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    09.10.2024 12th Bio Batch Chemistry Solution

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    sakshamkushwaha53

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    09.10.2024 12th Bio Batch Chemistry Solution

    Uploaded by

    sakshamkushwaha53
    2 views5 pages

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    2 views5 pages

    09.10.2024 12th Bio Batch Chemistry Solution

    Uploaded by

    sakshamkushwaha53

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 5

    dr"B's

    Hints and Solution: Li solution


    1.[a] According to Henry's law, partial pressure of gas in the solution is proportional to the mole
    fraction of gas in the solution.
    p=Kut
    Where, K" =11gnry's constant
    Hence, (a) mole fraction is the correct choice.
    z.lal 150 kg = ts' toa g samPle

    450mg = 450x l0-3 g Pollutant

    rnus, ppr = f9llgl' I 06 = 3 ppm


    l5xl0'
    3.[d] 1000 mL solution contains = 0.2 mol HCI
    o'2mol HCI
    1 mL solution contains =
    1000
    0'2
    .. 35.5 mL solution contains = x35.5mol =0.0071moI
    1000

    4.[c]
    5.[a] When solute is added to the solution three cases may arise
    [iJ It dissolves into solution then solution is unsaturated.
    (ii) lt does not dissolve in the solution then solution is known as saturated
    [iii] When solute get precipitated, solution is known as supersaturated solution.
    6.[d] Dissolution of sugar in water will be most rapid, when powdered sugar is dissolved in hot
    water because powder form can easily insert in the vacancies of liquid particles.
    7 .lcl Maximum amount of solid that can be dissolved in a specified amount of a given solvent does
    not depend upon pressure. This is because solid and liquid are highly incompressible and
    practically remain unaffected by change in pressure.
    B.td] Calculate required parameter using formula, MrV = MzVz
    lVhere, V1 =volume ofsolution before dilution
    Vz =volume of solution after dilution
    Mr = strength of solution before dilution
    M2 = strength of solution after dilution
    Give, M1 =0.02M, Y =4L, Mz =2,Y2=5L
    As we know, MrY =MzVz
    0.02x4L=Mzx5L

    1r4.=0'08=o.otoL,t

    Niwas. Near Varanasi. Ph (0542\ 2363455. Website: www.catiee.i


    9.ldl Mole fraction of toluene vapou. = --dlr-
    Pilr + PAIB
    X,r = mole fraction of toluene in solution =0.5

    Is = mole fraction of benzene =0.5

    p? = vapour phase of pure toluene = B0 mm

    p? = vapour phase of pure benzene = 120 mm

    _ 0.5 x 80 _ 0.s(80) _ 80 _ 0.40


    80x0.5+0.5x120 0.5(80+120) 80+120
    10.Ib]
    11.[c]
    12.[c] At equilibrium, the rate of dissolution ofsolid in a volatile liquid solvent is equal to the rate of
    crystallisation.
    L3.[b]
    14.Ib]
    15.[a] Value of Henry's constant (KFr) increases with increase in temperature representing the
    decrease in solubility for 02 and N2.
    16.[b] According to Henry's law, p oc 26 > p = K"1
    As value of Kg rises solubility of gases decreases.
    t7.lal 2lmg =21v19-rg CO2 in l00g H2O

    )tr1n-3
    =-"'-AA mol COr in l00mL H2O(d=lg/mL)

    2lxl0-3 ../ dm-? 2lxl0 .. m- ?


    =
    44 =-mol/
    33
    2L!10
    -mol
    Pco, =Ku xl1o2l =2'937kPam3 mol-lt to1t-: =14'0kPa

    18. [c] Value of Ks depends upon nature of gases dissolved in water.

    Gas Temperature (Kl Ks / kbar


    Ar 29BK 40.3
    coz 29BK L.67

    cH+ 298K 0.4t3


    HCHO 29BK 1.83x l0-s

    So, the order oftheir increasing solubility is


    Ar<CO2 <CH4 <HCHO.
    1e.[b]

    Raman Varanasi. Ph (0542\ 2363455


    20.[c]
    21.[b]
    lo9*60t3=7o,o,nHn
    zz.Lol p=piXA +p61B =4 -
    4
    70 mm (calculatedJ < 75 mm Hg (experimental)
    Thus, there is positive deviation [a) true mixture is more volatile due to decrease bp. Thus (b)
    is true; also force ofattraction is decreased thus (c) is true.
    23.[b]
    24.1d] Both are non-polar solution and do not change the strength of inter-molecular force of
    attraction on mixing.
    25.[b] When boiling point is lower, it means vaporisation is increased, hence vapour phase is greater
    than theoretical value, hence, positive deviation.

    26.lbl ptota =pl1e +pff1" =153a1 +240,?


    JJ

    = 210mm > 200mm (given)

    Observed value oftotal vapour pressure is decreased hence, there is negative deviation.
    27.lal
    28.[a] In pure methanol, molecules are hydrogen bonded. On adding acetone, its molecules get in
    between the host molecules and break some ofthe hydrogen bonds between them. Therefore,
    the intermolecular attractive forces between the solute-solute and solvent-solvent molecules.
    On the other hand, other three remaining options will show negative deviation from Raoult's
    law where the intermolecular attractive forces between the solute-solvent molecules are
    stronger than those between the solute-solute and solvent-solvent molecules.
    29.[d] lf two liquids A and B form minimum boiling azeotrope at some specific composition then A-
    B interactions are weaker than those of A-A and B-8. it is due to the fact that in case of
    positive deviation, we get minimum boiling azeotropes whereas in case of negative deviation
    we get maximum boiling azeotropes.
    30.[d] p=pi,(A +p$rs =pff1t-,(e)+pBxs

    =pi -(pi -pB)rs =120-75rs


    Thus, pf; =120 ton

    +PR-PB=75ton
    : PB = 45 ton
    31.[a] Sucroseisnon-electrolyte.
    Hence, it will not dissociate into ions and as a result there will be no lowering of vapour
    pressure,
    32.[d]
    33.[d]

    Varanasi. Ph (0542 ebsite: www


    34.[a] ATl =1161
    ruuuxw2
    IOOOr
    M(molality) - -l in all cases
    m2wl
    Freezing point = (lb - ATr )
    Smaller the value of ATs, larger the freezing point
    Urea remains undissociated, thus, i=1
    3s.[d]
    36.[c]
    37.[a] According to definition of of depression in freezing point, AT1 = 6rrn
    Where, Kg =freezing point depression constant, value of Kgdepends upon nature of solvent
    This is why although the solution have same molality two different solutions of sucrose of
    same molality prepared in different solvents will have different depression in freezing point.
    38.[a]
    3e.[d] pH=2
    .'. 1H+1=to-2u=cx=x
    .'. i =(l + x) =l + 0.01= l.0l

    40.[a]
    41.[a] r = cRr(i)
    Solutions are isotonic thus, lr cc i
    For CaCl2[i = (l + 2x)] is maximum.
    42.ldl When an unripe mango is placed in a concentrated salt solution to prepare pickle then mango
    loose water due to osmosis and get shrivel.
    a3.[a] According to definition of osmotic pressure we know that n = CRT. For concentrated solution
    C has higher value than dilute solution. Hence, as concentration of solution increases osmotic
    pressure will also increase.
    aa.kl
    45.[d] KCI-..K'+Cl-
    0smosis is a colligative property
    Osmolarity=pslarity xnumber of particles of that solute dissociates into.
    Osmolarity of 0.2 M KCI = 0.2x2 = 0.400 osmol.
    46.[b] NaF

    47.lbl
    48.[a]

    4e.[d]
    so.[dl

    s1.[c]

    s2.[d]

    s3.[b]

    sa.[c] -AT1 ot im a i x moles of solute

    ForKCl; in-2xl-2
    For 2/3 moles ofCaCl2, ixmoles =3x2/3=2
    55.[c] People aHng a lot of salt or salty food experience water retention in tissue cells and intercellular
    spaces because of osmosis, The resulting puffiness or swelling is called edema

    s6.[d]

    57.tbl NCERT Pge 14. Fact


    58.[a] Ethanol and water solution gives positive deviation from Roult's law.
    59.[d] pressure doesnot affect KH
    60.[d]

    *****

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