SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Product name : SYNPERONIC A9-LQ-(TH)

Registered Product Identity : SYNPERONIC A9

CAS-No. : 68131-39-5

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Surfactant
stance/Mixture

1.3 Details of the supplier of the safety data sheet

Company : Croda Europe Limited
Cowick Hall
Snaith
Goole
DN14 9AA
East Riding of Yorkshire
GB

Telephone : +441405860551

Telefax : +441405860205

E-mail address : [email protected]

1.4 Emergency telephone number
Emergency telephone number : USA: 24 Hour Emergency Response Information CHEMTREC
toll free: 1-800-424-9300; direct/international: 1-703-527-3887.
CANADA: CANUTEC 1-888-CAN-UTEC (226-8832), 613-996-
6666 or *666. EUROPE: 00 32 3575 5555. ASIA PACIFIC -
excl. China: +65 6542-9595. CHINA: +86 816-635 2206.
AUSTRALIA: +61 2 7808 3390. SOUTH AFRICA: +32 3 575 55
55. BRASIL:Suatrans 0800 707 7022 / 0800 707 1767. LATAM:
Suatrans (+55) 11 98149-0850 / (+55) 19 3833-5300. INDIA:
+91 22 30948601/2. JAPAN: +65 6542 9595 (24 時間 日本語対
応無料通話, シンガポール). TÜRKIYE: Sağlik Bakanliği Ulusal
Zehir Merkezi - 114

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

Acute toxicity, Category 4 H302: Harmful if swallowed.

Serious eye damage, Category 1 H318: Causes serious eye damage.
Long-term (chronic) aquatic hazard, Cat- H412: Harmful to aquatic life with long lasting ef-
egory 3 fects.
2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :

Signal word : Danger

Hazard statements : H302 Harmful if swallowed.

H318 Causes serious eye damage.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements :
Prevention:
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear eye protection/ face protection.
Response:
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if pre-
sent and easy to do. Continue rinsing. Immediately call a
POISON CENTER/doctor.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumula-
tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher

SECTION 3: Composition/information on ingredients

3.1 Substances
CAS-No. : 68131-39-5

Components
Chemical name CAS-No. Concentration (% w/w)
EC-No.
Alcohols, C12-15, ethox- 68131-39-5 >= 90 - <= 100
ylated

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

SECTION 4: First aid measures

4.1 Description of first aid measures

General advice : Consult a physician.

If inhaled : If breathed in, move person into fresh air.

If symptoms persist, call a physician.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off with soap and plenty of water.
If symptoms persist, call a physician.

In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
Seek medical advice.

If swallowed : If accidentally swallowed obtain immediate medical attention.

4.2 Most important symptoms and effects, both acute and delayed
Symptoms : None known.

4.3 Indication of any immediate medical attention and special treatment needed
Treatment : None known.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Suitable extinguishing media : Use extinguishing measures that are appropriate to local cir-
cumstances and the surrounding environment.
Use water spray, alcohol-resistant foam, dry chemical or car-
bon dioxide.

Unsuitable extinguishing : High volume water jet

media

5.2 Special hazards arising from the substance or mixture

Specific hazards during fire- : Do not use a solid water stream as it may scatter and spread
fighting fire.
Do not allow run-off from fire fighting to enter drains or water
courses.

5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Use personal protective equipment.
Ensure adequate ventilation.

6.2 Environmental precautions

Environmental precautions : Prevent product from entering drains.
If the product contaminates rivers and lakes or drains inform
respective authorities.

6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up and shovel into suitable containers for disposal.

6.4 Reference to other sections

None.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling : Handle in accordance with good industrial hygiene and safety
practice.
Advice on protection against : Normal measures for preventive fire protection.
fire and explosion

Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage : Store in original container. Keep container tightly closed in a
areas and containers dry and well-ventilated place. Containers which are opened
must be carefully resealed and kept upright to prevent leak-
age.

Advice on common storage : No special restrictions on storage with other products.

Further information on stor- : Keep in a dry place. Stable under recommended storage con-
age stability ditions.

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

7.3 Specific end use(s)

Specific use(s) : Surfactant

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Contains no substances with occupational exposure limit values.
8.2 Exposure controls

Personal protective equipment

Eye protection : Tightly fitting safety goggles
Hand protection
Remarks : For prolonged or repeated contact use protective gloves.
Skin and body protection : Impervious clothing
Respiratory protection : In the case of vapour formation use a respirator with an ap-
proved filter.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : viscous liquid
Colour : colourless
Odour : characteristic
Odour Threshold : No data available

pH : 5-8

Melting point : No data available

Boiling point/boiling range : No data available

Flash point : 200 °C

Method: open cup

Evaporation rate : No data available

Flammability (solid, gas) : No data available

Upper explosion limit / Upper : No data available

flammability limit

Lower explosion limit / Lower : No data available

flammability limit

Vapour pressure : No data available

Relative vapour density : No data available

Relative density : 0.99 - 1.05 (30 °C)

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

Density : No data available

Solubility(ies)
Water solubility : not determined
Partition coefficient: n- : No data available
octanol/water
Decomposition temperature : No data available

Viscosity
Viscosity, kinematic : No data available

Explosive properties : Classification Code: No data available

Oxidizing properties : No data available

9.2 Other information

Conductivity : No data available

Oxidizing potential : No data available

Refractive index : No data available

Self-ignition : No data available

SECTION 10: Stability and reactivity

10.1 Reactivity
No data available
10.2 Chemical stability
No data available
10.3 Possibility of hazardous reactions
Hazardous reactions : Stable under recommended storage conditions.

10.4 Conditions to avoid

Conditions to avoid : None known.

10.5 Incompatible materials

Materials to avoid : Strong oxidizing agents

10.6 Hazardous decomposition products

Carbon oxides

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

Product:
Acute oral toxicity : Remarks: Harmful if swallowed.
Information given is based on data obtained from similar sub-
stances.

Acute inhalation toxicity : Remarks: No data available

Acute dermal toxicity : Remarks: No data available

Skin corrosion/irritation

Product:
Remarks : No data available

Serious eye damage/eye irritation

Product:
Remarks : Risk of serious damage to eyes.

Respiratory or skin sensitisation

Product:
Remarks : No data available

Germ cell mutagenicity

Product:
Genotoxicity in vitro : Remarks: No data available

Carcinogenicity

Product:
Test substance : No data available

STOT - single exposure

Product:
Assessment : No data available

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

STOT - repeated exposure

Product:
Assessment : No data available

Aspiration toxicity

Product:
No data available

Further information

Product:
Remarks : No data available

SECTION 12: Ecological information

12.1 Toxicity

Product:
Toxicity to fish : Remarks: No data available

Toxicity to daphnia and other : Remarks: No data available

aquatic invertebrates
12.2 Persistence and degradability

Product:
Biodegradability : Remarks: No data available

12.3 Bioaccumulative potential

Product:
Bioaccumulation : Remarks: No data available

12.4 Mobility in soil

No data available
12.5 Results of PBT and vPvB assessment

Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.

12.6 Other adverse effects

Product:

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

Environmental fate and : No data available

pathways
Additional ecological infor- : No data available
mation

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product : Dispose of product residue in accordance with the instructions
of the person responsible for waste disposal.

Contaminated packaging : Empty remaining contents.

Empty containers should be taken to an approved waste han-
dling site for recycling or disposal.

SECTION 14: Transport information

14.1 UN number
Not regulated as a dangerous good
14.2 UN proper shipping name
Not regulated as a dangerous good
14.3 Transport hazard class(es)
Not regulated as a dangerous good
14.4 Packing group
Not regulated as a dangerous good
14.5 Environmental hazards
Not regulated as a dangerous good
14.6 Special precautions for user
Remarks : Not classified as dangerous in the meaning of transport regu-
lations.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture

The components of this product are reported in the following inventories:

REACH : On the inventory, or in compliance with the inventory, Regis-
tered for import by authorised entities only.

TSCA : On TSCA Inventory

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

DSL : All components of this product are on the Canadian DSL

AICS : On the inventory, or in compliance with the inventory

NZIoC : On the inventory, or in compliance with the inventory

ENCS : On the inventory, or in compliance with the inventory

ISHL : On the inventory, or in compliance with the inventory

KECI : On the inventory, or in compliance with the inventory

PICCS : On the inventory, or in compliance with the inventory

IECSC : On the inventory, or in compliance with the inventory

15.2 Chemical safety assessment

Not required

SECTION 16: Other information

Full text of other abbreviations

ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous
Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regula-
tion; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN
- Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Cana-
da); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - In-
ternational Air Transport Association; IBC - International Code for the Construction and Equip-
ment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentra-
tion; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical
Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Mari-
time Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisa-
tion for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration
to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal
Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not
Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International

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SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006

SYNPERONIC A9-LQ-(TH)

Version Revision Date: Product code: Date of last issue: Print Date :
3.0 09.10.2019 ETT1471 - 15.05.2020
Date of first issue:
09.10.2019

Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature;

SDS - Safety Data Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical
Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Sub-
stances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioac-
cumulative

Further information
Other information : Additions, Deletions, Revisions
Section 2

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

GB / EN

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