GM Oil 5w 30 Msds

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SAFETY DATA SHEET


according to Regulation (EC) No. 1907/2006

_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

Date of the previous version: 2010-04-16

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING 1.1. Product identifier


Product name Number Pure substance/mixture MOTOR OIL 5W-30 DEXOS2 QYA Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Motor oil.

1.3. Details of the supplier of the safety data sheet


Supplier TOTAL BELGIUM Handelsstraat, 93, Rue du Commerce B-1040 BRUSSEL - BRUXELLES Belgi - Belgique Tl : +32 (0)22 889 933 Fax : +32 (0)22 883 260

For further information, please contact Contact Point HSE E-mail Address [email protected]

1.4. Emergency telephone number


Official National Emergency Number: Teleserv S.O.S Total Belgium : +32 (0)16 271 261 On duty staff in Ertvelde (Lub): +32 (0)475 66 07 77 Burns Centers: Bruxelles - (NOH) - Brussel : +32 (0)2 264 48 48, Hopital Militaire Reine Astrid - Militair Hospitaal Koningin Astrid Antwerpen - Anvers : +32 (0)3 217 71 11, Algemeen centrum Ziekenhuis Gent - Gand : +32 (0)9 240 34 90 Centre Universitaire UZ Gand-Universitair Ziekenhuis UZ Gent Leuven - Louvain : +32 (0)16 34 87 50 U.Z. Leuven Loverval : +32 (0)71 44 80 00, Hpital Saint Joseph et Sainte Thrse, section I.M.T.R Luik - Lige : +32 (0)4 366 72 94, CHU Lige domaine Universitaire du Sart Tilman Poison center: c/o Hpital Militaire Reine Astrid Militair Hospitaal Koningin Astrid 1 Rue Bruyn - Bruynstraat 1 B-1120 Bruxelles - Brussel +32 (0)70 245 245
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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________ 2. HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture


REGULATION (EC) No 1272/2008 For the full text of the H-Statements mentioned in this Section, see Section 2.2.

DIRECTIVE 67/548/EEC or 1999/45/EC For the full text of the R-phrases mentioned in this Section, see Section 16. The substance/mixture is non-dangerous in accordance with Directive(s) 67/548/EEC with amendments and/or 1999/45/EC with amendments. Symbol(s) Not Classified

2.2. Label elements


Labelled according to: Not classified/No labelling required

R-phrase(s) None S-phrase(s) None Safety data sheet available for professional user on request.

2.3. Other hazards


Physical-Chemical Properties Environmental properties Contaminated surfaces will be extremely slippery. Should not be released into the environment.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name EC-No REACH Registration Number no data available no data available CAS-No Weight % Classification (Dir. 67/548) R53 Xi;R38 Xi;R41 N;R51-53 Xi;R38 N;R51-53 GHS Classification

Styrene hydrocarbon polymer Zinc alkyl dithiophosphate

272-028-3

^ 68649-42-3

<2.5 <0.55

Zinc alkyl dithiophosphate

272-028-3

no data available

68649-42-3

<0.55

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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________
Diphenylamine 204-539-4 no data available 122-39-4 <0.125 T; R23/24/25 R33 N; R50 R53 Acute Tox. 3 (H301) Acute Tox. 3 (H311) Acute Tox. 3 (H331) STOT RE 2 (H373) Aquatic Acute 1 (H400) Aquatic Chronic 1 (H410)

Additional information

Product containing mineral oil with less than 3% DMSO extract as measured by IP 346

For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16.

4. FIRST AID MEASURES 4.1. Description of first aid measures


General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OR EMERGENCY MEDICAL CARE. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contaminated clothing and shoes. Wash skin with soap and water. Wash contaminated clothing before reuse. Move to fresh air. If swallowed, do not induce vomiting - seek medical advice.

Eye contact Skin contact

Inhalation Ingestion

4.2. Most important symptoms and effects, both acute and delayed
Eye contact Skin contact Inhalation Not classified. Not classified. Not classified. Inhalation of vapours in high concentration may cause irritation of respiratory system. Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

Ingestion

4.3. Indication of immediate medical attention and special treatment needed, if necessary
Notes to physician Treat symptomatically.

5. FIRE-FIGHTING MEASURES 5.1. Extinguishing media


Suitable extinguishing media Unsuitable Extinguishing Media Foam. Carbon dioxide (CO2). ABC powder. Water spray. Do not use a solid water stream as it may scatter and spread fire.
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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________ 5.2. Special hazards arising from the substance or mixture


Special hazard Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These may be highly dangerous if inhaled in confined spaces or at high concentration.

5.3. Precautions for fire-fighters


Special protective equipment for fire-fighters Other information Wear self-contained breathing apparatus and protective suit.

Cool containers / tanks with water spray. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures
General Information Do not touch or walk through spilled material. Contaminated surfaces will be extremely slippery.

6.2. Environmental precautions


General Information Do not allow material to contaminate ground water system. Try to prevent the material from entering drains or water courses. Local authorities should be advised if significant spillages cannot be contained.

6.3. Methods and materials for containment and cleaning up


Methods for cleaning up Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labelled containers. Keep in suitable, closed containers for disposal.

6.4. Reference to other sections


Personal protective equipment Waste treatment See Section 8 for more detail See section 13

7. HANDLING AND STORAGE 7.1. Precautions for safe handling


Advice on safe handling When using, do not eat, drink or smoke. Use only in well-ventilated areas. Do not breathe vapours or spray mist. Avoid contact with skin, eyes and clothing. For personal protection see section 8.

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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________
Hygiene measures Ensure the application of strict rules of hygiene by the personnel exposed to the risk of contact with the product. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and at the end of workday. Do not use abrasives, solvents or fuels. Avoid extended and repeated contact with the skin as this may cause skin disorders, which may also be aggravated by minor injuries or by contact with soiled clothing. Avoid prolonged and repeated contact with the skin, especially with used or waste product. Do not dry hands with rags that have been contaminated with product. Do not put product contaminated rags into workwear pockets.

7.2. Conditions for safe storage, including any incompatibilities


Technical measures/Storage conditions Keep away from food, drink and animal feedingstuffs. Keep in a bunded area. Keep container tightly closed. Preferably keep in the original container. Otherwise, reproduce all the statutory information from the labels onto the new container. Do not remove the hazard labels of the containers (even if they are empty). Design the installations in order to avoid accidental emissions of product (due to seal breakage, for example) onto hot casings or electrical contacts. Take precautionary measures against static discharges. Protect from frost, heat and sunlight. Protect from moisture. Oxidizing agents, Acids.

Materials to avoid

7.3. Specific use(s) 8. EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parametres


Exposure limits
Chemical Name Diphenylamine 122-39-4

oil mist : 10mg/m3, for 15 minutes; oil mist : 5mg/m3, for 8 hours
European Union Belgium TWA 10 mg/m3

Legend

See section 16

8.2. Exposure controls


Occupational Exposure Controls Engineering measures Apply technical measures to comply with the occupational exposure limits. When working in confined spaces (tanks, containers, etc.), ensure that there is a supply of air suitable for breathing and wear the recommended equipment.

Personal protective equipment

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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________
General Information These recommendations apply to the product as supplied. If the product is used in mixtures, it is recommended that you contact the appropriate protective equipment suppliers. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Respirator with combination filter for vapour/particulate (EN 141). The use of breathing apparatus must comply strictly with the manufacturer's instructions and the regulations governing their choices and uses. If splashes are likely to occur, wear:. Safety glasses with side-shields. Protective gloves. Protective shoes or boots. Long sleeved clothing. Hydrocarbon-proof gloves. Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves.

Respiratory protection

Eye protection Skin and body protection Hand protection

Environmental exposure controls General Information The product should not be allowed to enter drains, water courses or the soil.

9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties
Colour Physical state @20C Odour Property pH Boiling point/boiling range Flash point Evapouration rate Flammability Limits in Air Vapour pressure Vapour density Density Water solubility Solubility in other solvents logPow Autoignition Temperature Values yellow to amber Liquid characteristic Remarks not applicable No information available Method

> 200 C > 392 F No information available No information available No information available No information available @ 15 C Insoluble Soluble in many common organic solvents No information available

Cleveland Open Cup (COC) Cleveland Open Cup (COC).

850 kg/m3

> 250 C > 482 F

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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________
Viscosity, kinematic 69 mm2/s 11.8 mm2/s Not explosive not applicable not applicable @ 40 C @ 100 C ISO 3104 ISO 3104

Explosive properties Oxidising Properties Possibility of hazardous reactions

9.2. Other information 10. STABILITY AND REACTIVITY 10.1. Reactivity 10.2. Chemical stability
Stability Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions


Hazardous reactions None under normal processing.

10.4. Conditions to Avoid


Conditions to Avoid Heat (temperatures above flash point), sparks, ignition points, flames, static electricity.

10.5. Incompatible materials


Materials to avoid Oxidizing agents, Acids.

10.6. Hazardous Decomposition Products


Hazardous Decomposition Products Incomplete combustion and thermolysis may produce gases of varying toxicity such as carbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot.

11. TOXICOLOGICAL INFORMATION 11.1. Information on toxicological effects


Acute toxicity Local effects, Product Information

Skin contact Eye contact Inhalation

Not classified. Not classified. Not classified. Inhalation of vapours in high concentration may cause irritation of respiratory system.

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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________
Ingestion Not classified. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.

Acute toxicity Component Information


Chemical Name Diphenylamine LD50 Oral = 1165 mg/kg ( Rat ) LD50 Dermal > 2000 mg/kg ( Rabbit ) LC50 Inhalation

Sensitisation Sensitisation Specific effects Carcinogenicity This product is not classified carcinogenic. During use in engines, contamination of oil with low levels of combustion products occurs. Used motor oils have been shown to cause skin cancer in mice following repeated application and continuous exposure. Brief or intermittent skin contact with used motor oil is not expected to have serious effects in humans if the oil is thoroughly removed by washing with soap and water. Not classified as a sensitizer.

Mutagenicity

None known.

Toxicity for reproduction Repeated Dose Toxicity Subchronic Toxicity Target Organ Effects (STOT) Target Organ Effects (STOT) Other information Other adverse effects

This product does not contain any known or suspected reproductive hazards.

No information available.

No information available.

Characteristic skin lesions (oil blisters) may develop following prolonged and repeated exposures (contact with contaminated clothing).

12. ECOLOGICAL INFORMATION 12.1. Toxicity

Acute aquatic toxicity Product Information No information available. Acute aquatic toxicity Component Information
Chemical Name Toxicity to algae Toxicity to daphnia and other aquatic invertebrates. Toxicity to fish Toxicity to microorganisms

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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________
Zinc alkyl dithiophosphate 68649-42-3 EC50 (48h) 1 - 1.5 mg/L Daphnia magna LC50 (96h) 1.0-5.0 mg/L Pimephales promelas (static) LC50 (96h) 10.035.0 mg/L Pimephales promelas (semi-static) LC50 (96h) 1.0-5.0 mg/L Pimephales promelas (static) LC50 (96h) 10.035.0 mg/L Pimephales promelas (semi-static) LC50 (96h) 3.47-4.14 mg/L Pimephales promelas (flowthrough)

Zinc alkyl dithiophosphate 68649-42-3

EC50 (48h) 1 - 1.5 mg/L Daphnia magna

Diphenylamine 122-39-4

EC50 (72h) = 1.5 mg/l Scenedesmus subspicatus

EC50 (48h) 1.69 - 2.46 mg/L Daphnia magna

EC50 = 4.77 mg/L 30 min EC50 = 2.81 mg/L 5 min EC50 = 3.46 mg/L 15 min

Chronic aquatic toxicity Product Information No information available. Chronic aquatic toxicity Component Information No information available.

Effects on terrestrial organisms No information available.

12.2. Persistence and Degradability


General Information No information available

12.3. Bioaccumulative potential


Product Information logPow Component Information No information available No information available
log Pow 3.5

Chemical Name Diphenylamine - 122-39-4

12.4. Mobility in soil


Given its physical and chemical characteristics, the product generally shows low soil mobility. Loss by evaporation is limited. The product is insoluble and floats on water.

Soil

Air Water

12.5. Results of PBT and vPvB assessment


PBT and vPvB assessment No information available.

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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________ 12.6. Other adverse effects 13. DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods
Waste from residues / unused products Dispose of in accordance with the European Directives on waste and hazardous waste. After use, this oil must be sent to a used oil collection location. Incorrect disposal of used oil endangers the environment. Every mixture with foreign substances such as solvents, brakeand cooling liquids is forbidden. Empty containers should be taken to an approved waste handling site for recycling or disposal The following Waste Codes are only suggestions:. 13 02 05. According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Waste codes should be assigned by the user based on the application for which the product was used.

Contaminated packaging

EWC Waste Disposal No Other information

14. TRANSPORT INFORMATION ADR/RID IMDG/IMO ICAO/IATA ADN

not regulated not regulated not regulated not regulated

15. REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture European Union

International Inventories
EINECS/ELINCS TSCA DSL Version EUBE

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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________
ENCS IECSC KECL PICCS AICS NZIoC Legend -

EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances NZIoC - New Zealand Inventory of Chemicals

Further information 15.2. Chemical Safety Assessment


Chemical Safety Assessment No information available

15.3. National regulatory information


Belgium Avoid exceeding occupational exposure limits (see section 8).

16. OTHER INFORMATION


Full text of R-phrases referred to under sections 2 and 3 R53 - May cause long-term adverse effects in the aquatic environment R38 - Irritating to skin R41 - Risk of serious damage to eyes R33 - Danger of cumulative effects R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. Full text of H-Statements referred to under section 2 and 3 H301 - Toxic if swallowed H311 - Toxic in contact with skin H331 - Toxic if inhaled H373 - May cause damage to organs through prolonged or repeated exposure H400 - Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects Abbreviations, acronyms

Legend Section 8 +

Sensitiser

Skin designation

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_____________________________________________________________________________________________ SDS # : 38674

MOTOR OIL 5W-30 DEXOS2


Revision Date: 2011-02-21 Version 2

_____________________________________________________________________________________________
** M: Hazard Designation Mutagen C: R: Carcinogen Toxic to reproduction

2011-02-21 Revision Date: *** Indicates updated section Revision Note This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006

_____________________________________________________________________________________________
This safety data sheet serves to complete but not to replace the technical product sheets. The information contained herein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by the user that any use of the product for purposes other than those for which it was designed entails potential risk.The information given herein in no way dispenses the user from knowing and applying all provisions regulating his activity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicated herein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It is the user's responsibility to ensure that he is subject to no other obligations than those mentioned. End of Safety Data Sheet

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