SAFETY DATA SHEET

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No. 1907/2006.

THINNER 91-83 (AMERCOAT 9 HF THINNER)

Print Date 9/26/2009
Revision date 28-06-09

MSDS UK 01 / EN Version 2

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information
Trade name

THINNER 91-83 (AMERCOAT 9 HF THINNER)

Recommended use

paint thinner

Company

PPG Coatings SPRL/BVBA

Noordersingel 23
B-2040 Borgerhout

Telephone

+32 3 3606470

Telefax

+32 3 3606435

Emergency telephone number

+31 20 4075210

E-mail address

[email protected]

2. HAZARDS IDENTIFICATION
Symbol(s) :
Harmful
Hazardous components :
xylene
R-phrase(s) :
FLAMMABLE.
HARMFUL BY INHALATION AND IN CONTACT WITH SKIN.
IRRITATING TO SKIN.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Components
xylene

EC No.
215-535-7

CAS-No.
1330-20-7

DSD
25th

ethylbenzene

202-849-4

100-41-4

1-methoxy-2-propanol

203-539-1

2-methoxy-1-methylethyl
acetate

203-603-9

Note
Nota C

Classification
R10
Xn; R20/21
Xi; R38

Concentration
>=25.00 - <50.00%

19th

F; R11
Xn; R20

>=10.00 - <25.00%

107-98-2

19th

R10

>=10.00 - <25.00%

108-65-6

19th

R10
Xi; R36

>=10.00 - <20.00%

Producer declares that for R-phrases not mentioned in chapters 3, the entire amount of hazardous substances is below
limits. For components with an occupational threshold limit value see chapter 8.

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SAFETY DATA SHEET

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No. 1907/2006.

THINNER 91-83 (AMERCOAT 9 HF THINNER)

Print Date 9/26/2009
Revision date 28-06-09

MSDS UK 01 / EN Version 2

If multiple components with identical identifiers appear, these have different hazardous properties, e.g. flashpoint.

4. FIRST AID MEASURES

General advice

Eye contact

Skin contact

Inhalation

Ingestion

Burns

When symptoms persist or in all cases of doubt seek medical advice. Never
give anything by mouth to an unconscious person.
Irrigate copiously with clean, fresh water for at least 10 minutes, holding the
eyelids apart. Remove contact lenses. Seek medical advice.
Take off all contaminated clothing immediately. Wash skin thoroughly with
soap and water or use recognized skin cleanser. Do NOT use solvents or
thinners.
Remove to fresh air. Keep patient warm and at rest. If breathing is irregular
or stopped, administer artificial respiration. If unconscious place in recovery
position and seek medical advice.
If accidently swallowed obtain immediate medical attention. Keep at rest. Do
NOT induce vomiting.
If spills on clothing catch fire, wash with plenty of water. Remove loose
clothing. Do not remove clothing that has melted to the skin.Obtain medical
attention.

5. FIRE-FIGHTING MEASURES
Specific hazards during fire
fighting

Special protective equipment

for fire-fighters
Suitable extinguishing media

Extinguishing media which

shall not be used for safety
reasons

As the product contains combustible organic components, fire will produce

dense black smoke containing hazardous products of combustion (see section
10). Exposure to decomposition products may be a hazard to health. Cool
closed containers exposed to fire with water spray. Do not allow run-off from
fire fighting to enter drains or water courses.
In the event of fire, wear self-contained breathing apparatus.
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Keep containers and surroundings cool with water spray.
Do NOT use water jet.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions

Environmental precautions

Methods for cleaning up

Additional advice

Use personal protective equipment. Ventilate the area. Refer to protective

measures listed in sections 7 and 8. Wear respiratory protection. Beware of
vapours accumulating to form explosive concentrations. Vapours can
accumulate in low areas. Remove all sources of ignition.
Try to prevent the material from entering drains or water ways. If the product
contaminates rivers and lakes or drains inform respective authorities.
Clean with detergents. Avoid solvents. Contain and collect spillage with noncombustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to local / national
regulations (see section 13).
Refer to section 15 for specific national regulation.

7. HANDLING AND STORAGE

Handling

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SAFETY DATA SHEET

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No. 1907/2006.

THINNER 91-83 (AMERCOAT 9 HF THINNER)

Print Date 9/26/2009
Revision date 28-06-09

MSDS UK 01 / EN Version 2

Safe handling advice

Advice on protection against

fire and explosion

Avoid exceeding of the given occupational exposure limits (see section 8).
Use only in area provided with appropriate exhaust ventilation. Avoid contact
with skin, eyes and clothing. Smoking, eating and drinking should be
prohibited in the application area. Avoid inhalation of vapour or mist. For
personal protection see section 8.
Prevent the creation of flammable or explosive concentrations of vapour in
air and avoid vapour concentration higher than the occupational exposure
limits. When transferring from one container to another apply earthing
measures and use conductive hose material. No sparking tools should be
used. Operators should wear anti-static footwear and clothing and floors
should be of the conducting type. Isolate from sources of heat, sparks and
open flame. Take necessary action to avoid static electricity discharge (which
might cause ignition of organic vapours). The product should only be used in
areas from which all naked lights and other sources of ignition have been
excluded. No smoking. The accumulation of contaminated rags and dry
overspray, particularly in spray booth filters, may result in spontaneous
combustion. Good housekeeping standards, regular safe removal of waste
materials and regular maintenance of spray booth filters will minimise the
risks of spontaneous combustion and other fire hazards.

Storage
Requirements for storage areas
and containers

Further information

Advice on common storage

Observe label precautions. Prevent unauthorized access. Containers which

are opened must be carefully resealed and kept upright to prevent leakage.
Store between 5 and 30C (41 - 86 F) in a dry, well ventilated place away
from sources of heat, ignition and direct sunlight. Solvent vapours are heavier
than air and may spread along floors. Vapours may form explosive mixtures
with air. Electrical installations / working materials must comply with the
technological safety standards. Keep away from sources of ignition - No
smoking. Store in accordance with the particular national regulations (see
section 15).
This product must be stored in accordance with the Highly Flammable
Liquids and Liquefied Petroleum Gases Regulations 1972.
Keep away from oxidising agents and strongly acid or alkaline materials.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components on the national list and/or the European TLV list (98/24/EC):

Components

CAS-No.

Value
[mg/m3]

3/8

Value
[ppm]

Basis

SAFETY DATA SHEET

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No. 1907/2006.

THINNER 91-83 (AMERCOAT 9 HF THINNER)

Print Date 9/26/2009
Revision date 28-06-09

MSDS UK 01 / EN Version 2

xylene
can be absorbed through skincan be
absorbed through skin

1330-20-7

220
441
221
442

50
100
50
100

EH40 WEL TWA

EH40 WEL STEL
EU ELV TWA
EU ELV STEL

ethylbenzene
can be absorbed through skincan be
absorbed through skin

100-41-4

441
552
442
884

100
125
100
200

EH40 WEL TWA

EH40 WEL STEL
EU ELV TWA
EU ELV STEL

1-methoxy-2-propanol
can be absorbed through skincan be
absorbed through skin

107-98-2

375
560
375
568

100
150
100
150

EH40 WEL TWA

EH40 WEL STEL
EU ELV TWA
EU ELV STEL

2-methoxy-1-methylethyl acetate
can be absorbed through skincan be
absorbed through skin

108-65-6

274
548
275
550

50
100
50
100

EH40 WEL TWA

EH40 WEL STEL
EU ELV TWA
EU ELV STEL

Personal protective equipment

General advice
Respiratory protection

Hand protection

When operators, whether spraying or not, have to work inside the spray
booth, ventilation is unlikly to be sufficient to control particulates and solvent
vapour in all cases. In such circumstances they should wear a compressed airfed respirator during the spraying process and until such time as the
particulates and solvent vapour concentration has fallen below the exposure
limits.
For prolonged or repeated contact use protective gloves.
Barrier creams may help to protect the exposed areas of skin, they should
however not be applied once exposure has occurred.
Skin should be washed after contact.
Use chemical resistant gloves classified under Standard EN 374: Protective
gloves against chemicals and micro-organisms.
Recommended gloves: Viton
Minimum breakthrough time: 480 min
The recommended gloves are based on most common solvent in this product.
When prolonged or frequently repeated contact may occur, a glove with a
protection class of 6 (breakthrough time greater than 480 minutes according
to EN 374) is recommended. When only brief contact is expected, a glove
with a protection class of 2 or higher (breakthrough time greater than 30
minutes according to EN 374) is recommended.
NOTICE: The selection of a specific glove for a particular application and
duration of use in a workplace should also take into account all relevant
workplace factors such as, but not limited to: Other chemicals which may be
handled,physicalrequirements (cut/puncture protection, dexterity, thermal
protection), potential body reactions to glovematerials, as wellas the
instructions/specifications provided by the glove supplier.

Eye protection
Skin and body protection

:
:

Chemical resistant goggles must be worn.

Personnel should wear protective clothing. Skin should be washed after
contact. Working clothes must not consist of textiles, which show a
dangerous melting behaviour in case of fire. Workers should wear antistatic
footwear.

Additional advice

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SAFETY DATA SHEET

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No. 1907/2006.

THINNER 91-83 (AMERCOAT 9 HF THINNER)

Print Date 9/26/2009
Revision date 28-06-09

MSDS UK 01 / EN Version 2

Environmental protection

Refer to national regulations in chapter 15 for regulations on environmental

protection.

Personal protection
Protective equipment

Enclosing glasses, safety gloves and P2A2 half-face combi mask

Please contact your personal protection equipment supplier for further advice

9. PHYSICAL AND CHEMICAL PROPERTIES

Form
Colour
Odour
Flash point

:
:
:
:

viscous

Autoignition temperature
Upper explosion limit

:
:

Lower explosion limit

1.14 %(V)
50.38 g/m3

Density

Water solubility

0.89 g/cm3
at 20 C
practically insoluble

pH
Viscosity, dynamic

:
:

Note: no data available

aromatic mild
26.0 C
Note: Calculated
8.43 %(V)
375.74 g/m3

10. STABILITY AND REACTIVITY

Conditions to avoid

Hazardous reactions

Hazardous decomposition
products

Avoid temperatures above 60C (140 F), direct sunlight and contact with
sources of heat.
Keep away from oxidising agents, strongly alkaline and strongly acid
materials in order to avoid exothermic reactions.
In case of fire hazardous decomposition products may be produced such as:
Carbon dioxide (CO2), carbon monoxide (CO), oxides of nitrogen (NOx),
dense black smoke.

11. TOXICOLOGICAL INFORMATION

Product information

Acute oral toxicity

There is no data available for this product.

The preparation has been assessed following the conventional method of the
Dangerous Preparations Directive 1999/45/EC and classified for
toxicological hazards accordingly. See Sections 3 and 15 for details.
May cause nausea, abdominal spasms and irritation of the mucous
membranes.

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SAFETY DATA SHEET

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No. 1907/2006.

THINNER 91-83 (AMERCOAT 9 HF THINNER)

Print Date 9/26/2009
Revision date 28-06-09

MSDS UK 01 / EN Version 2

Acute inhalation toxicity

Skin irritation

Eye contact
Further information

:
:

Exposure to component solvent vapours concentration in excess of the stated

occupational exposure limit may result in adverse health effects. Such as:
mucous membrane irritation, respiratory system irritation, adverse effects on
kidney, liver and central nervous system. Symptoms and signs: headache,
dizziness, fatigue, muscular weakness, drowsiness and in extreme cases loss
of consciousness.
Repeated or prolonged contact with the preparation may cause removal of
natural fat from the skin resulting in desiccation of the skin. The product may
be absorbed through the skin.
The liquid splashed in the eyes may cause irritation and reversible damage.
There is no data available for this product.

Acute Toxicity Data for Components

12. ECOLOGICAL INFORMATION

:

No data is available on the product itself.The preparation has been assessed

following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is not classified as dangerous for the environment. See
section 3 for details on components.The product should not be allowed to
enter drains, water courses or the soil.

Product

The product should not be allowed to enter drains, water courses or the soil.
Disposal together with normal waste is not allowed. Special disposal required
according to local regulations.

Waste key for the unused

product

The European Waste Catalogue classification of this product, when disposed

of as waste is:

Further information

13. DISPOSAL CONSIDERATIONS

08 01 11 Waste paint and varnish containing organic solvents or other

dangerous substances.

If this product is fully cured or mixed with other wastes, this code may no
longer apply. If mixed with other wastes, the appropriate code should be
assigned. For further information contact your local waste authority

14. TRANSPORT INFORMATION

Transport within user's premises: always transport in closed containers that are upright, labelled and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
Transport to be in accordance with ADR for road, IMDG for sea and IATA for air transport:
UN-Number
: 1263
Proper shipping name
: PAINT RELATED MATERIAL
Class
: 3
Packing group
: III
Label
: 3
Proper shipping name (ADR)
: PAINT RELATED MATERIAL
Marine Pollutant (IMDG)
EmS (IMDG)

:
:

F-E, S-E

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SAFETY DATA SHEET

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No. 1907/2006.

THINNER 91-83 (AMERCOAT 9 HF THINNER)

Print Date 9/26/2009
Revision date 28-06-09

MSDS UK 01 / EN Version 2

Limited quantity (ADR)

Limited quantity (IMDG)

Max. per inner pack. : 5.00 L

Max. per outer pack. : 30.00 KG
Max. per inner pack. : 5.00 L
Max. per outer pack. : 30.00 KG

15. REGULATORY INFORMATION

The product is classified and labelled in accordance with Directive 1999/45/EC.

Harmful
Hazardous components which must be listed on the label:
xylene

R-phrase(s)

R10
R20/21
R38

Flammable.
Harmful by inhalation and in contact with skin.
Irritating to skin.

S-phrase(s)

S23
S36/37
S38

Do not breathe spray.

Wear suitable protective clothing and gloves.
In case of insufficient ventilation, wear suitable
respiratory equipment.

The information contained in this safety data sheet does not constitute the user's own assessment of workplace risks, as
required by other health and safety legislation. The provisions of the national health and safety at work regulations
apply to the use of this product at work.
National legislation
Further information

Highly Flammable Liquids and Liquefied Petroleum Gases Regulations,

1972., HS (G) 178, Spraying of Flammable Liquids, HSE., HS (G) 176,
Storage of Flammable Liquids in Tanks, HSE., HS (G) 51, Storage of
Flammable Liquid in Containers, HSE., HS (G) 37, An introduction to Local
Exhaust Ventilation, HSE., Health and Safety at Work etc Act, 1974, and
relevant Statutory Provisions., Environmental Protection Act, 1990 and
associated legislation., The Special Waste Regulations, 1996 and
amendments., The Chemicals (Hazard Information and Packaging for Supply)
Regulations, 1994 and amendments., EH 40, Occupational Exposure Limits,
HSE. Revised annually., HS(G) 53, Respiratory Protective Equipment - A
Practical Guide for Users, HSE., HS(G) 97, A Step by Step guide to COSHH
Regulations, HSE., EH 173, Monitoring Strategies for Toxic Substances,
HSE.

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SAFETY DATA SHEET

This Safety Data Sheet is prepared in accordance with Annex II to Regulation (EC) No. 1907/2006.

THINNER 91-83 (AMERCOAT 9 HF THINNER)

Print Date 9/26/2009
Revision date 28-06-09

MSDS UK 01 / EN Version 2

16. OTHER INFORMATION

Explanation of R-phrases mentioned in section 3
xylene

R10
R20/21
R38

Flammable.
Harmful by inhalation and in contact with skin.
Irritating to skin.

ethylbenzene

R11
R20

Highly flammable.
Harmful by inhalation.

1-methoxy-2-propanol

R10

Flammable.

2-methoxy-1-methylethyl acetate

R10
R36

Flammable.
Irritating to eyes.

This Safety Data Sheet is based on the Safety Data Sheets obtained from the producer/manufacturer or/and internet
databases and valid regulations considering hazardous substances/preparations.
Training advice:
Persons taking part in a turnover of hazardous products ought to be trained in product handling, safety and hygiene.
Drivers ought to be trained and obtain a certificate in accordance with the requirements of transport regulations (ADR).
Version: 2

Revision date 28.06.2009

The information contained in this safety data sheet is based on the present state of knowledge and current European and
National legislation at the date of issue. The supplier reserves the right to modify data on the safety data sheet without
further notice. Any change in data will normally be followed by the issue of a new safety data sheet. The user should
check the date of issue and if more than 12 months have elapsed, then the data should only be used after checking with
the nearest sales office of the supplier to establish that the data is still valid. As the specific conditions of use of the
product are outside the suppliers control, the supplier is not reponsible for the (negative) consequences of these specific
conditions of use, which are outside of the suppliers control and which are not compliant with the handling, storage and
other instructions in this safety data sheet.
After all component(s) stated on the relevant Technical Data Sheet have been mixed the safety precautions mentioned
on each of the component(s) safety data sheets and labels should be used in assessing the safety precautions of the
mixed product.

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