Sodium Hydroxide, 18% w/w (5.39N) (5.

39M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Issue date: 10/15/2013 Revision date: 02/01/2021 Supersedes: 04/03/2018 Version: 1.2

SECTION 1: Identification
1.1. Identification
Product form : Mixtures
Product name : Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Product code : LC24085
1.2. Recommended use and restrictions on use
Use of the substance/mixture : For laboratory and manufacturing use only.
Recommended use : Laboratory chemicals
Restrictions on use : Not for food, drug or household use
1.3. Supplier
LabChem, Inc.
1010 Jackson's Pointe Ct.
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
[email protected] - www.labchem.com

1.4. Emergency telephone number

Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970

SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS US classification
Skin corrosion/irritation Category 1B H314 Causes severe skin burns and eye damage
Serious eye damage/eye irritation Category 1 H318 Causes serious eye damage
Full text of H statements : see section 16

2.2. GHS Label elements, including precautionary statements

GHS US labeling
Hazard pictograms (GHS US) :

Signal word (GHS US) : Danger

Hazard statements (GHS US) : H314 - Causes severe skin burns and eye damage
H318 - Causes serious eye damage
Precautionary statements (GHS US) : P260 - Do not breathe mist, spray, vapors.
P264 - Wash exposed skin thoroughly after handling.
P280 - Wear eye protection, face protection, protective clothing, protective gloves.
P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 - Immediately call a poison center or doctor/physician.
P321 - Specific treatment (see supplemental first aid instruction on this label).
P363 - Wash contaminated clothing before reuse.
P405 - Store locked up.
P501 - Dispose of contents/container to comply with local, state and federal regulations.

2.3. Other hazards which do not result in classification

Other hazards not contributing to the : None.
classification

02/01/2021 EN (English US) Page 1

Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

2.4. Unknown acute toxicity (GHS US)

Not applicable

SECTION 3: Composition/Information on ingredients

3.1. Substances
Not applicable
3.2. Mixtures
Name Product identifier % GHS US classification
Water (CAS-No.) 7732-18-5 82 Not classified
Sodium Hydroxide (CAS-No.) 1310-73-2 18 Skin Corr. 1A, H314
Eye Dam. 1, H318
Aquatic Acute 3, H402

Full text of hazard classes and H-statements : see section 16

SECTION 4: First-aid measures

4.1. Description of first aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately
call a poison center or doctor/physician.
First-aid measures after skin contact : Immediately call a poison center or doctor/physician. Remove/Take off immediately all
contaminated clothing. Rinse skin with water/shower.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a poison center or doctor/physician.
First-aid measures after ingestion : Do NOT induce vomiting. Immediately call a poison center or doctor/physician. Rinse mouth.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after inhalation : Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes.
Symptoms/effects after skin contact : Caustic burns/corrosion of the skin.
Symptoms/effects after eye contact : Causes serious eye damage.
Symptoms/effects after ingestion : Abdominal pain. Bleeding of the gastrointestinal tract. Burns to the gastric/intestinal mucosa.
Nausea. Possible esophageal perforation.
Symptoms/effects upon intravenous : Not available.
administration
Chronic symptoms : Not available.
4.3. Immediate medical attention and special treatment, if necessary
Obtain medical assistance.

SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Carbon dioxide. Dry powder. Water spray. Foam. Sand.
Unsuitable extinguishing media : Not available. Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Not flammable.
Explosion hazard : Not available.
Reactivity in case of fire : Reacts with (some) metals: release of highly flammable gases/vapours (hydrogen). Thermal
decomposition generates : Corrosive vapors.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. In case of fire, stop leak if safe to do so. When cooling/extinguishing: no water in
the substance. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Other information : Not available.

02/01/2021 EN (English US) 2/9

Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Eliminate ignition sources. Ensure adequate ventilation. Wear self-contained breathing
apparatus when entering area unless atmosphere is proved to be safe.

6.1.1. For non-emergency personnel

Protective equipment : Wear chemically protective gloves, lab coat or apron to prevent prolonged or repeated skin
contact.
Emergency procedures : Wash contaminated clothes. Evacuate unnecessary personnel. Keep containers closed.

6.1.2. For emergency responders

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Stop leak if safe to do so. Ventilate area.
6.2. Environmental precautions
Avoid release to the environment. Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
6.3. Methods and material for containment and cleaning up
For containment : Take up liquid spill into inert absorbent material.
Methods for cleaning up : Carefully collect the spill/leftovers. Clean contaminated surfaces with an excess of water. Wash
clothing and equipment after handling. Soak up spills with inert solids, such as clay or
diatomaceous earth as soon as possible. Collect spillage. Store away from other materials.
6.4. Reference to other sections
See Heading 8. Exposure controls and personal protection.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Additional hazards when processed : May be corrosive to metals.
Precautions for safe handling : Do not get in eyes, on skin, or on clothing. Remove contaminated clothing immediately. Use
corrosionproof equipment. Wash hands and other exposed areas with mild soap and water
before eating, drinking or smoking and when leaving work. Provide good ventilation in process
area to prevent formation of vapor. Do not breathe mist, spray, vapors.
Hygiene measures : Wash exposed skin thoroughly after handling. Wash contaminated clothing before reuse.
7.2. Conditions for safe storage, including any incompatibilities
Technical measures : Comply with applicable regulations.
Storage conditions : Keep container closed when not in use. Store in original container. Keep only in the original
container in a cool, well ventilated place away from : incompatible materials.
Incompatible products : Strong acids. metals.
Incompatible materials : Sources of ignition. Direct sunlight.
Storage temperature : 5 – 30 °C
Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: strong acids. metals. metal powders.
Storage area : Keep locked up. Store in a well-ventilated place. Keep only in the original container.
Special rules on packaging : SPECIAL REQUIREMENTS: corrosion-proof.
Packaging materials : Do not store in corrodable metal.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Sodium Hydroxide, 18% w/w (5.39N) (5.39M)

No additional information available
Water (7732-18-5)
No additional information available
Sodium Hydroxide (1310-73-2)
USA - ACGIH - Occupational Exposure Limits
Local name Sodium hydroxide
ACGIH Ceiling (mg/m³) 2 mg/m³
Remark (ACGIH) TLV® Basis: URT, eye, & skin irr

02/01/2021 EN (English US) 3/9

Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Regulatory reference ACGIH 2020

USA - OSHA - Occupational Exposure Limits
Local name Sodium hydroxide
OSHA PEL (TWA) [1] 2 mg/m³
Regulatory reference (US-OSHA) OSHA Annotated Table Z-1
USA - IDLH - Occupational Exposure Limits
IDLH 10 mg/m³
USA - NIOSH - Occupational Exposure Limits
NIOSH REL (Ceiling) 2 mg/m³

8.2. Appropriate engineering controls

Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential
exposure.

8.3. Individual protection measures/Personal protective equipment

Personal protective equipment:
Gloves. Safety glasses. Protective clothing. Head/neck protection. Chemical resistant apron.

Hand protection:
Wear chemically resistant protective gloves. Wear protective gloves.

Eye protection:
Chemical goggles or face shield

Skin and body protection:

Wear suitable protective clothing

Respiratory protection:
Respiratory protection not required in normal conditions

Personal protective equipment symbol(s):

Thermal hazard protection:

None necessary.
Other information:
Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Clear, colorless liquid.
Color : clear Colorless
Odor : odorless
Odor threshold : No data available
pH : ≥ 14
Melting point : No data available
Freezing point : No data available
Boiling point : No data available
Flash point : No data available
Relative evaporation rate (butyl acetate=1) : No data available

02/01/2021 EN (English US) 4/9

Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Flammability (solid, gas) : Non flammable.

Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Density : 1.2 g/ml
Solubility : No data available
Log Pow : No data available
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Viscosity, kinematic : 3.09 mm²/s
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available.
Oxidizing properties : No data available.
9.2. Other information
No additional information available

SECTION 10: Stability and reactivity

10.1. Reactivity
Reacts with (some) metals: release of highly flammable gases/vapours (hydrogen). Thermal decomposition generates : Corrosive vapors.
10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions
Reacts vigorously with strong oxidizers and acids.
10.4. Conditions to avoid
Incompatible materials. Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
metals. Strong acids. Strong oxidizers.
10.6. Hazardous decomposition products
Sodium oxide. Thermal decomposition generates : Corrosive vapors.

SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
LD50 dermal rabbit 7500 mg/kg
ATE US (dermal) 7500 mg/kg body weight
Water (7732-18-5)
LD50 oral rat ≥ 90000 mg/kg
ATE US (oral) 90000 mg/kg body weight
Skin corrosion/irritation : Causes severe skin burns.
pH: ≥ 14
Serious eye damage/irritation : Causes serious eye damage.
pH: ≥ 14
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified

Reproductive toxicity : Not classified

02/01/2021 EN (English US) 5/9

Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

STOT-single exposure : Not classified

STOT-repeated exposure : Not classified

Aspiration hazard : Not classified

Viscosity, kinematic : 3.09 mm²/s

Likely routes of exposure : Skin and eye contact.

Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
Symptoms/effects : Causes severe skin burns and eye damage.
Symptoms/effects after inhalation : Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes.
Symptoms/effects after skin contact : Caustic burns/corrosion of the skin.
Symptoms/effects after eye contact : Causes serious eye damage.
Symptoms/effects after ingestion : Abdominal pain. Bleeding of the gastrointestinal tract. Burns to the gastric/intestinal mucosa.
Nausea. Possible esophageal perforation.
Symptoms/effects upon intravenous : Not available.
administration
Chronic symptoms : Not available.

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Ecology - water : Toxic to aquatic life.
Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
LC50 fish 1 252 mg/l
EC50 Daphnia 1 224 mg/l

Sodium Hydroxide (1310-73-2)

EC50 Daphnia 1 40.4 mg/l (48 h, Ceriodaphnia sp., Experimental value, Locomotor effect)

12.2. Persistence and degradability

Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Persistence and degradability Not established.
Water (7732-18-5)
Persistence and degradability Not established.
Sodium Hydroxide (1310-73-2)
Persistence and degradability Biodegradability: not applicable.
Chemical oxygen demand (COD) Not applicable (inorganic)
ThOD Not applicable (inorganic)

12.3. Bioaccumulative potential

Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Bioaccumulative potential Not established.
Water (7732-18-5)
Bioaccumulative potential Not established.
Sodium Hydroxide (1310-73-2)
Bioaccumulative potential Not bioaccumulative.

12.4. Mobility in soil

Sodium Hydroxide (1310-73-2)

Surface tension No data available in the literature
Ecology - soil No (test)data on mobility of the substance available.

02/01/2021 EN (English US) 6/9

Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

12.5. Other adverse effects

Other adverse effects : May cause pH changes in aqueous ecological systems.

Other information : Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Disposal methods
Waste disposal recommendations : Dispose of contents/container to comply with local, state and federal regulations. Dispose in a
safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport information

Department of Transportation (DOT)
In accordance with DOT

Transport document description : UN1824 Sodium hydroxide solution, 8, II

UN-No.(DOT) : UN1824
Proper Shipping Name (DOT) : Sodium hydroxide solution
Transport hazard class(es) (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (DOT) : II - Medium Danger
Hazard labels (DOT) : 8 - Corrosive

DOT Packaging Non Bulk (49 CFR 173.xxx) : 202

DOT Packaging Bulk (49 CFR 173.xxx) : 242
DOT Special Provisions (49 CFR 172.102) : B2 - MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are
not authorized.
IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110
kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized.
N34 - Aluminum construction materials are not authorized for any part of a packaging which is
normally in contact with the hazardous material.
T7 - 4 178.274(d)(2) Normal............. 178.275(d)(3)
TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the
following: (image) Where: tr is the maximum mean bulk temperature during transport, tf is the
temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of
cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and
the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For
liquids transported under ambient conditions may be calculated using the formula: (image)
Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C
(59 F) and 50 C (122 F), respectively.
DOT Packaging Exceptions (49 CFR 173.xxx) : 154
DOT Quantity Limitations Passenger aircraft/rail : 1 L
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 30 L
CFR 175.75)
DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel.
DOT Vessel Stowage Other : 52 - Stow ‘‘separated from’’ acids
Other information : No supplementary information available.

Transport by sea (IMDG)

UN-No. (IMDG) : 1824

Proper Shipping Name (IMDG) : SODIUM HYDROXIDE SOLUTION
Class (IMDG) : 8 - Corrosive substances
02/01/2021 EN (English US) 7/9
Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Packing group (IMDG) : II - substances presenting medium danger

Limited quantities (IMDG) : 1L

Air transport (IATA/ICAO)

UN-No. (IATA) : 1824

Proper Shipping Name (IATA) : Sodium hydroxide solution
Class (IATA) : 8 - Corrosives
Packing group (IATA) : II - Medium Danger

SECTION 15: Regulatory information

15.1. US Federal regulations
Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
SARA Section 311/312 Hazard Classes Health hazard - Skin corrosion or Irritation
Health hazard - Serious eye damage or eye irritation
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory
Sodium Hydroxide (1310-73-2)
RQ (Reportable quantity, section 304 of EPA's 1000 lb
List of Lists)
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
15.2. International regulations
CANADA
Water (7732-18-5)
Listed on the Canadian DSL (Domestic Substances List)
Sodium Hydroxide (1310-73-2)
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
No additional information available
National regulations
No additional information available
15.3. US State regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or
reproductive harm

SECTION 16: Other information

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Revision date : 02/01/2021

Other information : None.

Full text of H-phrases: see section 16:

H314 Causes severe skin burns and eye damage
H318 Causes serious eye damage
H402 Harmful to aquatic life
NFPA health hazard : 3 - Materials that, under emergency conditions, can cause
serious or permanent injury.
NFPA fire hazard : 0 - Materials that will not burn under typical fire conditions,
including intrinsically noncombustible materials such as
concrete, stone, and sand.
NFPA reactivity : 1 - Materials that in themselves are normally stable but can
become unstable at elevated temperatures and pressures.

02/01/2021 EN (English US) 8/9

Sodium Hydroxide, 18% w/w (5.39N) (5.39M)
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Hazard Rating
Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
Flammability : 0 Minimal Hazard - Materials that will not burn
Physical : 1 Slight Hazard - Materials that are normally stable but can become unstable (self-react) at high
temperatures and pressures. Materials may react non-violently with water or undergo
hazardous polymerization in the absence of inhibitors.
Personal protection : D
D - Face shield and eye protection, Gloves, Synthetic apron

SDS US LabChem

Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.

02/01/2021 EN (English US) 9/9