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    Chapter 1-5 1st Half 1st Year

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    Chapter 1-5 1st Half 1st Year

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    Chapter 1-5 1st Half 1st Year

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    Alnoor Academy CHEMISTRY

    1st Half Part-1 FSc


    Intermediate Part – 1 (Class – XI)(1st Half Ch No.1-5)
    OBJECTIVE TYPE
    Time: 20 min Total Marks: 17

    Q1: Each question has four possible answers A,B,C and D . The choice which you think is correct, fill that
    circle infront of that question with marker or pen ink in the answer book. Cutting or filling of more than two
    circles will result zero mark in that question.
    1. which of the following pair has same number of molcules?
    (a) 280cm3 of CO2 and 280cm3 of N2O (b)11.2 dm3 of O2 and 32 g of CO2
    (c) 44g of CO2 and 11.2 dm3 of CO (d) 28g of N2 and 5.6 dm3 of CO2
    2. 48 gm O2 of will react completely with how much mass of Al to produce Al2O3?
    (a) 8 g of Al (b) 54 g of Al (c) 32 g of Al (d) 27 g of Al
    3. Which relation is used in mass spectroscopy?
    a. m/e= Hr/E b. e/m= Hr/E c. m/e= H2r/E d. m/e= Hr2/E

    4. The number of moles of CO2 which contains 8.0 g of oxygen:


    (a) 0.25 (b) 0.50 (c) 1.00 (d) 1.50
    5. The process used to separate a mixture of volatile and thermally stable products is
    a. Sublimation b. Solvent extraction c. Vaporization d. Filtration

    6. The rate of filtration can be increased by using:


    (a) Fluted filter paper (b) Desiccators (c) Suction flask (d) Chromatographic tank
    7. Solvent extraction in an equilibrium process and it is controlled by
    (a) Law of mass action (b) The amount of solvent used
    (c) Distribution law (d) The amount of solute

    8. Equal masses of methane and oxygen are mixed in an empty container at 25 0c . The fraction of total
    pressure exerted by methane is?
    (a) 1/3 (b) 8/9 (c) 1/9 (d) 2/3
    9. critical temperature depends upon?
    (a)size (b)shape (c)intermolecular force (d)All of these
    10. Normal human body temperature is: (LHR 2011)
    o o
    (a) 37 C (b) 98.6 F (c) 310K (d) All of above
    11. Crystals formed due to London forces of interaction are: (GRW 2008)
    (a) Ionic (b) Covalent (c) Molecular (d) Metallic
    12. Molar heat of vaporization of water is
    a. 140.6 kJ/mol b. 14.06 kJ/mol c. 18 kJ/mol d. 40.6 kJ/mol
    13. The weakest intermolecular force is
    a. hydrogen bonding b. ion-dipole forces
    c. dipole-dipole forces d. London dispersion forces

    14. In orthorhombic crystal, the unit cell dimensions are


    (a) a = b  c  =  =  = 90o (b) a  b  c  =  =  = 90o
    (c) a  b  c  =  =   90o (d) a  b  c  =  =   90o
    15. Mass of electron is:
    (a) 9.1095 × 1031 kg (b) 9.1095 × 10-31 kg (c) 9.1095 × 10-27 kg (d) 9.1095 × 10-31 g
    16. Lyman series are produced when electron jump from infinity to n = ?
    (a) 1 (b) 2 (c) 3 (d) 4

    17. What is the value of for the 3d sub-shell?


    (a) 2 (b) 1 (c) 5 (d) 3

    Prepared By: Muhammad Shoaib Anwer


    Alnoor Academy CHEMISTRY
    1st Half Part-1 FSc
    CHAMISTRY (subjective)
    CLASS XI 1st half CHAPTER-1-5
    Time=02:40 hrs
    (Total marks:68)
    SECTION 1

    Q 2: Write brief and concise answer for each question(Any8) (2 x 8 = 16)

    1. Why the isotopes have the same chemical properties but different physical properties?
    2. What is the mass of 2.24 dm3 of O2 and N2 at S.T.P?
    3. Why the experimental yield is mostly less than the theoratical yield?
    4. Why a limiting reactant controls the amount of the product formed in a chemical reaction?
    5. Justify that N2 and CO have same number of electrons, protons neutrons.
    6. What are molecular ions and how they are produced ?
    7. 23 g of sodium and 39 g of potassium have equal number of atoms. Justify it.
    8. What is number of H+ ions in 9.8 g of H3PO4?
    9. What is distribution Law or Distribution constant?
    10. Differentiate between adsorption and partition chromatography.
    11. How undesirable colours are removed in crystallization process?
    12. What are characteristics of an ideal solvent?
    Q 3: Write brief and concise answer for each question(Any8) (2 x 8 = 16)

    1. why do we use the density units g/dm3 for case of gases?


    2. Derive SI units of general gas constant R ?
    3. Why deep sea divers do not use air in their cylinders and what they use instead of it?
    4. SO2 is non-ideal at 273 K but behaves like an ideal gas at 273 oC. Justify the statement.?
    5. -273.16oC is regarded as the lowest possible temperature. Justify it.
    6. Calculate the density of methane at STP.
    7. Diamond is hard and electrically insulator. Why?
    8. Explain electron gas theory.
    9. Evaporation causes cooling effect. Why?
    10. Why conductances of metals decrease upon increasing temperature?
    11. Why metals show lustrous nature?
    12. Why HF is a weaker acid than HCl?
    Q 3: Write brief and concise answer for each question(Any6) (2 x 6 = 12)

    1. Calculate the wavelength of light emitted by a source having wave number 2x106 m-1 ?
    2. Give the Mosley’s equation. Also write its importance.

    3. Define (i) Pauli-exclusion principle (ii) Wavelength


    4. . Why are atomic orbital’s what are their types ?
    5. Give the electronic configuration of Ca20 and Br35
    6. Differentiate between Zeeman Effect and stark effect.
    7. The e/m value of positive rays obtained from hydrogen gas is 1836 times less than that of cathode rays.
    Justifys it.
    8. Why positive rays are called canal rays?
    9. Define Heisenberg’s principle of uncertainty and give its mathematical expression.

    Prepared By: Muhammad Shoaib Anwer


    Alnoor Academy CHEMISTRY
    1st Half Part-1 FSc

    SECTION II
    LONG QUESTIONS:

    Attempt the following question (8 x 3=24)

    Q.3 (a) Silicon carbide (SiC) is an important ceramic material . It is poduced by allowing sand (SiO2) to
    react with excess of caebon at high temperature.
    SiO2 + 3C → SiC + 2CO
    When 100kg sand is reacted with excess of carbon,51.4kg SiC is produced . What is the percentage yield of SiC?
    (4)
    (b) What is Hydrogen bonding? Give its examples(any two) and applications(any two)? (4)

    Q.4 (a) Describe Dalton;s Law of partial pressure and write down its important applications? (4)

    (b) How neutrons were discovered write their properties in detail? (4)
    Q.5 (a)A sample of 0.600 moles of a metal M reacts completely with excess of flourine to form 46.8 g of
    MF2. a) How many moles of F present in MF2?
    b) which element is represented by symbol M? (4)
    (b) Discuss liquid crystals in detail? (4)
    Q.6 (a) Serotenin ( Molar mass 176gmole-1) is a compound that conduct nerve impulse in brain and
    musceles . It contains 68.2% C, 6.86% H, 15.09% N, 9.08% O. what will be its molecular formula? (4)
    (b)What is vapour pressure?How it can be measured?give the factors effecting it in detail? (4)

    Q.7 (a)Derive Graham’s Law and Avogdros’s Law from kinetic gas equation? (4)
    (b)How you can calculate radius of nth orbit of hydrogen atom according to Bohr’s atomic model?(4)

    Prepared By: Muhammad Shoaib Anwer

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