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SEKHUKHUNE SOUTH

SEPTEMBER ENRICHMENT CLASSES


PHYSICAL SCIENCES PAPER 1 Straight lines

QUESTION 1
MCQ
>Gradient = V have constant
gradient
1.1 Which of the following position-time graphs represent the motion of an
object moving with constant velocity?

m=%

= (2)

1.2
A trolley X with a mass m is travelling at velocity v. it is brought to rest
by a braking force F over a distance d. An identical trolley Y, but with
twice the mass of X, has the same initial velocity v is brought to rest
vi.vital by the same force F. what will be the stopping distance of Y?

Ad Fuet = M a a=±m for]


◦ =V44 B 2d
C 4d a = Em for ×
gaby = Vi D 1/2d (2)
ay = tax
1.3 A ball is thrown upwards by a girl. Which one of the following
☐y= a combinations give the directions of the velocity of the ball, the
acceleration of the ball aand the net force that the ball experiences as
it travels upwards just after leaving the girl’s hand.

velocity acceleration Net force


A upwards downwards upwards
B upwards upwards upward
C upwards downwards downwards
D upwards upwards downwards (2)

1.4
A person weighs 750N. This person stand on a scale placed on the
*a:*"
floor of a lift. The lift can travels up and down in a tall building.
Which row in the table below describes the motion of the lift at the
moment the scale reads 700N.
↳ W at rest or constant v

Fuet = apparent
raft
Assume ↑ ⊕ N=Fg Same magnitude
N-Fg-ma Fg as the N

N =FgtM-aDirection of movement Type of motion .


A upwards Constant acceleration
B upwards Constant velocity /
C downwards Constant velocity
D downwards Constant acceleration (2)
NF.
1.5 A trolley with a mass m has momentum p. the kinetic energy of the
trolley will be:

A 𝑝𝑚 Ek =½MV²
𝑝
B𝑚
p = mV-①
𝑃2 𝑚
C 2

𝑃2
from ① µ m
D 2𝑚
(2)
[10]
M. V V
Ek=½.
EK=½P-¥)
EK=½*V P2
2m
Question 2

Two blocks, A (mass 1 kg) and B (mass 5kg), are pulled along a horizontal surface
by rope 1. They are connected by rope 2. While they are moving, block A
experrinces a frictional force of 3,9N and block B experiences a frictional force of
19,6 N.
no

.
-
> fk

While the blocks are moving, rope 2 snaps (breaks).


N Ifg
The velocity of block A is represented against time on the graph below, which is
not drawn to scale.
T > fk
N Tz '
T, → fk → Tiradient 2
-g

Ji-0ms' Gradient,

^ String snaps F
0,5-
ja uf-"
Define the term acceleration
2.1 (2)
2.2
Calculate the: tf-ti
2.2.1 Acceleration of the system before the rope 2 snaps (breaks) (3)
Graphs 2.2.2 Resultant force acting on block B (3)
2.3 State newton’s second law of motion in words (2)
arsm 2.4 Draw a free body diagram showing all the force acting of block B (4)
before the string breaks/snaps
austm ☁ Determine the tension on rope 2 before it snap(break)
2.5 (4)
2.6 After how long did the rope 2 snaps(breaks) (1)
a Usfnet 2.7 State work energy theorem (2)
2.8 Use energy principle to calculate the distance covered by block B (4)
after the rope snaps (breaks).
2.9 Classify frictional force as conservative or non-conservative force. (1)
2.10. Give reason for your answer in 2.9 (2)
2.11 Calculate work done to overcome frictional force acting on block A (4)
after the rope snaps(breaks)
[32]

Iffind Dafirst: A-¥4. at

Wfk = fk DX (OS ⊖
Question 3

A student places two bricks of mass 3 kg and 6 kg on a desk. The bricks are in
contact with each other and the student pushes on the 3 kg brick with a force
labelled X that acts at an angle of 25 to the horizontal, as shown in the sketch.
While moving, each brick experiences a kinetic friction force of
2 N.

Fgkgonbkg
fk

Fnet)y=0
f
-
L
N-Fay!The system accelerates at 1.5 m.s-2 to the left.
g
3.1 State newton’s third law in words (2)

3.2 Draw a free body diagram showing all the forces acting on the 6kg (4)
block.

3.3 Calculate the coefficient of kinetic friction on the 6 kg block. (3)


L
K' 3.4 Calculate the magnitude of the force X that causes the acceleration of (5)
-K the system
① Fuet=m-a- [14]

* draw free body diagram of 319

→ from the free body diagram identify

the reaction force of: emphasize

① Normal properties of
action-reaction
② weight
forces?
③ force of 6kg on 3kg
- Act on diff
bodies
- HAVE SAME MA9"l¼¼

- Act in opp dire

Day 2
QUESTION 1
MCQ
1.2 In the circuit shown below, the switch is open.

Emf
The reading on the voltmeter is.
⅔⇒R
A 0V
B 6V V=I (O)
C 0,6V V = OVOHS
D 12V (2)
1.2 The graph below shows the relationship between current through a
conductor and voltage across the conductor for four different
conductors. Which graph shows the behaviour of the ohmic resistor
with the highest resistance?
R=¥
- Explain ohmic
L
conductor R=}
t
- State ohm's/an
1 Ry=K
↳the
2 gradient
m=½ 9-
(2)
1.3 High-energy light is shone onto a zinc plate. The energy of the light is
greater than the work function of zinc.

Which graph correctly shows the number of electrons emitted from the
metal surface as the intensity of the light is increased?

(2)
QUESTION 2

Learners perform an experiment to determine the internal resistance of a battery


using the circuit diagram below.
RVs ¥

E-TCr+R)

E. +I

Exerty
The readings obtained from the experiment are shown in the table below.
l
g- E)c -

Y- M Ctc
-
-
↳ choosing a scale Draw line of best f MIE
2.1 1 (4)
Use the data from the table to draw a graph of R verses ON THE C =-r
I
GRAPH SHEET
2.2 State ohm’s law in words (2)
2.3 Use information from the graph to determine the value of the:
2.3.1 emf of the battery (3)
2.3.2 internal resistance of the battery (1)
[10]
Centre number
Examination
number

2.1
Question 3

Three resistors and an electrical device are connected to a 30 V battery with


internal resistance r as shown in the circuit diagram below. The ammeter has a
reading of 2 A.

3.1 Define the tern emf of a battery (2)

3.2 Calculate voltmeter reading V1 (6)

3.3 Calculate the internal resistance of the battery (3)

3.4 An additional resistor is connected at position X as indicated in the


diagram.
How will voltmeter reading V1 be affected? Write down only
INCREASE, DECREASE or STAYS THE SAME. Give an explanation
for your answer. (4)
[15]
QUESTION 4

The battery in the circuit represented below has an emf of 12 V and an internal
resistance r. Voltmeter V1 is connected across the battery. The resistance of the
connecting wires is negligible. Wives have or Resistance
→IT - S, ES, closed Short circuit

- Reads Emf

121126A If IT =
S, open v2=V,
- Reads Vex
Szclosed vz:O
1 HIT#°
- Both Switches Close

Switches S1 and S2 are both open.


✗ RT decreases
x
4.1 Write down the reading on voltmeter V2 (1)
4.2 Switch S1 is now closed. Switch S2 remains open. The reading on V1 is
now 10 V
Calculate the: → r is excluded!!
4.2.1 Total external resistance of the circuit (3)
4.2.2 Internal resistance of the battery (4)
4.2.3 The power dissipated to 10Ω resistor (4)
Both switches S1 and S2 are now closed
4.3 How will the following be affected?
Write down only INCREASE, DECREASE or STAYS THE SAME. Give
an explanation for your answer.
4.3.1 The reading on V1 (4)
4.3.2 The power calculated in 4.2.3 (4)
[20]

Order for explaining:-- RT


G- yImT... E =IT-RA
(Vin -IT. r)
Vex .. (E = Vin + Vext)

<
0 2 10
4 6
6 4
Day 3

Paper 2
Organic chemistry
Question 1

MCQ

1.1 Which of the following are STRUCTURAL ISOMERS of (2)


ethyl propanoate?
- Define Structural Isomer

- Identify the types

of structural isomer

& explain them.

- Identify homologous

series.
- write name of each
compound.

A (i), (ii) and (iii) Structure of functional


For esterification:
B (i) and (ii) only 1° group for id Iii

C (ii) only - iii) Identify the


D(iii) only
nd i alcohol & acid used.
1.2 Consider the reaction represented by the following chemical equation: (2)

The reaction is an example of a/an: ↘


- Identify if exo or endothem
A addition reaction

/ B dehydration reaction = Draw energy profile


Removal
C oxidation reaction > Identify all addition rxns
of Hz ✗
D endothermic reaction
from alcohol & their reaction conditions.
Bromine water is orange-brown,
> This is a bromine water test -
1.3 Which statement is correct for the reaction of an UNSATURATED (2)
hydrocarbon with bromine (test for unsaturation)? Emphasize Bromine water
A the reaction is slow is BK(e)
B the reaction is a substitution reaction
C the bromine will decolorize quickly due to an addition reaction
D ultraviolet light is needed for this reaction.
akane - SATURATED Brice/decourtoriz Slowly [6]Substitution
Question 2
Alkene unsaturated Brace) decolorize quickly Addition
Consider the organic compounds A to D shown below.

• Identify HS is HI, Saturated or

• General formula 293? why? unsaturated? why.


• IUPAC NAME
• Name of

functional
group
PARENT CHAIN MUST CONTAIN
THE FUNCTIONAL GROUP!!

2.1 Define the term hydrocarbon → it could be Ni/ Pd


(2)
2.2 Identify the letter that represent the hydrocarbon (1)
2.3 Identify the compound wish require platinum/ Pt as a catalyst (1)
2.4 Write the IUPAC name of the following compounds:
2.4.1 A (3)
2.4.2 B (2)
2.4.3 D (2)
2.5 Identify tertiary alcohol from the above compounds. (1)
2.6 Give reason for your answers in 2.5 (2)
2.7 Define the term functional isomers (2)
2.8 Draw the structural formula of the functional isomer of compound C (2)

↳ carboxylic acid.

learner must draw an acid with 6 (atoms


> be mindful of the number of bond lines!!

functional GROUP of the

2.9 Draw structural formula of the following compounds:


2.9.1 A "let them write names) (1)
2.9.2 D (1)
2.10 Classify compound A as saturated of unsaturated compound. (1)
2.11 Give reason to your answer in 2.10 (1)
2.12 Define the term positional isomer . more functional group OR
(2)
2.13 Draw structural formula of the positional isomer of compound B (2)substituent
[26]
Question 3 ✓ alkyl cannot be at a terminal carbon
Compounds A to E, indicated in the table below, are used during two
investigations to determine the factors which influence boiling point.
> have different surface area
'chain isomers
write
molecular formula

For each investigation write Independent, dependent & Control


3.1 Compounds A, B and C are structural isomers. Write down the:
compounds from same homologous series talk about surface
Definition of the term structural isomer
3.1.1 (2)
GENERAL FORMULA of the homologous series to which these (2) area &
3.1.2
compounds belong
3.1.3 Type of structural isomerism illustrated by these compounds (2)
condon
3.2 Consider the boiling points of the compounds in investigation
3.2.1 Define the term boiling point.
forces!!
Comparing 3.2.2 Write down the independent variable for this investigation.
compounds 3.2.3fromWrite down one control variable for this investigation.
Explain fully why the boiling points increase from compound A ☆ compare
3.2.4 series/
diff homologous
to compound C. surface area
3.2.5 Which one of compounds A or C will have the highest vapour
USE → strength of
pressure at a certain temperature?
IMF
Refer to the data in the table and give a reason for the answer. (2) → ENERGY
Identify IMF on each compound
3.3 To which homologous series does compound E belong? (1)
Compare strength of IMF
3.4 Consider investigation II. Refer to the type of Van Der Waals forces in
each of (COMPARE)
Energy needed the compounds and explain why the boiling point of compound
D is higher than that of compound E. (2)

[19]
Conclusion (therefore Compound E has low Boiling point
than Compond D)
Question 4

Haloalkanes are important in organic synthesis, for example


1−bromopropane is involved in four organic reactions, W, X, Y and Z, as
shown in the diagram below. Compounds A and B are organic compounds.
ur is used for turning to
alkane to haloalkane

↳this is a haloalkane: Haloakanes


The reaction conditions for each reaction are given in the table below.
undergo Eliminal

& substitution
ONLY

↳ this is substitution.

this is elimination

4.1 Write down the GENERAL types of reactions for each of the following:
4.1.1 Reaction X Addition, Elimination (1) and
4.1.2 Reaction Y (1)
4.1.3 Reaction Z substitution are general names
(1)
4.2 Write down the SPECIFIC types (NAMES) of each of the
following:
4.2.1 Reaction W ↗hadrohalogenation, Cracking,
(1)
4.2.2 Reaction X (1)
hydration are specific names
4.2.3 Reaction Y (1)
of reactions.
4.2.4 Reaction Z (1)
4.3 Identify the homologous series to which compound A belongs. (1)
4.4 Use condensed-structural formulae to write a balanced chemical (4)
equation
for reaction X
4.5 Use structural formulae to write a balanced chemical equation (4)
for reaction Y.
4.6 Write down the IUPAC name of the organic product produced when (2)
propan−1−ol is treated with concentrated sulfuric acid and heated.
[18]

Emphasize the diff between condensed structural,

structural and molecular formula. Write them

next to each other to emphasize the ir difference.


Question 5

Consider the following sequence of organic reactions labelled A to E.

5.1 Write down the type of reaction that occurs at:


5.1.1 A (1)
5.1.2 C (1)
5.2 Write down the NAME or FORMULA of the catalyst for reaction D. (1)
5.3 Reaction B is a substitution reaction that takes place in the presence
of water.
Write down the:
5.3.1 Types of substitution reaction for B (1)
5.3.2 Two other reaction conditions for this reaction (2)
5.3.3 IUPAC name of the major product Y (2)
5.4 Use the structural formulae to write a balance equation for reaction B, (3)
showing the formation of alcohol Y.
5.5 Reaction E is reaction between minor product, alcohol Z and a
carboxylic acid to form an ester.
Write down the:
5.5.1 Name of this type of reaction (1)
5.5.2 Name of the inorganic compound formed during this reaction. (1)
5.5.3 Name of the catalyst needed for this reaction (1)
5.5.4 IUPAC name for the functional isomer of the ester formed (2)
5.6 Draw the structural formula of the functional group of the carboxylic (1)
acid.
[17]
Take home
Day 4
Question 1
MCQ
1.1 Consider the following potential energy diagram for a chemical (2)
reaction:
- Effect of adding catalyst

on the curve

- write the value of:

I.. EA (reverse)

2. Energy absorbed

3. DH (reverse)
Which one of the following shows the values of the total energy change
and the activation energy for this reaction?

Energy change (kJ.mol-1) Activation energy (kJ.mol-1)


A 80 40
B 60 100
C 40 80
D -40 80
1.2 Consider the reaction represented by the balanced chemical equation below, (2)
using rhodium as a catalyst:
Expose learners
In a closed system of carbon monoxide, nitrogen monoxide andto diff
rhodium, which one of the grapths below best illustrates the change in
the amount of rhodium over time. catalysts:

- Pt
V2.05

- Mn 2

- HasOt

EA
learners draw
let the

the cans
xp iii

Expu
1.3 In a series of experiments 0, 05 g samples of magnesium were added (2)
separately to 100 cm3 volumes of hydrochloric acid. The table below
summarizes the experimental conditions:

In which two experiments would the magnesium be expected to


take the shortest time to completely react with the excess
hydrochloric acid?
A I and ii
use this to revise Collison
B iii and iv
C iii and v theory for Temperature,Surface
D ii and iv
area and concentration
1.4 One of the stages in the industrial preparation of Iron from its ore is (2)
represented by the equation below:

The following changes are made to the system:

Which 0f the above changes will favour the forward reaction ?

A i,ii and iii

B i and ii

C ii

D iii

[8]
Question 2

In an investigation into the effect of concentration and temperature on reaction


rate, the reaction as shown in the balanced chemical equation below is used:

Thandi places the reaction


vessel on a piece of paper
that has been marked withan
'X'. When a sufficient amount
of precipitate has formed,
the turbidity (cloudiness) of
the solution is such that the
'X' disappears. The figure
alongside shows the
experimental setup. Start of reaction Reaction after some time

The time taken for the X to disappear is measured for various reaction conditions
as shown in the table below. Note that the sodium thiosulfate is the limiting reagent
in Experiment 1 to 4 and the hydrochloric acid is the limiting reagent in experiment
5.

2.1 Write a chemical equation showing the ionization of hydrochloric acid in (3)
water.
2.2 Write the symbol for the product that is responsible for the precipitate (1)
2.3 For which experiment will the 'X' disappear the fastest? (1)
2.4 Consider Experiments 1 and 2
2.4.1 On the ANSWER SHEET, a partially labelled Maxwell (4)
Boltzmann distribution curve for Experiment 1 has
been given.
Label the y-axis.
Draw the distribution curve for Experiment 2.
Indicate and label the activation energy
2.4.2 Using the collision theory, and with reference to the (4)
Maxwell-Boltzmann distribution curves in Question 6.4.1,
explain fully which experiment would have the higher
reaction rate.
2.5 Consider the graphs below of mass of precipitate formed versus time labelled
A, B, and C.

Which graph, A, B, or C, represents:


2.5.1 Experiment 2? (1)
2.5.2 Experiment 4? (1)
2.5.3 Experiment 5? (1)
2.6 Thobeka changes another reaction condition which is represented in
the graph below. Curve R (solid line) denotes the initial conditions, and
curve C (dashed line) denotes the changed condition.

Reaction Coordinate
2.6.1 Define the term activation energy (2)
2.6.2 Classify this reaction as EXOTHERMIC or ENDOTHERMIC. (1)
2.6.3 What sign (POSITIVE or NEGATIVE) does the heat of reaction (1)
(enthalpy change) have?
2.6.4 Which reaction condition did Thobeka change? (1)
[22]
2.4.1

Centre number:
Examination number:
Question 3

Many industries in South Africa rely on sulphuric acid and the compounds it is used
to produce. The large-scale production of sulphuric acid involves the following
equilibrium:

3.1 State Le Chatelier’s principle . (2)


3.2 What does the double arrows in the above reaction represent? (1)
3.3 Give a reason for your answer in 3.2 (1)
3.4 Is the forward reaction endothermic or exothermic. (1)
3.5 Give reason for your answer in 3.4 (1)
3.6 How will each of the following changes affect the yield of SO 3 (g) at
equilibrium?
Choose from INCREASES, DECREASES and REMAINS THE SAME. Explain
by using Le Chatelier’s Principle.
3.6.1 An increase in pressure by decreasing the volume. (3)
3.6.2 An increase in temperature. (3)
3.6.3 Sulphur dioxide is removed (3)
3.7 In a laboratory experiment, 5 mol SO2 and 3 mol O2 are sealed in a 2 dm3
container. The graph below shows how the number of moles of reactants and
products change over a 15-minute period.

3.7.1 After 5 minutes, the concentration of oxygen gas in the container was (7)
found to be 0,9 mol.dm-3.
Calculate the value of Kc between 5 and 10 minutes.
3.7.2 What disturbance occurred at t = 10 minutes? (1)
3.7.3 How does the disturbance at t = 10 minutes affect the value of Kc? (1)
3.8 Write down only INCREASES or DECREASES or NO CHANGE.
After 12 minutes the following sketch graph of reaction rate against time is
obtained for the equilibrium mixture.
3.9 A catalyst is added to the equilibrium mixture at time 15 minutes. Redraw the (2)
graph above in your ANSWER BOOK. On the same set of axes, complete the
graph showing the effect of the catalyst on the
reaction rates

Day 5
QUESTION 1
MCQ
1.1 Consider the reversible reaction represented below: (2)

The correct conjugate acid-base pair is


A CH3 COO- and H2O
B CH3 COOH and OH-
C CH3 COOH and CHCOO-
D CH3 COOH and H2O
1.2 If the concentration of a sulphuric acid solution is 1 × 10-3 mol.dm-3, (2)
what will the pH and [OH-] of the solution be respectively.

Emphasize
relationship

between H
and [Hot] as
1.3 Consider the equation below:

well as The reactant A represents a/an:


A base having the formula HSO4-
B acid having the formula HSO4-
pH and[OH]
C base having the formula SO42-
D acid having the formula SO42-
[2]

STRENGTH Resulting
STREGTI
OF
OF PH
ACID
BASE
Methy orange Strong weak 27

Bromothyma Strong strong - 7

Phenolphtha weak Strong > 7


Question 2

Consider the following balanced chemical equations showing some


it reactions important to acid and base chemistry.

"a"
'ta't#¥."
Below is a table of common indicators, together with the ranges of
pH in which the colour change takes place.
Emphasie
when each
methyl
Indicator
orangeat is used
2.1 Define base in terms of Lowry Bronsted. (2)
2.2 Identify Lowry Bronsted base from the above equations. Write the (2)
is Red formula only
2.2 Consider all of the chemical equations (A to D) above

pH 231 2.2.1 Define the term ampholyte /AMPHOTERIC SUBSTANCE (2)


2.2.2 Write the formula of a chemical species (other than H2O) that (1)
is amphoteric.
2.2.3 Write the formula for the conjugate acid of this species. (2)
2.3 Write the name of a suitable indicator that will be used for reaction A. (1)
2.4 Give reason for your answer in 2.3 (1)
2.5 Consider reaction D AMMONIUM SALTS ARE THE ONLY
2.5.1 Define hydrolysis ACIDIC SALTS IN 912 (2)
2.5.2 NH4Cℓ is dissolve in water to make a solution. Will the solution (4)
be basic, acidic or neutral. Include any relevant hydrolysis
equations to EXPLAIN your answer. • ANIOUS OF strong acids
2.6 Consider reactions A and B, shown below again.
do not react with +120
_ • cations of metals do
not react with

A 13 g, impure sample of KOH is initially dissolved in 200 cm3 of a 1,2 420


mol·dm−3 nitric acid solution. The nitric acid was in excess.
50 cm3 of the resulting solution was then titrated to neutralization using 23,67 cm 3
of a standard 0,85 mol·dm−3 sodium carbonate solution.
2.6.1 Determine the number of moles of nitric acid that was added to the (4)
KOH.
2.6.2 Define standard solution (2)
2.6.3 Define neutralization point (2)
2.6.4 Calculate the percentage purity of the KOH sample (9)
[34]

B
A take 50cm³

Nails
+ 104 →

+ V= 23,67m³

V -200cm³ V= 50cm³ c = 0,85


⇐ 200cm³
Cf = 2 n-CV
c= 1,2mmol-dm³
B only contains

excess HCl Have

Samec

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