X Chemistry Acid Bases Salts
X Chemistry Acid Bases Salts
X Chemistry Acid Bases Salts
ALLEN
Acids, Bases and Salts
1. Introduction
The chemicals which we come across are usually categorised as acids, bases
and salts.
Earlier this classification was based on different taste of chemicals. THE
Acids were first recognized as substances that taste sour. Vinegar tastes SPOT P
sour because it is a dilute solution of acetic acid. Citric acid is responsible LIGHT
for the sour taste of a lemon. Acids are responsible to digest food
Bases, sometimes called alkalis, are characterised by their bitter taste and in the stomach, dissolve rock , to make
fertilizer, dissolve your tooth enamel
they are soapy to feel. Most hand soaps and commercial preparation for to form cavities.
unclogging drains are highly basic.
Substances having taste similar to that of common salt are called salts.
However, some substances have very unpleasant taste and even may be
poisonous. Usually salts are prepared by chemical reaction between acids
and bases.
Now, the question arises – how to test that the given substance is an acid
or a base without tasting it?
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CBSE : Class X
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Classification of acids
THE (a) On the basis of their source, acids are of two types.
SPOT P (i) Mineral acids / Inorganic acids
LIGHT They are generally obtained from minerals or rocks.
Basicity of an acid is determined by For example,
number of hydronium ions (H3O+ /
H+(aq)) produced per molecule of an Hydrochloric acid (HCl)
acid on ionisation. Sulphuric acid (H2SO4)
Nitric acid (HNO3)
Carbonic acid (H2CO3)
Phosphoric acid (H3PO4)
(ii) Organic acids
They are generally obtained from plants and animals.
For example,
Formic acid (HCOOH)
Acetic acid (CH3COOH)
Benzoic acid (C6H5COOH)
Citric acid (C6H8O7)
(b) On the basis of basicity, acids are of three types.
(i) Monobasic acids
THE
SPOT P One molecule of acid gives one hydronium ion.
For example, HCl, HBr, etc.
LIGHT (ii) Dibasic acids
The term "acid" is derived from the One molecule of acid gives two hydronium ion.
latin word "acidus" meaning sour to
taste. For example, H2SO4, H2CO3, etc.
(iii) Tribasic acid
One molecule of acid gives three hydronium ions.
For example, H3PO4, citric acid (C6H8O7), etc.
(c) On the basis of their strength, acids are of two types.
(i) Strong acid
They undergo complete ionisation in aqueous solution.
For example, HCl, H2SO4, etc.
Add acid to water !
Not water to acid ! !
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Theory
THE
SPOT P H Cl H +
H+
Cl–
LIGHT H Cl Cl
–
2
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(ii) Weak acid
They undergo incomplete ionisation in aqueous solution.
For example, CH3COOH, HCOOH, etc.
THE
Acetic acid SPOT P
Not as strong as inorganic acids
(vinegar) LIGHT
Bases which completely dissolve in
O water are called alkalis, example
|| NaOH, KOH, etc. "All alkalis are
R–C–O–H bases but all bases are not alkalis".
Citric acid
Formic acid
THE
Fig.3 Organic acids are weak acids.
(d) On the basis of concentration of the acid.
SPOT P
(i) Concentrated acid : They contain less amount of water and more
LIGHT
amount of acid. Acidity of a base is determined by
(ii) Dilute acid : They contain large amount of water and less amount the number of hydroxyl (OH—) ions
produced per molecule of a base or
of acid.
alkali on complete dissociation in
3. Bases water.
According to Arrhenius theory "Those substances which give hydroxide or
–
hydroxyl ion (OH ) in their aqueous solution are called bases".
For example, (i) NaOH(aq) ¾¾® Na+(aq) + OH–(aq)
Sodium hydroxide Sodium ion Hydroxyl ion
(ii) KOH(aq) ¾¾® K+(aq) + OH–(aq)
THE
Potassium hydroxide Potassium ion Hydroxyl ion
Classification of bases SPOT P
(a) On the basis of acidity, bases are of three types. LIGHT
(i) Mono acidic bases Strength of an acid does not depend
Produce one hydroxyl (OH–) ion per molecule. upon the concentration of an acid, but
on the concentration of hydronium ion.
For example, NaOH, KOH, etc.
(ii) Diacidic bases
For example, Ca(OH)2, Mg(OH)2, etc.
(iii) Triacidic bases
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CBSE : Class X
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CHECK YOUR CONCEPTS 1
1. Identify strong and weak acids as well as strong and weak bases from the
THE following. H2CO3, HNO3, CH3COOH, NaOH, NH4OH, KOH, Ca(OH)2, HCl.
SPOT P 4. Indicators
LIGHT Indicator as the name suggests, indicates the nature of particular solution
whether acidic, basic or neutral. Apart from this, indicator also represents
Carbonic acid (H2 CO 3) turns blue
the change in nature of the solution from acidic to basic and vice-versa.
litmus to pink which shows it is a
Depending upon the property of the indicator, we have the following two
weak acid.
types of acid-base indicators :
(1) Indicators showing different colours in acidic and basic medium.
Examples, Litmus, phenolphthalein and methyl orange.
(2) Indicators giving different odour in acidic and basic medium / olfactory
indicators.
THE Examples, Onion extract, vanilla and clove oil.
SPOT P BUILDING CONCEPTS 1
LIGHT What causes indicators to show different colours in acids and bases?
Litmus is the most commonly used
Explanation
indicator in the lab. Indicators undergo some structural changes in the presence of acids or bases
which causes them to show different colours.
5. Chemical properties of acids and bases
(1) Action of indicators
ACTIVE CHEMISTRY 1
THE
SPOT P Aim
To test acids and bases in the laboratory using colour change
LIGHT acid-base indicators.
Indicator Change in acidic Materials required
medium Watch glass, test tube, hydrochloric acid, sulphuric acid, nitric caid, acetic
Blue litmus paper Blue to Red acid, sodium hydroxide, calcium hydroxide, potassium hydroxide,
Methyl orange Orange to red magnesium hydroxide, ammonium hydroxide, red and blue litmus solution,
Phenolphthalein Remains phenolphthalein solution, methyl orange solution.
colourless
Method
Turmeric paper No change in
colour (i) Collect the following samples from the science laboratory-hydrochloric
acid (HCl), sulphuric acid (H2SO4), nitric acid (HNO3), acetic acid
(CH3COOH), sodium hydroxide (NaOH), calcium hydroxide [Ca(OH)2],
potassium hydroxide (KOH), magnesium hydroxide [Mg(OH)2], and
ammonium hydroxide (NH4OH).
(ii) Put a drop of each of the above solutions on a watch-glass and test
with a drop of the following indicators.
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Theory
THE
SPOT P Red litmus solution, Blue litmus solution, Phenolphthalein solution,
Methyl orange solution.
LIGHT Observation
Indicator Change in basic The changes observed are as follows :
medium Red Blue Methyl
Phenolphthalein
Sample solution litmus litmus orange
solution
Red Litmus Red to Blue solution solution solution
Methyl orange Orange to Hydrochloric acid (HCl) No effect Red Colourless Red
yellow Sulphuric acid (H2SO4) No effect Red Colourless Red
Phenolphthalein Colourless to pink Nitric acid (HNO3) No effect Red Colourless Red
Turmeric paper Yellow to red Acetic acid (CH3COOH) No effect Red Colourless Red
brown Sodium hydroxide(NaOH) Blue No effect Pink Yellow
Calcium hydroxide Ca(OH)2 Blue No effect Pink Yellow
Potassium hydroxide (KOH) Blue No effect Pink Yellow
Magnesium hydroxide Mg(OH)2 Blue No effect Pink Yellow
Ammonium hydroxide (NH4OH) Blue No effect Pink Yellow
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Conclusion
Acids turn blue litmus red but have no effect on red litmus.
Bases turn red litmus blue but have no effect on blue litmus.
Phenolphthalein is colourless in acidic medium and turns pink in basic medium.
Methyl orange is yellow in basic medium and red in acidic medium.
Stand
Burning of H2 gas
with a pop sound
Candle
Test tube
THE
SPOT P Dilute sulphuric
acid
H2 gas
bubbles
Soap bubble
LIGHT Zinc granules
filled with H 2
(iii) Repeat the rest of the steps as in previous activity and record your
observation.
Observation
It is observed that metals like zinc react with strong base like NaOH, KOH,
etc. to liberate hydrogen gas and form the corresponding salt.
THE For example,
SPOT P Zn(s) + 2NaOH(aq)
Zinc Sodium hydroxide
¾® Na2ZnO2(aq) +
Sodium zincate
H2(g)
Hydrogen
LIGHT Conclusion
Non metals do not react with dilute Some metals react with bases to liberate hydrogen gas.
acids as they do not displace Some more examples,
hydrogen from acids. (i) 2Al(s) + 2NaOH(aq) + 2H2O(l) ¾® 2NaAlO2(aq) + 3H2(g)
Sodium meta aluminate
(ii) Sn(s) + 2NaOH(aq) ¾® Na2SnO2(aq) + H2(g)
Sodium stannite
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(3) Reaction of acid with metal carbonates and metal hydrogen
carbonates
All metal carbonates and hydrogen carbonates react with acids to give
a corresponding salt, carbon dioxide and water.
Metal carbonate/Metal hydrogen carbonate + Acid
THE
¾¾® Salt + Carbon dioxide + Water
Lets discuss the following activity.
SPOT P
LIGHT
ACTIVE CHEMISTRY 5
Egg-shell also conta in calcium
Aim carbonate as the main constituent.
To study reaction of metal carbonates and metal hydrogen carbonates with acids. Hence they react with the acids.
Materials required
Test tubes, sodium carbonate, sodium hydrogen carbonate, dilute HCl
solution, lime water.
Method
(i) Take two test tubes. Label them as A and B.
(ii) Take about 0.5 g of sodium carbonate (Na2CO3) in test tube A and
about 0.5 g of sodium hydrogen carbonate (NaHCO3) in test tube B.
(iii) Add about 2 mL dilute HCl to both the test tubes.
(iv) Pass the gas produced in each case through lime water (calcium
hydroxide solution)
Observation
It is observed that carbon dioxide gas is evolved in each case which turns
lime water milky. THE
Na2CO3(s) + 2HCl(aq) ¾¾® 2NaCl(aq) + H2O(l) + CO2(g)
NaHCO3(s) + HCl(aq) ¾¾® NaCl(aq) + H2O(l) + CO2(g)
SPOT P
Ca(OH)2 + CO2(g) ¾¾® CaCO3(s) + H2O(l)
LIGHT
Lime Carbon Calcium carbonate Organic tissues like skin, etc. get
completely corroded by alkalis such
water dioxide (White ppt.)
as NaOH & KOH.
On passing excess CO2, the solution becomes clear due to conversion of
insoluble CaCO3 into soluble calcium hydrogen carbonate.
CaCO3(s) + H2O(l) + CO2(g) ¾¾® Ca(HCO3)2(aq)
Calcium hydrogen carbonate
(Soluble in water)
Conclusion
All metal carbonates and hydrogen carbonates react with acids to give a
corresponding salt, carbon dioxide and water.
One more example,
CaCO3(s) + 2HCl(dil) ¾¾® CaCl2(aq) + H2O(l) + CO2(g)
(4) Reaction of acid and base with each other
Whenever a solution of acid is treated with a solution of base, salt and
water are formed as the products. This reaction is known as
THE
P
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Theory
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pH
THE
SPOT P
LIGHT
Uses of some common mineral
acids :
HCl : in textile industry as bleaching
agent.
H3PO4 : used in antirust paints and
fertilizers.
HNO 3 : used in manufacture of
explosives and fertilizers. Fig.5 On complete neutralisation, the solution results is neutral with pH = 7.
ACTIVE CHEMISTRY 6
Aim
To study the reaction between acids and bases, i.e. neutralisation reaction.
Materials required
Test tube, dilute NaOH solution, phenolphthaein solution, dilute HCl
solution.
Method
(i) Take about 2 mL of dilute NaOH solution in a test tube and add two
drops of phenolphthalein solution.
(ii) Note the colour of the solution.
(iii) Add dilute HCl solution to the above solution drop by drop.
(iv) Note the change in colour of the reaction mixture.
(v) Now add a few drops of NaOH solution to the above mixture.
Now answer
(i) What is the colour of the NaOH solution on adding phenolphthalein?
(ii) What change in colour takes place on adding dilute HCl?
(iii) Does the pink colour of phenolphthalein reappear on adding NaOH?
(iv) Why do you think this has happened?
Observation and discussion
On adding phenolphthalein to NaOH solution, the colour becomes pink.
On adding dilute HCl solution dropwise, finally the pink colour disappears
and the solution again become colourless. On adding NaOH, pink colour
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ACTIVE CHEMISTRY 7
Aim
To study the reaction of metal oxides with acids. THE
Materials required SPOT P
Beaker, copper oxide, dilute hydrochloric acid. LIGHT
Method CO2, SO2, SO3 are non metallic oxide.
(i) Take a small amount of copper oxide in a beaker and add dilute They are acidic in nature.
hydrochloric acid slowly while stirring.
(ii) Note the colour of the solution.
Now answer
What has happened to the copper oxide?
Observation nad discussion
It is observed that the colour of the solution become blue-green and the
copper oxide dissolves.
The blue green colour of the solution is due to formation of copper (II)
chloride in the solution.
Conclusion
Metal oxides react with the acids to form salt and water.
Metal oxide + Acid ¾® Salt + Water
CuO + 2HCl ¾® CuCl2 + H2O
Copper (II) Hydrochloric Copper (II) chloride Water
THE
oxide acid (Blue-green)
This shows that metal oxides are basic in nature. SPOT P
Some more examples LIGHT
(i) CaO(s) + 2HCl(aq) ¾® CaCl2(aq) + H2O(l) H2S gas is weakly acidic in nature
(ii) MgO(s) + H2SO4(aq) ¾® MgSO4(aq) + H2O(l) but NH3 gas is basic in nature.
CHECK YOUR ANSWERS 1
1. Strong acids : HNO3, HCl
Weak acids : H2CO3, CH3COOH
Strong bases : NaOH, KOH, Ca(OH)2
Weak bases : NH4OH
(6) Reaction of a Non-Metallic oxide with a base
Acids react with metal oxides but base react with non-metallic oxide
to form their respective salts and water.
Base + Non-metallic oxide ¾® Salt + Water
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Theory
We have already discussed under acids that metal carbonates and metal
hydrogen carbonates react with acids to form carbon dioxide. On passing
the CO2 gas evolved through lime water [Ca(OH)2], lime water turns
milky.
Ca(OH)2(aq) + CO2(g) ¾® CaCO3(s) + H2O(l)
(White ppt.)
THE
Since this is similar to the reaction between a base and an acid, we
can conclude that non-metallic oxides are acidic in nature.
SPOT P
Some more examples,
LIGHT
2NaOH(aq) + CO2(g) ¾® Na2CO3(aq) + H2O(l) Some of the non-metal oxides are also
neutral i.e. they do not react with base
Sodium hydroxide Carbon dioxide Sodium carbonate Water
Ex. NO, CO and N2O
2KOH(aq) + CO2(g) ¾® K2CO3(aq) + H2O(l)
Potassium hydroxide Potassium carbonate
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CBSE : Class X
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Comparison between properties of acids and bases
Acids Bases
(i) Sour in taste. (i) Bitter in taste.
THE
SPOT P (ii) The properties are due to
the presence of hydrogen ion
(ii) The properties are due to the
presence of hydroxide ion (OH–)
LIGHT (H+) in water solution of an acid. in water solution of a base.
All acids and bases produce ions in (iii) Turns blue litmus to red. (iii) Turns red litmus to blue.
aqueous solution. (iv) Aqueous solution conducts (iv) Aqueous solution conducts
electricity. electricity.
(v) Reacts with active metals like (v) Does not react with metals
Na, K, Ca and Zn to give except with Zn, Al and Sn.
hydrogen gas.
(vi) Acidic properties disappear (vi) Basic properties disappear when
when react with bases react with acids (Neutralization).
(Neutralization).
(vii) Reacts with carbonates to give (vii) Absorbs carbon dioxide to form
carbon dioxide. carbonate.
(viii) Frequently corrosive to skin. (viii) Frequently corrosive to skin and
slippery in nature.
(ix) The pH value is less than (ix) The pH value is greater than
7 at 25°C (room temp.). 7 at 25°C (room temp.).
6. What do all acids and all bases have in common?
In general, all acids have similar chemical properties. We have seen that
all acids generate hydrogen gas on reacting with metals, so hydrogen seems
to be common to all acids.
All acids produce hydrogen ions [H+ (aq)] when dissolved in water.
For example, HCl, H2SO4, HNO3, CH3COOH, etc.
Similarly all bases produce hydroxide ions (OH–) when dissolved in water.
For example, NaOH, Mg(OH)2, Ca(OH)2, NH4OH, etc.
F Since the ions are the carriers of charge, therefore tendency to conduct
electric current is the common characteristic of all acids and bases when
dissolved in water.
ACTIVE CHEMISTRY 8
Aim
To study the conduction of electricity by aqueous solutions of acids and bases.
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Theory
Materials required
Beaker, solution of glucose, alcohol, hydrochloric acid, sulphuric acid, nails,
cork, battery, bulb, switch.
Method
THE (i) Take solution of glucose, alcohol, hydrochloric acid, sulphuric acid,
SPOT P etc.
LIGHT (ii) Fix two nails on a cork, and place the cork in a 100 mL beaker.
If a solution does not contain ions, it (iii) Connect the nails to the two terminals of a 6 volt battery through a
will not conduct electricity. bulb and a switch.
(iv) Now pour some dilute HCl in the beaker and switch on the current.
(v) Repeat with dilute sulphuric acid.
(vi) Repeat the experiment separately with glucose and alcohol solutions.
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Chemistry
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6 V battery Bulb
Switch
THE
Beaker SPOT P
LIGHT
Deliques cence :
Nail Certain crystalline substance when
Dilute HCl solution exposed to atmosphere absorb
moisture and change into solution.
Rubber cork The absorption of moisture from air
by crystals to form a solution is called
Fig.6 Acid solution in water conducts electricity. deliquescence.
Sodium hydroxide, potassium
Now answer
hydroxide, calcium chloride, etc. are
(i) What do you observe on passing electric current? deliquescent substances.
(ii) What do you observe in case of glucose and alcohol solution?
(iii) Does the bulb glow in all cases?
Observation and discussion
The bulb is found to glow in case of acids but not in case of glucose and
alcohol solutions.
Conclusion
As electric current is carried through the solution by ions, this shows that THE
acids dissociate in the solution to produce H+ (aq) ions but substances like
glucose and alcohol do not dissociate to give H+ ions and hence are not acidic.
SPOT P
Thus, H+ ions are responsible for the acidic properties. LIGHT
If we repeat the same activity using alkalis such as sodium hydroxide, calcium Hygroscopic Substances :
hydroxide etc, similar results will be observed. As bases also produce ions Certain substances absorb water
in water i.e. OH–(aq) ions, they are also electrically conducting in nature. from the atmosphere without under-
What happens to an acid or a base in a water solution? going change in physical state. Such
The acidic behaviour of acids is due to the presence of hydrogen ions [H+ substances are known as
(aq)], in them. The acids produce hydrogen ions only in the presence of water. hygroscopic substance.
So, in the absence of water, a substance will not form hydrogen ions and Anhydrous sodium carbonate,
hence will not show its acidic behaviour. anhydrous copper sulphate,
This can be well illustrated with the following activity. concentrated sulphuric acid are
examples of hygroscopic substances.
ACTIVE CHEMISTRY 9
Aim
To test that dry HCl gas is not acidic but its aqueous solution is acidic.
Materials required
Test tube, NaCl, concentrated sulphuric acid, moist blue litmus paper.
Method
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Theory
(i) Take about 1 g solid NaCl in a clean and dry test tube and set up the
apparatus.
(ii) Add some concentrated sulphuric acid to the test tube.
(iii) Test the gas evolved successively with dry and wet blue litmus paper.
THE
Moist litmus paper
SPOT P
Delivery tube
LIGHT
Cork H (aq) = H3O+
+
Conical flask containing
concentrated H2 SO4 or
Test tube
Aq. hydrogen ion = Hydronium ion
Test tube
Sodium chloride
(ii) Add a few drops of concentrated H2SO4 to it and swirl the beaker slowly.
(iii) Touch the base of the beaker.
(iv) Repeat the above activity with NaOH pellets.
Caution
Add sulphuric acid into water for dilution and not water into sulphuric acid
THE
SPOT P as other wise the solution may splash out and cause burns.
Now answer
LIGHT (i) Is there a change in temperature in the two cases?
Add acid/base to water, not water (ii) Is this an exothermic or endothermic process?
to acid/base. Observation and discussion
In both cases, the temperature is found to rise.
Conclusion
Dilution of concentrated H2SO4 with water as well as dissolution of NaOH
in water is exothermic.
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Precaution needed for dilution
During dilution small quantity of acid or base should be added in water with
stirring. Heat evolved in this case will be quite slow.
If water will be added to the container containing acid or base, large amount
of heat will be produced immediately, which may be harmful.
THE
7. How strong are acid or base solution? SPOT P
Acids and bases may be either strong or weak. We can compare their LIGHT
relative strengths on the basis of the Arrhenius theory. According to this pH is simply a number which indicates
+
theory, more the number of H ions released by acid in water, stronger is the acidic or basic nature of a solution.
–
the acid. Similarly, more the number of OH ions released by base in water,
stronger is the base.
+
Acids and bases on dilution with water, decrease the concentration of H (aq)
–
or OH (aq) ions in the acidic and basic solution respectively.
+ –
If we find quantitatively, the amount of H (aq)/OH (aq) ions present in a
solution, we can judge how strong an acid or a base is?
We can do this with the help of a universal indicator, which is a mixture
THE
of several indicators. The universal indicator shows different colours at
different concentration of hydrogen ions or pH values in solution. SPOT P
pH Scale LIGHT
S.P.L. Sorenson, a Danish chemist in 1909 introduced the concept of
+ Higher the hydronium ion
measuring the concentration of hydrogen ions (H (aq)] in a particular solution. concentration, lower is the pH value.
The 'p' in pH stands for 'potenz' in German, meaning power.
On the pH scale we can measure pH from "0" (very acidic) to 14
(very alkaline).
100 10–1 10–2 10–3 10–4 10–5 10–6 10–7 10–8 10–9 10–10 10–11 10–12 10–13 10–14 +
[H3O ]
ACTIVE CHEMISTRY 11
THE
Aim
To test the pH values of some solutions.
SPOT P
Materials required
LIGHT
+ –x
pH paper, given solutions in table. If [H ] = 10 M, then pH = x e.g If
+ –3
[H ] = 10 M then pH = 3 It shows
Method
acidic nature.
(i) Test the pH values of solution given in following table.
(ii) Record your observations.
Now answer
(i) What is the nature of each substance on the basis of your observations?
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Observations
Colur of Approximate Nature of
THE S.No. Solution
SPOT P 1
pH paper
Saliva (before meal) Light green
pH value
7.4
substance
Basic
LIGHT 2 Saliva (after meal) Yellow 5.8 Acidic
Mathematically pH is expressed
3 Lemon juice Red 2.3 Acidic
as pH = – log10 [H+] Colourless aerated
4 Red-orange 3 Acidic
drink
5 Carrot juice Yellow 6 Acidic
Yellowish
6 Coffee 5 Acidic
orange
7 Tomato juice Orange 4.1 Acidic
8 Tap water Light green 7.4 Basic
9 1M NaOH Dark violet 14 Basic
10 1M HCl Dark red 0 Acidic
Conclusion
Solutions with pH < 7 but close to 7 are weakly acidic, solutions with
pH << 7 are strongly acidic, solution with pH > 7 but close to 7 are weakly
basic, solutions with pH>>7 are strongly basic.
THE
SPOT P Soft &
diet Soaps &
LIGHT drinks
Blood
detergents
pH
The pH of human blood varies
between 7.36 to 7.42. It is
maintained by the soluble hydrogen
carbonates and carbonic acid
present in blood. These are known Acid pH scale Alkaline
as 'buffer'. In general, the role of
Fig.10 pH of some common substances.
different buffer is to help in controlling
the pH of solution. Table : pH Value of Some Common Substances
Solution pH Value Solution pH Value
1 M Hydrochloric acid 0 10 M HCl 1.0
1 M Sodium hydroxide 14.0 0.1 M Sodium
hydroxide 13.0
Gastric Juice 1–3 Lemon juice 2.2–2.4
Vinegar 2.4–3.4 Tomato juice 4.0–4.4
Saliva (before meals) 6.5–7.5 Saliva (after meals) 5.8
Coffee 4.5–5.5 Soft drinks 3.0
Blood 7.4 Eggs 7.8
Toothpaste 8.0 Baking Soda
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Theory
Solution 8.5
Washing Soda Solution 9.0 Pure Water 7.0
ACTIVE CHEMISTRY 12
Aim
To test the pH of the soil in the backyard of our home.
Materials required
Test tube, water, soil, pH paper.
Method
(i) Put about 2 g soil in a test tube and add 5 mL water to it.
(ii) Shake the contents of the test tube.
(iii) Filter the contents and collect the filtrate in the test tube.
(iv) Check the pH of this filtrate with the help of universal indicator paper.
Now answer
What can you conclude about the ideal soil pH for the growth of plants in
your region? Fig.12 For goldfish to survive, the
Observation and conclusion pH of the water must be carefully
controlled.
The ideal soil pH should be close to 7, i.e., neither very acidic nor very alkaline.
Treatment of acidic or basic Soil
The pH of acidic soil can reach as low as 4 and that of the basic soil can
go up to 8.3. Chemicals can be added to soil to adjust its pH and make
it suitable for growing plants.
If the soil is too acidic, then it is treated with materials like quicklime (calcium
oxide) or slaked lime (calcium hydroxide) or chalk (calcium carbonate). All
these materials are bases and hence react with the excess acid present in
soil and reduce its acidity. If the soil is too basic (or too alkaline) then its
alkalinity can be reduced by adding decaying organic matter (manure or
compost), which contains acidic materials.
Soils with high peat content or iron mineral or with rotting vegetation tend
to become acidic.
(3) Importance of pH in our digestive system
As we know our stomach produces gastric juice which contains large
amount of hydrochloric acid (pH about 1.4). The acid so produced does
not harm the stomach walls, but kills germs and bacteria which enter
in our digestive system along with food, thus in a way it protects us from
diseases and helps in digestion. Sometimes excess of acid is produced
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Theory
in the stomach due to overeating or eating spicy foods. This stage is called
acidity. To get relief from this pain, we take tablets known as antacids.
These are weak bases which neutralise the excess of acids.
For example, Magnesium hydroxide(milk of magnesia) Mg(OH)2 Fig.13 "Milk of Magnesia" commonly
(4) pH change as the cause of tooth decay used as antacid.
Generally, the pH in the mouth is more than 7, as the saliva produced
in the mouth is basic in nature. However, when we take food, some
food particles remain in the mouth after eating and bacteria present
in the mouth produce acids by degradation of food particles.
This acid lowers the pH in the mouth, tooth decay starts when the pH
of acid formed in the mouth falls below 5.5 and the enamel get corroded.
The bacteria present in the mouth break down the sugar that we eat
into acids. Lactic acid is one of these. The formation of these acids causes
decrease in pH. The acids react with calcium phosphate and the enamel
coating slowly breaks.
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Therefore, to prevent tooth decay, it is advised to clean the mouth and use
toothpastes which are generally basic, for cleaning the teeth. It neutralise
the excess acid and prevent tooth decay.
THE (5) Self defence by animals and plants through chemical warfare
SPOT P The sting of the honey bee contains formic acid, this acid causes a lot
of irritation and pain. The pain can be reduced by applying baking
LIGHT soda paste on the affected region as the acid gets neutralised.
Some flowering plants carry their own In plant kingdom, nettle (Bichu Booti) is a herbaceous plant which
'built in pH indicators'. For example,
grows in wild. The nettle leaves have stinging hair. When a person
the flowers of a hydrangea bush are
blue in colour when grown in an happens to touch the leaves of a nettle plant accidently, the stinging
acidic soil. If it is alkaline in nature, hair of nettle leaves inject methanoic acid (HCOOH) into the skin of
the flowers become pink. the person causing burning pain. The nettle sting, being acidic can be
neutralised by rubbing baking soda on the skin. Nature provides
remedy for the nettle sting in the form of a 'dock' plant, which often
grows besides the nettle plants. The leaves of dock plant contain some
basic chemicals which neutralises methanoic acid.
Some naturally occurring acids
Natural source Acid Natural source Acid
Vinegar Acetic acid Sour milk (Curd) Lactic acid
Orange Citric acid Lemon Citric acid
Tamarind Tartaric acid Ant sting Methanoic acid
Tomato Oxalic acid Nettle sting Methanoic acid
9. Salts
Salts are the ionic compounds consisting of two parts, one part carrying
a positive charge called positive ion or cation and the other part carrying
a negative charge called a negative ion or anion.
Some common salts
1. Sodium chloride (NaCl) 2. Sodium sulphate (Na2SO4)
3. Potassium nitrate (KNO3) 4. Copper sulphate (CuSO4)
5. Zinc sulphate (ZnSO4) 6. Calcium carbonate (CaCO3)
7. Calcium chloride (CaCl2) 8. Aluminium sulphate [Al2(SO4)3]
9. Ammonium chloride (NH4Cl)
Formation of salts
Salts can be prepared by many reactions. Some of these are-
(1) By neutralisation of acids and bases. For example,
NaOH + HCl ¾® NaCl + H2O
Sodium Hydrochloric Sodium Water
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Families of salts
Salts are generally formed by reaction between an acid and base. And on the
basis of kind of acid and base used they contain specific cation or anion. So
we can divide salts in different families on the basis of cation or anion present.
The salts having the same positive radical (or cation) or negative radical
(or anion) are said to belong to the same family.
Or we can say, salts can be classified into different families based on the
common ion present.
ACTIVE CHEMISTRY 13
Aim
Write the formulae of the salts and to identify their acids and bases and
their families.
Method
(i) Write down the formulae of the salts given below : (1) Potassium sulphate
(2) Sodium sulphate (3) Calcium sulphate (4) Magnesium sulphate Fig.15 A digital pH meter.
(5) Copper sulphate (6) Sodium chloride (7) Sodium nitrate
(8) Sodium carbonate (9) Ammonium chloride.
(ii) Identify the acids and bases from which the above salts may be obtained.
(iii) Salts having the same positive or negative radicals belong to the same
family. For example, NaCl and Na2SO4 belong to the family of sodium
salts. Similarly, NaCl and KCI belong to the family of chloride salts.
Now answer
How many families can you identify among the salts given in this activity?
Observation and Conclusion
THE
S.No.
1
Salt
Potassium sulphate
Formula
K2SO4
Acid
H2SO4
Base
KOH
SPOT P
2 Sodium sulphate Na2SO4 H2SO4 NaOH LIGHT
In a salt, total positive charge is equal
3 Calcium sulphate CaSO4 H2SO4 Ca(OH)2 to total negative charge, so that the
4 Magnesium sulphate MgSO4 H2SO4 Mg(OH)2 salt as a whole is electrically neutral.
pH of salts
Depending upon the nature of acid and base which react to form the salt.
OR
The nature of acid and base produced when salt reacts with water, the salts
can be classified into the following four types.
(1) Salts of strong acid and strong base. (Neutral salts)
For example, NaCl
NaCl + H2O ¾® NaOH + HCl
THE Sodium chloride Water Sodium hydroxide Hydrochloric acid
SPOT P (strong base) (strong acid)
Hence, the acid and the base produced neutralize each other completely,
LIGHT so pH = 7.
Metal sulphides are formed by the (2) Salt of strong acid and weak base. (Acidic salt)
complete displacement of ionisable For example, NH4Cl
hydrogen ions of H2S. For example, NH4Cl + H2O ¾® NH4OH + HCl
Ca(OH)2 + H2S ¾® CaS + 2H2O Ammonium Water Ammonium hydroxide Hydrochloric acid
Thus, metal sulphides are salts. chloride (weak base) (strong acid)
Here, pH < 7.
(3) Salt of weak acid and strong base (Basic salt)
For example, Na2CO3
Na2CO3 + 2H2O ¾® 2NaOH + H2CO3
Sodium carbonate Water Sodium hydroxide Carbonic acid
(strong base) (weak acid)
Here, pH > 7.
(4) Salt of weak acid and weak base (Neutral salts)
For example, CH3COONH4
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Salt solution
THE
SPOT P
LIGHT
The process of production of sodium
hydroxide from sodium chloride is
known as chlor-alkali process
HYDROGEN
CHLORINE
because of products formed – chlor Produced Produced
for chlorine and alkali for sodium
NaOH
at at
hydroxide.
cathode anode
Uses Uses
(In cleaning steel, in the preparation (In household bleaches,
THE of ammonium chloride, medicines) and bleaching fabric)
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(iii) Baking soda
The chemical name of baking soda is sodium hydrogencarbonate or sodium
bicarbonate. Baking soda (or sodium bicarbonate) is represented by the
formula NaHCO3. The soda commonly used in the kitchen for making tasty
crispy pakoras is baking soda. Sometime it is added for faster cooking. It
THE
is produced using sodium chloride as one of the raw materials.
In laboratory, baking soda can be prepared by passing excess of CO2
SPOT P
gas through the saturated solution of sodium carbonate. As a result, sodium
LIGHT
Anhydrous sodium carbonate
hydrogen carbonate is formed. It gets precipitated due to supersaturation. (Na2CO3) is generally called soda ash.
The precipitate is separated, washed and dried without heating.
Na2CO3 + CO2 + H2O ¾® 2NaHCO3 (ppt.)
On commercial scale, NaHCO3 is formed as an intermediate product,
when washing soda is prepared by Solvay process or ammonia-soda
process. In this method a solution of sodium chloride (called "brine") saturated
with ammonia is allowed to react with CO 2, sodium hydrogen carbonate
& ammonium chloride are formed.
NaCl(aq) + H2O(l) + CO2(g) + NH3(g) ® NH4Cl(aq) + NaHCO3(s)
Common salt Ammonium Sodium hydrogen
chloride carbonate
It can be used to neutralise an acid because it is mild non-corrosive base
due to the presence of HCO3– ion.
The following reaction takes place when it is heated during cooking.
Heat
2NaHCO3(s) ¾¾¾® Na2CO3(s) + H2O(l) + CO2(g)
Uses of sodium hydrogen carbonate (NaHCO3)
(a) For making baking powder which is a mixture of baking soda (sodium
hydrogen carbonate) and a mild edible acid like tartaric acid. When
baking powder is mixed with water, the following reaction takes place.
NaHCO3 + H+ ¾® CO2 + H2O + Sodium salt of the acid
From acid
Carbon dioxide so produced during the reaction is responsible for
Fig.18 Baking soda can be used to
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Theory
making the bread and cake to rise making them soft and spongy.
neutralise formic acid present in red
(b) As an ingredient in antacids. Being alkaline, it neutralises excess acid ant's sting.
BUILDING CONCEPTS 3
Why do we feel a burning sensation in the stomach when we overeat? What
is the medicine used called?
Explanation
Burning sensation is due to excess HCl produced in the stomach. The medicine
used to neutralise it, is called antacid. For example, milk of magnesia.
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(iv) Washing soda (sodium carbonate)
The chemical formula of washing soda is Na2CO3·10H2O (sodium carbonate
decahydrate). Washing soda is manufactured by Solvay process. This
process is also known as ammonia soda process. The raw materials
THE
SPOT P needed for the process are sodium chloride, lime stone (CaCO3) and
ammonia (NH3). The reactions involved are
LIGHT
Step-I
Since one of the source of washing
soda is ashes of plants, it is NaCl(aq) + H2O(l) + CO2(g) + NH3(g) ¾® NH4Cl(aq) + NaHCO3(s)
sometimes called soda ash. Common salt Ammonium Sodium
chloride hydrogen
carbonate
The CO2 required in this reaction is obtained by heating limestone.
Heat
CaCO3(s) ¾¾¾ ® CaO(s) + CO2(g)
Limestone Quicklime
Step-II
Dry sodium hydrogen carbonate is heated strongly to produce sodium
carbonate.
Heat
2NaHCO3(s) ¾¾¾® Na2CO3 (s) + H2O(l) + CO2(g)
Anhydrous sodium
carbonate (soda ash)
Step-III
Washing soda (Na2CO3·10H2O) is obtained by recrystallisation from a
saturated solution of soda ash (Na2CO3).
Na2CO3(s) + H2O(l) ¾® Na2CO3 (aq) ¾¾¾¾¾
crystallisation
® Na2CO3·10H2O
(Anhydrous Water Washing soda
sodium carbonate)
Uses of washing soda
(a) Washing soda (or sodium carbonate) is used for washing clothes (laundry
purposes).
(b) Washing soda is used for softening hard water.
(c) Sodium carbonate (soda ash) is used for the manufacture of detergents.
(d) Sodium carbonate is used for the manufacture of many important
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ACTIVE CHEMISTRY 15
Aim
To test the presence of water of crystallisation in copper sulphate crystals.
Materials required
Boiling tube, copper sulphate crystals, burner, water, test tube holder.
Method
(i) Heat a few crystals of copper sulphate in a dry boiling tube.
(ii) Note the colour of copper sulphate after heating.
(iii) Observe the water droplets in the boiling tube.
(iv) Add 2-3 drops of water on the sample of copper sulphate obtained Fig.20 Raw gypsum, an important
after heating. constituent of cement.
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Preparation of plaster of paris
Plaster of Paris is obtained by heating gypsum (CaSO4.2H2O) in a kiln at
373K (or 100°C).
373K,(100°C)
2[CaSO4.2H2O](s) ¾¾¾¾¾
heat
® (CaSO4)2.H2O(s) + 3H2O(g)
Gypsum Plaster of Paris
or
THE
SPOT P CaSO4.2H2O(s)
373K,(100°C)
¾¾¾¾¾
heat
® CaSO4. 1 H O(s) + 3 H O(g)
2
2 22
LIGHT Gypsum Plaster of Paris
During the preparation of Plaster of Paris, temperature should be
Gypsum slows down the rate of quick
setting of cement water paste.
controlled carefully. Otherwise, anhydrous calcium sulphate (CaSO4) will
be formed. Anhydrous calcium sulphate does not set into hard mass when
mixed with water. So, if temperature is not controlled carefully, the Plaster
of Paris obtained will have poor setting property.
More than
CaSO4.2H2O(s) ¾¾¾¾373 K
¾
® CaSO4(s) + 2H2O(g)
Dead burnt plaster
Properties of Plaster of Paris
(1) Plaster of Paris is a white, odourless powder.
(2) At ordinary room temperature, Plaster of Paris absorbs water and
a large amount of heat is liberated.
(3) When mixed with a limited amount of water (50% by mass), it forms
a plastic mass, evolves heat and quickly sets to a hard porous mass
within minutes. This is called the setting process.
During setting, a slight expansion in volume occurs. It is due to this
that it fills the mould completely and gives sharp impression. The
reaction during process is
1 3
CaSO4. H2O(s) + H O(l) ® CaSO4.2H2O(s)
2 2 2
Plaster of Paris Water Gypsum (Hard mass)
Uses of plaster of paris
(1) Plaster of Paris is used in making casts and patterns for moulds and
statues.
(2) Plaster of Paris is used as cement in ornamental casting and for making
decorative materials.
THE
SPOT P
LIGHT
Gypsum on heating gives Plaster of
Paris, on the other hand Plaster of
Paris on hydration gives gypsum.
Fig.21 Ornamental castings made from POP.
(3) Plaster of Paris is used as a fire proofing material and for making
chalks.
(4) Plaster of Paris is used in hospitals for immobilising the affected part
in case of bone fracture or strain.
(5) Plaster of Paris (POP) is used to fill small gaps on walls and roofs.
24
Chemistry
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NCERT QUESTIONS WITH SOLUTIONS
1. You have been provided with three test tubes. One 4. Metal compound A reacts with dilute hydrochloric
of them contains distilled water and the other two acid to produce effervescence.
contain an acidic solution and a basic solution, The gas evolved extinguishes a burning candle. Write
respectively. If you are given only red litmus paper, a balanced chemical equation for the reaction if one
of the compounds formed is calcium chloride.
how will you identify the contents of each test tube?
Ans. CaCO3(s) + 2HCl(aq) ® CaCl2(s) + CO2(g) + H2O(l)
Ans. Step 1- Let us mark the three test tubes as A, B
5. Why do HCl, HNO3, etc., show acidic character in
and C.
aqueous solution while solutions of compounds like
Step 2- A drop of the solution in test tube A is put
alcohol and glucose do not show acidic character?
on the red litmus paper. Same is repeated with Ans. HCl and HNO3 dissociate in the presence of water
solution B and C. If either of them changes the to form hydrogen or hydronium ions.
colour of red litmus to blue, then it is basic. Although aqueous solutions of glucose and alcohol
Therefore, out of three, one is eliminated. contain hydrogen, these cannot dissociate in water
Step 3- Out of the remaining two, any one can be to form hydrogen or hydronium ions. Hence, they
acidic or neutral. Now a drop of basic solution is do not show acidic character.
mixed with a drop of each of the remaining two 6. Why does an aqueous solution of an acid conduct
solutions separately and then a drop of each solution electricity?
is put on the red litmus paper. Ans. Acids dissociate in aqueous solutions to form ions.
If the colour of red litmus turns blue, then that These ions are responsible for conduction of
electricity.
solution is neutral and if there is no change in colour,
7. Why does dry HCl gas not change the colour of the
then that solution is acidic.
dry litmus paper?
This is because acidic and basic solutions neutralise
Ans. Acid do not ionize in the absence of water to liberate
each other. Hence, we can distinguish between the
H3O + which shows acidic nature of a solution.
three types of solutions. Therefore, dry HCl gas does not change the colour
2. Why should curd and sour substances not be kept of the dry litmus paper because it does not contain
in brass and copper vessels? H+ ions.
Ans. Curd and other sour substances contain acids. 8. While diluting an acid, why is it recommended that
Therefore, when they are kept in brass and copper the acid should be added to water and not water
vessels, the metal reacts with the acid to liberate to the acid?
hydrogen gas and harmful products, thereby Ans. It is recommended that the acid should be added
spoiling the food. to water and not water to the acid because the
3. Which gas is usually liberated when an acid reacts process of dissolving an acid in water is exothermic.If
with a metal? Illustrate with an example. How will water is added to acid, since large amount of acid
is present, a large amount of heat is generated.
you test for the presence of this gas?
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11. You have two solutions, A and B. The pH of solution 19. Write an equation to show the reaction between
A is 6 and pH of solution B is 8. Plaster of Paris and water.
Wh ich solution has more hydrogen ion Ans. The chemical equation for the reaction of Plaster
of Paris and water can be represented as-
concentration? Which of this is acidic and which one
1 1
is basic? CaSO4. H2O + 1 H2O ¾¾® CaSO4.2H2O
2 2
Ans. A pH value of less than 7 indicates an acidic solution, Plaster of Paris Water Gypsum
while greater than 7 indicates a basic solution. 20. A solution turns red litmus blue, its pH is likely to be
Therefore, the solution with pH = 6 is acidic and (1) 1 (2) 4 (3) 5 (4) 10
has more hydrogen ion concentration than the Ans. (4) 10
solution of pH = 8 which is basic. 21. A solution reacts with crushed egg-shells to give a
gas that turns lime-water milky. The solution contains
12. What effect does the concentration of H+(aq) ions
(1) NaCl (2) HCl (3) LiCl (4) KCl
have on the nature of the solution?
Ans. (2) HCl
Ans. If the concentration of H+ ions is increased, the 22. 10 mL of a solution of NaOH is found to be
solution becomes more acidic. If the concentration completely neutralised by 8 mL of a given solution
of H+ ions is decreased, the solution becomes less of HCl. If we take 20 mL of the same solution of
acidic or more basic. NaOH, the amount of HCl solution (the same
13. Do basic solutions also have H+(aq) ions ? If yes, then solution as before) required to neutralise it will be
(1) 4 mL (2) 8mL (3) 12 mL (4) 16 mL
why are these basic?
Ans. (4) 16 mL
Ans. Yes, a basic solution also has H +(aq) ions. However, 23. Which one of the following types of medicines is used
their concentration is less as compared to the for treating indigestion?
concentration of OH–(aq) ions which makes the (1) Antibiotic (2) Analgesic (3) Antacid (4) Antiseptic
solution basic. Ans. (3) Antacid
14. Under what soil condition do you think a farmer 24. Write word equations and then balanced equations
would treat the soil of his fields with quick lime for the reaction taking place when -
(1) Dilute sulphuric acid reacts with zinc granules.
(calcium oxide) or slaked lime (calcium hydroxide)
(2) Dilute hydrochloric acid reacts with magnesium
or chalk (calcium carbonate)? ribbon.
Ans. If the soil is acidic and improper for cultivation, then (3) Dilute sulphuric acid reacts with aluminium
to neutralise the acidity of the soil, the farmer would powder.
treat the soil with quick lime or slaked lime or chalk. (4) Dilute hydrochloric acid reacts with iron filings.
15. What is the common name of the compound Ans. (1) Sulphuricacid + Zinc ® Zinc sulphate + Hydrogen
CaOCl2? H2SO4 (aq) + Zn(s) ® ZnSO4 (aq) + H2(g)
(2) Hydrochloric acid + Magnesium ® Magnesium
Ans. The common name of the compound CaOCl2 is
chloride + Hydrogen
bleaching powder. 2HCl (aq) + Mg (s) ® MgCl2 (aq) + H2 (g)
16. Name the substance which on treatment with (3) Sulphuric acid + Aluminium ® Aluminium
chlorine yields bleaching powder? sulphate + Hydrogen
Ans. Calcium hydroxide [Ca(OH)2], on treatment with 3H2SO4 (aq) + 2Al(s) ® Al2(SO4)3 (aq) + 3H2(g)
chlorine, yields bleaching powder. (4) Hydrochloric acid + Iron ® Ferric chloride +
Hydrogen
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EXERCISE # 1
28
Chemistry
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9. Sodium hydrogencarbonate when added to acetic 15. Which of the following statements is not correct?
acid evolves a gas. Which of the following statements (1) All metal carbonates react with acid to give a salt,
are true about the gas evolved? water and carbon dioxide.
(i) It turns lime water milky. (2) All metal oxides react with water to give salt and
acid.
(ii) It extinguishes a burning splinter.
(3) Some metals react with acids to give salt and
(iii) It dissolves in a solution of sodium hydroxide.
hydrogen.
(iv) It has a pungent odour.
(4) Some non metal oxides react with water to form
(1) (i) and (ii) (2) (i), (ii) and (iii) an acid.
(3) (ii), (iii) and (iv) (4) (i) and (iv) 16. During the preparation of hydrogen chloride gas on
10. Which of the following substance will not give carbon a humid day, the gas is usually passed through the
dioxide on treatment with dilute acid? guard tube containing calcium chloride. The role of
(1) Marble (2) Limestone calcium chloride taken in the guard tube is to
(3) Baking soda (4) Lime (1) absorb the evolved gas
11. What happens when a solution of an acid is mixed (2) moisten the gas
with a solution of a base in a test tube? (3) absorb moisture from the gas
(i) The temperature of the solution increases generally. (4) absorb Cl– ions from the evolved gas
(ii) The temperature of the solution decreases. 17. Which of the following phenomena occur, when a
(iii) The temperature of the solution remains the small amount of acid is added to water?
same. (i) Ionisation (ii) Neutralisation
(iv) Salt formation takes place. (iii) Dilution (iv) Salt formation
(1) (i) only (2) (i) and (iii) (1) (i) and (ii) (2) (i) and (iii)
(3) (ii) and (iii) (4) (i) and (iv) (3) (ii) and (iii) (4) (ii) and (iv)
12. An aqueous solution turns red litmus solution blue.
18. Which of the following is/are true when HCl (g) is
Excess addition of which of the following solution
passed through water?
would reverse the change?
(1) It does not ionise in the solution as it is a covalent
(1) Baking powder
compound.
(2) Lime
(2) It forms salt.
(3) Ammonium hydroxide solution
(3) It gives both hydrogen and hydroxyl ion in the
(4) Hydrochloric acid
solution.
13. If a few drops of a concentrated acid accidentally
(4) It forms hydronium ion in the solution due to
spills over the hand of a student, what should be
combination with water.
done?
19. Which of the following are present in a dilute
(1) Wash the hand with saline solution.
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Exercise
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22. Which of the following statements is correct about 29. Which of the following gives the correct increasing
an aqueous solution of an acid and of a base? order of acidic strength?
(i) Higher the pH, stronger the acid (1) Water < Acetic acid < Hydrochloric acid
(ii) Higher the pH, weaker the acid (2) Water < Hydrochloric acid < Acetic acid
(3) Acetic acid < Water < Hydrochloric acid
(iii) Lower the pH, stronger the base
(4) Hydrochloric acid < Water < Acetic acid
(iv) Lower the pH, weaker the base
30. Common salt besides being used in kitchen can also
(1) (i) and (iii) (2) (ii) and (iii) be used as the raw material for making
(3) (i) and (iv) (4) (ii) and (iv) (i) washing soda (ii) bleaching powder
23. The pH of the gastric juices released during digestion (iii) baking soda (iv) slaked lime
is
(1) (i) and (ii) (2) (i), (ii) and (iv)
(1) less than 7 (2) more than 7 (3) (i) and (iii) (4) (i), (iii) and (iv)
(3) equal to 7 (4) equal to 0 31. Identify the correct representation of reaction
24. Which of the following is acidic in nature? occurring during chloralkali process.
(1) 2NaCl(l) + 2H2O(l) ® 2NaOH(l) + Cl2(g) + H2(g)
(1) Lime juice (2) Human blood
(2) 2NaCl(aq) + 2H2O(aq) ® 2NaOH(aq) + Cl2(g)
(3) Lime water (4) Antacid
+ H2(g)
25. Equal volumes of hydrochloric acid and sodium
(3) 2NaCl(aq) + 2H2O(l) ® 2NaOH(aq) + Cl2(aq)
hydroxide solutions of same concentration are mixed
+ H2(aq)
and the pH of the resulting solution is checked with
a pH paper. What can be the colour obtained? (4) 2NaCl(aq) + 2H2O(l) ® 2NaOH (aq) + Cl2(g)
+ H2(g)
(1) Red (2) Yellow
32. Milk of magnesia is an
(3) Green (4) Blue
(1) acid (2) antacid
26. Which of the following is a basic salt?
(3) alkali (4) rock salt
(1) SnCl2 (2) NaCl
33. Which of the following is represented by the formula
(3) NH4Cl (4) CH3COONa NaHCO3?
27. Sodium carbonate is a basic salt because it is a salt (1) Sodium carbonate (2) Baking soda
of (3) Sodium acetate (4) Washing soda
(1) strong acid and strong base 34. One of the constituents of baking powder is sodium
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2. A water soluble base produces ______ ions in so- 4. The acidity of phosphoric acid (H3PO4) is 3.
lutions.
5. Efflorescence is the process of heating a salt.
3. An indicator changes its ______ with change of the
6. Aqueous ammonia is acidic in nature.
nature of the solution.
4. Phenolphthalein gives a ______ colour when added 7. The aqueous solution of sodium chloride is acidic.
to sodium hydroxide solution. 8. Soda ash is hydrated sodium carbonate.
5. Blue litmus turns red when added to ______ 9. The right temperature for heating gypsum during
solution. the manufacture of Plaster of Paris is 273 K.
6. A farmer treats the soil of his field with lime when 10. Plaster of Paris can be stored in any type of
the soil has ______ nature. containers (open or closed or air tight).
7. The pH of an acidic solution is ______ than 7.
Match the column
8. Electrolysis of an aqueous solution of ______
produces hydrogen at cathode, chlorine at anode 1. Match the chemical substances given in Column (I) with
and sodium hydroxide in the solution. their appropriate application given in Column (II).
9. Hydrated copper sulphate contains five molecules
Column-I Column-II
of ______ of crystallization.
10. (a) NaCl + H2SO4 ¾¾ (1) Bleaching powder (i) Preparation of glass
D
® ______ + HCl. (2) Baking soda (ii) Production of H2 and
(b) 2P + 5H2SO4(conc.) ¾¾ Cl2
D
® ______ +2H2O + 5SO2. (3) Washing soda (iii) Decolourisation
(4) Sodium chloride (iv) Antacid
(c) 3Fe + 4H2O ¾® .............+ H2
(d) Fill in the missing data in the following table 2. Match the acids given in Column (I) with their correct
Salt obtained from source given in Column (II).
31
CBSE : Class X
ALLEN
Crossword puzzle
Complete the puzzle using the clues about chemical reactions shown below.
1
2 3
4 5
7
8
9 10 11
12
13 14
15 16
17 18
19
20
21 22 23
24
25
Across Down
4. Chemical that is corrosive, has a sour taste and a 3. Chemical that neutralises an acid.[4]
pH less than 7.[4] 5. Chemical that changes colour in acids and bases.[9]
6. Neutral substances have this pH.[5] 8. Common indicator used in liquid or paper form.[6]
9. Acid and base neutralise to form ____ and water.[4] 12. Common name for sodium hydroxide is ____
soda.[7]
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Exercise
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Chemistry
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EXERCISE # 1 ANSWER KEY
Interview with hydrochloric acid
1. HCl 2. Below 7 3. Strong acid 4. Blue litmus solution
5. In stomach, help in digestion
6. Household cleaning products (like: drain cleaner), also in production of gelatin and leather processing.
7. Yes, strong base like NaOH 8. Liberate H2 gas
9. A big fizz will result because of evolution of CO2
Neutralisation equation
1. HCl + NaOH ® NaCl + H2O 2. HNO3 + NaOH ® NaNO3+ H2O
3. 2HNO3+Zn(OH)2 ® Zn(NO3)2+ 2H2O 4. H2SO4 + Ca(OH)2 ® CaSO4 + 2H2O
5. 2HCl + Ca(OH)2 ® CaCl2 + H2O 6. H2SO4 + 2NH4OH ® (NH4)2SO4 + H2O
Multiple choice questions
Que. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans 1 3 2 2 4 3 4 1 2 4 4 4 2 3 2
Que. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans 3 2 4 1 1 3 4 1 1 3 4 4 4 1 3
Que. 31 32 33 34 35
Ans 4 2 2 2 2
Fill in the blanks
1. an acid 2. hydroxide(OH–) 3. colour 4. pink
5. an acidic 6. acidic 7. less 8. sodium chloride
9. water 10. (a) NaHSO4 (b) 2H3PO4 (c) Fe3O4
(d)
Salt obtained from
Name of the salt Formula Base Acid
(i) Ammonium chloride NH4Cl NH4OH HCl
(ii) Copper sulphate CuSO4 Cu(OH)2 H2SO4
(iii) Sodium chloride NaCl NaOH HCl
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Exercise
True/False
1. False 2. True 3. False 4. False 5. False
6. False 7. False 8. False 9. False 10. False
Match the column
1. (1) ® (iii) ; (2) ® (iv) ; (3) ® (i) ; (4) ® (ii) 2. (1) ® (iv) ; (2) ® (iii) ; (3) ® (ii) ; (4) ® (i)
3. (1) ® (ii) ; (2) ® (iii) ; (3) ® (iv) ; (4) ® (i) 4. (1) ® (iii) ; (2) ® (i) ; (3) ® (ii) ; (4) ® (iv)
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CBSE : Class X
ALLEN
Crossword puzzle
1
C A R B O N I C
L
2 3
E L B A S E
4 5
A C I D A I
6
N T S E V E N
7
I M O R E D
8
N U I L
9 10 11
G S A L T C L E A N I N G
12
C L A T
13 14
A L K A L I T M
U A I O U
15 16
S L M R E D S S
17 18
T I E L R E D
I 19
W S E V E N V
A 20
C S E A
21 22 23
L I T M U S C A R B O N I C
24
P E C I
25 D
H Y D R O C H L O R I C
D
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Chemistry
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EXERCISE # 2
Very short answer type questions 7. When zinc metal is treated with a dilute solution of
1. Name the acids present in (i) vinegar (ii) lemon (iii) a strong acid, a gas is evolved, which is utilised in
orange. the hydrogenation of oil. Name the gas evolved.
Write the chemical equation of the reaction involved
2. Which is a stronger acid and why? HCl or and also write a test to detect the gas formed.
CH3COOH
8. Name the gas evolved when dilute sulphuric acid
3. Name the gas which is liberated at cathode during react with sodium carbonate. Write the chemical
the electrolysis of mineral acid. equation for the reaction involved.
4. How alkalis differ from bases? Explain. 9. What happens when nitric acid is added to egg
5. Why does copper not react with dil. H 2SO4 or dil. shell?
HCl? 10. Name the acid present in ant sting and give its
6. Name the metals which are soluble only in aqua chemical formula. Also give the common method
regia. to get relief from the discomfort caused by the ant
sting.
7. Which type of acid & base forms only the normal
salts? 11. Why do we not categorise metal oxides as salts while
we categorise metal sulphide as salts?
8. What will happen to the concentration of [H+] ions
in a solution if NaOH is added to water? 12. A student prepared solutions of (i) an acid and
(ii) a base in two separate beakers. She forgot to
9. When concentrated acid is diluted, does the pH get
label the solutions and litmus paper is not available
higher or lower?
in the laboratory. Since both the solutions are
10. Name a salt (prepared by using sodium chloride) colourless, how will she distinguish between the two?
which does not contain water of crystallization.
13. What does pH stand for? What does a pH scale
Short answer type questions indicate?
1. Write down the molecular formula for : Sulphuric 14. What happen when electric current is passed
acid, Nitric acid, Phosphoric acid, Carbonic acid. through brine? Give reaction.
Hydrochloric acid, citric acid, acetic acid, nitric acid, 16. What happens when crystals of washing soda are
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Exercise
formic acid, sulphuric acid. left open in dry air. What is this named as?
17. How would you distinguish between baking powder
4. Select the formulae of acids, bases and salts from
and washing soda by heating?
the following list :
18. Salt A commonly used in bakery products on heating
NaCl, NaOH, H 3 PO 4 , Na 2 CO 3 , Ca(OH) 2 ,
gets converted into another salt B which itself is used
CuSO4.5H2O, H2SO4,H2CO3, HCl, NaHCO3,
for removal of hardness of water and a gas C is
Na2CO3.10H2O, Al(OH)3, KCl.
evolved. The gas C when passed through lime water,
5. How can you prepare acid-base indicator at home? turns it milky. Identify A, B and C.
6. What will be the action of the following substances 19. How is Plaster of Paris obtained ? What reaction is
on litmus paper? involved in the setting of a paste of Plaster of Paris?
Dry HCl gas, Moistened NH3 gas, Lemon juice, 20. A blue salt becomes white on heating. With the help
Carbonated soft drink, Curd, Soap solution. of a reaction explain the change in colour.
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CBSE : Class X
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Long answer type questions 9. A sanitary worker uses a white chemical having
1. With reference to Active Chemistry 2.3, what would strong smell of chlorine gas to disinfect the water
happen if following changes are made? tank.
(a) In place of zinc granules, same amount of zinc (i) Identify the compound.
dust is taken in the test tube. (ii) Write the chemical equation for its preparation.
(b) In stead of dilute sulphuric acid, dilute (iii) Write its uses.
hydrochloric acid is taken.
10. For making cake, baking powder is taken. If at home
(c) In place of zinc, copper turnings are taken. your mother uses baking soda instead of baking
(d) Sodium hydroxide is taken in place of dilute powder in cake,
sulphuric acid and the tube is heated. (a) how will it affect the taste of the cake and why?
2. Identify the compound X on the basis of the reactions
(b) how can baking soda be converted into baking
given below. Also, write the name and chemical
powder?
formulae of A, B and C.
(c) what is the role of tartaric acid added to baking
+Zn
A + H 2(g) soda?
Compound +HCl
B + H 2O
X +CH 3COOH 11. A metal carbonate X on reacting with an acid gives
C + H 2O
a gas which when passed through a solution Y gives
3. While constructing a house, a builder selects the carbonate back. On the other hand, a gas G
marble table tops for the kitchen where vinegar and that is obtained at anode during electrolysis of brine
juices of lemon, tamarind etc., are more often used is passed on dry Y, it gives a compound Z, used for
for cooking. Will you agree to this selection and why? disinfecting drinking water. Identity X, Y, G and Z.
4. (a) What will you observe when dil. HCl is added 12. A compound of sodium is used in kitchen to make
to a small amount of copper oxide in a beaker? pakoras crispy. It is also used to remove acidity in
stomach.
(b) Aqueous solution of HCl shows acidic charac-
ter. But the aqueous solution of glucose fails to (i) Identify the compound.
do so. Why? (ii) State how it is manufactured.
(c) Why curd and sour substances should not be
(iii) Write an equation to show the effect of heat on
kept in brass and copper vessels?
this compound.
5. Dry HCl gas does not affect a dry blue litmus paper,
(iv) Write its uses.
whereas it changes a moist blue litmus paper to red.
Explain. 13. A sulphate salt of Group 2 element of the Periodic
Table is a white, soft substance, which can be
CBSE-2021\Module\ADC_IHL\10th\Chemistry\3._Acids Bases and Salts\Exercise
8. Discuss chlor-alkali process for manufacturing so- 15. Comment on the statement : Are the crystals of salts
dium hydroxide. really dry?
36