insulation NIOSH 7404 varies 1000 varies SEM FLT/CL 225-1604 105

Cerium OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Chlordane NIOSH 5510 0.5 mg/m3 150 1000 2.5 GC-ECD ST 226-107 50 FLT 225-5 102
CST 225-2LF 115 SCN 225-26 117
C/HLD 225-1 116

Chlordane OSHA 67 0.5 mg/m3 480 1000 8 GC-ECD ST 226-30-16 48

Chlordane (non-occupational exposure) ASTM D 4947 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Chlordane (technical) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Chlorinated & organonitrogen herbicides NIOSH 5602 480 1000 8 GC-ECD ST 226-58 49

Chlorinated & organonitrogen herbicides (hand NIOSH 9200 GC-ECD NA SKC


wash)

Chlorinated camphene (toxaphene) NIOSH 5039 LFC 30 15 1000 1000 0.5 15 GC-ECD F/CST 225-3-01 102 C/HLD 225-1 116

Chlorinated diphenyl ether (chlorinated diphenyl NIOSH 5025 0.5 mg/m3 180 1000 3 GC-ECD F/CST 225-3-01 102 C/HLD 225-1 116
oxide)

Chlorinated diphenyl oxide NIOSH 5025 0.5 mg/m3 90 1000 1.5 GC-ECD F/CST 225-3-01 102 C/HLD 225-1 116

Chlorinated hydrocarbons (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 52

Chlorinated terphenyl (60% chlorine) NIOSH 5014 720 1500 8 GC-ECD F/CST 225-706 110 C/HLD 225-1 116

Chlorine NIOSH 6011 0.5 1 90 15 1000 1000 1.5 15 IC CF/CST 225-9006 68 C/HLD 225-1 116

Chlorine OSHA ID 101 1 (C) 240 15 1000 1000 4 15 ISE IMP 225-36-2 70 IT 225-22 70

Chlorine (prefiltered) OSHA ID 101 1 (C) 240 15 1000 1000 4 15 ISE IMP 225-36-2 70 IT 225-22 70
CST 225-3-23 115 SP 225-2901 117
FLT 225-3708 108

Chlorine dioxide OSHA ID 202 0.1 120 7.5 500 500 4 15 IC-CD IMP 225-36-2 70 IT 225-22 70

1-Chloro-1-nitropropane NIOSH S211 20 12 200 GC-FID ST NA SKC

5-Chloro-2-methyl-4-isothiazolin-3-one (Kathon NON 55 0.75 mg/m3 0.23 mg/m3 50 7.5 200 500 4 15 HPLC-UV ST 226-99 50
886)

1-Chloro-4-(trifluoromethyl)benzene NIOSH 1026 0.1-10.0 10-200 8 GC-FID ST 226-01 48

Chloroacetaldehyde NIOSH 2015 1 3 200 15 GC-ECD ST 226-15GWS 48

Chloroacetaldehyde OSHA 76 1 (C) 2.5 500 5 GC-ECD ST 226-15GWS 48

Chloroacetic acid NIOSH 2008 48 100 8 IC-CD ST 226-47-01 49

p-Chloroaniline OSHA PV2109 6 100 1 HPLC-UV ST 226-10 48

Chlorobenzene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Chlorobenzene Internal 14.4 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-104 96

Chlorobenzene Internal 14.4 ml/min 8-24 hrs SE, GC PS 690-105 96

Chlorobenzene (monochlorobenzene) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 197


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Chlorobenzene (monochlorobenzene) NIOSH 1003 10 10-200 varies GC-FID ST 226-01 48
(hydrocarbons, halogenated)

4-Chlorobenzotrifluoride NIOSH 1026 0.1-10.0 10-200 varies GC-FID ST 226-01 48

p-Chlorobenzotrifluoride NIOSH 1026 0.1-10.0 10-200 varies GC-FID ST 226-01 48

Chlorobiphenyl NIOSH 5503 0.001 mg/ 48 100(200) 8(4) GC-ECD FLT 225-16 110 CST 225-32 116
m3 (10 ST 226-39 49
hrs)

Chlorobromomethane (hydrocarbons, halogenated) NIOSH 1003 200 60 10-200 8 GC-FID ST 226-01 48

Chlorodiphenyl (42% Cl) OSHA PV2089 1 60 1000 1 GC-ECD ST 226-30-16 48

Chlorodiphenyl (42% Cl) (see polychlorinated NIOSH 5503


biphenyls)

Chlorodiphenyl (54% Cl) OSHA PV2088 0.5 60 1000 1 GC-ECD ST 226-30-16 48

Chlorodiphenyl (54% Cl) (see polychlorinated NIOSH 5503


biphenyls)

Chloroethane (ethyl chloride) NIOSH 2519 3 50 1 GC-FID ST 226-09 48

2-Chloroethanol (ethylene chlorohydrin) NIOSH 2513 1 10 20(50) 8(3.3) GC-FID ST 226-81A 49

Chloroform Internal 13.0 ml/min 8 hrs-7 SE, GC PS 690-105 96


days

Chloroform (trichloromethane) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Chloroform (trichloromethane) OSHA 05 50 (C) 10 200 50 min GC-FID ST 226-01 48

Chloroform (trichloromethane) (hydrocarbons, NIOSH 1003 2 15 10-200 varies GC-FID ST 226-01 48


halogenated)

bis-Chloromethyl ether OSHA 10 50 500 100 min GC-ECD IMP 225-36-2 70 IT 225-22 70

Chloromethyl methyl ether NON 29 2.4 0.3 10 20 4 15 GC-ECD ST NA SKC

Chloromethyl methyl ether OSHA 10 50 500 100 min GC-ECD IMP 225-36-2 70 IT 225-22 70

4-Chloronitrobenzene (nitrobenzenes) NIOSH 2005 0.1 ppm 96 200 8 GC-FID ST 226-10 48

p-Chlorophenol NIOSH 2014 24 50 8 HPLC-UV ST 226-10 48

Chloropicrin NON 51 0.1 144 100 24 GC-MSD ST 226-175 51

Chloropicrin OSHA PV2103 0.1 3 200 15 min GC-ECD ST 226-93 50

beta-Chloroprene NIOSH 1002 1 (15 min) 1.5 100 15 GC-FID ST 226-01 48

beta-Chloroprene OSHA 112 25 6 50 2 GC-ECD ST 226-111A 50

Chlorothalonil ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Chlorotoluron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Chlorpropham (Organonitrogen Pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Chlorpyrifos (Dursban) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Chlorpyrifos (Dursban) OSHA 62 480 1000 8 GC-FPD ST 226-30-16 48

Chlorpyrifos (Organophosphorus Pesticides) NIOSH 5600 0.2 mg/m3 240 1000 4 GC-FPD ST 226-58 49

Chromic acid & chromates (as CrO3) OSHA ID 215 0.005 mg/m3 960 2000 8 15 IC-UV F/CST 225-802 Ω 107 C/HLD 225-1 116
(V2)

Chromic acid & chromates (chromium hexavalent) NIOSH 7600 1 µg/m3 240 1000 4 VAS F/CST 225-803 107 C/HLD 225-1 116
(10 hrs)

Chromic acid & chromates (chromium hexavalent) NIOSH 7604 1 µg/m3 960 2000 8 IC-CD F/CST 225-803 107 C/HLD 225-1 116
(10 hrs)

Chromium & compounds (as Cr) NIOSH 7024 0.5 mg/m3 10 - 1000 1000-3000 varies AA-F F/CST 225-3-01 102
C/HLD 225-1 116

Chromium (Elements by Cellulosic Internal NIOSH 7306 0.5 mg/m3 1-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Capsule Sampler)

Chromium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.5 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Chromium (Elements by ICP HNO3 Digestion) NIOSH 7303 0.5 mg/m3 8-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Chromium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.5 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Chromium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Chromium acetate OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

198 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Chromium carbonate OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Chromium metal & insoluble compounds OSHA ID 121 1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Chromium metal & insoluble compounds OSHA ID 125G 1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Chromium phosphate OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Chromium soluble salts (except hexavalent) OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Chromium trioxide (CR(VI)) OSHA ID 215 0.005 mg/m3 960 2000 8 IC-UV F/CST 225-802 107 C/HLD 225-1 116
(V2)

Chromium, hexavalent ASTM D 6832 varies 1000-5000 varies IC F/CST 225-802 or F/CST 225-1713 or
F/CST 225-709 or F/CST 225-401 109

Chromium, hexavalent NIOSH 7600 1 µg/m3 240 1000 4 VAS F/CST 225-802 107 C/HLD 225-1 116
(10 hrs)

Chromium, hexavalent NIOSH 7604 1 µg/m3 240 1000 4 IC-CD F/CST 225-802 107 C/HLD 225-1 116
(10 hrs)

Chromium, hexavalent NIOSH 7605 0.001 mg/m3 1-400 1000-4000 varies IC-PCD-UV F/CST 225-802 107 C/HLD 225-1 116
(10 hrs)

Chromium, hexavalent NIOSH 7703 0.001 mg/m3 10-1200 1000-4000 varies P VAS F/CST 225-802 107 C/HLD 225-1 116
(10 hrs)

Chromium, hexavalent OSHA ID 103 0.005 mg/m3 (C) 960 30 2000 2000 8 15 DPP F/CST 225-802 107 C/HLD 225-1 116

Chromium, hexavalent OSHA W4001 0.005 mg/m3 (C) IC-UV FLT 225-5-37 or FLT 225-1822 109

Chromium, hexavalent (CR(VI)) OSHA ID 215 0.005 mg/m3 960 2000 8 IC-UV F/CST 225-802 Ω 107 C/HLD 225-1 116
(V2)

Chromium, hexavalent (in settled dust) NIOSH 9101 bulk bulk CLR or VAS
or IC

Chrysene OSHA 58 0.2 mg/m3 960 2000 8 GR & HPLC- FLT 225-7 110 CST 225-2LF 115
FD, or GR & C/HLD 225-1 116
HPLC-UV

Chrysene (Polynuclear Aromatic Hydrocarbons ASTM D 6209 350 m3 (max) 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
by GC-MS)

Chrysene (Polynuclear Aromatic Hydrocarbons NIOSH 5515 LFC 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
by GC) C/HLD 225-1 116

Chrysene (Polynuclear Aromatic Hydrocarbons NIOSH 5506 LFC 480 2000 4 HPLC-UV F/CST 225-1713 108 ST 226-30-04 48
by HPLC) C/HLD 225-1 116

Chrysotile (see asbestos fibers) NIOSH 9000 bulk XRD

Chrysotile fibers (see asbestos fibers) NIOSH 7400

Coal dust (> 5% SiO2) (see silica, respirable OSHA ID 142 (v4)
crystalline)

Coal tar naphtha (naphthas) NIOSH 1550 100 3 20 2.5 GC-FID ST 226-01 48

Coal tar pitch volatiles OSHA 58 0.2 mg/m 3


960 2000 8 GR & HPLC- FLT 225-7 110 CST 225-2LF 115
FD, or GR & C/HLD 225-1 116
HPLC-UV

Cobalt OSHA ID 213 0.1 mg/m3 480 2000 6 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Cobalt & compounds (as Co) NIOSH 7027 0.05 mg/m3 960 2000 8 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Cobalt (Elements by Cellulosic Internal Capsule NIOSH 7306 0.05 mg/ 1-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler) m3 (dust,
fume)

Cobalt (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.5 mg/ 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
m3 (dust, C/HLD 225-1 116
fume)

Cobalt (Elements by ICP HNO3 Digestion) NIOSH 7303 0.5 mg/ 3-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
m3 (dust,
fume)

Cobalt (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.05 mg/ 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
m3 (dust,
fume)

Cobalt (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 199


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Cobalt acetate OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Cobalt carbonyl OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Cobalt hydrocarbonyl OSHA ID 121 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116
(as Co)

Cobalt metal, dust & fume OSHA ID 125G 0.1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Cobalt metal, dust & fume (as Co) OSHA ID 121 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Coke oven emissions OSHA 58 0.15 mg/m 3


960 2000 8 GR & HPLC- FLT 225-7 110 CST 225-2LF 115
FD, or GR & C/HLD 225-1 116
HPLC-UV

Command (dimethazone) OSHA PV2066 60 1000 1 GC-ECD ST 226-30-16 48

Copper (Elements by ICP Aqua Regia Ashing) NIOSH 7301 1 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
(dust) 0.1 C/HLD 225-1 116
mg/m3
(fume)

Copper (Elements by ICP HNO3 Digestion) NIOSH 7303 1 mg/m3 15-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
(dust) 0.1
mg/m3
(fume)

Copper (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 1 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
(dust) 0.1
mg/m3
(fume)

Copper (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Copper dust NIOSH 7029 1 mg/m3 480 1000 8 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Copper dusts & mists OSHA ID 125G 1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Copper dusts & mists (as Cu) OSHA ID 121 1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Copper fume NIOSH 7029 0.1 mg/m 3


480 1000 8 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Copper fume OSHA ID 121 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Copper fume OSHA ID 125G 0.1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Copper fume (ICP analysis of metal/metalloid OSHA ID 206 0.1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
particulates from solder operations)

Co-Ral (coumaphos) OSHA PV2134 480 1000 8 GC-FPD ST 226-30-16 48

Corn starch (Particulates Not Otherwise


Regulated, respirable)

Corundum (Al2O3) (see alpha-alumina [total dust])

Corundum (emery) (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Corundum (emery) (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

di-tert-butyl-p-Cresol OSHA PV2108 100 1000 100 min GC-FID ST 226-57 49

Cresol (all isomers) NIOSH 2546 10 mg/m3 24 100 4 GC-FID ST 226-95 50

Cresol (all isomers) OSHA 32 5 24 100 4 HPLC-UV ST 226-95 50

Cresols EPA TO-8 < 80 L 100-1000 HPLC-UV IMP 225-36-1 70 IT 225-22 70


ml/min

Cristobalite (see silica, respirable crystalline) OSHA ID 142 (v4)

Cristobalite (silica, crystalline [respirable] by XRD ) NIOSH 7500 0.05 mg/m3 400-1000 2500 varies XRD F/CST 225-803 107 CYC 225-01-02 127
C/HLD 225-1 116

Cristobalite (silica, crystalline by IR) NIOSH 7602 0.05 mg/m3 1000 2000-4000 varies IR F/CST 225-803 107 C/HLD 225-1 116
CYC 225-01-02 127

Crocidolite fibers (see asbestos fibers) NIOSH 7400

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

200 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Crotonaldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 50

Crotonaldehyde NIOSH 3516 2 48 200 4 DPP IMP 225-36-2 70 IT 225-22 70

Crotonaldehyde OSHA 81 2 6 100 1 HPLC-UV CF/CST 225-9019 68 C/HLD 225-1 116

Crotonaldehyde (Aldehydes, Screening) NIOSH 2539 2 5 20 4 GC-FID & ST 226-118 50


GC-MS

Crufomate OSHA PV2015 60 1000 1 GC-FPD ST 226-30-16 48

Cryolite (fluorides) NIOSH 7902 2.5 mg/m 3


480 1000 8 ISE CF/CST 225-9001 68 C/HLD 225-1 116

Cumene (isopropyl benzene) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Cumene (isopropyl benzene) Internal 12.8 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-104 96

Cumene (isopropyl benzene) Internal 12.8 ml/min 8-24 hrs SE, GC PS 690-105 96

Cumene (isopropyl benzene) OSHA PV2137 50 24 200 2 GC-FID ST 226-01 48

Cumene (isopropyl benzene) (Hydrocarbons, NIOSH 1501 50 (skin) 1-30 10-200 8(3.3) GC-FID ST 226-01 48
Aromatic)

Cupric carbonate as Cu (Elements by ICP HNO3/ NIOSH 7300 960 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
HClO4 Ashing)

Cyanazine NIOSH 5602 480 1000 8 GC-ECD ST 226-58 49

Cyanide (as Cn) OSHA ID 120 5 mg/m3 120 1000 2 ISE F/CST 225-3-01 102 IMP 225-36-2 70
IT 225-22 70

Cyanides, aerosol & gas NIOSH 7904 5 mg/m3 120 500 4 ISE FLT 225-3705 ∆ 108 CST 225-2LF 115
(10 min) IMP 225-36-2 70 IT 225-22 70
C/HLD 225-1 116

Cyanogen OSHA PV2104 12 200 1 GC-NPD ST 226-117 50

Cyanuric acid NIOSH 5030 480 1000 8 HPLC-UV F/CST 225-802 107 C/HLD 225-1 116

Cyclohexane Internal 15.6 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Cyclohexane Internal 15.6 ml/min 8-24 hrs SE, GC PS 690-105 96

Cyclohexane (hydrocarbons, BP 36 to 216 C) NIOSH 1500 300 2.5-5 10-200 varies GC-FID ST 226-01 48

Cyclohexanol (alcohols combined) NIOSH 1405 50 (skin) 1-10 10-200 varies GC-FID ST 226-01 48

Cyclohexanol (alcohols III) NIOSH 1402 50 10 20(50) 8(3.3) GC-FID ST 226-01 48

Cyclohexanone EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Cyclohexanone Internal 15.6 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or


PS 690-104 96

Cyclohexanone Internal 15.6 ml/min 8-24 hrs SE, GC PS 690-105 96

Cyclohexanone OSHA 01 50 10 20(50) 8(3.3) GC-FID ST 226-110 50

Cyclohexanone (Ketones I) NIOSH 1300 25 10 20(50) 8(3.3) GC-FID ST 226-01 48

Cyclohexanone (Ketones I) NIOSH 2555 1-10 10-200 varies GC-FID ST NA SKC

Cyclohexene (hydrocarbons, BP 36 to 216 C) NIOSH 1500 300 5-7 10-200 varies GC-FID ST 226-01 48

Cyclohexylamine OSHA PV2016 20 200 100 min GC-FID ST 226-98 50

Cyclonite (RDX) OSHA PV2135 1.5 mg/m3 120 1000 HPLC-UV F/CST 225-709 110 C/HLD 225-1 116

Cyhexatin NIOSH 5504 0.1 mg/m3 500 1500 AA-GF F/CST 225-709 110 ST 226-30 48
C/HLD 225-1 116

Cypermethrin OSHA PV2063 60 1000 60 min GC-ECD ST 226-30-16 48

2,4-D (2,4-dichlorophenoxyacetic acid) NIOSH 5001 10 mg/m3 180 1000 3 HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

2,4-D (2-butoxyethyl ester) NIOSH 5602 480 1000 8 GC-ECD ST 226-58 49

2,4-D (2-butoxyethyl ester) NIOSH 5602 480 1000 8 GC-ECD ST 226-58 49

2,4-D acid NIOSH 5602 10 480 1000 8 GC-ECD ST 226-58 49

2,4-D, BE NIOSH 5602 480 1000 8 GC-ECD ST 226-58 49

2,4-D, EH NIOSH 5602 480 1000 8 GC-ECD ST 226-58 49

2,4-D, ME (2,4-dichlorophenoxyacetic acid) NIOSH 5602 480 1000 8 GC-ECD ST 226-58 49

Dacthal ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

DBP (see dibutyl phthalate) OSHA 104

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

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Sampling Guide
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SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
p,p-DDE ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

p,p-DDT ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

DDVP (dichlorvos) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Decabromodiphenyl oxide NIOSH 2559 48-960 2000 varies HPLC-UV FLT 225-1822 109 SP 225-27 117
CST 225-2LF 115

n-Decane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

n-Decane Internal 12.2 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-104 96

n-Decane Internal 12.2 ml/min 8-24 hrs SE, GC PS 690-105 96

n-Decane (hydrocarbons, BP 36 to 216 C) NIOSH 1500 2 10-50 varies GC-FID ST 226-01 48

DEHP (see di-2-ethylhexyl phthalate) OSHA 104

Demeton NIOSH 5514 0.1 mg/m3 480 1000 8 GC-FPD FLT 225-5 102 SCN 225-26 117
CST 225-2LF 115 ST 226-30-05 48
C/HLD 225-1 116

DEP (see diethyl phthalate) OSHA 104

Desflurane OSHA 106 3 50 1 GC-FID ST 226-81A 49

Di-(2-ethylhexyl) phthalate (DEHP) NIOSH 5020 180 1000 3 GC-FID F/CST 225-3-01 102 C/HLD 225-1 116

Di(ethyleneglycol) ethyl ether acrylate OSHA PV2132 1 mg/m3 48 200 4 GC-FID ST 226-110 50

Diacetone alcohol (alcohols combined) NIOSH 1405 50 1-10 10-200 varies GC-FID ST 226-01 48

Diacetone alcohol (alcohols III) NIOSH 1402 50 10 20(50) 8(3.3) GC-FID ST 226-01 48

Diacetyl OSHA 1012 0.005 0.025 9 3 50 200 3 15 GC-FID ST 226-183 51

Diallyl disulfide OSHA PV2086 10 20(50) 8(3.3) GC-FPD ST 226-110 50

1,2-Diaminoethane NIOSH 2540 10 100 1.7 HPLC-UV ST 226-30-18 48

o-Dianisidine OSHA 71 100 15 1000 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

o-Dianisidine dyes (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC-UV FLT 225-17P 108 CST 225-3LF 115
C/HLD 225-1 116

Diazinon ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 54

Diazinon OSHA 62 480 1000 8 GC-FPD ST 226-30-16 48

Diazinon (Organophosphorus Pesticides) NIOSH 5600 0.1 mg/m 3


240 1000 4 GC-FPD ST 226-58 49

Diazomethane NIOSH 2515 0.2 10 200 50 min GC-FID ST 226-23 48

Dibenz(a,h)anthracene (Polynuclear Aromatic ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Hydrocarbons by GC-MS) (max)

Dibenz(a,h)anthracene (Polynuclear Aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Dibenz(a,h)anthracene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Dibromodifluoromethane (difluorodibromomethane) NIOSH 1012 100 10 20(50) 8(3.3) GC-FID ST 226-01 48

1,2-Dibromoethane (ethylene dibromide) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

1,2-Dibromoethane (ethylene dibromide) NIOSH 1008 0.045 0.13 24 3 50 200 8 15 GC-ECD ST 226-01 48

2-Dibutyl aminoethanol (aminoethanol compounds NIOSH 2007 2 10 20(50) 8(3.3) GC-FID ST 226-10-04 48
I)

Dibutyl phosphate NIOSH 5017 1 2 240 2000 2 GC-FPD FLT 225-17-01 108 CST 225-2LF 115
C/HLD 225-1 116

Dibutyl phthalate NIOSH 5020 5 mg/m3 100 1000 100 min GC-FID F/CST 225-3-01 102 C/HLD 225-1 116

Dibutyl phthalate (DBP) OSHA 104 5 mg/m3 240 1000 4 GC-FID ST 226-56 49

Dibutyltin bis (isooctyl mercaptoacetate) (organotin NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC & ST 226-30 48 F/CST 225-709 110
compounds as Sn) AA-GF C/HLD 225-1 116

Dibutyltin dilaurate (as Sn) OSHA ID 500 1000 500 min AA F/CST 225-3-01 102 C/HLD 225-1 116
218SG

Dibutyltin maleate (as Sn) OSHA ID 200 1000 200 min AA-GF F/CST 225-3-01 102 C/HLD 225-1 116
224SG

2,2-Dichloro-1,1,1-trifluoroethane NON 50 9 50 3 GC-FID ST 226-09 48

1,1-Dichloro-1-fluoroethane OSHA 113 1 50 20 min GC-FID ST NA SKC

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

202 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
1,1-Dichloro-1-nitroethane NIOSH 1601 2 1.5-15 10-1000 GC-FID ST 226-81A 49

1,2-Dichlorobenzene Internal 12.5 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96


PS 690-104 96

1,2-Dichlorobenzene Internal 12.5 ml/min 8-24 hrs SE, GC PS 690-105 96

m-Dichlorobenzene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

m-Dichlorobenzene NIOSH 1003 3 10-200 GC-FID ST 226-01 48

o-Dichlorobenzene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

p-Dichlorobenzene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

o-Dichlorobenzene (hydrocarbons, halogenated) NIOSH 1003 50 3 10-200 varies GC-FID ST 226-01 48

p-Dichlorobenzene (hydrocarbons, halogenated) NIOSH 1003 1.7 (LOQ) 3 10-200 varies GC-FID ST 226-01 48

3,3’-Dichlorobenzidine OSHA 65 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

Dichlorodifluoromethane NIOSH 1018 1000 3 20 2.5 GC-FID ST 226-01 48 ST 226-09 48

1,2-Dichloroethane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

1,2-Dichloroethane Internal 14.2 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

1,2-Dichloroethane Internal 14.2 ml/min 1-7 days SE, GC PS 690-105 96

1,1-Dichloroethane (ethylidene chloride) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

1,1-Dichloroethane (Hydrocarbons, Halogenated) NIOSH 1003 100 10 10-200 varies GC-FID ST 226-01 48

Dichloroethyl ether NIOSH 1004 5 10 10 20(50) 8(3.3) GC-FID ST 226-01 48

cis-1,2-Dichloroethylene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

1,2-Dichloroethylene (hydrocarbons, halogenated) NIOSH 1003 200 3 10-200 varies GC-FID ST 226-01 48

Dichlorofluoromethane NIOSH 2516 10 3 20 2.5 GC-FID ST 226-25 48

Dichloromethane (methylene chloride) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Dichloromethane (methylene chloride) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Dichloromethane (methylene chloride) Internal 14.7 ml/min 8 hrs to 3 SE, GC PS 690-105 96


days

Dichloromethane (methylene chloride) Internal 0.54 ml/min 1-7 days SE, GC PS 690-105 with RR 690-300 96

Dichloromethane (see methylene chloride)

Dichloromonofluoromethane NIOSH 2516 10 3 20 2 GC-FID ST 226-09 ♠ 48


(dichlorofluoromethane)

2,4-Dichlorophenoxyacetic acid (2,4-D) NIOSH 5001 10 mg/m3 180 1000 3 HPLC-UV F/CST 225-709 110 C/HLD 225-1 116

1,2-Dichloropropane (propylene dichloride) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

1,2-Dichloropropane (propylene dichloride) Internal 14.3 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

1,2-Dichloropropane (propylene dichloride) Internal 14.3 ml/min 8-24 hrs SE, GC PS 690-105 96

1,2-Dichloropropane (propylene dichloride) NIOSH 1013 LFC 3 20 2.5 GC-ECN ST 226-81A 49

cis-1,3-Dichloropropene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

cis-1,3-Dichloropropene Internal 13.6 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

cis-1,3-Dichloropropene Internal 13.6 ml/min 8-24 hrs SE, GC PS 690-105 96

trans-1,3-Dichloropropene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

trans-1,3-Dichloropropene Internal 14.4 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

trans-1,3-Dichloropropene Internal 14.4 ml/min 8-24 hrs SE, GC PS 690-105 96

2,2-Dichloropropionic acid OSHA PV2017 10 200 50 min HPLC-UV ST 226-10 48

1,2-Dichlorotetrafluoroethane NIOSH 1018 1000 3 20 2.5 GC-FID ST 226-01 48 ST 226-09 48


(dichlorodifluoromethane)

Dichlorotrifluoroethane NON 50 9 50 3 GC-FID ST 226-09 48

Dichlorvos (DDVP) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Dichlorvos (DDVP) OSHA 62 1 mg/m 3


480 1000 8 GC-FPD ST 226-30-16 48

Dicloran ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Dicofol ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

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Sampling Guide
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SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Dicrotophos ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Dicrotophos (Bidrin) OSHA PV2099 480 1000 8 GC-FPD ST 226-30-16 48

Dicrotophos (Organophosphorus Pesticides) NIOSH 5600 0.25 mg/m3 240 1000 4 GC-FPD ST 226-58 49

Dicyclopentadiene OSHA PV2098 10 100 100 min GC-FID ST 226-01 48

Dieldrin ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Diesel emissions (see elemental carbon) NIOSH 5040 TOA-FID

Diesel exhaust particles (see elemental carbon) NIOSH 5040 TOA-FID

Diesel particulate matter ASTM D 6877 varies 1000-4000 varies EGA-TOS DPM 225-317 or F/CST 225-401 109

Diesel particulate matter MSHA 350 µg/ varies 2000 varies TOA-FID DPM 225-317 109 CYC 225-105 126
30CFR57 m3 (total C/HLD 225-1 120
carbon)

Diesel particulate matter MSHA 350 µg/ varies varies varies TOA-FID F/CST 225-401 109 CYC 225-100 126
30CFR57 m3 (total C/HLD 225-1 116
carbon)

Diethanolamine OSHA PV2018 10 100 100 min HPLC-UV ST 226-30-18 48

Diethanolamine (DEA) (Aminoethanol Compounds NIOSH 3509 3 240 1000 4 IC IMP 225-36-1 70 IT 225-22 70
II)

Diethyl ether (ethyl ether) NIOSH 1610 0.25-3 10-200 varies GC-FID ST 226-01 48

Diethyl ketone (3-pentanone) OSHA PV2136 10 100 100 GC-FID ST NA SKC

Diethyl phthalate (DEP) OSHA 104 240 1000 4 GC-FID ST 226-56 49

Diethylamine OSHA 41 25 10 3 200 200 50 min 15 HPLC ST 226-96 50

Diethylamine (amines, aliphatic) NIOSH 2010 10 25 24 3 50 200 8 15 GC-FID ST 226-10 48

2-Diethylaminoethanol (aminoethanol compounds NIOSH 2007 10 10 20(50) 8(3.3) GC-FID ST 226-10-04 48


I)

Diethylene dioxide (see dioxane)

Diethylene ether (see dioxane)

Diethylene glycol (glycols) NIOSH 5523 60 1000 1 GC-FID ST 226-57 49

Diethylenetriamine OSHA 60 10 100 100 min HPLC-UV ST 226-30-18 48

Difluorodibromomethane NIOSH 1012 100 6 50 2 GC-FID ST 226-01 48

Diglycidyl ether of bisphenol A OSHA 1018 240 1000 240 (min) HPLC-UV/ F/CST 225-709 110 C/HLD 225-1 116
PDA

Dihexyl phthalate OSHA PV2076 240 1000 4 GC-FID ST 226-56 49

Dihydrocapsaicin NIOSH 5041 480 15 1000 1000 8 15 HPLC-FD FLT 225-16 110 CST 225-32 116

Diisobutyl ketone Internal 10.3 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Diisobutyl ketone Internal 10.3 ml/min 8-24 hrs SE, GC PS 690-105 96

Diisobutyl ketone (Ketones I) NIOSH 1300 25 10 20(50) 8(3.3) GC-FID ST 226-01 48

Diisobutyl ketone (Ketones I) NIOSH 2555 1-10 10-200 varies GC-FID ST NA SKC

Diisocyanates OSHA 42 240 15 1000 1000 4 15 HPLC-UV or CF/CST 225-9002  or CF/ 225-9013 68
HPLC-FD C/HLD 225-1 116 CST

Dimethazone OSHA PV2066 60 1000 1 GC-ECD ST 226-30-16 48

Dimethoate OSHA PV2113 480 1000 8 GC-FPD ST 226-30-16 48

Dimethoxymethane (methylal) NIOSH 1611 1000 2 20 1.5 GC-FID ST 226-01 48

Dimethyl adipate OSHA PV2019 20 200 100 min GC-FID ST 226-01 48

Dimethyl arsenic acid (arsenic, organo-) NIOSH 5022 960 2000 8 IC-AA FLT 225-17-01 108 CST 225-2LF 115
C/HLD 225-1 116

Dimethyl disulfide NON 42 12 1000 12 min GC-FPD SB 253-10 or SB 263-10 or


SB 231-10 60

Dimethyl glutarate OSHA PV2020 20 200 100 min GC-FID ST 226-01 48

Dimethyl phthalate (DMP) OSHA 104 5 mg/m3 240 1000 4 GC-FID ST 226-56 49

Dimethyl succinate OSHA PV2021 20 200 100 min GC-FID ST 226-01 48

Dimethyl sulfate NIOSH 2524 0.1 (8 hrs) 12 50 4 GC-ECN ST 226-114 50

Dimethyl sulfate OSHA PV2147 1 10 100 100 min GC-FPD ST 226-115 50

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

204 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Dimethyl sulfide NON 42 12 1000 12 min GC-FPD SB 263-10 or SB 231-10 60

2,3-Dimethyl-2,3-dinitrobutane NON 44 0.15 mg/m3 10 200 50 min GC-ECD ST 226-35-03 48


OEL

Dimethylacetamide NIOSH 2004 10 80 1000 8 GC-FID ST 226-10 48

Dimethylamine NIOSH 2010 10 24 50 8 GC-FID ST 226-10 48

Dimethylamine OSHA 34 10 10 20 8 HPLC ST 226-96 50

2-Dimethylamino ethanol NIOSH 2561 10-24 20-100 varies GC-FID ST 226-94 50

1-Dimethylamino-2-propanol NIOSH 2561 10-24 20-100 varies GC-FID ST 226-94 50

2,4-Dimethylaminobenzene (Amines, Aromatic) NIOSH 2002 2 24 50 8 GC-FID or ST 226-10 48


GC-NSD

N,N-Dimethylaniline OSHA PV2064 5 30 200 2.5 GC-FID ST 226-98 50

N,N-Dimethylaniline (Amines, Aromatic) NIOSH 2002 5 10 24 3 50 200 8 15 GC-FID or ST 226-10 48


GC-NSD

2,5-Dimethylbenzaldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

N,N-Dimethylethanolamine NIOSH 2561 10-24 20-100 varies GC-FID ST 226-94 50

N,N-Dimethylformamide NIOSH 2004 10 24 50 8 GC-FID ST 226-10 48

N,N-Dimethylformamide OSHA 66 10 9.6 3 20 200 8 15 GC-NPD ST 226-01 48

1,1-Dimethylhydrazine NIOSH 3515 0.06 (120 60 1000 1 VAS IMP 225-36-2 70 IT 225-22 70
min)

N,N-Dimethyl-p-toluidine (Amines, Aromatic) NIOSH 2002 96 200 8 GC-FID or ST 226-10 48


GC-NSD

Dimethyltin dichloride NIOSH 5526 0.1 mg/m3 60 60 250 1000 4 60 GC-FPD ST 226-30-16 48

Di-n-hexyl phthalate OSHA PV2076 240 1000 4 GC-FID ST 226-56 49

Dinitrotoluene (DNT) OSHA 44 1.5 mg/m 3


60 1000 1 GC-TEA ST 226-56 49

Di-n-octyl phthalate (DNOP) OSHA 104 240 1000 4 GC-FID ST 226-56 49

n-Dioctyl phthalate (DNOP) OSHA 104 240 1000 4 GC-FID ST 226-56 49

Dioxane (diethylene dioxide) NIOSH 1602 1 (30 min) 10 20(50) 8(3.3) GC-FID ST 226-01 48

Dioxin (including, PHDDs, PCDDs, PBDDs) EPA TO-9A 200-280 L/ 24 hrs HRGC- PUF 226-131 55 FLT 225-1808 109
min HRMS

Diphenyl NIOSH 2530 0.2 30 100 5 GC-FID ST 226-35-01 48

Diphenyl ether OSHA PV2022 0.2 20 200 100 min GC-FID ST 226-95 50

p,p-Diphenyl methane diisocyanate (MDI) (see OSHA 47


methylene bisphenyl isocyanate)

Diphenylamine OSHA 78 100 1000 100 min HPLC-UV CF/CST 225-9004 68 C/HLD 225-1 116

Diphenylmethane-4,4’-diisocyanate (4,4-methylene NIOSH 5521 50 µg/m 3


200 µg/m 480
3
10 1000 1000 8 10 HPLC- IMP 225-36-1 70 IT 225-22 70
bisphenyl isocyanate) (isocyanates) (10 min) C ELCHM &
HPLC-UV

Dipropyl disulfide OSHA PV2086 10 20(50) 8(3.3) GC-FPD ST 226-110 50

Dipropylene glycol methyl ether OSHA 101 100 10 100 100 min GC-FID ST 226-01 48

Dipropylene glycol methyl ether (glycol ethers) NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 49

Dipropylene glycol monomethyl ether (glycol NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 49
ethers)

Direct black 38 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17P 108 CST 225-3LF 115
C/HLD 225-1 116

Direct blue 6 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17P 108 CST 225-3LF 115
C/HLD 225-1 116

Direct blue 8 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17P 108 CST 225-3LF 115
C/HLD 225-1 116

Direct brown 95 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17P 108 CST 225-3LF 115
C/HLD 225-1 116

Direct red 2 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17P 108 CST 225-3LF 115
C/HLD 225-1 116

Direct red 28 (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC FLT 225-17P 108 CST 225-3LF 115
C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

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Sampling Guide
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SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Di-sec-octyl phthalate (see di-[2-ethylhexy]
phthalate)

Disulfoton OSHA PV2105 480 1000 8 GC-FPD ST 226-30-16 48

Disulfoton (Organophosphorus Pesticides) NIOSH 5600 0.1 mg/m3 240 1000 4 GC-FPD ST 226-58 49

Diuron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Diuron (Organonitrogen Pesticides) NIOSH 5601 10 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Divinyl benzene OSHA 89 12 50 4 GC-FID ST 226-73 49

DMP (see dimethyl phthalate) OSHA 104

DNOP (see di-n-octyl phthalate) OSHA 104

DNT (dinitrotoluene) OSHA 44 1.5 mg/m3 60 1000 1 GC-TEA ST 226-56 49

n-Dodecane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Dursban (chlorpyrifos)(organophosphorus NIOSH 5600 0.2 mg/m3 0.6 mg/m3 240 1000 4 GC-FPD ST 226-58 49
pesticides)

Dust (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Dust, inorganic 15-150 15,000 1-10 min varies STC 225-9820 114

Dust, respirable OSHA PV2121 5.0 mg/m3 varies varies varies GR FLT 225-803 107 C/HLD 225-1 116
CYC 225-105 126

Dust, respirable (particulates) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Dust, respirable (in workplace atmospheres) ASTM D 4532 varies 2500 varies GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Dust, total OSHA PV2121 15 mg/m3 720 1500 8 GR FLT 225-802 107 C/HLD 225-1 116

Dust, total nuisance (particulates) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Dust, total, particulates not otherwise regulated NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Dyes, benzidine, o-tolidine, o-dianisidine NIOSH 5013 LFC 480 1000 8 HPLC-UV FLT 225-17P 108 CST 225-3LF 115
C/HLD 225-1 116

Elemental carbon (diesel exhaust) MSHA varies varies varies EGA-TOS DPM 225-317 109 CYC 225-105 126

Elemental carbon (diesel exhaust) NIOSH 5040 varies varies varies TOA-FID F/CST 225-401 109 CYC 225-100 126
C/HLD 225-1 116

Elements by Cellulosic Internal Capsule Sampler NIOSH 7306 Varies Varies 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
(see specific element)

Elements by ICP Aqua Regia ashing (see specific NIOSH 7301 varies varies 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
element) C/HLD 225-1 116

Elements by ICP HNO3 digestion (see specific NIOSH 7303 varies varies 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
element)

Elements by ICP HNO3/HClO4 ashing (see specific NIOSH 7300 varies varies 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
element)

Elements on wipes (see specific element) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Emery (corundum) (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Emery (corundum) (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Endosulfan (thiodan) OSHA PV2023 60 1000 1 GC-ECD ST 226-30-16 48

Endotoxins (bacteria in air) NON 48 62.5-375 12,500 + 5-30 varies BS 225-9595 138 VT 225-9598A ◊ 138

Endrin NIOSH 5519 0.1 mg/m3 240 1000 4 GC-ECD CST 225-2LF 115 FLT 225-5 102
SCN 225-26 117 ST NA SKC
C/HLD 225-1 116

Enflurane (ethrane) OSHA 103 12 50 4 GC-FID ST 226-81A 49

Enflurane (ethrane) OSHA 29 10 20 8 GC-FID ST 226-01 48

Environmental tobacco smoke (nicotine & NON 49 90-720 1500 1-8 GC-NSD ST 226-170 51
3-ethenylpyridine)

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

206 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Environmental tobacco smoke (respirable particles) ASTM D 5955 varies varies varies GR & FLT 225-3705 108 C/HLD 225-1 116
HPLC-UV & CYC 225-01-02 127 CST 225-3LF 115
HPLC-FD

Environmental tobacco smoke (solanesol, ASTM D 6271 150-3600 2500 1-24 HPLC-UV FLT 225-3705 108 CST 225-3LF 115
respirable particles) CYC 225-01-02 127 C/HLD 225-1 116

Epichlorohydrin NIOSH 1010 LFC 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 48

EPN NIOSH 5012 0.5 mg/m3 480 1000 8 GC-FPD F/CST 225-709 110 C/HLD 225-1 116

1,2-Epoxypropane (see propylene oxide)

tris(2,3-epoxypropyl)isocyanurate OSHA 1024 180 1 3 GC-FID FLT 225-7 110 CST 225-2LF 115
SP 225-27 117 C/HLD 225-1 116

2,4,D-Esters ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Esters I (see specific compounds) NIOSH 1450 varies 1-10 varies varies GC-FID ST 226-01 48

Estradiol OSHA PV2001 240 1000 4 HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

Estriol OSHA PV2001 60 1000 1 HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

Estrone OSHA PV2001 60 1000 1 HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

1,2-Ethanediol (ethylene glycol) (glycols) NIOSH 5523 24 100 4 GC-FID ST 226-57 49

1,2-Ethanediol dinitrate OSHA 43 0.2 (C) 15 1000 15 HPLC-TEA ST 226-35-03 48

Ethanol (ethyl alcohol ) OSHA 5001 1000 12 50 4 ST 226-82 50

Ethanol (ethyl alcohol) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Ethanol (ethyl alcohol) Internal 20.3 ml/min 8-24 hrs SE, GC PS 690-105 96

Ethanolamine OSHA PV2111 3 10 1.5 100 100 100 min 15 HPLC-UV ST 226-30-18 48

3-Ethenylpyridine NON 49 90-720 1500 1-8 GC-NSD ST 226-170 51

3-Ethenylpyridine & nicotine ASTM D 5075 90-2160 1500 1-24 GC-NPD ST 226-93 50

Ethion (Organophosphorus Pesticides) NIOSH 5600 0.4 mg/m3 240 1000 4 GC-FPD ST 226-58 49

Ethoprop (Organophosphorus Pesticides) NIOSH 5600 240 1000 4 GC-FPD ST 226-58 49

2-Ethoxyethanol EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

2-Ethoxyethanol (alcohols IV) NIOSH 1403 0.5 (skin) 1-6 10-50 varies GC-FID ST 226-01 48

2-Ethoxyethanol (CELLOSOLVE solvent) (alcohols NIOSH 1403 0.5 (skin) 1-6 10-50 varies GC-FID ST 226-01 48
IV)

2-Ethoxyethyl acetate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

2-Ethoxyethyl acetate (Esters I) NIOSH 1450 0.5 (skin) 1-10 10-200 varies GC-FID ST 226-01 48

Ethrane (enflurane) OSHA 29 10 100 1.6 GC-FID ST 226-01 48

Ethyl 2-cyanoacrylate OSHA 55 12 100 2 HPLC-UV ST 226-98 50

Ethyl acetate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Ethyl acetate Internal 13.1 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Ethyl acetate Internal 13.1 ml/min 8-24 hrs SE, GC PS 690-105 96

Ethyl acetate NIOSH 1457 400 10 20 8 GC-FID ST 226-01 48

Ethyl acrylate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Ethyl acrylate Internal 13.7 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Ethyl acrylate Internal 13.7 ml/min 8-24 hrs SE, GC PS 690-105 96

Ethyl acrylate NON 54 5 15 10 3 20 200 8 15 GC-FID ST 226-81A 49

Ethyl acrylate OSHA 92 25 12 0.75 50 50 4 15 GC-FID ST 226-73 49

Ethyl acrylate (Esters I) NIOSH 1450 4 (LOQ) 1-10 10-200 varies GC-FID ST 226-01 48

Ethyl alcohol (ethanol) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Ethyl alcohol (ethanol) Internal 20.3 ml/min 8-24 hrs SE, GC PS 690-105 96

Ethyl alcohol (ethanol) OSHA 5001 1000 12 50 4 GC-FID ST 226-82 50

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 207


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Ethyl alcohol (ethanol) (Alcohols I) NIOSH 1400 1000 1 50 20 min GC-FID ST 226-01 48

Ethyl amyl ketone NIOSH 1301 50 25 200 2 GC-FID ST 226-01 48

Ethyl benzene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Ethyl benzene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Ethyl benzene Internal 0.41 ml/min 24 hrs to 7 TD, GC PS 690-101 or PS 690-103 or


days PS 690-104 with RR 690-300 96

Ethyl benzene Internal 12.9 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or
PS 690-104 96

Ethyl benzene Internal 12.9 ml/min 8 hrs-30 SE, GC PS 690-105 96


days

Ethyl benzene OSHA 1002 100 13.83 8 GC-FID PS 575-002 82

Ethyl benzene OSHA 1002 100 12 50 4 GC-FID ST 226-01 48

Ethyl benzene (Hydrocarbons, Aromatic) NIOSH 1501 100 125 1-24 1-24 10-200 10-200 varies varies GC-FID ST 226-01 48

Ethyl bromide (bromoethane) NIOSH 1011 4 20 3.3 GC-FID ST 226-01 48

Ethyl butyl ketone (3-heptanone) (Ketones II ) NIOSH 2553 50 1-25 10-200 varies GC-FID ST NA SKC

Ethyl butyl ketone (3-heptanone) (Ketones II) NIOSH 1301 50 24 200 2 GC-FID ST 226-01 48

Ethyl chloride ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Ethyl chloride NIOSH 2519 3 50 1 GC-FID ST 226-25 48

Ethyl ether (ethyl ether) NIOSH 1610 0.25-3 10-200 varies GC-FID ST 226-01 48

Ethyl formate NIOSH 1452 100 10 20 8 GC-FID ST 226-01 48

Ethyl lactate OSHA PV2081 10 200 50 min GC-FID ST 226-01 48

Ethyl mercaptan (mercaptans) NIOSH 2542 0.5 (15 min) 48 12 100 200 8 60 GC-FPD CF/CST 225-9007 68 C/HLD 225-1 116

Ethyl methacrylate Internal 13.1 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Ethyl methacrylate Internal 13.1 ml/min 8-24 hrs SE, GC PS 690-105 96

Ethyl methacrylate NIOSH 2537 1-8 10-50 varies GC-FID ST 226-30-06 48

Ethyl methacrylate OSHA PV2100 10 20(50) 8(3.3) GC-FID ST 226-01 48

Ethyl O-(p-nitrophenyl) phenylphosphonothionate NIOSH 5012 0.5 mg/m 3


480 1000 8 GC-FPD F/CST 225-709 110 C/HLD 225-1 116
(EPN)

Ethyl parathion ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 54

Ethyl silicate NIOSH S-264 100 9 50 3 GC-FID ST 226-30-04 48

2-Ethyl toluene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

3-Ethyl toluene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

4-Ethyl toluene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Ethyl vinyl benzene OSHA 89 12 50 4 GC-FID ST 226-73 49

Ethyl-3-ethoxypropionate OSHA PV2025 10 100 100 min GC-FID ST 226-01 48

Ethylamine OSHA 36 10 10 200 50 min HPLC-UV ST 226-96 50

Ethylene chlorohydrin NIOSH 2513 1 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-81A 49

Ethylene dibromide (1,2-dibromoethane) NIOSH 1008 0.045 0.13 (15 10 3 20(50) 200 8(3.3) 15 GC-ECD ST 226-01 48
min)

Ethylene dibromide (1,2-dibromoethane) OSHA 02 20 30 10 1 20(50) 200 8(3.3) 5 GC-ECD ST 226-01 48

Ethylene dichloride EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Ethylene dichloride (1,2-dichloroethane) OSHA 03 50 100 10 3 200 200 1 15 GC-ECD ST 226-01GWS 48

Ethylene dichloride (1,2-dichloroethane) NIOSH 1003 1 2 3 3 10-200 10-200 varies varies GC-FID ST 226-01 48
(hydrocarbons, halogenated)

Ethylene glycol (glycols) NIOSH 5523 60 1000 1 GC-FID ST 226-57 49

Ethylene glycol dinitrate OSHA 43 0.2 (C) 15 1000 15 HPLC-TEA ST 226-35-03 48

Ethylene glycol dinitrate (nitroglycerine) NIOSH 2507 0.1 mg/m3 15 1000 15 GC-ECD ST 226-35-03 48

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

208 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Ethylene oxide ASTM D 4413 6 3 100 200 1 15 GC-FID ST 226-16 or ST 226-36 49

Ethylene oxide ASTM D 5578 9.6 1.5 20 100 8 15 GC-ECD ST 226-178 51

Ethylene oxide NIOSH 1614 0.1 5 (10 min) 24 1.5 100 150 4 10 GC-ECD ST 226-178 51

Ethylene oxide OSHA 1010 1 5.0 EL 12 0.75 50 50 4 15 GC-ECD ST 226-178 51

Ethylene oxide (by portable GC) NIOSH 3702 0.1 5 (10 min) varies varies 20-4000 varies varies varies P GC-PID SB 232 Series 61

Ethylene oxide (Qazi-Ketcham) NON 14 10 20(50) 8(3.3) GC ST 226-36 49

Ethylene thiourea NIOSH 5011 LFC 480 2000 4 VAS F/CST 225-802 107 C/HLD 225-1 116

Ethylene thiourea OSHA 95 480 2000 4 HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

Ethylenediamine NIOSH 2540 10 10 100 1.7 HPLC-UV ST 226-30-18 48

Ethylenediamine OSHA 60 10 10 100 100 min HPLC-UV ST 226-30-18 48

Ethylenimine NIOSH 3514 48 200 4 HPLC-UV IMP 225-36-2 70 IT 225-22 70

2-Ethylhexyl acrylate OSHA PV2026 12 100 2 GC-FID ST 226-73 49

di-2-Ethylhexyl phthalate (DEHP) OSHA 104 5 mg/m3 240 1000 4 GC-FID ST 226-56 49

ETS (see environmental tobacco smoke) NON 49

Fenamiphos (Organophosphorus Pesticides) NIOSH 5600 0.1 mg/m3 240 1000 4 GC-FPD ST 226-58 49

Fenvalerate ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Ferric chloride (see iron salts, soluble as Fe) OSHA ID 121

Ferrovanadium dust OSHA ID 125G 1 mg/m3 480 30 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Fibers (bioaerosols) 15-150 15000 1-10 min varies STC 225-9820 114

Fibers (see specific compounds)

Fibrous glass (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Fibrous glass (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Fibrous glass dust OSHA ID 160 15 mg/m3 1 fbr/cc EL 60-300 48 500-2500 1600 120 PCM FLT/CL 225-321 104

Fluometuron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Fluoranthene (Polynuclear Aromatic Hydrocarbons ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
by GC-MS) (max)

Fluoranthene (Polynuclear Aromatic Hydrocarbons NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
by GC) C/HLD 225-1 116

Fluoranthene (Polynuclear Aromatic Hydrocarbons NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 108 ST 226-30-04 48
by HPLC) C/HLD 225-1 116

Fluorene (Polynuclear Aromatic Hydrocarbons ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
by GC-MS) (max)

Fluorene (Polynuclear Aromatic Hydrocarbons NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
by GC) C/HLD 225-1 116

Fluorene (Polynuclear Aromatic Hydrocarbons NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 108 ST 226-30-04 48
by HPLC) C/HLD 225-1 116

Fluoride (particulate) NIOSH 7906 2.5 mg/m3 960 2000 8 IC-CD CF/CST 225-9031 68 C/HLD 225-1 116

Fluorides ASTM D 4765 varies 2000 varies ISE CF/CST 225-9001 68 C/HLD 225-1 116

Fluorides (aerosol & gas by ISE) NIOSH 7902 2.5 mg/m3 6 (HF) 480 22.5 1000 1500 8 15 ISE CF/CST 225-9001 68 C/HLD 225-1 116

Fluorides (as F) OSHA ID 110 2.5 mg/m3 90 22.5 1500 1500 1 15 ISE CF/CST 225-9001 68 C/HLD 225-1 116

Fluorine OSHA ID 110 0.1 480 1000 ISE IMP 225-36-2 70 IT 225-22 70

Fluorotrichloromethane (trichlorofluoromethane) NIOSH 1006 1000 5 20 240 GC-FID ST 226-09 48

Folpet ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Fonofos (Dyfonate) OSHA PV2027 480 1000 8 GC-FPD ST 226-30-16 48

Fonofos (Organophosphorus Pesticides) NIOSH 5600 0.1 mg/m3 240 1000 4 GC-FPD ST 226-58 49

Formaldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

Formaldehyde EPA IP-6A 100-1000 5 min-24 hrs HPLC-UV ST 226-119 or ST 226-120 50


ml/min

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 209


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Formaldehyde EPA IP-6C 20.4 ml/min 7 days HPLC-UV PS 500-100 92

Formaldehyde EPA IP-6C 20.4 ml/min 1-7 days HPLC-UV PS 500-100 92

Formaldehyde EPA IP-6C 20.4 ml/min 15 min-8 HPLC-UV PS 500-100 92


hrs

Formaldehyde EPA TO-11A 28.6 ml/min 15 min-8 HPLC-UV PS 500-100 92


hrs

Formaldehyde EPA TO-11A 28.6 ml/min 7 days HPLC-UV PS 500-100 92

Formaldehyde EPA TO-11A 28.6 ml/min 15 min-24 HPLC-UV PS 500-100 92


hrs

Formaldehyde EPA TO-11A varies 100-2000 varies HPLC-UV ST 226-119 or ST 226-120 50


ml/min

Formaldehyde NIOSH 2016 0.016 0.1 (C) 1-<15 1-<15 30-500 30-500 varies varies HPLC-UV ST 226-119 ♠ 50

Formaldehyde NIOSH 2541 0.016 0.1 (C) 24 1 100 100 4 10 GC-FID ST 226-118 50

Formaldehyde NIOSH 3500 0.016 0.1 96 15 200 1000 8 15 VAS IMP 225-36-1 70 IT 225-22 70
FLT 225-1709 ** 108 CST 225-2LF 115
SCN 225-26 117

Formaldehyde OSHA 1007 0.75 2 13.8 0.43 29.77 29.77 4 15 HPLC-UV PS 500-100 92

Formaldehyde OSHA 52 0.75 2 24 3 100 200 4 15 GC-NPD ST 226-117 or ST 226-54 49

Formaldehyde (Aldehydes, Screening) NIOSH 2539 0.016 0.1 5 20 4 GC-FID & ST 226-118 50
GC-MS

Formaldehyde on dust (textile or wood) NIOSH 5700 0.016 0.1 240 2000 4 HPLC-UV IOM 225-70A 122 FLT 225-5-25 107

Formetanate (Organonitrogen Pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Formic acid NIOSH 2011 5 24 200 2 IC-CD FLT 225-1728A 108 CST 225-3-25LF 115
ST 226-10-03 48 C/HLD 225-1 116

Freon 11 ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Freon 113 OSHA 113 1000 1 50 20 min GC-FID ST NA SKC

Freon 113 (1,1,2-trichloro-1,2,2-trifluoroethane) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Freon 114 ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Freon 12 ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Freon 123 NON 50 9 50 3 GC-FID ST 226-09 48

Freon 141b OSHA 113 1000 1 50 20 min GC-FID ST NA SKC

Fungi NIOSH 0800 varies 28,300 varies varies BI 225-9611 136

Fungi (in air) 15-150 15000 1-10 min varies STC 225-9820 114

Fungi (in air) (BioSampler method) NON 48 62.5-375 12,500 + 5-30 varies BS 225-9595 138 VT 225-9598A 138

Furans (including PHDFs, PCDFs, PBDFs) EPA TO-9A 200-280 L/ 24 hrs HRGC- PUF 226-131 55 FLT 225-1808 109
min HRMS

Furfural EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Furfural NIOSH 2529 5 20 4 GC-FID ST 226-118 50

Furfural OSHA 72 5 180 1000 3 GC-FID ST 226-81A 49

Furfural (Aldehydes, Screening) NIOSH 2539 5 20 4 GC-FID & ST 226-118 50


GC-MS

Furfuryl alcohol NIOSH 2505 10 15 5 20 4 GC-FID ST 226-115 50

Gallium (Elements by ICP HNO3 Digestion) NIOSH 7303 1-3,300 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Gasoline OSHA PV2028 10 1.5 20(50) 100 8(3.3) 15 GC-FID ST 226-01 48

Glass, fibrous (see asbestos fibers) NIOSH 7400

Glutaraldehyde NIOSH 2531 0.2 4 200 20 HPLC-UV ST 226-118 50

Glutaraldehyde NIOSH 2532 0.2 3 200 15 HPLC-UV ST 226-119 50

Glutaraldehyde NON 43 30 15 250 1000 2 15 GC-FID ST 226-10 48

Glutaraldehyde OSHA 64 15 1000 15 HPLC-UV CF/CST 225-9003 68 C/HLD 225-1 116

Glycerin mist (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Glycidol (2,3-epoxy-1-propanol) NIOSH 1608 25 10 20(50) 8(3.3) GC-FID ST 226-01 48

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

210 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Glycol chlorohydrin (see ethylene chlorohydrin)

Glycol ethers NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 49

Glycols NIOSH 5523 60 1000 1 GC-FID ST 226-57 49

Glyphosate OSHA PV2067 100 1000 100 min HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

Gold OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Gold (Elements by ICP HNO3 Digestion) NIOSH 7303 1-3,300 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Graphite (natural) (see Respirable dust) OSHA ID 142 (v4)

Graphite (synthetic) (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Graphite (synthetic) (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Grunerite fibers (see asbestos) OSHA ID 160

Gypsum (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Gypsum (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Hafnium OSHA ID 121 0.5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Halothane OSHA 103 12 50 4 GC-FID ST 226-81A 49

Halothane OSHA 29 9 100 1.5 GC-FID ST 226-01 48

HDI (see hexamethylene diisocyanate)

Heptachlor ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Heptachlor OSHA PV2029 0.5 mg/m3 60 1000 1 GC-ECD ST 226-30-16 48

Heptachlor (non-occupational exposure) ASTM D 4947 240-7200 250 1000-5000 4-24 GC-ECD PUF 226-92 54

Heptachlor epoxide ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Heptanal (Aldehydes, Screening) NIOSH 2539 5 20 4 GC-FID & ST 226-118 50


GC-MS

n-Heptane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

n-Heptane Internal 13.9 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

n-Heptane Internal 13.9 ml/min 8-24 hrs SE, GC PS 690-105 96

3-Heptanone (ethyl butyl ketone) (Ketones II ) NIOSH 2553 50 1-25 10-200 varies GC-FID ST NA SKC

2-Heptanone (methyl n-amyl ketone) (Ketones II ) NIOSH 2553 100 1-25 10-200 varies GC-FID ST NA SKC

Hexachloro-1,3-cyclopentadiene NIOSH 2518 0.01 24 50 8 GC-ECD ST 226-116 50

Hexachlorobenzene ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Hexachlorobutadiene NIOSH 2543 0.02 48 100 8 GC-ECD ST 226-30-04 48

Hexachlorocyclopentadiene ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-124 54

Hexachlorocyclopentadiene (hexachloro-1,3- NIOSH 2518 0.01 48 100 8 GC-ECD ST 226-116 50


cyclopentadiene)

Hexachloroethane (hydrocarbons, halogenated) NIOSH 1003 1 10 10-200 varies GC-FID ST 226-01 48

Hexamethylene diisocyanate NIOSH 5522 35 µg/m 3


140 µg/m 3
360 20 1000 2000 6 10 HPLC-FD IMP 225-36-1 70 IT 225-22 70

1,6-Hexamethylene diisocyanate OSHA 5002 15 1000 15 min HPLC-UV or CF/CST 225-9002 or CF/CST 225-9013 or
HPLC-FD CF/CST 225-9022  68 C/HLD 225-1 116

1,6-Hexamethylene diisocyanate homopolymer OSHA 5002 15 1000 15 min HPLC-UV or CF/CST 225-9002 or CF/CST 225-9013 or
HPLC-FD CF/CST 225-9022  68 C/HLD 225-1 116

Hexamethylene diisocyanate (gaseous) ASTM D 6562 15 1000 15 min HPLC-UV or CF/CST 225-9023 or CF/CST 225-9022  68
HPLC-FD C/HLD 225-1 116

Hexamethylene diisocyanate (HDI) (isocyanates) OR-OSHA 1010 0.02 0.02 45 5 1000 1000 45 min 5 HPLC IMP 225-36-1 70 IT 225-22 70
CF/CST 225-9029 68

Hexamethylene diisocyanate (isocyanates) NIOSH 5521 35 µg/m3 140 µg/m3 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 70 IT 225-22 70
(10 min) (C) ELCHM &
HPLC-UV

1,6-Hexamethylene diisocyanate (isocyanates, NIOSH 5525 35 µg/m3 140 µg/m3 1-500 1000-2000 varies HPLC-UV FLT 225-7 110 CST 225-4 115
total) (10 min) (C) SP 225-27 or IOM 225-76A 122
FLT 225-702 110

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 211


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Hexamethylene diisocyanate (monomeric aerosol) ASTM D 6561 15 1000 15 min HPLC-UV CF/CST 225-9023 or CF/CST 225-9022 ▼ 68
C/HLD 225-1 116

Hexamethylene diisocyanate (monomeric gaseous) ASTM D 6561 15 1000 15 min HPLC-UV CF/CST 225-9023 or CF/CST 225-9022 ▼ 68
C/HLD 225-1 116

Hexamethylene diisocyanate (oligomeric aerosol) ASTM D 6561 15 1000 15 min HPLC-UV CF/CST 225-9023 or CF/CST 225-9022 ▼ 68
C/HLD 225-1 116

Hexamethylene diisocyanate biuret OSHA PV2030 15 1000 15 min HPLC-UV FLT 225-7 110 CST 225-3LF 115
C/HLD 225-1 116

Hexamethylene diisocyanate biuret (HDI-BT) OR-OSHA 1010 1.0 mg/m3 0.5 mg/m3 45 5 1000 1000 45 min 5 HPLC IMP 225-36-1 70 IT 225-22 70
(isocyanates) CF/CST 225-9029 68

Hexamethylene diisocyanate isocyanurate (HDI- OR-OSHA 1010 1.0 mg/m3 0.5 mg/m3 45 5 1000 1000 45 min 5 HPLC IMP 225-36-1 70 IT 225-22 70
IC) (isocyanates) CF/CST 225-9029 68

Hexamethylenetetramine NON 52 15 1000 15 min GC-NPD or ST 226-57 49


GC-FID

Hexanal ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120 or ST 226-119 50

Hexanal (Aldehydes, Screening) NIOSH 2539 5 20 4 GC-FID & ST 226-118 50


GC-MS

n-Hexane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

n-Hexane Internal 14.3 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

n-Hexane Internal 14.3 ml/min 8-24 hrs SE, GC PS 690-105 96

n-Hexane NIOSH 1500 50 4 200 20 (min) GC-FID ST 226-01 48

n-Hexane OSHA 5000 500 4.9 50 1.63 GC-FID ST 226-01 48

1,6-Hexanediol NIOSH 1500 5 3 200 200 GC-FID ST 226-01 48

Hexanediol diacrylate NON 39 480 1000 8 GC-FID ST 226-56 49

1,6-Hexanediol diacrylate OSHA PV2133 1 mg/m3 48 200 4 GC-FID ST 226-110 50

2-Hexanone (Ketones I) NIOSH 2555 1-10 10-200 varies GC-FID ST NA SKC

2-Hexanone (methyl butyl ketone) (Ketones I) NIOSH 1300 1 10 20(50) 8(3.3) GC-FID ST 226-01 48

2-Hexanone (methyl butyl ketone, MBK) Internal 14.3 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

2-Hexanone (methyl butyl ketone, MBK) Internal 14.3 ml/min 8-24 hrs SE, GC PS 690-105 96

Hexavalent chromium ASTM D 6832 varies 1000-5000 varies IC F/CST 225-802 or F/CST 225-1713 or
F/CST 225-709 or F/CST 225-401 109

Hexavalent chromium NIOSH 7600 1 µg/m3 240 1000 4 VAS F/CST 225-802 107 C/HLD 225-1 116
(10 hrs)

Hexavalent chromium NIOSH 7604 1 µg/m3 240 1000 4 IC-CD F/CST 225-802 107 C/HLD 225-1 116
(10 hrs)

Hexavalent chromium NIOSH 7605 0.001 mg/m3 1-400 1000-4000 varies IC-PCD-UV F/CST 225-802 107 C/HLD 225-1 116
(10 hrs)

Hexavalent chromium NIOSH 7703 0.001 mg/m3 10-1200 1000-4000 varies P VAS F/CST 225-802 107 C/HLD 225-1 116
(10 hrs)

Hexavalent chromium OSHA ID 103 0.005 mg/ 960 30 2000 2000 8 15 DPP F/CST 225-802 107 C/HLD 225-1 116
m3 (C)

Hexavalent chromium OSHA W4001 0.005 mg/ IC-UV FLT 225-5-37 or FLT 225-1822 109
m3 (C)

Hexavalent chromium (CR(VI)) OSHA ID 215 0.005 mg/m3 960 2000 8 IC-UV F/CST 225-802 107 C/HLD 225-1 116
(V2)

Hexavalent chromium (in settled dust) NIOSH 9101 bulk bulk CLR or VAS
or IC

Hexone EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Hexone OSHA 1004 100 13.62 8 GC-FID PS 575-002 82

Hexone OSHA 1004 100 12 50 4 GC-FID ST NA SKC

Hexone (Ketones I) NIOSH 2555 50 1-10 10-200 varies GC-FID ST NA SKC

Hexone (methyl isobutyl ketone) (Ketones I) NIOSH 1300 50 75 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 48

sec-Hexyl acetate NIOSH 1450 50 10 200 50 (min) GC-FID ST 226-01 48

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

212 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Hexylene glycol OSHA PV2101 3 200 15 GC-FID ST 226-01 48

HMX OSHA PV2032 480 1000 8 HPLC-UV F/CST 225-709 110 C/HLD 225-1 116

Hydrazine NIOSH 3503 0.03 (120 90 1000 1.5 VAS IMP 225-36-2 70 IT 225-22 70
min)

Hydrazine NON 22 96 200 8 CLR ST 226-42-02 49

Hydrazine OSHA 108 1 240 1000 4 LC-UV CF/CST 225-9012 68 C/HLD 225-1 116

Hydrazine OSHA 20 1 20 100 3.3 HPLC-UV ST 226-42-02 49

Hydrazoic acid NON 25 15 1000 15 HPLC-UV ST 226-55 49

Hydrazoic acid OSHA ID 211 5 1000 5 IC-UV ST 226-55 49 FLT 225-5-37-P 107
CST 225-2LF 115 SPC 225-23 117
C/HLD 225-1 116

Hydrocarbons BP 36 to 216 C (see specific NIOSH 1500 varies varies varies varies GC-FID ST 226-01 48
compounds)

Hydrocarbons, aromatic (see specific compounds) NIOSH 1501 varies varies varies varies GC-FID ST 226-01 48

Hydrocarbons, halogenated (see specific NIOSH 1003 varies varies varies varies GC-FID ST 226-01 48
compounds)

Hydrofluoric acid (fluorides) NIOSH 7906 3 6 960 30 2000 2000 8 15 IC-CD CF/CST 225-9031 68 C/HLD 225-1 116

Hydrogen bromide NIOSH 7907 3 30 2000 15 IC-CD CF/CST 225-9032 68

Hydrogen bromide OSHA ID 3 97 3 200 200 8 15 IC ST 226-10-03 48


165SG

Hydrogen chloride NIOSH 7907 5 30 2000 15 IC-CD CF/CST 225-9032 68

Hydrogen chloride (hydrochloric acid) OSHA ID 5 7.5 500 15 IC ST 226-10-03 48


174SG

Hydrogen cyanide NIOSH 6010 4.7 2-90 50-200 varies VAS ST 226-210 52 CST 225-710 110

Hydrogen cyanide NIOSH 6017 4.7 2-90 50-200 varies IC/ELCM ST 226-210 52 CST 225-710 110

Hydrogen cyanide OSHA 1015 10 28.4 8 15 IC-ELCM PS 590-400 94

Hydrogen cyanide OSHA ID 120 10 120 15 1000 1000 2 15 ISE CST 225-3LF 115 IMP 225-36-2 70
IT 225-22 70 FLT 225-5 102
SP 225-2902 117

Hydrogen cyanide (cyanides) NIOSH 7904 5 mg/m3 15 1000 15 ISE FLT 225-3705 ∆ 108 CST 225-2LF 115
(10 min) IMP 225-36-2 70 IT 225-22 70
C/HLD 225-1 116

Hydrogen fluoride NIOSH 7906 3 6 960 30 2000 2000 8 15 IC-CD CF/CST 225-9031 68 C/HLD 225-1 116

Hydrogen fluoride (as F) OSHA ID 110 3 6 90 22 1500 1500 1 15 ISE CF/CST 225-9001 68 C/HLD 225-1 116

Hydrogen fluoride (fluorides) NIOSH 7902 3 6 480 30 1000 2000 8 15 ISE CF/CST 225-9001 68 C/HLD 225-1 116

Hydrogen peroxide OSHA 1019 1.0 (1.4 240 30 1000 2000 4 15 VAS CF/CST 225-9030 68 C/HLD 225-1 116
mg.m3)

Hydrogen sulfide NIOSH 6013 10 (10 min) 24 3 100 300 4 10 IC ST NA SKC

Hydrogen sulfide NON 42 12 1000 12 min GC-FPD SB 231-10 60

Hydrogen sulfide OSHA 1008 10 20 12 7.5 50 500 4 15 IC ST 226-177 51

Hydroquinone NIOSH 5004 2 mg/m3 30 2000 15 HPLC-UV F/CST 225-3-01 102 C/HLD 225-1 116
(15 min)

Hydroquinone OSHA PV2094 2 mg/m3 20 200 100 min HPLC-UV ST 226-98 50

4-Hydroxy-4-methyl-2-pentanone (see diacetone


alcohol)

4-Hydroxy-4-methyl-2-petanone (alcohols NIOSH 1405 50 1-10 10-200 varies GC-FID ST 226-01 48


combined)

2-Hydroxypropyl acrylate OSHA PV2078 10 100 100 min GC-FID ST 226-73 49

2-Imidazolidinethione (ethylene thiourea) NIOSH 5011 LFC 480 1000 8 VAS F/CST 225-803 107 C/HLD 225-1 116

Indeno(1,2,3-cd)pyrene (Polynuclear Aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Indeno(1,2,3-cd)pyrene (Polynuclear Aromatic ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Hydrocarbons by GC-MS) (max)

Indeno(1,2,3-cd)pyrene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 213


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Indium OSHA ID 121 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Indium & compounds (as In) OSHA ID 121 0.1 mg/m3 480-960 2000 4-8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Indium (Elements by Cellulosic Internal Capsule NIOSH 7306 0.1 mg/m3 8-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Indium (Elements by ICP HNO3 Digestion) NIOSH 7303 15-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Iodine NIOSH 6005 0.1 15 1000 15 IC ST 226-67 49

Iodine NON 16 48 100 8 IC ST 226-67 49

Iodine OSHA ID 212 0.1 (C) 2.5 500 5 IC ST 226-80 49

Iodine (particulates) OSHA ID 212 0.1 2.5 500 5 IC ST 226-142 51

Iodine (vapor) OSHA ID 212 0.1 2.5 500 5 IC ST 226-80 49

Iron OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Iron & compounds (as Fe) OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Iron (bulk) OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Iron (Elements by Cellulosic Internal Capsule NIOSH 7306 5 mg/m3 2-500 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler) (dust,
fume)
as Fe

Iron (Elements by ICP Aqua Regia Ashing) NIOSH 7301 5 mg/m3 5-100 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
(dust, C/HLD 225-1 116
fume)

Iron (Elements by ICP HNO3 Digestion) NIOSH 7303 0.5 mg/m3 1-5,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
(dust,
fume)

Iron (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 5 mg/m3 5-100 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
(dust,
fume)

Iron (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Iron oxide (Elements by ICP HNO3 Digestion) NIOSH 7303 1-5,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Iron oxide fume OSHA ID 121 10 mg/m 3


960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Iron oxide fume OSHA ID 125G 10 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Iron salts, soluble (as Fe) OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Isoamyl acetate (Esters I) NIOSH 1450 100 1-10 10-200 varies GC-FID ST 226-01 48

Isoamyl alcohol (alcohols combined) NIOSH 1405 100 125 (skin) 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 48

Isoamyl alcohol (alcohols III) NIOSH 1402 100 125 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 48

Isobutanol (isobutyl alcohol) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Isobutyl acetate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Isobutyl acetate OSHA 1009 150 13.16 13.16 8 15 GC-FID PS 575-002 82

Isobutyl acetate OSHA 1009 150 12 0.75 50 50 4 15 GC-FID ST 226-01 48

Isobutyl acetate (Esters I) NIOSH 1450 150 1-10 10-200 varies GC-FID ST 226-01 48

Isobutyl alcohol OSHA 5001 200 12 4 GC-FID ST 226-82 50

Isobutyl alcohol (alcohols combined) NIOSH 1405 50 2-10 10-200 varies GC-FID ST 226-01 48

Isobutyl alcohol (alcohols II) NIOSH 1401 50 10 20(50) 8(3.3) GC-FID ST 226-01 48

Isobutyl alcohol (isobutanol) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Isobutyl isobutyrate OSHA PV2090 10 200 50 min GC-FID ST 226-01 48

Isobutyraldehyde (Aldehydes, Screening) NIOSH 2539 5 20 4 GC-FID & ST 226-118 50


GC-MS

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

214 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Isocyanates (see specific isocyanate) NIOSH 5521 varies 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 70 IT 225-22 70
ELCHM &
HPLC-UV

Isocyanates (see specific isocyanate) NIOSH 5522 varies varies 360 20 1000 2000 6 10 HPLC-FD IMP 225-36-1 70 IT 225-22 70

Isocyanates (see specific isocyanate) OR-OSHA 1010 varies varies 45 5 1000 1000 45 min 5 HPLC IMP 225-36-1 70 IT 225-22 70
CF/CST 225-9029 68

Isocyanates, total (see specific isocyanate) NIOSH 5525 varies varies 1-500 1-500 1000-2000 1000-2000 varies varies HPLC-UV FLT 225-7 ‡ 110 CST 225-4 115
SP 225-27 or IOM 225-76A 122
FLT 225-702 ‡ 110

Isoflurane OSHA 103 12 50 4 GC-FID ST 226-81A 49

Isooctyl alcohol OSHA PV2033 100 10 20(50) 8(3.3) GC-FID ST 226-01 48

Isophorone NIOSH 2508 4 10 20(50) 8(3.3) GC-FID ST 226-81A 49

Isophorone NIOSH 2556 4 2-25 10-100 varies GC-FID ST 226-93 50

Isophorone (3,5,5-trimethylcyclohex-2-enone) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Isophorone (3,5,5-trimethylcyclohex-2-enone) Internal 11.3 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-104 96

Isophorone diisocyanate OSHA 5002 60 15 1000 1000 1 15 HPLC-UV CF/CST 225-9002 or CF/CST 225-9022 ▼ 68
C/HLD 225-1 116

Isophorone diisocyanate (IPDI) OR-OSHA 1010 0.02 0.02 45 5 1000 1000 45 min 5 HPLC IMP 225-36-1 70 IT 225-22 70
CF/CST 225-9029 68

Isophorone diisocyanate (isocyanates, total) NIOSH 5525 45 µg/m3 180 µg/m3 1-500 1000-2000 varies HPLC-UV FLT 225-7 ‡ 110 CST 225-4 115
(10 min) C SP 225-27 or IOM 225-76A 122
FLT 225-702 ‡ 110

Isopropanol (isopropyl alcohol) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Isopropanol (isopropyl alcohol) Internal 18.4 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Isopropanol (isopropyl alcohol) Internal 18.4 ml/min 8-24 hrs SE, GC PS 690-105 96

Isopropyl acetate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Isopropyl acetate NIOSH 1454 9 50 3 GC-FID ST 226-01 48

Isopropyl acetate NIOSH 1460 0.1-9 20-200 varies GC-FID ST 226-01 48

Isopropyl alcohol OSHA 5001 200 12 4 GC-FID ST 226-82 50

Isopropyl alcohol (Alcohols I) NIOSH 1400 400 500 3 3 20 200 2.5 15 GC-FID ST 226-01 48

Isopropyl alcohol (isopropanol) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Isopropyl alcohol (isopropanol) Internal 18.4 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Isopropyl alcohol (isopropanol) Internal 18.4 ml/min 8-24 hrs SE, GC PS 690-105 96

Isopropyl amine OSHA PV2126 5 20 100 200 min HPLC ST 226-30-18 48

N-Isopropyl aniline OSHA 78 100 1000 100 min HPLC-UV CF/CST 225-9004 68 C/HLD 225-1 116

Isopropyl benzen (cumene) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Isopropyl Benzene (cumene) Internal 12.8 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-104 96

Isopropyl Benzene (cumene) Internal 12.8 ml/min 8-24 hrs SE, GC PS 690-105 96

Isopropyl ether NIOSH 1618 500 0.1-3 10-50 varies GC-FID ST 226-01 48

Isopropyl glycidyl ether NIOSH 1620 50 (15 min) 3 200 15 GC-FID ST 226-01 48

Isovaleraldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

Isovaleraldehyde (Aldehydes, Screening) NIOSH 2539 5 20 4 GC-FID & ST 226-118 50


GC-MS

Kaolin (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Kaolin (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Kathon 886 (kathon biocide) NON 55 50 7.5 200 500 4 15 HPLC-UV ST 226-99 50

Kepone NIOSH 5508 1 µg/m 3


480 1000 8 GC-ECD F/CST 225-3-01 102 IMP 225-36-1 70
IT 225-22 70

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 215


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Kerosene OSHA PV2139 20 100 200 min GC-FID ST 226-01 48

Kerosene (naphthas) NIOSH 1550 100 mg/m3 10 20(50) 8(3.3) GC-FID ST 226-01 48

Ketones EPA TO-5 < 80 L 100-1000 HPLC-UV IMP 225-36-1 70 IT 225-22 70


ml/min

Ketones (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 52

Ketones I (see specific compounds) NIOSH 1300 varies varies 10-200 varies GC-FID ST 226-01 48

Ketones I (see specific compounds) NIOSH 2555 varies varies varies GC-FID ST NA SKC

Ketones II (see specific compounds) NIOSH 1301 varies varies varies 8 GC-FID ST 226-01 48

Ketones II (see specific ketone) NIOSH 2553 varies varies 1-25 1-25 10-200 10-200 varies varies GC-FID ST NA SKC

Lanthanum (Elements by Cellulosic Internal NIOSH 7306 Varies 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Capsule Sampler)

Lanthanum (Elements by ICP Aqua Regia Ashing) NIOSH 7301 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Lanthanum (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Lanthanum (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Lasso (aroclor) OSHA PV2035 100 1000 100 min HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

Lead NIOSH 7082 < 0.1 mg/ 720 1500 8 AAS-F F/CST 225-3-01 102 C/HLD 225-1 116
m3

Lead NIOSH 7105 < 0.1 mg/ 720 1500 8 AAS-GF F/CST 225-3-01 102 C/HLD 225-1 116
m3

Lead (by field portable XRF) NIOSH 7702 < 0.1 mg/ 960 2000 8 XRF F/CST 225-3-01 102
m3

Lead (by portable ultrasound extraction/ASV) NIOSH 7701 0.05 mg/m3 20-1500 1000-4000 varies P ASV F/CST 225-3-01 102 C/HLD 225-1 116

Lead (Elements by Cellulosic Internal Capsule NIOSH 7306 0.05 mg/m3 4-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Lead (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.05 mg/m3 50-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Lead (Elements by ICP HNO3 Digestion) NIOSH 7303 0.5 mg/m3 35-100,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Lead (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.05 mg/m3 50-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Lead (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Lead (ICP analysis of metal/metalloid particulates OSHA ID 206 480 2000 4 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
from solder operations)

Lead (in dust wipes) NIOSH 9105 SPOT W 550-001 or W 550-002 171

Lead (in surface dust) ASTM E 1792 bulk varies W 225-2414 172

Lead (in surface dust) OSHA ID 125G wipe ICP-AES W 225-2414 172

Lead (in workplace air) ASTM D 6785 varies varies varies AAS-F IOM 225-70A 122 FLT 225-1930 102

Lead (on surfaces) NIOSH 9100 AA-F or AA- W 225-2401A 172


GF or ICP

Lead chromate (CR(VI)) OSHA ID 215 0.005 960 2000 8 IC-UV F/CST 225-802 Ω 107 C/HLD 225-1 116
(V2) mg/m3

Lead oxide (as lead) NIOSH 7082 < 0.1 mg/m3 720 1500 8 AAS-F F/CST 225-3-01 102 C/HLD 225-1 116

Lead oxide (as Pb) NIOSH 7105 < 0.1 mg/m3 720 1500 8 AAS-GF F/CST 225-3-01 102 C/HLD 225-1 116

Lead oxide (by field portable XRF) NIOSH 7702 < 0.1mg/m3 960 2000 8 XRF F/CST 225-3-01 102

Lead oxide (by portable ultrasound extraction/ASV) NIOSH 7701 0.05 mg/m 3
20-1500 1000-4000 varies P ASV F/CST 225-3-01 102 C/HLD 225-1 116

Lead sulfide (as Pb) NIOSH 7505 < 0.1 mg/m3 750 2500 5 XRD F/CST 225-803 107 C/HLD 225-1 116
CYC 225-01-02 127

Lead, inorganic fumes & dusts (as Pb) OSHA ID 121 0.05 mg/m3 960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Lead, inorganic fumes & dusts (as Pb) OSHA ID 125G 0.05 mg/m3 480 30 2000 15 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Lead, inorganic surface dusts (as Pb) OSHA ID 121 AA or AES W 225-2401A 172

Limestone (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

216 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Limestone (see calcium carbonate)

Limestone (see Particulates Not Otherwise


Regulated, total and respirable)

Limonene OSHA PV2036 10 20(50) 8(3.3) GC-FID ST 226-01 48

Limonene (terpenes) NIOSH 1552 24 50 8 GC-FID ST 226-01 48

Lindane (gamma-BHC) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Linuron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Lithium OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Lithium (Elements by Cellulosic Internal Capsule NIOSH 7306 Varies 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Lithium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 100-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Lithium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 100-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Lithium hydride (as Li) OSHA ID 121 0.025 mg/ 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116
m3

Lithium hydroxide (alkaline dust) NIOSH 7401 960 2000 8 TITRA F/CST 225-1715 108 C/HLD 225-1 116

Lithium hydroxide (as Li) OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Magnesite (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Magnesite (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Magnesium OSHA ID 121 960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Magnesium (Elements by Cellulosic Internal NIOSH 7306 1-330 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Capsule Sampler)

Magnesium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 10 mg/m3 5-67 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 107
(fume, as C/HLD 225-1 116
oxide)

Magnesium (Elements by ICP HNO3 Digestion) NIOSH 7303 1-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Magnesium (Elements by ICP HNO3/HClO4 NIOSH 7300 10 mg/m3 5-67 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
Ashing) (fume, as
oxide)

Magnesium oxide (as Mg, elements by ICP) NIOSH 7303 10 5-33,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Magnesium oxide fume (respirable dust) OSHA ID 121 5 mg/m3 960 2000 8 GR & AA or F/CST 225-3-01 102 C/HLD 225-1 116
GR & AES CYC 225-105 126

Magnesium oxide fume (total dust) OSHA ID 121 15 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Malathion ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 54

Malathion OSHA 62 15 mg/m3 60 1000 1 GC-FPD ST 226-30-16 48

Malathion (Organophosphorus Pesticides) NIOSH 5600 10 mg/m3 60 1000 1 GC-FPD ST 226-58 49

Maleic anhydride EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Maleic anhydride NIOSH 3512 0.25 360 1000 6 HPLC-UV IMP 225-36-2 70 IT 225-22 70

Maleic anhydride OSHA 86 0.25 60 500 2 HPLC-UV CF/CST 225-9021 †† 68 C/HLD 225-1 116

Maneb OSHA 107 500 2000 250 HPLC-UV F/CST 225-3-01 102 C/HLD 225-1 116

Manganese & compounds (as Mn) OSHA ID 121 5 mg/m3 (C) 960 10 2000 2000 8 5 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Manganese & compounds (as Mn) OSHA ID 125G 5 mg/m3 10 2000 5 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Manganese (Elements by Cellulosic Internal NIOSH 7306 1 mg/m3 3 mg/m3 1-1000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Capsule Sampler)

Manganese (Elements by ICP Aqua Regia Ashing) NIOSH 7301 1 mg/m3 3 mg/m3 5-200 5-200 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Manganese (Elements by ICP HNO3 Digestion) NIOSH 7303 1 mg/m3 3 mg/m3 0.05-10,000 0.05- 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
10,000

Manganese (Elements by ICP HNO3/HClO4 NIOSH 7300 1 mg/m3 3 mg/m3 5-200 5-200 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
Ashing)

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 217


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Manganese (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Manganese fume OSHA ID 125G 5 mg/m3 480 30 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Manganese fume (as Mn) OSHA ID 121 5 mg/m3 (C) 960 10 2000 2000 8 5 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Manganese in welding fume NON 58 5 mg/m3 varies 750 varies GR FLT 225-8050 102 CST 225-6201 119
C/HLD 225-6200 119

Manganese tetroxide (as Mn) OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Manganese tetroxide (as Mn) OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Marble (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Marble (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Marble (see Particulates Not Otherwise Regulated,


total and respirable)

MDI (4,4-methylene bisphenyl isocyanate) OSHA 47 50 µg/m3 200 µg/m3 10 1000 10 HPLC-UV CF/CST 225-9002 or CF/CST 225-9013 68
C/HLD 225-1 116

MDI (4,4-methylenebis[phenyl isocyanate]) NIOSH 5525 50 µg/m3 200 µg/m3 1-500 1000-2000 varies HPLC-UV FLT 225-7 ‡ 110 CST 225-4 115
(isocyanates, total) (10 min) C SP 225-27 or IOM 225-76A 122
FLT 225-702 ‡ 110

MDI (4,4’-methylenebisphenyl isocyanate) NIOSH 5521 50 µg/m3 200 µg/m3 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 70 IT 225-22 70
(isocyanates) (10 min) C ELCHM &
HPLC-UV

MEK (see methyl ethyl ketone)

Mercaptans (see specific compounds) NIOSH 2542 0.5 (15 min) 48 12 100 200 8 60 GC-FPD CF/CST 225-9007 68 C/HLD 225-1 116

Mercury NIOSH 6009 0.05 mg/m 3


48 200 4 AA ST 226-17-1A 48 F/CST 225-3-01 102

Mercury (Rathje & Marcero) NON 17 48 100 8 AA ST 226-17-1A 48

Mercury (Rathje & Marcero) NON 17 varies 1000-3000 varies AA ST 226-17-3A 48

Mercury (vapor) OSHA ID 140 0.1 mg/m3 3-100 200 varies AA ST 226-17-1A 48 F/CST 225-3-01 102

Mercury, Particulate (in Workplace Atmospheres, OSHA ID 145 0.01 mg/m 3


30 2000 15 AA F/CST 225-3-01 102 C/HLD 225-1 116
air samples)

Mercury, Particulate (in Workplace Atmospheres, OSHA ID 145 0.01 mg/m3 wipe SM TB 225-24 172
wipe samples)

Mesityl oxide (Ketones II ) NIOSH 2553 10 1-25 10-200 varies GC-FID ST NA SKC

Mesityl oxide (Ketones II) NIOSH 1301 10 10 20(50) 8(3.3) GC-FID ST 226-01 48

Mesitylene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Mestranol OSHA PV2068 480 2000 4 HPLC F/CST 225-802 107 C/HLD 225-1 116

Metal & metalloid particulates OSHA ID 121 varies varies 960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Metal & metalloid particulates OSHA ID 125G varies varies 480 30 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Metal & metalloid particulates (bulk sample) OSHA ID 125G varies varies bulk bulk ICP-AES SM TB 225-24 172

Metal removal fluid (aerosol) ASTM D 7049 960 2000 8 GR FLT 225-37-07 108 CST 225-2LF 115
C/HLD 225-1 116 SP 225-27 117

Metal working fluids (aerosols) ASTM D 7049 960 2000 8 GR FLT 225-37-07 108 CST 225-2LF 115
C/HLD 225-1 116 SP 225-27 117

Metals (ICP analysis of metal/metalloid particulates OSHA ID 206 varies varies bulk bulk ICP-AES SM TB 225-24 172
from solder operations) (bulk sample)

Metals (in settled dust) ASTM D 6966 wipe wipe wipe varies W 225-2414 172 TMP 225-2415 172

Metals in workplace atmospheres ASTM D 4185 varies 2000 varies AAS F/CST 225-3-01 102 C/HLD 225-1 116

Metals, trace (Elements by ICP HNO3/HClO4 NIOSH 7300 varies varies varies varies 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
Ashing)

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

218 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Metalworking fluids (thoracic particulates) NIOSH 5524  0.4 mg/m3 2000 varies varies GR PPI 225-381 130 FLT 225-37-07 108
(thoracic IS 225-388 130 SP 225-27 or
particulates) SCN 225-26 117

Metalworking fluids (total particulates) NIOSH 5524  0.5 mg/m3 1000 (min) 2000 varies GR FLT 225-37-07 108 CST 225-2LF 115
(total particulates) C/HLD 225-1 116 SP 225-27 117

Methacrylic acid OSHA PV2005 20 20 100 4 LC-UV ST 226-30-08 48

Methacrylic acid NON 60 24 100 4 HPLC-UV ST 226-30-08 48

Methamidophos (Organophosphorus Pesticides) NIOSH 5600 240 1000 4 GC-FPD ST 226-58 49

Methanol (methyl alcohol) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methanol (methyl alcohol) NIOSH 2000 200 250 5 3 20 200 4 15 GC-FID ST 226-51 49

Methidathion OSHA PV2074 60 1000 1 GC-ECD ST 226-58 49

Methiocarb (Organonitrogen Pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Methomyl OSHA PV2114 60 1000 1 HPLC-UV ST 226-30-16 48

Methomyl (Organonitrogen Pesticides) NIOSH 5601 2.5 mg/m3 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Methotrexate OSHA PV2146 120 1000 2 HPLC-UV ST 226-30-16 48

2-Methoxy-1-propanol OSHA 99 10 100 100 min GC-FID ST 226-01 48

2-Methoxy-1-propyl acetate OSHA 99 10 100 100 min GC-FID ST 226-01 48

1-Methoxy-2-propanol OSHA 99 10 100 100 min GC-FID ST 226-01 48

1-Methoxy-2-propanol (glycol ethers) NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 49

1-Methoxy-2-propyl acetate OSHA 99 10 100 100 min GC-FID ST 226-01 48

1-Methoxy-2-propyl acetate (glycol ethers) NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 49

Methoxychlor ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Methoxychlor OSHA PV2038 15 mg/m3 60 1000 1 GC-ECD ST 226-30-16 48

2-Methoxyethanol EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

2-Methoxyethanol (methyl CELLOSOLVE solvent) NIOSH 1403 0.1 (skin) 6-50 10-50 varies GC-FID ST 226-01 48
(alcohols IV)

2-Methoxyethyl acetate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

2-Methoxyethyl acetate OSHA 53 25 10 100 100 min GC-FID ST 226-01 48

2-Methoxyphenol OSHA PV2039 20 200 100 min GC-FID ST 226-95 50

3-Methoxyphenol OSHA PV2039 20 200 100 min GC-FID ST 226-95 50

4-Methoxyphenol OSHA PV2039 20 200 100 min GC-FID ST 226-95 50

Methoxypropanol EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methyl acetate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methyl acetate NIOSH 1458 200 250 5 3 20 200 4 15 GC-FID ST 226-01 48

Methyl acrylate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methyl acrylate Internal 15.7 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Methyl acrylate Internal 15.7 ml/min 8-24 hrs SE, GC PS 690-105 96

Methyl acrylate NIOSH 1459 10 5 20 4 GC-FID ST 226-01 48

Methyl acrylate NIOSH 2552 10 1-5 10-200 varies GC-FID ST NA SKC

Methyl acrylate NON 54 5 15 10 3 20 200 8 15 GC-FID ST 226-81A 49

Methyl acrylate OSHA 92 10 12 50 4 GC-FID ST 226-73 49

Methyl acrylonitrile OSHA 37 20 200 100 min GC-NPD ST 226-01 48

Methyl alcohol (methanol) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methyl alcohol (methanol) NIOSH 2000 200 250 5 3 20 200 4 15 GC-FID ST 226-51 49

Methyl alcohol (RH < 50% @ 25 C) OSHA 5001 200 3 50 1 GC-FID ST 226-82 50

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 219


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Methyl alcohol (RH > 50% @ 25 C) OSHA 5001 200 5 50 100 min GC-FID ST 226-82 50

Methyl amine OSHA 40 10 10 20 8 HPLC-UV ST 226-96 50

Methyl arsonic acid (arsenic, organo-) NIOSH 5022 480 1000 8 IC-AA FLT 225-17-01 108 CST 225-2LF 115
C/HLD 225-1 116

Methyl bromide ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Methyl bromide NIOSH 2520 LFC 1-5 10-100 varies GC-AED ST 226-82 50 ST 226-44-02 49

Methyl bromide OSHA PV2040 20 3 200 15 GC-FID ST 226-82 50

Methyl butyl ketone (Ketones I) NIOSH 2555 1-10 10-200 varies GC-FID ST NA SKC

Methyl butyl ketone (MBK, 2-hexanone) Internal 14.3 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Methyl butyl ketone (MBK, 2-hexanone) Internal 14.3 ml/min 8-24 hrs SE, GC PS 690-105 96

Methyl butyl ketone (MBK, 2-hexanone) (Ketones I) NIOSH 1300 1 10 20(50) 8(3.3) GC-FID ST 226-01 48

Methyl CELLOSOLVE acetate (2-methoxyethyl NIOSH 1451 0.1 12 50 4 GC-FID ST 226-01 48


acetate)

Methyl CELLOSOLVE solvent (2-methoxyethanol) NIOSH 1403 0.1 (skin) 6-50 10-50 varies GC-FID ST 226-01 48
(alcohols IV)

Methyl chloride ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Methyl chloride NIOSH 1001 LFC 0.5 100 5 GC-FID ST 226-09 48 ST 226-01 48

Methyl chloroform ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Methyl chloroform (1,1,1-Trichloroethane) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methyl chloroform (1,1,1-Trichloroethane) Internal 14.1 ml/min 8-24 hrs SE, GC PS 690-105 96

Methyl chloroform (1,1,1-trichloroethane) OSHA 14 350 3 3 20 200 2.5 15 GC-FID ST 226-01 48

Methyl chloroform (1,1,1-trichloroethane) NIOSH 1003 350 3 10-200 varies GC-FID ST 226-01 48
(hydrocarbons, halogenated)

Methyl cyclohexane Internal 14.2 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Methyl cyclohexane Internal 14.2 ml/min 8-24 hrs SE, GC PS 690-105 96

Methyl cyclohexane (hydrocarbons, BP 36 to NIOSH 1500 400 4 10-200 varies GC-FID ST 226-01 48
216 C)

Methyl ethyl ketone EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methyl ethyl ketone Internal 16.9 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Methyl ethyl ketone Internal 16.9 ml/min 8-24 hrs SE, GC PS 690-105 96

Methyl ethyl ketone OSHA 1004 200 12 50 4 GC-FID ST NA SKC

Methyl ethyl ketone (Ketones I) NIOSH 2555 1-10 10-200 varies GC-FID ST NA SKC

Methyl ethyl ketone (MEK) (see 2-butanone)

Methyl ethyl ketone (MEK) (see 2-butanone) NIOSH 2500 200 300 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-81A 49

Methyl ethyl ketone (MEK, 2-butanone) OSHA 1004 200 16.88 8 GC-FID PS 575-002 82

Methyl ethyl ketone peroxide NIOSH 3508 0.2 (15 min) 120 1000 120 VAS IMP 225-36-1 70 IT 225-22 70

Methyl ethyl ketone peroxide OSHA 77 15 1000 15 HPLC-UV ST 226-93 50

Methyl formate OSHA PV2041 100 3 50 1 GC-FID ST 226-83 50

Methyl iodide NIOSH 1014 2 48 100 8 GC-FID ST 226-01 48

Methyl isoamyl acetate (Esters I) NIOSH 1450 50 1-10 10-200 varies GC-FID ST 226-01 48

Methyl isoamyl ketone OSHA PV2042 100 24 50 8 GC-FID ST 226-01 48

Methyl isobutyl carbinol (methyl amyl alcohol) NIOSH 1405 25 40 (skin) 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 48
(alcohols combined)

Methyl isobutyl carbinol (methyl amyl alcohol) NIOSH 1402 25 40 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 48
(Alcohols III)

Methyl isobutyl ketone EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methyl isobutyl ketone Internal 13.5 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Methyl isobutyl ketone Internal 13.5 ml/min 8-24 hrs SE, GC PS 690-105 96

Methyl isobutyl ketone OSHA 1004 100 12 50 4 GC-FID ST NA SKC

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

220 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Methyl isobutyl ketone (hexone) OSHA 1004 100 13.62 8 GC-FID PS 575-002 82

Methyl isobutyl ketone (hexone) (Ketones I) NIOSH 1300 50 75 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 48

Methyl isobutyl ketone (Ketones I) NIOSH 2555 50 1-10 10-200 varies GC-FID ST NA SKC

Methyl isocyanate (MIC) OSHA 54 0.02 15 50 5 HPLC-FD ST NA SKC

Methyl mercaptan NIOSH 2542 0.5 (15 min) 48 12 100 200 8 60 GC-FPD CF/CST 225-9007 68 C/HLD 225-1 116

Methyl mercaptan NON 42 12 1000 12 min GC-FPD SB 231-10 60

Methyl mercaptan OSHA 26 10 20 200 100 min GC-FPD CF/CST 225-9007 68 C/HLD 225-1 116

Methyl methacrylate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methyl methacrylate Internal 13.1 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Methyl methacrylate Internal 13.1 ml/min 8-24 hrs SE, GC PS 690-105 96

Methyl methacrylate NIOSH 2537 100 1-8 10-50 varies GC-FID ST 226-30-06 48

Methyl methacrylate NON 54 50 75 10 3 20 200 8 15 GC-FID ST 226-81A 49

Methyl methacrylate OSHA 94 100 3 50 1 GC-FID ST 226-73 49

Methyl n-amyl ketone (2-heptanone) (Ketones II ) NIOSH 2553 100 1-25 10-200 varies GC-FID ST NA SKC

Methyl parathion ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 54

Methyl parathion OSHA PV2112 480 1000 8 GC-FPD ST 226-30-16 48

Methyl parathion (Organophosphorus Pesticides) NIOSH 5600 0.2 mg/m3 240 1000 4 GC-FPD ST 226-58 49

Methyl propyl ketone (2-pentanone) NIOSH 1300 150 10 200 50 (min) 15 GC-FID ST 226-01 48

Methyl propyl ketone (Ketones I) NIOSH 2555 1-10 10-200 varies GC-FID ST NA SKC

alpha-Methyl styrene Internal 12.6 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-104 96

alpha-Methyl styrene Internal 12.6 ml/min 8-24 hrs SE, GC PS 690-105 96

alpha-Methyl styrene (Hydrocarbons, Aromatic) NIOSH 1501 50 100 1-30 1-30 10-200 10-200 varies varies GC-FID ST 226-01 48

beta-Methyl styrene (Hydrocarbons, Aromatic) NIOSH 1501 50 100 1-30 1-30 10-200 10-200 varies varies GC-FID ST 226-01 48

Methyl styrene (vinyl toluene) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

17-a-Methyl testosterone OSHA PV2001 60 1000 1 HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

Methyl-2-cyanoacrylate OSHA 55 12 100 2 HPLC-UV ST 226-98 50

1-Methyl-2-ethyl benzene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

1-Methyl-2-pyrrolidinone OSHA PV2043 10 200 50 min GC-FID ST 226-01 48

N-Methyl-2-pyrrolidinone NIOSH 1302 96 200 8 GC-NPD, ST 226-01 48


FID

N-Methyl-2-pyrrolidinone OSHA PV2043 10 200 50 min GC-FID ST 226-01 48

1-Methyl-3-ethyl benzene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

5-Methyl-3-heptanone (ketones II ) NIOSH 2553 25 1-25 10-200 varies GC-FID ST NA SKC

5-Methyl-3-heptanone (ketones II) NIOSH 1301 25 10 20(50) 8(3.3) GC-FID ST 226-01 48

1-Methyl-4-ethyl benzene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

2-Methyl-4-isothiazolin-3-one (Kathon 886) NON 55 1.5 mg/m3 4.5 mg/m3 50 7.5 200 500 4 15 HPLC-UV ST 226-99 50

Methylal (dimethoxymethane) NIOSH 1611 1000 1.8 20 1.5 GC-FID ST 226-01 48

Methylal (see dimethoxymethane)

Methylcyclohexanol NIOSH 1404 50 12 25 8 GC-FID ST 226-01 48

Methylcyclohexanone NIOSH 2521 50 75 3 50 1 GC-FID ST 226-115 50

4,4-Methylene bisphenyl isocyanate (MDI) OSHA 5002 200 µg/m3 15 1000 15 HPLC-UV CF/CST 225-9002 or CF/CST 225-9013 or
CF/CST 225-9022  68 C/HLD 225-1 116

4,4-Methylene bisphenyl isocyanate (MDI) NIOSH 5521 50 µg/m3 200 µg/m3 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 70 IT 225-22 70
(isocyanates) (10 min) C ELCHM &
HPLC-UV

4,4-Methylene bisphenyl isocyanate (MDI) OR-OSHA 1010 0.02 0.005 45 5 1000 1000 45 min 5 HPLC IMP 225-36-1 70 IT 225-22 70
(isocyanates) CF/CST 225-9029 68

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 221


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Methylene chloride NIOSH 1005 LFC 2 1.5 20 100 1.6 15 GC-FID ST 226-01 48

Methylene chloride OSHA 80 25 125 3 0.25 50 50 1 5 GC-FID ST NA SKC

Methylene chloride (dichloromethane) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methylene chloride (dichloromethane) Internal 0.54 ml/min 1-7 days SE, GC PS 690-105 with RR 690-300 96

Methylene chloride (dichloromethane) Internal 14.7 ml/min 8 hrs-3 SE, GC PS 690-105 96


days

4,4-Methylene diphenyl isocyanate (MDI) NIOSH 5522 50 µg/m3 200 µg/m3 360 20 1000 2000 6 10 HPLC-FD IMP 225-36-1 70 IT 225-22 70
(10 min) C

4,4’-Methylenebis(2-chloroaniline) (MOCA) OSHA 71 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

Methylene-bis-(4-cyclohexylisocyanate) OSHA 5002 15 1000 15 HPLC-UV CF/CST 225-9013 or CF/CST 225-9022  68


C/HLD 225-1 116

Methylene-bis-(4-cyclohexylisocyanate) NIOSH 5525 110 µg/m3 1-500 1000-2000 varies HPLC-UV FLT 225-7 ‡ 110 CST 225-4 115
(isocyanates, total) (10 min) C SP 225-27 or IOM 225-76A 122
FLT 225-702 ‡ 110

4,4-Methylenebisphenyl isocyanate (MDI) NIOSH 5525 50 µg/m3 200 µg/m3 1-500 1000-2000 varies HPLC-UV FLT 225-7 ‡ 110 CST 225-4 115
(isocyanates, total) (10 min) C SP 225-27 or IOM 225-76A 122
FLT 225-702 ‡ 110

4,4’-Methylenedianiline (MDA) NIOSH 5029 LFC 480 1000 8 HPLC-UV CF/CST 225-9004 68 C/HLD 225-1 116

4,4’-Methylenedianiline (MDA) OSHA 57 100 1000 100 GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

Methyl-n-amyl ketone (2-heptanone) (Ketones II) NIOSH 1301 100 1-25 10-200 8 GC-FID ST 226-01 48

Methylphenols EPA TO-8 < 80 L 100-1000 HPLC-UV IMP 225-36-1 70 IT 225-22 70


ml/min

Methyl-t-butyl-ether (MTBE) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Methyl-t-butyl-ether (MTBE) Internal 13.6 ml/min 8 hrs-30 SE, GC PS 690-105 96


days

Methyl-tert-butyl ether NIOSH 1615 96 200 8 GC-FID ST 226-37 49

Methyltetrahydrophthalic anhydride NON 28 200 20 40 1000 8 20 GC-FID ST 226-30 48

Methyltin dichloride NIOSH 5526 0.1 mg/m3 60 60 250 1000 4 60 GC-FPD ST 226-30-16 48

Metolachlor ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Metolachlor NIOSH 5602 480 1000 8 GC-ECD ST 226-58 49

Metribuzin OSHA PV2044 240 1000 4 GC-FPD ST 226-30-16 48

Mevinphos (phosdrin) (Organophosphorus NIOSH 5600 0.01 240 1000 4 GC-FPD ST 226-58 49
Pesticides)

Mexacarbate ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

MIBK (see methyl isobutyl ketone)

MIC (methyl isocyanate) OSHA 54 0.02 15 50 5 HPLC-FD ST NA SKC

Mica (see Respirable dust) OSHA ID 142 (v4)

Mineral spirits (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 3 1 20 200 2.5 5 GC-FID ST 226-01 48

Mineral wool fiber (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Mineral wool fiber (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Mirex ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Mold spores (in air) 15-150 15000 1-10 min varies STC 225-9820 114

Molybdenum (Elements by Cellulosic Internal NIOSH 7306 1-330 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Capsule Sampler)

Molybdenum (Elements by ICP Aqua Regia NIOSH 7301 5 mg/m3 5-67 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 107
Ashing) (soluble) C/HLD 225-1 116
10 mg/m3
(insoluble)

Molybdenum (Elements by ICP HNO3 Digestion) NIOSH 7303 5 mg/m3 0.5-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
(soluble)
10 mg/m3
(insoluble)

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

222 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Molybdenum (Elements by ICP HNO3/HClO4 NIOSH 7300 5 mg/m3 6-67 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
Ashing) (soluble)
10 mg/m3
(insoluble)

Molybdenum (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Molybdenum insolubles (as Mo) OSHA ID 125G 15 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Molybdenum insolubles (as Mo) (respirable OSHA ID 121 15 mg/ 960 2000 8 GR & AA or F/CST 225-3-01 102 C/HLD 225-1 116
fraction) m3 (total GR & AES CYC 225-105 126
dust)

Molybdenum solubles (as Mo) OSHA ID 121 5 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Monochloroacetic acid (chloroacetic acid) NIOSH 2008 48 100 8 IC-CD ST 226-47-01 49

Monochlorotoluene (1-chloro-2-methyl benzene; Internal 13.0 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or
OXSOL 10) PS 690-104 96

Monochlorotoluene (1-chloro-2-methyl benzene; Internal 13.0 ml/min 8-24 hrs SE, GC PS 690-105 96
OXSOL 10)

Monocrotophos (Azodrin) OSHA PV2045 480 1000 8 GC-FPD ST 226-30-16 48

Monocrotophos (Organophosphorus Pesticides) NIOSH 5600 0.25 mg/m 3


240 1000 4 GC-FPD ST 226-58 49

Monoethanolamine (2-aminoethanol) NIOSH 3509 3 6 240 1000 4 IC IMP 225-36-1 70 IT 225-22 70

Monoethanolamine (see 2-aminoethanol)

Monomethyl aniline NIOSH 3511 0.5 100 1000 100 min GC-FID IMP 225-36-2 70 IT 225-22 70

Monomethyl hydrazine NIOSH 3510 0.04 (120 15 1000 15 VAS IMP 225-36-2 70 IT 225-22 70
min)

Monomethyl hydrazine OSHA 20 0.2 4.5 300 15 HPLC-UV ST 226-42-02 49

Monuron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Morpholine OSHA PV2123 20 10 100 100 min GC-FID ST 226-98 50

Mycobacteria NIOSH 0801 50-300 28300 varies GC-FID BI 225-9611 136

Mycobacterium tuberculosis (airborne) NIOSH 0900 1920 4000 8 PCR FLT 225-3705 108 SP 225-27 117
CST 225-3LF 115 C/HLD 225-1 116

Mycotoxins (fungi in air) NON 48 62.5-375 12,500 + 5-30 varies BS 225-9595 138 VT 225-9598A 138

Naphtha (coal tar) NIOSH 1550 100 10 20(50) 8(3.3) GC-FID ST 226-01 48

Naphtha (coal tar) OSHA 48 100 3 200 15 min GC-FID ST 226-01 48

Naphthalene OSHA 35 10 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-110 50

Naphthalene (Polynuclear Aromatic Hydrocarbons ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
by GC-MS) (max)

Naphthalene (Polynuclear Aromatic Hydrocarbons NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
by GC) C/HLD 225-1 116

Naphthalene (Polynuclear Aromatic Hydrocarbons NIOSH 5506 10 15 480 2000 4 HPLC-UV F/CST 225-1713 108 ST 226-30-04 48
by HPLC) C/HLD 225-1 116

1,5-Naphthalene diisocyanate OSHA PV2046 60 1000 1 HPLC-UV- CF/CST 225-9013 68 C/HLD 225-1 116
FD

1,5-Naphthalene diisocyanate (isocyanates, total) NIOSH 5525 40 µg/m3 70 µg/m3 1-500 1-500 1000-2000 1000-2000 varies varies HPLC-UV FLT 225-7 ‡ 110 CST 225-4 115
(10 min) C SP 225-27 or IOM 225-76A 122
FLT 225-702 ‡ 110

Naphthas (see specific compounds) NIOSH 1550 varies varies varies 8 GC-FID ST 226-01 48

alpha-Naphthylamine OSHA 93 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

beta-Naphthylamine OSHA 93 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

Naphthylamines (alpha- & beta-) NIOSH 5518 96 200 8 GC-FID FLT 225-16 110 CST 225-32 116
ST 226-51 49

Naphthylene diisocyanate (NDI) (isocyanates) NIOSH 5521 40 µg/m3 70 µg/m3 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 70 IT 225-22 70
(10 min) C ELCHM &
HPLC-UV

Naphthylthiourea (see ANTU)

Nickel (Elements by Cellulosic Internal Capsule NIOSH 7306 0.015 mg/ 2-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler) m3

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 223


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Nickel (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.015 mg/ 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 107
m3 C/HLD 225-1 116

Nickel (Elements by ICP HNO3 Digestion) NIOSH 7303 0.012 mg/ 1-50,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
m3

Nickel (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.15 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Nickel (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Nickel (metal & insoluble compounds as Ni) OSHA ID 125G 1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Nickel (metal, soluble, & insoluble compounds OSHA ID 121 1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116
as Ni)

Nickel (soluble compounds as Ni) OSHA ID 121 1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Nickel (soluble compounds as Ni) OSHA ID 125G 1 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Nickel carbonyl NIOSH 6007 0.001 72 150 8 AA-GF ST NA SKC F/CST 225-3-01 102

Nicotine NIOSH 2544 0.5 mg/m 3


360 1000 6 GC-NPD ST 226-30-04 48

Nicotine NIOSH 2551 0.5 mg/m3 480 1000 8 GC-NPD ST 226-93 50

Nicotine NON 19 120 1000 2 GC ST 226-93 50

Nicotine NON 49 90-720 1500 1- 8 GC-NSD ST 226-170 51

Nicotine & 3-ethenylpyridine ASTM D 5075 varies 1500 varies GC-NPD ST 226-93 50

Niobium (Elements by ICP HNO3 Digestion) NIOSH 7303 0.012 mg/ 0.1-3,300 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
m3

Nitric acid NIOSH 7907 2 4 600 30 2000 2000 5 15 IC-CD CF/CST 225-9032 68 C/HLD 225-1 116

Nitric acid OSHA ID 2 96 7.5 200 500 8 15 IC ST 226-10-03 48


165SG

Nitric oxide NON 59 25 3-24 100 4 IC ST 226-40A 49

p-Nitroaniline NIOSH 5033 3 mg/m 3


240 1000 4 HPLC-UV F/CST 225-3-01 102 C/HLD 225-1 116

Nitrobenzene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Nitrobenzene NIOSH 2005 1 48 100 8 GC-FID ST 226-10 48

Nitrobenzene NIOSH 2017 1 24 200 2 GC-FID CF/CST 225-9004 68 ST 226-15 48

p-Nitrochlorobenzene (nitrobenzenes) NIOSH 2005 0.1 96 200 8 GC-FID ST 226-10 48

Nitrochloroform NON 51 0.1 144 100 24 GC-MSD ST 226-175 51

Nitrochloromethane NON 51 0.1 144 100 24 GC-MSD ST 226-175 51

4-Nitrodiphenyl OSHA PV2082 240 500 8 GC-FID ST 226-30-16 48

Nitroethane NIOSH 2526 100 2.4 20 2 GC-FID ST 226-3002A 48

Nitrofurazone OSHA PV2069 240 1000 4 HPLC-UV F/CST 225-709 110 C/HLD 225-1 116

Nitrogen dioxide NIOSH 6014 1 (NO2) 1.5-6 25-200 varies VAS ST 226-40-02 49

Nitrogen dioxide OSHA ID 182 5 (C) 3 200 15 IC ST 226-40-02 49

Nitroglycerin NIOSH 2507 0.1 mg/m3 3 200 15 GC-ECD ST 226-35-03 48

Nitroglycerin OSHA 43 0.1 mg/m3 15 1000 15 HPLC ST 226-35-03 48

Nitromethane NIOSH 2527 2.4 20 2 GC-NSD ST 226-111A 50

1-Nitropropane OSHA 46 25 3 100 30 min GC-FID ST 226-93 50

2-Nitropropane NIOSH 2528 LFC 2 20 1.5 GC-FID ST 226-110 50

2-Nitropropane OSHA 46 25 3 100 30 min GC-FID ST 226-93 50

1-Nitropyrene in diesel particulates NIOSH 2560 480-960 1000-2000 varies GC-NCD FLT 225-7 110 SP 225-27 117
SPC 225-23 117

N-Nitrosodiethanolamine OSHA 31 480 2000 4 GC-TEA F/CST 225-706 110 C/HLD 225-1 116

N-Nitrosodiphenylamine OSHA 23 240 1000 4 HPLC-UV IMP 225-36-2 70 IT 225-22 70

m-Nitrotoluene (nitroaromatic compounds) NIOSH 2005 2 ppm 96 200 8 GC-FID ST 226-10 48

o-Nitrotoluene (nitroaromatic compounds) NIOSH 2005 2 ppm 96 200 8 GC-FID ST 226-10 48

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

224 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
p-Nitrotoluene (nitroaromatic compounds) NIOSH 2005 2 ppm 96 200 8 GC-FID ST 226-10 48

Nitrotoluene (nitrobenzenes) NIOSH 2005 2 ppm 96 200 8 GC-FID ST 226-10 48

Nitrous oxide NIOSH 6600 25 3 100-4000 varies P IR SB 231-05 60

trans-Nonachlor ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Nonane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Nonane Internal 10.6 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-104 96

Nonane Internal 10.6 ml/min 8-24 hrs SE, GC PS 690-105 96

n-Nonane (hydrocarbons, BP 36 to 216 C) NIOSH 1500 200 4 10-200 varies GC-FID ST 226-01 48

Nonpolar organic compounds NON 38 varies varies varies GC PUF 226-129 55

Norethindrone OSHA PV2070 480 2000 4 HPLC-UV F/CST 225-802 107 C/HLD 225-1 116

Nuisance dust (Particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Nuisance dust (see dust, respirable nuisance)

n-Octane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

n-Octane Internal 12.7 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-104 96

n-Octane Internal 12.7 ml/min 8-24 hrs SE, GC PS 690-105 96

n-Octane OSHA 5000 500 12 50 4 GC-FID ST 226-01 48

n-Octane (hydrocarbons, BP 36 to 216 C) NIOSH 1500 75 385 4 4 0-200 0-200 varies varies GC-FID ST 226-01 48

1-Octanethiol NIOSH 2510 0.5 (15 min) 3 200 15 GC-FPDS ST 226-35-03 48

Octanol EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Octyl alcohol EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

di-n-Octyl phthalate (DNOP) OSHA 104 240 1000 4 GC-FID ST 226-56 49

Oil mist (mineral) NIOSH 5026 5 mg/m3 10 mg/m3 480 30 1000 2000 8 15 IR F/CST 225-3-01 or F/CST 225-802 107
C/HLD 225-1 116

Oil mist (mineral) OSHA ID 5 mg/m3 960 2000 8 GR & IR FLT 225-5-37-P 107 C/HLD 225-1 116
178SG CST 225-2LF 115

Oil mist (total aerosol) NON 46 5 mg/m3 varies 2000 varies GR IOM 225-70A 122 FLT 225-5-25 107

Oil mist (vegetable) (see Particulates Not


Otherwise Regulated, total and respirable)

Organic vapors (charcoal tube method) ASTM D 3686 varies varies varies varies varies varies GC ST 226-01 48

Organic vapors (diffusive sampler method) ASTM D 4597 varies varies varies varies varies varies GC PS 575-001 or PS 575-002 82

Organonitrogen pesticides (see specific NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48
compounds)

Organophosphorus pesticides (see specific NIOSH 5600 varies varies varies 8 GC-FPD ST 226-58 49
compounds)

Organotin compounds as Sn (see specific NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC & ST 226-30 48 F/CST 225-709 110
compounds) AA-GF C/HLD 225-1 116

Organotin compounds as Sn (see specific NIOSH 5526 0.1 mg/m3 60 60 250 1000 4 60 GC-FPD ST 226-30-16 48
compounds)

Oxalic acid OSHA PV2115 1 mg/m3 100 1000 100 min IC FLT 225-701 110 CST 225-3LF 115
C/HLD 225-1 116

Oxamyl (Organonitrogen Pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Oxychlordane ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Ozone OSHA ID 214 0.1 90-120 22.5 250-500 1500 180 min at 500 ml/min IC CF/CST 225-9014 68
480 min at 250 ml/min

PAHs (Polynuclear Aromatic Hydrocarbons by GC, NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
see specific compounds) C/HLD 225-1 116

PAHs (Polynuclear Aromatic Hydrocarbons by ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
GC-MS, see specific compounds) (max)

PAHs (Polynuclear Aromatic Hydrocarbons by NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 108 ST 226-30-04 48
HPLC, see specific compounds) C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 225


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Palladium (Elements by ICP HNO3 Digestion) NIOSH 7303 0.1-3300 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Paper fiber (cellulose) (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Paper fiber (cellulose) (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Paraffin wax fume OSHA PV2047 100 1000 100 min GC-FID F/CST 225-706 110 C/HLD 225-1 116

Paraquat NIOSH 5003 0.1 mg/m3 480 1000 8 HPLC-UV FLT 225-17-01 108 CST 225-2LF 115
C/HLD 225-1 116

Parathion OSHA 62 0.1 mg/m3 480 1000 8 GC-FPD ST 226-30-16 48

Parathion (Organophosphorus Pesticides) NIOSH 5600 0.05 mg/m3 240 1000 4 GC-FPD ST 226-58 49

Particulates not otherwise regulated (total dust) OSHA PV2121 15 mg/m3 960 2000 4-8 GR FLT 225-802 107 C/HLD 225-1 116

Particulates not otherwise regulated, respirable NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Particulates not otherwise regulated, respirable OSHA PV2121 5 mg/m3 varies varies varies GR FLT 225-803 107 C/HLD 225-1 116
fraction CYC 225-105 126

Particulates, inorganic (bioaerosols) 15-150 15000 1-10 min varies STC 225-9820 114

Particulates, respirable NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Particulates, total (see specific compounds) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Particulates, total (see specific compounds) NIOSH 0501 120 2000 1 GR AC 225-8516GLA 106 C/HLD 225-1 116
CST 225-2LF 115

PCBs (42% CI) (see polychlorobiphenyls) NIOSH 5503

PCBs (54% CI) (see polychlorobiphenyls) NIOSH 5503

PCBs (polychlorinated biphenyls) EPA TO-4A 200-280 L/ 24 hrs varies PUF 226-131 55 FLT 225-1808 109
min

Pentachlorobenzene ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Pentachlorobenzene (polychlorobenzenes) NIOSH 5517 12 25 8 GC-ECD FLT Special order CST Special order
ST 226-30-04 48

Pentachlorophenol ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Pentachlorophenol NIOSH 5512 0.5 mg/m3 480 1000 8 HPLC-UV CST 225-3LF 115 SCN 225-26 117
IMP 225-36-2 70 IT 225-22 70
FLT 225-5 102

Pentachlorophenol OSHA 39 0.5 mg/m3 48 200 4 HPLC-UV ST 226-97 50

Pentaerythritol (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Pentaerythritol (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Pentamidine isethionate NIOSH 5032 960 2000 8 HPLC-FD CST 225-4 115 FLT 225-5-37-P 107
C/HLD 225-1 116

n-Pentane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

n-Pentane Internal 14.9 ml/min 8-24 hrs SE, GC PS 690-105 96

n-Pentane (hydrocarbons, BP 36 to 216 C) NIOSH 1500 120 610 4 4 10-200 10-200 varies varies GC-FID ST 226-01 48

2,3-Pentanedione OSHA 1016 0.5 10 3 50 200 200 (min) 15 GC-FID ST 226-183 51

2-Pentanone (Ketones I) NIOSH 2555 1-10 10-200 varies GC-FID ST NA SKC

2-Pentanone (methyl propyl ketone) NIOSH 1300 150 10 200 50 (min) 15 GC-FID ST 226-01 48

2-Pentanone (methyl propyl ketone) (Ketones I) NIOSH 1300 150 10 20(50) 8(3.3) GC-FID ST 226-01 48

Peracetic acid and Hydrogen peroxide NON 57 15 1000 π 15 MAS/HPLC- CF/CST 225-9030 68 ST 226-193-UC or
UV ST 226-199-UC 52

Peracetic acid OSHA PV2321 0.4 15 1000 15 GC-FID CF/CST 225-9037 68 IMP 225-0024 70

Perchloric acid OSHA ID 120 500 4 CLR IMP 225-36-2 70 IT 225-22 70


115SG

Perchloroethylene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

226 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Perchloroethylene Indoor 13.1 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or
PS 690-104 96

Perchloroethylene Internal 0.55 ml/min 24 hrs to 7 TD, GC PS 690-101 or PS 690-103 or


days PS 690-104 with RR 690-300 96

Perchloroethylene Internal 13.1 ml/min 8 hrs-30 SE, GC PS 690-105 96


days

Perchloroethylene (tetrachloroethylene) OSHA 1001 100 200 (C) 13.06 8 5 GC-FID PS 575-002 82

Perchloroethylene (tetrachloroethylene) OSHA 1001 100 200 (C) 12 0.75 50 50 4 5 GC-FID ST 226-01 48

Perchloroethylene (tetrachloroethylene) NIOSH 1003 LFC 3 10-200 varies GC-FID ST 226-01 48


(hydrocarbons, halogenated)

Perchloroethylene (tetrachloroethylene) (portable NIOSH 3704 LFC 1 20-5000 varies P GC SB 232-01 or SB 249-01-PP with
GC) PT NA SKC with SBLK NA SKC

Perlite (< 1% Quartz) (see Particulates Not


Otherwise Regulated, total and respirable)

cis-Permethrin ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

trans-Permethrin ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Peroxyacetic acid (peracetic acid) & Hydrogen NON 57 15 1000 π 15 MAS/HPLC- CF/CST 225-9030 68 ST 226-193-UC or
peroxide UV ST 226-199-UC 52

Pesticides EPA IP-8 1-5 L/min 4-24 hrs GC-ECD PUF 226-92 or PUF 226-124 54

Pesticides EPA TO-10A 1-5 L/min 4-24 hrs GC-ECD PUF 226-92 or PUF 226-124 54

Pesticides, carbamate ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Pesticides, organochlorine ASTM D 4861 240-7200 1000-5000 4-24 varies PUF 226-92 or PUF 226-124 54

Pesticides, organochlorine EPA TO-4A 200-280 L/ 24 hrs varies PUF 226-131 55 FLT 225-1808 109
min

Pesticides, organonitrogen (see specific NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48
compounds)

Pesticides, organophosphorus ASTM D 4861 240-7200 1000-5000 4-24 varies PUF 226-92 or PUF 226-124 54

Pesticides, pyrethrin ASTM D 4861 240- 7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Pesticides, triazine ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV or PUF 226-92 54
GC-ECD

Petroleum distillate (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 3.6 1.5 20 100 3 15 GC-FID ST 226-01 48

Petroleum distillate fractions (PDF) OSHA 48 500 3 20 2.5 GC-FID ST 226-01 48

Petroleum ether (benzin) (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 3 1.5 20(50) 100 2.5(1) 15 GC-FID ST 226-01 48

Petroleum naphtha (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 3 1.5 20(50) 100 2.5(1) 15 GC-FID ST 226-01 48

Phenanthrene OSHA 58 960 2000 8 GR & HPLC- FLT 225-7 110 CST 225-2LF 115
FD, or GR & C/HLD 225-1 116
HPLC-UV

Phenanthrene (Polynuclear Aromatic ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Hydrocarbons by GC-MS) (max)

Phenanthrene (Polynuclear Aromatic NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by GC) C/HLD 225-1 116

Phenanthrene (Polynuclear Aromatic NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 108 ST 226-30-04 48
Hydrocarbons by HPLC) C/HLD 225-1 116

Phenol EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Phenol EPA TO-8 < 80 L 100-1000 HPLC-UV IMP 225-36-1 70 IT 225-22 70


ml/min

Phenol OSHA 32 5 24 100 4 HPLC-UV ST 226-95 50

Phenol (cresols) NIOSH 2546 5 15.6 (15 24 3 100 200 4 15 GC-FID ST 226-95 50
min)

Phenolics (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 52

Phenothiazine OSHA PV2048 100 1000 1 GC-NPD F/CST 225-706 110 C/HLD 225-1 116

Phenyl ether NIOSH 1617 1 48 100 8 GC-FID ST 226-01 48

Phenyl ether OSHA PV2022 1 20 200 100 min GC-FID ST 226-95 50

Phenyl ether-biphenyl mix NIOSH 2013 1 24 50 8 GC-FID ST 226-10 48

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 227


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Phenyl glycidyl ether NIOSH 1619 1 (15 min) 80 1000 80 GC-FID ST 226-01 48

Phenyl hydrazine NIOSH 3518 0.14 (120 120 1000 120 VAS IMP 225-36-2 70 IT 225-22 70
min)

Phenyl mercaptan OSHA PV2075 20 200 100 min GC-FID CF/CST 225-9007 68 C/HLD 225-1 116

N-Phenyl-1-naphthylamine OSHA 96 240 2000 4 HPLC-FD FLT 225-703 ‡ 110 CST 225-3-23 115
C/HLD 225-1 116

N-Phenyl-2-naphthylamine OSHA 96 240 1000 4 HPLC-FD FLT 225-703 ‡ 110 CST 225-3-23 115
C/HLD 225-1 116

m-Phenylenediamine OSHA 87 100 1000 100 min HPLC-UV CF/CST 225-9004 68 C/HLD 225-1 116

o-Phenylenediamine OSHA 87 100 1000 100 min HPLC-UV CF/CST 225-9004 68 C/HLD 225-1 116

p-Phenylenediamine OSHA 87 0.1 mg/m3 100 1000 100 min HPLC-UV CF/CST 225-9004 68 C/HLD 225-1 116

o-Phenylphenol ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Phorate ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 54

Phorate (Organophosphorus Pesticides) NIOSH 5600 0.05 mg/m3 0.2 mg/m3 240 1000 4 GC-FPD ST 226-58 49

Phosdrin (mevinphos) (Organophosphorus NIOSH 5600 0.01 0.03 120 15 1000 1000 2 15 GC-FPD ST 226-58 49
Pesticides)

Phosgene EPA TO-6 < 50 L 100-1000 HPLC-UV IMP 225-36-1 70 IT 225-22 70


ml/min

Phosgene OSHA 61 0.1 240 1000 4 GC-NPD ST 226-117 50

Phosgene & chloroformates NON 40 24 50 8 GC-FPD ST 226-153 51

Phosphine NIOSH 6002 0.3 1 12 3 100 200 8 15 UV-VIS ST 226-165A †† 51

Phosphine OSHA 1003 0.3 240 30 1000 2000 4 15 ICP-AES CF/CST 225-9018 †† 68 C/HLD 225-1 116

Phosphoric acid NIOSH 7908 1 mg/m3 3 mg/m3 960 30 2000 2000 8 15 IC-CD CF/CST 225-9033 68 C/HLD 225-1 116

Phosphoric acid OSHA ID 111 1 mg/m3 960 30 2000 2000 8 15 IC F/CST 225-3-01 102 C/HLD 225-1 116

Phosphoric acid OSHA ID 1 mg/m3 960 30 2000 2000 8 15 IC ST 226-10-03 48


165SG

Phosphorous (Elements by ICP HNO3 Digestion) NIOSH 7303 0.1 mg/m3 250- 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
500,000

Phosphorus NIOSH 7905 0.1 mg/m3 12 200 1 GC-FPD ST 226-35-03 48

Phosphorus (Elements by Cellulosic Internal NIOSH 7306 0.1 mg/m3 9-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Capsule Sampler)

Phosphorus (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.1 mg/m3 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 107
C/HLD 225-1 116

Phosphorus (Elements by ICP HNO3/HClO4 NIOSH 7300 0.1 mg/m3 25-200 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
Ashing)

Phosphorus (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Phosphorus pentasulfide OSHA ID 1 mg/m3 960 30 2000 2000 8 15 IC F/CST 225-802 107 C/HLD 225-1 116
128SG

Phosphorus pentoxide OSHA ID 111 480 1000 8 IC F/CST 225-3-01 102 C/HLD 225-1 116

Phosphorus trichloride NIOSH 6402 0.2 0.5 24 200 2 VAS IMP 225-36-2 70 IT 225-22 70

Phthalates (see specific compounds)

Phthalic anhydride OSHA 90 2 75 1000 1.25 HPLC-UV CF/CST 225-9034 68 C/HLD 225-1 116

Picloram (tordon) ( total dust) OSHA PV2049 15 mg/m3 60 1000 1 GR F/CST 225-803 107 C/HLD 225-1 116

Picloram (tordon) (respirable dust) OSHA PV2049 5 mg/m 3


varies varies varies GR FLT 225-706 110 C/HLD 225-1 116
CYC 225-105 126

alpha-Pinene Internal 11.3 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-104 96

alpha-Pinene Internal 11.3 ml/min 8-24 hrs SE, GC PS 690-105 96

alpha-Pinene (terpenes) NIOSH 1552 24 50 8 GC-FID ST 226-01 48

beta-Pinene (terpenes) NIOSH 1552 24 50 8 GC-FID ST 226-01 48

Piperonyl butoxide OSHA PV2110 30 1000 30 min HPLC-UV ST 226-30-16 48

Pirimiphos methyl OSHA PV2071 120 1000 2 GC-ECD ST 226-30-16 48

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

228 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Plaster of Paris (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Plaster of Paris (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Platinum OSHA ID 90 1000 1.5 AA F/CST 225-3-01 102 C/HLD 225-1 116
130SG

Platinum (Elements by ICP HNO3 Digestion) NIOSH 7303 200- 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
25,000,000

Platinum (as Pt), metal OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Platinum (as Pt), soluble salts OSHA ID 121 2 µg/m 3


960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

PM2.5 EPA IP-10A 9 L/min 24 hrs GR CI 225-370 134 FLT 225-3708 108
FLT 225-1709 108

PM2.5 EPA IP-10A 10 L/min 24 hrs GR PEM 761-203B 132 FLT 225-1709 108

PNAs (Polynuclear Aromatic Hydrocarbons by GC, NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
see specific compounds) C/HLD 225-1 116

PNAs by HPLC (see specific compounds) NIOSH 5506 480 2000 4 HPLC-UV F/CST 225-1713 108 ST 226-30-04 48
C/HLD 225-1 116

PNAs selected OSHA 58 960 2000 8 GR & HPLC- FLT 225-7 110 CST 225-2LF 115
FD, or GR & C/HLD 225-1 116
HPLC-UV

Pollen (in air) 15-150 15000 1-10 min varies STC 225-9820 114

Pollen (in air) NON 48 62.5-375 12,500 + 5-30 varies BS 225-9595 138 VT 225-9598A ◊ 138

Polychlorinated biphenyls ASTM D 4861 240-7200 1000-5000 4-24 varies PUF 226-92 or PUF 226-124 54

Polychlorinated biphenyls NIOSH 5503 0.001 mg/ 48 100(200) 8(4) GC-ECD FLT 225-16 110 CST 225-32 116
m3 (10 ST 226-39 49
hrs)

Polychlorobenzenes (see specific compounds) NIOSH 5517 varies varies varies 8 GC-ECD FLT Special order ST 226-30-04 48
CST Special order C/HLD 225-1 116

Polychlorobiphenyls (42% Cl) NIOSH 5503 0.001 mg/ 48 100(200) 8(4) GC-ECD FLT 225-16 110 CST 225-32 116
m3 (10 ST 226-39 49
hrs)

Polychlorobiphenyls (54% Cl) NIOSH 5503 0.001 mg/ 48 100(200) 8(4) GC-ECD FLT 225-16 110 CST 225-32 116
m3 (10 ST 226-39 49
hrs)

Polycyclic aromatic compounds (PACs), total NIOSH 5800 960 30 2000 2000 8 15 FLUOR F/CST 225-1713 108 ST 226-30-04 48
C/HLD 225-1 116

Polycyclic aromatic hydrocarbons (PAHs) EPA IP-7 30,000 L 20 L/min GC-FID, PUF 226-131 55 FLT 225-1808 109
-MS, HPLC

Polycyclic aromatic hydrocarbons (PAHs) EPA TO-13A 220 L/min 24 hrs GC-MS PUF 226-131 55 FLT 225-1808 109

Polynuclear aromatic hydrocarbons (polynuclear NIOSH 5515 varies 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
aromatic hydrocarbons by GC, see specific C/HLD 225-1 116
compounds)

Polynuclear aromatic hydrocarbons (Polynuclear ASTM D 6209 varies 350 m3 225 L/min 4-24 GC-MS PUF 226-131 55 FLT 225-1808 109
Aromatic Hydrocarbons by GC-MS) (max)

Polynuclear aromatic hydrocarbons by HPLC (see NIOSH 5506 varies 480 2000 4 HPLC-UV F/CST 225-1713 108 ST 226-30-04 48
specific compounds) C/HLD 225-1 116

Portland cement (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Portland cement (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Portland cement (respirable dust) (see respirable OSHA ID 142 (v4)


dust)

Portland cement (total dust) OSHA ID 207 15 mg/m3 240 1000 4 XRD F/CST 225-803 107 C/HLD 225-1 116

Potassium & compounds OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Potassium (Elements by Cellulosic Internal NIOSH 7306 Varies 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Capsule Sampler)

Potassium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 229


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Potassium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Potassium chromate (CR(VI)) OSHA ID 215 0.005 mg/ 960 2000 8 IC-UV F/CST 225-802 107 C/HLD 225-1 116
(V2) m3

Potassium cyanide (cyanides) NIOSH 7904 5 mg/m3 15 1000 15 ISE FLT 225-3705 ∆ 108 CST 225-2LF 115
(10 min) IMP 225-36-2 70 IT 225-22 70
C/HLD 225-1 116

Potassium hydroxide (alkaline dust) NIOSH 7401 960 2000 8 TITRA F/CST 225-1715 108 C/HLD 225-1 116

Potassium hydroxide (as K) OSHA ID 121 10 2000 5 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Progesterone OSHA PV2001 60 1000 1 HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

Propane OSHA PV2077 1000 5 100 50 min GC-FID ST NA SKC

1,2,3-Propanetriol trinitrate OSHA 43 15 1000 15 min HPLC-UV ST 226-35-03 48

n-Propanol EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Propargyl alcohol OSHA 97 6 50 2 GC-ECD ST 226-178 51

Propazine ASTM D 4861 240-7200 1000-5000 4-24 GC-NPD PUF 226-92 54

Propham (Organonitrogen Pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Propionaldehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

Propionaldehyde (Aldehydes, Screening) NIOSH 2539 5 20 4 GC-FID & ST 226-118 50


GC-MS

Propionic acid OSHA PV2293 18 2000 90 min IC ST 226-15 48

Propionitrile EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Propoxur (Baygon) ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Propoxur (Baygon) OSHA PV2007 60 1000 1 HPLC-UV ST 226-30-16 48

Propoxur (Organonitrogen Pesticides) NIOSH 5601 0.5 mg/m 3


240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

n-Propyl acetate EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

n-Propyl acetate (Esters I) NIOSH 1450 200 250 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 48

Propyl alcohol EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

n-Propyl alcohol OSHA 5001 200 12 4 GC-FID ST 226-82 50

n-Propyl alcohol (alcohols combined) NIOSH 1405 200 250 (skin) 1-10 1-10 10-200 10-200 varies varies GC-FID ST 226-01 48

n-Propyl alcohol (alcohols II) NIOSH 1401 200 250 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 48

n-Propyl benzene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Propylene dichloride (1,2-dichloro propane) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Propylene dichloride (1,2-dichloro propane) NIOSH 1013 LFC 3 20 2.5 GC-ECN ST 226-81A 49

Propylene glycol NIOSH 5523 60 1000 1 GC-FID ST 226-57 49

Propylene glycol OSHA PV2051 60 15 1000 1000 1 15 GC-FID ST 226-57 49

Propylene glycol monomethyl ether (glycol ethers) NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 49

Propylene glycol monomethyl ether acetate (glycol NIOSH 2554 3-25 100-200 varies GC-FID ST 226-81A 49
ethers)

Propylene oxide (1, 2-epoxypropane) NIOSH 1612 LFC 5 20 4.2 GC-FID ST 226-01 48

Propylene oxide (1, 2-epoxypropane) OSHA 88 100 5 5 100 1000 50 min 5 GC-FID ST 226-81A 49

Pyrene OSHA 58 960 2000 8 GR & HPLC- FLT 225-7 110 CST 225-2LF 115
FD, or GR & C/HLD 225-1 116
HPLC-UV

Pyrene (Polynuclear Aromatic Hydrocarbons by ASTM D 6209 350 m3 225 L/min 1-24 GC-MS PUF 226-131 55 FLT 225-1808 109
GC-MS) (max)

Pyrene (Polynuclear Aromatic Hydrocarbons NIOSH 5515 480 2000 4 GC-FID F/CST 225-1713 108 ST 226-30-04 48
by GC) C/HLD 225-1 116

Pyrene (Polynuclear Aromatic Hydrocarbons by NIOSH 5506 480 2000 4 HPLC-FD F/CST 225-1713 108 ST 226-30-04 48
HPLC) C/HLD 225-1 116

Pyrethrin pesticides (see specific compounds) ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

230 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Pyrethrum ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Pyrethrum NIOSH 5008 5 mg/m3 100 1000 2 HPLC-UV F/CST 225-709 110 C/HLD 225-1 116
SP 225-27 117

Pyrethrum OSHA 70 5 mg/m3 60 1000 1 GC-ECD ST 226-30-16 48

Pyridine EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Pyridine NIOSH 1613 5 48 100 8 GC-FID ST 226-01 48

Pyridine OSHA PV2295 5 10 100 100 min GC-FID ST 226-95 50

Quartz (respirable) in coal dust, (silica in coal NIOSH 7603 0.05 mg/m3 300-1000 2000-4000 varies IR FLT 225-5-37-P 107 C/HLD 225-1 116
mine dust) CYC 225-01-02 127 CST 225-309 115

Quartz (see silica, respirable crystalline) OSHA ID 142 (v4)

Quartz (silica, crystalline [respirable]) by XRD NIOSH 7500 0.05 mg/m3 400-1000 2500 varies XRD F/CST 225-803 107 CYC 225-01-02 127
C/HLD 225-1 116

Quartz (silica, crystalline by IR) NIOSH 7602 0.05 mg/m3 1000 2000-4000 varies IR F/CST 225-803 107 C/HLD 225-1 116
CYC 225-01-02 127

Radon progeny (on dust, in mines) NON 56 5 2000 5 min DRI FLT 225-702 110 CST 225-1107 116

Resmethrin ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Resmethrin OSHA PV2052 60 1000 1 HPLC-UV ST 226-30-16 48

Resorcinol NIOSH 5701 10 120 500 4 GC-FID ST 226-57 49

Respirable Dust using Aluminum Cyclone OSHA ID 142 (v4) 50 µg/m 3


1200 2500 8 GR & XRD FLT 225-5-37-P 107 CST 225-3050LF 115
C/HLD 225-1 116 CYC 225-01-02 127

Respirable Dust using GS-3 Cyclone OSHA ID 142 (v4) 50 µg/m3 1320 2750 8 GR & XRD FLT 225-5-37-P 107 CST 225-3050LF 115
C/HLD 225-1 116 CYC 225-100 126

Respirable Dust using PPI Samplers OSHA ID 142 (v4) 50 µg/m3 960 2000 8 GR & XRD FLT 225-5-37-P 107 PPI 225-385 128

Rhodamine B OSHA PV2072 240 1000 4 HPLC-UV F/CST 225-709 110 C/HLD 225-1 116

Ribavirin NIOSH 5027 480 1000 8 HPLC-UV F/CST 225-709 110 C/HLD 225-1 116

Ronnel ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-92 54

Ronnel OSHA PV2054 15 mg/m3 60 1000 1 GC-FPD ST 226-30-16 48

Ronnel (Organophosphorus Pesticides) NIOSH 5600 10 mg/m3 60 1000 1 GC-FPD ST 226-58 49

Rotenone NIOSH 5007 5 mg/m3 120 1000 2 HPLC-UV FLT 225-17-01 108 CST 225-4 115
C/HLD 225-1 116

Rouge (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Rouge (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Rubber solvent (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 10 1.5 20(50) 100 8(3.3) 15 GC-FID ST 226-01 48

Safrotin OSHA PV2050 60 1000 1 GC-ECD F/CST 225-709 110 C/HLD 225-1 116

Scopolamine methyl nitrate OSHA PV2144 120 1000 2 HPLC-UV F/CST 225-709 or F/CST 225-706 110
C/HLD 225-1 116

Selenium OSHA ID 121 0.2 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Selenium (Elements by Cellulosic Internal Capsule NIOSH 7306 0.2 mg/m3 2-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Selenium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.2 mg/m3 13-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Selenium (Elements by ICP HNO3 Digestion) NIOSH 7303 0.2 mg/m3 8-250,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Selenium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.2 mg/m 3


13-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Selenium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Sevin (see carbaryl)

Silica (quartz) in coal dust (quartz in coal mine NIOSH 7603 0.05 mg/m3 300-1000 2000-4000 varies IR FLT 225-5-37-P 107 C/HLD 225-1 116
dust by IR) CYC 225-01-02 127 CST 225-3LF 115

Silica, amorphous (respirable) NIOSH 7501 6 mg/m3 50-400 2500 varies XRD F/CST 225-803 107 C/HLD 225-1 116
CYC 225-01-02 127

Silica, crystalline (respirable) by XRD NIOSH 7500 0.05 mg/m3 400-1000 2500 varies XRD F/CST 225-803 107 CYC 225-01-02 127
C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 231


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Silica, crystalline by IR NIOSH 7602 0.05 mg/m3 1000 2000-4000 varies IR F/CST 225-803 107 C/HLD 225-1 116
CYC 225-01-02 127

Silica, fused (see silica, respirable crystalline) OSHA ID 142 (v4)

Silica, respirable crystalline (as quartz, cristobalite, OSHA ID 142 (v4) 50 µg/m3 1200 2500 8 XRD FLT 225-5-37-P 107 CST 225-3050LF 115
tridymite) using Aluminum Cyclone C/HLD 225-1 116 CYC 225-01-02 127

Silica, respirable crystalline (as quartz, cristobalite, OSHA ID 142 (v4) 50 µg/m3 1320 2750 8 XRD FLT 225-5-37-P 107 CST 225-3050LF 115
tridymite) using GS-3 Cyclone C/HLD 225-1 116 CYC 225-100 126

Silica, respirable crystalline (as quartz, cristobalite, OSHA ID 142 (v4) 50 µg/m3 960 2000 8 XRD FLT 225-5-37-P 107 PPI 225-385 128
tridymite) using PPI Samplers

Silicon (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Silicon (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Silicon carbide (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Silicon carbide (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Silver (Elements by Cellulosic Internal Capsule NIOSH 7306 0.01 mg/m3 6-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Silver (Elements by ICP Aqua Regia Ashing) NIOSH 7301 250-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 107
C/HLD 225-1 116

Silver (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.01 mg/ 250-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
m3 (metal,
soluble)

Silver (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Silver, metal & soluble compounds (as Ag) OSHA ID 121 0.01 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Silver, metal & soluble compounds (ICP analysis of OSHA ID 206 0.01 mg/m 3
960 2000 8 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
metal/metalloid particulates from solder operations)

Simazine ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Simazine NIOSH 5602 480 1000 8 GC-ECD ST 226-58 49

Sodium azide OSHA ID 211 5 1000 5 IC-UV ST 226-55 49 FLT 225-5-37-P 107
CST 225-2LF 115 SPC 225-23 117
C/HLD 225-1 116

Sodium bisulfite OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Sodium fluoride (fluorides) NIOSH 7902 2.5 mg/m3 480 30 1000 2000 8 15 ISE CF/CST 225-9001 68 C/HLD 225-1 116

Sodium fluoride (fluorides) NIOSH 7906 2.5 mg/m3 960 30 2000 2000 8 15 IC-CD CF/CST 225-9031 68 C/HLD 225-1 116

Sodium hexafluoroaluminate (fluorides) NIOSH 7902 2.5 mg/m3 480 30 1000 2000 8 15 ISE CF/CST 225-9001 68 C/HLD 225-1 116

Sodium hexafluoroaluminate (fluorides) NIOSH 7906 2.5 mg/m3 960 2000 8 IC-CD CF/CST 225-9031 68 C/HLD 225-1 116

Sodium hydroxide OSHA ID 121 2 mg/m 3


960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Sodium hydroxide (alkaline dust) NIOSH 7401 2 mg/m3 360 1500 4 TITRA F/CST 225-1715 108 C/HLD 225-1 116
(15 min)

Sodium metabisulfite OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Sodium polyacrylate (see super absorbent


polymer)

Solanesol (environmental tobacco smoke, ASTM D 6271 150-3600 2500 1-24 HPLC-UV FLT 225-3705 108 CST 225-3LF 115
respirable particles) CYC 225-01-02 127 C/HLD 225-1 116

Solder fume (ICP analysis of metal/metalloid OSHA ID 206 480 2000 4 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
particulates from solder operations)

Soot (see elemental carbon) NIOSH 5040 TOA-FID

Spores (bacterial, fungal) (in air) 15-150 15000 1-10 min varies STC 225-9820 114

Spores (bacterial, fungal) (in air) NON 48 62.5-375 12,500 + 5-30 varies BS 225-9595 138 VT 225-9598A 138

Starch (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Starch (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

232 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Starch (see Particulates Not Otherwise Regulated,
total and respirable)

Stoddard solvent OSHA 48 500 3 200 15 min GC-FID ST 226-01 48

Stoddard solvent (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 10 1.5 20(50) 100 8(3.3) 15 GC-FID ST 226-01 48

Strontium (Elements by Cellulosic Internal Capsule NIOSH 7306 Varies 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Strontium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 10-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Strontium (Elements by ICP HNO3 Digestion) NIOSH 7303 300-100,000,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Strontium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.5 mg/m3 10-1000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Strontium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Strychnine NIOSH 5016 0.15 mg/m3 180 1500 2 HPLC-UV F/CST 225-706 110 C/HLD 225-1 116
(10 hrs)

Styrene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Styrene Internal 13.7 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or


PS 690-104 96

Styrene Internal 13.7 ml/min 8-24 hrs SE, GC PS 690-105 96

Styrene (phenylethylene) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Styrene (phenylethylene) NON 54 10 3 20 200 8 15 GC-FID ST 226-81A 49

Styrene (phenylethylene) OSHA 1014 100 200 (C) 13.55 13.55 8 15 HPLC-UV PS 575-006 82

Styrene (phenylethylene) OSHA 89 100 200 (C) 12 0.75 50 50 4 15 GC-FID ST 226-73 49

Styrene (phenylethylene) (Hydrocarbons, NIOSH 1501 50 100 1-14 1-14 10-1000 10-1000 varies varies GC-FID ST 226-01 48
Aromatic)

Sucrose (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Sucrose (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Sulfur (see Particulates Not Otherwise Regulated,


total and respirable)

Sulfur dioxide NIOSH 6004 2 5 180 15 1000 1000 3 15 IC CF/CST 225-9005 68 C/HLD 225-1 116

Sulfur dioxide OSHA 1011 5 ppm 12 7.5 50 500 4 15 IC CF/CST 225-9005 68

Sulfur hexafluoride by portable GC NIOSH 6602 1000 varies 20-100 varies P GC-ECD SB 232-03 or SB 231-03 60

Sulfur tetrafluoride OSHA ID 110 5 1000 5 ISE IMP 225-36-2 70 IT 225-22 70

Sulfuric acid NIOSH 7908 1 mg/m3 960 2000 8 IC-CD CF/CST 225-9033 68 C/HLD 225-1 116

Sulfuric acid NIOSH 7908 0.2 mg/m3 ∑ 960 2000 8 IC PPI 225-381 130 FLT 225-1827 109
IS 225-388 130 SP 225-27 117

Sulfuric acid OSHA ID 113 1 mg/m3 480 2000 4 IC F/CST 225-3-01 102 C/HLD 225-1 116

Sulfuric acid OSHA ID 113 0.2 mg/m ∑ 3


480 2000 4 IC PPI 225-381 130 FLT 225-5 102
IS 225-388 130 SP 225-27 117

Sulfuric acid OSHA ID 165SG 1 mg/m3 96 200 8 IC ST 226-10-03 48

Sulfuric acid mist ASTM D 4856 40 1000 40 min IC F/CST 225-3-01 102 C/HLD 225-1 116

Sulfuryl fluoride NIOSH 6012 5 10 varies 50-100 varies IC-CD ST 226-16 48

Sulprofos OSHA PV2037 240 1000 4 GC-FPD ST 226-30-16 48

Sulprofos (Organophosphorus Pesticides) NIOSH 5600 1 mg/m 3


240 1000 4 GC-FPD ST 226-58 49

Super absorbent polymers NIOSH 5035 960 2000 8 ICP-AES F/CST 225-802 107 C/HLD 225-1 116
or AA

Systox (see demeton)

Talc (containing asbestos) (see asbestos) OSHA ID 160

Talc (respirable, no asbestos) OSHA PV2121 20 mppcf varies varies varies GR CYC 225-105 126 F/CST 225-803 107
C/HLD 225-1

2,4-TDI (toluene diisocyanate) ASTM D 5932 15 1000 15 HPLC-UV- CF/CST 225-9022  68 C/HLD 225-1 116
FD

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 233


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
2,4-TDI (toluene diisocyanate) NIOSH 5522 LFC 360 20 1000 2000 6 10 HPLC-FD IMP 225-36-1 70 IT 225-22 70

2,4-TDI (toluene diisocyanate) OSHA 42 0.02 (C) 240 15 1000 1000 4 15 HPLC-UV or CF/CST 225-9002 or CF/CST 225-9013 68
HPLC-FD C/HLD 225-1 116

2,6-TDI (toluene diisocyanate) ASTM D 5932 15 1000 15 HPLC-UV- CF/CST 225-9022  68 C/HLD 225-1 116
FD

2,6-TDI (toluene diisocyanate) NIOSH 5522 LFC 360 20 1000 2000 6 10 HPLC-FD IMP 225-36-1 70 IT 225-22 70

2,6-TDI (toluene diisocyanate) OSHA 42 15 2000 15 HPLC-UV or CF/CST 225-9002 or CF/CST 225-9013 68
HPLC-FD C/HLD 225-1 116

2,4-TDI (Toluene diisocyanate) (isocyanates) OR-OSHA 1010 0.02 0.005 45 5 1000 1000 45 min 5 HPLC IMP 225-36-1 70 IT 225-22 70
CF/CST 225-9029 68

2,6-TDI (Toluene diisocyanate) (isocyanates) OR-OSHA 1010 0.02 0.005 45 5 1000 1000 45 min 5 HPLC IMP 225-36-1 70 IT 225-22 70
CF/CST 225-9029 68

2, 4-TDI (toluene diisocyanate) (isocyanates, total) NIOSH 5525 LFC 1-500 1000-2000 varies HPLC-UV FLT 225-7 ‡ 110 CST 225-4 115
SP 225-27 or IOM 225-76A 122
FLT 225-702 ‡ 110

2, 6-TDI (toluene diisocyanate) (isocyanates, total) NIOSH 5525 LFC 1-500 1000-2000 varies HPLC-UV FLT 225-7 ‡ 110 CST 225-4 115
SP 225-27 or IOM 225-76A 122
FLT 225-702 ‡ 110

Tellurium OSHA ID 121 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Tellurium OSHA ID 132SG 0.1 mg/m3 100 to 1000 1500 to varies AA-GF F/CST 225-3-01 102 C/HLD 225-1 116
2000

Tellurium (Elements by Cellulosic Internal Capsule NIOSH 7306 7-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Tellurium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.1 mg/m3 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Tellurium (Elements by ICP HNO3 Digestion) NIOSH 7303 0.1 mg/m3 125- 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
500,000

Tellurium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.1 mg/m3 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Tellurium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Temephos (respirable dust) OSHA PV2056 5 mg/m3 varies varies varies GC-FPD F/CST 225-706 110 C/HLD 225-1 116

Temephos (total dust) OSHA PV2056 15 mg/m3 60 1000 HPLC-UV F/CST 225-802 107 C/HLD 225-1 116

Terbufos (Organophosphorus Pesticides) NIOSH 5600 240 1000 4 GC-FPD ST 226-58 49

Terbuthiuron ASTM D 4861 240-7200 1000-5000 4-24 HPLC-UV PUF 226-92 54

Terpenes (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 52

Terpenes (see specific compounds) NIOSH 1552 24 50 8 GC-FID ST 226-01 48

o-Terphenyl NIOSH 5021 0.5 30 2000 15 GC-FID F/CST 225-1713 108 C/HLD 225-1 116

Testosterone OSHA PV2001 60 1000 1 HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

1,1,2,2-Tetrabromoethane NIOSH 2003 96 200 8 GC-FID ST 226-10 48

Tetrabutyltin (organotin compounds as Sn) NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC & ST 226-30 48 F/CST 225-709 110
AA-GF C/HLD 225-1 116

1,1,2,2-Tetrachloro-1,2-difluoroethane NIOSH 1016 500 2 20 1.5 GC-FID ST 226-01 48

1,1,1,2-Tetrachloro-2,2-difluoroethane NIOSH 1016 500 2 20 1.5 GC-FID ST 226-01 48

1,2,3,4-Tetrachlorobenzene ASTM D 4861 240-7200 1000-5000 4-24 GC-ECD PUF 226-124 54

1,2,4,5-Tetrachlorobenzene (polychlorobenzenes) NIOSH 5517 12 25 8 GC-ECD FLT Special order CST Special
ST 226-30-04 48 order
C/HLD 225-1 116

1,1,1,2-Tetrachloroethane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

1,1,2,2-Tetrachloroethane ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

1,1,2,2-Tetrachloroethane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

1,1,2,2-Tetrachloroethane Internal 11.8 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or


PS 690-104 96

1,1,2,2-Tetrachloroethane Internal 11.8 ml/min 8-24 hrs SE, GC PS 690-105 96

1,1,2,2-Tetrachloroethane NIOSH 1019 1 24 50 8 GC-FID ST 226-81A 49

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

234 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
1,1,2,2-Tetrachloroethane NIOSH 2562 1 3-30 10-200 varies GC-FID ST NA SKC

Tetrachloroethylene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Tetrachloroethylene Indoor 13.1 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or


PS 690-104 96

Tetrachloroethylene Internal 0.55 ml/min 24 hrs to 7 TD, GC PS 690-101 or PS 690-103 or


days PS 690-104 with RR 690-300 96

Tetrachloroethylene Internal 13.1 ml/min 8 hrs-30 SE, GC PS 690-105 96


days

Tetrachloroethylene (hydrocarbons, halogenated) NIOSH 1003 LFC 3 10-200 varies GC-FID ST 226-01 48

Tetrachloroethylene (perchloroethylene) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Tetrachloroethylene (perchloroethylene) OSHA 1001 100 200 (C) 13.06 8 5 GC-FID PS 575-002 82

Tetrachloroethylene (perchloroethylene) OSHA 1001 100 200 (C) 12 0.75 50 50 4 5 GC-FID ST 226-01 48

Tetrachloroethylene (perchloroethylene) (portable NIOSH 3704 LFC 1 20-5000 varies P GC SB 232-01 or SB 249-01-PP with
GC) PT NA SKC with SBLK NA SKC

2,3,4,6-Tetrachlorophenol OSHA 45 48 200 4 HPLC-UV ST 226-97 50

Tetraethyl lead (as Pb) NIOSH 2533 0.075 mg/ 30-200 10-1000 GC-PID ST 226-30-04 48
m3

Tetraethyl pyrophosphate NIOSH 2504 0.05 mg/m3 24 50 8 GC-FPD ST NA SKC

Tetraethyl tin OSHA 110 0.1 mg/m3 48 3 200 200 4 15 GC-FID ST 226-95 50

Tetraethylene glycol NIOSH 5523 60 1000 1 GC-FID ST 226-57 49

Tetrahydrofuran Internal 17.7 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Tetrahydrofuran Internal 17.7 ml/min 8-24 hrs SE, GC PS 690-105 96

Tetrahydrofuran NIOSH 1609 200 250 9 1.5 20(50) 100 7(3) 15 GC-FID ST 226-01 48

Tetrahydrofurfuryl acrylate OSHA PV2131 1 mg/m 3


48 200 4 GC-FID ST 226-110 50

Tetrakis(hydroxymethyl)phosphonium chloride NIOSH 5046 1-480 1000-1700 varies HPLC-UV CF/CST 225-9003 68

Tetramethyl lead (as Pb) NIOSH 2534 0.075 mg/ 15-100 10-200 GC-PID ST 226-30-06 48
m3

Tetramethyl thiouram disulfide (see thiram)

Tetramethyl thiourea NIOSH 3505 96 200 8 VAS IMP 225-36-1 70 IT 225-22 70

Tetramethyl tin OSHA PV2057 0.1 mg/m 3


20 200 100 min GC-FID ST 226-01 48

Tetranitromethane NIOSH 3513 1 240 1000 4 GC-NPD IMP 225-36-1 70 IT 225-22 70

Tetrasodium pyrophosphate OSHA ID 111 960 2000 8 GR & IC FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Tetrasodium pyrophosphate OSHA ID 121 960 2000 8 AA or AES FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Thalium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.1 mg/ 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 107
m3 (skin, C/HLD 225-1 116
soluble)

Thallium (Elements by Cellulosic Internal Capsule NIOSH 7306 0.1 mg/m3 7-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler) (skin)

Thallium (Elements by ICP HNO3 Digestion) NIOSH 7303 0.1 mg/ 35-500,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
m3 (skin,
soluble)

Thallium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.1 mg/ 25-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
m3 (skin,
soluble)

Thallium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Thallium (soluble compounds) (as Tl) OSHA ID 121 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Thiobencarb (Organonitrogen Pesticides) NIOSH 5601 240 1000 4 HPLC-UV ST 226-58 or ST 226-30-16 48

Thiophanate-methyl OSHA PV2058 240 1000 4 HPLC-UV F/CST 225-709 110 C/HLD 225-1 116

Thiophanate-methyl in air NIOSH 5606 20-480 10-1000 varies HPLC-UV ST 226-58 49

Thiourea OSHA PV2059 480 2000 4 HPLC-UV F/CST 225-706 110 C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 235


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Thiram NIOSH 5005 5 mg/m3 120 1000 2 HPLC-UV FLT 225-17-01 108 CST 225-2LF 115
C/HLD 225-1 116

Tin (Elements by Cellulosic Internal Capsule NIOSH 7306 2 mg/m3 1-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Tin (Elements by ICP Aqua Regia Ashing) NIOSH 7301 2 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Tin (Elements by ICP HNO3 Digestion) NIOSH 7303 2 mg/m3 1-25,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Tin (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 2 mg/m3 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Tin (ICP analysis of metal/metalloid particulates OSHA ID 206 2 mg/m 3


480 2000 4 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
from solder operations)

Tin (inorganic compounds, except oxides) (as Sn) OSHA ID 121 2 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Tin (organic compounds) (as Sn) (organotin NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC & ST 226-30 48 F/CST 225-706 110
compounds) AA-GF C/HLD 225-1 116

Tin oxide ((Stannous Oxide) as Sn) OSHA ID 121 0.1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Titanium (Elements by Cellulosic Internal Capsule NIOSH 7306 Varies 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Titanium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Titanium (Elements by ICP HNO3 Digestion) NIOSH 7303 0.1-10,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Titanium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 5-100 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Titanium dioxide (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Titanium dioxide (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Titanium dioxide (total dust) OSHA PV2121 15 mg/m3 480-960 2000 4-8 GR F/CST 225-802 107 C/HLD 225-1 116

TNT (2,4,6-trinitrotoluene) OSHA 44 1.5 mg/m3 60 1000 1 GC-TEA- ST 226-56 49


EAP

o-Tolidine OSHA 71 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

o-Tolidine dyes (dyes, benzidine) NIOSH 5013 LFC 480 1000 8 HPLC-UV FLT 225-17P 108 CST 225-3LF 115
C/HLD 225-1 116

m-Tolualdehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

o-Tolualdehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

p-Tolualdehyde ASTM D 5197 varies 500-1200 5 min-24 hrs HPLC-UV ST 226-120  or ST 226-119 50

Toluene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Toluene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Toluene Internal 14.5 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or


PS 690-104 96

Toluene Internal 0.63 ml/min 24 hrs to 7 days TD, GC PS 690-101 or PS 690-103 or


PS 690-104 with RR 690-300 96

Toluene Internal 14.5 ml/min 8 hrs-30 days SE, GC PS 690-105 96

Toluene OSHA 111 200 300 (C) 12 0.5 50 50 4 10 GC-FID ST 226-81A 49 ST 226-01 48

Toluene (Hydrocarbons, Aromatic) NIOSH 1501 100 150 1-8 1-8 10-200 10-200 varies varies GC-FID ST 226-01 48

2,4-Toluene diisocyanate ASTM D 5836 15 1000 15 HPLC-UV or CF/CST 225-9002 68 C/HLD 225-1 116
HPLC-FD

2,4-Toluene diisocyanate ASTM D 5932 15 1000 15 HPLC-UV- CF/CST 225-9022  68 C/HLD 225-1 116
FD

2,4-Toluene diisocyanate OSHA 5002 0.02 (C) 240 15 1000 1000 4 15 HPLC-UV or CF/CST 225-9002 or CF/CST 225-9013 or
HPLC-FD CF/CST 225-9022  68 C/HLD 225-1 116

2,6-Toluene diisocyanate ASTM D 5836 15 1000 15 HPLC-UV CF/CST 225-9002 68 C/HLD 225-1 116
or HPLC-FD

2,6-Toluene diisocyanate ASTM D 5932 15 1000 15 HPLC-UV- CF/CST 225-9022  68 C/HLD 225-1 116
FD

2,6-Toluene diisocyanate OSHA 5002 240 1000 4 HPLC-UV or CF/CST 225-9002 or CF/CST 225-9013 or
HPLC-FD CF/CST 225-9022  68 C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

236 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
2,4-Toluene diisocyanate (isocyanates) NIOSH 5521 LFC 480 10 1000 1000 8 10 HPLC- IMP 225-36-1 70 IT 225-22 70
ELCHM &
HPLC-UV

2,4-Toluene diisocyanate (isocyanates) OR-OSHA 1010 0.02 0.005 45 5 1000 1000 45 min 5 HPLC IMP 225-36-1 70 IT 225-22 70
CF/CST 225-9029 68

2,6-Toluene diisocyanate (isocyanates) NIOSH 5521 LFC 480 1000 8 HPLC- IMP 225-36-1 70 IT 225-22 70
ELCHM &
HPLC-UV

2,6-Toluene diisocyanate (isocyanates) OR-OSHA 1010 0.02 0.005 45 5 1000 1000 45 min 5 HPLC IMP 225-36-1 70 IT 225-22 70
CF/CST 225-9029 68

2,4-Toluene diisocyanate (isocyanates, total) NIOSH 5525 LFC 1-500 1000-2000 varies HPLC-UV FLT 225-7 ‡ 110 CST 225-4 115
SP 225-27 or IOM 225-76A 122
FLT 225-702 ‡ 110

2,6-Toluene diisocyanate (isocyanates, total) NIOSH 5525 LFC 1-500 1000-2000 varies HPLC-UV FLT 225-7 ‡ 110 CST 225-4 115
SP 225-27 or IOM 225-76A 122
FLT 225-702 ‡ 110

p-Toluene sulfonic acid NIOSH 5043 960 45 2000 3000 8 15 HPLC-UV FLT 225-16 110 CST 225-32 116

Toluene-2,4-diamine OSHA 65 0.02 (C) 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

2,4-Toluenediamine NIOSH 5516 LFC 480 1000 8 HPLC-UV IMP 225-36-1 70 IT 225-22 70

2,4-Toluenediamine OSHA 65 0.02 (C) 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

2,6-Toluenediamine NIOSH 5516 LFC 480 1000 8 HPLC-UV IMP 225-36-1 70 IT 225-22 70

2,6-Toluenediamine OSHA 65 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

2,6-Toluenediamine OSHA 65 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

m-Toluidine OSHA 73 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

o-Toluidine NIOSH 2017 LFC 24 200 2 GC-FID CF/CST 225-9004 68 ST 226-15 48

o-Toluidine OSHA 73 5 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

p-Toluidine OSHA 73 100 1000 100 min GC-ECD CF/CST 225-9004 68 C/HLD 225-1 116

o-Toluidine (Amines, Aromatic) NIOSH 2002 LFC 48 100 8 GC-FID or ST 226-10 48


GC-NSD

Toxaphene (see chlorinated camphene)

Tremolite (see asbestos fibers) NIOSH 7400

Tremolite fibers (see asbestos) OSHA ID 160

Triazine pesticides ASTM D 4861 960 2000 8 GC-ECD PUF 226-92 54

Tributyl phosphate NIOSH 5034 0.2 90 1500 1 GC-FPD F/CST 225-3-01 102 C/HLD 225-1 116

Tributyltin benzoate (tin, organic compounds OSHA ID 222SG 200 2000 100 min AA-GF F/CST 225-803 107 C/HLD 225-1 116
[as Sn])

Tributyltin chloride (organotin compounds as Sn) NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC & ST 226-30 48 F/CST 225-709 110
AA-GF C/HLD 225-1 116

Tributyltin fluoride (tin, organic compounds [as Sn]) OSHA ID 223SG 200 2000 100 min AA-GF F/CST 225-803 107 C/HLD 225-1 116

Tributyltin neodecanoate (see tin, organic


compounds)

1,1,2-Trichloro-1,2,2-trifluoroethane OSHA 113 1000 1 50 20 min GC-FID ST NA SKC

1,1,2-Trichloro-1,2,2-trifluoroethane (Freon 113) NIOSH 1020 1000 1250 2.4 0.3 20 20 2 15 GC-FID ST 226-01 48

Trichloroacetic acid OSHA PV2017 10 200 50 HPLC-UV ST 226-10 48

1,2,3-Trichlorobenzene ASTM D 4861 240-7200 1000-5000 4 to 24 GC-ECD PUF 226-124 54

1,2,3-Trichlorobenzene OSHA in 12 200 GC-ECD F/CST NA SKC ST 226-30-04 48


house file C/HLD 225-1 116

1,2,4-Trichlorobenzene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

1,2,4-Trichlorobenzene (polychlorobenzenes) NIOSH 5517 5 12 3 25 200 8 15 GC-ECD FLT Special order CST Special
ST 226-30-04 48 order
C/HLD 225-1 116

1,1,2-Trichloroethane ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

1,1,2-Trichloroethane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

1,1,2-Trichloroethane Internal 12.5 ml/min 8-24 hrs SE, GC PS 690-105 96

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 237


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
1,1,2-Trichloroethane OSHA 11 10 10 200 1 GC-FID ST 226-01 48

1,1,2-Trichloroethane (hydrocarbons, halogenated) NIOSH 1003 10 (skin) 10 10-200 varies GC-FID ST 226-01 48

1,1,1-Trichloroethane (methyl chloroform) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

1,1,1-Trichloroethane (methyl chloroform) Internal 14.1 ml/min 8-24 hrs SE, GC PS 690-105 96

1,1,1-Trichloroethane (methyl chloroform) NIOSH 1003 350 3 10-200 varies GC-FID ST 226-01 48
(hydrocarbons, halogenated)

Trichloroethylene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Trichloroethylene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

Trichloroethylene Internal 14.9 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 96

Trichloroethylene Internal 14.9 ml/min 8-24 hrs SE, GC PS 690-105 96

Trichloroethylene Internal 0.596 ml/ 24 hrs to 7 SE, GC PS 690-105 with RR 690-300 96


min days

Trichloroethylene NIOSH 1022 25 2 (1 hrs) 10 2 20(50) 200 8(3.3) 10 GC-FID ST 226-01 48

Trichloroethylene OSHA 1001 100 200 (C) 14.24 8 5 GC-FID PS 575-002 82

Trichloroethylene OSHA 1001 100 200 (C) 12 0.75 50 50 4 5 GC-FID ST 226-01 48

Trichloroethylene (hydrocarbons, halogenated) NIOSH 1003 10 10-200 varies GC-FID ST 226-01 48

Trichloroethylene by portable GC NIOSH 3701 25 2 (1 hrs) varies varies 20-50 varies varies varies P GC-PID SB 232 Series 61

Trichlorofluoromethane (fluorotrichloromethane) NIOSH 1006 1000 5 20 240 GC-FID ST 226-09 48

Trichloronitromethane NON 51 0.1 144 100 24 GC-MSD ST 226-175 51

2,4,5-Trichlorophenol ASTM D 4861 240-7200 1000-5000 4 to 24 GC-ECD PUF 226-92 54

2,4,5-Trichlorophenoxyacetic acid (see 2,4,5-T)

1,2,3-Trichloropropane Internal 11.9 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or


PS 690-104 96

1,2,3-Trichloropropane Internal 11.9 ml/min 8-24 hrs SE, GC PS 690-105 96

1,2,3-Trichloropropane (hydrocarbons, NIOSH 1003 10 (skin) 0.6-60 10-200 varies GC-FID ST 226-01 48
halogenated)

Tricyclohexyltin hydroxide (organotin compounds NIOSH 5504 0.1 mg/m3 480 1000 8 HPLC & ST 226-30 48 F/CST 225-709 110
as Sn) AA-GF C/HLD 225-1 116

Tridymite (see silica, respirable crystalline) OSHA ID 142 (v4)

Tridymite (Silica, cCystalline (respirable) by XRD) NIOSH 7500 0.05 mg/m3 400-1000 2500 varies XRD F/CST 225-803 107 CYC 225-01-02 127
C/HLD 225-1 116

Tridymite (Silica, Crystalline by IR) NIOSH 7602 0.05 mg/m3 1000 2000-4000 varies IR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-309 115

Triethanolamine (TEA) OSHA PV2141 120 1000 2 GC-FID F/CST 225-709 110 C/HLD 225-1 116

Triethanolamine (TEA) NIOSH 3509 240 1000 4 IC IMP 225-36-1 70 IT 225-22 70


(Aminoethanol Compounds II)

Triethylamine OSHA PV2060 25 5 3 100 200 50 min 15 GC-FID ST 226-98 50

Triethylene glycol NIOSH 5523 60 1000 1 GC-FID ST 226-57 49

Triethylenetetramine (TETA) OSHA 60 10 100 100 min HPLC-UV ST 226-30-18 48

Trifluorobromomethane NIOSH 1017 1000 1 20 50 min GC-FID ST 226-01 48 ST 226-09 48

Trifluoromonobromomethane NIOSH 1017 1000 1 20 50 min GC-FID ST 226-01 48 ST 226-09 48


(trifluorobromomethane)

Trifluralin ASTM D 4861 240-7200 1000-5000 4 to 24 GC-ECD PUF 226-92 54

1,3,5-triglycidyl isocyanurate OSHA 1024 180 1 3 GC-FID FLT 225-7 110 CST 225-2LF 115
SP 225-27 117 C/HLD 225-1 116

1,3,5-triglycidyl-s-triazinetrione OSHA 1024 180 1 3 GC-FID FLT 225-7 110 CST 225-2LF 115
SP 225-27 117 C/HLD 225-1 116

Trimellitic anhydride (TMA) NIOSH 5036 0.005 (10 960 2000 8 GC-FID F/CST 225-802 107 C/HLD 225-1 116
hrs)

Trimellitic anhydride (TMA) OSHA 98 480 2000 4 HPLC-UV CF/CST 225-9010 68 C/HLD 225-1 116

2,2,4-Trimethyl-1,3-pentanediol diisobutyrate OSHA PV2002 10 100 100 min GC-FID ST 226-110 50

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

238 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
1,2,3-Trimethylbenzene OSHA 1020 25 2.78 11.6 4 15 GC-FID PS 575-002 82

1,2,3-Trimethylbenzene OSHA 1020 25 12 50 4 GC-FID ST 226-01 48

1,2,4-Trimethylbenzene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

1,2,4-Trimethylbenzene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

1,2,4-Trimethylbenzene Internal 13.0 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or


PS 690-104 96

1,2,4-Trimethylbenzene Internal 13.0 ml/min 8-24 hrs SE, GC PS 690-105 96

1,2,4-Trimethylbenzene OSHA 1020 25 2.81 11.7 4 15 GC-FID PS 575-002 82

1,2,4-Trimethylbenzene OSHA 1020 25 12 50 4 GC-FID ST 226-01 48

1,3,5-Trimethylbenzene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

1,3,5-Trimethylbenzene (mesitylene) ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

1,3,5-Trimethylbenzene (mesitylene) OSHA 1020 25 2.9 12.1 4 15 GC-FID PS 575-002 82

1,3,5-Trimethylbenzene (mesitylene) OSHA 1020 25 12 50 4 GC-FID ST 226-01 48

Trimethylbenzene OSHA 5000 25 12 50 4 GC-FID ST 226-01 48

3,5,5-Trimethylcyclohex-2-enone (isophorone) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

3,5,5-Trimethylcyclohex-2-enone (isophorone) Internal 11.3 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-104 96

Trimethyltin dichloride NIOSH 5526 0.1 mg/m3 60 60 250 1000 4 60 GC-FPD ST 226-30-16 48

2,4,7-Trinitrofluoren-9-one NIOSH 5018 480 3000 2.7 HPLC-UV FLT 225-17-04 108 CST 225-3LF 115
C/HLD 225-1 116

2,4,6-Trinitrotoluene (TNT) OSHA 44 1.5 mg/m3 60 1000 1 GC-TEA- ST 226-56 49


EAP

Triorthocresyl phosphate NIOSH 5037 0.1 mg/m3 90 1000 1.5 GC-FPD F/CST 225-3-01 102 C/HLD 225-1 116

Triphenyl phosphate NIOSH 5038 3 mg/m3 240 1000 4 GC-FPD F/CST 225-3-01 102 C/HLD 225-1 116

Triphenyl tin chloride (as Sn) NIOSH 5527 0.1 mg/m3 100-2000 1000-4000 varies HPLC & FLT 225-5-37-P 107 C/HLD 225-1 116
(skin) ICP-AES

Triphenyltin hydroxide {tin, organic compounds OSHA ID 225SG 0.1 mg/m3 200 2000 100 min AA-GF F/CST 225-709 110 C/HLD 225-1 116
(as Sn)}

Tripoli (see silica, respirable crystalline) OSHA ID 142 (v4)

Tripropylene glycol diacrylate (TPGDA) NON 39 480 1000 8 GC-FID ST 226-56 49

Tuberculosis (mycobacterium tuberculosis), NIOSH 0900 1920 4000 8 PCR FLT 225-3705 108 SP 225-27 117
airborne CST 225-3LF 115 C/HLD 225-1 116

Tungsten & compounds (insoluble) (as W) OSHA ID 213 480 30 2000 2000 4 15 ICP F/CST 225-3-01 102 C/HLD 225-1 116

Tungsten & compounds (soluble) (as W) OSHA ID 213 480 30 2000 2000 4 15 ICP F/CST 225-3-01 102 C/HLD 225-1 116

Tungsten (Elements by Cellulosic Internal Capsule NIOSH 7306 5 mg/m3 10 mg/m3 Varies 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Tungsten (Elements by ICP Aqua Regia Ashing) NIOSH 7301 5 mg/m3 10 mg/m3 50-1000 50-1000 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Tungsten (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 5 mg/m3 10 mg/m3 5-1000 5-1000 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Tungsten insoluble NIOSH 7074 5 mg/m3 10 mg/m3 480 1000 8 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Tungsten soluble NIOSH 7074 1 mg/m3 3 mg/m3 480 1000 8 AA-F F/CST 225-3-01 102 C/HLD 225-1 116

Turpentine NIOSH 1551 100 10 20(50) 8(3.3) GC-FID ST 226-01 48

n-Undecane EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

n-Undecane (hydrocarbons, BP 36 to 216 C) NIOSH 1500 2 2 10-50 varies GC-FID ST 226-01 48

Uranium (soluble compounds) OSHA ID 170SG 0.05 mg/m3 240 2000 2 POL F/CST 225-803 107 C/HLD 225-1 116

Urea pesticides ASTM D 4861 240-7200 1000-5000 4 to 24 GC-ECD PUF 226-92 54

n-Valeraldehyde ASTM D 5197 varies 500-1200 5 min to HPLC-UV ST 226-120 or ST 226-119 50


24 hrs

n-Valeraldehyde NIOSH 2536 50 10 20 8 GC-FID ST 226-118 50

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 239


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
n-Valeraldehyde OSHA 85 3 50 1 HPLC-UV CF/CST 225-9020 68 C/HLD 225-1 116

n-Valeraldehyde (Aldehydes, Screening) NIOSH 2539 50 5 20 4 GC-FID & ST 226-118 50


GC-MS

Vanadium (Elements by ICP HNO3 Digestion) NIOSH 7303 0.05 mg/m3 2.5- 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
500,000

Vanadium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 0.05 mg/m3 5-2000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Vanadium (Elements by Cellulosic Internal NIOSH 7306 0.05 mg/m3 C Varies 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Capsule Sampler) (as pentoxide)

Vanadium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 0.05 mg/m3 5-2000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Vanadium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Vanadium fume (as V2O5) OSHA ID 125G 0.05 mg/m3 0.1 480 20 2000 1000 4 20 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Vanadium oxides NIOSH 7504 0.05 mg/m3 600 2600 4 XRD F/CST 225-803 107 C/HLD 225-1 116
(15 min) CYC 225-01-02 127

Vanadium pentoxide (V2O5) (see vanadium NIOSH 7504


oxides)

Vanadium pentoxide (fume) OSHA PV2121 0.1 mg/m3 (fume) 960 2000 8 GR F/CST 225-803 107 C/HLD 225-1 116

Vanadium pentoxide (respirable dust) OSHA PV2121 0.5 mg/m3 960 2000 8 GR F/CST 225-803 107 C/HLD 225-1 116
(respirable dust) CYC 225-105 126

Vanadium respirable dust (as V2O5) OSHA ID 125G 0.5 mg/m3 varies varies varies ICP-AES F/CST 225-3-01 102 CYC 225-105 126
C/HLD 225-1 116

Vanadium trioxide (see vanadium oxides) NIOSH 7504

Vermiculite (see Particulates Not Otherwise


Regulated, total and respirable)

Vinyl acetate NON 21 24 50 8 GC ST 226-68 49

Vinyl acetate OSHA 51 24 3 100 200 4 15 GC-FID ST NA SKC

Vinyl bromide NIOSH 1009 LFC 10 20(50) 8(3.3) GC-FID ST 226-09 48

Vinyl bromide OSHA 08 5 20 4 GC-FID ST 226-01 48

Vinyl chloride ASTM D 4766 24 100 or 50 4 or 8 GC-FID ST 226-16 48

Vinyl chloride ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Vinyl chloride NIOSH 1007 LFC 5 50 1.6 GC-FID ST 226-01 48

Vinyl cyclohexene dioxide OSHA PV2083 10 20(50) 8(3.3) GC-FID ST 226-30 48

Vinyl toluene NIOSH 1501 100 30 200 2.5 GC-FID ST 226-01 48

Vinyl toluene (methyl styrene) EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

N-Vinyl-2-pyrrolidinone OSHA PV2106 10 100 100 min GC-FID ST 226-01 48

Vinylidene chloride ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

Vinylidene chloride NIOSH 1015 LFC 5 20 4 GC-FID ST 226-01 48

Vinylidene chloride OSHA 19 3 3 200 200 15 min 15 GC-FID ST 226-01 48

Viruses (in air) NON 48 62.5-375 12,500 + 5-30 varies BS 225-9595 138 VT 225-9598A 138

VM&P naphtha OSHA 48 3 3 20 200 2.5 15 GC-FID ST 226-01 48

VM&P naphtha (naphthas) NIOSH 1550 350 mg/m3 1800 mg/m3 10 3 20(50) 200 8(3.3) 15 GC-FID ST 226-01 48

Volatile organic compounds (screening) NIOSH 2549 5 20 4 GC-MS ST 226-330 52

Volatile organic compounds (VOCs) (canister) EPA TO-14A varies varies varies GC-MS CAN 228 Series PK 228 Series

Volatile organic compounds (VOCs) (canister) EPA TO-15 varies varies varies GC-MS CAN 228 Series PK 228 Series

Volatile organic compounds (VOCs) (sample bag) EPA 0040 250-1000 1-2 hrs GC-MS VAC 231-939 or VAC 231-940 with
ml/min SB 236-004 or SB 232-939 or
SB 236-001 or SB 232-01 61

Volatile organic compounds (VOCs) (thermal EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
desorption tube) 66.7 ml/min CPC 224-26-CPC 37

VOST (volatile organic sampling train) EPA 0031 20 min 1 L/min 20 min TD, GC-MS ST 226-134 £ 51 ST Special
Order

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

240 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Warfarin NIOSH 5002 0.1 mg/m3 360 1500 4 HPLC-UV FLT 225-17-01 108 CST 225-2LF 115
C/HLD 225-1 116

Welding fumes (total particulate) OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Wood alcohol (methanol) NIOSH 2000 200 250 5 3 20 200 4 15 GC-FID ST 226-51 49

Wood dust OSHA PV2121 15 mg/m3 960 2000 4-8 GR F/CST 225-802 107 C/HLD 225-1 116

Wood dust, hardwood OSHA PV2121 15 mg/m3 960 2000 4-8 GR F/CST 225-802 107 C/HLD 225-1 116

Wood dust, softwood OSHA PV2121 15 mg/m 3


960 2000 4-8 GR F/CST 225-802 107 C/HLD 225-1 116

Wood spirit (methanol) NIOSH 2000 200 250 5 3 20 200 4 15 GC-FID ST 226-51 49

m-Xylene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

m-Xylene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

m-Xylene Internal 0.61 ml/min 24 hrs to 7 TD, GC PS 690-101 or PS 690-103 or


days PS 690-104 with RR 690-300 96

m-Xylene Internal 12.5 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or


PS 690-104 96

m-Xylene Internal 12.5 ml/min 8 hrs-30 SE, GC PS 690-105 96


days

m-Xylene OSHA 1002 100 13.82 8 GC-FID PS 575-002 82

o-Xylene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

o-Xylene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

o-Xylene Internal 0.61 ml/min 24 hrs to 7 TD, GC PS 690-101 or PS 690-103 or


days PS 690-104 with RR 690-300 96

o-Xylene Internal 11.9 ml/min 8-24 hrs TD, GC PS 690-101 or PS 690-103 or


PS 690-104 96

o-Xylene Internal 11.9 ml/min 8 hrs-30 SE, GC PS 690-105 96


days

o-Xylene OSHA 1002 100 14.24 8 GC-FID PS 575-002 82

p-Xylene ASTM D 5466 6 varies varies GC-MS CAN 228 Series PK 228 Series

p-Xylene EPA TO-17 1L&4L 16.7 ml/min & TD, GC ST 226-300 Series 52 TH 224-26-02 37
66.7 ml/min CPC 224-26-CPC 37

p-Xylene Internal 12.8 ml ml/ 8-24 hrs TD, GC PS 690-101 or PS 690-103 or


min PS 690-104 96

p-Xylene Internal 0.61 ml/min 24 hrs to 7 TD, GC PS 690-101 or PS 690-103 or


days PS 690-104 with RR 690-300 96

p-Xylene Internal 12.8 ml ml/ 8 hrs-30 SE, GC PS 690-105 96


min days

p-Xylene OSHA 1002 100 13.94 8 GC-FID PS 575-002 82

m-Xylene (Hydrocarbons, Aromatic) NIOSH 1501 100 2-23 10-200 varies GC-FID ST 226-01 48

o-Xylene (Hydrocarbons, Aromatic) NIOSH 1501 100 150 2-23 2-23 10-200 10-200 varies varies GC-FID ST 226-01 48

p-Xylene (Hydrocarbons, Aromatic) NIOSH 1501 100 2-23 10-200 varies GC-FID ST 226-01 48

Xylene (o-, m-, & p-isomers) OSHA 1002 100 12 50 4 GC-FID ST 226-01 48

m-Xylenediamine (mXDA) OSHA 105 15 1000 15 HPLC-UV CF/CST 225-9004 68 C/HLD 225-1 116

p-Xylenediamine (pXDA) OSHA 105 15 1000 15 HPLC-UV CF/CST 225-9004 68 C/HLD 225-1 116

2,4-Xylidine (Amines, Aromatic) NIOSH 2002 2 10 20(50) 8(3.3) GC-FID or ST 226-10 48


GC-NSD

Yttrium OSHA ID 121 1 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Yttrium (Elements by ICP HNO3 Digestion) NIOSH 7303 0.1-50,000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Yttrium (Elements by Cellulosic Internal Capsule NIOSH 7306 1 mg/m3 1-2000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler)

Yttrium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 107
C/HLD 225-1 116

Yttrium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 5-1000 1000-4000 varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 241


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Yttrium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Zinc OSHA ID 121 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Zinc OSHA ID 125G 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Zinc & compounds (as Zn) NIOSH 7030 5 mg/m3 15 mg/m3 240 30 1000 2000 4 15 AA-F F/CST 225-3-01 102 C/HLD 225-1 116
(ZnO) (ZnO)

Zinc (Elements by Cellulosic Internal Capsule NIOSH 7306 5 mg/m3 15 mg/m3 Varies 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Sampler) C (dust)
10 mg/m3
(fume)

Zinc (Elements by ICP Aqua Regia Ashing) NIOSH 7301 5-200 1000-4000 varies ICP-AES F/CST 225-3-01 or F/CST 225-803 ¥ 107
C/HLD 225-1 116

Zinc (Elements by ICP HNO3 Digestion) NIOSH 7303 5 mg/m3 15 mg/m3 0.5-10,000 0.5-10,000 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
(ZnO) (ZnO)

Zinc (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 5 mg/m3 10 mg/m3 5-200 5-200 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
(ZnO) (ZnO)

Zinc (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Zinc bromide (see Particulates Not Otherwise


Regulated, total and respirable)

Zinc chloride fume OSHA ID 121 1 mg/m3 960 30 2000 2000 8 15 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Zinc chloride fume OSHA ID 125G 1 mg/m3 480 30 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Zinc chromate (CR(VI)) OSHA ID 215 0.005 mg/m3 960 2000 8 IC-UV F/CST 225-802 Ω 107 C/HLD 225-1 116
(V2)

Zinc chromates (as CrO3) OSHA ID 215 0.005 mg/m3 960 2000 15 IC-UV F/CST 225-802 Ω 107 C/HLD 225-1 116
(V2)

Zinc dibutyldithiocarbamate OSHA PV2065 180 1000 3 HPLC-UV ST 226-30-16 48

Zinc oxide NIOSH 7502 5 mg/m3 15 mg/m3 240 30 1000 2000 4 15 XRD FLT 225-3705 108 CST 225-3-23 115
(15 min)

Zinc oxide (Elements by ICP HNO3 Digestion) NIOSH 7303 5 mg/m3 15 mg/m3 0.5-10,000 0.5-10,000 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Zinc oxide (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Zinc oxide (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Zinc oxide dust (respirable dust) OSHA PV2121 5 mg/m3 varies varies varies GR F/CST 225-803 107 C/HLD 225-1 116
CYC 225-105 126

Zinc oxide dust (total dust) OSHA PV2121 15 mg/m3 960 2000 4-8 GR F/CST 225-802 107 C/HLD 225-1 116

Zinc oxide fume OSHA ID 121 5 mg/m3 960 30 2000 2000 8 15 AA or AES FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Zinc oxide fume OSHA ID 125G 5 mg/m3 480 30 2000 2000 4 15 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Zinc oxide fume OSHA ID 143 5 mg/m3 960 30 2000 2000 8 15 XRD FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Zinc oxide fume (ICP analysis of metal/metalloid OSHA ID 206 5 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116
particulates from solder operations)

Zinc stearate (particulates, respirable) NIOSH 0600 375 2500 2.5 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CYC 225-01-02 127 CST 225-3LF 115

Zinc stearate (particulates, total) NIOSH 0500 120 2000 1 GR FLT 225-5-37-P 107 C/HLD 225-1 116
CST 225-2LF 115

Zinc stearate (respirable dust) OSHA PV2121 5 mg/m3 varies varies varies GR F/CST 225-803 107 C/HLD 225-1 116
CYC 225-105 126

Zinc stearate (total dust) OSHA ID 121 15 mg/m3 960 2000 8 AA or AES F/CST 225-3-01 102 C/HLD 225-1 116

Zinc stearate (total dust) OSHA ID 125G 15 mg/m3 480 2000 4 ICP-AES F/CST 225-3-01 or F/CST 225-3100 or
F/CST 225-803 or F/CST 225-8215 107
C/HLD 225-1 116

Agency standards for OSHA listings represent the OSHA PELs reported in the 29 CFR 1910.1000 Part 1910, Section 1000. Abbreviations and references are found on pages 244-245.

242 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za


Sampling Guide
skcinc.com for updates

SAMPLING ∞
Agency Standard Vol. (liter) Rate (ml/min) Time
Agency TWA (ppm) CLG/STEL TWA CLG/STEL TWA CLG/STEL TWA (hrs) CLG/STEL Analytical
Chemical Hazard Reference (ppm) (min) Method SKC Collecting Equipment & Page Number
Zineb OSHA 107 500 2000 250 min HPLC-UV F/CST 225-3-01 102 C/HLD 225-1 116

Ziram OSHA PV2073 120 1000 2 HPLC-UV ST 226-30-16 48

Zirconium (Elements by Cellulosic Internal NIOSH 7306 5 mg/m3 10 mg/m3 1-1000 1000-4000 varies ICP-AES SC 225-8517 103 C/HLD 225-1 116
Capsule Sampler)

Zirconium (Elements by ICP Aqua Regia Ashing) NIOSH 7301 5 mg/m3 10 mg/m3 5-200 5-200 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 or F/CST 225-803 107
C/HLD 225-1 116

Zirconium (Elements by ICP HNO3/HClO4 Ashing) NIOSH 7300 5 mg/m3 10 mg/m3 5-200 5-200 1000-4000 1000-4000 varies varies ICP-AES F/CST 225-3-01 102 C/HLD 225-1 116

Zirconium (Elements on Wipes) NIOSH 9102 wipe ICP-AES W 225-2414 172 TMP 225-2415 172

Zirconium compounds (as Zr) OSHA ID 121 5 mg/m3 960 30 2000 2000 8 15 AA or AES F/CST 225-803 107 C/HLD 225-1 116

Symbols and Notes


∞ ������������������The sampling parameters shown are suggestions based on the ranges of volume, flow, and ♠ ��������������������Modified procedure or sampler
time specified in the methods. It is the responsibility of the analyst performing the sampling
and analysis to adjust parameters so that the required detection limits can be obtained. It is ◊ ��������������������Other collection liquids may be more suited to target microorganisms.
the responsibility of the user to research published methods to determine validation level ¥ ��������������������This method does not digest PVC filter Cat. No. 225-803 completely.
and suitability for unique applications. ∆ ��������������������1.0-micron PTFE filter is a NIOSH recommended substitute filter for the 0.8-micron PVC
C �������������������Ceiling Value filter originally recommended in NIOSH Method 7904.

EL ������������������Excursion Limit ∑ ������������������ACGIH Thoracic TWA. Use PPI for thoracic fraction TWA.

LFC ����������������NIOSH standard: Lowest Feasible Concentration + ��������������������Sonic flow

LOQ ����������������Limit of Quantitation



��������������������Use sorbent tube Cat. No. 226-120 when sampling in atmospheres containing ozone.

NA SKC ���������Not available from SKC †† ������������������Special order/limited shelf-life; contact SKC

NON ���������������Non-agency reference ▼ ������������������The MOPIP Derivatizing Solution, Cat. No. 225-9050, is needed to analyze for monomer/
oligomer aerosol.
OEL ���������������U.S. Army Occupational Exposure Limit ٠������������������� For sampling in chromium plating operations, PVC filters Cat. No. 225-802 require special
OR-OSHA �������Oregon OSHA method and target concentrations treatment after receipt at the laboratory. Alternatively quartz fiber filters Cat. No. 225-1827
treated with NaOH may be used. Refer to the method for details.
PV �������������������Provisional Method
π �������������������� SKC recommends the AirChek TOUCH, Essential, Connect, or XR5000 Sample Pump when
Special
using a silica gel sorbent tube with the coated filter at flows above 500 ml/min.
order ��������������Because of limited shelf-life, certain sampling media are available only as special
order items. £ �������������������� Collect six samples at 20 minutes each. Use two Cat. No. 226-134 per sample.
** ��������������������Optional, use filter if particulates are present  ������������������� NIOSH Method 5524 analysis requires a Filter Funnel, which is not available from SKC.
‡ ��������������������Filter or tube must be chemically treated before sampling.

SCIENCE. SERVING PEOPLE.

SKC Asia skc-asia.com • SKC Inc. skcinc.com 243


Sampling Guide
Abbreviations

Analytical Methods Abbreviations


AA Atomic absorption GR Gravimetric analysis P VAS Portable visible absorption
AAS Atomic absorption HGA Heated graphite atomizer spectrophotometry
spectroscopy HPLC High-performance liquid PASV Portable anodic stripping
AED Atomic emission detection chromatography voltammetry
AES Atomic emission spectroscopy HRGC High resolution gas PCD Post-column derivatization
CA Chromotropic acid assay chromatography PCM Phase contrast microscopy
CD Conductivity detection HRMS High resolution mass spectrometry PCR Polymerase chain reaction
CI Colorimetric IC Ion chromatography PDA Photo diode array detector
CLR Spectrophotometric method or IC-CD Ion chromatography detector PES Plasma emission
colorimeter ICP Inductively coupled plasma spectrometry
DET TB Detector tube, color-indicating ICP-DCP Inductively coupled plasma- PID Photoionization detector
DID Discharge ionization detector directly coupled plasma PLM Polarized light microscopy
DPCSP Differential pulse cathodic spectroscopy POL Polarography
stripping polarography ICP-MS Inductively coupled plasma-mass SCD Sulfur chemiluminescence
DPP Differential pulse polarography spectrometry detector
DR Direct-reading IR Infrared spectrophotometry SE Soxhlet extraction
DRI Direct-reading instrument IRA Immunoradiometric assay SEM Scanning electron
EAP Explosives analysis package ISE Ion-specific electrode microscopy
ECD Electron capture detector LC Liquid chromatography SPOT Chemical spot test
ECN Electrolytic conductivity MAS Molecular absorption spectometry TCD Thermal conductivity detector
detector MD Multi-detector TD Thermal desorption
EGA-TOS Evolved gas analysis with MS Mass spectrometry TEA Thermal energy analyzer
thermal-optical sensor MSD Mass selective detector TEM Transmission electron
ELCHM Electrochemical detector N ACT Neutron activation microscopy
F Flame NCD Nitrogen chemiluminescence TITRA Titration
FAME Fatty acid methyl ester detector TOA Thermal-optical analysis
FD Fluorescence detector NPD Nitrogen-phosphorus detector UV Ultraviolet detector
FID Flame ionization detector NSD Nitrogen-specific detector VAS Visible absorption
FLAG Flame arsine generation NVM No validated method spectrophotometry
FLUOR Fluorescence P FLUOR Portable fluorescence VIS Visual
FPD Flame photometric detector P GC Portable gas chromatography W Wipe
FPDS Flame photometric detector P IR Portable infrared spectro- XRD X-ray diffraction
sulfur specific photometry XRF X-ray fluorescence
GC Gas chromatography P IS Portable infrared XRFS X-ray fluorescence
GF Graphite furnace spectrophotometer spectroscopy

AC Accu-CAP Capsule F/CST Filter in Preloaded SC Solu-CAP


Collecting Equipment BI Bioaerosol Impactor Cassette SCN Screen
BS BioSampler FLT Filter SCRN Stainless Steel Screen
C Capsule FLT/CL Filter Cassette with SH Sampling Head
C/HLD Filter Cassette and Cowl SM TB Smear Tab
Cyclone Holder FOAM Foam SP Support Pads
CAN Canister IMP Impinger SPC Spacer
CF/CST Coated Filter in IOM IOM Particulate SSC Stainless Steel
Preloaded Cassette Sampler Cassette
CH Capsule Holder IS Impaction Substrate ST Sorbent Tube
CI Cascade Impactor IT Impinger Trap STC Spore Trap Cassette
CPC Constant Pressure JAR Jar SV Sorbent Vial
Controller MVC Microvacuum Cassette T Tape
CST Filter Cassette PK Passive Kit TH Tube Holder
CYC Cyclone PPI Parallel Particle Impactor TK Test Kit
DR Direct-reading PS Passive Sampler TMP Template
DRI Direct-reading PT Plastic Tubing VAC Vac-U-Chamber
Instrument PUF PUF Cartridge VT ViaTrap for use with
DRT Drying Tube RR Rate Reducer BioSampler
DT Detector Tube, Color SB Sample Bag W Wipe
EPAM Environmental SBLK Bulk Sorbent
Particulate Monitor

244 SKC Ltd. skcltd.com • SKC South Africa skcsouthafrica.co.za

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