SKKU-CS-009

기초자연과학영역(BSM) 공동시험문제
Basic Science and Mathematics Common Examination
학기 2016년 1학기 시험구분 중간 Mid Term □ 시험시간
60 분/Minutes
Semester Year Semester Exam Type 기말 Final ☑ Exam Time
학과/계열 학번 Student No. 성명
Dept./Division 개인고유번호 PIN No. Name
과목명 일반화학1 학수번호 분반
Subject General Chemistry 1 Course Code GEDB012 Section Number
수업정보 요일 시간 수업담당교수 감독자확인
Class Time Day Time Instructor Proctor’s Signature
※ 답안은 주어진 공간을 활용하여 영어로 작성 / Using languages other than English is not allowed.
유의사항 ※ 연습장 및 사전 사용 불가 / Using extra paper and dictionary is not permitted.
Note ※ 계산기 사용 가능(빌리는 것 불허) / You may use a calculator, but cannot borrow it.
※ 4, 6, 9-12번은 풀이과정을 보일 것/ Show your solving process for the questions of 4, 6 and 9-12.

H He ( A ) Which of the following lists of atoms are arranged in

Li Be B C N O F Ne order of INCREASING first ionization energy?
Na Mg Al Si P S Cl Ar (A) Li < O < N < F (B) Li < N < O < F
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
(C) F < O < N < Li (D) Na < Sr < O < F
(E) Ca > Cs > S > Se
Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
Cs Ba La Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn ( B ) Using the following bond energies (kJ/mol) for each bond:
Fr Ra Ac CºC (839 kJ/mol), C=O (799 kJ/mol), C-H (413 kJ/mol)
O-H (467 kJ/mol), O=O (495 kJ/mol)
1. Write ‘T’ for true statement or ‘F’ for false statement in ( ). Estimate the heat of combustion for one mole of acetylene:
[5 pt for right answer, −3 pt for wrong, and 0 pt for no answer]
C2H2(g) + 5/2O2(g) →
2CO2(g) + H2O(g)
( T ) The magnetic quantum number is related to the orientation (A) 1228 kJ (B) -1228 kJ (C) -447 kJ (D) 447 kJ (E)365 kJ
of the orbital in space relative to the other ones in an atom.
( F ) A 2p orbital has a higher electron density near the nucleus ( C ) Which of the following set of quantum numbers (n, l, ml,
than a 2s orbital. ms) is not permissible for the electron in the hydrogen atom?
( F ) Linear molecules cannot have a net dipole moment. (A) 9, 8, -4, 1/2 (B) 8, 2, 2, -1/2 (C) 6, -5, -1, 1/2
( T ) Dipole moments result from the unequal distribution of (D) 6, 5, -5, -1/2 (E) All are allowed.
electrons in a molecule. ( B ) Which of the following pairs is isoelectronic?
( F ) The larger the bond order is, the longer the bond length is. (A) Li+ and K+ (B) Na+ and Ne (C) I- and Cl-
2- 3+ 3+
( T ) Two p atomic orbitals along the bond axis from two (D) S and Ne (E) Al and B
different atoms can form a sigma bonding molecular orbital.
( T ) Liquids with large intermolecular forces tend to have high ( D ) Which of the following compounds is expected to have the
LOWEST melting point?
surface tension.
(A) CH3OCH3 (B) CH3CH2OH (C) CH3CH2CH2CH3
( F ) Atomic solids generally have low melting points. (D) CH3CH2CH3 (E) CH3Cl
( F ) Molal freezing-point depression constants (Kf) depend only
( E ) What is the simplest formula of a solid containing A and B
on the number of the solute particles.
atoms at the corners and the faces of a cubic lattice, respectively?
( F ) If the density of a solvent is exactly 1.00 g/mL, molarity (A) A4B3 (B) AB (C) AB2 (D) A2B (E) AB3
and molality of a solution are the same.
( E ) Which of the following 1M acid or base solutions has the
highest normality composition?
2. Choose the correct answer and write it in ( ). [10 pt each]
(A) HClO4 (B) NH4OH (C) CH3CO2H
( E ) Which of the following have 10 electrons in the d (D) HNO3 (E) All have the same normality
orbitals?
( D ) Which of the following pairs would have positive deviation
(A) Mn (B) Fe (C) Cu (D) Zn (E) two of these
from the Raoult’s law.
( B ) Which of the following ionic compounds will have the (A) acetone-chloroform (B) water-ethanol
largest lattice energy? (C) benzene-toluene (D) ethanol-hexane
(A) BaO (B) BeO (C) CsI (D) NaBr (E) BaS (E) None of above

(이 부분은 출제자 및 채점자를 위한 공간입니다. / Do not write your answer here: this is only for grading/marking.)
문제번호 1 2 3 4 5 6 7 8 9 10 11 12 합계
Problem No. Total
점수
Score 50 100 18 25 25 25 32 25 25 25 25 25 400
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Copyright ⓒ 2014 College of Science, Sungkyunkwan University (SKKU)
 SKKU-CS-009

3. Given the following electronic configuration of neutral atoms, 8. Determine the expected hybridization of the central atom for
identify the element and state the number of unpaired electrons in each of the following molecules from its Lewis structure:
its ground state: [18 pt] [25 pt]
2 2 3
(a) NO3- ( sp ) (b) XeF4 ( d sp )
Electronic Configuration Element Unpaired electrons 3 3
1 5 (c) OF2 ( sp ) (d) IF3 ( dsp )
[Ar] 4s 3d Cr 6
2
2 10
[Kr] 5s 4d 5p
4
Te 2 (e) O3 ( sp )
[Xe] 6s 24f 145d 7 Ir 3
9. You are given a small bar of an unknown metal, M. You
3
find the density of the metal to be 10.5 g/cm . An X-ray
4. Consider an atom traveling at 1% of the speed of light. If de
-3 diffraction experiment measures the edge length of the unit cell
Broglie wavelength of this atom is 1.46 × 10 pm. What is its
-34 as 409 pm. Assuming that the metal crystallizes in a
atomic weight in g/mol? [h = 6.626 × 10 J·s and c = 2.998 ×
8 face-centered cubic lattice, what is the atomic weight of M in
10 m/s.] [25 pt]
gram per mole?
λ = h / mv [NA = 6.02×10-23 mol-1] [25 pt]
-34 8
m = h / vλ = (6.626 × 10 J·s) / {(0.01 × 2.998 × 10
-3 -25 2 2
m/s)(1.46 × 10 pm)} = 1.514 × 10 J·s /m Volume of unit cell = (409 pm)3 = 6.84×10-23 cm3
-25
= 1.514 × 10 kg (per atom)
-25 3 23 -1
Mass of 4 atoms ( ∵ fcc crystal) = 4 × atomic weight / NA
Atomic weight = (1.514 × 10 kg)(10 g/kg)(6.022 × 10 mol ) Density = Mass / Volume
= 91.2 g/mol (Zr) ∴ Atomic weight = Density × Volume × NA / 4
5. Draw the most stable Lewis structure in the box below with
formal charges for each of the following. [25 pt] Answer: 10.5 g/cm3 × 6.84×10-23 cm3 × 6.02×10-23 mol-1 / 4
(i) SO3 (ii) SO32- (iii) SO42- = 108 g/mol

10. Diethyl ether (CH3CH2OCH2CH3), whose boiling point is 34.6

°C, has a vapor pressure of 440 Torr at 20.0 °C. What is the
ΔH of vaporization for diethyl ether? [R = 8.3145 J/K·mol]
[25 pt]

−
ln(P1/P2) = (ΔH/R)×(1/T2 1/T1)
6. Using the following data, estimate ΔHf° for sodium chloride −
ln(760/440) = (ΔH/8.3145J/K·mol)×(1/293.15K 1/307.75K)
Na(s) + 1/2 Cl2(g) → NaCl(s) Therefore, ΔH = 2.81×104 J/mol = 28.1 kJ/mol

lattice energy for NaCl -786 kJ/mol

ionization energy for Na 495 kJ/mol 11. An aqueous 0.1 m (molality) NaCl solution containing 200 g
electron affinity of Cl -349 kJ/mol of an unknown nonelectrolyte compound in 1000 g of water was
bond energy of Cl2 239 kJ/mol found to have a freezing point of -1.5 °C. Calculate the molar
enthalpy of sublimation for Na 109 kJ/mol mass of the unknown compound. [Molar mass of NaCl is 58.4
-
Na+(g) + Cl (g) →
NaCl(s) ΔH = -786 kJ/mol
g/mol, Kf for water is 1.86 °C·kg/mol]. [25 pt]
Na(g) → Na+(g) + e- ΔH = 495 kJ/mol
Cl(g) + e
-
→ -
Cl (g) ΔH = -349 kJ/mol
Freezing point depression by NaCl is 2×1.86 °C·kg/mol×0.1
Cl2(g) → 2Cl(g) ΔH = 239 kJ/mol
mol/kg = 0.372 °C. Thus freezing point depression by an
Na(s) → Na(g) ΔH = 109 kJ/mol
unknown is 1.128 °C.
1.128 °C. = 1×1.86 °C·kg/mol×(x mol/1 kg)
109 + 0.5×239 + 495 + (-349) + (-786) = - 411.5
∴ ΔHf° = -412 kJ/mol
x=0.606 mol
200g/0.606 mol = 330 g/mol
7. Consider the following molecular orbital (MO) energy level
diagram and answer the following questions. [32 pt]
12. Solution of 1-propanol (60.1g/mol) and 2-propanol have
(1) Compare the bond strengths of enthalpy of solution close to zero and can be assumed as an
+ ideal solution. What mass of 1-propanol must be mixed with
CN and NO
+ 100 g of 2-propanol to give a solution with vapor pressure of
( NO ) > ( CN )
37.3 torr at 25 °C? [At 25 °C, 1-propanol and 2-propanol have
(2) Is NO paramagnetic or vapor pressures of 20.9 torr and 45.2 torr, respectively.]
diamagentic? [25 pt]
( Paramagnetic ) Ptotal = P1 χ1 + P2 χ2=P1 χ1 + P2 (1-χ1)
37.3 = 20.9 χ1+ 45.2 (1-χ1)
(3) What is the bond order of NO−? χ1= 0.325, χ2= 0.675
( 2.0 ) 0.325:0.675=x:100
48.1 g
(4) Among the following, which is the most stable heteronuclear
atomic species? ( CN− )

CN, NO−, HF, CN−, NO

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Copyright ⓒ 2014 College of Science, Sungkyunkwan University (SKKU)