Hydrocarbons 1
Hydrocarbons 1
Hydrocarbons 1
rate
Ques compare the
⑦ ⑦ -
13 R <R M 2004. R G
onn
-
C00N
-
-
-
-
oz No
(move stable
( I)-
2- I) greate
UCEC con.
az-m-won cn
c-con <
-
2)
↓ ⑦ ⑦
⑦
( c rC =
c
=
( H2
-
Redp+
reduction
o
nI
⑧ by using
red p
* R-ON > R 4.-
20 Iz
+ +
nI
①
11
R
R > ( 4
-
* n
-
-
-
0
Red P
* R -
H -
R > R GR
-
nI
·
* R -
-
on -s R -
c37 10 12
+
prone
fromaldehydeatoutin
⑨
8 -
R-
x -
pi
quins,e > R cz R
- -
L-INNERRENT
A
②
7 0 >
)(y N4
=
+
(ii)
kon/p
③ MOINGO REGION
-=0
/
(03/ko);you
⑩
from
Gard reagent:
⑤
RMGB
↓
onganometallic
pound)
CHC MGB CCE ->
R
cc+10 (yy 1.
-
-
prsionprpretes
#
(rowa mdar man
senfar
ener
of
molecule.
n-hescome
↳
n-pentance
n-butane
>
of branching marchains
so
↓in case
⑥ ~ -
I
7 > X
*
n-
CHEMICAL PROPERTIES i -
1) OXIDATION (HALYTIC)
red notbe lute
2
CH+O2 cPtutes
3 cou
O
MOLOz 1
(n 02
+
[CsCOOK
Mn, CM-CEU2>n-100N.
Ch () M
+ -
high I
② PHOTOMALOGENATION:
(free
bra
radical methanisms
R-
4 +
X2 A
>R-X 4X.
+
X F,G,Br, I.
=
Momism
&n
chain initiation X -
X 2x
&2
17
propagation chon X0
+
-> 24 +
X
-
(
d
X8-X
+
- ( -
x x0
+
termination
i)
x+ x0
+
- >
y2
20 +
x cz
+
x
-
(0 10 Cz+ -
-
CH3.
uncontrollable reaction
highly exothermia &
FRNATION:
*
best
NOTthe
possible way
to
prepare allye flourides.
* RINATION Imon reative & les selective
Ch
ae
>ayk
-
-
muz a)
monochlorinated
product.
yeeofry?
X
Calculate
->i:1:3:: 1:3.8: 5.
1) Roactivityratio
3y
27 no
of in, sn, ->
= 20
20
10
a
?
③,
#
↑
& ·
I see
Eg
ydrogen
20
⑨
it=1. -
-
selective
#Bomination...
less reactive
a more
free
radical
*
major product formationis by stale
-
BVz +NBr
>
hp
product.B
BC
v
fz ⑬
CC-I -
weakbond isiodination
④ iodination
is reversible.
72 M
L
(
y( 3
yI o
-
> -
HI
+
removal.
h
- >
<
↓somone MIon
of
reaction withOA
agent.
HNOZ
->
.
-
③ iserisation
yo-cell
O BC cr.
④
pyrolysis or
cracking lower albone.
higher albanes -> -
n-heptanc "! ·
Fltoutine
I
n-octane
o-lens
AKENES: -
method propation:
of loss of Mos
of
alcohols
from alcohols?(dehydration
**
-
1)
dB 1 1 20
20
- +
-
- =
I by -
I
⑨
dehydration
- >
by Alcos (no
formation)
eyer-on hop, in the
V.)
CHz-21-04 concyson 10 =
ch2 (85004y00,
>Mk
(C-intermediate possibilityof rearrangement
manism
pansion
i) az
-
z cy
-
- -
00
0 04
⑥
·2
-
Mz
-
M -
Go- -az
-
aut
④
E
3-ch e
RDS.
y( m( (<
-
B
- - -
=
6xH
·ov az u M3.
-
-
L
-
stable
priet
my more
SAYTIEF -
*
⑦
↳c cza M2. 12 2 M
- C
-
=
- -
224.
GOFFMANN
- I
las
formation of
is RAS so
stability
of formed.
it
First
decides the rate
of dehydration.
Rodon ↓
> 104.
mon
stable
~
10.
aide?
②
fromalty
a) by dehydro halogenation
al kon/A.
R X R -CH cz nX.
cy - >
=
- - -
t 'vz2 NONG.
Mechanism R M a
BC-H.-X.
- =
-
- >
base alo
kon, Nannz.
strong
A
EMSWat/Hon
formation other bases.
④
↓ noc
v v all Kon
BC C C-Ab. HC
C-C-c) Hoffman
=
k - -
->
C
(C-c uts.saytze
·