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    Tutorial-2024 240305 131855

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    hiepcon1216
    The document contains 10 exercises involving crystal structures, phase diagrams, corrosion rates, and electrochemical cells. The exercises calculate lattice parameters, atomic packing factors, theoretical densities, Miller indices, interplanar spacings, atomic radii, stresses, factors of safety, liquidus and solidus temperatures, compositions of liquid and solid phases, temperatures required for partial melting, weight losses due to corrosion, and electrode potentials.

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    Tutorial-2024 240305 131855

    Uploaded by

    hiepcon1216
    17 views4 pages
    The document contains 10 exercises involving crystal structures, phase diagrams, corrosion rates, and electrochemical cells. The exercises calculate lattice parameters, atomic packing factors, theoretical densities, Miller indices, interplanar spacings, atomic radii, stresses, factors of safety, liquidus and solidus temperatures, compositions of liquid and solid phases, temperatures required for partial melting, weight losses due to corrosion, and electrode potentials.

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    tutorial-2024_240305_131855

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    The document contains 10 exercises involving crystal structures, phase diagrams, corrosion rates, and electrochemical cells. The exercises calculate lattice parameters, atomic packing factors, theoretical densities, Miller indices, interplanar spacings, atomic radii, stresses, factors of safety, liquidus and solidus temperatures, compositions of liquid and solid phases, temperatures required for partial melting, weight losses due to corrosion, and electrode potentials.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    17 views4 pages

    Tutorial-2024 240305 131855

    Uploaded by

    hiepcon1216
    The document contains 10 exercises involving crystal structures, phase diagrams, corrosion rates, and electrochemical cells. The exercises calculate lattice parameters, atomic packing factors, theoretical densities, Miller indices, interplanar spacings, atomic radii, stresses, factors of safety, liquidus and solidus temperatures, compositions of liquid and solid phases, temperatures required for partial melting, weight losses due to corrosion, and electrode potentials.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    Exercises

    1. Indium has a tetragonal unit cell for which the a and c lattice parameters are 0.459 and 0.495
    nm, respectively.

    (a) If the atomic packing factor and atomic radius are 0.693 and 0.1625 nm, respectively,
    determine the number of atoms in each unit cell.

    (b) The atomic weight of indium is 114.82 g/mol; compute its theoretical density.

    2. Determine the indices for the directions shown in the following cubic unit cell:

    3. What are the indices for the two planes drawn in the sketch below?

    4. Determine the Miller indices for the planes shown in the following unit cell:

    1
    5. The metal rhodium has an FCC crystal structure. If the angle of diffraction for the (311) set
    of planes occurs at 36.12 oC (first-order reflection) when monochromatic x-radiation
    having a wavelength of 0.0711 nm is used, compute (a) the interplanar spacing for this set
    of planes, and (b) the atomic radius R for a rhodium atom. (For FCC crystal structure(𝑅 =
    𝑎/2√2), 𝑎 is the lattice parameter.

    6. Two gage marks are placed exactly 250 mm apart on a 12-mm-diameter aluminum rod
    with E = 73 GPa and an ultimate strength of 140 MPa. Knowing that the distance between
    the gage marks is 250.28 mm after a load is applied; determine (a) the stress in the rod,
    (b) the factor of safety.

    7. A lead–tin alloy of composition 30 wt% Sn–70 wt% Pb is slowly heated from a temperature
    of 150o C (300o F).

    (a) At what temperature does the first liquid phase form?

    (b) What is the composition of this liquid phase?

    (c) At what temperature does complete melting of the alloy occur?

    (d) What is the composition of the last solid remaining prior to complete melting?

    2
    8. (use figure in question 7)
    A 2.0-kg specimen of an 85 wt% Pb–15 wt%Sn alloy is heated to 200oC; at this temperature
    it is entirely an α -phase solid solution (Figure 2). The alloy is to be melted to the extent that 50%
    of the specimen is liquid, the remainder being the α phase. This may be accomplished by heating
    the alloy or changing its composition while holding the temperature constant.
    (a) To what temperature must the specimen be heated?

    (b) How much tin must be added to the 2.0-kg specimen at to achieve this state?

    9. A thick steel sheet of area 100 in.2 is exposed to air near the ocean. After a one-year period
    it was found to experience a weight loss of 485 g due to corrosion. To what rate of corrosion, in
    both mpy and mm/yr, does this correspond?

    10. An electrochemical cell is constructed such that on one side a pure Zn electrode is in
    contact with a solution containing Zn2+ ions at a concentration of 10-2 M. The other cell half
    consists of a pure Pb electrode immersed in a solution of Pb2+ ions that has a concentration of 10-
    4 M. At what temperature will the potential between the two electrodes be +0.568 V?

    3
    4

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