ACIDS, BASES AND SALTS

4
CHAPTER

Substance Acid present

CONTENTS 1. Orange, lemon Citric acid, ascorbic acid
(vitamin C)
 INTRODUCTION
2. Apple Malic acid
 ACIDS
3. Tamarind (imli), Tartaric acid
 BASES grape

 INDICATOR 4. Vinegar Acetic acid

5. Curd Lactic acid
INTRODUCTION 6. Tomato Oxalic acid
A chemical substance is a kind of matter that 7. Gastric juice Hydrochloric acid
cannot be separated into any other kind of matter
by physical method. Pure substances have 8. Tea Tannic acid
uniform composition and always have some 9. Red ants Formic acid
properties like taste, smell, texture, etc.
Aqueous solutions of acids are generally sour in
We use several materials in our daily life for taste. Acids turn blue litmus red, conduct
various purposes. Some of them are sweet in taste, electricity and react with bases to form salts and
some are salty, some are sour and some are bitter. water. [Bases and salts are discussed a little later.]
The sweet taste of a substance is due to sugar An acid may be defined in various ways. Here, we
present in it. Why are certain food materials sour shall study the definition given by Liebig in 1838.
in taste like curd, vinegar, tamarind, lemon juice, According to Liebig, an acid is a compound
green mango, tomatoes, orange, unripened grapes, which contains hydrogen that can be replaced
others are sweet in taste whereas some are salty partially or wholly by a metal or a group of
and some are bitter in taste ? What substance are elements acting like a metal, to produce a salt.
present in which make them sour, bitter or salty ?
For example, sulphuric acid (H2SO4) is an acid
ACIDS because of the following reasons.
(i) It contains hydrogen atoms in its molecule.
The term 'acid' has its origin in the Latin word
acidus, meaning sour. In fact, anything that tastes (ii) The two hydrogen atoms present in its
sour contains an acid. For example, lemon juice, molecule can be replaced partially or wholly
tomato, vinegar, etc., all taste sour. So, each of by a metal like sodium (Na) to produce
these substances must contain an acid. Some of sodium hydrogensulphate or sodium sulphate.
the naturally occurring substances that contain
acids are given in Table
 –1 H+
NaHSO4 (partial replacement) common acids that are generally used in the
+Na + sodium hydrogensulphate
laboratory are hydrochloric acid (HCl),
H2SO4
sulphuric acid (H2SO4) and nitric acid (HNO3).
–2H+
Na2SO4 (complete replacement) These are inorganic acids, also called mineral
+2Na + sodium sulphate
acids. Hydrochloric acid is also present in the
The hydrogen atoms in H2SO4 can also be gastric juice in our stomach.
partially or wholly replaced by a group of
2. Concentrated and dilute acids : An acid
elements, like an ammonium ion ( NH 4 ) to form
solution may be concentrated or dilute
ammonium hydrogensulphate (NH4HSO4) or depending upon the amount of the acid
ammonium sulphate ((NH4)2SO4) respectively. present in the solution. Concentrated and
–1 H+
NH4HSO4 (partial replacement) dilute solutions of acids are generally used in
+ NH 4 ammonium hydrogensulphate laboratories. Let us see what these acids are.
H2SO4
–2H+
An acid is generally used as solution in water.
(NH4)SO4 (complete replacement)
+2 NH 4 ammonium sulphate When the solution contains a larger amount
of the acid, it is said to be concentrated,
The substances NaHSO4, Na2SO4, NH4HSO4 and whereas a dilute solution contains smaller
(NH4)2SO4 are all salts. amount of the acid.

(iii) The acid dissolves in water to make a solution Thus, concentrated and dilute solutions of an
that turns blue litmus red. acid differ from each other only in the
proportions of the acid and water in them.
(iv) It is sour in taste.
3. Strong and weak acids : The strength of an
(v) It reacts vigorously with a base to produce a
acid is determined by the amount of hydrogen
salt.
ions (H+) that the acid provides when
The hydrogen atoms present in an acid that can be dissolved in water.
replaced by a metal or a group of elements are
Some of the acids, when dissolved in water,
called replaceable hydrogen or acidic hydrogen.
get almost completely dissociated to provide
 Classification of Acids : hydrogen ions. These acids are called strong
Depending upon the elements present, acids may acids. For example, hydrochloric acid (HCl),
be classified as follows. nitric acid (HNO3) and sulphuric acid
(H2SO4) are strong acids.
(i) Oxyacid : Acids that contain both hydrogen
and oxygen are called oxyacids. For example, On the other hand, there are some acids
nitric acid (HNO3), sulphuric acid (H2SO4) which when dissolved in water, are only
and phosphoric acid (H3PO4) are oxyacids. incompletely dissociated to give hydrogen
ions. These are called weak acids. For
(ii) Hydracid : Acids that contain hydrogen and example, carbonic acid (H2CO3) and acetic
other nonmetallic element(s), except oxygen, acid (CH3COOH) are weak acids.
are called hydracids. For example,
hydrochloric acid (HCl) and hydrocyanic acid  Basicity of an acid :
(HCN) are hydracids. The basicity of an acid is the number of
Acids may also be classified as follows. replaceable hydrogen atoms present in a molecule
of the acid.
1. Organic and inorganic acids : All sour things
that we use in our daily food contain acids. The acid which contains one replaceable
These acids are organic acids. Some of the hydrogen atom in its molecule is called a
 monobasic acid and its basicity is 1. The acids 3. By the action of an acid on the salt of
containing two or three replaceable hydrogen another acid : An acid having higher boiling
atoms in their molecules are called dibasic acids point can react with the salt of an acid of
or tribasic acids and their basicities are 2 or 3. lower boiling point to produce an acid. For
example, NaCl is a salt of HCl. The boiling
Examples of a few acids with their basicities are
point of HCI is lower than that of H2SO4,
given in the table below.
When NaCl (salt of HCl) reacts with H2SO4,
Acid Basicity HCl is formed.
HCl 1 H2SO4 + NaCl  NaHSO4 + HCl
HNO3 1  General Properties of Acids :
H2SO4 2 1. They are sour in taste.
H3PO4 3 2. They turn blue litmus paper red.
 Preparation of Acids : 3. Acids show acidic properties only in the
There are several methods for preparing acids. presence of water. This can be demonstrated
Some of them are discussed here. by the following activity.

1. Synthetic method : In the synthetic method, Dry hydrogen chloride gas does not produce
acids are prepared by direct combination of H+ ions in the absence of moisture/water. It
elements. For example, hydrogen and produces H+ ions only in the presence of
chlorine react together under the action of an moisture/water.
electric spark to produce hydrogen chloride HCl + H2O  H3O+ + Cl–
gas which is absorbed in water to give
4. Their aqueous solutions conduct electricity.
hydrochloric acid.
electric spark
5. They react with certain metals with the
H 2  Cl 2     2HCl evolution of hydrogen gas.
Similarly, sulphuric acid may be obtained EXAMPLES :
from its elements as follows.
Metals like potassium, sodium, calcium,
S  O 2  SO 2 magnesium, aluminium, zinc and iron can react
sulphur oxygen sulphur dioxide
with the aqueous solution of an acid to evolve
2SO 2  O 2  2 SO3 hydrogen gas.
sulphur trioxide
2Na + 2HCl  2 NaCl  H2 
sodium chloride hydrogen
SO3  H 2O  H 2 SO 4
sulphuric acid
Fe + 2HCl  FeCl2  H2 
2. By dissolving acidic oxides in water : Some ferrous chloride

oxides dissolve in water to give acids. These

oxides are called acidic oxides. For example, Mg + H2SO4  MgSO 4  H2 
magnesium sulphate
sulphur trioxide (SO3) dissolves in water to
give H2SO4. 2Al + 3H2SO4  Al2 (SO 4 )3  3H 2 
alu min ium sulphate
SO3 + H2O  H2SO4
Silimlarly, carbon dioxide (CO2) dissolves in These reactions show certain metals can displace
water to produce carbonic acid (H2CO3). hydrogen from acids to form salts.
CO2 + H2O  H2CO3
 Nitric acid reacts only with magnesium and carbonate. In case of fire, the plunger is struck
manganese. In both the reactions hydrogen gas is against a hard surface to break the bottle. As a
evolved. result, sulphuric acid comes in contact with the
Mg + 2HNO3  Mg ( NO3 ) 2  H 2  sodium carbonate. The carbon dioxide gas which
magnesium nitrate comes out is directed towards the fire.

Mn + 2HNO3  Mn ( NO3 ) 2  H 2 
Plunger
magnesium nitrate

Nitric acid does not behave like this with any

H2SO4
other metal.
6. They can react with bases to produce salts
and water. [We will study these reactions Sodium carbonate
when we deal with the bases.] solution
Nozzle
7. They react with carbonates and
hydrogencarbonates to form carbon dioxide
and a salt. 7. Acids react with the oxides of metals to form
salts and water.
Na 2CO3 + 2HCl
sodium carbonate
Na 2 O + 2HCl  2NaCl + H2O
sodium oxide
 2 NaCl + H 2O + CO2 
sodium carbonate water carbon dioxide
CuO + H2SO4  CuSO 4 + H 2O
cuprix oxide cupric sulphate water
Na2CO3 + H2SO4 

Na 2SO 4 + H2O + CO2 CaO + 2HCl CaCl2 + H 2O

calcium oxide calcium chloride water
sodium sulphate

CaCO3 + 2HCl  All acids contain hydrogen :

calcium carbonate
All acids have similar chemical properties. This
 CaCl2 + H2O + CO2 indicates that all acids must have something in
calcium chloride common. You know, all acids react with metal to
  NaHCO3 + HCl  NaCl + H2O + CO2 produce hydrogen gas. Thus, hydrogen is the
sodium common substance present in all acids. But all
hydrogencarbonate
compounds containing hydrogen are not acids.
2NaHCO3 + H2SO4  Na2SO4 + 2H2O + CO2 For example, hydrochloric acid and sulphuric acid
This activity may be used as a method of contain hydrogen and these are acids. On the
determining if a given substance is an acid or not. other hand, alcohol and glucose also contain
hydrogen but they are not acids.
 Fire extinguisher :
The acidic properties of acids are due to the fact
The reaction between sulphuric acid and sodium
that they produce H+ ions in aqueous solution.
carbonate or sodium hydrogencarbonate is
utilized in the making of fire extinguisher as  Uses of Acids :
shown in Figure. A sealed glass bottle filled with
The following table shows the uses of some
dilute sulphuric acid is kept inside a container
organic and inorganic acids.
filled with an aqueous solution of sodium
 Acid Uses BASES
Organic acids
Bases are substances that are soapy to touch and
Citric acid 1. As a preservative for food bitter in taste.
2. As a flavouring agent A base is a substance, usually the oxide or the
Ascorbic acid In the treatment of bone hydroxide of a metal, which can react with an acid
marrow and scurvy diseases to produce salt and water.
(also called
vitamin C) For example, sodium oxide (Na2O), calcium oxide
(CaO), cupric oxide (CuO), iron oxides (FeO,
Acetic acid Added to pickles to make Fe2O3 etc.), sodium hydroxide (NaOH) and
them sour
calcium hydroxide (Ca(OH)2 are all bases.
Tartaric acid A component of baking power
Certain substances are also called bases, though
(baking powder is a mixture
they do not fit into the above definition. For
of sodium hydrogencarbonate
and tartaric acid) example, ammonia (NH3). It forms salt with an
acid without giving water. So, it should not be
Inorganic acids treated as a base. But ammonium hydroxide
Hydrochloric 1. Its presence in the gastric (NH4OH), the aqueous solution of NH3, is a base
acid juice helps digestion of food as it reacts with an acid to give salt and water
we eat. NH4OH + HCl  NH4Cl + H2O
2. As a bathroom cleaner  Alkalis :
3. In the manufacture of
Bases that are soluble in water are called alkalis.
polyvinyl chloride (PVC)
For example, sodium hydroxide, potassium
Nitric acid 1. Nitric acid present in hydroxide, calcium hydroxide are soluble in
rainwater forms nitrates in the water. Therefore, they are alkalis. But bases like
soil which are then used by copper hydroxide (Cu(OH)2 ferric hydroxide
plants to obtain nitrogen. (Fe(OH)3), aluminium hydroxide (Al(OH)3 do not
2. In the manufacture of dissolve in water. They are, therefore, not alkalis.
fertilizers like ammonium Hence, all alkalis are bases, but all bases are not
nitrate alkalis. Some of the bases are listed here in Table.
3. In making explosives like Oxides Soluble Insoluble
TNT and dynamite hydroxides hydroxides
Sulphuric acid 1. In storage batteries
Sodium Sodium hydroxide Ferric hydroxide
2. In the manufacture of monoxide (NaOH) (Fe(OH)3).
fertilizers, paints and (Na2O)
pigments, detergents and
artificial fibre Calcium Potassium Aluminium
oxide (CaO) hydroxide (KOH) hydroxide
3. In the manufacture of
hydrochloric acid and alum (Al(OH)3)

Phosphric acid In fertilizer and detergent Cupric oxide Calcium

industries (CuO) hydroxide
(Ca(OH)2)
Boric acid 1. In the manufacture of glass, ZnO
glazes and enamels, leather, Ammonium
hydroxide
paper, adhesives and explosives
NH4OH
2. Widely used in detergents
Lime water, baking soda and washing soda are all
3. As a grain preservative bases
 Preparation of Bases : 4. By the action of an alkali on a salt solution
For example, when an aqueous solution of
 Bases can be prepared by the following methods.
sodium hydroxide is added to an aqueous
1. By the direct union of a metal with oxygen solution of magnesium sulphate, magnesium
Some metals when heated in air or oxygen hydroxide gets precipitated and sodium
form the oxides of the metals. sulphate remains in the solution.
4Na + O2  2Na 2O MgSO4 + 2NaOH  Mg (OH) 2  + Na 2SO 4
sodium oxide magnesium sodium
hydroxide sulphat
4K + O2  2K 2 O
potassium oxide General Properties of Bases

2Ca + O2  2CaO 1. The solutions of bases in water give a soapy

calcium oxide
touch. When dissolved in water they produce
These oxides when dissolves in water make the hydroxide ions (OH–) in solution.
hydroxides of metals. H O
NaOH 
2
 Na+ + OH–
Na2O + H2O  2NaOH
H O
Ca(OH)2 
2
 Ca2+ + 2OH–
K2O + H2O  2KOH
H O
CaO + H2O  Ca(OH)2 Mg(OH)2 
2
 Mg2+ + 2OH–

2. By the action of water or steam on some 2. They turn red litmus paper blue.
active metals Some active metals like sodium Take some soap solution in a test tube. Dip
and potassium react with cold water to form the tip of a red litmus paper into it. You will
hydroxides with the evolution of hydrogen see that red litmus paper turns blue. This
gas. indicates that the soap solution contains a
base.
2Na + 2H2O  2NaOH + H2
3. They react with acids to produce salt and
Magnesium reacts with steam to form
water.
magnesium oxide with the evolution of
hydrogen gas. NaOH + HCI  NaCl + H2O
Mg + H2O  MgO + H 2 2KOH + H2SO4  CuSO4 + 2H2O
magnesium oxide
Cu(OH)2 + H2SO4  CuSO4 + 2H2O
On passing superheated steam over red-hot
iron, ferrosoferric oxide is formed and In these reactions, the acid and the base
hydrogen gas is evolved. neutralize each other. Therefore, these
reactions are called neutralization reactions.
3Fe  4H 2O  Fe3O 4  4H 2 
iron steam ferrosoferric hydrogen Thus, a neutralization reaction may be
(red -hot) (superheated) oxide defined as a reaction between an acid and a
3. By heating carbonates of some metals When base, producing salt and water.
calcium carbonate is heated, calcium oxide This neutralization reaction may be explained
and carbon dioxide are formed. as follows. You know, all acids provide H+
CaCO3  CaO + CO2 ions and all bases provide OH– ions in
aqueous solution. Let us see what happens
 Similarly, when zinc carbonate is heated, zinc when HCl and NaOH react together.
oxide and carbon dioxide are formed
HCl + NaOH  NaCl + H2O
ZnCO3  ZnO + CO2
 or H+ + Cl– + Na+ + OH– Some of the bases, when dissolved in water, get
almost completely dissociated to provide
 Na+ + Cl– + H2O
hydroxide ions. These bases are called strong
or H+ + OH–  H2O bases. (Bases soluble in water are also called
Thus, during neutralization of an acid with a alkalis.) For example, sodium hydroxide and
base or vice versa H+ ions (from acid) and potassium hydroxide are strong bases.
OH– ions (from base) combine to produce
But there are bases which, when dissolved in
H2O molecules.
water, get only partially dissociated to give
4. The oxides which produce acids in aqueous hydroxide ions. These are weak bases. For
solutions are called acidic oxides which are example, magnesium hydroxide and ammonium
usually the oxides of nonmetals. Acidic
hydroxide are weak bases.
oxides react with bases to give salts and
water. Acidity of a Base :
2NaOH + CO 2  Na 2 CO3  H 2O The acidity of a base is defined as the number of
Carbon dioxide sodium carbonate water hydroxyl (OH) groups present in a molecule of
Ca(OH)2 + CO 2  CaCO3  H 2O the base.
Carbon dioxide calcium carbonate water
In each molecule of NaOH, KOH and NH4OH
5. When a base is heated with an ammonium only one hydroxyl group is present. Therefore, the
salt, ammonia gas, another salt and water are acidity of all these bases is 1.
produced. For example, when sodium
In Ca(OH)2 and Ba(OH)2 there are two hydroxyl
hydroxide is heated with ammonium chloride,
groups present in each molecule. Hence, their
the products formed are sodium chloride,
water and ammonia gas. acidity is 2.

NaOH + NH 4 Cl Similarly, the acidity of Fe(OH)3 and Al(OH)3 is 3.

ammonium chloride
The base containing one hydroxyl group in a
 NaCl + H2O + NH 3  molecule is said to be mono acidic base, that
sodium chloride ammonia containing two hydroxyl groups is called diacidic
Ammonia gas is recognized by its pungent base, and that containing three hydroxyl groups is
smell. called triacidic base. Thus, NaOH, Ca(OH)2 and
Fe(OH)3 are monoacidic, diacidic and triacidic
6. Bases react with certain salts to produce
bases respectively.
another salt and another base. For example,
when NH4OH is added to a solution of Common bases and their uses :
Al2(SO4)3, (NH4)2SO4 and Al(OH)3 are
produced. Table lists some of the common bases and their
uses.
6NH 4OH  Al2 (SO 4 ) 
ammonium hydroxide aluminium sulphate Bases Uses
2Al(OH)3  3(NH 4 ) 2 SO 4 Sodium hydroxide 1. In the manuacture of
aluminium hydroxide aluminimum sulphate (salt)
soaps, textile, paper,
 Strong Bases and Weak Bases : medicines
The strength of a base is determined by the 2. In the refining of
amount of hydroxide ions (OH–) that the base petroleum
provides when dissolved in water.
Ammonium hydroxide 1. As a reagent in the
laboratory
 2. In making fertilizers, Litmus paper : Blue or red litmus paper is
rayon, plastics and prepared by dipping a strip of filter paper in
blue or red litmus solutions. The paper is then
dyes
removed from the solution and dried.
Calcium hydroxide 1. In making cement
Blue litmus paper turns red in an acidic
and mortar solution and red litmus paper blue in a basic
2. In making bleaching solution.
powder Phenolphthalein : It is a colourless
3. In whitewashing compound. An alcoholic solution of
phenolphthalein is used as an indicator. It is
4. In removing acidity colourless in an acidic solution, but
of soils becomes pink (red) in basic solution:
Methyl orange : A very small amount of
INDICATOR
 solid methyl orange is dissolved in hot
An indicator may be defined as follows. water and filtered. The filtrate is used as an
indicator. It turns red in acid solutions and
An acid-base indicator is defined as a substance yellow in basic solutions.
that assumes different colours in acidic, basic
Household indicators :
and neutral solutions.
Some useful household indicators are discussed
Litmus, methyl orange and phenolphthalein are
below.
some of the most commonly used acid-base
indicators that change colour as follows. (i) Turmeric juice It is yellow in colour. It
remains yellow in acidic or neutral
Basic solutions but turns deep brown in a basic
Acid Neutral
Indicator solutio solution.
solution solution
n (ii) Red-cabbage juice Itself purple in colour, it
Blue litmus Red No No turns red in an acid solution, but green in a
solution change change in basic solution.
in colour The household indicators may be used to test
colour whether some of the substances of daily use as
listed below are acidic or basic.
Red litmus No Blue No
solution change in change in
colour colour Acidic substances Basic substance
Methyl Red Yellow Orange Vitamine C tablets Antacids
orange (ascorbic acid)
Phenolphtha Colourles Red Colourless Toothpaste
lein s Soap solution
Lemon juice
Litmus : It is a natural dye made from small Washing soda solutions
Orange juice
plants called lichens. Blue and red litmus
solutions are prepared from two different Tomato juice
varieties of lichens. Vinegar

Olfactory indicators : EXAMPLES
There are substances like onion juice, vanilla Na2SO4 obtained in the reaction between H2SO4
essence and clove oil which by change of their and NaOH is a normal salt because it is formed
smell indicate whether the sample solution is by the complete replacement of both the H
acidic or basic. These are called olfactory atoms of H2SO4,
indicators.
Similarly, calcium su1phate (CaSO4), sodium
You have learnt that in neutralization reactions phosphate (Na3PO4) and potassium phosphate
an acid and a base react to produce salt and (K3PO4) are also normal salts.
water. For example, the neutralization reaction
2. Acid salt : When a polybasic acid is not
between NaOH and HCl gives the salt NaCl
completely neutralized by a base, the salt
and water.
produced will contain replaceable hydrogen
NaOH + HCl  NaCl + H2O atoms. Hence, it may further take part in the
reaction with the base as an acid. Such a salt is
Thus, a salt may be defined as follows.
called an acid salt. For example, the salt
A salt is a compound formed by the reaction of NaHSO4 produced in the reaction between
an acid with a base in which the hydrogen of NaOH and H2SO4 is an acid salt because it is
the acid is replaced by the metal. capable of further reaction with the base NaOH
In polybasic acids, more than one hydrogen to produce the normal salt Na2SO4.
atoms are present in a molecule. These H2SO4 + NaOH  NaHSO4 + H2O
hydrogen atoms can be replaced partially or
completely. So, two kinds of salts are possible. NaHSO4 + NaOH  Na2SO4 + H2O
Thus, an acid salt may be defined as follows.
(i) H2SO4 + NaOH  NaHSO 4 + H 2O
sodium water water
hydrogensulphate A salt that contains replaceable hydrogen atoms
is called an acid salt.
Here, partial replacement of hydrogen
atoms from H2SO4 has resulted in the EXAMPLES :
formation of sodium hydrogensulphate. NaHSO4, NaH2PO4 and Na2HPO4 are examples
of acid salts.
(ii) H2SO4 + 2NaOH  Na 2SO 4 + 2H 2O
sodium sulphate water
3. Basic salt : When a polyacidic base reacts
Here, complete replacement of hydrogen with lesser amount of acid than is necessary for
atoms from H2SO4 has resulted in the complete neutralization, the salt produced
formation of sodium sulphate. NaHSO4 and contain hydroxyl group(s) (OH) also. Such a
Na2SO4 represent two kinds of salts. salt is called a basic salt.

Types of Salts : EXAMPLES :

The different types of salts are: normal salt, 1 mole of Pb(OH)2 requires 2 moles of HCl for
acid salt, basic salt and double salt. complete neutralization. But when 1 mole of
Pb(OH)2 is made to react with 1 mole of HCl,
1. Normal salt : A salt that does not contain some Pb(OH)2 is left unreacted. The salt
any replaceable hydrogen atoms or hydroxyl produced is not PbCl2, but Pb(OH)Cl.
groups is
Pb(OH)2 + HCl  Pb(OH)Cl + H2O
lead oxychloride
 Similarly, when one mole of Bi(OH)3 is reacted NaOH + HCl  NaCl + H2O
with 1 mole of HNO3, the salt Bi(OH)2NO3 is
CuO + 2HCl CuCl2 + H2O
formed.
3. By direct union of a metal and a
Bi(OH)3 + HNO3  Bi(OH)2NO3 + H2O
nonmetal : Sodium and chlorine combine
Salts like Pb(OH)Cl and Bi(OH)2NO3 contain directly to form sodium chloride.
the OH group. These salts are called basic salts,
2Na + Cl2 2NaCl
because they can further react with the acids to
form H2O and the corresponding normal salts. Similarly, when sulphur is heated with iron
filings, ferrous sulphide (FeS) is formed.
Pb(OH)Cl + HCl  PbCl2 +H2O
4. By the union between an acidic oxide and
Bi(OH)2NO3 + HNO3 + Bi(OH)(NO3)2 + H2O
a basic :
Bi(OH)(NO3)2 + HNO3 Bi(NO3)3 + H2O
CO 2  CaO  CaCO3
Thus, a basic salt is formed when a poly acidic carbon dioxide calciumoxide calcium carbonate

base reacts with a lesser amount of an acid than SO3  Na 2O  Na 2SO 4

is necessary for the formation of a normal salt. sulphurtrioxide sodium oxide sodiumsulphate

4. Double salt : In a double salt, there are two 5. By the reaction between a metal and a
different negative ions and/or positive ions. For base : When zinc is heated with an aqueous
example, the mineral dolomite, CaCO3·MgCO3, solution of NaOH, sodium zincate (salt) is
contains both Ca2+ and Mg2+ ions. Hence, it is a formed with the evolution of hydrogen gas.
double salt. Potash alum, K2SO4·Al2(SO4)3
General Properties of Salts :
24H2O, also is a double salt.
1. Reaction with an acid : When a salt reacts
Double salts exist only in the solid state. When
with an acid, another salt and acid are
dissolved in water, they break up into a mixture
formed. For example, when sodium
of two separate salts. For example, when potash
chloride is heated with sulphuric acid,
alum is dissolved in water, it breaks up as
sodium hydrogensulphate (at low
follows.
temperature) and then sodium sulphate (at
K2SO4 2K+ + SO 24 high temperature) are produced and
hydrogen chloride gas is evolved.
Al2(SO4)3 2Al3+ + 3SO 24
NaCl + H2SO4  NaHSO4 + HCl
 Preparation of Salts :
(at low temperature)
1. By the reaction between metal and acid
2NaCl + H2SO4  Na2SO4 + 2HCl
Certain metals (for example, Zn and Mg)
react with HCl or H2SO4 to form salt and (at high temperature)
hydrogen. 2. Reaction with a base : A salt reacts with a
Zn + 2HCl  ZnCl2 + H2 base to produce another salt and base.

Zn + H2SO4  ZnSO4 + H2 (NH4)2SO4 + 2NaOH  Na2SO4 + 2NH4OH

2. By the reaction between an acid and a 3. Reaction with a metal : Sometimes, a salt
base : All acid-base reactions solution may react with a metal. For
(neutralization reactions) produce salts. example, when an iron nail is dipped into
 an aqueous solution of copper sulphate,  Uses of Salts :
copper gets deposited on the surface of the The following table lists uses of some salts.
nail and the ferrous sulphate formed
remains in the solution. Salts Uses
Sodium chloride 1. An essential requirement of
CuSO4 + Fe  FeSO4 + Cu
our food
This reaction shows that iron is more
2. In the preservation of food
reactive than copper.
3. In curing fish and meat
Thus, more reactive metal can displace a
less reactive metal from a solution of its 4. In making a freezing mixture
salt. which is used by icecream
vendors
4. Behaviour of salts towards water :
5. In the manufacture of soaps
When a salt is dissolved in water, the solution
may be neutral, acidic or alkaline. This Sodium 1. As washing soda for cleaning
depends upon the nature of the salt used. carbonate clothes

(i) A normal salt derived from a strong acid 2. Used in the manufacture of
and a strong base gives a neutral solution. glass, paper, textiles, caustic
For example, the aqueous solutions of soda, etc.
NaCl and K2SO4 are neutral to litmus. 3. In the refining of petroleum
(ii) A normal salt derived from a weak acid 4. In fire extinguishers
and a strong base gives an alkaline
Sodium 1. Used as baking soda
solution. For example, the aqueous
bicarbonate
solutions of both sodium carbonate 2. In fire extinguishers
(Na2CO3) and sodium acetate
3. As an antacid in medicine
(CH3COONa) are alkaline.
Potassium nitrate 1. To make gunpowder, fireworks
Na2CO3 + 2H2O  2NaOH + CO2 + H2O
and glass
CH3COONa + H2O  CH3COOH + NaOH 2. As a fertilizer in agriculture
(iii) A salt derived from a strong acid and a
Copper sulphate 1. Commonly called 'blue vitriol',
weak base gives an acidic solution. For
used as a fungicide to kill
example, both aluminium chloride
certain germs
(AlCl3) and ammonium chloride (NH4Cl)
make acidic aqueous solutions. 2. In electroplating

AlCl3 + 3H2O  Al(OH)3 + 3HCl 3. In dyeing

NH4Cl + H2O  NH4OH + HCl Potash alum 1. Used to purify water; makes
(iv) Solutions of acidic salts are acidic to suspended particles in water
litmus, i.e., these solutions turn blue settle down
litmus paper red. For example, a solution
2. As an antiseptic
of sodium hydrogensulphate (NaHSO4)
turns blue litmus paper red. 3. In dyeing
Sodium hydrogencarbonate (NaHCO3) solution, 
however, is slightly alkaline.

 The pH Scale : We can say that the pH of a neutral solution is 7.
In an acidic solution, [H+] > 1.0 × 10–7 M.
A litmus solution or litmus paper can be used to
determine whether a given solution is acidic or Let us assume, [H+] = 1.0 × 10–5 M.

basic. But suppose you have two acidic solutions  pH = –log (1.0 × 10–5) = 5.
containing different amounts of acids in them. Here, we find that the pH of an acidic solution is
How can you say which solution is more acidic? less than 7.
Similar is the case with the basic solutions. This In an alkaline solution, [H+] < 1.0 × 10–7 M. Let
problem is solved by using a scale known as the
as assume, [H+] = 1.0 × 10–9 M.
pH scale introduced by S P Sorensen in 1909. pH
 pH = –log (1.0 × 10–9) = 9.
of a solution indicates which solution is more
acidic or more basic than the other. In other words, the pH of an alkaline solution is
more than 7.
The acidity or basicity (alkalinity) of a solution is
The pH of different solutions at 298 K can now be
usually expressed in terms of a function of the H+
expressed on the pH scale as shown below.
ion concentration. This function is called the pH
pH 1 2 3 4 5 6 7 8 9 10 11 12 13 14
of a solution.

The pH of an aqueous solution is the negative

Neutral solution
logarithm of its H+ ion concentration. That is, Acidic solution Alkaline solution
pH = –log [H+]. Rules for pH scale (at 298 K)

pOH = –log [OH–]. 1. Acidic solutions have pH less than 7.

Note: [H+] and [OH–] denote the concentrations of 2. The lower the pH, the more acidic is the
solution.
H+ and OH– ions respectively.
3. Neutral solutions or pure water has pH equal
The concentrations of H+ and OH– ions in
to 7.
aqueous solutions are usually very small numbers
4. Basic solutions have pH greater than 7.
and therefore difficult to work with. Since pH is
the negative logarithm of [H+], we get positive' 5. The higher the pH, the more basic is the
solution.
numbers and the inconvenience of dealing with
small numbers is eliminated. The pH values of some common solutions

It should be noted here that pH is only a number, Substance pH

because we can take the logarithm of a number Gastric juice 1.0

and not of a unit. Therefore, pH of a solution is a Lemon juice 2.5
dimensionless quantity.
Vinegar 3.0
+ –7
In a neutral solution, [H ] = 1.0 x 10 M.
Wine 3.5
 pH = –log (1.0 × 10–7) = 7. Tomato juice 4.1
 Acid rain 5.6 2. Acids cause tooth decay : When we eat
sugary food, it gets degraded by bacteria
Urine 6.0 present in the mouth and an acid is formed.
Milk 6.5 When the pH becomes lower than 5.5, tooth
enamel gets corroded. Saliva, which is
Pure water 7 slightly alkaline, produced in the mouth
neutralizes some acid, but excess acid
Blood 7.4
remains unaffected. The excess acid can be
Lime water 11.0 removed only by the use of toothpaste which
is alkaline. Neem stick contains alkaline
How is pH measured?
juice. So, the cleaning of tooth by Neem stick
The pH of a solution is generally determined with also helps to reduce tooth decay.
the help of a pH paper, or universal indicator. The 3. Acid is produced in fatigued muscle : As a
pH paper gives a particular colour with a solution result of physical exercise, stiffness and pain
in the muscle starts due to the formation of
of particular pH. The colour is compared with a
lactic acid. The supply of oxygen in the
chart which has different colours at different pH muscle is reduced. This causes difficulty in
values. the release of energy leading to increase in
the rate of anaerobic metabolism. As a result,
lactic acid gets accumulated in the muscles.
4. Some animals and plants contain acids :
Honey-bee injects an acid through its stings
which causes pain and irritation. Hence, a
mild base like baking soda is applied to treat
the wound. Similarly, nettle leaves, which
have stinging hairs, when touched inject
formic acid in our body. This causes a
Role of pH in everyday life : burning pain.

pH plays a very important role in our everyday Note : Nettle is a stinging plant. When one
accidentally touches its hairs, a painful effect
life.
is produced. As a remedy, the affected area is
1. In our digestive system : Hydrochloric acid rubbed with the dock plant. The dock plant is
alkaline which neutralizes the effect of the
produced in our stomach helps the digestion
acid.
of food without causing any harm to the
5. The brilliance of a tarnished copper vessel
stomach. But when the amount of the acid
can be restored by using acid : You know,
goes beyond a certain limit due to indigestion, lemon juice contains an acid. In order to clean
pain and irritation are created in the stomach. a copper vessel, we rub it with the piece of a
So, in order to neutralize the effect of excess lemon. The tarnish on the vessel is caused by
the formation of a layer of basic copper
acid, a mild base called antacid is usually
oxide. Since lemon juice contains citric acid,
taken. Magnesium hydroxide (milk of it reacts with the copper oxide to form copper
magnesia) is a mild base which is usually citrate and is washed away. The vessel then
used as an antacid. regains its shining appearance.
 6. pH of soil : Soils are generally acidic. Plants Acids turn blue litmus red, whereas bases turn red
require definite pH range for their proper litmus blue.
growth. They do not grow in alkaline soil.
When a solution of an acid contains larger amount
Many plants do not grow properly in highly
of the acid, it is said to be concentrated, while that
acidic or highly alkaline soil. So, highly
containing smaller amount of the acid, is said to
acidic soil is treated by spreading quicklime,
be dilute.
slaked lime or calcium carbonate to lower its
 Metals like sodium, potassium and calcium react
acidity.
with an acid to liberate hydrogen gas.
pH of Salts :
Acids react with bases to produce salts and water.
The aqueous solutions of all kinds of salts do
Acids react with the carbonates and the
not have the same pH value.
hydrogencarbonates to give carbon dioxide gas.
(i) Salts of strong acids and strong bases :
 The hydrogen atoms of an acid which can be
Sodium chloride (NaCl), potassium
partially or completely replaced by an atom or a
nitrate (KNO3), sodium sulphate
group of atoms are called replaceable hydrogen
(Na2SO4), etc., are salts of this category.
atoms. They are also called acidic hydrogen.
The aqueous solutions of these salts are
neutral with pH value of 7. The number of replaceable hydrogen atoms
present in a molecule of the acid is known as the
(ii) Salts of strong acids and weak bases :
basicity of the acid.
Aluminium chloride (AlCl3), copper
sulphate (CuSO4), zinc sulphate (ZnSO4), A compound that reacts with an acid to form a salt
etc., are salts of this category. The and water is called a base.
aqueous solutions of these salts are acidic
Bases that are soluble in water are called alkalis.
with pH value less than 7.
All alkalis are bases, but all bases are not alkalis.
(iii) Salts of weak acids and strong bases :
The reaction between an acid and a base is called
Sodium acetate (CH3COONa), sodium
neutralization reaction. In such a reaction, the acid
carbonate (Na2CO3) and sodium
and the base destroy the properties of each other.
hydrogencarbonate (NaHCO3) are
The number of hydroxyl groups (OH) present in a
examples of this category of salts. The
molecule of the base is called the acidity of the
aqueous solutions of these salts are basic
base.
in nature with pH value more than 7
A salt is a compound formed by the reaction of an
POINT TO REMEMBER
acid with a base.
 Everything that tastes sour contains an acid.
Na2SO4, CaSO4 and Na3PO4 are normal salts,
Acetic acid, citric acid, tartaric acid are a few
organic acids. Sulphuric acid, nitric acid and whereas NaHSO4, NaHCO3, Na2HPO4 are acid
hydrochloric acid are examples of inorganic acids. salts.
 A strong acid is one which gets almost
completely dissociated when dissolved in
water to give hydrogen ions, whereas a weak
acid gets only partially dissociated in water to
give hydrogen ions.

 A strong base gets almost completely

dissociated when dissolved in water to give
hydroxide ions (OH–), whereas a weak base,
when treated as such, gets only partially
dissociated to provide hydroxide ions.
 Exercise-I
A. Very Short Answer Type Questions Q.20 (i) Find out the pH of 0.05 M H2SO4.
(ii) Find out the pH of H+ ion concentration
Q.1 What is the nature of the solution which turns
= 3× 10–3.
blue litmus to red ?
Q.21 What is the pH range ?
Q.2 Conjugate acid-base pair differ by
Q.22 If pH is equal to 7, what kind of solution is
Q.3 A substance gives H3O+ ions in aqueous
indicated ?
solution. What is that substance ?
Q.23 Define and give one example of Bronsted–
Q.4 The conjugate base of a strong acid
Lowry base ?
Q.5 In a reaction H+ ions combine with OH– ions
Q.24 Define the term of Neutralisation.
to form water. What is the type of reaction ?
Q.25 What is the Arrhenius theory of acids and
Q.6 Arrhenius theory of acids-bases is not
bases ? Give its two important limitations.
applicable to
Q.26 Describe the Bronsted-Lowry concept of
Q.7 What is the conjugate base of CH3OH ?
acids and bases. What are the conjugate acid
Q.8 What is the conjugate acid of CH3COOH ? base pairs according to the concept ?
Q.9 Write conjugate base of HCN Q.27 Explain giving reasons.
(i) Water behaves as an acid and also like a
Q.10 Write conjugate base of HN3
base on the basis of protonic concept ?
Q.11 In the Bronsted-Lowry system a base is
Q.28 Find the conjugate acid/base for the following
defined as.
species:
Q.12 In the following system HNO2, HClO4, OH–, CO3–2, S–2
CN– + H2O HCN + OH– the conjugate
acid-base pairs are. C. Long Answer Type Questions
Q.13 What is the nature of the solution which turns Q.29 Define the term acid and base on the basis of
red litmus to blue ? Arrhenius concept.
Q.14 Give one example of Bronsted-Lowry acid. Q.30 What are strong and weak electrolytes ?
Explain with suitable examples.
Q.15 Give one example of Amphoteric compound
Q.31 Define pH. What is pH-scale ?
B. Short Answer Type Questions
Q.16 Find the pH value of the solution when its H+
ion concentration is
(a) 10–4 mol L–1
(b) 10–7 mol L–1
Q.17 Discuss Arrhenius theory of acids and bases
taking the example of NaOH and NH4OH.
Q.18 What is the pH of a solution when the
hydrogen ion concentration is 1×10–10 ?
Q.19 Calculate the pH of solution containing
concentration of hydroxyl ions as 1×10–11.
 Exercise-II
A. Fill in the Blanks Q.24 NH4+ ion is Bronsted acid
Q.25 pH + pOH = 14 is valid at all temperatures
Q.1 According to Arrhenius acid-base theory, in
neutralisation reaction....... molecule is Q.26 pH of water increases with increase in
formed. temperature
Q.2 The conjugate acid of HPO32– is.......
Q.3 The conjugate base of NH3 is.......
Q.4 A conjugate acid forms a conjugate base
by....... of a proton.
Q.5 A strong base would have a....... Conjugate
acid.
Q.6 The conjugate acid of O2– ion is.......
Q.7 ....... acid-base theory cannot define that NH3
is a base.
Q.8 HSO4– is a conjugate acid of.......
Q.9 In the reaction I, HCO3– behaves as....... and
in the reaction II HCO3– behaves as .......
hence, HCO3– is said to be.......
HCO3– + H2O CO32– + H3O+ (I)
HCO3– + H2O H2CO3 + OH– (II)
Q.10 In the following reaction
[Al(H2O)6]3+ + H2O
[Al(H2O)5OH]2+ + H3O+
3+
[Al(H2O)6] is.......
Q.11 The pH of an acidic solution is....... than 7
Q.12 An acid produce....... ions when dissolved in
water.
Q.13 A Base produce....... ions when dissolved in
water.
Q.14 The pH of a basic solution is....... than 7
Q.15 The hydrogen ion concentration in pure water
is.......
Q.16 pOH for a solution can be calculated by
subtracting....... from 14.

B. True /False Type Questions

Q.17 A base turns blue litmus red.

Q.18 NH4OH is a strong base.
Q.19 In pure water [H3O+] = [OH–].
Q.20 pH of acidic solutions ranges from 7 to 14.
Q.21 Arrhenius concept of acids and bases is based
on theory of ionization.
Q.22 An acid turns blue litmus red
Q.23 pH of pure water is always 7
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