Sec 8
Sec 8
Sec 8
Course codeCH406
Lecture 8
I-Choose the correct answer:
1. The use of a thermoplastic with a high degree of polymerization makes the
fabrication process more (difficult- easer)
2.Using a polymer with(high-low) MFI is more suitable for the operation of mold
filling process.
3. The (higher-lower ) the MFI , the greater the strength and heat resistance of
the desired plastic.
4.Before (yield elongation-ultimate elongation) point , reversible deformation of
thermoplastic polymer takes place, while (yield elongation – ultimate elongation)
is the total elongation just before fracture.
5.Ductile thermoplastic polymers have a (higher-lower) module of elasticity than
elastomers
6. A brittle material will deform reversibly to a very (small -large ) amount and then
fracture comparing ductile and elastomeric polymers
III- problems:
1.We have a HDPE sample containing :
4000 chains with molecular weights between 0 and 5000 g/mol
8000 chains with molecular weights between 5000 and 10000 g/mol
7000 chains with molecular weights between 10000 and 15000 g/mol
2000 chains with molecular weights between 15000 and 20000 g/mol
Determine the number and weight average molecular weights and the
degree of polymerization
2.Calculate the degree of polymerization if 6,6-nylon has average
number molecular weight of 120000 g/mol
Mwt of hexamethylene amine is 116 g/mol
Mwt of adipic acid is 146 g/mol , Mwt of water is 18
3. The linear polymer 6,6-nylon is prepared by combining 1000 g of
hexamethylene diamine with adipic acid .
How many kilograms of adipic acid are needed , and how much 6,6-
nylon is produced , assuming 95% efficiency.
4.The stress applied to PET wire was 6.37x104 N/m2 and the strain was
3.08x10-4.Find the modulus of elasticity for PET in MPa
5.HDPE cylindrical rod has a radius R of 0.9mm and a length L of 81 cm.
A force F of 6.2x102 N stretches it axially. What is the stress in the rod
in N/m2? And what is the elongation of the rod under this load if the
modulus of elasticity is 1x109 N/m2.