MSDS Hand Satitizer

SAFETY DATA SHEET
PURELL® Advanced Instant Hand Sanitizer

Foam
Version Revision Date: MSDS Number: Date of last issue: 12/11/2014

1.1 02/18/2015 36539-00002 Date of first issue: 12/11/2014
SECTION 1. IDENTIFICATION
Product name : PURELL® Advanced Instant Hand Sanitizer Foam
Manufacturer or supplier's details

Company name of supplier : GOJO Industries, Inc.
Address : One GOJO Plaza, Suite 500

Akron OH 44311
Telephone : 1 (330) 255-6000
Emergency telephone : 1-800-424-9300 CHEMTREC
Recommended use of the chemical and restrictions on use

Recommended use : Hand Sanitizer
Restrictions on use : This is a personal care or cosmetic product that is safe for
consumers and other users under normal and reasonably
foreseeable use. Cosmetics and consumer products,
specifically defined by regulations around the world, are
exempt from the requirement of an SDS for the consumer.
While this material is not considered hazardous, this SDS
contains valuable information critical to the safe handling and
proper use of the product for industrial workplace conditions
as well as unusual and unintended exposures such as large
spills. This SDS should be retained and available for
employees and other users of this product. For specific
intended-use guidance, please refer to the information
provided on the package or instruction sheet.
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Flammable liquids : Category 3
Eye irritation : Category 2A
GHS Label element

Hazard pictograms :
Signal Word : Warning
Hazard Statements : H226 Flammable liquid and vapor.
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H319 Causes serious eye irritation.
Precautionary Statements : Prevention:

P210 Keep away from heat/sparks/open flames/hot surfaces. -
No smoking.
P233 Keep container tightly closed.
P241 Use explosion-proof electrical/ ventilating/ lighting/
equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ eye protection/ face protection.
Response:
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
all contaminated clothing. Rinse skin with water/shower.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P337 + P313 If eye irritation persists: Get medical advice/
attention.
Storage:
P403 + P235 Store in a well-ventilated place. Keep cool.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Other hazards
Vapors may form explosive mixture with air.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous ingredients
Chemical Name CAS-No. Concentration (%)
Ethanol 64-17-5 >= 50 - < 70
Propan-2-ol 67-63-0 >= 1 - < 5
SECTION 4. FIRST AID MEASURES
General advice : In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.
If inhaled : If inhaled, remove to fresh air.

Get medical attention if symptoms occur.
In case of skin contact : Wash with water and soap as a precaution.

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In case of eye contact : In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention.
If swallowed : If swallowed, DO NOT induce vomiting.

Rinse mouth thoroughly with water.
Most important symptoms : Causes serious eye irritation.

and effects, both acute and
delayed
Protection of first-aiders : First Aid responders should pay attention to self-protection,

and use the recommended personal protective equipment
when the potential for exposure exists.
Notes to physician : Treat symptomatically and supportively.
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media : Water spray

Alcohol-resistant foam
Dry chemical
Carbon dioxide (CO2)
Unsuitable extinguishing : High volume water jet

media
Specific hazards during fire : Do not use a solid water stream as it may scatter and spread
fighting fire.
Flash back possible over considerable distance.
Vapors may form explosive mixtures with air.
Exposure to combustion products may be a hazard to health.
Hazardous combustion prod- : Carbon oxides

ucts Silicon oxides
Specific extinguishing : Use extinguishing measures that are appropriate to local

methods circumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Special protective equipment : In the event of fire, wear self-contained breathing apparatus.
for fire-fighters Use personal protective equipment.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Remove all sources of ignition.
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protective equipment and Use personal protective equipment.

emergency procedures Follow safe handling advice and personal protective
equipment recommendations.
Environmental precautions : Discharge into the environment must be avoided.

Prevent further leakage or spillage if safe to do so.
Prevent spreading over a wide area (e.g. by containment or oil
barriers).
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.
Methods and materials for : Non-sparking tools should be used.

containment and cleaning up Soak up with inert absorbent material.
Suppress (knock down) gases/vapors/mists with a water spray
jet.
For large spills, provide diking or other appropriate
containment to keep material from spreading. If diked material
can be pumped, store recovered material in appropriate
container.
Clean up remaining materials from spill with suitable
absorbent.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.
SECTION 7. HANDLING AND STORAGE
Technical measures : See Engineering measures under EXPOSURE

CONTROLS/PERSONAL PROTECTION section.
Local/Total ventilation : Use with local exhaust ventilation.

Use only in an area equipped with explosion proof exhaust
ventilation.
Advice on safe handling : Do not breathe vapors or spray mist.

Do not swallow.
Do not get in eyes.
Avoid prolonged or repeated contact with skin.
Handle in accordance with good industrial hygiene and safety
practice.
Non-sparking tools should be used.
Keep container tightly closed.
Keep away from heat and sources of ignition.
Take precautionary measures against static discharges.
Take care to prevent spills, waste and minimize release to the
environment.
Conditions for safe storage : Keep in properly labeled containers.

Keep tightly closed.
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Keep in a cool, well-ventilated place.

Store in accordance with the particular national regulations.
Keep away from heat and sources of ignition.
Materials to avoid : Do not store with the following product types:

Strong oxidizing agents
Organic peroxides
Flammable solids
Pyrophoric liquids
Pyrophoric solids
Self-heating substances and mixtures
Substances and mixtures which in contact with water emit
flammable gases
Explosives
Gases
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Ingredients with workplace control parameters

Ingredients CAS-No. Value type Control Basis
(Form of parameters /
exposure) Permissible
concentration
Ethanol 64-17-5 TWA 1,000 ppm NIOSH REL
1,900 mg/m3
TWA 1,000 ppm OSHA Z-1
1,900 mg/m3
STEL 1,000 ppm ACGIH
Propan-2-ol 67-63-0 TWA 200 ppm ACGIH
STEL 400 ppm ACGIH
TWA 400 ppm NIOSH REL
980 mg/m3
ST 500 ppm NIOSH REL
1,225 mg/m3
TWA 400 ppm OSHA Z-1
980 mg/m3
Biological occupational exposure limits
Ingredients CAS-No. Control Biological Sam- Permissible Basis
parameters specimen pling concentratio
time n
Propan-2-ol 67-63-0 Acetone Urine End of 40 mg/l ACGIH
shift at BEI
end of
work-
week
Engineering measures : Minimize workplace exposure concentrations.
Use only in an area equipped with explosion proof exhaust
ventilation.
Use with local exhaust ventilation.
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Personal protective equipment

Respiratory protection : General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.
Hand protection
Material : Impervious gloves
Material : Flame retardant gloves
Remarks : Choose gloves to protect hands against chemicals depending

on the concentration specific to place of work. Breakthrough
time is not determined for the product. Change gloves often!
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.
Eye protection : Wear the following personal protective equipment:

Safety goggles
Skin and body protection : Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Wear the following personal protective equipment:
Flame retardant antistatic protective clothing.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).
Hygiene measures : Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid
Color : clear, colorless, yellow
Odor : fruity
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Odor Threshold : No data available
pH : 5.5 - 9.0
Melting point/freezing point : No data available
Initial boiling point and boiling : 75 °C

range
Flash point : 25.5 °C
Evaporation rate : No data available
Flammability (solid, gas) : Not applicable
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapor pressure : No data available
Relative vapor density : No data available
Density : 0.895 g/cm3
Solubility(ies)
Water solubility : soluble
Partition coefficient: n- : Not applicable

octanol/water
Autoignition temperature : No data available
Decomposition temperature : The substance or mixture is not classified self-reactive.
Viscosity
Viscosity, kinematic : 10 - 20 mm2/s (20 °C)
Explosive properties : Not explosive
Oxidizing properties : The substance or mixture is not classified as oxidizing.
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Not classified as a reactivity hazard.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reac- : Flammable liquid and vapor.

tions Vapors may form explosive mixture with air.
Can react with strong oxidizing agents.
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Conditions to avoid : Heat, flames and sparks.
Incompatible materials : Oxidizing agents
Hazardous decomposition : No hazardous decomposition products are known.

products
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure

Inhalation
Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Ingredients:
Ethanol:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 124.7 mg/l

Exposure time: 4 h
Test atmosphere: vapor
Propan-2-ol:
Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg
Acute inhalation toxicity : LC50 (Rat): 72.6 mg/l

Exposure time: 4 h
Test atmosphere: vapor
Acute dermal toxicity : LD50 (Rat): > 5,000 mg/kg
Skin corrosion/irritation
Product:
Result: No skin irritation
Ingredients:
Ethanol:
Species: Rabbit
Method: OECD Test Guideline 404
Propan-2-ol:
Species: Rabbit
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Serious eye damage/eye irritation

Causes serious eye irritation.
Ingredients:
Ethanol:
Species: Rabbit
Result: Irritation to eyes, reversing within 21 days
Propan-2-ol:
Species: Rabbit
Result: Irritation to eyes, reversing within 21 days
Respiratory or skin sensitization

Skin sensitization: Not classified based on available information.
Respiratory sensitization: Not classified based on available information.
Product:
Assessment: Does not cause skin sensitization.
Ingredients:
Ethanol:
Test Type: Local lymph node assay (LLNA)
Routes of exposure: Skin contact
Species: Mouse
Result: negative
Propan-2-ol:
Test Type: Buehler Test
Routes of exposure: Skin contact
Species: Guinea pig
Result: negative
Germ cell mutagenicity

Ingredients:
Ethanol:
Genotoxicity in vitro : Test Type: In vitro mammalian cell gene mutation test
Result: negative
Genotoxicity in vivo : Test Type: Rodent dominant lethal test (germ cell) (in vivo)
Species: Mouse
Application Route: Ingestion
Result: negative
Propan-2-ol:
Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo
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cytogenetic assay)
Species: Mouse
Application Route: Intraperitoneal injection
Result: negative
Carcinogenicity
Ingredients:
Propan-2-ol:
Species: Rat
Application Route: inhalation (vapor)
Exposure time: 104 weeks
Result: negative
IARC No ingredient of this product present at levels greater than or

equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA No ingredient of this product present at levels greater than or

equal to 0.1% is identified as a carcinogen or potential carcino-
gen by OSHA.
NTP No ingredient of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Reproductive toxicity
Ingredients:
Ethanol:
Effects on fertility : Test Type: Two-generation reproduction toxicity study
Species: Mouse
Result: negative
Propan-2-ol:
Effects on fertility : Test Type: Two-generation reproduction toxicity study
Species: Rat
Result: negative
Effects on fetal development : Test Type: Embryo-fetal development

Species: Rat
Result: negative
STOT-single exposure
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Ingredients:
Propan-2-ol:
Assessment: May cause drowsiness or dizziness.
STOT-repeated exposure
Repeated dose toxicity
Ingredients:
Ethanol:
Species: Rat
NOAEL: 2,400 mg/kg
Exposure time: 2 y
Propan-2-ol:
Species: Rat
NOAEL: 5000 ppm
Application Route: inhalation (vapor)
Exposure time: 104 w
Aspiration toxicity
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Ingredients:
Ethanol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): > 1,000 mg/l
Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 1,000 mg/l
aquatic invertebrates Exposure time: 48 h
Toxicity to algae : EC50 (Chlorella vulgaris (Fresh water algae)): 275 mg/l
Exposure time: 72 h
Toxicity to daphnia and other : NOEC (Daphnia magna (Water flea)): 9.6 mg/l
aquatic invertebrates Exposure time: 9 d
(Chronic toxicity)
Toxicity to bacteria : EC50 (Photobacterium phosphoreum): 32.1 mg/l

Exposure time: 0.25 h
Propan-2-ol:
Toxicity to fish : LC50 (Pimephales promelas (fathead minnow)): 10,000 mg/l
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Exposure time: 96 h
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): > 10,000 mg/l
aquatic invertebrates Exposure time: 24 h
Toxicity to algae : ErC50 (Scenedesmus quadricauda (Green algae)): > 1,800

mg/l
Exposure time: 8 d
Toxicity to bacteria : EC50 (Pseudomonas putida): > 1,050 mg/l

Exposure time: 16 h
Persistence and degradability
Ingredients:
Ethanol:
Biodegradability : Result: Readily biodegradable.
Biodegradation: 84 %
Exposure time: 20 d
Propan-2-ol:
Biodegradability : Result: rapidly degradable
Bioaccumulative potential
Ingredients:
Ethanol:
Partition coefficient: n- : log Pow: -0.35
octanol/water
Propan-2-ol:
Partition coefficient: n- : log Pow: 0.05
octanol/water
Mobility in soil
No data available
Other adverse effects
No data available
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Dispose of in accordance with local regulations.
Contaminated packaging : Dispose of as unused product.

Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not burn, or use a cutting torch on, the empty drum.
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SECTION 14. TRANSPORT INFORMATION
International Regulation
UNRTDG
UN number : UN 1987
Proper shipping name : ALCOHOLS, N.O.S.
(Ethanol, Propan-2-ol)
Class : 3
Packing group : III
Labels : 3
IATA-DGR
UN/ID No. : UN 1987
Proper shipping name : Alcohols, n.o.s.
Class : 3
Packing group : III
Labels : Flammable Liquids
Packing instruction (cargo : 366
aircraft)
Packing instruction : 355
(passenger aircraft)
IMDG-Code
UN number : UN 1987
Class : 3
Packing group : III
Labels : 3
EmS Code : F-E, S-D
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49 CFR
UN/ID/NA number : UN 1987
Class : 3
Packing group : III
Labels : FLAMMABLE LIQUID
ERG Code : 127
Marine pollutant : no
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SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know
CERCLA Reportable Quantity

This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards : Fire Hazard

Acute Health Hazard
SARA 302 : No chemicals in this material are subject to the reporting

requirements of SARA Title III, Section 302.
SARA 313 : The following components are subject to reporting levels

established by SARA Title III, Section 313:
Propan-2-ol 67-63-0 3.013 %
US State Regulations
Pennsylvania Right To Know

Ethanol 64-17-5 50 - 70 %
Water 7732-18-5 30 - 50 %
Propan-2-ol 67-63-0 1-5%
New Jersey Right To Know
Ethanol 64-17-5 50 - 70 %
Water 7732-18-5 30 - 50 %
Propan-2-ol 67-63-0 1-5%
Dimethyl Siloxane, 102783-01-7 1-5%
Dimethyl(propyl(polyethylene
oxide))hydroxy)siloxy-terminated
California Prop 65 This product does not contain any chemicals known to the
State of California to cause cancer, birth, or any other
reproductive defects.
The ingredients of this product are reported in the following inventories:

REACH : All ingredients (pre-)registered or exempt.
TSCA : All chemical substances in this material are included on or

exempted from listing on the TSCA Inventory of Chemical
Substances.
DSL : All chemical substances in this product comply with the CEPA
1999 and NSNR and are on or exempt from listing on the
Canadian Domestic Substances List (DSL).
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AICS : All ingredients listed or exempt.
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), NECSI (Taiwan), TSCA
(USA)
SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS III:

Flammability
HEALTH 2
3
Instability
Health
2 0 FLAMMABILITY 3
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight,
Special hazard.
2 = Moderate, 3 = High
4 = Extreme, * = Chronic
Full text of other abbreviations

ACGIH : USA. ACGIH Threshold Limit Values (TLV)
ACGIH BEI : ACGIH - Biological Exposure Indices (BEI)
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA Z-1 : USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants
ACGIH / TWA : 8-hour, time-weighted average
ACGIH / STEL : Short-term exposure limit
NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
NIOSH REL / ST : STEL - 15-minute TWA exposure that should not be exceeded
at any time during a workday
OSHA Z-1 / TWA : 8-hour time weighted average
Sources of key data used to : Internal technical data, data from raw material SDSs, OECD
compile the Material Safety eChem Portal search results and European Chemicals Agen-
Data Sheet cy, http://echa.europa.eu/
Revision Date : 02/18/2015
The information provided in this Safety Data Sheet is correct to the best of our knowledge, in-
formation and belief at the date of its publication. The information is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information pro-
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vided relates only to the specific material identified at the top of this SDS and may not be valid
when the SDS material is used in combination with any other materials or in any process, un-
less specified in the text. Material users should review the information and recommendations
in the specific context of their intended manner of handling, use, processing and storage, in-
cluding an assessment of the appropriateness of the SDS material in the user’s end product, if
applicable.
US / Z8
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SAFETY DATA SHEET

PURELL® Advanced Instant Hand Sanitizer

Version Revision Date: MSDS Number: Date of last issue: 12/11/2014

Product name : PURELL® Advanced Instant Hand Sanitizer Foam

Manufacturer or supplier's details

Address : One GOJO Plaza, Suite 500

Telephone : 1 (330) 255-6000

Emergency telephone : 1-800-424-9300 CHEMTREC

Recommended use of the chemical and restrictions on use

SECTION 2. HAZARDS IDENTIFICATION

Eye irritation : Category 2A

GHS Label element

Signal Word : Warning

Hazard Statements : H226 Flammable liquid and vapor.

PURELL® Advanced Instant Hand Sanitizer

Version Revision Date: MSDS Number: Date of last issue: 12/11/2014

H319 Causes serious eye irritation.

Precautionary Statements : Prevention:

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture : Mixture

SECTION 4. FIRST AID MEASURES

If inhaled : If inhaled, remove to fresh air.

In case of skin contact : Wash with water and soap as a precaution.

PURELL® Advanced Instant Hand Sanitizer

Version Revision Date: MSDS Number: Date of last issue: 12/11/2014

If swallowed : If swallowed, DO NOT induce vomiting.

Most important symptoms : Causes serious eye irritation.

Protection of first-aiders : First Aid responders should pay attention to self-protection,

Notes to physician : Treat symptomatically and supportively.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Water spray

Unsuitable extinguishing : High volume water jet

Hazardous combustion prod- : Carbon oxides

Specific extinguishing : Use extinguishing measures that are appropriate to local

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, : Remove all sources of ignition.

PURELL® Advanced Instant Hand Sanitizer

Version Revision Date: MSDS Number: Date of last issue: 12/11/2014

protective equipment and Use personal protective equipment.

Environmental precautions : Discharge into the environment must be avoided.

Methods and materials for : Non-sparking tools should be used.

SECTION 7. HANDLING AND STORAGE

Technical measures : See Engineering measures under EXPOSURE

Local/Total ventilation : Use with local exhaust ventilation.

Advice on safe handling : Do not breathe vapors or spray mist.

Conditions for safe storage : Keep in properly labeled containers.

PURELL® Advanced Instant Hand Sanitizer

Version Revision Date: MSDS Number: Date of last issue: 12/11/2014

Keep in a cool, well-ventilated place.

Materials to avoid : Do not store with the following product types:

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

PURELL® Advanced Instant Hand Sanitizer

Version Revision Date: MSDS Number: Date of last issue: 12/11/2014

Personal protective equipment

Material : Flame retardant gloves

Remarks : Choose gloves to protect hands against chemicals depending

Eye protection : Wear the following personal protective equipment:

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES