Halogen Derivative
Halogen Derivative
Halogen Derivative
FROM
(1) ALCOMOLS
(lucas
reagent zH2)
->
HR +
① LAS LEAGENT .
EET
test 1 3 alwhols
identify
to 23 .
* this reaction is used as a , ,
C >
-
>
-
-
zuz
MECHANISM
C
catalyst
-
R-Oand
R
1)
Zul
-U
>
/Opt
2) Ro
4
.
+
0
-In
RoDoS
>
#
in n ⑦
,
H
10 +
Zn2
3) RO + 40 -U I produced in alwholis
↓
(ii) alsohal
-
turbidity produced
.
Resonance stalulise
immediately
O
3 resonance
& >
-
stabilised .
20 Alcohol
. I 5-10 mis
hours
.
days
>
-
10 alohel .
,
Question
. Which
of
the
following produces turbidity immediately
⑳
.
o
On
4)
cry-al e
-
Ou
# A 04
# a C
(5) C 04
= -
-
Cyclopropylmethyl
Carhocation .
(damag resonances
Na I
NaBe k
R-Br R-On
# R-OH &
+ 120
Eso ?
D
HsOn
I+ 1504 > I2
(NaBr + HSOy HBr)
-
>
- .
* R- ou + HI 43DOuc R-I
gr
. .
oil
:
of products formed ?
UBR
Question 1 >
no ·
I s
⑦
I - 4
Join
-
HBS 2
- products
①Y
&942
>
~ >
⑦
40 A4 I
I
-
(7x n)
in
-
pout
use
?
[Y-Be.
2) ,
or
Bo
HBr- H
Y ①
Orz #
&
I
< #
- -
③ CH-On
,
HI
Enz b 7
an-on access
CH2-I .
M 40
c =
w
>
-
no
-
Su
3 o
_Pour 3
cr-c-on +
Puz
Sp2
Sab-M2-on +
PUS
rearrangement
No
③ DARZEN's PROCESS in
socz
1) R -
Ou ,
R-c + set + 40 +
strahemistry CH3 as
⑫ retention
of
I
⑫
solz
configuration
.
H On
> H ↳
EUS CMs .
2) R- on
ou (inversion)
⑫ ⑤
CH3
E
⑤ ②
Souz
Y on
-
Ens
Cry.
Halogenation of
Albanes
1) .
2) Et addition on .
albenes
strechemistry t
.
albenes
STEREOCHEMISTRY Of - addition Ry on
Br St
( H u Hec CH2
-
~
S
Chy ①I
bromamine
cyclic
↳r
Brz
>
40
Br
Bro
.
Y 4
4
C
- >
j
-
4 H
anti-addition
D
H H
Be
#
Hz
CS
-
C =
,
C
CH3
Br2
>
n - 4
.
Br
>
H
H
Cy H
Br
ANTI ADDITION
CHz ⑫
CH3
① Br
Cha
H B2 H
CH3
J
↳
>
- -
H
H Br
H
Cry Bis H
Br
CH3
CH3 Y
C3
CH3 CHz
# Br ⑤
>
X
br
-
I H Br
us
Br H
>
Y Br
By 4
CAT ( + -) ·
CH3
B ,
4
BR2
TA/M
C = C
/ 420
H us
↓ ⑦
E- Bet
Nut-on-
Bi/wy
Br -
Br.