SAFETY DATA SHEET

MasterBrace 1441 PART B

Version Revision Date: SDS Number: Date of last issue: -

1.0 01.06.2021 000000338510 Date of first issue: 01.06.2021

1. PRODUCT AND COMPANY IDENTIFICATION

Product name : MasterBrace 1441 PART B

Product code : 000000000050491035

Manufacturer or supplier's details

Company : Master Builders Solutions India Pvt. Ltd

Address : PLOT NO D-126, TTC IND AREA,MIDC , SHIRAVANE

NAVI MUMBAI ,MAHARASHTRA, INDIA MAH 400706

Telephone : +918657927378

Emergency telephone : ChemTel: +1-813-248-0585; India: 000-800-100-4086

Recommended use of the chemical and restrictions on use

Recommended use : Product for construction chemicals

2. HAZARDS IDENTIFICATION

GHS Classification
Skin corrosion : Category 1B

Serious eye damage : Category 1

Skin sensitization : Category 1

Long-term (chronic) aquatic : Category 3

hazard

GHS label elements

Hazard pictograms :

Signal Word : Danger

Hazard Statements : H317 May cause an allergic skin reaction.

H314 Causes severe skin burns and eye damage.
H412 Harmful to aquatic life with long lasting effects.

Precautionary Statements :
Prevention:
P280 Wear protective gloves/ protective clothing/ eye protec-
tion/ face protection.
P260 Do not breathe dusts or mists.
P273 Avoid release to the environment.
P272 Contaminated work clothing should not be allowed out of
the workplace.
P264 Wash face, hands and any exposed skin thoroughly after

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Version Revision Date: SDS Number: Date of last issue: -

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handling.
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/ physi-
cian.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediate-
ly all contaminated clothing. Rinse skin with water/ shower.
P304 + P340 IF INHALED: Remove person to fresh air and
keep comfortable for breathing.
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P362 + P364 Take off contaminated clothing and wash it before
reuse.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/container to appropriate hazardous
waste collection point.

Other hazards which do not result in classification

If applicable information is provided in this section on other hazards which do not result in classi-
fication but which may contribute to the overall hazards of the substance or mixture.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical nature : amine

silicates
Pigment
additives
Components
Chemical name CAS-No. Concentration (%
w/w)
Amines, polyethylenepoly-, triethylenetetramine 90640-67-8 >= 1 - < 3
fraction
3,6,9-triazaundecamethylene-1,11-diamine 112-57-2 >= 0 - < 5
2,4,6-tris(dimethylaminomethyl)phenol 90-72-2 >= 1 - < 3

4. FIRST AID MEASURES

General advice : First aid personnel should pay attention to their own safety.
Immediately remove contaminated clothing.

If inhaled : If difficulties occur after vapour/aerosol has been inhaled,

remove to fresh air and seek medical attention.
In case of skin contact : After contact with skin, wash immediately with plenty of water
and soap.
Under no circumstances should organic solvent be used.
If irritation develops, seek medical attention.
In case of eye contact : Wash affected eyes for at least 15 minutes under running

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MasterBrace 1441 PART B

Version Revision Date: SDS Number: Date of last issue: -

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water with eyelids held open, consult an eye specialist.

If swallowed : Immediately rinse mouth and then drink 200-300 ml of water,
seek medical attention.
Do not induce vomiting unless told to by a poison control cen-
ter or doctor.
Most important symptoms : Causes severe skin burns and eye damage.
and effects, both acute and May cause an allergic skin reaction.
delayed Causes serious eye damage.
Notes to physician : Treat symptomatically.

5. FIRE-FIGHTING MEASURES

Suitable extinguishing media : Foam

Water spray
Dry powder
Carbon dioxide (CO2)
Unsuitable extinguishing : water jet
media
Hazardous combustion prod- : nitrogen oxides
ucts fumes/smoke
carbon black
corrosive gases/vapours
carbon oxides

Specific extinguishing meth- : The degree of risk is governed by the burning substance and
ods the fire conditions.
Contaminated extinguishing water must be disposed of in
accordance with official regulations.
Special protective equipment : Wear a self-contained breathing apparatus.
for fire-fighters

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- : Use personal protective clothing.

tive equipment and emer- Do not breathe vapour/aerosol/spray mists.
gency procedures Handle in accordance with good building materials hygiene
and safety practice.

Environmental precautions : Contain contaminated water/firefighting water.

Do not discharge into drains/surface waters/groundwater.

Methods and materials for : Sweep/shovel up.

containment and cleaning up Dispose of absorbed material in accordance with regulations.

7. HANDLING AND STORAGE

Advice on protection against : The product is not an oxidizer, not self-combustible and not
fire and explosion explosive.

Advice on safe handling : Avoid contact with the skin, eyes and clothing.
Avoid aerosol formation.
Avoid inhalation of mists/vapours.
Avoid skin contact.
Ensure adequate ventilation.
No special measures necessary provided product is used

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SAFETY DATA SHEET

MasterBrace 1441 PART B

Version Revision Date: SDS Number: Date of last issue: -

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correctly.
Further information on stor- : Keep only in the original container in a cool, well-ventilated
age conditions place.
Protect from direct sunlight.
Store protected against freezing.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection : Wear respiratory protection if ventilation is inadequate.
Combination filter for gases/vapours of organic, inorganic,
acid inorganic and alkaline compounds (e.g. EN 14387 Type
ABEK).
Hand protection

Remarks : Suitable chemical resistant safety gloves (EN 374) also with
prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to
EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5
mm), butyl rubber (0.7 mm) etc. Manufacturer's directions for
use should be observed because of great diversity of types.
Eye protection : Wear safety goggles at working overhead and danger of sput-
tering.
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Skin and body protection : Body protection must be chosen depending on activity and
possible exposure, e.g. apron, protecting boots, chemical-
protection suit (according to EN 14605 in case of splashes or
EN ISO 13982 in case of dust).
Protective measures : Avoid contact with the skin, eyes and clothing.
In order to prevent contamination while handling, closed work-
ing clothes and working gloves should be used.
Handle in accordance with good building materials hygiene
and safety practice.
Hygiene measures : When using, do not eat, drink or smoke.
Hands and/or face should be washed before breaks and at the
end of the shift.
At the end of the shift the skin should be cleaned and skin-
care agents applied.
Gloves must be inspected regularly and prior to each use.
Replace if necessary (e.g. pinhole leaks).

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : paste

Color : dark gray

Odor : ammonia-like

pH : alkaline

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MasterBrace 1441 PART B

Version Revision Date: SDS Number: Date of last issue: -

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Boiling range : > 200 °C

Flash point : > 120 °C

negligible

Flammability (solid, gas) : not flammable

Self-ignition : not self-igniting

Upper explosion limit / Upper : Not applicable

flammability limit

Lower explosion limit / Lower : Not applicable

flammability limit

Vapor pressure : < 1 hPa

Density : approx. 1,80 g/cm3 (20 °C)

Bulk density : Not applicable

Solubility(ies)
Water solubility : insoluble

Partition coefficient: n- : not applicable for mixtures

octanol/water
Autoignition temperature : No data available

Decomposition temperature : No decomposition if stored and handled as pre-

scribed/indicated.

Viscosity
Viscosity, dynamic : Not applicable

Explosive properties : Not explosive

Oxidizing properties : not fire-propagating

Self-heating substances : It is not a substance capable of spontaneous heating.

Metal corrosion rate : No corrosive effect on metal.

10. STABILITY AND REACTIVITY

Reactivity : No hazardous reactions if stored and handled as pre-

scribed/indicated.
Chemical stability : The product is stable if stored and handled as pre-
scribed/indicated.
Possibility of hazardous reac- : The product is stable if stored and handled as pre-
tions scribed/indicated.

Conditions to avoid : See SDS section 7 - Handling and storage.

Incompatible materials : Strong acids

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MasterBrace 1441 PART B

Version Revision Date: SDS Number: Date of last issue: -

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Strong bases
Strong oxidizing agents
Hazardous decomposition : No hazardous decomposition products if stored and handled
products as prescribed/indicated.

11. TOXICOLOGICAL INFORMATION

Acute toxicity
Not classified based on available information.
Skin corrosion/irritation
Causes severe skin burns and eye damage.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitization

Skin sensitization
May cause an allergic skin reaction.
Respiratory sensitization
Not classified based on available information.
Germ cell mutagenicity
Not classified based on available information.
Carcinogenicity
Not classified based on available information.
Reproductive toxicity
Not classified based on available information.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Aspiration toxicity
Not classified based on available information.
Product:
No aspiration hazard expected.

Further information

Product:
Remarks : The product has not been tested. The statement has been
derived from the properties of the individual components.

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MasterBrace 1441 PART B

Version Revision Date: SDS Number: Date of last issue: -

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12. ECOLOGICAL INFORMATION

Ecotoxicity

Product:

Ecotoxicology Assessment
Chronic aquatic toxicity : Harmful to aquatic life with long lasting effects.

Persistence and degradability

Product:
Biodegradability : Remarks: Taking into consideration the properties of several
ingredients, the product is estimated not to be readily biode-
gradable according to OECD classification.

Bioaccumulative potential

Product:
Bioaccumulation : Remarks: No data available.
Discharge into the environment must be avoided.

Mobility in soil
No data available
Other adverse effects

Product:
Results of PBT and vPvB : Remarks: The product does not contain a substance fulfilling
assessment the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB
(very persistent/very bioaccumulative) criteria.

Ozone-Depletion Potential : Remarks: The product does not contain substances that are
listed in Regulation (EC) 1005/2009 on substances that de-
plete the ozone layer.

Additional ecological infor- : Do not discharge product into the environment without control.
mation The product has not been tested. The statements on ecotoxi-
cology have been derived from the properties of the individual
components.

13. DISPOSAL CONSIDERATIONS

Disposal methods
Waste from residues : Observe national and local legal requirements.
Residues should be disposed of in the same manner as the
substance/product.
Contaminated packaging : Contaminated packaging should be emptied as far as possi-
ble; then it can be passed on for recycling after being thor-
oughly cleaned.

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MasterBrace 1441 PART B

Version Revision Date: SDS Number: Date of last issue: -

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14. TRANSPORT INFORMATION

International Regulations

UNRTDG
UN number : UN 2735
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
(TRIETHYLENETETRAMINE, 3,6,9-
TRIAZAUNDECAMETHYLENEDIAMINE)
Class : 8
Packing group : II
Labels : 8
IATA-DGR
UN/ID No. : UN 2735
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
(TRIETHYLENETETRAMINE, 3,6,9-
TRIAZAUNDECAMETHYLENEDIAMINE)
Class : 8
Packing group : II
Labels : Corrosive
Packing instruction (cargo : 855
aircraft)
Packing instruction (passen- : 851
ger aircraft)
IMDG-Code
UN number : UN 2735
Proper shipping name : AMINES, LIQUID, CORROSIVE, N.O.S.
(TRIETHYLENETETRAMINE, 3,6,9-
TRIAZAUNDECAMETHYLENEDIAMINE)
Class : 8
Packing group : II
Labels : 8
EmS Code : F-A, S-B
Marine pollutant : no
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Special precautions for user
The transport classification(s) provided herein are for informational purposes only, and solely
based upon the properties of the unpackaged material as it is described within this Safety Data
Sheet. Transportation classifications may vary by mode of transportation, package sizes, and var-
iations in regional or country regulations.

15. REGULATORY INFORMATION

Safety, health and environmental regulations/legislation specific for the substance or mix-
ture
If other regulatory information applies that is not already provided elsewhere in this safety data
sheet, then it is described in this subsection.

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MasterBrace 1441 PART B

Version Revision Date: SDS Number: Date of last issue: -

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16. OTHER INFORMATION

Full text of other abbreviations

AIIC - Australian Inventory of Industrial Chemicals; ANTT - National Agency for Transport by
Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body weight; CMR -
Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for
Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration associated with
x% response; ELx - Loading rate associated with x% response; EmS - Emergency Schedule;
ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys-
tem; GLP - Good Laboratory Practice; IARC - International Agency for Research on Cancer; IATA
- International Air Transport Association; IBC - International Code for the Construction and
Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory con-
centration; ICAO - International Civil Aviation Organization; IECSC - Inventory of Existing Chemi-
cal Substances in China; IMDG - International Maritime Dangerous Goods; IMO - International
Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO - International Or-
ganisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Con-
centration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population (Median
Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicology Program; NZIoC - New
Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operation and Develop-
ment; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumu-
lative and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substanc-
es; (Q)SAR - (Quantitative) Structure Activity Relationship; REACH - Regulation (EC) No
1907/2006 of the European Parliament and of the Council concerning the Registration, Evalua-
tion, Authorisation and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tem-
perature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG - Trans-
portation of Dangerous Goods; TSCA - Toxic Substances Control Act (United States); UN - Unit-
ed Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods;
vPvB - Very Persistent and Very Bioaccumulative; WHMIS - Workplace Hazardous Materials In-
formation System

The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.

UN / EN

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