HINTS and Solutions

Part – A (PHYSICS)
SECTION – A
Sol 1. Given Acceleration of m2 is 2m/s2
(upward)
N = 20a T – m2g = m2a
T – 20g = 20a
T = 200 + 20 × 2
T = 240 N
T = m1 a1
240 = 10a1
a1 = 24 m/s2
 Ta + Ta1 − Ta2 = 0
a2 = 24 + 2 = 26m/ s2
F – T – N = Ma2
F – 240 = 100 × 26 + 20 × 26
F = 3360 N

Sol 2. 1 = 6MHz = 6 106 Hz

C 3  108
1 = = = 50m
1 6  106
C 3  108
2 = = 10  106 = = 30m
2 10  106
 Wavelength bandwidth
= 1 − 2 = 20m

Sol 3. A = Aoe−t
 2250 = 4250e−t
   10  0.434 = 0.274
0.274
 = = 0.63min−1
10  0.434

Sol 4. E = I A
= 100  1  10−4
 = 10−2 W
c
E = nh

6.64  10−34  3  108
10−2 = n 
900  10−9
10−2  9  10−7
n=
6.64  10−34  3  108
n = 4.5  1016

Sol 5.  = 12mm = 12 10−3 m

 12  10−3
' = = = 9  10−3 m
 4/3
 ' = 9mm

w 1.5  1011
Sol 6. Speed of light C = = = 3  108 m / s
k 0.5  10 3

So,E0 = B0 C
= 2 × 10−8 × 3 × 108
= 6v/m
Direction will be along z – axis

R R
Sol 7. P1 = cos  = =
z XL + R2
2

R 1
P1 = cos  = =
R 2 2
P1 1
So, =
P2 2

Sol 8. a ⊥B
 a.B = 0
 (2 − 12 ) = 0
=6

 0l
Sol 9. B =N
2
N
B

x Nx ry
= 
 y rx Ny
Bx 200 20 1
=  =
By 20 400 2
 8
Sol 10. R =  = 4 (wheat stone bridge)
2
V 40
I = = = 10A
R 4

Sol 11. Ceq = C1 + C2 + C3 + C4

=1+2+4+3
= 10F
Q = Ceq v
= (10 × 20) C
Q = 200 C

Sol 12. x = A sin t

 v = Acos t
 v =  A2 − x2
v2
+ x2 = A2
 2

Elliptical

Sol 13. u = nC V T
3R
=n T
2
3
= 7   8.3  40
2
= 3486 J

Sol 14. Constant Entropy means Adiabatic process

Pv y = C
P1v1y = P2 v2y
y
 y

 v1   v 
P2 = P1   = P  
 v2   1v
8 
5
P2 = P ( 8 )
3
P2 = 32 P

4 3 4
Sol 15. R = 729 r3
3 3
3 3
R = 729r
1 1
R = ( 729 ) (r )  
3 3
 R = 9r
u = T ( 4 r2 )  729 − T  4R2

= T  4 8R2
= 75.39  10−5 J
u = 7.5  10−4 J

 2h   32 
Sol 16. g1 = g  1 −  = g  1 − 2  
 R  6400 
99g
g1 = = 0.99g
100
g − g1
% decrease is wt =  100 = 1%
g

Sol 17. Let m = 250 g = 0.25 kg

By Reduced mass method

mm mm m
mr = 1 2 = =
m1 + m2 m + m 2
By wet
w SP = K.E.
1 1m
− kx2 = 0 −   (2v )
2

2 2 2 
2 2
x = 0.25v2
2
x2 = 0.25v2
v
x=
2

Sol 18. For climbing downward

50 g – T = 50a
T = 500 – 50 × 4
= 300 N < 350 N
for climbing upwards
T – 50 g = 50 a
T – 500 = 50 × 5
T = 750 N > 350 N

Sol 19. H1 = H2
u12 sin2 1 u22 sin2 2
=
2g 2g
 u12 ( sin30) = u22 ( sin45)
2 2
 u1
 = 2
u2

0.5
Sol 20. Least count = mm = 0.01 mm
50
Diameter, d = 1.5 + 7 × 0.01
= 1.57
 Surface Area = (2r)
= 3.4 cm2

Section – B
 x
Sol 1. y = x5 (1 – x) = x tan   1 − 
 R
tan = 5, R = 1
5 1
sin  = ,cos  =
26 26
u2 sin2
R= =1
g
 u2 = 26  u = 26m/ s
y – component of initial velocity
= u sin 
5
= = 26 
26
= 5 m/s

Sol 2. Loss in P.E. = Gain in k.E

11 2 2 2
2 mg R =  mR + mR  
22 
8g g
= =4
3R 2  3R
g
x= =5
2

Sol 3. L=1m
L = 0.4  10−3 m
m = 1kg
d = 0.4 × 10−3 m
F L
=y
A L

y=
FL
=
(mg )  1
AL  d 2
−3
   0.4  10
 4 
 y = 0.1 0.199 1012 = 1.99 1010
= 1.99

 C 
Sol 4. f1 = 100 = fo  
 C − VS 
C = Speed of sound
Vs = Speed of source
 C 
f2 = 50 = fo =  
 C + Vs 
f1 C + VS
=2=
f2 C − VS
200 x
fo = =
3 3
x = 200

Sol 5. Capacitance of each capacitor

A3 0
C1 = = 6A 0
1
2
C2 = A40 = 4A 0
Equivalent capacitance
240A0
v2 = = 60v
4A0
v foil = 60v

P 40 2
Sol 6. Initially , = = -(1)
Q 60 3
P + x 80 4
Finally, = =
Q 20 1
(2)  (1)
P + x 43
= =6
P 2
x
1+ = 6
P
x
=5
P
X = 5 P = 5 × 4 = 20 
Sol 7. At very high frequencies
1
XC = →0
C
X L = L → 
Thus equivalent circuit
Z = 1 + 2 + 2 = 5
220
l= = 44A
5

1 1
Sol 8. for point B, = −0.10cm−1 , = 0
u v
Thus u = −10 cm, v = 
i.e., f = 10 cm
1 2 1 1
= (1.5 − 1)    =
10  R  R 10
R = 10 cm

Sol 9. For first line of Lyman

1  1 3
= R1 −  = R
  4 4
4
=
3R
rd
3 line (Paschen)
1 1 1 R 3
= R 2 − 2  = 
3 3 6  9 4
2nd line (B almer)
1 1 1 R 3
= R 2 − 2  = 
2 2 4  4 4
 4  20
a  =  a = 5
 3R  3R

120 − 60
Sol 10. l = = 0.015A
4000
Thus l2 = l - LL
= 0.015 – 0.006
= 0.009 = 9mA
 Part – B (Chemistry)
Section – A
Sol 1. In 4d orbital, n = 4 and = 2
Radial nodes = n − − 1
Radial nodes = 4 – 2 – 1 = 1
And angular nodes, = 2

Sol 2. Invertase → Cane sugar to glucose and fructose

Zymase → Glucose to ethanol
Diastase → Starch to Maltose
Maltase → Maltose to glucose

Sol 3. Except Te, all are metals.

Sol 4. In sulphide ore, depressants selectively prevent impurity from coming to the fourth.

Sol 5. During removal of temporary hardness of water.

Mg (HCO3 )2 ⎯⎯ →Mg ( OH)2 + 2CO2 
Boil

Ca (HCO3 )2 ⎯⎯ → CaCO3 + H2O + CO2

Boil

Sol 6. Be does not perform in flame colouration due to highly ionization energy.

Sol 7.

Sol 8. Disproportionation reaction is

+6 +7 +4
Mg O4−− + 4H+ → 2MnO4− + MnO2 + 2H2O

Sol 9. Ce3+ → Xe 4f 1 5d0

 Ce4 + → Xe 4f 0 5d0 (Noble gas configuration)

Sol 10. Highly polluted water has higher value of BOD  17 ppm

Sol 11. Nucleophilicity is directly proportional to the electron density of atom and inversely
proportional to its electronegativity.

Sol 12.

Sol 13.

Sol 14. OH group is the more activating group and ortho-para director, hence ortho position attach
will provide meta substituted product with respect to – CH3 in option (C).

Sol 15.

Sol 16.

Sol 17. p- toluenesulphonyl chloride

Only gives soluble product with alkali for 1° amine and for 2°- amine it gives insoluble product.

Sol 18.
Sol 19. CH3 – (CH2)16 – COONa is the sodium salt of fatty acid used in soap is not synthetic detergent.

Sol 20. Vitamin B12 is not water soluble chemical.

Section – B
1. CH4 + 2O2 → CO2 + 2H2O
100 208
Mole
16 32
 
6.25 6.5 (Here O2 is the limiting reagent)
6.5
Hence mole of CO2 formed =
2
6.5
And wt of CO2 in gm =  44 = 143g
2

1 
Sol 2. After removal A = 4 −   2  = 3
2 
After removal B = 4 – 1 = 4 (only two atoms are removed)
Final formula of the compound = A3B4

Sol 3. Water has only two lone pair and XeF4 has two lone pair electron in opposite plane of the
central atom.

Sol 4. Vapourisation of H2O,H2O( ) → H2O( g )

36
Mole of H2O = = 2mol
18
E = H − nRT
 1  8.31  373
= 41.1 − = 38kJ / mole
1000

2  0.83  300
Sol 5.  = i c R  T = = 0.00415bar
60  103
= 415 Pa

1 1
Sol 6. Hl H2 + l2
2 2
 
t = eq 1 -   = 0.4
2 2
1 1

(P )  (P ) = ( 0.2)  ( 0.2)
1 1
2 2
H2 l2 2 2
Kp =
PHl 0.6
1
= −8.31  300  2.3  log   = 2735J / mol
3

Sol 7. cell reaction is ;

Cu( s ) + Sn2(aq+ ) → Cu(++aq) + Sn(s)

Cu++  0.01
Q= = and n = 2
Sn++  0.001
0.059 0.01
Ecell = Ecell
o
− log
2 0.001
0.059
= −0.48 − log10 = −0.509
2
= 983.33  10 −1 KJ / mole
Nearest integer = 983

(Ea)cat (Ea)uncat
Sol 8. Kcat = Ae− and Kuncat = Ae−
RT RT
(Ea)uncat −(Ea)cat 101000
Kcat
=e RT
= e 8.314300 = e4.009 = ex
Kuncat
x = 4

2+ 3+
Sol 9. Co (H2O )6  + NH3(excess ) → Co (NH3 )6  + 6H2O
Diamagnetic nature

3+
Co → 3d 4s 6 0

 t2g 6eg 0 (form of paired electron)

No. of electron in t2g = 6

Sol 10. CH4 + 2O2 → CO2 + 2H2O

2 moles of water produced by 1 mole of methane
 Or 36 gm of water produced by 1 mole of CH4
1  81
 81 gm of water produced = = 2.25 mole of CH4
36
Mole of CH4 required = 225 × 10−2
Nearest integer = 225

Part – C (Mathematics)
Section – A
Sol 1. z = iz2
Let z = x + iy
x – iy = i(x2 – y2 + 2xiy)
Case-I
x=0
−y2 = −y
y = 0, 1
Case – II
1
y=−
2
1 1 3
 x2 − = x=
4 2 2
Area of polygon

0 1 1
1 3 −1 1 3 3 3
= 1 = − 3− =
2 2 2 2 2 4
− 3 −1
1
2 2

Sol 2. x + 2y + z = 2
x + 3y − z = 
−x + y + 2z = −
1 2 1
 =  3 −1 = 1 ( 6 + 1) − 2 (2 −  ) + 1 (  + 3 ) = 7 + 2a
− 1 2
 7
=−
2

 
1 1  n 1
Sol 3. x =  an = ;y =  bn = ;c =
n= 0 1−a n= 0 1 − b n= 0 1−c
Now,
a, b, c → AP
1 – a, 1 – b, 1 – c → AP
1 1 1
, , → HP
1 − a 1 −b 1 − c
x, y, z → HP

dy ax − by + a
Sol 4. =
dx bx + cy + a
= bxdy + cy dy + ady = axdx − bydx + adx
cy2 ax2
= + ay − − ax + bxy = k
2 2
ax2 + ay2 + 2ax − 2ay = k
 x2 + y2 + 2x − 2y = 
Short distance of (11,6)
= 122 + 52 − 5
= 13 – 5
=8

18 − 1 − x 
Sol 5. lim
x →7 x − 3a
exist & aI.
17 −  −x 
= lim
x →7 x  − 3a
exist
17 −  −x  25  7 
RHL = lim+ = a
x  − 3a
x →7 7 − 3a  3 
17 −  −x  24
LHL = lim
x →7  x  − 3a
= a  2
−
6 − 3a
LHL = RHL
25 8
 =
7 − 3a 2 − a
a = −6
Sol 6. f ( x ) = x 4 − 4x + 1 = 0
f ' ( x ) = 4x 3 − 4
= 4 ( x − 1) ( x 2 + 1 + x )
 Two solution

Sol 7. CD = (10 + x ) − (10 − x )

2 2 2 2
= 2 10 x
Area

=  CD  AB =  2 10 x (20 − 2x2 )
1 1
2 2
 10 − x = 2x
2

3x2 = 10
x=k
3k2 = 10

5
y x
Sol 8. cos −1   = log e   , y  2
2  5
Differentiating on both side
1 y' 5 1
−  = 
y
2 2 x 5
1−  5
2
2
−xy' y
= 5 1− 
2 2
Square on both side
x2 y'2  4 − y2 
= 25  
4  4 
Diff on both side
xy'+ y''x2 + 25y = 0

ex ( x 2 + 1 )
Sol 9. l=  dx = f ( x ) eX + c
( x + 1)
2

ex ( x 2 − 1 + 1 + 1 )
l = dx
( x + 1)
2

x −1 2 
=  ex  +  dx
 x + 1 ( x + 1) 
2

for x = 1
12 12 3
f ''' (1) = = =
24 16 4
 2 x3 + x
Sol 10. l =  dx …….(i)
−2 ex x + 1
2 x3 + x
l=  dx …....(ii)
−2 e− x x + 1
 16 4 
= +  − 0
 4 2
=4+2=6

dy 2 ( 2 − 1 )
x −y y

Sol 11. + =0
dx 2x − 1
x, y > 0, y(1) = 1
dy 2x ( 2 y − 1 )
=− y x
dx 2 (2 − 1)
2y 2x
 2y − 1 dy = −  2x − 1 dx
log e ( 2y − 1 ) log e ( 2x − 1 ) log e c
== =− +
log e 2 log e 2 log e 2
Taking log of base 2.
 y = 2 – log2 3

2x + y = 4 
Sol 12.  y = 2,x = 3
2x + 6y = 14 
B (1, 2)
Let C (k, 4 – 2k)
Now AB2 = AC2
 5k2 – 24k + 19 = 0
10
6 +1+
= 5 = 18
3 5
Now 15 ( + )
 17 
15   = 51
 5

x2 y2
Sol 13. + =1
a2 b2
2
 2
 −4 
 5  32
 + 2 =1
a2 b
32 9
 2 + 2 = 1 ……..(i)
5a b
From (i)
 6 9
+ = 1  b2 = 15&a2 = 16
b2 b2
a2 + b2 = 15 + 16 = 31

Sol 14. l + m – n = 0  n = l + m
3l2 + m2 + cnl = 0
3l2 + m2 + cl (l + m) = 0
2
 l   l 
= (3 + c)   + c   + 1 = 0
m m
Lines are parallel
D=0
c = 4 (as c > 0)

Sol 15. a = ˆi + ˆj − kˆ
c = 2iˆ − 3jˆ + 2kˆ
Now,
b c = a
( )(
 ˆi + ˆj − kˆ 2iˆ − 3jˆ + 2kˆ = 0 )
=2–3–2=0
 −3 = 0 (Not possible)
 No possible value of
b is possible.

Sol 16. Total case = 18C5

Favourable cases
6 3 7
C1 C1 C1
(Select x1) (Select x3) (Select x5)
6.3.7 1
P = 18 =
C5 68

Sol 17. Given P(X = 3) = 5P (X = 4) and n = 7

7 C3p3q4 = 57 C4p4q3
 q = 5p and also p + q = 1
1 5
 p = and q =
6 6
7 35
Mean = and variance =
6 36
Mean + Variance
7 35 77
= + +
6 36 36
   2 6  
2 4 6
sin3    + 
Sol 18. + cos + cos =  7
cos 
7 7 
7 7 7  2
sin
7
 3   4   8 
sin   .cos   2sin 4  cos 4  sin   − sin 
=  
7  7 = 7 7 =  7 = 7 = −1
    2
sin   2sin 2sin 2sin
 
7 7 7 7

 3 
−1 − 3

Sol 19. sin−1   + tan ( −1 )
−1
 + cos 
 2   2 
 5 
= + −
3 6 4
4 + 10 − 3 11
= =
12 12

Sol 20.

pq pq pq

p q ( (p  q))  q p→q p → (p  q)
T T T F T T T T
T F F T T T F T
F T F T T T T T
F F F T T F T T
Tautology Tautology

Section – B
2x 2 −2x
2e 2e
Sol 1. f (x ) = and f (1 − x ) = 2−2x 1−x
e +e
2x x
e +e
f ( x ) + f (1 − x )
 =1
2
i.e. f(x) + f(1 – x) = 2
 1   2   99 
f  +f  + .... + f  
 100   100   100 
49
 x   x  1
 f  100  + f  1 − 100  + f  2 
x =1

= 49 × 2 + 1 = 99

Sol 2. Let ex = t then equation reduces to

45 81
t2 − 11t − + = 0
t 2
 2t − 22t + 81t − 45 = 0
3 2
…….(i)
If roots of
81
e2x − 11ex − 45e−x + = 0
2
  1 + 2 +  3 = n45  p = 45

adj( adj ( A ) ) = A
22 4
Sol 3. =A
14 28 −14
4
 A = −14 14 28
25 −14 14
1 2 −1
= (14 )
3
−1 1 2
2 −1 1

= (14 ) ( 3 − 2 ( −5) − 1 ( −1) )

3

A = (14 )  A = 14
4 4

Sol 4. First we arrange 5 red cubes in a row and assume x1 ,x 2 ,x 3 ,x 4 ,x 5 and x 6 number of blue cubes
between them
Here,x1 + x2 + x 3 + x 4 + x 5 + x 6 = 11
and x 2 ,x 3 ,x 4 ,x 5  2
so x1 + x2 + x 3 + x 4 + x 5 + x 6 = 3
No. of solutions = 8C5 = 56
60 −r r 60 −r r
 1   −1   −41   12 
Sol 5. Tr +1 = Cr  x 2   x 3 
60
5  5 
       
for
60 − r r
x10 − = 10
2 3
 180 − 3r − 2r = 60
 r = 24
60
k = 3 + exponent of 5 in C24
  60   60   24   24   36   36  
= 3+  +  2  −   −  2  −   −  2 
 5  5   5  5   5  5 
= 3 + (12 + 2 – 4 – 0 – 7 – 1)
=3+2=5

Sol 6.

Required area (above x-axis)

  8−x
4

A1 = 2  − x  dx
0 
2
 16 8  40
= 2  16 − − =
 4 3 / 2  3
1 
and A2 = 4  .k2  = 2k2
2 

= 5. (2k2 )
40
27.
3
k=6
for above x-axis.

r
Sol 7. Tr =
(2r ) 2 2
+1
r
=
(2r + 1 ) − ( 2r )
2 2 2

1 4r
=
4 (2r + 2r + 1)(2r2 − 2r + 1)
2

1 10  1 1 
S10 =   − 
4 r =1  (2r2 − 2r + 1) (2r2 + 2r + 1) 
 
1 220 55 m
 S10 = . = =
4 221 221 n
m + m = 276

Sol 8. As slope of line joining (1, 2) and (3, 6) is 2 given diameter is parallel to side
( 3 − 1) + ( 6 − 2 )
2 2
a = = 20 and
b 4 8
= b =
2 5 5
Area
8
ab = 2 5. = 16
5

Sol 9. Let the equation of circle be

  1
x  x −  + y2 + y = 0
 2
1
 x2 + y2 − x + y = 0
2
1 2
Radius = + =2
16 4
2 2
63  1  
 2 =  x −  +y +  = 4
4  4  2
This circle and parabola
2
 1
y −  =  x −  touch each other, so
 4
  2 63
 = − + 2   − 2 = −  (  − 2) = =
2

2 2 4 16
( 4 − 8 )
2
= 63

x − a y − b z − c −2 ( 3a − 4b + 12c + 19 )
Sol 10. = = =
−4 32 + ( −4 ) + 122
2
3 12
x − a y − b z − c −6a + 8b − 24c − 38
= = =
3 −4 12 169
( x,y,z )  ( a − 6,,  )
( a − b ) − a =  − b =  − c = −6a + 8b − 24c − 38
3 −4 12 169
 −b
= −2
−4
 = 8 + b
 3a − 4b + 12c = 150 …..(i)
a+b+c=5
 3a + 3b + 3c = 15 …..(ii)
Applying (i) – (ii), we get :
= 56 + 216 + 7b – 9c = 56 + 216 – 135 = 137