Flushing Chemical Treatment Method Statement - MISK City

MISK
City ‐ Site Wide Infrastructure ‐ Phase1
Flushing & Chemical Treatment Method Statement:

Project: District Cooling and Gas Network Package –
Mohammed bin Salman Non‐Profit City ‐
Sitewide Infrastructure ‐ Phase1

Contractor: Future Horizons

Service Provider: FLUCON

FLUCON Document No.: MISK‐FL‐MOS‐0523‐01
Rev #: 00

MISK City ‐ Site Wide Infrastructure ‐ Phase1

Flushing & Chemical Treatment
Method Statement


Table of Contents
1. INTRODUCTION .......................................................................................................................................... 4
2. PRELIMINARIES: ........................................................................................................................................ 4
3. PUMPS SELECTION .................................................................................................................................... 6
4. SEQUENCE OF OPERATION ........................................................................................................................ 6
5. FLUSHING LOOPS .................................................................................................................................... 10
6. CARTRIDGE FILTERS DATASHEET .......................................................................................................... 12
7. NALCO FINAL CHEMICALS DATASHEETS ............................................................................................. 15
8. FILTER DRAWING ................................................................................................................................... 34
9. RISK ASSESSMENT ..................................................................................................................................38
Flushing & Chemical Treatment Method Statement
1. INTRODUCTION
This submittal represents the preparation and operational procedures for flushing & chemical treatment
of the carbon steel pipeline MISK City ‐ Site Wide Infrastructure ‐ Phase1 Project.
Preparation works, Circulation & filtration will be implemented by FLUCON.
Chemical treatment & testing samples will be supervised by third party chemical specialist; NALCO.

The scope of flushing & chemical treatment includes the following:
1) Chilled water pipeline network (Supply & Return).
2) Flushing process will be performed using High Performance Filtration skid with pumping skid
connected to the DCP tapping point.
3) Filtration process is considering Full Stream filtration system including:
 Four Stainless Steel Filtration skids , each skid with (21) housing.
 Suction & Discharge Headers connecting the (4) filtration skids
 Pipe supports for Headers.
 Valves & Fittings.
 Bag & Cartridge filters 50microns, 10 microns, 1 micron.

4) Total water volume equals to 2400m3.
5) Water will be circulated by 5 Rental pumps HL‐250.
6) Flushing process will be performed in two main loops (Section‐1 & Section‐2) as shown in section no.5.

2. PRELIMINARIES:
‐ FLUCON is following the full stream filtration procedure, which means all the water in the network
pipeline will be filtered without feed & bleed strategy.
‐ FLUCON considered that cleaning chemical stage has been finished & the chemical water drained
completely & the network refilled with fresh water; Knowing that FLUCON did the site survey &
took sample from network water and the results was as the following:
‐ TDS: around 456
‐ PH:8.8

That means network water clear from the cleaning chemical NALCO 3DT401.

‐ As per project specifications water velocity should be 3 m/s to make sure all dirts & particles
moved & trapped in filtration skid. However; water velocity will be increased from 1m/s to 3m/s
gradually in each section of the network and this is to enable filtration skid to trap the very fine
particles.
Knowing that most of the dense debris to be found in the typical system will be below 5mm in
diameter According to BSRIA Standards (BG29‐2021 Pre‐commissioning Cleaning of Pipework
Systems ‐ Amended 6th edition) page no. 49.

3. PUMPS SELECTION
‐ Biggest main pipe size: 750mm
‐ Flushing velocity: 3m/s
‐ Flushing flowrate:
Q = A X V
= (0.441562 X 3,600) X 3
= 4,768.87 m3/hr

Accordingly, we select HL‐250 knowing that the roughly estimated head loss in the network, pumping
skid & filtration skid will be around 60 meters.

4. SEQUENCE OF OPERATION

As mentioned before, flushing process will be on 2 stages consists of: Filtration Stage & Final
Treatment Stage.
These stages will be applied as per the following:

i. Filtration Stage:
The purpose is to remove pre‐existing debris and any suspend solids or foreign objects from the
main network pipe line. This step includes:
- Practically water velocity used for the filtration process will be 1m/s to 2m/s in the most work
duration. However; velocity will reach 3m/s at the end of filtration for each section to make sure
it’s clear of all dirt, Debris & suspended solids before going to the other section.
- Before running the pump, the following should be checked:
a. Flushing skid connections, to ensure no leakage.
b. Automatic air vents are open.
c. Drain points are closed.
- Filters will be cleaned when necessary, till water comes clear.

At the end of this stage, the following parameters should be checked and water quality parameters
should be as per the following before moving to next step:

Parameters Control Limits
PH 7 ‐ 8.5
Conductivity 100 ‐ 700
Total iron < 5 ppm as Fe
TSS < 20 ppm

ii. Addition of Final Treatment Chemical Stage:
The purpose is to add the final treatment chemicals to the system to ensure that the system is
treated with inhibiting chemicals to prevent future corrosion and scale problems, as per the
following:
- After the final flushing step is completed and the iron level is lower than 5 ppm is achieved and
test verified by chemical specialist and the consultant representative, all flushing activities will
be stopped and start injection of final treatment chemicals.
- Add Final chemicals depends on the chemical supplier’s procedure as follows;
 Add NALCO TRAC109 by 3.5Kg/M3 and circulate for period enough to circulate the water
volume 3 to 4 times in the network, then add NALCO 77352 with a dose rate 0.1Kg/M3 and
circulate for 4 Hrs.

Following control parameters should be achieved and confirmed by testing the final sample:

Chilled water test and control parameters (according to chemicals specialist):

Parameters Control Limits
pH 8.5‐11.5
Conductivity < 4000 µSiemens/cm
TSS < 20 ppm
Total Iron, ppm as Fe 1 ppm Maximum
Nitrite as NaNO2 800‐1600 ppm as NaNO2
Total Bacteria Account <10 CFU/100ml

Test samples will be collected in attendance of main contractor/consultant.

If the test samples passed the control parameters, then flushing and chemical treatment process is
considered accomplished, and will start dismantling the filtration skids.

Note: flushing and chemical treatment stages will be processed with attendance of chemical
specialist.
5. FLUSHING LOOPS
DISTRICT COOLING NETWORK
7
MISK CITY 4
10
1 8
5 11
9
2
6
KEY PLAN
IVC24- Check Point N 2732678.068
E 658929.702
V=4.8288 m/s R
Q=1981.2 m3/h R 0+
20
0
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V=5.032 m/s S LI
N E
0
40
Q=2023.2 m3/h S DC Ø
Drain Point 400mm NOTES:
.1 ALL DIMENSIONS ARE IN METERS UNLESS OTHERWISE NOTED.
5 DP6
0
0+10
4
-2
C
IV
N 2732556.398
-4 E 658858.960
NE
LI
0
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DC
Ø
0+
N 2732495.345
LEGENDS:
00
00
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23
Ø
C-
40
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IV
0
LIN
PROJECT BOUNDARY
0
50
DC
Ø
AV PHASE 1 BOUNDARY
0
N 2732447.657 25
Ø DISTRICT COOLING SYSTEM - SUPPLY LINE
E 658745.463
Ø
20
0
N 2732448.598
DC
DISTRICT COOLING SYSTEM - RETURN LINE
Ø
LI
35
E 658836.538
NE
0
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0+
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PLANT CHAMBER
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Drain Point 250mm
DC
E 658712.049 DC BUILDING PLOT CHAMBER

AV
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DC E 658742.380 NE AV
Ø
-1 AUTOMATIC AIR VALVE CHAMBER

25
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0+200 Drain Point 400mm

Ø500
DP5
IVC20- Check Point
0+200
V=3.639 m/s R DP1

IVC22- Check Point
Q=4771.3 m3/h R
V=4.1675 m/s R
V=3.7300 m/s S
Ø3
5
Q=3976.8 m3/h R
0
50
Ø3
DC LINE -1
N 2732257.294
Q=4890.1 m3/h S
N 2732252.519
Drain Point 350mm

E 659818.406
0+600
E 659666.327
Ø500
N 2732249.896 00
0+1
V=4.1795 m/s S E 659980.654
Ø70
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.48
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0+000
IVC
0+500
IVC-11
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IVC-13
Ø20
DC LINE -2 NE 0+
DC LINE -14
DC LINE -13
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C LI
Ø700 .67
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COORDINATED BY
Q=3988.2 m3/h S 60
0
E D
DC LIN
0+000 Ø350 22 .946
73 5
Ø800
0+763.396 N 2 6014
Ø200
0+400 Ø700 E 6
ENGR. BINYAH SAUD CONSULT
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CIVIL
DC L
4 IVC10- Check Point N 2732220.368 IVC-14
0
INE -7 E 659763.030
DC L IVC-22 N 2732219.054
INE -1
Ø40
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0+3
0
DP4 N 2732205.222
Ø350
V=3.6129 m/s R
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E 658688.418
8 ELECTRICAL
IVC-1
Q=4736.5 m3/h R N 2732189.260
-1
E 659601.285
E
ARCHITECTURAL
C LIN
V=3.5523 m/s S
0
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IN DISCIPLINE
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Q=4657.2 m3/h S 1 Ø7
00
CIVIL STRUCTURAL MECHANICAL
SURVEY ARCHITECTURAL
0+4
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00
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0+0
Ø300
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5 APPROVED CODES LEGEND
00
IVC-2
DC
IVC21- Check Point N 2732102.810
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N 2732121.517 E 659350.140
LIN00
0
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Ø3
E 658717.328 N 2732091.069 0+ A APPROVED B APPROVED WITH COMMENTS C REVISED AND RESUBMIT
00
E-
E 658766.663
V=3.0250 m/s R 0
Ø7
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Q=3968.9 m3/h R 2 D REJECTED E REVIEW NOT REQUIRED

IV
0+
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IFC DRAWINGS REF.
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Ø7
46
21
E 659396.287
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IFC# MC-PH01-SIW-00005-SAC-MOD-INF-900024-05-DISTRICT COOLING SYSTEM
V=3.3727 m/s S
DC
6 N 2732050.246
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IV
IV
REV
N
Ø3
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Q=4425.1 m3/h S
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N 2732036.101 0
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LIN
TYPE OF DRAWINGS.
2
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DC
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SHOP-DRAWING FOR CONSTRUCTION MOBILIZATION

Ø7
DC 5 0
LIN
00
PROJECT TITLE:
E
Ø3
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Ø7
E- MISK CITY PHASE-01
LIN
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DC
00 00
SITE WIDE INFRASTRUCTURE
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CLIENT :
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DC L E 659180.553
50
DC
MiSK City at MiSK Foundation

Ø7
N 2731925.498
E 658900.882 N 2731930.127 Diplomatic Quarters
E 659128.817
Riyadh/Safarat, Saudi Arabia,KSA
PUMP
N 2731888.947
#1 PMO:
E 658631.487 Jones Lang LaSalle
DC LINE -3
17th Floor, South Tower, Abraj Attawuniya

0+
-9
30
0
King Fahd Road

E
LIN
Ø750
Riyadh, Kingdom of Saudi Arabia

00
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TEL: +966 (0)11 2180303

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Web: www.jll-mena.com
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PMCM:
DC
N 2731842.916
n
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E 658804.121
oi Prince Turki Ibn Abdulaziz Al Awwal Rd,
PUMP Dr ain P Al Nakheel District ، Al Raidah Digital City,

Building WH14, 2nd Floor ، Riyadh
-3 TEL: +966 (0) 126044700
LINE
Design & Consultancy
#6 n for natural and
DC Ø750 o
cti
Web: www.arcadis.com built assets
0+
0
0+80
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40
nn
0
SAUDI CONSULTING SERVICES CO.
Co ENGINEERING CONSULTANT
ol
AV
ENGINEER DR. TAREK M. A. SHAWAF

-3
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0
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DP2
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LI
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P.O.Box 2341, Riyadh 11451

E
N 2731766.418
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S c Tel: 4659975 Fax: 4647540

E-mail [email protected]
DC
N 2731726.412
p to www.saudconsult.com
DP3 E 658810.161
CONTRACTOR :
PU
50
Ø7
00
SAUDI REAL ESTATE INFRASTRUCTURE CO. (BINYAH)
0
DC
0+6
P-1
Ø90
P.O. BOX 2567, RIYADH12244

DC
FR
OM PUMP KINGDOM OF SAUDI ARABIA
0+500
E -3 m TEL: 4190728
F ro
LIN #2 Web: www.binyah.com.sa
DC 50
Ø7
AV PUMP SUB CONTRACTOR :
Drain Point 300mm N 2731689.917
E 658750.237 #3 General Contractor, Design
and Engineering Company
FUTURE HORIZONS P.O. Box 102 Bisha,
PUMP
#1
Kingdom of Saudi Arabia
Tel. No. (+966) 17 622-8000
N
Fax No. (+966) 17 622-9000
#4
PUMP
C TIO DRAWING TITLE :
From
#5 SE DISTRICT COOLING SYSTEM NETWORK
DCP #2 OVERALL LAYOUT PHASE-1
U p to N
Gate IO
No. 2 ECT BNY-DWG.NO : REV
S SCALE
DRAWN
DATE
CHECKED
PREPARED APPROVED
6. CARTRIDGE FILTERS DATASHEET

ProClean Normal Filter Bag
Products Features:
• Higher dirt-holding capacity and longer lifetime because of the special material.
• Special handle easy installation and removal, option for Eaton type ring & FSI type ring.
• Polypropylene materials are FDA listed as acceptable for potable and edible liquid
contact according to CFR Title 21
• The Thermal welded type filter bags feature 100% welded fabrication. This
construction eliminates the bypass which can occur in standard sewn filter bags.
BROTHER proprietary Thermal welding technology produces a super-strong seam that will
stand up to even the most demanding applications without failure.
• All filter bags are manufactured with a proprietary downstream surface treatment to
prevent fiber migration. A special finish is obtained by glazing the surface, melting fibers
together to form a tight, secure downstream matrix. In addition, the weld seams are heat
bonded to eliminate loose fibers which might result during fabrication
Applications: Technical Data:

Prefiltration for RO Desalination Materials Size Operation conditions
Oil & Gas Filter Media Polypropylene/Polyester/Nylon 1# 7”(178mm) dia*17”L Max. Temperature ~80 ℃
Painting Ring type Polypropylene/SUS304 2# 7”(178mm) dia * 32”L Recommended DP for 1.2-1.6bar
3# 4”(102mm) dia * 8”L change-out
Petrochemicals
4# 4”(102mm) dia * 14”L
Food & Beverage
5# 4”(102mm) dia * 20”L
Semiconductor
Municipal Water
Flowrate & Filtration Area:

Size Max. Flow Rate Recommended Flow Rate Filtration area
1# 20m³/hr 13m³/hr 0.25m²
2# 40m³/hr 26m³/hr 0.5m²
3# 6m³/hr 4m³/hr 0.09m²
4# 12m³/hr 8m³/hr 0.16m²
5# 18m³/hr 12m³/hr 0.2m²
Ordering Information:
BCFB -01 -PP -0100 -PE -S
Product Size Media Material Micron Rating Ring Material Technique
0100=1um 4000=40um
01=Size 1
ProClean PP=Polypropylene 0500=5um 7000=70um PE=Plastic E Type Ring
02=Size 2 S=Seam
Normal PE=Polyester 1000=10um 10000=100um PF=Plastic F Type Ring
03=Size 3 W=Welding
Filter Bag NY=Nylon Mesh 1500=15um 20000=200um S=Stainless Steel
04=Size 4
2000=20um 25000=250um
10 inch =25.4 cm
Polykleen Bag Pleated High Flow Filter Cartridge
Products Features:
• High dirt-holding capacity pleated construction makes high efficiency
• Greater surface area compared with traditional bag filter
• Wide range chemical compatibility
• Fitting into all standard filter bag baskets and housings
• Nominally rated with retention ratings between 1-100µm at 90-95% efficiencies
• Absolute rated with retention ratings between 1-20µm at 98-99% efficiencies
• Silicone free construction
• Two layers of polypropylene or polyester media along with thermally bonded end caps help
prevent particulate bypass and offers 5-10 times the surface area of standard bag filters
• Polypropylene materials in compliance with FDA regulations for food contact under CFR21
• Type A can be fit in CSC/CST Classic Single Bag Housing and Classic Multi Bag Filter
Housing; Type B can fit in Falt Single Cartridge Stainless housing
Type A Type B
Applications: Technical Data:
Prefiltration for RO Desalination Materials Operation conditions
Oil & Gas Filter Media Polypropylene/Glass Fiber Max. Temperature ~80 ℃
Power Generation Condensate System Inner Core& Outer cage & End caps Polypropylene Recommended DP for 2.1-2.4bar
Petrochemicals Gasket EPDM/Silicone/Buna-N/Viton change-out
Food & Beverage Size
Pharmaceutical Length 320mm (equivalent bag filter size#1)
Automotive 660mm (equivalent bag filter size#2)
OD 6inch(152mm)
Waste water
Filtration area 1.51㎡@Size #1 PP,3.1㎡@Size#2 PP
1.69㎡@Size #1 GF,3.48㎡@Size#2 GF
Flow Rate:
Max. Flow Rate Recommended Flow Rate
Size 1# 25m³/hr 15m³/hr
Size 2# 40m³/hr 25m³/hr
Ordering Information: Polykleen Bag Pleated High Flow(GPM)
BHFPB -PP -1 -N -0100 -E -H -A

Model Media Material Length Filtration Efficiency Micron Rating O-ring Surface Treatment Handle
0100=1um
Polykleen Bag 0500=5um E=EPDM A-Top Single
N=Nominal 1000=10um housing &
Pleated High PP=Polypropylene 1=Size 1 1500=15um S=Silicon H=Hard Cage
Multi housing
A=Absolute(1-
Flow Filter GF=Glass Fiber 2=Size 2 2000=20um V=Viton N=Netting B-Flat Single
20um) 4000=40um Housing
Cartridge 7000=70um B=Buna-N
10000=100um
10 inch =25.4 cm
7. NALCO FINAL CHEMICALS DATASHEETS
SAFETY DATA SHEET
NALCO® TRAC109
Section: 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : NALCO® TRAC109
Other means of identification : Not applicable
Restrictions on use : Refer to available product literature or ask your local Sales Representative for
restrictions on use and dose limits.
Company : Nalco Gulf Ltd.

P.O. Box 17063, FD3, R/A8
Jebel Ali Free Zone, DubaiTEL: +971-4-814-6800
Nalco Saudi Company Limited

First Industrial City, Dammam – 11th Street, P.O. Box 7372
Dammam 31462
Saudi Arabia
TEL: 00966 13 824 9100
Emergency telephone : +32-(0)3-575-5555

number
Issuing date : 01/17/2018
COMPANY CONTACT TELEPHONE NUMBERS.
USA Nalco Company (630)305-1000

Nalco European Operations NALCO EUROPE B.V. 0031 71 5241100
UAE Nalco Gulf Ltd. Tel. +97148836049
Fax. +97148836050
Jordan Nalco Gulf Ltd. Tel. +96265377150
Fax. +96265377160
Saudi Arabia Nalco Saudi Co. Ltd. Tel. +966-3-847-1517
Fax. +966-3-847-2978
Egypt Nalco Egypt Ltd Tel. +20222910740
Fax. +20222910350
Section: 2. HAZARDS IDENTIFICATION
GHS Classification
Oxidizing liquids : Category 3
Acute toxicity (Oral) : Category 4
Skin corrosion : Category 1B
Serious eye damage : Category 1
Specific target organ toxicity : Category 1 (Blood)
- single exposure (Oral)
GHS Label element

Hazard pictograms :
Signal Word : Danger
Hazard Statements : May intensify fire; oxidiser.
1/8
SAFETY DATA SHEET
NALCO® TRAC109
Harmful if swallowed.
Causes severe skin burns and eye damage.
Causes damage to organs (Blood) if swallowed.
Precautionary Statements : Prevention:

Keep away from heat. Keep/Store away from clothing and other combustible
materials. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective
gloves/ protective clothing/ eye protection/ face protection.
Response:
IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel
unwell. Rinse mouth.IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water/shower.IF INHALED: Remove
person to fresh air and keep comfortable for breathing. Immediately call a
POISON CENTER/doctor.IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/ physician.
IF exposed: Call a POISON CENTER or doctor/ physician.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.
Other hazards : None known.
Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS
Pure substance/mixture : Mixture
Chemical Name CAS-No. Concentration: (%)

Sodium Nitrite 7632-00-0 30 - 60
Sodium Hydroxide 1310-73-2 1-5
Sodium Tetraborate 1330-43-4 0.1 - 1
Section: 4. FIRST AID MEASURES
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Get medical attention immediately.
In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild
soap if available. Wash clothing before reuse. Thoroughly clean shoes before
reuse. Get medical attention immediately.
If swallowed : Rinse mouth with water. Do NOT induce vomiting. Never give anything by
mouth to an unconscious person. Get medical attention immediately.
If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms
occur.
Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put
yourself at risk of injury. If in doubt, contact emergency responders. Use
personal protective equipment as required.
Notes to physician : Treat symptomatically.
Most important symptoms : See Section 11 for more detailed information on health effects and symptoms.
and effects, both acute and
delayed
Section: 5. FIREFIGHTING MEASURES
2/8
SAFETY DATA SHEET
NALCO® TRAC109
Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
Specific hazards during : Oxidizer. Contact with other material may cause fire.
firefighting
Hazardous combustion : Decomposition products may include the following materials: Carbon oxides
products nitrogen oxides (NOx) Sulphur oxides Oxides of phosphorus
Special protective equipment : Use personal protective equipment.

for firefighters
Specific extinguishing : Fire residues and contaminated fire extinguishing water must be disposed of in
methods accordance with local regulations. In the event of fire and/or explosion do not
breathe fumes.
Section: 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, : Ensure adequate ventilation. Keep people away from and upwind of spill/leak.
protective equipment and Avoid inhalation, ingestion and contact with skin and eyes. When workers are
emergency procedures facing concentrations above the exposure limit they must use appropriate
certified respirators. Ensure clean-up is conducted by trained personnel only.
Refer to protective measures listed in sections 7 and 8.
Environmental precautions : Do not allow contact with soil, surface or ground water.
Methods and materials for : Stop leak if safe to do so. Contain spillage, and then collect with non-
containment and cleaning up combustible absorbent material, (e.g. sand, earth, diatomaceous earth,
vermiculite) and place in container for disposal according to local / national
regulations (see section 13). For large spills, dike spilled material or otherwise
contain material to ensure runoff does not reach a waterway. Flush away traces
with water.
Section: 7. HANDLING AND STORAGE
Advice on safe handling : Do not ingest. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in
eyes, on skin, or on clothing. Wash hands thoroughly after handling. Use only
with adequate ventilation.
Conditions for safe storage : Keep in a cool, well-ventilated place. Do not store near acids. Keep away from
reducing agents. Keep away from combustible material. Keep out of reach of
children. Keep container tightly closed. Store in suitable labelled containers.
Suitable material : The following compatibility data is suggested based on similar product data
and/or industry experience: Compatibility with Plastic Materials can vary; we
therefore recommend that compatibility is tested prior to use.
Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Form of exposure Permissible Basis

concentration
Sodium Hydroxide 1310-73-2 Ceiling 2 mg/m3 ACGIH
Ceiling 2 mg/m3 NIOSH REL
TWA 2 mg/m3 OSHA Z1
Sodium Tetraborate 1330-43-4 TWA 1 mg/m3 NIOSH REL
3/8
SAFETY DATA SHEET
NALCO® TRAC109
TWA (Inhalable 2 mg/m3 (Borate) ACGIH

fraction)
STEL (Inhalable 6 mg/m3 (Borate) ACGIH
fraction)
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below
occupational exposure standards.
Personal protective equipment
Eye protection : Safety goggles

Face-shield
Hand protection : Wear the following personal protective equipment:

Standard glove type.
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.
Skin protection : Personal protective equipment comprising: suitable protective gloves, safety
goggles and protective clothing
Respiratory protection : When workers are facing concentrations above the exposure limit they must use
appropriate certified respirators.
Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove
and wash contaminated clothing before re-use. Wash face, hands and any
exposed skin thoroughly after handling. Provide suitable facilities for quick
drenching or flushing of the eyes and body in case of contact or splash hazard.
Section: 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Liquid
Colour : clear
Odour : odourless
Flash point : does not flash
pH : 12.1 - 14.0, (25 °C)
Odour Threshold : no data available
Melting point/freezing point : no data available
Initial boiling point and boiling : no data available
range
Evaporation rate : no data available
Flammability (solid, gas) : no data available
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapour pressure : no data available
Relative vapour density : no data available
Relative density : 1.34, (25.0 °C),
Density : 1.33 g/cm3 , 11.1 lb/gal
Water solubility : completely soluble
Solubility in other solvents : no data available
4/8
SAFETY DATA SHEET
NALCO® TRAC109
Partition coefficient: n- : no data available

octanol/water
Auto-ignition temperature : no data available
Thermal decomposition : no data available
Viscosity, dynamic : no data available
Viscosity, kinematic : no data available
Molecular weight : no data available
VOC : no data available
Section: 10. STABILITY AND REACTIVITY
Chemical stability : Stable under normal conditions.
Possibility of hazardous : No dangerous reaction known under conditions of normal use.

reactions
Incompatible materials : Amines

Strong acids
Reducing agents
Hazardous decomposition : Decomposition products may include the following materials:

products Carbon oxides
nitrogen oxides (NOx)
Sulphur oxides
Oxides of phosphorus
Section: 11. TOXICOLOGICAL INFORMATION
Information on likely routes of : Inhalation, Eye contact, Skin contact

exposure
Potential Health Effects
Eyes : Causes serious eye damage.
Skin : Causes severe skin burns.
Ingestion : Harmful if swallowed. Causes digestive tract burns.
Inhalation : May cause nose, throat, and lung irritation.
Chronic Exposure : May cause damage to organs.
Experience with human exposure
Eye contact : Redness, Pain, Corrosion
Skin contact : Redness, Pain, Corrosion
Ingestion : Corrosion, Abdominal pain
Inhalation : Respiratory irritation, Cough
Toxicity
Product
5/8
SAFETY DATA SHEET
NALCO® TRAC109
Acute oral toxicity : Acute toxicity estimate: 475.13 mg/kg

Acute inhalation toxicity : no data available
Acute dermal toxicity : no data available
Skin corrosion/irritation : no data available
Serious eye damage/eye : no data available
irritation
Respiratory or skin : no data available
sensitization
Carcinogenicity : no data available
Reproductive effects : no data available
Germ cell mutagenicity : no data available
Teratogenicity : no data available
STOT - single exposure : Based on available data, the classification criteria are not met.
STOT - repeated exposure : no data available
Aspiration toxicity : no data available
Section: 12. ECOLOGICAL INFORMATION
Ecotoxicity
Environmental Effects : Very toxic to aquatic life.
Product
Toxicity to fish : LC50 Oncorhynchus mykiss (rainbow trout): 100.83 mg/l
Exposure time: 96 hrs
Test substance: Product
Test Type: Static
NOEC Oncorhynchus mykiss (rainbow trout): 25 mg/l

Test Type: Static
Toxicity to daphnia and other : EC50 Daphnia magna (Water flea): 215.8 mg/l
aquatic invertebrates Exposure time: 48 hrs
Test Type: Static
NOEC Daphnia magna (Water flea): 80 mg/l

Test Type: Static
Persistence and degradability
Greater than 95% of this product consists of inorganic substances for which a biodegradation value is not
applicable.
Mobility
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total
6/8
SAFETY DATA SHEET
NALCO® TRAC109
input and output. The level III model does not require equilibrium between the defined media. The information
provided is intended to give the user a general estimate of the environmental fate of this product under the
defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;
Air : <5%
Water : 30 - 50%
Soil : 50 - 70%
The portion in water is expected to be soluble or dispersible.
Bioaccumulative potential
This preparation or material is not expected to bioaccumulate.
Other information
no data available
Section: 13. DISPOSAL CONSIDERATIONS
Disposal methods : The product should not be allowed to enter drains, water
courses or the soil. Where possible recycling is preferred to
disposal or incineration. If recycling is not practicable, dispose
of in compliance with local regulations. Dispose of wastes in
an approved waste disposal facility.
Disposal considerations : Dispose of as unused product. Empty containers should be

taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.
Section: 14. TRANSPORT INFORMATION
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in
compliance with the selected mode of transport.
Land transport (ADR)

UN number: UN 3266
UN proper shipping name: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (Sodium Nitrite,
Sodium Hydroxide)
Transport hazard class(es): 8
Packing group: III
Environmental hazards: Yes
Air transport (IATA)

UN number: UN 3266
Sodium Hydroxide)
Packing group: III
Environmental hazards: Yes
Sea transport (IMDG/IMO)

UN number: UN 3266
Sodium Hydroxide)
Packing group: III
7/8
SAFETY DATA SHEET
NALCO® TRAC109
Environmental hazards: Yes (Marine Pollutant)

*Marine pollutant: SODIUM NITRITE
Section: 15. REGULATORY INFORMATION
NATIONAL REGULATIONS
National regulations in the country where this substance is used, should be followed.
Section: 16. OTHER INFORMATION
NFPA: HMIS III:

Flammability
HEALTH 3*
0
Instability
Health
3 1 FLAMMABILITY 0
OX PHYSICAL HAZARD 1
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
Special hazard. 4 = Extreme, * = Chronic
Due to our commitment to Product Stewardship, we have evaluated the human and environmental hazards and
exposures of this product. Based on our recommended use of this product, we have characterized the product's
general risk. This information should provide assistance for your own risk management practices. We have
evaluated our product's risk as follows:
* The human risk is: Low
* The environmental risk is: Low
Any use inconsistent with our recommendations may affect the risk characterization. Our sales representative
will assist you to determine if your product application is consistent with our recommendations. Together we can
implement an appropriate risk management process.
Trans-European +32-(0)3-575-5555
Saudi Arabia +966-(3)847-1515
UAE +44-(0)7071-223-738
Revision Date : 01/17/2018

Version Number : 1.2
Prepared By : Regulatory Affairs
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated
by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and
belief at the date of its publication. The information given is designed only as a guidance for safe handling,
use, processing, storage, transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material designated and may not be valid for
such material used in combination with any other materials or in any process, unless specified in the text.
8/8
SAFETY DATA SHEET
PRODUCT
NALCO® 77352
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME : NALCO® 77352
APPLICATION : BIOCIDE
COMPANY IDENTIFICATION :
INDIA : NALCO WATER INDIA LIMITED TEL: +91 2039394000 FAX: +91 2039394380
MALAYSIA : NALCO INDUSTRIAL SERVICES MALAYSIA SDN BHD TEL: 603-5569 4118 FAX: 603-5569 5955
PHILIPPINES : NALCO PHILIPPINES INC. TEL: 63-49-5451550 FAX: 63-49-5453442
SINGAPORE : NALCO PACIFIC PTE LTD TEL: 65- 6505-6868 FAX: 65-6862 0850
THAILAND : NALCO INDUSTRIAL SERVICES (THAILAND) CO LTD TEL: 66-38-955-160 FAX: 66-38-955-166
Date issued : 14.03.2013

Version Number : 1.4
See Section 16 for address information.
EMERGENCY TELEPHONE NUMBER(S) : For local telephone numbers, refer to Section 16.
International Emergency Number: + 65 6542 9595
2. COMPOSITION/INFORMATION ON INGREDIENTS
Our hazard evaluation has identified the following chemical substance(s) as hazardous. Consult Section 15 for
the nature of the hazard(s).
CHEMICAL NAME CAS NO % (w/w)

5-Chloro-2-Methyl-4-Isothiazolin-3-one 26172-55-4 1- 5
2-Methyl-4-Isothiazolin-3-one 2682-20-4 0.1 - 1
The balance of the substances in this product are not classified as hazardous or
are present below hazard cut-off limits
3. HAZARDS IDENTIFICATION
HUMAN HEALTH HAZARDS - ACUTE
EYE CONTACT
Corrosive. Will cause eye burns and permanent tissue damage.
SKIN CONTACT
Corrosive; causes permanent skin damage. Causes skin burns. May cause severe irritation or tissue damage
depending on the length of exposure and the type of first aid administered. May cause sensitization by skin
contact.
INGESTION
Corrosive, causes burns to gastro-intestinal tract. Nausea, vomiting and stomach pain may occur. In severe
cases blood may be vomited.
INHALATION
1 / 10
SAFETY DATA SHEET
PRODUCT
NALCO® 77352
May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid
administered. Aerosols or product mist may irritate the upper respiratory tract.
HUMAN HEALTH HAZARDS - CHRONIC :

No adverse effects expected other than those mentioned above.
ENVIRONMENTAL HAZARDS :
Spilled product may pose a risk to the aquatic ecosystem if released.
4. FIRST AID MEASURES
EYE CONTACT :
PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15
minutes while holding eyelids open. If only one eye is affected be sure to use care not to contaminate the other
eye with the run-off. Get immediate medical attention.
SKIN CONTACT :
PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush with plenty of water for at least
15 minutes. For a large splash, flood body under a shower. Remove contaminated clothing. Wash off affected
area immediately with plenty of water. Get immediate medical attention. Contaminated clothing, shoes, and
leather goods must be discarded or cleaned before re-use.
INGESTION :
DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink. If reflexive vomiting
occurs, rinse mouth and repeat administration of water. Get immediate medical attention.
INHALATION :
Remove to fresh air, treat symptomatically. Get immediate medical attention.
NOTE TO PHYSICIAN :
Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of
the patient, the physician's judgement should be used to control symptoms and clinical condition.
5. FIRE FIGHTING MEASURES
FLASH POINT : Not flammable
EXTINGUISHING MEDIA :
Not expected to burn. Use extinguishing media appropriate for surrounding fire. Water mist may be used to cool
closed containers.
FIRE AND EXPLOSION HAZARD :

May evolve oxides of nitrogen (NOx) and sulfur (SOx) under fire conditions. May evolve HCl under fire
conditions.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING :

In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit.
SENSITIVITY TO STATIC DISCHARGE :

Not expected to be sensitive to static discharge.
2 / 10
SAFETY DATA SHEET
PRODUCT
NALCO® 77352
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS :
Restrict access to area as appropriate until clean-up operations are complete. Use personal protective
equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is
safe to do so. Ventilate spill area if possible. Ensure clean-up is conducted by trained personnel only. Do not
touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify
appropriate government, occupational health and safety and environmental authorities.
METHODS FOR CLEANING UP :

SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled
container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches
or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated
surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of
contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13
(Disposal Considerations). DEACTIVATION SOLUTION - Estimate volume of remaining spilled material on the
floor and prepare 10 times as much deactivation solution as follows. Prepare fresh by mixing 5% sodium
hypochlorite (household bleach) and 5% sodium bicarbonate or potassium bicarbonate away from the immediate
area of the spill. The solution can be prepared by adding household bleach to the 3-quart fill mark on the 1 gallon
plastic container containing 1/3 of a lb. (150 grams) of sodium bicarbonate. Put on the appropriate personal
protection equipment and close the container securely and shake well for 1 minute. The materials and
equipment for preparing solutions should be kept available for use in areas where spills may occur.
ENVIRONMENTAL PRECAUTIONS :
Prevent material from entering sewers or waterways., Harmful to aquatic organisms., May cause long-term
adverse effects in the aquatic environment., If drains, streams, soil or sewers become contaminated, notify local
authority.
7. HANDLING AND STORAGE
HANDLING :
Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe
vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills,
leaks, etc.) readily available. Ensure all containers are labeled.
STORAGE CONDITIONS :
Protect product from freezing. Store in suitable labeled containers. Store the containers tightly closed.
UNSUITABLE CONSTRUCTION MATERIAL :

Shipping and long term storage compatibility with construction materials can vary; we therefore recommend that
compatibility is tested prior to use.,
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
OCCUPATIONAL EXPOSURE LIMITS

This product does not contain any substance that has an established exposure limit.
ENGINEERING MEASURES :
3 / 10
SAFETY DATA SHEET
PRODUCT
NALCO® 77352
General ventilation is recommended.
PERSONAL PROTECTION
RESPIRATORY PROTECTION :
Respiratory protection is not normally needed.
HAND PROTECTION :
Rubber gloves PVC gloves Neoprene gloves Nitrile gloves Gloves should be replaced immediately if signs of
degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers.
SKIN PROTECTION :
Wear protective overalls, chemical splash goggles and impervious gloves. A full slicker suit is recommended if
gross exposure is possible.
EYE PROTECTION :
Wear a face shield with chemical splash goggles.
HYGIENE RECOMMENDATIONS :
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep
a safety shower available. Always wash thoroughly after handling chemicals. When handling this product never
eat, drink or smoke. If clothing is contaminated, remove clothing and thoroughly wash the affected area.
Dispose of contaminated clothing as hazardous waste.
ENVIRONMENTAL EXPOSURE CONTROL PRECAUTIONS :

Consider the provision of containment around storage vessels.
9. PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Liquid

APPEARANCE Clear Yellow
ODOR Pungent
pH (100 %) 3-5
VAPOR PRESSURE 0.01 kPa (20 °C)
VAPOR DENSITY No data available.
SPECIFIC GRAVITY 1.02 (20 °C)
DENSITY No data available.
SOLUBILITY IN WATER Complete
VISCOSITY 3 cps (25 °C)
VISCOSITY 3 mPa.s (25 °C)
FREEZING POINT -3 °C
BOILING POINT 100 °C
FLASH POINT Not flammable
LOWER EXPLOSION LIMIT No data available.
UPPER EXPLOSION LIMIT No data available.
AUTOIGNITION TEMPERATURE No data available.
Note: These physical properties are typical values for this product and are subject to change.
4 / 10
SAFETY DATA SHEET
PRODUCT
NALCO® 77352
10. STABILITY AND REACTIVITY
STABILITY :
Stable under normal conditions.
HAZARDOUS POLYMERIZATION :
Hazardous polymerization will not occur.
CONDITIONS TO AVOID :
Avoid extremes of temperature. Freezing temperatures.
MATERIALS TO AVOID :
Amines Organic materials and reducing agents Mercaptans Oxidizing agents
HAZARDOUS DECOMPOSITION PRODUCTS :

Under fire conditions: Oxides of nitrogen, Oxides of sulfur, HCl
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY DATA :

No toxicity studies have been conducted on this product.
SENSITIZATION :
May cause an allergic skin reaction.
CHRONIC TOXICITY DATA :

A 90-day dietary study in dogs of 840 ppm of isothiazolinone resulted in no mortalities or pathological findings. A
90-day dermal study in rabbits of 0.4 mg/kg/day of isothiazolinone resulted in irritation but no pathological
effects. A 30-month skin painting study with mice using 400 ppm isothiazolinone three times per week showed
no increased tumor frequency over control. A teratology study with rabbits and rats was negative using dosages
of 1.5 to 15 mg/kg isothiazolinone. Mutagenicity results have been equivocal.
CARCINOGENICITY :
None of the substances in this product are listed as carcinogens by the International Agency for Research on
Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial
Hygienists (ACGIH).
REPRODUCTIVE EFFECTS :
No reproductive toxic effects expected.
MUTAGENICITY :
Not expected to be a mutagen.
For additional information on the hazard of the preparation, please consult section 2 and 12.
HUMAN HAZARD CHARACTERIZATION :

Based on our hazard characterization, the potential human hazard is: High
5 / 10
SAFETY DATA SHEET
PRODUCT
NALCO® 77352
12. ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL EFFECTS :
The following results are for the active components.
Acute Fish Results :

Species Exposure Test Type Value Test Descriptor
Bluegill Sunfish 96 hrs LC50 0.28 mg/l Active Substance
Rainbow Trout 96 hrs LC50 0.19 mg/l Active Substance
Sheepshead Minnow 96 hrs LC50 0.3 mg/l Active Substance
ACUTE INVERTEBRATE RESULTS :

Daphnia magna 48 hrs LC50 0.16 mg/l Active Substance
Fiddler Crab 96 hrs LC50 59 mg/l Active Substance
AQUATIC PLANT RESULTS :

Marine Algae (Skeletonema EC50 0.003 mg/l Active Substance
costatum)
Green Algae EC50 0.018 mg/l Active Substance
(Pseudokirchneriella
subcapitata, previously
Selenastrum capricornutum)
MOBILITY AND BIOACCUMULATION POTENTIAL :

The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program
interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total
input and output. The level III model does not require equilibrium between the defined media. The information
provided is intended to give the user a general estimate of the environmental fate of this product under the
defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the
approximate respective percentages;
Air Water Soil/Sediment

<5% 30 - 50% 50 - 70%
The portion in water is expected to be soluble or dispersible.
This preparation or material is not expected to bioaccumulate.
PERSISTENCY AND DEGRADATION :
The organic portion of this preparation is expected to be readily biodegradable.
ENVIRONMENTAL HAZARD CHARACTERIZATION

Based on our hazard characterization, the potential environmental hazard is: Moderate
13. DISPOSAL CONSIDERATIONS
6 / 10
SAFETY DATA SHEET
PRODUCT
NALCO® 77352
Hazardous wastes must be transported by a licensed hazardous waste transporter and disposed of or treated in
a properly licensed hazardous waste treatment, storage, disposal or recycling facility. Consult local, state, and
federal regulations for specific requirements.
Triple rinse (or equivalent) all containers and offer for recycling or reconditioning, or puncture and dispose of in a
sanitary landfill, or by other procedures approved by state and local authorities.
NATIONAL REGULATIONS, INDIA

Dispose of unused product in accordance with the "Hazardous Wastes (Management and Handling) Rules 1989"
and local and State legislation, as applicable.
NATIONAL REGULATIONS, MALAYSIA

Dispose of in accordance with the Environmental Quality (Scheduled Wastes) Regulation 2005 and other
guidelines issued by DOE and/or local authorities.
NATIONAL REGULATIONS, PHILIPPINES

Dispose of in accordance with Presidential Decree No. 984-1976 ("The Pollution Control Law"); DENR
Department Administrative Order No.29-92 ("The Implementing Rules or Regulations of RA6969") and
Presidential Decree No.825.
NATIONAL REGULATIONS, SINGAPORE

Dispose of waste in accordance with the Environmental Health Act (Chapter 95, Rg 11), Environmental Public
Health (Toxic Industrial Waste) Regulations 1990 Ed.
NATIONAL REGULATIONS, THAILAND

Dispose of hazardous waste in accordance with the " The Notification of the Ministry of Industry B.E. 2548,
subject : Disposal of Wastes or Unusable Materials".
14. TRANSPORT INFORMATION
The information in this section is for reference only and should not take the place of a shipping paper (bill of
lading) specific to an order. Please note that the proper Shipping Name / Hazard Class may vary by packaging,
properties, and mode of transportation. Typical Proper Shipping Names for this product are as follows.
LAND TRANSPORT
Proper Shipping Name : CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Technical Name(s) : A mixture of: 5-chloro-2-methyl-2H-isothiazol-3-one and 2-
methyl-2H-isothiazol-3-one (3:1)
UN/ID No : UN 3265
Hazard Class - Primary : 8
Packing Group : II
HAZCHEM CODE : 2X
NATIONAL REGULATIONS, INDIA

Transport in accordance with the Central Motor Vehicles Rules 1989.
NATIONAL REGULATIONS, MALAYSIA

There are no regulations specifically governing the transport of chemicals. Use best practice.
7 / 10
SAFETY DATA SHEET
PRODUCT
NALCO® 77352
NATIONAL REGULATIONS, PHILIPPINES

Transport in accordance with the following legislation (as applicable): Presidential Decree No. 1185, 1977 ("Fire
Code of the Philippines") and implementing rules and regulations; Presidential Decree No. 856, 1975 ("Code of
Sanitation"); Republic Act No 6969, 1990 ("Toxic Substances and Hazardous and Nuclear Wastes Control Act")
and implementing rules and regulations.
NATIONAL REGULATIONS, SINGAPORE

Land Transport complies with the Environmental Pollution Control (Hazardous Substances) Regulations 1999,
which follows the "Specification for Caution Labelling for Hazardous Substances" - Singapore Standard 286
(1984).
NATIONAL REGULATIONS, THAILAND

The product should be transported in accordance with "Hazardous Substances Acts B.E.2535", "Notification of
Ministry of Public Health Re: Label and Level of Toxicity of Dangerous Articles Which are Under the
Responsibility of Food and Drug Administration 2534 (If applicable)" and "Notification of Land Transportation
Department, Subject : Label of truck which contain hazardous material, Notification date : 14 November
B.E.2543 (14 November 2000)".
AIR TRANSPORT (ICAO/IATA)

UN/ID No : UN 3265
Packing Group : II
MARINE TRANSPORT (IMDG/IMO)

UN/ID No : UN 3265
Packing Group : II
EmS-Nr. : F-A, S-B
15. REGULATORY INFORMATION
NATIONAL REGULATIONS, MALAYSIA :
HAZARD SYMBOLS
CORROSIVE
8 / 10
SAFETY DATA SHEET
PRODUCT
NALCO® 77352
Contains:..5-Chloro-2-Methyl-4-Isothiazolin-3-one 2-Methyl-4-Isothiazolin-3-one
RISK PHRASES
R34 - Causes burns.
R43 - May cause sensitization by skin contact.
SAFETY PHRASES
S23 - Do not breathe .. (gas/fumes/vapor/spray).
S24/25 - Avoid contact with skin and eyes.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
INTERNATIONAL REGULATIONS
NFPA RATING
HEALTH : 3 FLAMMABILITY : 0 INSTABILITY : 0 OTHER :
0 = Insignificant 1 = Slight 2 = Moderate 3 = High 4 = Extreme
INTERNATIONAL CHEMICAL CONTROL LAWS
AUSTRALIA
All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme
(NICNAS).
UNITED STATES :
This product is exempted under TSCA and regulated under FIFRA. The inerts are on the Inventory List.
CANADA :
The substances in this preparation are listed on the Domestic Substances List (DSL), are exempt, or have been
reported in accordance with the New Substances Notification Regulations.
EUROPE
The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories.
JAPAN
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical
Substances and are listed on the Existing and New Chemical Substances list (ENCS).
CHINA
All substances in this product comply with the Provisions on the Environmental Administration of New Chemical
Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC).
KOREA
All substances in this product comply with the Toxic Chemical Control Law (TCCL) and are listed on the Existing
Chemicals List (ECL)
9 / 10
SAFETY DATA SHEET
PRODUCT
NALCO® 77352
PHILIPPINES
All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines
Inventory of Chemicals & Chemical Substances (PICCS).
NEW ZEALAND
All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act
1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals.
16. OTHER INFORMATION
This product material safety data sheet provides health and safety information. The product is to be used in
applications consistent with our product literature. Individuals handling this product should be informed of the
recommended safety precautions and should have access to this information. For any other uses, exposures
should be evaluated so that appropriate handling practices and training programs can be established to insure
safe workplace operations. Please consult your local sales representative for any further information.
NALCO WATER INDIA LIMITED; S. No. 238/239, 3rd Floor, Quardra 1, Panchshil, Magarpatta Road, Sade
Satra Nali, Pune 411028 India
NALCO INDUSTRIAL SERVICES MALAYSIA SDN BHD; No 1, Jalan Jururancang U1/21, Seksyen U1, Hicom-
Glenmarie Industrial Park, 40150 Shah Alam, Selangor Darul Ehsan, Malaysia
NALCO PHILIPPINES INC.; Barrio Real, Calamba, Laguna, Philippines
NALCO PACIFIC PTE LTD; 21 Gul Lane, Singapore 629416
NALCO INDUSTRIAL SERVICES (THAILAND) CO LTD; Rayong Plant, 109/19 M00 4, Eastern Seaboard
Industrial Estate, Soi ESIE 6, T. Pluakdaeng, A. Pluakdaeng Rayong 21140 Thailand
EMERGENCY TELEPHONE NUMBER(S) :
INDIA : +65 6542 9595

MALAYSIA : 03 5569 4054
PHILIPPINES : 1800 10 8421250
SINGAPORE : +65 6542 9595
THAILAND : 02-104-0545
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by
a bar in the left-hand margin of the SDS.
Prepared By: Nalco Asia Pacific, Regulatory Affairs (RA) Specialist
10 / 10
8. FILTER DRAWING
DETAIL DESIGN
NOTE: DO NOT SCALE OFF THIS DRAWING.
ALWAYS WORK TO NOTED DIMENSIONS
NOTES & LEGEND:
R00 SHOP DRAWING 22/05/2023 A.S N.Z

REV DESCRIPTION DATE BY CHK
Client:
Site:
MISK City - Phase1

Status: Scale:
1:3
Date Created: Drawn By: Sheet Size:
22/05/2023 A.S A0
Drawing Title:
Filtration skid & pumps skid

arrangement
Project No.: Rev:

DB70309 R00
Drawing No.:
SUD-MISK-DM-FL-01
© Sudlows Limited
DETAIL DESIGN
NOTES & LEGEND:

Client:
Site:
MISK City - Phase1

Status: Scale:
1:3
22/05/2023 A.S A0
Drawing Title:
Filtration
Filtration skid
skid &
& pumps
pumps skid
skid
arrangement
arrangement
Project No.: Rev:

R00
Drawing No.:
SUD-MISK-DM-FL-02
DETAIL DESIGN
NOTES & LEGEND:

Client:
Site:
MISK City - Phase1
Status: Scale:
1:3
22/05/2023 A.S A0
Drawing Title:
Filtration skid & pumps skid

arrangement
Project No.: Rev:

R00
Drawing No.:
SUD-MISK-DM-FL-03
9. RISK ASSESSMENT
Job Safety Analysis
(H) (I)
(A) (B) (C) (D) (E) (F) (G) (J)
Severit Likeliho
Activity/Step Hazards Control Measures Severity Likelihood Risk Additional Control measures Risk
y od
 Ensure all access/egress is
clear of any obstruction
 Sufficient Lighting is
provided for safe access
especially in dark areas.
 Emergency backup lights to
be installed on access / work
 Access and Egress areas
 Unfamiliar environment  Site Road Speed limits must
 Motor Vehicle &
be observed and always
 Low visibility due to Plant Collision
 Site access via followed
vehicle
adverse weather of
darkness during night
 Damage to property 3 3 9  Provide Flagman if needed
3 1 3
 Injury to pedestrians
work  Monitor weather conditions
 Moving Vehicles & Plants  Ensure walkways are
properly marked
 MEPI (Moving Equipment &
Personnel Interface) to be
properly put in place to avoid
confusion for the pedestrians
and Drivers/Operators on
where the correct way is.
 Operatives to be encouraged
 Miscommunication to participate in open
due to language discussions with regards on
barrier that may their experiences/lesson
 Language barrier
cause wrong learned with the hazards and
 Toolbox Meeting  Poor Communication
understanding of the
2 2 4 risk associated in the activity.
2 1 2
topic that is being  Topic to be communicated in
communicated a Multilanguage way in order
to be understood correctly
 Method statement and JSA
Job Safety Analysis
must be available before

work commences.
 Risk Assessment to be
communicated to all involves
parties. Especially the
hazards of the activity.
 Make sure housekeeping is

done before the start of any
activity. Doing housekeeping will
create a much safer area for all
 Heat stroke the operatives/staff/public that
 Housekeeping  Fatigue will be in the area
 Heat stress   Ensure that there is adequate
 Site Preparation
 Manual handling 
Muscle spasms
Sprains mad broken
3 3 9 drinking water available at the
3 1 3
 Use of hand tools bones work area
 Proper or required PPE must be
worn at all times.
 Sufficient Rest Breaks to be
provided to the operatives
 Ensure operatives are trained,

experienced & qualified in fall
prevention & protection
 Ensure ladder in good condition
at all times.
 Bents, dents, cracks and loose
 Incompetent Person  Personnel injury
or missing rivets, broken or
performing the task  Fall from height
missing rungs in any other way
 Use of Step Ladder  Working at height 
& Straight Ladder  Over reaching 
Property damage
Trip, slips & fall/pinch
2 3 6 
shall not be used.
Ensure that one person on
2 1 2
 Improper use point ladder at a time & secured by
 Using wrong type
ladder attendant.
 Step ladder should only use in
inside the building where the
floor is firm and level and
ensure it is fully open.
 Only non-metallic approved
Job Safety Analysis
ladder will be used during

operations where employees
may come into contact with
electrical circuit or system.
 Do not use a ladder in a
horizontal position as a platform.
 Ensure face ladder when
climbing up or down.
 Ladder shall be capable to carry
4x the weight of the user
 Ladder shall be used by one
personnel at a time
 Ladder or working platform shall
be adequate to reach area for
inspection
 Ladder or working platform used
in energized equipment shall be
adequately grounded or earthed
 A third-party certified Scaffold

Supervisor must be deployed to
supervise scaffold activities
 Scaffold erectors should be
trained, third party certified and
certified by the contractor
 Mechanical failure Scaffold Dept.
 Scaffold Erection  Personnel injury  All scaffold materials must be
 Use of MEWP (Sky  Incompetent Person  property damage properly inspected and records

Jack / Man Lift)
Use of 
performing the task  Fall from Height 4 3 12 
to be kept for good conditions
Setup exclusion zones to
4 1 4
Working at height  Trip, slip, and
Scaffolding fall/Pinch Point prevent unauthorized entry
 Ensure operator have contractor
approval
 Ensure operatives undergone
working at heights training
 All workers shall wear full-body
harness properly anchored to a
stable and rigid structure
Job Safety Analysis
capable to withstand 5000lbs.

 All personnel working at height
of more than 1.8 meters shall be
equipped with an (FBH) full
body harness with 2 shock-
absorbing lanyards.
 Ensure protection equipment
(i.e. full-body harness) is
inspected and color-coded to
ensure safe use.
 Materials and tools shall be
properly secured to prevent
from falling, provide lashing or
closed toolboxes.
 PFAS to be provided to
operatives working at heights.
 Equipment and operator must
have an up to date third party
certification
 Equipment to be properly
inspected before use.
 In case of emergency, Contact
number will be post on strategic
places & follow rescue plan, &
 Call#011-212-7111 (EOC)
Emergency Operation Center.
 Contractor shall establish a war

 Body sprain room to where review of
 Chronic documents is undertaken
 Review of drawings
 Awkward positioning
musculoskeletal  War room shall be equipped
and as-built plans disorder with table, ergonomic chair,
for the planning of
 Inadequate
materials
storage of
 Loss or damage to
2 3 6 storage cabinet and etc.
2 1 2
commissioning property  Commissioning Engineer shall
 Ergonomics hazards be responsible in proper storage
of documents
Make a borrowers log book to
Job Safety Analysis
TRS-HS-FRM-0001
monitor the loaned documents
 Activity shall be disseminated to

all affected workers day before
the actual testing
 Warning notice shall be posted
on a strategic location of the
building day before the actual
testing indicating start and end
date, exact location of the
testing indicated on a floor plan
 Only competent person shall
conduct earth/grounding testing
 Competent person shall closely
communicate with the assistant
to avoid contact with electricity
 Personal Injury  Toolbox meeting shall be
 Electrical Hazard due to  Electrocution conducted by the competent
person on a daily basis
 Pre damage cables  Skin Burn
emphasizing the risk involve on
Commissioning
and Start-Up
 Inadequate
notice
warning 

Fire
Damage to property
3 3 9 the activity and its mitigating
3 1 3
measure to eliminate or
 Slip, Trip & Fall minimize the impact
  Workers shall wear appropriate
PPE when doing the task.
 Safety Officer shall monitor
compliance and provide advice
to pre-commissioning team as
necessary
 Perform lockout / tag out on the
equipment that might be
energized during the testing
 Provision of adequate fire
extinguisher to be positioned in
the strategic locations
 Tools, earth spikes and wiring
shall be handled in a manner to
avoid damage and incurred
Job Safety Analysis
injury
Call#011-212-7111 (EOC)
 MSDS shall be posted on site.
 Workers shall be instructed on
proper use of materials in
accordance with MSDS
requirements.
 MSDS requirements for
transport, storage, use and
disposal shall be implemented
 Work crews will use appropriate
PPE (Hand gloves, safety
goggles, face mask, cover all
 Unauthorized Entry and respirators)
 Simultaneous operation  Unauthorized entry to water
 Ignoring safety distance  Personal injury flushing area is not allowed.
 Improper Manual Handling  Cuts, laceration, burn  Activity Area shall be barricaded
 Pinch points  Damage to the prior to start the work.
 Flushing
 Vibrations property  Control of substances
 Use of defective/ wrong  Slips, trips & fall hazardous to health trainings as
hand tools/power tools Tool Box Talks Topic.
 Electric Shock  Appropriate training to the
 Hose or coupling Failure workers prior to start of work.
 Safety personnel shall secure
the test boundary all time and
remove any unauthorized
personnel from or nearby the
test boundary
 First Aid kit will be available.
 Safety Tasks Assignment for all
workers working in hazardous
substances.
 Control of Substances
Hazardous to Health training as
Job Safety Analysis
Tool Box Topic
 Activity shall be disseminated to

all affected workers day before
the actual testing
 Authorized Engineer shall be
responsible on a proper
information dissemination
 Install barricade around the
testing area including the earth
matting being tested and
provide adequate safety sign to
communicate activity and
 Accident resulting hazards involve
serious injury or death  Ensure that all involved
to other worker personnel were competent
 Inadequate warning  Hand laceration or cut, /experienced/ trained to perform
notification bruise, contusion. the task.
 Testing &  Lack of information  Head injury or bruise  Perform lockout / tag out on the
Commissioning  Energized electrical  Damage to asset and equipment that might be
for Chilled Water equipment equipment
3 4 12 energized during the testing
3 1 3
Piping  Pinch Point  Electric shock, skin  Evacuate the people from the
 Entry of Unauthorized burn area if they are likely to be
person  Inappropriate test affected. Place sign on local
result stop/start button to warn
commissioning is in progress.
 Assigned a standby-man to
prevent unauthorized entry
within the testing area.
 Competent person shall closely
communicate with the assistant
to avoid contact with electricity
 Toolbox meeting shall be
conducted by the competent
person on a daily basis
emphasizing the risk involve on
the activity and its mitigating
measure to eliminate or
Job Safety Analysis
minimize the impact

 Provision of adequate fire
extinguisher to be positioned in
the strategic locations
 Wear appropriate hand gloves
when installing earth spikes
 Tools, earth spikes and other
equipment shall be inspected by
competent person before using
to the site
 Implement proper cable
management to avoid dangling,
short circuit, damage to wire
and tripping accident
 Establish equipment access and
shall be free from any
obstruction

Call#011-212-7111 (EOC)
 Ensure to plan correct manual

lifting procedures and body
positioning before the actual lift.
 Only 20 kg allowed lifting by an
individual.
 Muscular injuries  Use buddy system if load
 Improper manual handling/ (Back pain, strain, exceed.
 Housekeeping lifting of equipment and
material 
fractures)
Pinch/crash points
2 3 6  Provide material handling
2 1 2
resulting hand injuries equipment for transport of heavy
and large materials / equipment.
 Inspection oh Material Handling
equipment prior to use
 Provide Manual handling
Training to the workers.
Job Safety Analysis
 Use hand protection (cotton

gloves minimum) during
handling of materials.
 Keep hands away from
pinch/crash points
 Ensure safe and clear pathways
before lifting.
ENVIROMENATAL RISK ASSESSMENT
Degree of Risk Risk Rating
Task or Activity Hazard Identificaion Severity Liklehood Risk score Level of Risk Required Action
Storage of chemicals required in Risk of chemical leakage during Use A plastic sheet to cover

1 2 3 6 Medium
chemical treatment process storage the area of chemicals storage
Use spill containment Bowl
Drainage of water with chemicals Risk of damage occure in drainage under drainage hose to
2 2 3 6 Medium
from the drain points hose so the water may spill on prevent spill the water on the
the floor floor

Flushing Chemical Treatment Method Statement - MISK City

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Flushing Chemical Treatment Method Statement - MISK City

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MISK

-1 IVC ISOLATION VALVES CHAMBER

E 658712.049 DC BUILDING PLOT CHAMBER

-1 AUTOMATIC AIR VALVE CHAMBER

0+200 Drain Point 400mm

V=3.639 m/s R DP1

Drain Point 350mm

V=4.1795 m/s S E 659980.654

Q=3968.9 m3/h R 2 D REJECTED E REVIEW NOT REQUIRED

SHOP-DRAWING FOR CONSTRUCTION MOBILIZATION

MiSK City at MiSK Foundation

17th Floor, South Tower, Abraj Attawuniya

King Fahd Road

Riyadh, Kingdom of Saudi Arabia

TEL: +966 (0)11 2180303

PUMP Dr ain P Al Nakheel District ، Al Raidah Digital City,

SAUDI CONSULTING SERVICES CO.

ENGINEER DR. TAREK M. A. SHAWAF

P.O.Box 2341, Riyadh 11451

S c Tel: 4659975 Fax: 4647540

P.O. BOX 2567, RIYADH12244

Applications: Technical Data:

Flowrate & Filtration Area:

Max. Flow Rate Recommended Flow Rate

Size 1# 25m³/hr 15m³/hr

Size 2# 40m³/hr 25m³/hr

Ordering Information: Polykleen Bag Pleated High Flow(GPM)

BHFPB -PP -1 -N -0100 -E -H -A

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : NALCO® TRAC109

Other means of identification : Not applicable

Company : Nalco Gulf Ltd.

Nalco Saudi Company Limited

Emergency telephone : +32-(0)3-575-5555

Issuing date : 01/17/2018

COMPANY CONTACT TELEPHONE NUMBERS.

USA Nalco Company (630)305-1000

Section: 2. HAZARDS IDENTIFICATION

GHS Label element

Signal Word : Danger

Hazard Statements : May intensify fire; oxidiser.

Precautionary Statements : Prevention:

Other hazards : None known.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : Mixture

Chemical Name CAS-No. Concentration: (%)

Section: 4. FIRST AID MEASURES

Notes to physician : Treat symptomatically.

Section: 5. FIREFIGHTING MEASURES

Special protective equipment : Use personal protective equipment.

Section: 6. ACCIDENTAL RELEASE MEASURES

Section: 7. HANDLING AND STORAGE

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Form of exposure Permissible Basis

TWA (Inhalable 2 mg/m3 (Borate) ACGIH

Personal protective equipment

Eye protection : Safety goggles

Hand protection : Wear the following personal protective equipment: