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YAKEEN-2.0
Test-02 (Chemistry) 24-10-2021

46. The IUPAC name of the compound 50. The IUPAC name of the compound
CH3 CH3
HO
CH3
CH3CH2CH2CH CH CH2CH3

C CH2CH3 is is
CH

CH3 CH3 CH2CH3

(A) 1, 1- dimethyl -3- hydroxy cyclohexane
(A) 3, 3 – diethyl – 4 – methyl – 5 – isopropyl (B) 3, 3-dimethyl-1-hydroxy cyclohexane
octane (C) 3, 3-dimethyl cyclohexanol
(B) 3, 3 – diethyl – 5 – isopropyl – 4 – methyl (D) 1, 1- dimethyl-3-cyclohexanol
octane
(C) 4 – isopropyl – 5 – methyl – 6, 6 – diethyl 51. Which of the following compounds represents
octane 2, 2, 3- trimethylhexane?
(D) 6, 6 – diethyl – 4 – isopropyl – 5 – methyl (A) CH3C(CH3)2CH2CH2CH(CH3)2
octane (B) CH3C(CH3)2CH2CH(CH3)CH2CH3
(C) CH3C(CH3)2CH(CH3)CH2CH2CH3
47. The IUPAC name of the compound (D) CH3C(CH3)2CH2C (CH3)2CH3
CH3CH = CH–CH = CH–C  CCH3 is
(A) 4, 6 – octadien – 2 – yne 52. The IUPAC name of the compound
(B) 2, 4 – octadien – 6 – yne O OH
(C) 2 – octyn – 4, 6 – diene
(D) 6 – octyn – 2, 4 – diene CH3 C CH2 C O is
(A) 1-hydroxy butan-1, 2-dione
48. The correct IUPAC name of the compound (B) 4-hydroxy butan-2, 4-dione
O CH3 (C) 3-oxo butanoic acid
(D) 1- hydroxy-1, 3-dioxo butane
CH3 CH C CH2 CH is :

CH2 CH3 53. The IUPAC name of the compound

(CH3)2C CH2COCH3 is
CH3
CN
(A) 2, 5 – dimethyl heptan – 4 – one
(B) 3, 6 – dimethyl heptan – 4 – one (A) 4 – cyano – 4 – methyl – 2 – oxo pentane
(C) 2 – ethyl – 5 – methyl hexan – 3 – one (B) 2 – cyano – 2 – methyl – 4 – oxo pentane
(D) 1, 1 – dimethyl – 4 – ethyl pentan – 3 – (C) 2, 2 – dimethyl – 4 – oxo pentanenitrile
one (D) 4 – cyano – 4 – methyl – 2 – pentanone

49. The IUPAC name of 54. The IUPAC name of

CH3 CH CH2 C(CH3)2 is (C2H5)2 NCH2CH COOH is

OH OH
(A) 1, 1 – dimethyl – 1, 3 – butanendiol Cl
(B) 2 – methyl – 2, 4 – pentane diol (A) 2-chloro-4-(N-ethyl) pentanone acid
(C) 1, 3, 3 – trimethyl – 1, 3 – propane diol (B) 2-chloro-3- (N, N-diethyl amino)
(D) 4 – methyl – 2, 4 – pentane diol propanoic acid
(C) 2-chloro-2-oxo diethyl amine
(D) 2-chloro-2-carboxy-N-ethyl ethane
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55. Which of the following compound contains 1 2 3

isopropyl group? H3C CH2 C CH CH3
(B) 4
(A) 2-methyl pentane 5
H2C CH3
(B) 2, 2, 3-tri methyl pentane 5 2 1
4 3
(C) 2, 2, 3, 3-tetra methyl pentane (C) H3C CH2 CH C CH
(D) 2, 3-dimethyl pentane
H2C CH2 CH3
56. Which one is the wrong statement? CH3
(A) saturated hydrocarbons are called alkenes H3C C CH CH CHO
(D)
(B) open – chain compounds are called 5 4 3 2 1
aliphatic CH3
(C) unsaturated hydrocarbons contain double
or triple bond (bonds) between carbon 61. IUPAC name of CH3CHO is
atoms (A) Acetaldehyde
(D) aromatic compounds possess a (B) Ethanal
characteristic aroma (C) Methyl aldehyde
(D) Formalin
57. Which is the correct statement?
(A) the prefix are written before the name of 62. IUPAC name of CH3CH(OH)CH2CH2COOH
the compound is
(B) the suffix are written after the name of the (A) 4-hydroxy pentanoic acid
compound (B) 1-carboxy-3-butanol
(C) the IUPAC name of a compound is (C) 1-carboxy-4-butanol
always written as one word (D) 4-carboxy-2-butanol
(D) all the above are correct
63. The IUPAC name of the following compound
58. Which of the following statement is wrong? H2 C CH CH2
(A) the IUPAC name of alkenes ends with
suffix –ene CN CN CN
(B) the IUPAC name of alkynes ends with (A) 1, 2, 3-tricyano propane
suffix –yne (B) Propane tricarbylamine
(C) the substituents gets lower number in (C) 1, 2, 3-propane tricarbonitrile
comparison to functional group (D) 3-cyanopropane-1, 5-dinitrile
(D) the IUPAC name of acid amides is
alkanamide 64. The structure of 4-methyl-2-penten-1-ol is
(A) (CH3)2C = CHCH2CH2OH
59. The correct decreasing order of preference of (B) (CH3)2CHCH = CHCH2OH
functional groups during the IUPAC (C) CH3CH2CH = CHCH2OH
nomenclature of poly functional compounds is (D) CH3CHOHCH = C(CH3)2
(A) ⎯COOH, ⎯CHO, ⎯OH, ⎯NH2
(B) ⎯NH2, ⎯OH, ⎯CHO, ⎯COOH 65. The IUPAC name for the following compound
(C) ⎯COOH, ⎯OH, ⎯NH2, ⎯CHO is
OH OH
(D) ⎯COOH, ⎯NH2, ⎯CHO, ⎯OH
CH3 C CH2 CH CH3
60. In which of the following compounds the
carbon atom chain has been correctly CH3
numbered (A) 1, 1-dimethyl-1, 3-butandiol
7 6 5 4 3 2 1
(A) H3C CH CH CH CH2 CH2 CH3 (B) 2-methyl-2, 4-pentandiol
C2 H5 CH3 (C) 4-methyl-2, 4-pentandiol
(D) 1, 3, 3-trimethyl-1, 3-propandiol
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66. Numbers of possible isomers of glucose are 73. Which type of isomerism is observed between
(A) 10 I and II.
(B) 14 I. CH3–CH2–NH–CHO
(C) 16 II. CH3C – CH – CHO
(D) 20 |
NH2
67. Draw all structurally isomeric alkenes with (A) Chain isomers
molecular formula C4H8. (B) Position isomers
(A) 3 (C) Functional isomers
(B) 4 (D) Metamers
(C) 5
(D) 6 74. How many positional isomers are possible for
dimethylcyclohexane?
68. Draw all structurally isomeric 2º chlorides (A) 3
with molecular formula C5H11Cl (B) 4
(A) 7 (C) 5
(B) 3 (D) 6
(C) 2
(D) 6 75. How many structural isomers of all the tertiary
alcohols with molecular formula C6H14O.
69. How many structurally isomeric benzene can (A) 2 (B) 3
be formed by molecular formula C7H8O (C) 4 (D) 5
(A) 9
(B) 4 76. Number of structurally isomeric ethers with
(C) 8 molecular formula C5H12O.
(D) 5 (A) 4 (B) 5
(C) 6 (D) 7
70. How many structurally isomeric cyclic
bromides can be formed having molecular 77. What is the number of all (structurally
formula C4H7Br isomeric) alkynes with molecular formula
(A) 5 C6H10.
(B) 4 (A) 6 (B) 7
(C) 8 (C) 8 (D) 9
(D) 3
78. Which one of the compound is not isomer of
71. Isomers have essentially identical others?
(A) Structural formula
(B) Chemical properties (A)
(C) Molecular formula
(D) Physical properties

72. What is the correct relationship between the (B)

following compounds?

(C)
(A) Chain isomers
(B) Position isomers
(C) Functional isomers
(D)
(D) Identical
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79. Which of the following compounds has wrong 82. Which one of the following pair represents
IUPAC name stereo isomerism
(A) CH3 – CH2 – CH2 – COO – CH2CH3 (A) Linkage isomerism and Geometrical
→ Ethyl butanoate isomerism
(B) (B) Chain isomerism and Rotational
isomerism
(C) Optical isomerism and Geometrical
→ 3-Methylbutanal isomerism
(C) (D) Structural isomerism and Geometrical
isomerism
→ 2-Methyl-3-butanol
83. Which of the following is not chiral?
(D) (A) 2–Butanol
(B) 2, 3–Dibromo pentane
(C) 3–Bromo pentane
→ 2-Methyl-3-pentanone (D) 2–Hydroxy propanoic acid
80. Which of the following pairs of compounds are 84. Among the following which one can have a
enantiomers meso form?
CH3 CH3
(A) CH3CH(OH)CH(CI)C2H5
H OH HO H (B) CH3CH(OH)CH(OH)CH3
(A) OH H and H OH (C) C2H5CH(OH)CH(OH)CH3
(D) HOCH2CH(CI)CH3
CH3 CH3
CH3 CH3 85. CH3–CHCI–CH2–CH3 has a chiral centre
H OH HO H which one of the following represents its R
(B) HO H
and H configuration
HO
C2H5 C2H5
CH3 CH3 | |
CH3 (A) H — C — CH3 (B) CI — C — CH3
| |
H OH CI H
(C) and OH CH3 C2H5
H | |
CH3 (C) H — C — CI (D) H3C — C — CI
| |
CH3 CH3 C2H5 H
HO H HO H
(D) OH
and H 86. In the following the most stable conformation
H HO
of n-butane is
CH3 CH3

81. The configuration of the given compound is (A)

(A) E (B) R
(B)
(C) S (D) Z
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CH3

(C) H OH

CH3 OH

H
(A) 2S, 3S (B) 2S, 3R
(C) 2R, 3S (D) 2R, 3R
(D)
89. Which of the following compound is expected
to be optically active?
(A) (CH3)2 CHCHO
87. The geometrical isomerism is shown by (B) CH3CH2CH2CHO
CH2
CH2 (C) CH3CH2CHBrCHO
(A) (B) (D) CH3CH2CBr2CHO

CHCI 90. The IUPAC name of the compound

CHCI
(C) (D) is
HO
(A) 3, 3 - dimethyl - 1 - hydroxy cyclohexane
88. Correct configuration of the following is
(B) 1, 1 - dimethyl - 3 -hydroxy cyclohexane
(C) 3, 3 - dimethyl - 1 - cyclohexanol
(D) 1, 1 - dimethyl - 3 - cyclohexanol
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Answer Key
46. (B)
47. (B)
48. (A)
49. (B)
50. (C)
51. (C)
52. (C)
53. (C)
54. (B)
55. (A)
56. (A)
57. (D)
58. (C)
59. (C)
60. (D)
61. (B)
62. (A)
63. (C)
64. (B)
65. (B)
66. (C)
67. (A)
68. (B)
69. (D)
70. (B)
71. (C)
72. (A)
73. (C)
74. (B)
75. (B)
76. (C)
77. (B)
78. (D)
79. (C)
80. (A)
81. (B)
82. (C)
83. (C)
84. (B)
85. (B)
86. (A)
87. (D)
88. (A)
89. (C)
90. (C)
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Hint and Solutions

46. (B) 67. (A)

H2C = CH–CH2CH3, H3C–CH = CH–CH3,
47. (B) H 2 C = C – CH3
|
CH3
48. (A)
68. (B)
49. (B)

50. (C)

51. (C)

52. (C) 69. (D)

53. (C)

54. (B)

55. (A)
70. (B)
56. (A)

57. (D)

58. (C)

59. (C) 71. (C)

60. (D) 72. (A)

Carbon skeleton is different in both
61. (B) compounds.

73. (C)
62. (A)

63. (C)

64. (B)

65. (B)

66. (C)
Glucose has four dissimilar asymmetric
carbon atoms; a = 24.
Hence, (C) is the correct answer.
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74. (B) CH3

|
(iv) H — C  C — C — CH3
|
CH3
(v) CH3—C  C—CH2—CH2—CH3
CH3
|
75. (B) (vi) CH3 — C  C — CH — CH3
CH2 (vii) CH3—CH2—C  C—CH2—CH3
|
(i) CH3 — C — CH 2 — CH 2 — CH 2
|
OH 78. (D)
CH 2
|
(ii) CH3 — C — CH — CH — CH 2
| |
OH OH It has different molecular formula with
CH2 different DU.
|
(iii) CH3 — CH 2 — C — CH 2 — CH3 79. (C)
|
OH 80. (A)
76. (C)
(i) CH3—O—CH2—CH2—CH2—CH3
CH3
|
(ii) CH3 — O — CH — CH 2 — CH3
CH3
|
(iii) CH 3 — O — CH 3 — CH — CH3 non-super impossible mirror image
CH3 stereoisomers
|
(iv) CH 2 — O — C — CH3 81. (B)
|
CH3
(v) CH3—CH2—O—CH2—CH2—CH3
CH3
|
(vi) CH 2 — CH 2 — O — CH — CH3

77. (B) Clockwise arrow represents 'R'

(i) H—C  C—CH2—CH2—CH2—CH3
configuration
CH3
|
(ii) H — C  C — CH — CH 2 — CH3
CH3 82. (C)
|
(iii) H — C  C — CH 2 — CH — CH3
83. (C)
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3–Bromopentane does not have chiral

carbon 86. (A)
Anti form of butane is more stable because
84. (B) of less strains.

87. (D)
meso form
88. (A)

89. (C)

85. (B) 90. (C)

clockwise arrow represent

'R' configuration

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