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    Novel Alloys: István Mészáros Bme Att 2019

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    Parijat Mitra
    The document discusses novel alloys, including high entropy alloys (HEAs). It describes how HEAs contain multiple principal elements in equimolar or near-equimolar concentrations, resulting in solid solution phases and high entropy effects. The document presents diagrams showing the relationship between concentration, configuration entropy, and alloy properties for multi-component systems. It also discusses some characteristic properties of HEAs, such as high strength and ductility simultaneously, even at low temperatures.

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    Novel Alloys: István Mészáros Bme Att 2019

    Uploaded by

    Parijat Mitra
    35 views11 pages
    The document discusses novel alloys, including high entropy alloys (HEAs). It describes how HEAs contain multiple principal elements in equimolar or near-equimolar concentrations, resulting in solid solution phases and high entropy effects. The document presents diagrams showing the relationship between concentration, configuration entropy, and alloy properties for multi-component systems. It also discusses some characteristic properties of HEAs, such as high strength and ductility simultaneously, even at low temperatures.

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    12_Novel_alloys

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    The document discusses novel alloys, including high entropy alloys (HEAs). It describes how HEAs contain multiple principal elements in equimolar or near-equimolar concentrations, resulting in solid solution phases and high entropy effects. The document presents diagrams showing the relationship between concentration, configuration entropy, and alloy properties for multi-component systems. It also discusses some characteristic properties of HEAs, such as high strength and ductility simultaneously, even at low temperatures.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    35 views11 pages

    Novel Alloys: István Mészáros Bme Att 2019

    Uploaded by

    Parijat Mitra
    The document discusses novel alloys, including high entropy alloys (HEAs). It describes how HEAs contain multiple principal elements in equimolar or near-equimolar concentrations, resulting in solid solution phases and high entropy effects. The document presents diagrams showing the relationship between concentration, configuration entropy, and alloy properties for multi-component systems. It also discusses some characteristic properties of HEAs, such as high strength and ductility simultaneously, even at low temperatures.

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    © All Rights Reserved
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    Download as pdf or txt
    of 11

    2019. 05. 27.

    Novel alloys

    István Mészáros

    BME ATT
    2019.

    Modern alloys
    Novel steels, HEA, stainless steels

    1
    2019. 05. 27.

    2
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    3
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    4
    2019. 05. 27.

    0 atom % C 25
    1538 A H
    B 1493
    delta
    ferrit I
    folyadék
    1394
    δ N
    0,5
    0,16 D
    1252
    0,1

    ausztenit
    E 1147 C F
    γ
    912 G
    M
    O
    769
    P S 727 K

    ferrit
    a Schematic diagram of heat treatment processing of cold-rolled TRIP steels.

    ledeburit

    cementit
    perlit

    A: austenite, B: bainite, F: ferrite, M: martensite.

    Intercritical annealing, rolling


    Q
    ferrite (50%), bainite (35%), metastable rest austenite (15%) L
    Plastic deformation: austenite ➔ martensite
    ! m ax =030%, 980 MPa
    0,8 2,1 tömeg % C 4,3 6,7
    Fe 0,02 Fe3C
    0 tömeg % Fe3C 100

    High-entropy alloys (HEA)

    10

    5
    2019. 05. 27.

    Configuration entropy in alloy systems

    Multi-component system
    •Configuration entropy or entropy of mixing.
    The change of the system’s entropy due to the mixing
    (arrangement) of component atoms.

    11

    Entropy of mixing, configuration


    entropy
    dQ
    Thermodynamical definition of entropy: dS =
    T
    Statistical meaning of entropy: S = k ln w
    (A+B two component system,
    N: number of lattice points, n: number of „A” atoms)
    Statistical meaning of thermodynamical probability:
    (Number of arrangement possibilities.) N!
    w=
    N! n !( N - n ) !
    Sk = k ln w = k ln
    n !( N - n ) !

    Stirling’s formula ln x ! = x ln x - x ha x > 10

    12

    6
    2019. 05. 27.

    Configuration entropy
    N!
    Sk = k ln w = k ln =
    n !( N - n ) !
    = k ëé N ln N - N - ( n ln - n ) - ( N - n ) ln ( N - n ) + ( N - n ) ûù
    æ N -n N -n n nö
    = -kN ç ln + ln ÷
    è N N N Nø

    Sk = -kN [ cB ln cB + c A ln c A ]

    If: N=Avogadro’s number, kN=R universal gas constant


    (R=8.134 J/(K mol)

    13

    Configuration entropy
    S>0
    6

    50% « Max S
    5

    4
    Slope of the
    3 tangents at C=0
    S

    and C=1 huge.


    2

    0
    0.0 0.2 0.4 0.6 0.8 1.0

    koncentráció

    14

    7
    2019. 05. 27.

    Amorphous alloys (~ 20 – 30 µm): main component 70-90 at.%

    extended solid solution with amorphous structure, ΔHm big

    Bulk metallic glasses (1 –20 mm) : main components 50-70 at.%

    Bulk High entropy alloys: min. 4-5 equimolar components


    extended solid solution with crystalline structure, ΔHm small

    Richards’ rule ln3 = 1.09; ln4 = 1.38; ln5 = 1.6

    Jien-Wei Yeh et al, “Nanostructured high entropy alloys


    with multiple principal elements: novel alloy design concept and outcomes”
    Advanced Engineering Materials (2004) 6 nr 5 pp. 299-303

    B. Cantor, I.T.H. Chang, P. Knight, A.J.B. Vincent


    “Microstructural development in equiatomic multicomponent alloys”
    Materials Science and Engineering A 375–377 (2004) 213–218

    8
    2019. 05. 27.

    Nagy entrópiájú ötvözetek (HEA)

    Több komponens, azonos moláris arányban.


    Szilárd oldat.

    17

    18

    9
    2019. 05. 27.

    Schematic illustration of BCC structure.


    (a) Perfect lattice with the same atoms of Cr;
    (b) serious distorted lattice for CrFeCoNiAlTi
    yield stress, fracture strength and plastic strain of 2.259 GPa, 3.135 GPa
    and 23.33%, respectively.

    Advanced Engineering Materials 2008, 10, No. 6, p534

    10
    2019. 05. 27.

    HEA tulajdonságai

    • Nagy szilárdság és szívósság (egyidejűleg)


    • Nagy szilárdság és szívósság (alacsony
    hőmérsékleten is)
    • Szupravezetés
    • Szuper-paramágneses viselkedés
    • ...

    21

    11

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