Dichtol WFT Macro SD - 1546 - EN

Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

according to Regulation (EU) 2015/830
Article No.: 1546 Dichtol WFT Macro (1546)

Print date: 09.02.2018 Revision date: 23.06.2017 EN
Version: 6.0 Issue date: 23.06.2017 Page 1 / 9
SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. product identifiers
Article No. (manufacturer/supplier) 1546
Identification of the substance or mixture Dichtol WFT Macro (1546)
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses:
Metalimpregnation / capillary-active sealing
1.3. Details of the supplier of the safety data sheet
supplier (manufacturer/importer/downstream user/distributor)
DIAMANT Metallplastic GmbH
Hontzlarstr. 12-14 Telephone: +49(0)2166-98360
41238 Mönchengladbach Telefax: +49(0)2166-83025
Dept. responsible for information:
Lab
E-mail (competent person) [email protected]
1.4. Emergency telephone number
Emergency telephone number +49(0)2166-98360
Only available during office hours.
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 [CLP]
The mixture is classified as hazardous according to regulation (EC) No 1272/2008 [CLP].
Flam. Liq. 3 / H226 Flammable liquids Flammable liquid and vapour.
Skin Irrit. 2 / H315 skin corrosion/irritation Causes skin irritation.
Eye Dam. 1 / H318 Serious eye damage/eye irritation Causes serious eye damage.
STOT SE 3 / H336 Specific target organ toxicity (single May cause drowsiness or dizziness.
exposure)
2.2. Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms
Danger
Hazard statements
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H336 May cause drowsiness or dizziness.
Precautionary statements
P102 Keep out of the reach of children.
P103 Read label before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P333 + P313 If skin irritation or rash occurs: Get medical advice/attention.
P501 Dispose of contents/container to industrial incineration plant.
Safety Data Sheet

contains:
2-methylpropan-1-ol
n-butyl acetate
Supplemental Hazard information (EU)
EUH066 Repeated exposure may cause skin dryness or cracking.
2.3. Other hazards
SECTION 3: Composition / information on ingredients
3.2. Mixtures
Product description / chemical characterization
Description Mixed solvent + polymer mixture
Hazardous ingredients
EC No. REACH No.
CAS No. Chemical name Wt %
INDEX No. classification // Remark
204-658-1 01-2119485493-29-XXXX
123-86-4 n-butyl acetate 50 - 100
607-025-00-1 Flam. Liq. 3 H226 / STOT SE 3 H336
201-148-0 01-2119484609-23-XXXX
78-83-1 2-methylpropan-1-ol 10 - 25
603-108-00-1 Flam. Liq. 3 H226 / STOT SE 3 H335 / Skin Irrit. 2 H315 / Eye Dam. 1
H318 / STOT SE 3 H336
201-872-8 01-2119519223-49-XXXX
80-56-8 2,6,6-Trimethylbicyclo(3.1.1)hept-2-en < 0,5
Acute Tox. 4 H302 / Skin Irrit. 2 H315 / Skin Sens. 1 H317 / Asp. Tox. 1
H304 / Aquatic Chronic 1 H410 (M = 1) / Flam. Liq. 3 H226
Additional information
Full text of classification: see section 16
SECTION 4: First aid measures
4.1. Description of first aid measures
General information
In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness give nothing by mouth,
place in recovery position and seek medical advice.
In case of inhalation
Remove casualty to fresh air and keep warm and at rest. In case of irregular breathing or respiratory arrest provide artificial
respiration.
Following skin contact
Take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of water and soap. Do
not use solvents or thinners.
After eye contact
Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek
medical advice immediately.
After ingestion
If swallowed, rinse mouth with water (only if the person is conscious). Seek medical advice immediately. Keep victim calm.
Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
In all cases of doubt, or when symptoms persist, seek medical advice.
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
alcohol resistant foam, carbon dioxide, Powder, spray mist, (water)
Safety Data Sheet

Extinguishing media which must not be used for safety reasons:

strong water jet
5.2. Special hazards arising from the substance or mixture
Dense black smoke occurs during fire. Inhaling hazardous decomposing products can cause serious health damage.
5.3. Advice for firefighters
Provide a conveniently located respiratory protective device. Cool closed containers that are near the source of the fire. Do
not allow water used to extinguish fire to enter drains, ground or waterways.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Keep away from sources of ignition. Ventilate affected area. Do not breathe vapours.
6.2. Environmental precautions
Do not allow to enter into surface water or drains. If the product contaminates lakes, rivers or sewages, inform competent
authorities in accordance with local regulations.
6.3. Methods and material for containment and cleaning up
Isolate leaked material using non-flammable absorption agent (e.g. sand, earth, vermiculit, diatomaceous earth) and collect it
for disposal in appropriate containers in accordance with the local regulations (see section 13). Clean using cleansing
agents. Do not use solvents.
6.4. Reference to other sections
Observe protective provisions (see chapter 7 and 8).
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Advices on safe handling
Avoid formation of flammable and explosive vapour concentrations in the air and exceeding the exposure limit values. Only
use the material in places where open light, fire and other flammable sources can be kept away. Electrical equipment must
be protected meeting the accepted standard. Product may become electrostatically charged. Provide earthing of containers,
equipment, pumps and ventilation facilities. Anti-static clothing including shoes are recommended. Floors must be electrically
conductive. Keep away from heat sources, sparks and open flames. Use only spark proof tools. Avoid contact with skin, eyes
and clothes. Do not inhale dusts, particulates and spray mist when using this preparation. Avoid respiration of swarf. When
using do not eat, drink or smoke. Personal protection equipment: refer to section 8. Do not empty containers with pressure -
no pressure vessel! Always keep in containers that correspond to the material of the original container. Follow the legal
protection and safety regulations.
Precautions against fire and explosion:
Vapours are heavier than air. Vapours form explosive mixtures with air.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Storage in accordance with the Ordinance on Industrial Safety and Health (BetrSiVO). Keep container tightly closed. Do not
empty containers with pressure - no pressure vessel! Smoking is forbidden. Access only for authorised persons. Store
carefully closed containers upright to prevent any leaks. Soils have to conform to the "Guidelines for avoidance of ignition
hazards due to electrostatic charges (TRBS 2153)".
Hints on joint storage
Keep away from strongly acidic and alkaline materials as well as oxidizers.
Further information on storage conditions
Take care of instructions on label. Store in a well-ventilated and dry room at temperatures between 15 °C and 20 °C. Protect
from heat and direct sunlight. Keep container tightly closed. Remove all sources of ignition. Smoking is forbidden. Access
only for authorised persons. Store carefully closed containers upright to prevent any leaks.
7.3. Specific end use(s)
Observe technical data sheet. Observe instructions for use.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational exposure limit values:
not applicable
Safety Data Sheet

DNEL:
n-butyl acetate
INDEX No. 607-025-00-1 / EC No. 204-658-1 / CAS No. 123-86-4
DNEL acute inhalative (local), Workers: 960 mg/m³
DNEL acute inhalative (systemic), Workers: 960 mg/m³
DNEL long-term inhalative (local), Workers: 480 mg/m³
DNEL long-term inhalative (systemic), Workers: 480 mg/m³
DNEL acute inhalative (local), Consumer: 859,7 mg/m³
DNEL acute inhalative (systemic), Consumer: 859,7 mg/m³
DNEL long-term inhalative (local), Consumer: 102,34 mg/m³
DNEL long-term inhalative (systemic), Consumer: 102,34 mg/m³
2-methylpropan-1-ol
DNEL long-term inhalative (local), Workers: 310 mg/m³
DNEL long-term oral (repeated), Consumer: 25 mg/kg
DNEL long-term inhalative (local), Consumer: 55 mg/m³
2,6,6-Trimethylbicyclo(3.1.1)hept-2-en
EC No. 201-872-8 / CAS No. 80-56-8
DNEL long-term inhalative (systemic), Workers: 5,98 mg/m³
PNEC:
n-butyl acetate
PNEC aquatic, freshwater: 0,18 mg/l
PNEC aquatic, marine water: 0,018 mg/l
PNEC aquatic, intermittent release: 0,36 mg/l
PNEC sediment, freshwater: 0,981 mg/kg
PNEC sediment, marine water: 0,0981 mg/kg
PNEC, Soil: 0,0903 mg/kg
PNEC sewage treatment plant (STP): 35,6 mg/l
2-methylpropan-1-ol
PNEC aquatic, freshwater: 0,4 mg/l
PNEC aquatic, intermittent release: 11 mg/l
PNEC sewage treatment plant (STP): 10 mg/l
EC No. 201-872-8 / CAS No. 80-56-8
PNEC aquatic, freshwater: 4 mg/l
PNEC sewage treatment plant (STP): 3,26 mg/l
8.2. Exposure controls
Provide good ventilation. This can be achieved with local or room suction. If this should not be sufficient to keep aerosol and
solvent vapour concentration below the exposure limit values, a suitable respiratory protection must be used.
Occupational exposure controls
Respiratory protection
If concentration of solvents is beyond the occupational exposure limit values, approved and suitable respiratory protection
must be used. Observe the wear time limits according GefStoffV in combination with the rules for using respiratory protection
apparatus (BGR 190). Use only respiratory protection equipment with CE-symbol including four digit test number.
Hand protection
For prolonged or repeated handling the following glove material must be used: Nitrile rubber or butyl rubber
Thickness of the glove material > 0,4 mm ; Breakthrough time (maximum wearing time) > 480 min.
Observe the instructions and details for use, storage, maintenance and replacement provided by the protective glove
Safety Data Sheet

manufacturer. Penetration time of glove material depending on intensity and duration of exposure to skin. Recommended
glove articles DIN EN 374
Barrier creams can help protecting exposed skin areas. In no case should they be used after contact.
Eye protection
Wear closely fitting protective glasses in case of splashes.
Protective clothing
Wear antistatic clothing of natural fibers (cotton) or heat resistant synthetic fibers.
Protective measures
After contact clean skin thoroughly with water and soap or use appropriate cleanser.
Environmental exposure controls
Do not allow to enter into surface water or drains. See chapter 7. No additional measures necessary.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance:
Physical state: liquid
Colour: refer to label
Odour: characteristic
Odour threshold: not applicable
pH at 20 °C: not applicable
Melting point/freezing point: not applicable
Initial boiling point and boiling range: not applicable
Flash point: 24 °C
Method: DIN 53213-1 (08/2002: replaced by EN ISO 1523)
Evaporation rate: not applicable
Flammability (solid, gas):
burning time (s): not applicable
Upper/lower flammability or explosive limits:
Lower explosion limit: 1,7 Vol-%
Upper explosion limit: 11 Vol-%
Source: 2-methylpropan-1-ol
Vapour pressure at 20 °C: 1,77 mbar
Vapour density: not applicable
Relative density:
Density at 20 °C: 0,90 g/cm³
Solubility(ies):
Water solubility (g/L) at 20 °C: insoluble
Partition coefficient: n-octanol/water: see section 12
Auto-ignition temperature: 370 °C
Source: n-butyl acetate
Decomposition temperature: not applicable
Viscosity at 20 °C: 20 s 4 mm
Method: DIN 53211
Explosive properties: not applicable
Oxidising properties: not applicable
9.2. Other information
Solid content (%): 24,80 Wt %
solvent content:
Organic solvents: 75 Wt %
Water: 0 Wt %
SECTION 10: Stability and reactivity
Safety Data Sheet

10.1. Reactivity
10.2. Chemical stability
Stable when applying the recommended regulations for storage and handling. Further information on correct storage: refer to
chapter 7.
10.3. Possibility of hazardous reactions
Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
10.4. Conditions to avoid
Hazardous decomposition byproducts may form with exposure to high temperatures.
10.5. Incompatible materials
10.6. Hazardous decomposition products
Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
smoke, nitrogen oxides.
SECTION 11: Toxicological information
No data on preparation itself available.
11.1. Information on toxicological effects
Acute toxicity
n-butyl acetate
oral, LD50, Rat: 10760 mg/kg
dermal, LD50, Rabbit: > 14112 mg/kg
inhalative (vapours), LC50, Rat: 23,4 mg/l (4 h)
2-methylpropan-1-ol
oral, LD50, Rat: > 2830 mg/kg
dermal, LD50, Rabbit: > 2000 mg/kg
inhalative (vapours), LC50, Rat: 24,6 mg/l (4 h)
oral, LD50, Rat: 500 mg/kg
Method: OECD 423
skin corrosion/irritation; Serious eye damage/eye irritation
n-butyl acetate
Skin, OECD 404, Rabbit (4 h): evaluation Not an irritant.
eyes, OECD 405, Rabbit (4 h): evaluation Not an irritant.
2-methylpropan-1-ol
Skin, OECD 404, Rabbit (4 h)
skin corrosion/irritation
eyes, OECD 405, Rabbit (4 h)
Respiratory or skin sensitisation
n-butyl acetate
Skin, OECD 406, Guinea pig: ; evaluation not sensitising.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
n-butyl acetate
Germ cell mutagenicity; evaluation Ames test negative.
Method: Ames test
Specific target organ toxicity
Toxicological data are not available.
Aspiration hazard
Practical experience/human evidence
Other observations:
Inhaling of solvent components above the MWC-value can lead to health damage, e.g. irritation of the mucous membrane
and respiratory organs, as well as damage to the liver, kidneys and the central nerve system. Indications for this are:
headache, dizziness, fatigue, amyosthenia, drowsiness, in serious cases: unconsciousness. Solvents may cause some of the
Safety Data Sheet

aforementioned effects through skin resorption. Repeated or prolonged contact with the preparation may cause removal of
natural fat from the skin resulting in non-allergic contact dermatitis and/or absorption through skin. Splashing may cause eye
irritation and reversible damage.
Overall Assessment on CMR properties
The ingredients in this mixture do not meet the criteria for classification as CMR category 1A or 1B according to CLP.
SECTION 12: Ecological information
overall evaluation
There is no information available on the preparation itself .
Do not allow to enter into surface water or drains.
12.1. Toxicity
n-butyl acetate
Fish toxicity, LC50, Pimephales promelas (fathead minnow): 18 mg/l (96 h)
Daphnia toxicity, EC50, Daphnia magna: 44 mg/l (48 h)
Algae toxicity, ErC50, Scenedesmus subspicatus: 647,7 mg/l (72 h)
2-methylpropan-1-ol
Fish toxicity, LC50, Pimephales promelas (fathead minnow): 1430 mg/l (96 h)
Daphnia toxicity, EC50, Daphnia magna (Big water flea): 1100 mg/l (48 h)
Algae toxicity, ErC50, Pseudokirchneriella subcapitata: 1799 mg/l (72 h)
Daphnia toxicity, EC50, Daphnia magna (Big water flea): 0,475 mg/l (48 h)
Algae toxicity, ErC50, Pseudokirchneriella subcapitata: 0,247 mg/l (72 h)
Long-term Ecotoxicity
Fish toxicity, LC50, Pimephales promelas (fathead minnow): 0,28 mg/l (96 h)
Daphnia toxicity, EC50, Daphnia magna (Big water flea): 41 mg/l (48 h)
12.2. Persistence and degradability
12.3. Bioaccumulative potential
Partition coefficient: n-octanol/water: 4,1
12.4. Mobility in soil
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Appropriate disposal / Product
Recommendation
Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste
disposal according to directive 2008/98/EC, covering waste and dangerous waste.
List of proposed waste codes/waste designations in accordance with EWC
080111 waste paint and varnish containing organic solvents or
other dangerous substances
packaging
Recommendation
Non-contaminated packages may be recycled. Vessels not properly emptied are special waste.
SECTION 14: Transport information
14.1. UN number
UN 1263
Safety Data Sheet

14.2. UN proper shipping name

Land transport (ADR/RID): Paint
Sea transport (IMDG): PAINT
Air transport (ICAO-TI / IATA-DGR): Paint
14.3. Transport hazard class(es)
3
14.4. Packing group
III
14.5. Environmental hazards
Land transport (ADR/RID) not applicable
Marine pollutant not applicable
14.6. Special precautions for user
Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in
case of an accident or leakage.
Advices on safe handling: see parts 6 - 8
Further information
Land transport (ADR/RID)

tunnel restriction code D/E
Sea transport (IMDG)
EmS-No. F-E, S-E
Air transport (ICAO-TI / IATA-DGR)
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation
Directive 2010/75/EU on industrial emissions
VOC-value (in g/L): 672
National regulations
Restrictions of occupation
Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC).
15.2. Chemical Safety Assessment
For the following substances of this preparation a chemical safety assessment has been carried out:
EC No. Chemical name REACH No.
CAS No.
204-658-1 n-butyl acetate 01-2119485493-29-XXXX
123-86-4
201-148-0 2-methylpropan-1-ol 01-2119484609-23-XXXX
78-83-1
201-872-8 2,6,6-Trimethylbicyclo(3.1.1)hept-2-en 01-2119519223-49-XXXX
80-56-8
SECTION 16: Other information
Full text of classification in section 3:
Flam. Liq. 3 / H226 Flammable liquids Flammable liquid and vapour.
STOT SE 3 / H336 Specific target organ toxicity (single May cause drowsiness or dizziness.
exposure)
STOT SE 3 / H335 Specific target organ toxicity (single May cause respiratory irritation.
exposure)
Skin Irrit. 2 / H315 skin corrosion/irritation Causes skin irritation.
Eye Dam. 1 / H318 Serious eye damage/eye irritation Causes serious eye damage.
Safety Data Sheet

Acute Tox. 4 / H302 Acute toxicity (oral) Harmful if swallowed.

Skin Sens. 1 / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
Asp. Tox. 1 / H304 Aspiration hazard May be fatal if swallowed and enters airways.
Aquatic Chronic 1 / H410 Hazardous to the aquatic environment Very toxic to aquatic life with long lasting
effects.
Abbreviations and acronyms
For abbreviations and acronyms, see: ECHA Guidance on information requirements and chemical safety assessment,
chapter R.20 (Table of terms and abbreviations).
Further information
The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations. Without written approval, the product must not be used for purposes different from those mentioned in
chapter 1. It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules
and regulations. The details in this safety data sheet describe the safety requirements of our product and are not to be
regarded as guaranteed attributes of the product.

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Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Article No.: 1546 Dichtol WFT Macro (1546)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

SECTION 2: Hazards identification

Article No.: 1546 Dichtol WFT Macro (1546)

Article No.: 1546 Dichtol WFT Macro (1546)

Extinguishing media which must not be used for safety reasons:

Article No.: 1546 Dichtol WFT Macro (1546)

Article No.: 1546 Dichtol WFT Macro (1546)

Article No.: 1546 Dichtol WFT Macro (1546)

Article No.: 1546 Dichtol WFT Macro (1546)

Article No.: 1546 Dichtol WFT Macro (1546)

14.2. UN proper shipping name

Land transport (ADR/RID)

Article No.: 1546 Dichtol WFT Macro (1546)

Acute Tox. 4 / H302 Acute toxicity (oral) Harmful if swallowed.

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