Material Safety Data Sheet

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

Product Name: SAMAD BOND 101

Recommended Use: Bonding laminated plastics, rubber, leather, canvas, wood, cork,
hardboard, metals and fibrous cement sheet.

Supplier: Samad Rubber Works (Pvt.) Limited

Street Address: 409 Ferozepur Road

Lahore 54600 Pakistan

Telephone Number: +92 (42) 111 409 111

Facsimile: +92 (42) 583 6088
Internet: http://www.samadrubber.com

2. HAZARDS IDENTIFICATION
Risk Phrases: Highly Flammable. Harmful by inhalation.

Safety Phrases: Keep away from sources of ignition - No Smoking

Avoid contact with eyes. Do not empty into drains.
Take precautionary measures against static discharges.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Components CAS Number Proportion Risk Phrases
Toluene 108-88-3 30-60% R11, R20

Naphtha (petroleum) 64742-49-0 30-60% R11, R51/53, R65

Synthetic polymer(s) - 10-<30% -

4. FIRST AID MEASURES

Inhalation: Remove victim from area of exposure - avoid becoming a casualty. Remove
contaminated clothing and loosen remaining clothing. Allow patient to assume most
comfortable position and keep warm.
Keep at rest until fully recovered. If patient finds breathing difficult and develops a bluish
discoloration of the skin (which suggests a lack of oxygen in the blood - cyanosis), ensure
airways are clear of any obstruction and have a qualified person give oxygen through a face
mask. Apply artificial respiration if patient is not breathing. Seek immediate medical advice.

Skin Contact: Wipe excess material from skin with a clean rag or paper towel (do NOT use solvent to
clean skin). If skin contact occurs, remove contaminated clothing and wash skin with
running water. If irritation occurs seek medical advice.

Eye Contact: If in eyes, wash out immediately with water. In all cases of eye contamination it is a
sensible precaution to seek medical advice.

Ingestion: Rinse mouth with water. If swallowed, do NOT induce vomiting. Give a glass of
water. Seek medical advice.

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 5. FIRE FIGHTING MEASURES

Hazards from combustion Highly flammable liquid. On burning will emit toxic fumes,
products: including those of oxides of carbon .

Precautions for fire fighters Keep containers cool with water spray. If safe to do so, remove and
special protective containers from path of fire. Fire fighters to wear self-contained
equipment: breathing apparatus and suitable protective clothing if risk of
exposure to vapour or products of combustion.

Suitable Extinguishing Foam, dry agent (carbon dioxide, dry chemical powder).
Media:

6. ACCIDENTAL RELEASE MEASURES

Emergency procedures: If contamination of sewers or waterways has occurred advise local
emergency services.

Methods and materials for SMALL SPILLS: Slippery when spilt. Avoid accidents, clean up
containment and clean up: immediately. Wipe up with absorbent (clean rag or paper towels).
Allow absorbent to dry before disposing with normal household
garbage. Any residual material can be cleaned up with mineral
turpentine or similar hydrocarbon solvent, or acetone based nail polish
remover.

LARGE SPILLS: Shut off all possible sources of ignition. Clear area of
all unprotected personnel. Slippery when spilt. Avoid accidents, clean up
immediately. Wear protective equipment to prevent skin and eye contact
and breathing in vapours. Work up wind or increase ventilation. Contain
- prevent run off into drains and waterways. Use absorbent (soil, sand
or other inert material).
Collect and seal in properly labelled containers or
drums for disposal.

7. HANDLING AND STORAGE

Conditions for safe storage: Store in cool place and out of direct sunlight. Store in a well
ventilated area away from foodstuffs, oxidising agents and sources of
heat or ignition. Keep containers closed when not in use - check
regularly for leaks.

Precautions for safe handling: Avoid skin and eye contact and breathing in vapour. May form
flammable vapour mixtures with air. All potential sources of ignition
(open flames, pilot lights, furnaces, spark producing switches and
electrical equipment etc) must be eliminated both in and near the work
area. Do NOT smoke. Vapour may travel a considerable distance to
source of ignition and flash back.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits:

Toluene: 8 hr TWA = 191 mg/m3 (50 ppm), 15 min STEL = 574 mg/m3 (150 ppm), Sk

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TWA - The time-weighted average airborne concentration over an eight-hour working day, for a five-day
working week over an entire working life.

STEL (Short Term Exposure Limit) - the average airborne concentration over a 15 minute period which
should not be exceeded at any time during a normal eight hour work day. According to current knowledge
this concentration should neither impair the health of, nor cause undue discomfort to, nearly all workers.

`Sk' Notice - absorption through the skin may be a significant source of exposure. The exposure standard is
invalidated if such contact should occur.

These Exposure Standards are guides to be used in the control of occupational health hazards. All
atmospheric contamination should be kept to as low a level as is workable. These exposure standards should
not be used as fine dividing lines between safe and dangerous concentrations of chemicals. They are not a
measure of relative toxicity.

Engineering controls:
Ensure ventilation is adequate and that air concentrations of components are controlled below quoted
Exposure Standards. Vapour heavier than air - prevent concentration in hollows or sumps. DO NOT enter
confined spaces where vapour may have collected.

Personal Protective Equipment:

FOR CONSUMER USE: Avoid contact with eyes and skin. Use with adequate ventilation. Wash hands after
use.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Viscous liquid
Colour: Yellow
Odour: Solvent
Solubility: Insoluble in water.
Specific Gravity: Approx. 0.84 g/ml
Flash Point (°C): -5 (Est.)
Flammability Limits (%): Not Available
Auto ignition Temperature (°C): Not Available
% Volatile by Volume: Approx. 75
Solubility in water (g/L): Insoluble
Melting Point/Range (°C): Not Applicable
pH: Not Applicable

10. STABILITY AND REACTIVITY

Chemical stability: Stable under normal conditions of use.
Conditions to avoid: Avoid contact with foodstuffs. Avoid exposure to heat, sources of
ignition, and open flame.
Incompatible materials: Incompatible with oxidising agents.
Hazardous decomposition Oxides of carbon.
products:
Hazardous reactions: None known.

11. TOXICOLOGICAL INFORMATION

No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the
product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:

Ingestion: Swallowing can result in nausea, vomiting and central nervous system depression.
If the victim is showing signs of central system depression (like those of

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 drunkenness) there is greater likelihood of the patient breathing in vomit and causing
damage to the lungs. Breathing in vomit may lead to aspiration pneumonia (inflammation
of the lung).
Eye contact: May be an eye irritant.
Skin contact: Contact with skin may result in irritation. Will have a degreasing action on the skin.
Repeated or prolonged skin contact may lead to irritant contact dermatitis. Component/s of
this material can be absorbed through the skin with resultant toxic effects.
Inhalation: Material may be irritant to the mucous membranes of the respiratory tract (airways).
Breathing in vapour can result in headaches, dizziness, drowsiness, and possible nausea.
Breathing in high concentrations can produce central nervous system depression, which can
lead to loss of co-ordination, impaired judgement and if exposure is prolonged,
unconsciousness.
Long Term No information available for the product. For Toluene (1) : Evidence indicates that
Effects: repeated or prolonged exposure to this chemical could result in central nervous system
disorders.

Toxicological Data:
No LD50 data available for the product. The toxicity of the product may be attributed to the solvents it
contains. Additive effects may occur with mixtures of solvents. Similar effects can occur where the
consumption of alcohol is also involved.

For the constituent Toluene:

Oral LD50 (rat): 636 mg/kg

Dermal LD50 (rabbit): 14100 uL/kg
SKIN: Moderate irritant (rabbit).
EYES: Moderate irritant (rabbit).

12. ECOLOGICAL INFORMATION

Ecotoxicity Avoid contaminating waterways.

13. DISPOSAL CONSIDERATIONS

Disposal methods: Refer to Waste Management Authority. Advise flammable nature. Dispose off
material through a licensed waste contractor. Normally suitable for incineration by
an approved agent.

14. TRANSPORT INFORMATION

For Road, rail, marine and air transport:

UN No: 1133
Class-primary: 3 Flammable Liquid
Packing Group: II
Proper Shipping Name: ADHESIVES

15. REGULATORY INFORMATION

Hazard Category: Xn: Harmful

Risk Phrase(s): R11: Highly Flammable.

R20: Harmful by inhalation.

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 Safety Phrase(s): S16: Keep away from sources of ignition - No smoking.
S25: Avoid contact with eyes.
S29: Do not empty into drains.
S33: Take precautionary measures against static discharges.

Poisons Schedule: S5 Caution.

16. OTHER INFORMATION

This MSDS summarises to our best knowledge at the date of issue, the chemical health and safety hazards of
the material and general guidance on how to safely handle the material in the workplace. Samad Rubber
Works (Pvt.) Ltd. cannot anticipate or control the conditions under which the product may be used, each
user must, prior to usage, assess and control the risks arising from its use of the material.

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