Scribd Logo
Upload

Welcome to Scribd!

  • 7 views

    111上試題 (含解答)

    Uploaded by

    wanyun345

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    111上試題 (含解答)

    Uploaded by

    wanyun345
    7 views8 pages

    Original Title

    111上試題(含解答)

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    7 views8 pages

    111上試題 (含解答)

    Uploaded by

    wanyun345

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 8

    國立高雄大學

    111 學年度第一學期

    理學院

    普通化學會考

    December 24, 2022 (Wed.)

    9:30 ~ 11:30

    姓名： 學號：
    －考試注意事項－
    考試時間：120分鐘
    總分：100分
    作答方式：
    ˙請使用原子筆或簽字筆於「答案卷」上作答。
    ˙未依規定於答案卷作答以致無法辨識答案者，其後果由考生
    自行負責。
    ˙答案卷每人一張，不得要求增補。
    ˙選擇題共 32 題，均為單選題。
    1-28 題，每題 3 分；29-32 題，每題 4 分。
    ˙試卷請繳回。

    參考資料

    一、元素週期表

    二、常數
    R = 8.314 J/mol·K = 0.08206 L·atm/K·mol; Avogadro’s number = 6.022×1023; 1 atm = 101325 Pa
    選擇題 (1-28 題，每題 3 分；29-32 題，每題 4 分)

    (B) 1. Which of the following statements is/are true of molecular orbital?


    1. A bonding molecular orbital is lower in energy than the atomic orbitals of which it is composed.
    2. Electrons in a bonding molecular orbital favor the separated atoms.
    3. An antibonding molecular orbital is higher in energy than the atomic orbitals of which it is
    composed.
    (A) 1 only
    (B) 1 and 3
    (C) 2 only
    (D) 2 and 3
    (E) 3 only

    (B) 2. Bromine exists naturally as a mixture of bromine-79 and bromine-81 isotopes. An atom of
    bromine-79 contains
    (A) 79 protons, 79 electrons, and 35 neutrons.
    (B) 35 protons, 44 neutrons, and 35 electrons.
    (C) 44 protons, 44 electrons, and 35 neutrons.
    (D) 34 protons and 35 electrons only.
    (E) 35 protons, 79 neutrons, and 35 electrons.

    (E) 3. Which of the following statements is(are) true?


    Oxidation and reduction
    I. cannot occur independently of each other.
    II. accompany all chemical changes.
    III. describe the loss and gain of electron(s), respectively.
    IV. result in a change in the oxidation states of the species involved.

    (A) I only
    (B) II only
    (C) III only
    (D) IV only
    (E) I, III, and IV

    (B) 4. If four orbitals on one atom overlap four orbitals on a second atom, how many molecular orbitals will
    form?
    (A) 1
    (B) 8
    (C) 4
    (D) 16
    (E) none of these
    (A) 5. Identify the following unbalanced reactions AgNO3 + KCl →AgCl + KNO3 using the following
    choices:
    (A) Precipitation reaction
    (B) Acid-base reaction
    (C) Oxidation-reduction reaction
    (D) Combustion reaction
    (E) More than one of answers a-d apply.

    (D) 6. Which of the following statements is incorrect?


    (A) A molecule with very polar bonds can be nonpolar.
    (B) Ionic bonding results from the transfer of electrons from one atom to another.
    (C) Dipole moments result from the unequal distribution of electrons in a molecule.
    (D) Linear molecules cannot have a net dipole moment.
    (E) The electrons in a polar bond are found nearer to the more electronegative element.

    (A) 7. What is the hybridization of the central atom in SF3?


    (A) dsp3
    (B) sp3
    (C) d2sp3
    (D) sp
    (E) sp2

    (C) 8. Vibrational transitions in molecules typically require energies that correspond to the _________
    region of the electromagnetic spectrum.
    (A) visible
    (B) microwave
    (C) IR
    (D) X-ray
    (E) UV

    (D) 9. What is the hybridization of C in the molecule CO?


    (A) dsp3
    (B) sp2
    (C) d2sp3
    (D) sp
    (E) sp3

    (E) 10. The _____ is defined as the change in energy that takes place when separated gaseous ions are
    packed together to form an ionic solid.
    (A) atomic binding energy
    (B) bond energy
    (C) band gap energy
    (D) ionization energy
    (E) lattice energy
    (E) 11. Atoms that are sp3 hybridized form ____ pi bond(s).
    (A) 1
    (B) 4
    (C) 2
    (D) 3
    (E) 0

    (D) 12. The electron pair in a C–F bond could be considered


    (A) an inadequate model because the bond is ionic.
    (B) closer to C because carbon has a lower electronegativity than fluorine.
    (C) closer to C because carbon has a larger radius and thus exerts greater control over the shared
    electron pair.
    (D) closer to F because fluorine has a higher electronegativity than carbon.
    (E) centrally located directly between the C and F.

    (D) 13. The configuration (σ2s)2(σ2s*)2(π2py)1(π2px)1 is the molecular orbital description for the ground state
    of which of the following species?
    (A) Be2
    (B) Li2+
    (C) B22–
    (D) B2
    (E) C2

    (C) 14. How many electrons can be described by the quantum number n = 3?
    (A) 32
    (B) 2
    (C) 18
    (D) 8
    (E) 10

    (A) 15. Identify the true statement(s) about acids and bases.
    1. An acid is a substance that produces H+ ions when it is dissolved in water.
    2. A base is a substance that produces OH– ions when dissolved in water.
    3. An acid that dissociates completely in aqueous solution is called a weak acid.
    4. A base that dissociates completely in aqueous solution is called a weak base.
    (A) 1 and 2
    (B) 1 and 3
    (C) 3 and 4
    (D) 2 and 4
    (E) 1, 2, 3, and 4
    (A) 16. Which of the following molecules has a dipole moment?
    (A) SF4
    (B) CF4
    (C) XeF4
    (D) All of these have a dipole moment.
    (E) None of these has a dipole moment.

    (E) 17. Which of the following statements is/are true of water?


    1. An individual water molecule is V-shaped, with an H–O–H angle of about 105°.
    2. The O–H bonds in a water molecule are ionic bonds.
    3. Polar and ionic substances are more soluble in water than nonpolar substances.
    (A) 1 only (B) 2 only (C) 3 only (D) 1 and 2 (E) 1 and 3

    (B) 18. As the number of bonds between two carbon atoms increases, which one of the following decreases?
    (A) the number of electrons between the carbon atoms
    (B) the bond length
    (C) the bond energy
    (D) all of these
    (E) none of these

    (B) 19. Which of the following compounds contains only one unshared pair of valence electrons?
    (A) NaCl
    (B) NH3
    (C) BeF3
    (D) CH4
    (E) H2O

    (A) 20. In which groups do all the elements have the same number of valence electrons?
    (A) O, S, Se
    (B) N, As, Se
    (C) Ag, Cd, Ar
    (D) Na, Ca, Ba
    (E) N, O, Br

    (D) 21. Of the following, which molecule has the largest bond angle?
    (A) O3 (B) H2S (C) OF2 (D) XeF (E) PCl3

    (D) 22. Consider the compound crotonaldehyde, whose skeleton is

    Which carbon in this molecule has tetrahedral bonding?


    (A) 2 (B) 3 (C) 4 (D) 1 (E) All have tetrahedral bonding.
    (A) 23. An element with the electron configuration [Xe]4f145d76s2 would belong to which class on the
    periodic table?
    (A) transition elements
    (B) alkaline earth elements
    (C) rare earth elements
    (D) halogens
    (E) none of these

    (E) 24. Place the elements Ge, S, and Ne in order of increasing atomic radius.
    (A) Ge, Ne, S
    (B) S, Ne, Ge
    (C) S, Ge, Ne
    (D) Ge, S, Ne
    (E) Ne, S, Ge

    (A) 25. Which is the highest occupied energy orbital in a silicon atom?
    (A) 3p (B) 3d (C) 3s (D) 2s (E) 1s

    (D) 26. What is the electron configuration for the chromium (Cr) atom?
    (A) [Kr] 4s13d5
    (B) [Ar] 4s23d4
    (C) [Kr] 4s23d4
    (D) [Ar] 4s13d5
    (E) none of these

    (E) 27. Which of the following combinations of quantum numbers is not allowed?
    (Combinations are listed as follows: n, l, m(l), m(s).)
    (A) 4 0 0 –1/2
    (B) 5 3 1 –1/2
    (C) 4 1 1 1/2
    (D) 3 1 0 1/2
    (E) 3 3 0 -1/2

    (B) 28. Of the following elements, which has occupied d orbitals in its ground-state neutral atoms?
    (A) Al (B) Ba (C) Ca (D) P (E) Cl
    (D) 29. Which charge(s) of O2 would give a bond order of 2.5?

    (A) +2 (B) –2 (C) –1 (D) +1 (E) +3 (F) 0

    (C) 30. When the equation C6H14 + O2 → CO2 + H2O is balanced with the smallest set of integers, the sum
    of the coefficients is
    (A) 28 (B) 33 (C) 47 (D) 4 (E) 40

    (C) 31. The combustion of methanol takes place according to the reaction
    2CH3OH(l) + 3O2(g) → 2CO2(g) + 4H2O(l)
    Calculate ΔH for the combustion of 1 mol of methanol under standard conditions.
    Use the following standard enthalpies of formation:
    ΔH°f for CH3OH(l) = –238.5 kJ/mol
    ΔH°f for CO2(g) = –393.5 kJ/mol
    ΔH°f for H2O(l) = –285.6 kJ/mol

    (A) –1452.4 kJ/mol


    (B) +1452.4 kJ/mol
    (C) –726.2 kJ/mol
    (D) +726.2 kJ/mol
    (E) none of these

    (A) 32. 1.00 mL of a 3.50 × 10–4 M solution of oleic acid is diluted with 9.00 mL of petroleum ether,
    forming solution A. 2.00 mL of solution A is diluted with 8.00 mL of petroleum ether, forming
    solution B. How many grams of oleic acid are in 5.00 mL of solution B? (molar mass for oleic acid =
    282 g/mol)
    (A) 9.87 × 10–6 g
    (B) 4.94 × 10–5 g
    (C) 4.94 × 10–4 g
    (D) 1.97 × 10–6 g
    (E) 7.00 × 10–6 g

    You might also like