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    09 Properties of Solutions

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    Jihee Yoon
    This document contains 10 problems about properties of solutions including: 1) Calculating percentage by volume, mass, and mass/volume of an ethanol solution. 2) Determining molarity, molality, and mole fractions of a glycerol/water solution. 3) Finding the mole fraction of a solute in a 1 M aqueous solution. 4) Calculating grams of water needed to reduce molality of a methanol solution.

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    09 Properties of Solutions

    Uploaded by

    Jihee Yoon
    214 views1 page
    This document contains 10 problems about properties of solutions including: 1) Calculating percentage by volume, mass, and mass/volume of an ethanol solution. 2) Determining molarity, molality, and mole fractions of a glycerol/water solution. 3) Finding the mole fraction of a solute in a 1 M aqueous solution. 4) Calculating grams of water needed to reduce molality of a methanol solution.

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    © © All Rights Reserved

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    This document contains 10 problems about properties of solutions including: 1) Calculating percentage by volume, mass, and mass/volume of an ethanol solution. 2) Determining molarity, molality, and mole fractions of a glycerol/water solution. 3) Finding the mole fraction of a solute in a 1 M aqueous solution. 4) Calculating grams of water needed to reduce molality of a methanol solution.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    214 views1 page

    09 Properties of Solutions

    Uploaded by

    Jihee Yoon
    This document contains 10 problems about properties of solutions including: 1) Calculating percentage by volume, mass, and mass/volume of an ethanol solution. 2) Determining molarity, molality, and mole fractions of a glycerol/water solution. 3) Finding the mole fraction of a solute in a 1 M aqueous solution. 4) Calculating grams of water needed to reduce molality of a methanol solution.

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    © All Rights Reserved
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    of 1

    GENERAL CHEMISTRY WORKSHOP

    PROPERTIES OF SOLUTIONS
    1. An aqueous solution with density 0.988 g/mL at 20.0 C is prepared by dissolving
    12.8 mL CH3CH2CH2OH (d = 0.803 g/mL) in enough water to produce 75.0 mL of
    solution. What is the percent CH3CH2CH2OH expressed as a) percent by volume;
    b) percent by mass; c) percent (mass/volume)?
    2. A solution (d = 1.159 g/mL) is 62.0% glycerol, C3H8O3, and 38.0% H2O, by mass.
    Determine a) the molarity of C3H8O3 (with water as the solvent); b) the molarity of
    H2O (with C3H8O3 as the sovent); c) the molality of H2O in C3H8O3; d) the mole
    fraction of C3H8O3; e) the mole fraction of H2O.
    3. What is the mole fraction of the solute in a 1.000 m aqueous solution?
    4. How many grams of water would you add to 1.0000 kg of 1.38 m CH3OH(aq) to
    reduce the molality to 1.00 m CH3OH?
    5. a) What are the partial and total pressures of a solution obtained by mixing 35.8 g
    benzene, C6H6, and 56.7 g toluene, C7H8, at 25.0 C? b) Determine the composition
    of the vapor above this benzene-toluene solution. At 25.0 C the vapor pressures of
    benzene and toluene are 95.1 mm Hg and 28.4 mm Hg respectively.
    6. Calculate the mole fraction of benzene in a benzene-toluene solution that is in
    equilibrium at 25.0 C with a vapor phase that contains 62.0 mol % C6H6. At 25.0 C
    the vapor pressures of benzene and toluene are 95.1 mm Hg and 28.4 mm Hg
    respectively.
    7.

    A compound is 42.9% C, 2.4% H, 16.7% N, and 38.1% O by mass. Addition of 6.45


    g of this compound to 50.0 mL benzene, C6H6 (d = 0.879 g/mL), lowers the freezing
    point from 5.53 to 1.37 C. What is the molecular formula of this compound?

    8. Coniferin is a glycoside (a derivative of a sugar) found in conifers such as fir trees.


    When a 1.205 g sample of coniferin is subjected to combustion analysis, the products
    are 0.698 g H2O and 2.479 g CO2. In another experiment, a 2.216 g sample of
    coniferin is dissolved in 48.68 g water, and the normal boiling point of this solution is
    found to be 100.068 C. What is the molecular formula of coniferin?
    9. The molar mass of hemoglobin is 6.86 x 104 amu. What mass of hemoglobin must be
    present per 100,0 mL of an aqueous solution to exert an osmotic pressure of 7.25 mm
    Hg at 25.0 C?
    10. Predict the freezing point of an aqueous 0.845 m lead (II) nitrate solution. Explain
    why the experimentally measured value is -2.20 C.

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