Antiko 60 SB - ENG - MSDS
Antiko 60 SB - ENG - MSDS
Antiko 60 SB - ENG - MSDS
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use Clear coat for marble and granite. Professional use only.
The product is classified as hazardous pursuant to the provisions set forth in EC Regulation 1272/2008 (CLP) (and subsequent amendments and
supplements). The product thus requires a safety datasheet that complies with the provisions of EC Regulation 1907/2006 and subsequent
amendments.
Any additional information concerning the risks for health and/or the environment are given in sections 11 and 12 of this sheet.
Hazard labelling pursuant to EC Regulation 1272/2008 (CLP) and subsequent amendments and supplements.
Hazard statements:
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SDS: Antiko 60 SB
Precautionary statements:
Contains: TETRACHLOROETHYLENE
On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.
3.2. Mixtures.
Contains:
The full wording of hazard (H) phrases is given in section 16 of the sheet.
EYES: Remove contact lenses, if present. Wash immediately with plenty of water for at least 15 minutes, opening the eyelids fully. If problem
persists, seek medical advice.
SKIN: Remove contaminated clothing. Wash immediately with plenty of water. If irritation persists, get medical advice/attention. Wash
contaminated clothing before using it again.
INHALATION: Remove to open air. In the event of breathing difficulties, get medical advice/attention immediately.
INGESTION: Get medical advice/attention. Induce vomiting only if indicated by the doctor. Never give anything by mouth to an unconscious
person, unless authorised by a doctor.
PROTECTIVE MEASURES FOR THE FIRST RESCUE WORKERS: for PPE (personal protection equipment) required for first aid refer to section
8.2 of this safety data sheet.
4.2. Most important symptoms and effects, both acute and delayed.
For symptoms and effects caused by the contained substances, see chap. 11.
4.3. Indication of any immediate medical attention and special treatment needed.
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GENERAL INFORMATION
Use jets of water to cool the containers to prevent product decomposition and the development of substances potentially hazardous for health.
Always wear full fire prevention gear. Collect extinguishing water to prevent it from draining into the sewer system. Dispose of contaminated water
used for extinction and the remains of the fire according to applicable regulations.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS
Normal fire fighting clothing i.e. fire kit (BS EN 469), gloves (BS EN 659) and boots (HO specification A29 and A30) in combination with self-
contained open circuit positive pressure compressed air breathing apparatus (BS EN 137).
The product must not penetrate into the sewer system or come into contact with surface water or ground water.
Collect the leaked product into a suitable container. Evaluate the compatibility of the container to be used, by checking section 10. Absorb the
remainder with inert absorbent material.
Make sure the leakage site is well aired. Check incompatibility for container material in section 7. Contaminated material should be disposed of in
compliance with the provisions set forth in point 13.
Any information on personal protection and disposal is given in sections 8 and 13.
Before handling the product, consult all the other sections of this material safety data sheet. Avoid leakage of the product into the environment. Do
not eat, drink or smoke during use. Remove any contaminated clothes and personal protective equipment before entering places in which people
eat.
Store only in the original container. Store the containers sealed, in a well ventilated place, away from direct sunlight. Keep containers away from
any incompatible materials, see section 10 for details.
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SDS: Antiko 60 SB
No use other than specified in Section 1.2 of this safety data sheet.
Regulatory References:
TETRACHLOROETHYLENE
Threshold Limit Value.
Type Country TWA/8h STEL/15min
mg/m3 ppm mg/m3 ppm
MAK AUS 345 50 1380 200
VLEP BEL 172 25 695 100
TLV BGR 120 SKIN.
TLV CZE 250 750 SKIN.
AGW DEU 138 20 276 40 SKIN.
TLV DNK 70 10
VLA ESP 172 25 689 100
TLV EST 70 10 170 25
VLEP FRA 138 20 275 40
WEL GRB 345 50 689 100
TLV GRC 335 50 1000 150
GVI HRV 345 50 689 100
AK HUN 50 50 SKIN.
OEL IRL 170 25 678 100
RD LTU 70 10 170 25
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SDS: Antiko 60 SB
RV LVA 10
OEL NLD 138 SKIN.
TLV NOR 40 6 SKIN.
NDS POL 60 480
NPHV SVK 345 50 SKIN.
MAK SWE 70 10 170 25
TLV-ACGIH 170 25 678 100
Predicted no-effect concentration - PNEC.
Normal value in fresh water 0,051 mg/l
Normal value in marine water 0,0051 mg/l
Normal value for fresh water sediment 0,903 mg/kg/d
Normal value for marine water sediment 0,0903 mg/kg/d
Normal value for water, intermittent release 364 mg/l
Normal value of STP microorganisms 11,2 mg/l
Normal value for the terrestrial compartment 0,01 mg/kg/d
Health - Derived no-effect level - DNEL / DMEL
Effects on Effects on
consumers. workers
Route of exposure Acute local Acute systemic Chronic local Chronic Acute local Acute Chronic local Chronic
systemic systemic systemic
Oral. VND 1,3 mg/kg
bw/d
Inhalation. VND 138 mg/m3 VND 34,5 mg/m3 VND 275 mg/m3 VND 138 mg/m3
Skin. VND 23 mg/kg VND 39,4 mg/kg
bw/d bw/d
Legend:
(C) = CEILING ; INHAL = Inhalable Fraction ; RESP = Respirable Fraction ; THORA = Thoracic Fraction.
VND = hazard identified but no DNEL/PNEC available ; NEA = no exposure expected ; NPI = no hazard identified.
TETRACHLOROETHYLENE: Biological Exposure Indices (IBE): tetrachlororoethylene in blood: 0,4 mg/l. Sampling time: before shift.
Tetrachlororoethylene end-expiratory air: 3 ppm. Sampling time: before shift. (ACGIH 2014).
As the use of adequate technical equipment must always take priority over personal protective equipment, make sure that the workplace is well
aired through effective local aspiration. Personal protective equipment must be CE marked, showing that it complies with applicable standards.
HAND PROTECTION
Protect hands with category III work gloves (see standard EN 374).
The following should be considered when choosing work glove material: compatibility, degradation, failure time and permeability.
The work gloves' resistance to chemical agents should be checked before use, as it can be unpredictable. The gloves' wear time depends on the
duration and type of use.
SKIN PROTECTION
Wear category II professional long-sleeved overalls and safety footwear (see Directive 89/686/EEC and standard EN ISO 20344). Wash body with
soap and water after removing protective clothing.
EYE PROTECTION
Wear airtight protective goggles (see standard EN 166).
RESPIRATORY PROTECTION
If the threshold value (e.g. TLV-TWA) is exceeded for the substance or one of the substances present in the product, use a mask with a type A
filter whose class (1, 2 or 3) must be chosen according to the limit of use concentration. (see standard EN 14387). In the presence of gases or
vapours of various kinds and/or gases or vapours containing particulate (aerosol sprays, fumes, mists, etc.) combined filters are required.
Respiratory protection devices must be used if the technical measures adopted are not suitable for restricting the worker's exposure to the
threshold values considered. The protection provided by masks is in any case limited.
If the substance considered is odourless or its olfactory threshold is higher than the corresponding TLV-TWA and in the case of an emergency,
wear open-circuit compressed air breathing apparatus (in compliance with standard EN 137) or external air-intake breathing apparatus (in
compliance with standard EN 138). For a correct choice of respiratory protection device, see standard EN 529.
The emissions generated by manufacturing processes, including those generated by ventilation equipment, should be checked to ensure
compliance with environmental standards.
Product residues must not be indiscriminately disposed of with waste water or by dumping in waterways.
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Appearance liquid
Colour transparent
Odour aromatic
Odour threshold. 27 ppm (DOW) (TETRACHLOROETHYLENE).
pH. Not applicable.
Melting point / freezing point. -22 °C (101,3 kPa, DOW) (TETRACHLOROETHYLENE).
Initial boiling point. 121 °C (101,3 kPa, DOW) (TETRACHLOROETHYLENE).
Boiling range. Not applicable.
Flash point. > 60 °C.
Evaporation rate 1,5 (butyl acetate = 1) (DOW) (TETRACHLOROETHYLENE).
Flammability (solid, gas) Not applicable.
Lower inflammability limit. Not applicable.
Upper inflammability limit. Not applicable.
Lower explosive limit. Not applicable.
Upper explosive limit. Not applicable.
Vapour pressure. 2,5 kPa (25°C) (TETRACHLOROETHYLENE).
Vapour density 5,76 (air =1) (DOW) (TETRACHLOROETHYLENE).
Relative density. 1,440 Kg/l
Solubility insoluble in water
Partition coefficient: n-octanol/water 2,53 Log Pow (23°C) (TETRACHLOROETHYLENE).
Auto-ignition temperature. No (DOW) (TETRACHLOROETHYLENE).
Decomposition temperature. >150°C (TETRACHLOROETHYLENE).
Viscosity 0,844 mPas (dynamic at 25°C) (TETRACHLOROETHYLENE).
Explosive properties No (DOW) (TETRACHLOROETHYLENE).
Oxidising properties No (DOW) (TETRACHLOROETHYLENE).
10.1. Reactivity.
There are no particular risks of reaction with other substances in normal conditions of use.
TETRACHLOROETHYLENE: incombustable, however it decomposes above 150°C/302°F. Decomposition also occurs due to the action of UV
rays and moisture.
TETRACHLOROETHYLENE: risk of explosion on contact with: alkaline metals, aluminium, alkaline hydroxides, sodium amide. May react violently
on contact with: strong bases, strong oxidising agents, alkaline earth metals, light metals, metal powders and zinc oxide.
None in particular. However the usual precautions used for chemical products should be respected.
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SDS: Antiko 60 SB
TETRACHLOROETHYLENE: hydrogen chloride, phosgene, chlorine, ethane tetrachloride, other toxic chlorine compounds.
TETRACHLOROETHYLENE: has a toxic effect on the central and peripheral nervous system, liver, kidneys and heart. Mucous membranes and
skin are affected by its irritant effect.
ACUTE TOXICITY:
LD50 (Oral).3005 mg/kg Rat (Equivalent or similar to OECD Guideline 401)
LC50 (Inhalation).3786 ppm/4h Rat (Equivalent or similar to OECD Guideline 403)
SKIN CORROSION/IRRITATION: Causes skin irritation. (Rabbit, OECD Guideline 404)
SERIOUS EYE DAMAGE/IRRITATION: Causes eyes irritation (Annex VI, REGULATION (EC) No 1272/2008)
RESPIRATORY OR SKIN SENSITISATION: sensitizing weak (mouse, OECD Guideline 429, GLP)
GERM CELL MUTAGENICITY: negative, (Mouse, test in vivo, Equivalent or similar to OECD Guideline 474)
CARCINOGENICITY: LOAEC = 100 ppm (Mouse, Equivalent or similar to OECD Guideline 451)
REPRODUCTIVE TOXICITY: NOAEL = 100 ppm (parental systemic toxicity), NOAEL = 1000 ppm (effects on fertility), NOAEL = 100 ppm
(development toxicity) (Rat, EPA OTS 798.4700, GLP)
STOT-SINGLE EXPOSURE: May cause respiratory irritation. (Annex VI, REGULATION (EC) No 1272/2008)
STOT-REPEATED EXPOSURE:
Oral: LOAEL= 390 mg/kg bw/day (Mouse, Publication Environ Health Perspect. 21; 7-16)
Inalation: LOAEC = 200 ppm (Rat, Carcinogenicity study report)
ASPIRATION HAZARD: No data available.
TETRACHLOROETHYLENE
LC50 - for Fish. 5 mg/l/96h Oncorhynchus mykiss (Bulletin of Environmental Contamination and Toxicology 28
(1), 7- 10)
EC50 - for Crustacea. 8,5 mg/l/48h Daphnia magna (ASTM 1980)
EC50 - for Algae / Aquatic Plants. 3,64 mg/l/72h Chlamydomonas reinhardtii (Environmental Science Pollution Research
International 1; 223-228)
Chronic NOEC for Fish. 234 mg/l Jordanella floridae (Archives of Environmental Contamination and Toxicology 20, 94-
102)
Chronic NOEC for Crustacea. 0,51 mg/l Daphnia magna (ASTM Draft No. 4)
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SDS: Antiko 60 SB
TETRACHLOROETHYLENE
Solubility in water. 150 mg/l
NOT rapidly biodegradable.
TETRACHLOROETHYLENE
Partition coefficient: n-octanol/water. 2,53
BCF. 49
TETRACHLOROETHYLENE
Partition coefficient: soil/water. 2,15
On the basis of available data, the product does not contain any PBT or vPvB in percentage greater than 0,1%.
Reuse, when possible. Product residues should be considered special hazardous waste. The hazard level of waste containing this product should
be evaluated according to applicable regulations.
Disposal must be performed through an authorised waste management firm, in compliance with national and local regulations.
Waste transportation may be subject to ADR restrictions.
CONTAMINATED PACKAGING
Contaminated packaging must be recovered or disposed of in compliance with national waste management regulations.
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SDS: Antiko 60 SB
IATA: NO
For Air transport, environmentally hazardous mark is only mandatory for UN 3077 and UN 3082.
ADR / RID: HIN - Kemler: 60 Limited Quantities: 5 L Tunnel restriction code: (E)
Special Provision: -
IMDG: EMS: F-A, S-A Limited Quantities: 5 L
IATA: Cargo: Maximum quantity: 220 L Packaging instructions: 663
Pass.: Maximum quantity: 60 L Packaging instructions: 655
Special Instructions: -
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code.
Restrictions relating to the product or contained substances pursuant to Annex XVII to EC Regulation 1907/2006.
Product.
Point 3. Liquid substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set
out in Annex I to Regulation (EC) No 1272/ 2008:
(a) hazard classes 2.1 to 2.4, 2.6 and 2.7, 2.8 types A and B, 2.9, 2.10, 2.12, 2.13 categories 1 and 2, 2.14
categories 1 and 2, 2.15 types A to F;
(b) hazard classes 3.1 to 3.6, 3.7 adverse effects on sexual function and fertility or on development, 3.8
effects other than narcotic effects, 3.9 and 3.10;
(c) hazard class 4.1;
(d) hazard class 5.1.
None.
None.
None.
None.
None.
Healthcare controls.
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Workers exposed to this chemical agent must not undergo health checks, provided that available risk-assessment data prove that the risks related
to the workers' health and safety are modest and that the 98/24/EC directive is respected.
A chemical safety assessment has been performed for the following contained substances.
TETRACHLOROETHYLENE
LEGEND:
- ADR: European Agreement concerning the carriage of Dangerous goods by Road
- CAS NUMBER: Chemical Abstract Service Number
- CE50: Effective concentration (required to induce a 50% effect)
- CE NUMBER: Identifier in ESIS (European archive of existing substances)
- CLP: EC Regulation 1272/2008
- DNEL: Derived No Effect Level
- EmS: Emergency Schedule
- GHS: Globally Harmonized System of classification and labeling of chemicals
- IATA DGR: International Air Transport Association Dangerous Goods Regulation
- IC50: Immobilization Concentration 50%
- IMDG: International Maritime Code for dangerous goods
- IMO: International Maritime Organization
- INDEX NUMBER: Identifier in Annex VI of CLP
- LC50: Lethal Concentration 50%
- LD50: Lethal dose 50%
- OEL: Occupational Exposure Level
- PBT: Persistent bioaccumulative and toxic as REACH Regulation
- PEC: Predicted environmental Concentration
- PEL: Predicted exposure level
- PNEC: Predicted no effect concentration
- REACH: EC Regulation 1907/2006
- RID: Regulation concerning the international transport of dangerous goods by train
- TLV: Threshold Limit Value
- TLV CEILING: Concentration that should not be exceeded during any time of occupational exposure.
- TWA STEL: Short-term exposure limit
- TWA: Time-weighted average exposure limit
- VOC: Volatile organic Compounds
- vPvB: Very Persistent and very Bioaccumulative as for REACH Regulation
- WGK: Water hazard classes (German).
GENERAL BIBLIOGRAPHY
1. Regulation (EU) 1907/2006 (REACH) of the European Parliament
2. Regulation (EU) 1272/2008 (CLP) of the European Parliament
3. Regulation (EU) 790/2009 (I Atp. CLP) of the European Parliament
4. Regulation (EU) 2015/830 of the European Parliament
5. Regulation (EU) 286/2011 (II Atp. CLP) of the European Parliament
6. Regulation (EU) 618/2012 (III Atp. CLP) of the European Parliament
7. Regulation (EU) 487/2013 (IV Atp. CLP) of the European Parliament
8. Regulation (EU) 944/2013 (V Atp. CLP) of the European Parliament
9. Regulation (EU) 605/2014 (VI Atp. CLP) of the European Parliament
- The Merck Index. - 10th Edition
- Handling Chemical Safety
- INRS - Fiche Toxicologique (toxicological sheet)
- Patty - Industrial Hygiene and Toxicology
KLINDEX srl S.S. 05 Tiburtina Valeria km 209+200 Manoppello (PE) Italy Tel. +39 085 859 546
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SDS: Antiko 60 SB
KLINDEX srl S.S. 05 Tiburtina Valeria km 209+200 Manoppello (PE) Italy Tel. +39 085 859 546
Fax +39 085 8599 224 Registro AEE: IT08030000004548 web: www.klindex.it
Last update March 2016 11