Atomic Structure
Atomic Structure
Atomic Structure
ATOMIC STRUCTURE
SYNOPSIS - 1
INTRODUCTION
1. Matter is made up of small particles.
2. These small particles can be atoms, molecules (or) ions.
3. The words anu and paramany stand for small and very small particles.
4. The idea of finiest unit of matter was proposed by Maharshi Kannada in
Vedic period in our country.
5. John Dalton is 1808 published them of atom assuming that atom are the
ultimate indivisible particles of matter.
The views of Kanad
Way back as the sixth century BC, the Indian philosopher Maharshi Kanad
came forward with the following idea.
Matter is not continuous, and made up of tiny particles, named paramanus.
(In Sanskrit, ‘param’ means ‘final’ or ‘ultimate’, ‘and’ anu means ‘particle’.)
Kanad further said that two or more paramanus combine to form bigger
particles.
The Views of Democritus and Leucippus
In the fifth century BC, the Greek philosophers Democritus and
Leucippus came up with a similar idea.
They thought that on dividing a piece of a substance, one would
ultimately get a particle that could not be divided further.
They gave the name atomos (in Greek, atomos means indivisible)
to these ultimate particles.
Dalton’s Theory
The theories of Kanad as well as of Democritus and Leucippus remained
forgotten for more than two thousand years.
JOHN DALTON
But when experimental chemistry developed, it became necessary to explain
the observed facts.
Exhaust pump
High-voltage source
Cathode rays produced in a discharge tube
The characteristics of cathode rays
Sir J.J.Thomson and others found that cathode rays have the following
characteristics.
Cathode rays was disovered by Crooks
Cathode rays are the stream of electrons
Cathode rays travel in straight lines.
Cathode rays are deflected towards anode
Positive rays have one or more units of +ve charge.
Ex: H the charge is +1
H 2 the charge is +2
The charge and mass of an electron
1. The charge to mass ratio (e/m) of an electron was determined by J.J.Thomson
to be 1.78 × l08 C/g (coulomb per gram).
2. In 1908, R.A.Millikan determined the charge of an electron to be 1.6 ×
10–19 C.or 4.802 1010 esu.
3. THe e/m value of the electron is called its specific charge.
1
4. Electron has a mass of of that of the hydrogen atom.
1836
5. Absolute mass of the electron = 9.11 10 28 grams or 9.11 10 31 kg or 0.0005486
amu.
The Proton
An atom is electrically neutral. But the electrons present in it are negatively
charged particles.
Hence, the atom must also contain some positively charged particles so that
the overall charge on it becomes zero.
These particles should be found in the discharge tube itself, when cathode
rays are formed.
Anode rays
Goldstein repeated the cathode-ray experiment using a perforated cathode.
He observed that there was a glow on the wall opposite the anode.
So, some rays must be travelling in the direction opposite that of the cathode
rays, i.e., from the anode towards the cathode.
These rays were called anode rays or canal rays (as they moved through the
perforations, or canals, in the cathode).
It was found that these rays contained positively charged particles, and so,
J.J.Thomson called them positive rays.
Positive rays Cathode rays Positive Red
from anode from Cathode rays glow
Anode Cathode
High-voltage source
Anode rays
The characteristics of anode rays
Ø Goldstein discovered the protons in an anode ray experiment.
Ø Anode rays are also called as canal rays or positive rays.
Ø They travel in straight lines.
Ø Cause mechanical motion.
Ø Anode rays cause heating effect.
Ø They get deflected both in electric and magnetic filed but in opposite direction
to that deflections caused by cathode ray.
e
Ø The value of anode rays is not constant and depends on the nature of gas
m
inside the discharge tube.
The charge and mass of a proton
Charge
The charge on a proton is the same (1.6 × 10–193) as that on an electron, but
with opposite sign. It is taken as a unit of positive charge. So, a proton has a
unit positive charge, i.e., +1.
Mass
The mass of a proton is the same as that of a hydrogen atom, i.e., 1 amu.
A proton is about 1840 times heavier than an electron. Its absolute mass is
1.67 x 10–24 g (or) 1.67 × 10–27 kg.
The Neutron:
Ø Neutron was discovered by Chadwick.
Ø Neutron is lightly heavier than (about 0.18%) proton.
e
Ø The value of neutron is zero as it does not possess any charge.
m
Ø The discovery of neutrons became late as it does not possess any charge.
WORK SHEET - 1
Comprehension Type
Writeup-1
Atom is no longer indivisible, but consists of neutrons, protons and electrons.
25. The first atomic theory was proposed by:
1) Democritus 2) John Dalton 3) William crookes 4) J.J. Thomson
26. As the number of protons is equal to number of electrons in an atom, there
for it is:
1) Electrically positive 2) Electrically negative
3) Electrically neutral 4) None
VII Class - Chemistry 142
CHEMISTRY ATOMIC STRUCTURE
27. who proposed that matter is made up of extremely small particles called
atoms?
1) Democritus 2) John Dalton 3) Maharshi kanada4) Neil Bohr
Writeup-2
Cathode rays consists of negatively charged material particles called
electrons. These electrons are fundamental sub atomic particles carrying
negative charge and having mass 9.1 × 10–31 kg. Discovered by J.J Thomson.
Charge to mass (e/m) ratio of an electron is 1.76 × 108 C/g. Charge to mass
(e/m) ratio for an proton is 9.55 × 104 C/g.
28. Particles in cathode rays have same charge to mass ratio as:
1) - particles 2) - particles
3) - rays 4) Protons
29. The e/m ratio for proton is:
1) 1.76 × 108 C/g 2) 9.1 × 10–31 kg 3) 9.55 × 104 C/g 4) 9.55 × 104 kg
30. Which of the following particles has maximum charge to mass ratio?
1) Electrons 2) Protons
3) - particles 4) Neutrons
SYNOPSIS - 2
Atomic model: Atomic model depects the systematic arrangement of fundamental
particles in the atom.
Thomsons atomic model:Thomson was the first to propose a detailed model of
the atom.He proposed that an atom consists of a uniform sphere of positive
electricity in which electrons are distributed more or less uniformly.This
model of an atom is known as the ‘plum-pudding model’ or ‘raisin
pudding model’ or ‘water melon model’.This model assumed that mass of
the atom is evently spread over the entire atom.This model could explain the
electrical neutrality of an atom but failed to explain the observations of
Rutherfords -particle scattering experiment.
Positively Electron
Charged
sphere
E
Ø Rutherford also theorised that electrons revolve round the nucleus at large
distances from it.
Ø Rutherford estimated the diameter of the nucleus to be of the order of 10–13
cm and that of the atom to be of the order of 10–8 cm. Thus, the diameter of
the nucleus is about 105(= 1,00,000) times smaller than that of the atom.
Nucleus of atom
- particles
The electrons revolve round the nucleus in their own orbits, just like planets
around the sun in solar system. Hence this theory is also called Rutherford’s
planitary theory of an atom.
Nucleus
(Protons+neutrons)
Electron
WORK SHEET - 2
Comprehension Type
Writeup-1:
According to the classical laws of mechanics or dynamics of physics, any
charged particle revolving around another charged particle should lose energy
continuously.
Hence electron revolving round the nucleus should lose energy and fall
inside the nucleus. But nucleus is found to be stable. Thus Rutherford’s
atomic model does not explain the stability of an atom. It could not explain
the distribution of electrons around the nucleus and does not tell us anything
about their energies. If the electron loses energy continuously, then the
atomic spectra should be continuous but it is discontinuous. Hence It could
not explain the line spectrum.
12. Rutherford atomic model does not obey:
1) Classical laws of electrodynamics. 2) Laws of electrolysis
3) Both 1 and 2 4) None of these
13. Rutherford’s atomic model could not explain.
1) Gaps present in the spectrum 2) Stability of the atom
3) Both 1 and 2 4) None of these
14. In Rutherford’s atomic model one of the defect is:
1) Comparison of atomic model with Solar system.
2) Comparision of atomic model with water melon.
3) Comparision of atomic model with Custard apple.
4) None of these.
Writeup-2:
The first concrete attempt to study the structure of an atom was made by
Rutherford
through his “alpha ray scattering experiment”.
15. Rutherford’s scattering experiments led to the discovery of :
1) Nucleus 2) Presence of neutrons in the nucleus
3) Both 1 and 2 4) Revolving nature of electrons around the
nucleus
16. In Rutherford’s -ray scattering experiment, which of the following does
not happen?
1) Most of the -rays passed through without deflection.
2) A few -particles pass through the nucleus.
3) A few -particles are deflected back.
4) -particles going near the nucleus are slightly deflected.
17. Deflection back of a few particles on hitting thin foil of gold shows that:
1) Nucleus is heavy
2) Nucleus is small
3) Both 1 and 2
4) Electrons create hindrance in the movement of -particles.
SYNOPSIS - 3
Atomic number:
In 1913, H.G.J. Moseley devised an experiment to find out positive change
on the nucleus of an atom. The number of unit positive charges on the
nucleus of an atom of the element is called atomic number of the element.
Atomic number is also equal to the number of electrons in an atom of the
element. Thus atomic number of an element is equal to the number of
protons in the nucleus of its atom or the number of extra nuclear electrons.
Generally, it is denoted by the letter Z.
Atomic number (Z) = Number of protons
= Number of electrons.
Mass number:
Protons and neutrons are collectively called nucleons. Total number of protons
and neutrons in the nucleus is called mass number of the atom. It is generally
represented by the letter A.
Mass number (A) = Number of protons + Number of neutrons
= Number of nucleons.
Isotopes, Isobars and Isotones:
Isotopes of an element are the atoms of the element with same atomic
number but different mass numbers. For example, hydrogen has three
isotopes, protium (H), deuterium (D) and tritium (T). All the three isotopes
have atomic number 1, however, their mass numbers are 1,2 and 3
respe ctively. The three isotope s of carbon are represe nted as
12
6 C, 13
6 C and
14
6 C.
The atoms of different elements which have same mass number are called
14
isobars. For example, 6 C and 14
7 N
are isobars.
Isotones may be defined as the atoms of different elements containing same
number of neutrons.
For example, 13 14
6 C and 7 N
. For isotones, the difference of mass number and
atomic number is same.
Isodiaphers: The atoms of the different elements which contain same number
of A–2Z are Isodiaphers.
Examples: 9F19 and 11Na 23
atom.
Mg – 2e– Mg2+
Therefore, Mg2+ ion has two electrons less than the number of electrons in
Mg atom. Knowing that the atomic number and mass number of Mg are 12
and 24, respectively , the number of electrons, protons and neutrons in Mg2+
ions may be calculated as under:
Number of protons =Atomic number = 12
Number of electrons =Atomic number - 2 = 10
Number of neutrons = Mass numbert - Atomic number
= 24 - 12 = 12.
P + 3e– P3–
Knowing that atomic number of phosphorus is 15 and mass number is 31,
the number of electrons, protons and neutrons in phosphide ion may be
calculated as under:
Number of protons =Atomic number = 15
Number of electrons =Atomic number + 3 = 18
Number of neutrons = Mass numbert - Atomic number
= 31-15 = 16.
SHELLS OF AN ATOM
The electrons revolve around the nucleus of the atom. The actual path the
electron takes while revolving around the nucleus is called its orbit or shell.
The orbit of an electron is the region around the nucleus in which it revolves.
1. The shells closest to the atom in the first shell called K-shell and can
have a maximum of 2 electrons.
2. The shell next to the K-shell is the second shell called the L-shell and
can have a maximum of 8 electrons.
3. The shell next to the L-shell is the third shell called the M-shell and
can have a maximum of 18 electrons.
4. The shell next to the M-shell is the fourth shell called the N-shell and
can have a maximum of 32 electrons.
The maximum number of electrons in an orbit is fixed and is given by the
formula 2n 2 , where n is the number of the shell.
The first shell is closest to the nucleus and can hold a maximum of 2
electrons. The second shell is the next shell and can hold a maximum of 8
electrons. The third shell is the next shell and can hold a maximum of 18
electrons.
WORK SHEET - 3
11
3) 3 C
, 14
4 C
, 12
7 C
4) 10
2 C
, 16
2 C
, 14
7 C
Comprehension Type
The atoms of same element having different number of neutrons or the
atoms of same element having same atomic number but different mass
number are Isotopes.
The atoms of different elements containing same mass number are known
as isobars.
The atoms of different elements containing same number of neutrons are
Isotones.
The atoms of the different elements which contain same number of A–2Z
are Isodiaphers.
13. Identify the correct example for Isodiaphers:
1) 9F19 and 11Na23 2) 9F19 and 19K39
3) 19K and 11Na
39 23
4) All of these
14. Identify the correct set of an example for Isotopes:
1) 1H1, 1H2, 1H3 2) 8O16, 8O17, 9O18
3) 8C12, 6C14 4) 92U235, 93U236
15. Isotones have same:
1) Atomic number 2) Mass number
3) Number of neutrons 4) Number of electrons
SYNOPSIS - 4
VALENCY ELECTRONS
The electrons in an atom are distributed in the shell sof an atom. The last
shell electrons play an important role while combining with other atoms.
The last shell of an atom is called its valency shell.
The electrons in the valence shell are called valence electrons.
The valence electrons take part in chemical reactions.
The number of valence electrons determines the chemical reactivity of the
element.
NUCLEONS
Nucleons are all the particles present in the nucleus of an atom. The most
important nucleons are the protons and neutrons as they are responsible
for the mass of the atom. There are several other particles like mesons in
the nucleus.
REPRESENTING AN ELEMENT
The Atomic number and Mass number of an element are very important
physical quantities that are referred to frequently. To make it easier they
are written using special notations.
An element is represented using its symbol with Atomic number as a subscript
and Mass number as superscript.
Example: 17 Cl 35
ELECTRONIC CONFIGURATION OF ELEMENTS (BOHR-BURY RULES)
Electronic configuration of an atom shows the actual way in which the
electrons are distributed in the shells.
Bohr-Bury rules of electronic configuration
a) The electrons revolve in orbits around the nucleus of the atom.
b) The centre of the atom consists of the nucleus with the nucleons (protons
and neutrons) in it.
c) The orbits are numbered from the centre outward. The first orbit closest
to the nucleus is numbered as 1 and is denoted as the K-shell. The
next is numbered as 1 and is denoted as the K-shell. The next is
numbered as 2 and is denoted as the L-shell. The next with number 4
is denoted as the N-shell and so on.
d) The maximum number of electrons in an orbit is given by 2n 2 where n
is the number of the orbit. The first orbit can have a maximum of 2
electrons, the second orbit a maximum of 8 electrons, the third a
maximum of 18 electrons and so on. The last orbit however irrespective
of its number cannot have more than 8 electrons.
e) The maximum number of electrons in the outermost shell cannot exceed
8 and in the second last shell 18, irrespective of the shell number.
f) It is not necessary that the last orbit should be filled with electrons for
the next orbit to start filling - a new orbit starts filling as soon as the
last orbit gets 8 electrons. (For example the maximum number of
electrons in the 3rd shell is 18. But the fourth shell starts filling as
soon as the 3rd shell has 8 electrons.
Sulphur 32
16 S 32 16 16 16 16 2, 8, 6, ....
Chlorine 32
17 C 35 17 18 17 17 2, 8, 7, ....
Potassium 39
19 K 39 19 20 19 19 2, 8, 8,1 ....
Calcium 40
20 Ca 40 20 20 20 20 2, 8, 8, 2 ....
Flourine 19
9 F 19 9 10 9 9 2, 7 ....
20
Neon 10 Ne 20 10 10 10 10 2, 8....
Sodium 23
11 Na 23 11 12 11 11 2, 8,1....
Aluminium 27
13 A 27 13 14 13 13 2, 8, 3....
Carbon 12
6 C 12 6 6 6 6 2, 4,....
Nitrogen 14
7 N 14 7 7 7 7 2, 5,....
Oxygen 16
8 O 16 8 8 8 8 2, 6,....
WORK SHEET - 4
1) O 2) B 3) Ne 4) Mg
6. The correct electronic configuration of chromium (atomic number - 24) is:
1) 1s2, 2s2, 2p6, 3s2, 3p6, 4s1, 3d5 2) 1s2, 2s2, 2p6, 3s2, 3p6, 3d6
3) 1s2, 2s2, 2p6, 3s2, 3p6, 3d6, 4s2 4) 1s2, 2s2, 2p6, 3s2, 3p5, 3d5, 4s2
Comprehension Type
Knowing the mass and atomic number of an element we can easily represents
its geometric structure.
24
14. The number of protons present in 12 Mg is:
1) 12 2) 24 3) 36 4) 26
15. The number of neutrons in magnesium is:
1) 24 2) 12 3) 36 4) 20
16. The electrons present in first shell
1) 2 2) 8 3) 16 4) 32
SYNOPSIS - 5
PAULI’S EXCLUSION PRINCIPLE
Ø No two electrons in the same atom can have the same values for all the
four quantum numbers.
Ø Each electron in an atom is designated by a set of four quantum numbers.
Ø An orbital accommodates two electrons with opposite spin: These two
electrons have same values of principal, azimuthal and magnetic quantum
number but the forth, i.e., spin quantum number will be different.
Example:
N z 7 1s 2 2s 2 2 p3
1s 2 2 s 2 2 p1x 2 p1y 2 p1z
AUFBAU PRINCIPLE :
Ø The subshell with minimum energy is filled up first and when this obtains
maximum quota of electrons, then thenext subshell of higher energy
starts filling”.
Ø Electron filling follows energy ranking.
Ø If two orbitals have the same value for n l , the orbital having lower n
value is first filled.
Ø The sequence in which the various subshells are filled in the following
HUND’S RULE:
Orbitals of the same kind should be half filled before electron pairing
takes place.
Orbitals having the same values for n and l are called degenerate orbitals.
Unpaired electrons have parallel spin.
Half filled and completely filled degenerate orbitals give greater stability
to atoms.
Chromium (Z = 24) and copper (Z = 29) have anomalous electronic
configuration due to this reason.
Electronic configuration of chromium atom is 1s 2 2s2 2p6 3s23p6 3d5
4s1 but not 1s2 2s2 2p6 3s2 3p6 3d4 4s2.
WORK SHEET - 5
10. The increasing order of energy of the orbitals 1s, 2s and 2p is:
1) 2p < 2s < 1s 2) 2s < 2p < 1s 3) 1s < 2s < 2p 4) 2p > 3d > 4s
11. The orbital diagram in which the aufbau principle is violated is:
2s 2p 2s 2p
1) 2)
2s 2p 2s 2p
3) 4)
12. Aufbau principle fails to explain the configuration of element with atomic
number.
1) 18 2) 21 3) 24 4) 27
13. According to Aufbau’s principle, which of the three 4d, 5p and 5s orbitals
will be filled with electrons first?
1) 4d 2) 5p
3) 5s 4) 4d and 5s will be filled simultaneously
14. The atomic orbitals are progressively filled in the order of the increasing
energy’. This statement is known as:
1) Hund’s rule 2) Exclusion principle
3) Aufbau rule 4) de-Broglie rule
15. The electronic configuration of nitrogen is 1s 2 2s 2 2p1x 2p1y 2Pz1. This is in
accordance with
1) Aufbau principle 2) Pauli’s rule
3) Hund’s rule 4) Bohr Bury principle
16. The presence of five unpaired electrons in 3d orbitals of manganese atom
is according to
1) Pauli’s principle 2) Hund’s rule
3) Aufbau principle 4) de-Broglie’s theory
17. If Pauli’s exclusion principle is not known, the electronic arrangement of
lithium atom is:
1) 1s2 2s1 2) 1s1 2s2 3) 1s3 4) 1s2 2s1 2p1
18. Nitrogen, phosphorus, Arsenic, Antimony and Bismuth atoms have s
unpaired electrons in their p-orbitals because of:
1) Pauli’s principle 2) Hund’s rule
3) Aufbau principle 4) All the above
19. Nitrogen has the electronic configuration 1s 2 2s 2 2p1x 2p1y 2p1z and not
1s 2 2s 2 2p2x 2p1y 2p0z . This is determined by:
1) Aufbau principle 2) Pauli exclusion principle
3) Hund’s rule 4) Uncertainty principle
20. The fact that the two electrons in an orbital must have opposite spins is
deduced from?
1) Hund’s rule of maximum multiplicity
2) Pauli’s exclusion principle
3) Aufbau’s rule
4) Heisenberg’s uncertainty principle
21. The principle which excludes the possibility of presence of a third electron
in an orbital is:
1) Aufbau rule 2) Hund’s rule
3) Pauli’s exclusion principle 4) None of these
22. Which of the following is the correct statement?
1) In pauli’s principle, there is room for only two electrons in an orbital and
they should have opposite spins.
2) In an atom if electrons have same n, l and m values they must differ in
spin quantum number.
3) The order of filling the different orbitals in 9 sub energy level is governed
by Hund’s rule.
4) Pairing of electrons take place in a sub-shell only after all the orbitals
are singly filled.
23. Which of the following is correct statement
1) K-shell can accommodate 2 electrons
2) Maximum number of electrons in L-shell is 6 electrons
3) Maximum number of electrons, accommodated in N-shell is 32 electrons
4) Maximum number of electrons, accommodated in M-shell is 18 electrons
24. Based on what principle(s), the electronic configuration of any atom depends?
1) Pauli’s exclusion 2) Hunds rule
3) Aufbau’s principle 4) None of these
Comprehension Type
Writeup-1
Pairing of electrons take place in a sub - shell only after all the orbitals are
singly filled.
In p sub - level pairing of electrons take place with 4th electron according to
Hund’s rule.
Similarly pairing of electrons starts with 6th electron and 8th electron in d
and f sub - levels respectively.
34. The orbital diagram, in which both Pauli’s exclusion principle and Hund’s
rule are violated?
2s 2p
1) 2) 3) 4)
35. Quantum numbers of an atom can be defined on the basis of
1) Hund’s rule 2) Aufbau’s principle
3) Pauli’s exclusion principle 4) Heisenberg’s uncertainty principle
36. The electronic configuration in the valence shell of silicon is:
3s 3p
The rule violated is:
1) Auf-bau principle 2) Paul’s rule 3) Hund’s rule 4) All
Writeup-2
Electrons occupy orbitals with lower energy first. Electronic Configuration
is a representation of the occupation of electrons in the orbitals in the
increasing order of their energies.
37. Which of the following represent the energy of the orbital?
1) n + l 2) n – l 3) l + m 4) n + s
38. Which of the following has more energy?
1) 1s 2) 2s 3) 3p 4) 3d
39. No two electrons in an atom can have:
1) The same principal quantum numbers only .
2) The azimuthal quantum numbers only .
3) The same magnetic quantum numbers only .
4) An identical set of four quantum numbers.
Writeup-3
Pairing of electrons take place in a sub - shell only after all the orbitals
are singly filled.
In p sub - level pairing of electrons take place with 4 th electron according
to Hund’s rule.
Similarly pairing of electrons starts with 6 th electron and 8th electron in d
and f sub - levels respectively.
40. The orbital diagram, in which both Pauli’s exclusion principle and Hund’s
rule are violated?
2s 2p
1) 2) 3) 4 )
The rule violated is:
1) Auf-bau principle 2) Paul’s rule 3) Hund’s rule
4) All
6) 2 7) 2 8) 2 9) 3 10) 2
16) A-3
B-2
C-1
D-4
6) 1 7) 3 8) 1 9) 4 10) 1,2,3,4
6) 2 7) 3 8) 4 9) 1 10) 3