Drosera Ms 32: Safety Data Sheet

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SAFETY DATA SHEET


according to Regulation (EC) No. 1907/2006

_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32

Date of the previous version: not applicable

Revision Date: 2013-04-30

Version 2

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING


1.1. Product identifier
Product name
Number
Pure substance/mixture

DROSERA MS 32
312
Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses

Multifunctional oil , machine tools.

1.3. Details of the supplier of the safety data sheet


Supplier

TOTAL UK LIMITED
40 Clarendon Road
Watford. Hertfordshire. WD17 1TQ
UNITED KINGDOM
Tel: +44 (0)1923 427700
Fax: +44 (0)1923 427701

For further information, please contact:


Contact Point
E-mail Address

Specific Product Related Info : 01977 636200


[email protected]

1.4. Emergency telephone number


+33 1 49 00 00 49 (24h/24, 7d/7)
Total UK - 01923 427700
NHS Direct: 0845 46 47 / Textphone: 0845 606 46 47

2. HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
REGULATION (EC) No 1272/2008
For the full text of the H-Statements mentioned in this Section, see Section 2.2.

DIRECTIVE 67/548/EEC or 1999/45/EC


For the full text of the R-phrases mentioned in this Section, see Section 16.

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_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32
Revision Date: 2013-04-30

Version 2

_____________________________________________________________________________________________
The substance/mixture is non-dangerous in accordance with Directive(s) 67/548/EEC with amendments and/or 1999/45/EC with
amendments
Symbol(s)
Not Classified

2.2. Label elements


Labelled according to

Not classified/No labelling required

Hazard pictograms
None

R-phrase(s)
None
S-phrase(s)
None

2.3. Other hazards


Physical-Chemical Properties

Contaminated surfaces will be extremely slippery.

Environmental properties

Should not be released into the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixture
Hazardous components

Do not contain hazardous substance nor substance with european workplace exposure
limits in concentration above regulatory thresholds

Additional information

Product containing mineral oil with less than 3% DMSO extract as measured by IP 346

For the full text of the R-phrases mentioned in this Section, see Section 16.
For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES


4.1. Description of first aid measures
General advice

IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR


EMERGENCY MEDICAL CARE.

Eye contact

Rinse thoroughly with plenty of water, also under the eyelids.

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_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32
Revision Date: 2013-04-30

Version 2

_____________________________________________________________________________________________
Skin contact

Remove contaminated clothing and shoes. Wash skin with soap and water. Wash
contaminated clothing before reuse.
High pressure jets may cause skin damage. In this case, the casualty should be sent
immediately to hospital.

Inhalation

Move to fresh air.

Ingestion

Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a
physician or poison control centre immediately.

4.2. Most important symptoms and effects, both acute and delayed
Eye contact

Not classified.

Skin contact

Not classified. High pressure injection of the products under the skin may have very
serious consequences even though no symptom or injury may be apparent.

Inhalation

Not classified. Inhalation of vapours in high concentration may cause irritation of respiratory
system.

Ingestion

Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhoea.

4.3. Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician

Treat symptomatically.

5. FIRE-FIGHTING MEASURES
5.1. Extinguishing media
Suitable extinguishing media

Carbon dioxide (CO 2). ABC powder. Foam. Water spray or fog.

Unsuitable Extinguishing Media

Do not use a solid water stream as it may scatter and spread fire.

5.2. Special hazards arising from the substance or mixture


Special hazard

Incomplete combustion and thermolysis may produce gases of varying toxicity such as
carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may
be highly dangerous if inhaled in confined spaces or at high concentration.

5.3. Precautions for fire-fighters


Special protective equipment for
fire-fighters

Wear self-contained breathing apparatus and protective suit.

Other information

Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing
water must be disposed of in accordance with local regulations.

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_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32
Revision Date: 2013-04-30

Version 2

_____________________________________________________________________________________________
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
General Information

Do not touch or walk through spilled material. Contaminated surfaces will be extremely
slippery. Use personal protective equipment. Ensure adequate ventilation. Remove all
sources of ignition.

6.2. Environmental precautions


General Information

Do not allow material to contaminate ground water system. Try to prevent the material from
entering drains or water courses. Local authorities should be advised if significant spillages
cannot be contained.

6.3. Methods and materials for containment and cleaning up


Methods for cleaning up

Dam up. Contain spillage, and then collect with non-combustable absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according
to local / national regulations (see section 13). Keep in suitable, closed containers for
disposal.

6.4. Reference to other sections


Personal protective equipment

See Section 8 for more detail.

Waste treatment

See section 13.

7. HANDLING AND STORAGE


7.1. Precautions for safe handling
Advice on safe handling

When using, do not eat, drink or smoke. For personal protection see section 8. Use only in
well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with skin, eyes
and clothing.

Prevention of fire and explosion

Take precautionary measures against static discharges. Ground/bond containers, tanks


and transfer/receiving equipment.

Hygiene measures

Ensure the application of strict rules of hygiene by the personnel exposed to the risk of
contact with the product. Regular cleaning of equipment, work area and clothing is
recommended. Wash hands before breaks and immediately after handling the product. Do
not use abrasives, solvents or fuels. Do not dry hands with rags that have been
contaminated with product. Do not put product contaminated rags into workwear pockets.

7.2. Conditions for safe storage, including any incompatibilities

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_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32
Revision Date: 2013-04-30

Version 2

_____________________________________________________________________________________________
Technical measures/Storage
conditions

Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep
container tightly closed. Preferably keep in the original container. Otherwise, reproduce all
the statutory information from the labels onto the new container. Do not remove the hazard
labels of the containers (even if they are empty). Design the installations in order to avoid
accidental emissions of product (due to seal breakage, for example) onto hot casings or
electrical contacts. Protect from frost, heat and sunlight. Protect from moisture.

Materials to avoid

Strong oxidising agents.

7.3. Specific use(s)


8. EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parametres
Exposure limits

oil mist : 10mg/m3, for 15 minutes


oil mist : 5mg/m3, for 8 hours

Legend

See section 16

8.2. Exposure controls


Occupational Exposure Controls
Engineering measures

Apply technical measures to comply with the occupational exposure limits. When working in
confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for
breathing and wear the recommended equipment.

Personal protective equipment


General Information

If the product is used in mixtures, it is recommended that you contact the appropriate
protective equipment suppliers. These recommendations apply to the product as supplied.

Respiratory protection

When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators. Respirator with combination filter for vapour/particulate (EN
14387). The use of breathing apparatus must comply strictly with the manufacturer's
instructions and the regulations governing their choices and uses.

Eye protection

If splashes are likely to occur, wear:. Safety glasses with side-shields.

Skin and body protection

Wear suitable protective clothing. Protective shoes or boots. Long sleeved clothing.

Hand protection

Hydrocarbon-proof gloves: Nitrile rubber, Fluorinated rubber. Please observe the


instructions regarding permeability and breakthrough time which are provided by the
supplier of the gloves. Also take into consideration the specific local conditions under which
the product is used, such as the danger of cuts, abrasion. If used in solution, or mixed with
other substances, and under conditions which differ from EN 374, contact the supplier of
the EC approved gloves.
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_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32
Revision Date: 2013-04-30

Version 2

_____________________________________________________________________________________________

Environmental exposure controls


General Information

The product should not be allowed to enter drains, water courses or the soil.

9. PHYSICAL AND CHEMICAL PROPERTIES


9.1. Information on basic physical and chemical properties
Clear
yellow
Liquid
No information available

Appearance
Colour
Physical state @20C
Odour
Property
pH
Boiling point/boiling range

Values

Flash point

> 160 C
> 320 F

Evapouration rate
Flammability Limits in Air
Vapour pressure
Vapour density
Density
Water solubility
Solubility in other solvents
logPow
Autoignition Temperature
Viscosity, kinematic
Explosive properties
Oxidising Properties
Possibility of hazardous reactions

873 kg/m3

28.8 - 35.2 mm2/s


Not explosive
not applicable
not applicable

Remarks
not applicable
not applicable

Method

Cleveland Open Cup (COC)


Cleveland Open Cup (COC).
No information available
No information available
No information available
No information available
@ 15 C
not applicable
No information available
No information available
No information available
@ 40 C

ISO 3104

9.2. Other information


Pour point

<= -12 C

ISO 3016

10. STABILITY AND REACTIVITY


10.1. Reactivity
10.2. Chemical stability
Stability

Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions


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_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32
Revision Date: 2013-04-30

Version 2

_____________________________________________________________________________________________
Hazardous reactions

None under normal processing.

10.4. Conditions to Avoid


Conditions to Avoid

Heat (temperatures above flash point), sparks, ignition points, flames, static electricity.

10.5. Incompatible materials


Materials to avoid

Strong oxidising agents.

10.6. Hazardous Decomposition Products


Hazardous Decomposition Products None under normal use.

11. TOXICOLOGICAL INFORMATION


11.1. Information on toxicological effects
Acute toxicity Local effects Product Information

Skin contact

. Not classified. High pressure injection of the products under the skin may have very
serious consequences even though no symptom or injury may be apparent.

Eye contact

. Not classified.

Inhalation

. Not classified. Inhalation of vapours in high concentration may cause irritation of


respiratory system.

Ingestion

. Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and
diarrhoea.

Acute toxicity - Component Information


Sensitisation
Sensitisation

Not classified as a sensitizer.

Specific effects
Carcinogenicity
Mutagenicity
Reproductive toxicity
Repeated Dose Toxicity

This product is not classified carcinogenic.


This product is not classified as mutagenic.
This product does not present any known or suspected reproductive hazards.

Subchronic Toxicity

No information available.

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_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32
Revision Date: 2013-04-30

Version 2

_____________________________________________________________________________________________
Target Organ Effects (STOT)
Target Organ Effects (STOT)

No information available.

Other information
Other adverse effects

Characteristic skin lesions (oil blisters) may develop following prolonged and repeated
exposures (contact with contaminated clothing).

12. ECOLOGICAL INFORMATION


12.1. Toxicity
Not classified.
Acute aquatic toxicity - Product Information
No information available.
Acute aquatic toxicity - Component Information
No information available.
Chr
oni
caquat
i
ct
oxi
ci
t
y Pr
oductI
nf
or
mat
i
on
No information available.
Chronic aquatic toxicity - Component Information
No information available.
Effects on terrestrial organisms
No information available.

12.2. Persistence and Degradability


General Information
No information available.

12.3. Bioaccumulative potential


Product Information

No information available.

logPow
Component Information

No information available
No information available.

Soil

Given its physical and chemical characteristics, the product generally shows low soil
mobility.

12.4. Mobility in soil

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_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32
Revision Date: 2013-04-30

Version 2

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Air

Loss by evaporation is limited.

Water

Insoluble. The product spreads on the surface of the water.

12.5. Results of PBT and vPvB assessment


PBT and vPvB assessment

No information available.

12.6. Other adverse effects


General Information

No information available.

13. DISPOSAL CONSIDERATIONS


13.1. Waste treatment methods
Waste from residues / unused
products

Should not be released into the environment. Dispose of in accordance with the European
Directives on waste and hazardous waste. Dispose of in accordance with local regulations.

Contaminated packaging

Empty containers should be taken to an approved waste handling site for recycling or
disposal.

EWC Waste Disposal No

The following Waste Codes are only suggestions:. 13 01 10, 13 02 05. According to the
European Waste Catalogue, Waste Codes are not product specific, but application specific.
Waste codes should be assigned by the user based on the application for which the product
was used.

14. TRANSPORT INFORMATION


ADR/RID

not regulated

IMDG/IMO

not regulated

ICAO/IATA

not regulated

ADN

not regulated

15. REGULATORY INFORMATION


15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture

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_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32
Revision Date: 2013-04-30

Version 2

_____________________________________________________________________________________________
European Union
International Inventories
EINECS/ELINCS
TSCA
DSL
ENCS
IECSC
KECL
PICCS
AICS
NZIoC
Legend

EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
NZIoC - New Zealand Inventory of Chemicals

Further information
15.2. Chemical Safety Assessment
Chemical Safety Assessment

No information available

15.3. National regulatory information


The United Kingdom

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Ireland

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16. OTHER INFORMATION


Full text of R-phrases referred to under sections 2 and 3
not applicable
Abbreviations, acronyms

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_____________________________________________________________________________________________
SDS # : 31161

DROSERA MS 32
Revision Date: 2013-04-30

Version 2

_____________________________________________________________________________________________
Legend Section 8
+
**
M:

Revision Date:
Revision Note

Sensitiser
Hazard Designation
Mutagen

*
C:
R:

Skin designation
Carcinogen
Toxic to reproduction

2013-04-30
*** Indicates updated section.

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

_____________________________________________________________________________________________
This safety data sheet serves to complete but not to replace the technical product sheets. The information contained
herein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the
user that any use of the product for purposes other than those for which it was designed entails potential risk.The
information given herein in no way dispenses the user from knowing and applying all provisions regulating his
activity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicated
herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It is
the user's responsibility to ensure that he is subject to no other obligations than those mentioned.
End of Safety Data Sheet

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