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Prof Santosh Yadav’s

ACE CHEMISTRY PRIVATE TUITIONS
MCQ Test –47 XI + XIIth ORGANIC CHEMISTRY
Time: 60 min STD: XI + XII
Marks: 180 Negative Marking Date: 15/09/2024
SECTION – A
ALL THE QUESTIONS ARE COMPULSORY. 55] Which alkene is most stable?
51] Which one of the following is NOT formed when 1) (H3C)2C = C(CH3)2
a mixture of methyl bromide and bromobenzene 2) (H3C)2C = CHCH3
is heated with sodium metal in the presence of 3) H3CCH = CHCH3
dry ether? 4) (H3C)2C = CH2
1) Ethane 2) Diphenyl
3) Propane 4) Toluene 56] Which of the following has halogen atom
attached to a sp3 hybridized carbon?
52] The IUPAC name of,
1) Chloroacetylene
CH3 2) 1-iodo-4-methylbenzene
3) 1-chloro-3-phenylpropene
H5C2 CH CH C 2 H5
4) 3-bromopropene
CHO
is, 57] Iodoform test is not given by
1) 2-Ethyl-3-methylpentanal 1) 2-Pentanone 2) Ethanol
2) 4-Methylhexanal 3) Ethanal 4) 3-Pentanone
3) 4-Methyl-3-hexanal
58] The IUPAC name of the compound
4) 2, 3-Diethylbutanal
O
O
53] Match the columns H C
Column – I Column - II
(Elements) (Colour of precipitate
formed in Lassaigne's test)
1) 1, 5-Formylhex-2-en-3-one
A) Nitrogen (p) Yellow
2) 5-methyl-4-oxohex-2-en-5-al
B) Sulphur (q) Prussian blue
3) 3-keto-2-methylhex-5-enal
C) Chlorine (r) Violet
4) 3-keto-2-methylhex-4-enal
D) Phosphorus (s) White
1) A – (q), B – (r), C – (p), D – (s) 59] In the formation of Ph – CHO, following
2) A – (r), B – (q), C – (p), D – (s) reactions are used. Match them
3) A – (q), B – (r), C – (s), D – (p) CORRECTLY.
4) A – (r), B – (q), C – (s), D – (p) Reaction Reagent
[A] Rosenmund (i) CO + HCl
54] Which of the following alkenes will give same [B] Gattermann-Koch (ii) CrO2Cl2
product by any method out of hydration, [C] Etard (iii) SnCl2/HCl
hydroboration-oxidation? [D] Stephen (iv)Pd/BaSO4
1) CH3CH = CH2 2) CH3CH = CHCH3 1) [A]-(iv), [B]-(iii), [C]-(iii), [D]-(i)
CH3CHCH = CH2 2) [A]-(iv), [B]-(i). [C]-(ii),[D]-(iii)
3) CH2 3) [A]-(iv). [B]-(ii). [C]-(iii),[D]-(i)
CH3 4) 4) [A]-(iv), [B]-(iii), [C]-(i),[D]-(ii)
Ace Chemistry Private Tuitions Prof. Santosh Yadav
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60] The IUPAC name for 65] Cl in chlorobenzene iso-/p-directing but
Cl deactivating group. This is because
NO2 1) –I effect of Cl dominates
2) +I effect of Cl dominates
3) +R effect of Cl dominates
4) –R effect of Cl dominates

CH3 66] Aldol condensation would not occur in :

1) 1-Chloro-2-nitro-4-methyl benzene 1) CH3COCH3 2) CH3CH2CHO
2) 1-Chloro-4-methyl-2-nitrobenzene 3) HCHO 4) CH3CHO
3) 2-Chloro-1-nitro-5-methyl benzene
4) m-Nitro-p-chlorotoluene 67] Mixture of Benzyl alcohol and potassium
benzoate is formed by heating
61] The CORRECT order of decrease acidity in the 1) benzoic acid with KOH
following in the following organic compounds is 2) butyric and with K2CO3
1) CCl3COOH > CHCl2COOH > CH2ClCOOH 3) benzaldehyde with caustic potash
> CH3COOH 4) benzaldehyde with hydrazine
2) CCl3COOH < CHCl2COOH < CH2ClCOOH
< CH3COOH 68] 10, 20 and30 alcohols can be chemically
3) CH2ClCOOH < CH3COOH > CHCl2COOH distinguished using which reagent?
> CCl3COOH 1) PCl5 2) Cu
4) CH3COOH < CH2ClCOOH > CHCl2COOH 3) CH3Cl 4) SOCl2
> CCl3COOH
69] Reaction between (CH3)2Cd and
62] Schiff’s base is formed from aldehyde and
C6H5COCl leads to the formation of
1) Ammonia 2) Primary amine
1) Benzophenone 2) Acetophenone
3) HCN 4) Zn+Hg and dil. HCl
3) Acetone 4) Benzaldehyde
63] Which of the following compounds has wrong
IUPAC name? 70] Which of the following reagents can be used to
1) CH3–CH2–CH2–COO–CH2CH3 ⎯⎯ → Prepare salicylaldehyde from phenol?
ethyl butanoate 1) CCl4 +NaOH+H3O+
2) CO2+NaOH at 410 K
2) 3) CHCl3+NaOH+H3O+
4) Heat with CaO +NaOH
3) 71] Freon (dichlorodifluoro methane) is used
1) as local anaesthetic
2) for dissolving impurities in metallurgical
4) process
3) in refrigerator
4) in printing industry
64] Isopropyl isocyanide can be obtained
By the reaction between 72] p-nitrophenol is more soluble in water than
1) CH3CH2CH2I and AgCN o- nitrophenol because
2) CH3CHBrCH3 and KCN 1) It show intramolecular H-bonding
3) (CH3)2CHI and AgCN 2) It shows intermolecular H-bonding with water
4) (CH3)2CHCl and HCN 3) It shows intermolecular H-bonding with itself
4) It is more polar
Ace Chemistry Private Tuitions Prof. Santosh Yadav
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73] Match the columns 77] Simple distillation can be used to separate
Column - I Column - II 1) A mixture of benzene (boiling point 80oC)
A) C H ⎯⎯⎯⎯⎯Cl2 /UVlight
→ p) Finkelstein and toluene (boiling point 110oC)
2 6
reaction 2) A mixture of ether (boiling point 35oC)
C2 H5Cl and toluene (boiling point 110oC)
B) C6 H5 NH 2 q) Free radical 3) A mixture of ethanol (boiling point 78oC)
NaNO2 + HCl /Cu 2Cl2
⎯⎯⎯⎯⎯⎯⎯→
substitution and water (boiling point 100oC)
273−278K 4) Mixture of solid & liquid
C6 H5Cl
C) CH Cl + NaI ⎯⎯→ r) Swarts reaction 78] In the free radical chlorination of methane,
3
the chain initiating step involves the formation of
CH3I + NaCl
1) chlorine free radical
D) CH − Br + AgF ⎯⎯
3 → s) Sandmeyer’s 2) hydrogen chloride
reaction
CH3F + AgBr 3) methyl radical
4) chloromethyl radical.
1) A – (q), B – (s), C – (p), D – (r)
2) A – (q), B – (r), C – (p), D – (s) 79] Which of the following is an optically active
3) A – (r), B – (p), C – (s), D – (q) compound?
4) A – (s), B – (r), C – (p), D – (q) 1) 1-Butanol 2) 1-Propanol
3) 2-Chlorobutane 4) 4-Hydroxyheptane
74] In the reaction,
80] If formaldehyde and KOH are heated, then we
(i) NaNH2/liq. NH3 (i) NaNH2/liq. NH3
H C CH X Y get
(iii) CH3CH2Br (ii) CH3CH2Br
1) methane 2) methyl alcohol
X and Y are 3) ethyl formate 4) acetylene
1) X = 2- butyne, Y = 2-hexyne
2) X = 1- butyne, Y = 2-hexyne
3) X = 1- butyne, Y = 3-hexyne
4) X = 2- butyne, Y = 3-hexyne
81]
The Compound B is
75] In the following sequence of reaction NO2
CH3CH2CH2CH2I NO2
alc KOH HBr (aq.) KOH 1) 2) Br
'A' 'B' 'C'
boil

‘C’ is? Br
1) Butan-2-ol 2) Butan-1-ol NO2
3) Butyne 4) Butene NO2

76] Which of the following is the example of Friedal 3) 4)

Craft reaction? Br
1) C6H6 + CH3CH2Cl ⎯⎯⎯ AlCl3
→ C6H5C2H5 + HCl Br Br
2) C6H5OH+CH3CH2Cl ⎯⎯⎯ AlCl3
→ C6H5C2H5 + 82] Phenylmethyl ketone can be converted into
HOCl ethylbenzene in one step by which of the
 3
3) C6H5 Cl + CH3CH2Cl ⎯⎯⎯ → C6H5C2H5 +
AlCl
following reagents?
Cl2 1) LiAlH4 2) Zn-Hg/HCl
 3 3) NaBH4 4) CH3MgI
4) C6H5CH3+CH3CH2Cl ⎯⎯⎯ → C6H5C2H5 +
AlCl

CH3Cl
Ace Chemistry Private Tuitions Prof. Santosh Yadav
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83] In the given reaction
1) 2)

3) 4)

OH O
87] What are A, B, C, in the following series of
reaction?
1) 2) CH3 − CHCl2 ⎯⎯⎯
aq.
→ A ⎯⎯⎯⎯
dil.Na 2 CO3 
→ B ⎯⎯ →C
KOH

1) CH3 - CHO, CH3 - CH3, CH3 - COOH

OH 2) CH3 – CHO, CH3 – CHOH – CH2 – CHO,
O
CH3 – CH = CH – CHO
O 3) CH3 - CH2 - OH, CH3 - CHO, CH3 - COOH
4) CH3CHO - CH3CH2OH, CH2 = CH2
CHO
3) 4) 88] Most stable Carbanion is :-

CH 2 CH 2
CH2
1) 2)

84] In the given reactions

Cl NO 2
CH 2

3) 4) CH 2

OCH 3
89] Find the product of the given reaction?
CH3
A, B, C and D are respectively
CH3 H+
1) HBr, Br2, CH3COCH3, CH3CHO 
2) Br2, HBr, CH3COCH3, CH3CHO OH
3) HBr, HBr, CH3COCH3, CH3CHO
4) Br2, HBr, CH3CH2CHO, CH3CHO CH3
1) CH3 2)
CH3 CH3
85] One mole of a symmetrical alkene on ozonolysis
gives two moles of an aldehyde having a CH3 CH3
molecular mass of 44 u. The alkene is 3) 4)
1) propene 2) 1-butene CH3 CH3
3) 2-butene 4) ethene
SECTION – B 90] In Carius tube, the compound ClCH2COOH
ANY 10 MCQS SHOULD BE ATTEMPTED OUT was heated with fuming HNO3 and AgNO3.
OF 15 MCQ’S After filtration and washing, a white ppt.
86] The product B in the above reaction sequence is was formed. The ppt. is
1) AgCl 2) AgNO3
3) Ag2SO4 4) ClCH2COOAg

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91] Aryl halides are extremely less reactive towards 2) If both assertion and reason are true but
nucleophilic substitution than alkylhalides. reason is not the correct explanation of the
Which of the following accounts for this? assertion
3) If assertion is false but reason is true
(i) Due to resonance in aryl halides.
4) If the assertion and reason both are false
(ii) In alkyl halides carbon atom in C–X bond is
sp2 hybridised whereas in aryl halides carbon 95] The major products formed by heating with
atom in C–X bond is sp³ hybridized. HI is
(iii) Due to stability of phenyl cation.
(iv) Due to possible repulsion there are less
chances of nucleophile to approach electron
rich arenes.
1) (i), (ii) and (iv) 2) (i), (ii) and (iii)
3) (i) and (iv) 4) (ii), (iii) and (iv)
1)
92] The correct order of acid strength of the
following compounds:
(A) Phenol (B) p-Cresol 2)
(C) m-Nitrophenol (D) p-Nitrophenol
1) D > C > A > B 2) B > D > A > C 3)
3) A > B > D > C 4) C > B > A > D

93] Which of the following are benzylic alcohols? 4)

96] The descending order of stability of the

carbonium ions
+ +
C6 H 5 C H 2 , p − (CH 3O)C6 H 4 C H 2 ,
(I) (II)
+ +
p − (NO 2 )C6 H 4 C H 2 and p − (CH3 )C6 H 4 C H3
(III) (IV)

1) IV > II > I > III 2) II > IV > III > I

3) II > IV > I > III 4) IV > II > III > I
1) (i) and (ii) 2) (ii) and (iii)
97] Product of the following reaction is
3) (i), (ii) and (iv) 4) (i) and (iv)

94] Read the assertion and reason carefully to

mark the CORRECT option out of the options
given below:
Assertion: Acid catalysed dehydration of
t-butanol is slower than n-butanol
Reason: Dehydration involves formation of the 1) 2)
ROH +2 protonated alcohol,
1) If both assertion and reason are true and the
reason is the correct explanation of the
assertion 3) 4)

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98] Cycloheptatrienyl cation is ______. 2) If both assertion and reason are true but
1) Aromatic 2) Non-aromatic reason is not the correct explanation of the
3) Non-planar 4) Aliphatic assertion
3) If assertion is false but reason is true
99] Which of the following free radicals 4) If the assertion and reason both are false
will be most stable considering
hyperconjugation?

CH3
CH3
CH3
H3C CH CH
H3C
I II

CH3 CH3
CH3
H3C CH CH3 CH CH3
H3C
III IV

1) I 2) II
3) III 4) IV

100]Read the assertion and reason carefully to

mark the CORRECT option out of the options
given below:
CH3
Assertion: is less reactive than
Cl
Cl
towards SN1 reactions

Reason: Tertiary alkyl halides react

predominantly by SN1 mechanism
1) If both assertion and reason are true and the
reason is the correct explanation of the
assertion

TYPES OF MISTAKES
1. Factual Mistake No of Q Standard fact given in NCERT Textbook in Q. No
Sentences, Table, Graphs.
2. Analysis Mistake Not a standard fact, but analysis of the concept
(Conceptual Mistake)
3. Marking Mistake Marked wrongly in Answer copy. Correct on
Question paper.
4. Reading Mistake Question wrongly read or read in hurry,
important key word missed.
5. Time deficient Mistake No time available to read the question.
6. Formula Mistake Formula forgotten
7. Numerical approach Formula known. Not able to use it properly.
8. Calculation Mistake –
Ace Chemistry Private Tuitions Prof. Santosh Yadav