Aspirmatic Safety Data Sheet

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
aspirmatic® No Change Service!

Version Revision Date: Date of last issue: 08.02.2017
02.03 28.11.2018 Date of first issue: 07.01.2002
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Trade name : aspirmatic®
1.2 Relevant identified uses of the substance or mixture and uses advised against
Use of the Sub- : Disinfectants
stance/Mixture
Recommended restrictions : Restricted to professional users.

on use
1.3 Details of the supplier of the safety data sheet

Manufacturer/ Supplier : Schülke & Mayr GmbH
Robert-Koch-Str. 2
22851 Norderstedt
Germany
Telephone: +49 (0)40/ 52100-0
Telefax: +49 (0)40/ 52100318
[email protected]
www.schuelke.com
E-mail address of person : Application Department

responsible for the +49 (0)40/ 521 00 8800
SDS/Contact person [email protected]
(Schülke & Mayr UK Ltd.: +44-1142543500)
1.4 Emergency telephone number

Emergency telephone num- : UK Poisons Emergency number: 0870 600 6266
ber
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification (REGULATION (EC) No 1272/2008)

Skin corrosion, Sub-category 1B H314: Causes severe skin burns and eye damage.
Serious eye damage, Category 1 H318: Causes serious eye damage.
2.2 Label elements
Labelling (REGULATION (EC) No 1272/2008)

Hazard pictograms :
Signal word : Danger
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SAFETY DATA SHEET

Hazard statements : H314 Causes severe skin burns and eye damage.
Precautionary statements : P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do
NOT induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immedi-
ately all contaminated clothing. Rinse skin with water or show-
er.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if pre-
sent and easy to do. Continue rinsing. Immediately call a
POISON CENTER/doctor.
P501 Dispose of contents/ container to an approved waste
disposal plant.
Special labelling of certain : Labelling according to Regulation (EC) No. 648/2004: (< 5 %
mixtures non-ionic surfactants, < 5% soap, perfumes)
2.3 Other hazards

This substance/mixture contains no components considered to be either persistent, bioaccumula-
tive and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or
higher.
No special risks known.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Chemical nature : Solution of the following substances with harmless additives.
Components
Chemical name CAS-No. Classification Concentration
EC-No. (% w/w)
Index-No.
Registration number
Dimethyldioctylammonium chlo- 5538-94-3 Acute Tox. 4; H302 5- 8
ride 226-901-0 Skin Corr. 1B; H314
--- Aquatic Acute 1;
--- H400; M = 1
Ethanol 64-17-5 Flam. Liq. 2; H225 <5

200-578-6 Eye Irrit. 2; H319
603-002-00-5
01-2119457610-43-
XXXX
Alcohol alkoxylated 68551-13-3 Aquatic Acute 1; <1
--- H400
---
---
For explanation of abbreviations see section 16.

SAFETY DATA SHEET

SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : Take off all contaminated clothing immediately.
In case of skin contact : Wash off immediately with plenty of water.

If symptoms persist, call a physician.
In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
If eye irritation persists, consult a specialist.
If swallowed : Do NOT induce vomiting.

Drink water as a precaution.
If symptoms persist, call a physician.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : Treat symptomatically.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : For specialist advice physicians should contact the Poisons
Information Service.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Dry powder
Foam
Water spray jet
Carbon dioxide (CO2)
Unsuitable extinguishing : Do not use a solid water stream as it may scatter and spread
media fire.
5.2 Special hazards arising from the substance or mixture

Specific hazards during fire- : No information available.
fighting
5.3 Advice for firefighters

Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for firefighters

SAFETY DATA SHEET

SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Increased risk of slipping in the presence of leaked / spilled
product.
Use personal protective equipment.
6.2 Environmental precautions

Environmental precautions : Avoid subsoil penetration.
6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Wipe up with absorbent material (e.g. cloth, fleece).
Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
6.4 Reference to other sections

see Section 8 + 13
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Prepare the working solution as given on the label(s) and/or
the user instructions.
Advice on protection against : No special protective measures against fire required.

fire and explosion
Hygiene measures : Keep away from food and drink.
7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage : Recommended storage temperature: 5 - 25°C
areas and containers
Further information on stor- : Keep away from heat. Keep container tightly closed.
age conditions
Advice on common storage : No materials to be especially mentioned.
7.3 Specific end use(s)

Specific use(s) : none

SAFETY DATA SHEET

SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:

Substance name End Use Exposure routes Potential health ef- Value
fects
Ethanol Workers Inhalation Acute effects, Local 1900 mg/m3
effects
Workers Skin contact Chronic effects 343 mg/kg
Workers Inhalation Chronic effects 950 mg/m3
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:

Substance name Environmental Compartment Value
Ethanol Fresh water 0,96 mg/l
Marine water 0,79 mg/l
Fresh water sediment 3,6 mg/kg
Soil 0,63 mg/kg
8.2 Exposure controls
Personal protective equipment

Eye protection : Safety glasses with side-shields conforming to EN166
Hand protection
Directive : The selected protective gloves have to satisfy the specifica-
tions of Regulation (EU) 2016/425 and the standard EN 374
derived from it.
Remarks : Splash protection: disposable nitrile rubber gloves e.g.

Dermatril (layer thickness: 0.11 mm) made by KCL or gloves
from other manufacturers offering the same protec-
tion.Prolonged contact: Nitrile rubber gloves e.g. Camatril
(>480 Min., layer thickness: 0,40 mm) or butyl rubber gloves
e.g. Butoject (>480 Min., layer thickness: 0,70 mm) made by
KCL or gloves from other manufacturers offering the same
protection.
Protective measures : Avoid contact with skin and eyes.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : liquid
Colour : blue
Odour : odourized
Odour Threshold : not determined

SAFETY DATA SHEET

pH : 6,5 - 7,5 (20 °C)
Melting point/freezing point : ca. 0 °C
Decomposition temperature Not applicable
Boiling point/boiling range : ca. 100 °C
Flash point : Not applicable
Evaporation rate : No data available
Flammability (solid, gas) : Not applicable

Upper explosion limit / Upper : No data available
flammability limit
Lower explosion limit / Lower : No data available

flammability limit
Vapour pressure : No data available
Vapour density : No data available
Relative density : ca. 0,99 g/cm3 (20 °C)
Solubility(ies)
Water solubility : in all proportions (20 °C)
Partition coefficient: n- : Not applicable

octanol/water
Auto-ignition temperature : No data available
Viscosity
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2 Other information

No data available
SECTION 10: Stability and reactivity
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
The product is chemically stable.
10.3 Possibility of hazardous reactions
Hazardous reactions : None reasonably foreseeable.

SAFETY DATA SHEET

10.4 Conditions to avoid

Conditions to avoid : Protect from frost, heat and sunlight.
10.5 Incompatible materials

Materials to avoid : None reasonably foreseeable.
10.6 Hazardous decomposition products

None reasonably foreseeable.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate: > 5.000 mg/kg
Acute inhalation toxicity : Acute toxicity estimate: > 50 mg/l
Acute dermal toxicity : Acute toxicity estimate: > 15.000 mg/kg
Components:
Dimethyldioctylammonium chloride:
Acute oral toxicity : LD50 (Rat): 200 - 2.000 mg/kg
Acute inhalation toxicity : Remarks: No data available
Acute dermal toxicity : Remarks: No data available
Ethanol:
Acute oral toxicity : LD50 (Mouse): 8.300 mg/kg
Acute inhalation toxicity : LC50 (Mouse): 39 mg/l

Exposure time: 4 h
Acute dermal toxicity : LD50 (Rabbit): 20.000 mg/kg
Alcohol alkoxylated:
Acute oral toxicity : (Rat): > 5.000 mg/kg
Acute inhalation toxicity : Remarks: No data available
Acute dermal toxicity : Remarks: No data available
Skin corrosion/irritation
Product:
Assessment : Causes severe skin burns and eye damage.
SAFETY DATA SHEET

Method : Calculation method
Components:
Species : Rabbit
Exposure time : 24 h
Result : Corrosive
Ethanol:
Species : Rabbit
Result : No skin irritation
Species : Rabbit
Result : slight irritation
Serious eye damage/eye irritation
Product:
Assessment : Causes serious eye damage.
Method : Calculation method
Components:
Species : Rabbit
Result : Corrosive
Ethanol:
Species : Rabbit
Assessment : Causes serious eye irritation.
Method : OECD Test Guideline 405
Species : Rabbit
Result : Moderate eye irritation
Respiratory or skin sensitisation
Components:
Remarks : No data available
Ethanol:
Test Type : Maximisation Test
Species : Guinea pig
Result : Did not cause sensitisation on laboratory animals.
SAFETY DATA SHEET

Germ cell mutagenicity
Components:
Germ cell mutagenicity- As- : No data available
sessment
Ethanol:
Genotoxicity in vitro : Method: OECD Test Guideline 471
Result: Not mutagenic in Ames Test
Genotoxicity in vivo : Remarks: Non mutagenic
Germ cell mutagenicity- As- : Tests on bacterial or mammalian cell cultures did not show
sessment mutagenic effects.
Germ cell mutagenicity- As- : No data available
sessment
Carcinogenicity
Components:
Carcinogenicity - Assess- : No data available
ment
Ethanol:
Carcinogenicity - Assess- : Did not show carcinogenic effects in animal experiments.
ment
Carcinogenicity - Assess- : No data available
ment
Reproductive toxicity
Components:
Reproductive toxicity - As- : No data available
sessment

SAFETY DATA SHEET

Ethanol:
Effects on foetal develop- : Species: Rat
ment Application Route: Oral
General Toxicity Maternal: NOAEL: 2.000 mg/kg body weight
Reproductive toxicity - As- : In animal testing, risk of impaired fertility was shown only after
sessment administration of very high doses of this substance.
Reproductive toxicity - As- : No data available
sessment
STOT - single exposure
Components:
Ethanol:
STOT - repeated exposure
Components:
Ethanol:
Repeated dose toxicity
Components:
Ethanol:
Species : Rat
NOAEL : 1.730 mg/kg
LOAEL : 3.160 mg/kg
Application Route : Oral
Exposure time : 90 d

SAFETY DATA SHEET

Aspiration toxicity
No data available
Further information
Product:
Remarks : No data is available on the product itself.
SECTION 12: Ecological information
12.1 Toxicity
Product:
Toxicity to microorganisms : EC50 : 520 mg/l
Method: OECD 209
Components:
Toxicity to fish : LC50 (Oncorhynchus mykiss): 0,35 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : Remarks: No data available

aquatic invertebrates
Toxicity to algae : Remarks: No data available
M-Factor (Acute aquatic tox- : 1

icity)
Ethanol:
Toxicity to fish : LC50 (Leuciscus idus (Golden orfe)): 8.140 mg/l
Exposure time: 48 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 5.000 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : IC50 (Scenedesmus quadricauda (Green algae)): > 100 mg/l
Exposure time: 72 h
Toxicity to fish : LC50 (Oncorhynchus mykiss): 0,61 - 0,75 mg/l
Exposure time: 96 h
Test Type: static test
Toxicity to daphnia and other : EC50 (Daphnia magna): 0,17 - 0,25 mg/l
aquatic invertebrates Exposure time: 48 h
Test Type: static test
Toxicity to microorganisms :
Remarks: No data available
SAFETY DATA SHEET

12.2 Persistence and degradability
Product:
Biodegradability : Result: Readily biodegradable.
Method: OECD 301D / EEC 84/449 C6
Chemical Oxygen Demand : ca. 2.630 mg/l

(COD) Test substance: 1 % solution
Components:
Biodegradability : Result: Biodegradable
Ethanol:
Biodegradability : Result: Readily biodegradable.
12.3 Bioaccumulative potential
Components:
Bioaccumulation : Remarks: No data available
Ethanol:
Bioaccumulation : Remarks: Bioaccumulation is unlikely.
Partition coefficient: n- : log Pow: -0,14

octanol/water Method: Calculated value
Bioaccumulation : Remarks: No data available
12.4 Mobility in soil
Components:
Mobility : Remarks: No data available
Ethanol:

SAFETY DATA SHEET

12.5 Results of PBT and vPvB assessment
Product:
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..
12.6 Other adverse effects
Product:
Additional ecological infor- : No data is available on the product itself.
mation
SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : Dispose of the product according to the defined EWC (Euro-
pean Waste Code) No.
Contaminated packaging : Take empty packaging to the recycling plant.
Waste key for the unused : European waste catalog (EWC) 070601
product
Waste key for the unused : Waste material of HZVA from fats, lubricants, soaps, deter-
product(Group) gents, disinfectants and personal protection products.
SECTION 14: Transport information
14.1 UN number
IMDG : UN 1903
IATA : UN 1903
14.2 UN proper shipping name
IMDG : DISINFECTANT, LIQUID, CORROSIVE, N.O.S.

(Dimethyldioctylammonium chloride)
IATA : DISINFECTANT, LIQUID, CORROSIVE, N.O.S.
(Dimethyldioctylammonium chloride)
14.3 Transport hazard class(es)
IMDG : 8
IATA : 8
14.4 Packing group
IMDG
Packing group : III
SAFETY DATA SHEET

Labels : 8
EmS Code : F-A, S-B
IATA (Cargo)
Packing instruction (cargo : 856
aircraft)
Packing group : III
Labels : Corrosive
IATA (Passenger)
Packing group : III
Labels : Corrosive
14.5 Environmental hazards
IMDG
Marine pollutant : no
14.6 Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var-
iations in regional or country regulations.
For personal protection see section 8.
14.7 Transport in bulk according to Annex II of Marpol and the IBC Code
Not applicable for product as supplied.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
REACH - Candidate List of Substances of Very High : Not applicable
Concern for Authorisation (Article 59).
Regulation (EC) No 850/2004 on persistent organic pol- : Not applicable

lutants
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of
major-accident hazards involving dangerous substances.
Not applicable
Volatile organic compounds : Volatile organic compounds (VOC) content: < 5 %

Directive 2010/75/EC on the limitation of emissions of volatile
organic compounds
Other regulations:
Take note of Directive 98/24/EC on the protection of the health and safety of workers from the
risks related to chemical agents at work.
Take note of Directive 2000/39/EC establishing a first list of indicative occupational exposure
limit values.

SAFETY DATA SHEET

15.2 Chemical safety assessment

Exempt
SECTION 16: Other information
Full text of H-Statements

H225 : Highly flammable liquid and vapour.
H302 : Harmful if swallowed.
H314 : Causes severe skin burns and eye damage.
H319 : Causes serious eye irritation.
H400 : Very toxic to aquatic life.
Full text of other abbreviations
Acute Tox. : Acute toxicity
Aquatic Acute : Short-term (acute) aquatic hazard
Eye Irrit. : Eye irritation
Flam. Liq. : Flammable liquids
Skin Corr. : Skin corrosion
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous
Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging Regula-
tion; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN
- Standard of the German Institute for Standardisation; DSL - Domestic Substances List (Cana-
da); ECHA - European Chemicals Agency; EC-Number - European Community number; ECx -
Concentration associated with x% response; ELx - Loading rate associated with x% response;
EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -
Concentration associated with x% growth rate response; GHS - Globally Harmonized System;
GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA - In-
ternational Air Transport Association; IBC - International Code for the Construction and Equip-
ment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory concentra-
tion; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemical
Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International Mari-
time Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Organisa-
tion for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration
to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal
Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. - Not
Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; RID - Regulations concerning the International
Carriage of Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature;
SDS - Safety Data Sheet; SVHC - Substance of Very High Concern; TCSI - Taiwan Chemical
Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic Sub-
stances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very Bioac-
cumulative

SAFETY DATA SHEET

Further information
Classification and procedure used to derive the classification for mixtures according to Regulation
(EC) No. 1272/2008
Skin Corr. 1B, H314 : Calculation method
Eye Dam. 1, H318 : Calculation method
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

aspirmatic® No Change Service!

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

Recommended restrictions : Restricted to professional users.

1.3 Details of the supplier of the safety data sheet

E-mail address of person : Application Department

1.4 Emergency telephone number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Serious eye damage, Category 1 H318: Causes serious eye damage.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)

Signal word : Danger

Z11501 ZSDB_P_ALL EN Page 1/16

aspirmatic® No Change Service!

2.3 Other hazards

SECTION 3: Composition/information on ingredients

Ethanol 64-17-5 Flam. Liq. 2; H225 <5

For explanation of abbreviations see section 16.

aspirmatic® No Change Service!

SECTION 4: First aid measures

4.1 Description of first aid measures

In case of skin contact : Wash off immediately with plenty of water.

If swallowed : Do NOT induce vomiting.

SECTION 5: Firefighting measures

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Z11501 ZSDB_P_ALL EN Page 3/16

aspirmatic® No Change Service!

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on protection against : No special protective measures against fire required.

Hygiene measures : Keep away from food and drink.

7.2 Conditions for safe storage, including any incompatibilities

Advice on common storage : No materials to be especially mentioned.

7.3 Specific end use(s)

Z11501 ZSDB_P_ALL EN Page 4/16

aspirmatic® No Change Service!

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:

Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:

Personal protective equipment

Remarks : Splash protection: disposable nitrile rubber gloves e.g.

Protective measures : Avoid contact with skin and eyes.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Odour Threshold : not determined

Z11501 ZSDB_P_ALL EN Page 5/16

aspirmatic® No Change Service!

pH : 6,5 - 7,5 (20 °C)