Halogen Derivative

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HALOGEN DERIVATIVE

PREPARATION # AYL HDES


#

FROM
(1) ALCOMOLS

(lucas
reagent zH2)
->
HR +

① LAS LEAGENT .
EET

test 1 3 alwhols
identify
to 23 .
* this reaction is used as a , ,

(altho allyl halide


44
* R OU R -

C >
-
>
-
-

zuz

MECHANISM
C
catalyst
-

R-Oand
R
1)
Zul
-U

>
/Opt
2) Ro
4
.
+

0
-In
RoDoS
>
#
in n ⑦
,

H
10 +
Zn2
3) RO + 40 -U I produced in alwholis

- medium so it produces turtidity .


is
stability of formed fir Di
rate < .


(ii) alsohal
-
turbidity produced
.
Resonance stalulise

immediately
O

3 resonance
& >
-
stabilised .

20 Alcohol
. I 5-10 mis

hours
.
days
>
-

10 alohel .
,

Question
. Which
of
the
following produces turbidity immediately

.

o
On
4)
cry-al e
-

Ou

# A 04

# a C
(5) C 04
= -
-

Cyclopropylmethyl
Carhocation .

(damag resonances
Na I
NaBe k
R-Br R-On
# R-OH &
+ 120
Eso ?
D
HsOn
I+ 1504 > I2
(NaBr + HSOy HBr)
-

>
- .

* R- ou + HI 43DOuc R-I

gr
. .

oil
:

of products formed ?
UBR
Question 1 >
no ·

I s

I - 4

Join
-

HBS 2
- products
①Y
&942
>
~ >

40 A4 I
I
-

(7x n)

in
-

pout
use
?
[Y-Be.
2) ,
or

Bo
HBr- H

Y ①
Orz #
&

I
< #
- -
③ CH-On
,
HI

Enz b 7

an-on access
CH2-I .

M 40
c =

w
>
-

no
-

② From PUS &


PUS- >
2

Su

3 o
_Pour 3
cr-c-on +
Puz
Sp2
Sab-M2-on +
PUS
rearrangement
No

③ DARZEN's PROCESS in

socz
1) R -

Ou ,
R-c + set + 40 +

strahemistry CH3 as

⑫ retention
of
I

solz
configuration
.

H On
> H ↳

EUS CMs .
2) R- on
ou (inversion)
⑫ ⑤

CH3
E
⑤ ②
Souz
Y on

-
Ens
Cry.

I From Aerocarbon (Renethy

Halogenation of
Albanes
1) .

2) Et addition on .
albenes

strechemistry t
.
albenes
STEREOCHEMISTRY Of - addition Ry on

Br St

( H u Hec CH2
-

~
S

Chy ①I
bromamine
cyclic
↳r
Brz
>
40
Br

Bro
.

Y 4
4
C
- >
j

-
4 H
anti-addition
D
H H

Be

#
Hz
CS
-

C =
,
C
CH3
Br2
>
n - 4
.
Br
>

H
H
Cy H
Br
ANTI ADDITION
CHz ⑫
CH3
① Br
Cha
H B2 H
CH3
J

>
- -

H
H Br
H
Cry Bis H
Br
CH3
CH3 Y
C3
CH3 CHz
# Br ⑤
>
X
br
-

I H Br

us
Br H
>
Y Br
By 4

CAT ( + -) ·

CH3
B ,
4
BR2

TA/M
C = C

/ 420
H us
↓ ⑦
E- Bet
Nut-on-
Bi/wy
Br -
Br.

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