Isomers
Isomers
Isomers
(b) Write the structural formula of the chain isomer of this chloroalkane
compound.
(c) Write the structural formula of the position isomer of this chloroalkane.
(d) Which isomers, the one in (b) or (c), has a higher boiling point? Explain your
answer.
3. For each of the following pairs of molecules, state whether they are ‘identical
molecules’, ‘chain isomers’, ‘position isomers’ or ‘functional group isomers’.
(a)
(b)
(c)
(d)
2
4. For each of the following pairs of molecules, state whether they are ‘identical
molecules’, ‘chain isomers’, ‘position isomers’ or ‘functional group isomers’.
(a)
(b)
(c)
(d)
5. Write the structural formulae for all the structural isomers with the molecular
formula of C4H10O.
3
Suggested Answer
1. (a)
(b)
2. (a) 2-chlorobutane
(b)
(c)
The molecules of isomer in (c) are rod-shaped, while the molecules of isomer
in (b) have a spherical shape.
Thus, the van der Waals’ forces between the molecules of isomer in (c) are
stronger and more energy is needed to separate the molecules.
4
5.