Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - Italy

SAFETY DATA SHEET

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier Product name Product code SDS no. EC number CAS number Product type Transcal N 403979-IT01 403979 Not available. Not available. Liquid.

1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Heat transfer fluid. For specific application advice see appropriate Technical Data Sheet or consult our company substance/mixture representative. 1.3 Details of the supplier of the safety data sheet Supplier BP Italia S.p.a. Via Anton Cechov, 50/2 20151 Milano Product information: +39 02 334451 E-mail address [email protected]

1.4 Emergency telephone number EMERGENCY Carechem:+44 (0) 1235 239 670 (24 hours) TELEPHONE NUMBER

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture Product definition Mono-constituent substance Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS] Not classified. Classification according to Directive 67/548/EEC [DSD] Not classified. See sections 11 and 12 for more detailed information on health effects and symptoms and environmental hazards. 2.2 Label elements Signal word Hazard statements Precautionary statements Prevention Response Storage Disposal Supplemental label elements

No signal word. No known significant effects or critical hazards. Not applicable. Not applicable. Not applicable. Not applicable. Not applicable.

Special packaging requirements Containers to be fitted Not applicable. with child-resistant fastenings Tactile warning of danger
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Not applicable.
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SECTION 2: Hazards identification

2.3 Other hazards Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII Other hazards which do not result in classification No.

Not available.

Defatting to the skin. Contact with hot product may cause burns.

SECTION 3: Composition/information on ingredients

Substance/mixture Mono-constituent substance Highly refined base oil (IP 346 DMSO extract < 3%). Classification Product/ingredient name Base oil - unspecified Identifiers Varies % 100 67/548/EEC Not classified. Regulation (EC) No. 1272/2008 [CLP] Not classified. Type
[A]

Type [A] Constituent [B] Impurity [C] Stabilising additive Occupational exposure limits, if available, are listed in Section 8.

SECTION 4: First aid measures

4.1 Description of first aid measures Eye contact Cold product - Wash eye thoroughly with copious quantities of water, ensuring eyelids are held open. Obtain medical advice if any pain or redness develops or persists. Hot product - Flood with water to dissipate heat. In the event of any product remaining, do not try to remove it other than by continued irrigation with water. Obtain medical attention immediately. Skin contact Cold Product - Wash contaminated skin with soap and water. Remove contaminated clothing and wash underlying skin as soon as reasonably practicable. Hot Product - Flood skin with cold water to dissipate heat, cover with clean cotton or gauze, obtain medical advice immediately. If inhaled, remove to fresh air. Get medical attention if symptoms appear. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. No action shall be taken involving any personal risk or without suitable training.

Inhalation Ingestion Protection of first-aiders

4.2 Most important symptoms and effects, both acute and delayed See Section 11 for more detailed information on health effects and symptoms. 4.3 Indication of any immediate medical attention and special treatment needed Notes to physician Treatment should in general be symptomatic and directed to relieving any effects.

SECTION 5: Firefighting measures

5.1 Extinguishing media Suitable extinguishing media Unsuitable extinguishing media In case of fire, use foam, dry chemical or carbon dioxide extinguisher or spray. Do not use water jet.

5.2 Special hazards arising from the substance or mixture

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SECTION 5: Firefighting measures

Hazards from the substance or mixture In a fire or if heated, a pressure increase will occur and the container may burst. Oil soaked lagging may spontaneously ignite and should be replaced by fresh lagging as soon as possible. During use heat transfer oils may be thermally degraded leading to the formation of volatile hydrocarbons with flash points considerably lower than the original product. It is therefore essential that the system is not drained while hot unless an inert gas system is used to displace flammable gaseous residues. Adequate ventilation is essential during draining operations as hot oil will fume. The temperature at which spent product is drained is a compromise between the need to have the oil sufficiently hot to facilitate drainage, the need to avoid fuming and the dangers of fire from degraded oil with a low flash point. It is recommended therefore that spent oil is drained at a temperature of less than 100C. During system filling and venting, care should be taken to ensure that hot oil is not pumped through the expansion tank. A failure to prevent this could, under certain conditions, lead to the creation of a flammable atmosphere in the expansion tank. As the expansion tank is being filled it is essential that the gases and vapours formed should be free to vent to an open atmosphere where they can quickly disperse. Product contaminated rags, paper or material used to absorb spillages, represent a fire hazard, and should not be allowed to accumulate. Dispose of safely immediately after use. Combustion products may include the following: carbon oxides (CO, CO2) (carbon monoxide, carbon dioxide)

Hazardous combustion products 5.3 Advice for firefighters Special precautions for fire-fighters Special protective equipment for fire-fighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Clothing for firefighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures For non-emergency No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch personnel or walk through spilt material. Floors may be slippery; use care to avoid falling. Put on appropriate personal protective equipment. For emergency responders If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel". Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up Small spill Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Large spill Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor. 6.4 Reference to other sections See Section 1 for emergency contact information. See Section 5 for firefighting measures. See Section 8 for information on appropriate personal protective equipment. See Section 12 for environmental precautions. See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling Protective measures Put on appropriate personal protective equipment. Advice on general Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Wash thoroughly after handling. Remove contaminated clothing and occupational hygiene protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Italy

SECTION 7: Handling and storage

7.2 Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10). Keep away from heat and direct sunlight. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Store and use only in equipment/containers designed for use with this product. Do not store in unlabelled containers.
Prolonged exposure to elevated temperature

Not suitable

7.3 Specific end use(s) Recommendations

See section 1.2 and Exposure scenarios in annex, if applicable.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters Occupational exposure limits Product/ingredient name Base oil - unspecified ACGIH TLVs Base oil - unspecified Exposure limit values ACGIH (United States). TWA: 5 mg/m 8 hour(s). Form: Mineral oil, mist

ACGIH (United States). TWA: 5 mg/m 8 hour(s). Form: Mineral oil, mist For information and guidance, the ACGIH values are included. For further information on these please consult your supplier. Whilst specific OELs for certain components may be shown in this section, other components may be present in any mist, vapour or dust produced. Therefore, the specific OELs may not be applicable to the product as a whole and are provided for guidance only. Recommended monitoring If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to determine the effectiveness of the ventilation or other procedures control measures and/or the necessity to use respiratory protective equipment. Reference should be made to European Standard EN 689 for methods for the assessment of exposure by inhalation to chemical agents and national guidance documents for methods for the determination of hazardous substances. Derived No Effect Level No DELs available. Predicted No Effect Concentration No PNEC available. 8.2 Exposure controls Appropriate engineering controls

Provide exhaust ventilation or other engineering controls to keep the relevant airborne concentrations below their respective occupational exposure limits. All activities involving chemicals should be assessed for their risks to health, to ensure exposures are adequately controlled. Personal protective equipment should only be considered after other forms of control measures (e.g. engineering controls) have been suitably evaluated. Personal protective equipment should conform to appropriate standards, be suitable for use, be kept in good condition and properly maintained. Your supplier of personal protective equipment should be consulted for advice on selection and appropriate standards. For further information contact your national organisation for standards. The final choice of protective equipment will depend upon a risk assessment. It is important to ensure that all items of personal protective equipment are compatible.

Individual protection measures Hygiene measures Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Ensure that eyewash stations and safety showers are close to the workstation location. Respiratory protection Respiratory protective equipment is not normally required where there is adequate natural or local exhaust ventilation to control exposure. Respiratory protective equipment must be checked to ensure it fits correctly each time it is worn. In case of insufficient ventilation, wear suitable respiratory equipment. Provided an air-filtering/air-purifying respirator is suitable, a filter for particulates can be used. Use filter type P or comparable standard. Air-filtering respirators, also called air-purifying respirators, will not be adequate under conditions of oxygen deficiency (i.e. low oxygen concentration), and would not be considered suitable where airborne concentrations of chemicals with a significant hazard are present. In these cases air-supplied breathing apparatus will be required. A combination filter for particles, organic gases and vapours (boiling point >65C) may be required if mist or fume is present as well as vapour. Use filter type AP or comparable standard.
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Italy

SECTION 8: Exposure controls/personal protection

Approved air-supplied breathing apparatus must be worn where there is a risk of exceeding the exposure limit of carbon monoxide Approved air-supplied breathing apparatus must be worn where there is a risk of exposure to hazardous combustion and thermal decomposition products. Entry into a confined space or poorly ventilated area contaminated with vapour, mist or fume is extremely hazardous without the correct respiratory protective equipment and a safe system of work. The correct choice of respiratory protection depends upon the chemicals being handled, the conditions of work and use, and the condition of the respiratory equipment. Safety procedures should be developed for each intended application. Respiratory protection equipment should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Eye/face protection Cold material: wear safety glasses with side shields. Hot material: to prevent thermal burns wear a helmet, full face visor and heat resistant neck flap / apron. Cold material: Wear chemical resistant gloves. Recommended: nitrile gloves. Hot material: to prevent thermal burns wear heat resistant and impervious gauntlets/gloves. Wear protective gloves if prolonged or repeated contact is likely. The correct choice of protective gloves depends upon the chemicals being handled, the conditions of work and use, and the condition of the gloves (even the best chemically resistant glove will break down after repeated chemical exposures). Most gloves provide only a short time of protection before they must be discarded and replaced. Because specific work environments and material handling practices vary, safety procedures should be developed for each intended application. Gloves should therefore be chosen in consultation with the supplier/manufacturer and with a full assessment of the working conditions. Use of protective clothing is good industrial practice. Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required. Wear impervious and heat resistant coveralls covering the full body and limbs. Cotton or polyester/cotton overalls will only provide protection against light superficial contamination that will not soak through to the skin. Overalls should be laundered on a regular basis. When the risk of skin exposure is high (e.g. when cleaning up spillages or if there is a risk of splashing) then chemical resistant aprons and/or impervious chemical suits and boots will be required. Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels.

Skin protection Hand protection

Skin and body

Thermal hazards

Environmental exposure controls

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties Appearance Physical state Liquid. Colour Clear Odour Not available. Not available. Odour threshold pH Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Vapour pressure Vapour density Relative density
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Not available. Not available. >316C (>600.8F) Open cup: >210C (>410F) [Cleveland.] Not available. Not available. Lower: 0.9% Upper: 7% Not available. Not available. 0.865
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Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II - Italy

SECTION 9: Physical and chemical properties

Solubility(ies) Partition coefficient: noctanol/water Auto-ignition temperature Decomposition temperature Viscosity Explosive properties Oxidising properties 9.2 Other information No additional information. insoluble in water. Not available. Not available. Not available. Kinematic: 30 mm2/s (30 cSt) at 40C Kinematic: 4.5 to 5.7 mm2/s (4.5 to 5.7 cSt) at 100C Not available. Not available.

SECTION 10: Stability and reactivity

10.1 Reactivity No specific test data available for this product. Refer to Conditions to avoid and Incompatible materials for additional information. The product is stable. Under normal conditions of storage and use, hazardous reactions will not occur. Under normal conditions of storage and use, hazardous polymerisation will not occur. Prolonged exposure to elevated temperature No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced.

10.2 Chemical stability 10.3 Possibility of hazardous reactions 10.4 Conditions to avoid 10.5 Incompatible materials 10.6 Hazardous decomposition products

SECTION 11: Toxicological information

11.1 Information on toxicological effects Aspiration hazard Conclusion/Summary Not classified. Based on available data, the classification criteria are not met. Information on the likely Routes of entry anticipated:Dermal, Inhalation. routes of exposure Potential acute health effects Inhalation Vapour inhalation under ambient conditions is not normally a problem due to low vapour pressure. Ingestion No known significant effects or critical hazards. Skin contact Defatting to the skin. May cause skin dryness and irritation. Eye contact No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Inhalation No specific data. Ingestion No specific data. Skin contact Adverse symptoms may include the following: irritation dryness cracking Eye contact No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Inhalation Overexposure to the inhalation of airborne droplets or aerosols may cause irritation of the respiratory tract. Ingestion of large quantities may cause nausea and diarrhoea. Prolonged or repeated contact can defat the skin and lead to irritation and/or dermatitis. Potential risk of transient stinging or redness if accidental eye contact occurs.

Ingestion Skin contact Eye contact Potential chronic health effects General No known significant effects or critical hazards. Carcinogenicity No known significant effects or critical hazards.
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SECTION 11: Toxicological information

Mutagenicity Developmental effects Fertility effects No known significant effects or critical hazards. No known significant effects or critical hazards. No known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity Environmental hazards Not classified as dangerous

12.2 Persistence and degradability Biodegradable 12.3 Bioaccumulative potential This product is not expected to bioaccumulate through food chains in the environment. 12.4 Mobility in soil Soil/water partition coefficient (KOC) Mobility

Not available. Spillages may penetrate the soil causing ground water contamination.

12.5 Results of PBT and vPvB assessment PBT No. vPvB Not available. 12.6 Other adverse effects Other ecological information

Spills may form a film on water surfaces causing physical damage to organisms. Oxygen transfer could also be impaired.

SECTION 13: Disposal considerations

13.1 Waste treatment methods Product Methods of disposal Where possible, arrange for product to be recycled. Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations. Hazardous waste Yes. European waste catalogue (EWC) Waste code 13 03 07* Waste designation mineral-based non-chlorinated insulating and heat transmission oils

However, deviation from the intended use and/or the presence of any potential contaminants may require an alternative waste disposal code to be assigned by the end user. Packaging Methods of disposal Where possible, arrange for product to be recycled. Dispose of via an authorised person/ licensed waste disposal contractor in accordance with local regulations. Waste code 15 01 10* Special precautions European waste catalogue (EWC) packaging containing residues of or contaminated by dangerous substances This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.

SECTION 14: Transport information

ADR/RID 14.1 UN number 14.2 UN proper shipping name 14.3 Transport hazard class(es) Not regulated. ADN/ADNR Not regulated. IMDG Not regulated. IATA Not regulated. -

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SECTION 14: Transport information

14.4 Packing group 14.5 Environmental hazards 14.6 Special precautions for user Additional information No. No. No. No.

Not available.

Not available.

Not available.

Not available.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorisation Substances of very high concern None of the components are listed. Annex XVII - Restrictions Not applicable. on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles Other regulations REACH Status United States inventory (TSCA 8b) Australia inventory (AICS) Canada inventory China inventory (IECSC) Japan inventory (ENCS) Korea inventory (KECI) Philippines inventory (PICCS) National regulations D.Lgs. 152/06 15.2 Chemical Safety Assessment The company, as identified in Section 1, sells this product in the EU in compliance with the current requirements of REACH. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted. All components are listed or exempted.

Not classified. This product contains substances for which Chemical Safety Assessments are still required.

SECTION 16: Other information

Abbreviations and acronyms ADN/ADNR = European Provisions concerning the International Carriage of Dangerous Goods by Inland Waterway ADR = The European Agreement concerning the International Carriage of Dangerous Goods by Road ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor CAS = Chemical Abstracts Service CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008] CSA = Chemical Safety Assessment CSR = Chemical Safety Report DMEL = Derived Minimal Effect Level DNEL = Derived No Effect Level DPD = Dangerous Preparations Directive [1999/45/EC] DSD = Dangerous Substances Directive [67/548/EEC] EINECS = European Inventory of Existing Commercial chemical Substances ES = Exposure Scenario EUH statement = CLP-specific Hazard statement EWC = European Waste Catalogue GHS = Globally Harmonized System of Classification and Labelling of Chemicals
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SECTION 16: Other information

IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) OECD = Organisation for Economic Co-operation and Development PBT = Persistent, Bioaccumulative and Toxic PNEC = Predicted No Effect Concentration RID = The Regulations concerning the International Carriage of Dangerous Goods by Rail RRN = REACH Registration Number SADT = Self-Accelerating Decomposition Temperature SVHC = Substances of Very High Concern STOT-RE = Specific Target Organ Toxicity - Repeated Exposure STOT-SE = Specific Target Organ Toxicity - Single Exposure TWA = Time weighted average UN = United Nations UVCB = Complex hydrocarbon substance VOC = Volatile Organic Compound vPvB = Very Persistent and Very Bioaccumulative Full text of abbreviated H statements Full text of classifications [CLP/GHS] Full text of abbreviated R phrases Full text of classifications [DSD/DPD] History Date of issue/ Date of revision Date of previous issue
Prepared by

Not applicable. Not applicable. Not applicable. Not applicable.

16/09/2011. No previous validation.

Product Stewardship

Indicates information that has changed from previously issued version. Notice to reader All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the accuracy or completeness of the data and information in this data sheet. The data and advice given apply when the product is sold for the stated application or applications. You should not use the product other than for the stated application or applications without seeking advice from BP Group. It is the users obligation to evaluate and use this product safely and to comply with all applicable laws and regulations. The BP Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material, from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. You can contact the BP Group to ensure that this document is the most current available. Alteration of this document is strictly prohibited.

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