Clariant SDS PRAEPAGEN WB Brazil English

SAFETY DATA SHEET
ABNT NBR 14725-4:2014 Standard
PRAEPAGEN WB Page 1(23)

Substance key: SXR112695 Revision Date: 28.06.2023
Version : 1 - 1 / BR Date of printing : 28.09.2023
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Substance or preparation name (trade name)

PRAEPAGEN WB
Internal substance key for identification of product

Material number : 110009
Substance key : SXR112695
Name of company / address

GAC - GLOBAL AMINES COMÉRCIO DE PRODUTOS QUÍMICOS
Avenida das Nações Unidas, 18.001, 8º andar, Sala 817
Santo Amaro - São Paulo
Telephone no. : +55 11 5683 7358
Information about the substance / preparation

Product Stewardship
e-mail : [email protected]
Emergency telephone number : +55 11 47 47 47 41 (24 h)
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification in accordance with ABNT NBR 14725 Standard

Skin corrosion : Category 1A
Serious eye damage : Category 1
Short-term (acute) aquatic : Category 2

hazard
Long-term (chronic) aquatic : Category 1

hazard
GHS label elements in accordance with ABNT NBR 14725 Standard

Hazard pictograms :
Signal word : Danger
Hazard statements : H314 Causes severe skin burns and eye damage.
H401 Toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention:
P260 Do not breathe dust.
P264 Wash skin thoroughly after handling.
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P273 Avoid release to the environment.

P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water/
shower.
P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a
POISON CENTER/ doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/ doctor.
P363 Wash contaminated clothing before reuse.
P391 Collect spillage.
Other hazards which do not result in classification

None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Chemical nature : Preparation of distearyldimethylammonium chloride in ethanol.
Components
Chemical name CAS-No. Classification Concentration (% w/w)
Distearyldimethylammonium 61789-80-8 Serious eye damage, >= 70 -< 90
chloride Category 1
Short-term (acute)
aquatic hazard,
Category 2
Long-term (chronic)
aquatic hazard,
Category 1
Ethanol 64-17-5 Flammable liquids, >= 10 -< 20

Category 2
Eye irritation,
Category 2A
Bis(hydrogenated tallow 61788-63-4 Skin irritation, >= 1 -< 2,5

alkyl)methylamine Category 2
Short-term (acute)
aquatic hazard,
Category 1
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SAFETY DATA SHEET

SECTION 4. FIRST AID MEASURES
General advice : Remove/ Take off immediately all contaminated clothing.
If inhaled : If inhaled, remove to fresh air.

Get medical advice/ attention.
In case of skin contact : Wash off immediately with plenty of water.

Consult a physician.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Consult a physician.
If swallowed : Rinse mouth with water.

If conscious, give the victim plenty of water to drink.
Get medical advice/ attention.
Most important symptoms : Inhalation may provoke the following symptoms:

and effects, both acute and Coughing
delayed Dizziness
Drowsiness
Headache
Protection of first-aiders : First Aid responders should pay attention to self-protection

and use the recommended protective clothing
Notes to physician : Treat symptomatically.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Water mist

Foam
Dry chemical
Carbon dioxide (CO2)
Specific hazards during : In case of fire hazardous decomposition products may be

firefighting produced such as:
Nitrogen oxides (NOx)
Hydrogen chloride
Carbon monoxide
Specific extinguishing : Cool endangered containers with water spray jet.

methods
Special protective equipment : Self-contained breathing apparatus

for firefighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
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Personal precautions, : Stay upwind/ keep distance from source.

protective equipment and Keep away sources of ignition.
emergency procedures
Environmental precautions : Do not empty into drains.
Methods and materials for : Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, universal binder, sawdust).
SECTION 7. HANDLING AND STORAGE
Advice on protection against : Ignitable mixtures can form in the empty container.
fire and explosion Take precautionary measures against build-up of electrostatic
charges, e.g earthing during loading and off-loading
operations.
Use explosion-proof equipment.
Use only non-sparking tools.
Advice on safe handling : Handle and open container with care.

Ensure adequate ventilation.
Observe emission limit.
Hygiene measures : When using do not eat, drink or smoke.

Take off immediately all contaminated clothing and wash it
before reuse.
Wash hands immediately after work, if necessary take a
shower
Conditions for safe storage : Compatible with packaging of stainless steel with ceramic
coating of high performance and corrosion resistance or
polyethylene packaging.
Further information on : Keep containers tightly closed in a dry, cool and well-
storage conditions ventilated place.
Materials to avoid : Do not store together with

Alkalis
oxidants
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters

Components CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
Ethanol 64-17-5 LT 780 ppm BR OEL
1.480 mg/m3
Further information: Degree of harmfulness: minimum
STEL 1.000 ppm ACGIH
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SAFETY DATA SHEET

Engineering measures : Local ventilation recommended - mechanical ventilation may

be used.
Personal protective equipment

Respiratory protection : Half mask
Filter A (organic gases and vapours) to standard DIN EN 141
The use of filter apparatus presupposes that the environment

atmosphere contains at least 17% oxygen by volume, and
does not exceed the maximum gas concentration, usually
0.5% by volume. Relevant guidelines to be considered
include EN 136/141/143/371/372 as well as other national
regulations.
Hand protection
Remarks : PVC or PE gloves
Take note of the information given by the producer

concerning permeability and break through times, and of
special workplace conditions (mechanical strain, duration of
contact).
Eye protection : Depending on the risk, wear sufficient eye protection (safety
glasses with side protection or goggles, and if necessary,
face shield.)
Skin and body protection : Wear suitable protective clothing.

PVC apron
PVC Boots - depending on the operation, consider using
PVC Boots with steel toe caps.
Protective measures : Do not inhale vapours

Avoid contact with skin and eyes.
Ensure that eyewash stations and safety showers are close
to the workstation location.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Pasty solid
Colour : light yellow
Odour : mild alcoholic
Odour Threshold : not tested.
pH : 6,5 (20 °C)

Concentration: 10 g/l
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SAFETY DATA SHEET

Method: ASTM E 70
Melting point : approx. 35 - 45 °C

Method: ASTM D 2386
Boiling point : approx. 95 - 113 °C

Method: OECD Test Guideline 103
Flash point : 19 °C
Method: closed cup
Burning number : 2
Short flaring up without spreading
Upper explosion limit / upper : 13,7 %(V)

flammability limit Data relate to solvent
Lower explosion limit / Lower : 3,7 %(V)

flammability limit Data relate to solvent
Vapour pressure : 0,00573 hPa (20 °C)
Relative vapour density : Not applicable
Density : 0,86 g/cm3 (50 °C)

0,91 g/cm3 (25 °C)

Solubility(ies)
Water solubility : 10 - 50 g/l emulsifiable (50 °C)
Solubility in other solvents : > 1.000 g/lsoluble

Solvent: Ethanol
Partition coefficient: n- : This property is not applicable for mixtures.

octanol/water
Auto-ignition temperature : ca. 385 °C

Method: ASTM E 659
Decomposition temperature : >= 170 °C

Heating rate: 3 K/min
Decomposition energy (mass): 724 kJ/kg
Method: ASTMD 3417
Viscosity
Viscosity, dynamic : approx. 34 mPa.s ( 50 °C)
Method: DIN 53015
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SAFETY DATA SHEET

Viscosity, kinematic : approx. 39,5 mm2/s ( 50 °C)

Method: calculated
Dust explosion class : not capable of dust explosion
SECTION 10. STABILITY AND REACTIVITY
Reactivity : See section 10.3. "Possibility of hazardous reactions"
Chemical stability : Stable
Possibility of hazardous : oxidants

reactions Alkalis
Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Strong acids and oxidizing agents
Hazardous decomposition : Hydrogen chloride

products Nitrogen oxides (NOx)
SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Product:
Acute oral toxicity : LD50 (Rat): > 2.000 mg/kg
Acute inhalation toxicity : LC50 (Mouse): ca. 39 mg/l

Exposure time: 4 h
Test atmosphere: dust/mist
Remarks: The data refer to the solvent
Components:
Distearyldimethylammonium chloride:
Acute oral toxicity : LD50 (Rat, male and female): > 2.000 mg/kg
GLP: yes
Assessment: The substance or mixture has no acute oral
toxicity
Remarks: By analogy with a product of similar composition
Acute inhalation toxicity : LC50 (Rat, male): > 180 mg/l

Exposure time: 1 h
Test atmosphere: dust/mist
Method: FDA method
GLP: no
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Acute dermal toxicity : LD50 (Rat, male and female): > 2.000 mg/kg
GLP: yes
Assessment: The substance or mixture has no acute dermal
toxicity
Ethanol:
Acute oral toxicity : LD50 (Rat, male and female): 10.470 mg/kg
GLP: no
Acute inhalation toxicity : LC50 (Rat, male and female): 124,7 mg/l
Exposure time: 4 h
Test atmosphere: vapour
GLP: no
Acute dermal toxicity : LD50 (Rabbit): > 2.000 mg/kg

Assessment: The substance or mixture has no acute dermal
toxicity
Skin corrosion/irritation
Product:
Species : Rabbit
Exposure time : 4h
Assessment : corrosive (causes burns)
Method : OECD Test Guideline 404
Result : Corrosive
Remarks : Information given is based on tests on the mixture itself.
Components:
Species : Rabbit
Exposure time : 4h
Result : No skin irritation
GLP : yes
Remarks : By analogy with a product of similar composition
Ethanol:
Species : Rabbit
Exposure time : 24 h
Result : No skin irritation
GLP : yes
Bis(hydrogenated tallow alkyl)methylamine:
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Result : Irritating to skin.
Serious eye damage/eye irritation

Product:
Species : rabbit eye
Result : Corrosive
Assessment : Risk of serious damage to eyes.
Components:
Species : rabbit eye
Result : Risk of serious damage to eyes.
Exposure time : 24 h
GLP : yes
Ethanol:
Species : Rabbit
Result : Irritating to eyes.
GLP : No information available.
Respiratory or skin sensitisation

Components:
Test Type : Guinea pig maximization test
Exposure routes : Skin contact
Species : Guinea pig
Result : Does not cause skin sensitisation.
GLP : yes
Ethanol:
Exposure routes : Dermal
Species : Mouse
Method : Other
Result : Not a skin sensitizer.
Germ cell mutagenicity

Product:
Germ cell mutagenicity - : Contains no ingredient listed as a mutagen
Assessment
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Components:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Concentration: 4 - 1000
Metabolic activation: with and without metabolic activation
Result: negative
GLP: no
Test Type: Chromosome aberration test in vitro

Test system: Chinese hamster lung cells
Concentration: 4 - 50 mg/ml
Result: negative
GLP: yes
Germ cell mutagenicity - : It is concluded that the product is not mutagenic based on
Assessment evaluation of several mutagenicity tests.
Ethanol:
Genotoxicity in vitro : Test Type: Ames test
Test system: Salmonella typhimurium
Result: negative
GLP: No information available.
Test Type: In vitro mammalian cell gene mutation test

Test system: mouse lymphoma cells
Result: negative
Test Type: Chromosome aberration test in vitro

Test system: Human lymphocytes
Result: negative
Genotoxicity in vivo : Test Type: In vivo micronucleus test

Species: Rat (male)
Strain: Other
Cell type: Bone marrow
Application Route: Drinking water
Result: negative
Germ cell mutagenicity - : It is concluded that the product is not mutagenic based on
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Assessment evaluation of several mutagenicity tests.
Carcinogenicity
Product:
Carcinogenicity - : Contains no ingredient listed as a carcinogen
Assessment
Components:
Carcinogenicity - : Not classifiable as a human carcinogen.
Assessment
Ethanol:
Species : Mouse, female
Application Route : Drinking water
Exposure time : 24 month(s)
Dose : 0, 2.5 and 5% in drinking wate
Control Group : yes
: 4.400 mg/kg bw/day
Method : OPPTS 870.4200
GLP : yes
Carcinogenicity - : Not classifiable as a human carcinogen.

Assessment
Reproductive toxicity
Product:
Reproductive toxicity - : Contains no ingredient listed as toxic to reproduction
Assessment No teratogenic effects to be expected.
Components:
Effects on fertility : Test Type: One generation study
Species: Rat, male and female
Application Route: oral (gavage)
Dose: 62,5 - 125 - 500 mg/kg
General Toxicity - Parent: NOAEL: 125 mg/kg body weight
General Toxicity F1: NOAEL: 125 mg/kg body weight
GLP: yes
Effects on foetal : Species: Rat

development Strain: Sprague-Dawley
Application Route: oral (gavage)
Dose: 100 - 500 mg/kg
General Toxicity Maternal: NOAEL: 500 mg/kg body weight
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Teratogenicity: NOAEL: 500 mg/kg body weight

GLP: no
Reproductive toxicity - : No evidence of adverse effects on sexual function and fertility,

Assessment or on development, based on animal experiments.
Ethanol:
Effects on fertility : Test Type: Two-generation study
Species: Mouse, male and female
Strain: CD1
Application Route: Drinking water
Dose: 5, 10 and 15% v/v in water
Duration of Single Treatment: 126 d
General Toxicity - Parent: NOAEL: 15 %
General Toxicity F1: NOAEL: 10 %
General Toxicity F2: NOAEL: < 15 %
Effects on foetal : Test Type: Pre-natal

development Species: Rat, female
Strain: Sprague-Dawley
Application Route: Inhalation
Dose: 10000, 16000, 20000 ppm nom.
Duration of Single Treatment: 19 d
Frequency of Treatment: 1 daily
General Toxicity Maternal: NOAEL: 16.000 ppm
Teratogenicity: NOAEL: 20.000 ppm
Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.
STOT - single exposure

Components:
Assessment : The substance or mixture is not classified as specific target
organ toxicant, single exposure.
Ethanol:
organ toxicant, single exposure.
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STOT - repeated exposure

Components:
organ toxicant, repeated exposure.
Ethanol:
Remarks : no data available
Repeated dose toxicity

Components:
Species : Rat, male and female
NOAEL : 100 mg/kg
Application Route : oral (gavage)
Exposure time : 29 d
Number of exposures : daily
Dose : 20 - 100 - 500 mg/kg
Control Group : yes
GLP : yes
Species : Rabbit, male and female

NOAEL : 40 mg/kg
Application Route : Skin contact
Exposure time : 28 d
Number of exposures : 5 days per week
Dose : 0,2 - 2 % per unit body weight
Control Group : yes
GLP : yes
Application Route : Inhalation

Remarks : This information is not available.
Ethanol:
Species : Rat, male and female
LOAEL : ca. 3200 mg/kg
Application Route : oral (gavage)
Exposure time : 7 weeks or 14 weeks
Number of exposures : twice daily, 7 days a week
Dose : 5, 10, 20 ml/kg
Control Group : yes
Species : Rat, male

NOEL : > 20 mg/l
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Application Route : inhalation (vapour)

Exposure time : 3, 6, 9, 26 day groups
Number of exposures : continuous
Dose : >20 mg/l
Control Group : yes
Method : Other
Aspiration toxicity
Components:
No aspiration toxicity classification
Ethanol:
No aspiration toxicity classification
Further information
Product:
Remarks : The product has not been tested. The information is derived
from the properties of the individual components.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Product:
Toxicity to fish : LC50 (Danio rerio (zebra fish)): 1,96 mg/l
Exposure time: 96 h
Toxicity to daphnia and other :

aquatic invertebrates Remarks: no data available
Toxicity to algae/aquatic :
plants Remarks: no data available
Toxicity to microorganisms : Remarks: no data available
Components:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 3,55 - 36,2
mg/l
Exposure time: 96 h
Test Type: semi-static test
Analytical monitoring: no data available
Method: EPA
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Remarks: The details of the toxic effect relate to the nominal

concentration.
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 3,1 mg/l
aquatic invertebrates Exposure time: 48 h
Analytical monitoring: yes
Method: EPA
GLP: no
Toxicity to algae/aquatic : EC50 (Selenastrum capricornutum (green algae)): 1,17 mg/l

plants End point: Growth rate
Exposure time: 96 h
Method: Other
River-water test
The details of the toxic effect relate to the nominal
concentration.
NOEC (Scenedesmus capricornutum (fresh water algae)):

0,062 - 0,078 mg/l
End point: Biomass
Exposure time: 5 d
Method: Other
Remarks: River-water test
The details of the toxic effect relate to the nominal
concentration.
M-Factor (Acute aquatic : 1

toxicity)
Toxicity to fish (Chronic : NOEC (Pimephales promelas (fathead minnow)): 0,053 mg/l
toxicity) Exposure time: 34 d
GLP: no
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 0,38 mg/l
aquatic invertebrates End point: Reproduction rate
(Chronic toxicity) Exposure time: 21 d
GLP: no
M-Factor (Chronic aquatic : 10

toxicity)
Toxicity to microorganisms : EC50 (activated sludge): 278 mg/l

End point: Bacteria toxicity (respiration inhibition)
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Exposure time: 3 h
Test Type: aquatic
Analytical monitoring: no
GLP: yes
Remarks: The details of the toxic effect relate to the nominal
concentration.
Toxicity to soil dwelling : Test Type: artificial soil

organisms NOEC (Other): 1.000 mg/kg
Exposure time: 14 d
End point: mortality
Method: Other
Plant toxicity : NOEC: 1.000 mg/kg

Exposure time: 14 d
End point: Growth
Species: Avena sativa (oats)
Method: Other
NOEC: 1.000 mg/kg

Exposure time: 14 d
End point: Growth
Species: Brassica rapa
Method: Other
Sediment toxicity : NOEC (Nematode Caenorhabditis elegans): 1350 mg/kg dry

weight (d.w.)
Sediment: artificial soil
Exposure duration: 3 d
Nominal / Measured: nominal
Basis for effect: Reproduction
Method: ISO 10872
NOEC (Lumbriculus variegatus (Worm)): 5837 mg/kg dry

weight (d.w.)
Sediment: Natural sediment
Exposure duration: 28 d
Basis for effect: Reproduction
Method: Other
Toxicity to terrestrial : Remarks: Not applicable

organisms
Ecotoxicology Assessment
Chronic aquatic toxicity : Very toxic to aquatic life with long lasting effects.
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Ethanol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 15.300 mg/l
Exposure time: 96 h
Test Type: flow-through test
Method: Other
LC50 (Oncorhynchus mykiss (rainbow trout)): 11.200 mg/l

Exposure time: 24 h
Test Type: flow-through test
Method: Other
Toxicity to daphnia and other : LC50 (Ceriodaphnia dubia (water flea)): 5.012 mg/l
aquatic invertebrates End point: mortality
Exposure time: 48 h
Test Type: static test
Method: Other
EC50 (Daphnia magna (Water flea)): > 10.000 mg/l

End point: Immobilization
Exposure time: 48 h
Method: DIN 38412
GLP: no
Toxicity to algae/aquatic : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l
plants Exposure time: 72 h
EC10 (Chlorella vulgaris (Fresh water algae)): 11,5 mg/l

Exposure time: 72 h
Toxicity to fish (Chronic : NOEC (Danio rerio (zebra fish)): 250 mg/l
toxicity) End point: Other
Exposure time: 120 h
Toxicity to daphnia and other : Remarks: no data available

aquatic invertebrates
(Chronic toxicity)
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SAFETY DATA SHEET

Toxicity to microorganisms : EC50 (Natural microorganism): 5.800 mg/l

Exposure time: 4 h
Toxicity to soil dwelling : Remarks: Not applicable

organisms
Plant toxicity : Remarks: Not applicable
Sediment toxicity : Remarks: Not applicable
Toxicity to terrestrial : Remarks: Not applicable

organisms
Bis(hydrogenated tallow alkyl)methylamine:

M-Factor (Acute aquatic : 10
toxicity)
Ecotoxicology Assessment
Acute aquatic toxicity : Very toxic to aquatic life.
Persistence and degradability

Product:
Biodegradability : Result: Readily biodegradable.
Biodegradation: > 90 %
Chemical Oxygen Demand : 2.800 mg/l

(COD)
Components:
Biodegradability : aerobic
Inoculum: activated sludge, domestic
Concentration: 2,6 mg/l
BOD in % of theoretical OD
Result: Not rapidly biodegradable
Biodegradation: 3 %
Exposure time: 28 d
Method: OECD Test Guideline 301D
GLP: yes
Ethanol:
Biodegradability : aerobic
Result: Readily biodegradable.
Biodegradation: 84 %
Exposure time: 20 d
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SAFETY DATA SHEET

Bioaccumulative potential
Components:
Bioaccumulation : Species: Lepomis macrochirus (Bluegill sunfish)
Bioconcentration factor (BCF): 13
Exposure time: 49 d
Concentration: 0,023 mg/l
Ethanol:
Bioaccumulation : Bioconcentration factor (BCF): 0,66
Method: calculated
Remarks: Does not bioaccumulate.
Partition coefficient: n- : log Pow: -0,35 (24 °C)

octanol/water pH: 7,4
Mobility in soil
Components:
Distribution among : Adsorption/Soil
environmental compartments Medium: water - soil
log Koc: < 10
Method: Other
Ethanol:
Distribution among : adsorption
environmental compartments Medium: water - soil
Remarks: Not expected to adsorb on soil.
Other adverse effects

Product:
Additional ecological : The product has not been tested. The information is derived
information from the properties of the individual components.
Components:
Results of PBT and vPvB : Remarks: no data available
assessment
Additional ecological : The results of the river water test must be divided by a factor
information of 10 for the determination of the classification and
labelling/M-factors.
The product should not be allowed to enter drains, water
19 / 23
SAFETY DATA SHEET

courses or the soil.
Ethanol:
Results of PBT and vPvB : This substance is not considered to be persistent,
assessment bioaccumulating and toxic (PBT).
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Must be incinerated in a suitable incineration plant holding a
permit delivered by the competent authorities.
Contaminated packaging : Contaminated packages or drums must be treated as waste,

and must be disposed of or treated for reuse/recycling in an
installation approved by Environmental Authorities according
to local regulations. The wastes generated from such
treatment of the packages must be processed in order to
avoid environmental contamination.
SECTION 14. TRANSPORT INFORMATION
Terrestrial (railways, highways) - ANTT:

Proper shipping name: Flammable solid, corrosive, organic, n.o.s.
Class: 4.1
Packing group: II
UN no. UN 2925
Primary risk: 4.1
Secondary risk: 8
Hazard no. : 48
Remarks Shipment permitted
Hazard inducer(s): Ethanol
Di-hydrogenated tallowfattyalkyl dimethyl ammonium chloride
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SAFETY DATA SHEET

Air - ANAC:
Class: 4.1
Packing group: II
UN/ID number: UN 2925
Primary risk: 4.1
Secondary risk: 8
Ship (sea, rivers, lakes) - IMDG:

Class: 4.1
Packing group: II
UN no. UN 2925
Primary risk: 4.1
Secondary risk: 8
Marine pollutant: Marine Pollutant
EmS : F-A S-G
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
SECTION 15. REGULATORY INFORMATION
Safety, health and environmental regulations/legislation specific for the substance or

mixture
The product is classified and labelled in accordance with GHS regulation and the relevant
national laws.
Brazil. List of chemicals controlled by the Federal : Ethanol
Police
SECTION 16. OTHER INFORMATION
Revision Date : 28.06.2023
Date format : dd.mm.yyyy
Further information
Other information : Observe national and local legal requirements
Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
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SAFETY DATA SHEET

BR OEL : Brazil. NR 15 - Unhealthy activities and operations
ACGIH / STEL : Short-term exposure limit

BR OEL / LT : Up to 48 hours /week
AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer;
IATA - International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing
Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No
Observed (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level;
NOELR - No Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National
Toxicology Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution
Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines
Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity
Relationship; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals;
SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan
Chemical Substance Inventory; TDG - Transportation of Dangerous Goods; TECI - Thailand
Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN - United
Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials
Information System
This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.
22 / 23
SAFETY DATA SHEET

BR / EN
23 / 23

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SAFETY DATA SHEET

ABNT NBR 14725-4:2014 Standard

PRAEPAGEN WB Page 1(23)

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Substance or preparation name (trade name)

Internal substance key for identification of product

Name of company / address

Information about the substance / preparation

Emergency telephone number : +55 11 47 47 47 41 (24 h)

SECTION 2. HAZARDS IDENTIFICATION

GHS Classification in accordance with ABNT NBR 14725 Standard

Serious eye damage : Category 1

Short-term (acute) aquatic : Category 2

Long-term (chronic) aquatic : Category 1

GHS label elements in accordance with ABNT NBR 14725 Standard

Signal word : Danger

PRAEPAGEN WB Page 2(23)

P273 Avoid release to the environment.

Other hazards which do not result in classification

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

Chemical nature : Preparation of distearyldimethylammonium chloride in ethanol.

Ethanol 64-17-5 Flammable liquids, >= 10 -< 20

Bis(hydrogenated tallow 61788-63-4 Skin irritation, >= 1 -< 2,5

PRAEPAGEN WB Page 3(23)

SECTION 4. FIRST AID MEASURES

General advice : Remove/ Take off immediately all contaminated clothing.

If inhaled : If inhaled, remove to fresh air.

In case of skin contact : Wash off immediately with plenty of water.

If swallowed : Rinse mouth with water.

Most important symptoms : Inhalation may provoke the following symptoms:

Protection of first-aiders : First Aid responders should pay attention to self-protection

Notes to physician : Treat symptomatically.

SECTION 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Water mist

Specific hazards during : In case of fire hazardous decomposition products may be

Specific extinguishing : Cool endangered containers with water spray jet.

Special protective equipment : Self-contained breathing apparatus

SECTION 6. ACCIDENTAL RELEASE MEASURES

PRAEPAGEN WB Page 4(23)

Personal precautions, : Stay upwind/ keep distance from source.

Environmental precautions : Do not empty into drains.

SECTION 7. HANDLING AND STORAGE

Advice on safe handling : Handle and open container with care.

Hygiene measures : When using do not eat, drink or smoke.

Materials to avoid : Do not store together with

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

PRAEPAGEN WB Page 5(23)

Engineering measures : Local ventilation recommended - mechanical ventilation may

Personal protective equipment

The use of filter apparatus presupposes that the environment

Take note of the information given by the producer

Skin and body protection : Wear suitable protective clothing.

Protective measures : Do not inhale vapours

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : Pasty solid

Colour : light yellow

Odour : mild alcoholic