Rajiv Gandhi University of Knowledge Technologies, Basar B. Tech 1 Year

RAJIV GANDHI UNIVERSITY OF KNOWLEDGE
TECHNOLOGIES, BASAR
END SEMESTER Remedial EXAMINATION-Sem 2 – Nov 2020
B. Tech 1st Year
Subject Name: Engineering Chemistry Subject Code: CY1001
Branch/Year: All Branches Max. Marks: 60
Date: 5/11/2020 Time: 2 Hrs
Section A
Answer all questions. Each question carry one mark [30 x 1=30 Marks]
1. Which of the following molecule exhibit microwave spectrum
a) CO2 b) C2H2 c) H2O d) All the above
2. What is the number of vibrational degrees of freedom for CO molecule?

a) 4 b) 3 c) 2 d) 1
3. Which of the following is an absorption shift?

a) Bathochromic b) Hyperchromic c) Hypochromic d) None of the above
1. Calomel electrode is an example of

a) Metal-metal ion electrode
b) Metal-insoluble salt-anion electrode
c) Gas-ion electrode
d) All the above
2. Consider the following equations

i. ∆G = −nFEcell
ii. ∆S = nF(dE/dT)P
∆G = ∆H – nFT(dE/dT)P Then
a) i and ii are correct
b) ii and iii are correct
c) i and iii are correct
d) i, ii, and iii are correct
3. On dilution the pH of a basic solution

a) decreases
b) increases
c) no change
d) data insufficient
4. The rate of corrosion increases with

a) decrease in temperature and increase in humidity
b) increase in temperature and decrease in humidity
c) increase in temperature and increase in humidity
d) decrease in temperature and decrease in humidity
5. An article is protected from corrosion by electroplating method. In this process the article acts as
__________________.
6. The triple point in the phase diagram of water system is

a) invariant
b) monovariant
c) bivariant
d) none
7. Consider the following statements

a) Enzyme reactions are highly stereospecific reactions
ii) In homogeneous catalysis the reactants and the catalyst should be in same physical state
iii) Intermediate compound formation theory failed to explain homogeneous catalysis
Then
a) statement i is wrong
b) statement ii is wrong
c) statement iii is wrong
d) all are wrong
8. Addition polymerization process results mainly in the formation of

a) thermosetting polymer
b) thermoplastic polymer
c) thermosetting as well as thermoplastic polymers
d) no products
9. Give the equation for Reimer Tiemann Reaction

10. Cannizaro reaction occurs in
a) Aromatic or aliphatic aldehydes with -H
b) Aromatic or aliphatic aldehydes without -H
c) Only aliphatic aldehydes with -H
d) Only aliphatic aldehydes without -H
11. Isotopic effect is observed in--------------elimination reactions
12. Give the structure of alanine (amino acid)
13. Molecular formula of oleic acid is

e) C17H35COOH
f) C17H31COOH
g) C17H34COOH
h) C17H33COOH
14. Bakalite is an example of -------------------polymer

i) Thermosetting polymer
j) Thermoplastic polymer
k) Elastomer
l) Monomer
2. Give the reaction for Williamson’s etherification process
3. Enzymes functions most effectively at optimum temperature of

a) 45C
b) 20C
c) 15C
d) 30C
4. Moment of inertia relation for oblate type symmetric molecule is

a) IA=IB=IC
b) IA>IB=IC
c) IA<IB=IC
d) IA IB IC
5. Relation between Absorbance and Transmittance is

a) A=1/T
b) A=Log T
c) A= Log 100/T
d) A = Log 1/T
6. Different transitions observed in CO group are

a) →*, →*, n→*
b) →*, →*, n→*, n→*
c) →*, →*
d) →*, →*, n→n*
7. Salt present in the Calomel electrode is

a) HgCl2
b) HgSO4
c) Hg2SO4
d) Hg2Cl2
8. Leclanche cell is an example of

a) Primary Cell
b) Secondary cell
c) Fuel cell
d) Concentration cell
9. Coating with Sn on Fe to safeguard it from corrosion is called

a) Sherardizing
b) Tinning
c) Galvanizing
d) anodising
10. Example for a material showing phosphorescence phenomenon is

a) CaF2
b) Uranium
c) Chlorophyll
d) ZnS
11. Number of phases in the saturated salt solution

a) 1 b) 2 c) 3 d) 4
12. Composition of lead and silver at eutectic point is-------------------
13. Polymerization of methyl methacrylate to polymethyl methacryalte is an example of

a) Free Radical addition polymerization reaction
b) Cationic addition polymerization reaction
c) Anionic addition polymerization reaction
d) Coordination addition polymerization reaction
14. The intermediate formed during SN1 reaction is

a) Free radical
b) Carbocation
c) Carbanion
d) No intermediate
e)
Section – B
Answer any three questions out of six. Each carry ten marks [3 x 10=30 Marks]
1. a) Explain the Phase diagram of H2O system (5M)

b) Explain the intermediate compound formation theory with two examples? (5M)
2. a) Write down the mechanism for the synthesis of polystyrene by cationic polymerization.
(5M)
b) Give the steps involved in skraup synthesis (5M)
3. a) Give an example and mechanism for Electrophillic Addition reaction with

rearrangement (5M)
b) Discuss functions of lipids (5M)
4. a) Draw the vibrational modes of AB2 type angular molecule (6M)

b) Calculate the vibrational degrees of freedom for the following molecules:
(i) NH3 (ii) CO2 (iii) CH4 (iv) HCl (4M)
5. a) Discuss the following with a neat labeled diagram for each

(i) H2 Gas Electrode concentration cell (ii) Daniel Cell (6M)
b) Calculate the pH of the resulting solution obtained by mixing 20 mL of 0.2M HCl solution and
50 mL of 0.1M NaOH solution by assuming complete dissociation of HCl and NaOH in the
solution? (4M)
6. a) Derive rate equation for parallel reaction and give two examples for the same (5M)
b) Write any five differences between electrochemical corrosion and Dry corrosion. (5M)

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RAJIV GANDHI UNIVERSITY OF KNOWLEDGE

2. What is the number of vibrational degrees of freedom for CO molecule?

3. Which of the following is an absorption shift?

1. Calomel electrode is an example of

2. Consider the following equations

3. On dilution the pH of a basic solution

4. The rate of corrosion increases with

6. The triple point in the phase diagram of water system is

7. Consider the following statements

8. Addition polymerization process results mainly in the formation of

9. Give the equation for Reimer Tiemann Reaction

11. Isotopic effect is observed in--------------elimination reactions

12. Give the structure of alanine (amino acid)

13. Molecular formula of oleic acid is

14. Bakalite is an example of -------------------polymer

2. Give the reaction for Williamson’s etherification process

3. Enzymes functions most effectively at optimum temperature of

4. Moment of inertia relation for oblate type symmetric molecule is

5. Relation between Absorbance and Transmittance is

6. Different transitions observed in CO group are

7. Salt present in the Calomel electrode is

8. Leclanche cell is an example of

9. Coating with Sn on Fe to safeguard it from corrosion is called

10. Example for a material showing phosphorescence phenomenon is

11. Number of phases in the saturated salt solution

12. Composition of lead and silver at eutectic point is-------------------

13. Polymerization of methyl methacrylate to polymethyl methacryalte is an example of

14. The intermediate formed during SN1 reaction is

1. a) Explain the Phase diagram of H2O system (5M)

3. a) Give an example and mechanism for Electrophillic Addition reaction with

4. a) Draw the vibrational modes of AB2 type angular molecule (6M)

5. a) Discuss the following with a neat labeled diagram for each

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