51. 58.

52. 59.

53.
60.

54.

55.

61. Among the three isomeric pentanes—pentane,

2-methylbutane, and 2,2-dimethylpropane—
which has the highest boiling point?
a. 2-methylbutane b. Pentane
c. 2,2-dimethylpropane d. All have the same
boiling point
62. Why does 2,2-dimethylpropane have a lower
boiling point compared to pentane?
a. It has stronger intermolecular forces.
b. It has a higher molecular weight.
c. Its spherical shape results in a smaller area of
contact and weaker intermolecular forces.
d. It contains more carbon atoms.
56. 63. What trend is observed in the boiling points of
isomeric pentanes as the number of branched
chains increases?
a. Boiling points increase significantly.
b. Boiling points decrease.
c. Boiling points remain constant.
d. Boiling points fluctuate unpredictably.
At what temperature does 2,2-dimethylpropane
64. boil?
57
a. 309.1 K b. 295.5 K c. 282.5 K d. 310.5
K
65. What type of forces do alkanes primarily
exhibit due to their non-polar nature?
a. Ionic bonds
b. Strong covalent bonds
c. Weak van der Waals forces
d. Hydrogen bonds
66. At 298 K, what physical state are the first four b. To visualize and perceive the three-
members of the alkane series (C₁ to C₄) dimensional shapes of organic molecules.
typically found in? c. To calculate the molecular weight of
a. Liquids b. Gases c. Solids compounds.
d. Aqueous solutions d. To predict the boiling points of substances.
67. Which of the following statements is true 73. In the framework model of molecular
regarding the physical states of alkanes as their representation, what is primarily emphasized?
carbon chain length increases? a. The size of the atoms.
a. All alkanes are gases regardless of size. b. The bonds connecting the atoms.
b. Alkanes with 5 to 17 carbon atoms are c. The electronic configuration of atoms.
always solids. d. The molecular weight of the compound.
c. Alkanes with 18 or more carbon atoms are 74. In the ball-and-stick model, what do the "balls"
generally solids at room temperature. represent?
d. Alkanes become more volatile with a. Bonds between atoms. b. Atoms of the
increasing carbon number. molecule.
68. What is the primary reason for the change in c. Molecular orbitals. d. Electrons in the
physical state of alkanes from gases to liquids molecule.
and solids as the number of carbon atoms 75. Which model emphasizes the relative size of
increases? each atom based on its van der Waals radius?
a. Increased molecular weight leading to a. Framework model b. Ball-and-stick
stronger van der Waals forces. model
b. Increased polarity of the molecules. c. Space-filling model d. Ball-and-spring
c. Presence of functional groups. model
d. Formation of ionic interactions. 76. In the wedge-and-dash representation of
69. When naming a compound with multiple molecules, which of the following accurately
substituents, which rule is applied if there are describes the significance of a dashed wedge?
two chains of equal size? a. It represents a bond lying in the plane of the
a. Choose the chain with the higher molecular paper.
weight. b. It indicates a bond projecting towards the
b. Select the chain that contains the greater observer.
number of side chains. c. It signifies a bond projecting away from the
c. Select the chain with fewer substituents. observer.
d. Choose any chain at random. d. It is used exclusively for double bonds.
70. When two substituents are found in equivalent 77. The bond length of 139 pm in benzene is
positions on a carbon chain, how is the intermediate between which of the following
numbering determined? bond lengths?
a. The lower number is given to the substituent A) 133 pm (C-C double bond) and 154 pm
with the highest molecular weight. (C-C single bond)
b. The lower number is given to the substituent B) 128 pm (C-N bond) and 165 pm (C-H bond)
that comes first in the alphabetical listing. C) 150 pm (C-C bond) and 120 pm (C=C bond)
c. The numbers are assigned randomly. D) 134 pm (C-N single bond) and 152 pm
d. The substituents are not numbered at all. (C-H bond)
71. Why is the numbering of carbon atoms in a 78. What would be expected if any one of the
parent alkane chain done from left to right structures of benzene (A or B) was correct?
when there are branches? A) One type of C-C bond length
a. To maximize the total number of carbon B) Two types of C-C bond lengths
atoms. C) Three types of C-C bond lengths
b. To ensure that branched carbon atoms D) No C-C bond lengths
receive the lowest possible numbers. 79. Which of the following compounds were
c. To follow alphabetical order of the carcinogenic hydrocarbon?
substituents.
d. To simplify the molecular formula.
72. What is the primary purpose of molecular
models?
a. To determine the chemical reactivity of a
molecule.
 b) Siemens per meter (S/m)

c) Coulombs per second (C/s)

d) Ampere per meter (A/m)

84. Molar conductivity of an electrolyte is
maximum at:

a) Infinite dilution.

b) High concentration.

(a) I and II (b) I and III (c) All of these c) Zero dilution.
(d) None of these
80. Write the IUPAC Name of given structure- d) Saturation point.
85. Specific conductance is defined as:

a) The conductance of all ions present in 1

mole of electrolyte.

b) The conductance of an electrolyte solution

contained between two electrodes 1 cm apart
(a) 9, 10-Dimethyl, 3,4-benzanthracene and having 1 cm² area.
(b) 9, 10-Dimethyl, 1,2-benzanthracene
(c) Benzanthracene c) The total number of ions in a solution.
(d) 3- methyl cholanthrene
81. Which data reveals benzene is a planar a planar d) The rate of ion migration.
molecule? 86. The limiting molar conductivity of a solution
(a) X-Ray Diffraction (XRD) (Λ°m) is the molar conductivity at:
(b) U.V. Spectroscopy (U.V)
(c) Cyclovoltammetry (C.V.)
a) Infinite concentration. b) Infinite dilution.
(d) Molecular Orbital Theory (M.O.T.)
82. Which of the following statements is correct
regarding conductivity (κ) and molar c) Zero temperature. d) Maximum voltage.
conductivity (Λm)? 87. A group of compounds having poly benzenoid
structures have been named as __?
(a) Benzalene (c) Kekulenes
(a) Conductivity increases with dilution.
(b) Anthracene (d) Phenalene
88. Due to absence of Pure double bonds in
(b)Molar conductivity decreases with dilution. benzene accounts for the reluctance of benzene
to show which reaction under normal
(c)Conductivity decreases with dilution, while condition?
molar conductivity increases. (a) Elimination reaction (c) Radical reaction
(b)Substitution reaction (d) Addition reaction
(d)Both conductivity and molar conductivity 89. Why does arenium ion lose its Aromatic
decrease with dilution. Character?
(a) Because it has a cyclic structure
(b) Because delocalization of electrons
83. What is the SI unit of conductivity (κ)? stops at SP2 hybridized carbons.
(c) Because it undergoes a resonance
stabilization.
a) Ohm⁻¹ cm² mol⁻¹ (d) Because delocalization of electrons
stops at SP3 hybridized carbons.
90. Which is nonbenzenoid tropone?
 97.

91.

98.

92. 99.

10
0
93.

94.

95.

96.