Priliminary Tests : 1, Colour White Cu', Fe' & Mn' cations may be absent. 2. State Crystall1ne EXPERIMENT OBSERVATION INFERENCE 3. Flame test : Clean the platinumwire by dipping in Colour tlameis not observed CaSr.Ba .CuZn con.HCland heat it on flame upto no olour appears. Now, prepare the paste (or) MnPb of con.HCl+ sali in watch glass, then are absent. introduce this paste by platinum wire loop into the tlame. 4, Action of heat : Asmall quantity of salt is taken in Charateristics smell of vinegar. May be Acetate R adry test tube and strongly heated. (CH CO0 ) ion is presert. Coat 58 : ldentification of Anion
1. Action of dil.HCI : Asmall quantity of saltis taken ina ColourlesS vapours with smellof May be Acetate dry test tube and dil.HCI isadded. inegaris evolved and which turns blue (CHCO0) ion is litmus to red. present.
Confirmation tests for Acetate ion
|1.Action of Neutral FeCl,
Solution: To the small quantity of salt Deep Red filtrate is formed. Acetate(CH,CO0) is taken in atest tube and neutral On boiling above solution with water it ion is contimed. FeCl, solution is added. becomes brownish red ppt.
2. Esterification test : To the salt solution Conc.H,SO Fruity odour is obtained. Acetate (CH,CO0-) and CH,OH are added and heated. ion is confimed. It is poured into water.
CHEMISTRY PRACTICAL MANUAL 33 ANALYSIS OF SIMPLE SALT
ldentification of Cation
EXPERIMENT OBSERVATION NFERENCE Test for Ammoniumn (NH, )ion : smellof ammonia Tothe small quantity of salt is taken in colour gas with pungent Ammonium less(NH,)is evolvedand givescation maybe pre(NH a dry testtube a few dropsof Na0H (NH,C)with solution is added and heated strongly. dense white fumes dipped in Conc.HCI glass rod when Note: 1fAmmoniumi cationisidentificdthen wVrite following table. Do confirmation test of Ammonjium Cator,
Name of the dnos Group Reagents ldentification Tests of cations ) Name of the Precipitate Cation
Salt solution + dil. HCI White ppt. PbCI, is not formed. Lead (Ph) absent
SCORER I Salt solution +dil. HCI+H,S gas Black ppt. CuS is not formed. Copper (Cu) abser: Salt solution +NH Cl salt + White gelatino us ppt.AI/OH), 0s not formed. Aluminium (At') abce NH,OH solution Dirty Green ppt. Fe(OH), is not formed. Ferrous (Fe**) absert 9440122758Cont : Salt solution + NH,Cl salt + White ppt. ZnS is not formed. Zinc (Zn) absent Flesh colour ppt.MnSis not formed. Manganese (Mn) abse: NH,OH solution +H_S gas Black ppt. Nis is not formed. Nickel (N)) absent Salt solution + NH,Cl salt + White ppt. CaC0, is not formed. Calcium (Ca) absent NH,OH solution + White ppt. BaCO, is not formed. solution (NH),CO, Barium (Ba) absent White ppt. SrCo, is not formed. Strontium (Sr) absen: V No group reagents Magnesium (Mg) absent
Confirmation Test for Ammonium
Action of Nessler's reagent : Tothe salt solution reagent ( K,Hgl, ] is added.Nessler's Reddish( Brown colour ppt. is formed. lodide ofMillion's base ) Ammonium (\H cation is confimed
Report : The given Cation is The given Anion is Ammonium (NH") The given salt is Acetate (CHCO0 ) CHEMISTRY PRACTICAL MANUAL Ammoni 34 um Acetate NH, (CH COO) ANALYSIS OF
