Properties Materials 5

1- ELECTRICAL PROPERTIES
1-1 CONDUCTIVITY
This property governs how well the material conducts electricity.
The best material is silver but this is too expensive so for general
use copper is the best compromise. Materials with bad conductivity
may be used as insulators. These are various polymers and
ceramics. The formula for calculating the resistance of a wire is as
follows.
R = A/L where is the resistivity, L the length and A is the cross sectional area
Example
Calculate the electrical conductivity of pure copper at (a) 400C
and (b) -100C.
The resistivity of copper at room temperature is 1.67 * 10-6 ohm cm, and
the temperature.
resistivity coefficient is 0.0043 ohm (ohm C). (See Table 19-3).
(a) At 400C
p = pRT (1 + aRT) = (1.67 x 10-6)[1 +
0.0043(400 - 25)]
p= 4.363 x 10-6 ohm. Cm

s = 1>p = 2.29 x 105 ohm-1 . cm-1
3-1 RELATIVE PERMEABILITY

This is a property that governs the magnetic strength of a material.
The symbol is r. This is a property that is difficult to give as a
constant in tables and you need to understand magnetisation in
depth to follow how to use this property. The main equation that
this property occurs is B/H = o
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Chapter 5
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PROPERTIES OF MATERIALS
NON-MECHANICAL PROPERTIES OF MATERIALS
absolute permeability with a value of 12.566 x 10
4-1 RELATIVE PERMITTIVITY

This is a property that governs the electro-static charge stored on
an electric capacitor. The symbol is r. The main equation that this is
found in is C = orA/d
C is the capacitance in Farads and A the area of the capacitor plates
and d the distance between them. o is the absolute permittivity with
a value of o 8.85 x 10-12
Here is a table of some common figures.
MATERIAL
Free Space
Air
Paper
Glass
Mica
Ceramic
Plastics
1.000
1.006
2 approx
7 approx
4 approx
6 approx.
various
2 -THERMAL PROPERTIES
1-2 MELTING POINT
This is the temperature at which the material melts and it is
denoted Tm (K) or m oC. Here is a table of the melting points of
metals.
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Chapter 5
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o is the
B is the flux density in Tesla, H is the magnetising force and
Elements
Symbol
m oC
Aluminum
Brass (85 Cu15Zn)
Al
Cu+Zn
Cu+Sn
659
900-940
850-1000
C+Si+M+Fe
C
Cr
Cu
Au
H
Ni+Cr+Fe
Fe
Pb
1260
3600
3600
1083
1063
-259
1393
1530
327
Magnesium
Mg
670
Elements
Symbol
Manganese
Monel
Nickel
Phosphorous
Silicon
Silver
Stainless Steel
Steel-High Carbon
Medium Carbon
Low Carbon
Tin
Titanium
Tungsten
Zinc
Mn
Ni+Cu+Si
Ni
P
Si
Ag
Cr+Ni+Mn+C
Cr+Ni+Mn+C
Cr+Ni+Mn+C
Cr+Ni+Mn+C
Sn
Ti
W
Zn
m oC
1260
1301
1452
44
1420
961
1363
1353
1427
1464
232
1795
3000
419
Bronze (90 Cu10 Sn)

Cast Iron
Cast Iron
Chromium
Copper
Gold
Hydrogen
Inconel
Iron
Lead
2-2 LATENT HEAT OF FUSION

This is the energy required to melt 1 kg of material.
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Chapter 5
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This is a property that governs how well a material conducts heat.

The formula for the heat flow rate through a wall of area A is given
by the following formula.
= k A /t
is the heat flow rate in Watts

is the thermal conductivity in W/m K
is the thickness of the wall
is the temperature difference between the two sides of the wall.
4-2 THERMAL EXPANSION

When solids and liquids are heated, the molecules vibrate more and
take up more space so the material expands. Consider first the
expansion in one direction.
If a bar of material of length Lo has its temperature increased by
degrees,
the increase of length is L.
This is directly proportional to the original length L and to the

temperature change . It follows that
L constant x Lo
The constant of proportionality is called the coefficient of linear

expansion
L = Lo
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Chapter 5
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3-2 THERMAL CONDUCTIVITY
1-3 CORROSION RESISTANCE

Corrosion
occurs
through
the
oxidation
of
metals
in
our
environment. Most metals corrode, some more rapidly than others,

depending on that environment. Students are familiar with rust, the
iron oxide corrosion product of steel. The form and amount
of.corrosion that occurs depends on factors such as
Amount of water in the environment
Presence of salt or other chemicals
State of stress of the stee
Presence of other metals in the environment
2-3 OXIDISATION
Corrosion takes many forms and it would require a very
large section to explain it. The following is a brief
summary of the forms of corrosion that occur with
materials.
Oxygen from the environment combines with the
material to form a new substance, usually an oxide film
on the surface. If the oxide film is easily removed to
expose new material, the process will continue until all
the material is oxidised. In the case of most ferrous materials the
oxide film is rust and this lets water through and crumbles away. In
the case of copper and aluminium, the oxide film is durable and
forms a protective coat on the surface. Materials like Gold and
Silver do not oxidise easily but important engineering materials that
resist oxidation are zinc, chromium, cadmium and others.
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Chapter 5
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3- DURABILITY
There are other factors that affect corrosion. The presence of water,
especially if it contains salt, will enable electrolytic action to occur
and greatly accelerate the process. This is greatly accelerated if
there are two different metals present to create an electrolytic cell
and so care must be taken when different metals are used in an
assembly. The compatibility of metals is listed as the Electrode
Potential (in volts) and the further apart two metals are in the
table, the worse the electrolytic action.
TABLE OF ELECTRODE POTENTIAL IN VOLTS
Lithium
Potassium
Sodium
Magnesium
Aluminium
Zinc
Iron
Cobalt
-3.02
-2.92
-2.71
-2.34
-1.66
-0.76
-0.44
-0.29
Gold
Nickel
Tin
Lead
Hydrogen
Copper
Mercury
Silver
+1.68
-0.23
-0.14
-0.12
0.00
+0.34
+0.8
+0.8
Components and structures are often treated or coated to reduce

corrosion. Here is a list of some of the preparatory treatments and
coatings used for metals.
TREATMENT
Pickling
Degreasing
Wire brushing
Shot and vapour blasting
Flame descaling
Abrasive finishing
Polishing
Barrelling
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PROTECTIVE
COATINGS
Galvanising
Sherardising
Calorising
Chromising
Chromating
Phosphating
Metal Spraying
Cladding
Anodising
Electroplating
Plastic Coating
Paint Coating
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3-3 ELECTROLYTIC ACTION BI METAL CORROSION
Metals may be degraded by a variety of

chemicals such as acids and alkali and
these must always be considered.
Polymers do not corrode but may be prone to attack from other
chemicals such as SOLVENTS which dissolves them away.
Ceramics are in the main resistant to most forms of chemicals and
this is why they have been used for containers down the centuries
5-3 POROSITY
We should mention here the importance of porosity. If a material
allows liquid or gas to seep through it then this may cause
problems such as contamination of food stuffs. On the other hand,
porosity is necessary for a material used as a filter.
6-3 DIMENSIONAL STABILITY

We should also mention dimensional stability here. A material
subjected to prolonged heat, cold, pressure and stress may change
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Chapter 5
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4-3 CHEMICAL ATTACK
Plastic bottles containing pressurised fizzy drinks should not change

their shape over its intended shelf life.
EXERCISE
1-Calculate Conductivity of Metals and Alloys at -100C.
2-Miley knew Oxidative stress.
3-What are the forms of corrosion that occurs for materials.
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Chapter 5
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its dimensions and shape (e.g. creep covered in a later tutorial).

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1- ELECTRICAL PROPERTIES

p= 4.363 x 10-6 ohm. Cm

3-1 RELATIVE PERMEABILITY

NON-MECHANICAL PROPERTIES OF MATERIALS

NON-MECHANICAL PROPERTIES OF MATERIALS

absolute permeability with a value of 12.566 x 10

4-1 RELATIVE PERMITTIVITY

Bronze (90 Cu10 Sn)

NON-MECHANICAL PROPERTIES OF MATERIALS

2-2 LATENT HEAT OF FUSION

NON-MECHANICAL PROPERTIES OF MATERIALS

This is a property that governs how well a material conducts heat.

is the heat flow rate in Watts

4-2 THERMAL EXPANSION

the increase of length is L.

This is directly proportional to the original length L and to the

The constant of proportionality is called the coefficient of linear

3-2 THERMAL CONDUCTIVITY

NON-MECHANICAL PROPERTIES OF MATERIALS

1-3 CORROSION RESISTANCE

environment. Most metals corrode, some more rapidly than others,

NON-MECHANICAL PROPERTIES OF MATERIALS

Components and structures are often treated or coated to reduce

3-3 ELECTROLYTIC ACTION BI METAL CORROSION

NON-MECHANICAL PROPERTIES OF MATERIALS

Metals may be degraded by a variety of

6-3 DIMENSIONAL STABILITY

4-3 CHEMICAL ATTACK

NON-MECHANICAL PROPERTIES OF MATERIALS

Plastic bottles containing pressurised fizzy drinks should not change

its dimensions and shape (e.g. creep covered in a later tutorial).

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