SDS - Merck-Pte-Ltd - 125700-67-6 - 851008 - 20171005 - en Tbtu PDF
SDS - Merck-Pte-Ltd - 125700-67-6 - 851008 - 20171005 - en Tbtu PDF
SDS - Merck-Pte-Ltd - 125700-67-6 - 851008 - 20171005 - en Tbtu PDF
CAS-No. 125700-67-6
1.2 Relevant identified uses of the substance or mixture and uses advised against
1.4 Emergency telephone Please contact the regional company representation in your country.
number
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Page 1 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For the full text of the H-Statements mentioned in this Section, see Section 16.
Hazard pictograms
Signal word
Danger
Hazard statements
H228 Flammable solid.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
Prevention
P210 Keep away from heat.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
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Page 2 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Hazard pictograms
Signal word
Danger
CAS-No. 125700-67-6
3.1 Substance
EC-No. 423-040-4
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Page 3 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
For the full text of the H-Statements mentioned in this Section, see Section 16.
3.2 Mixture
Not applicable
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/
shower.
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
After swallowing: immediately make victim drink water (two glasses at most). Consult a
physician.
4.2 Most important symptoms and effects, both acute and delayed
irritant effects, Cough, Shortness of breath
The following applies to boron compounds in general: resorption is followed by nausea and
vomiting, agitation, spasms, CNS disorders, cardiovascular disorders.
4.3 Indication of any immediate medical attention and special treatment needed
No information available.
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Page 4 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Further information
Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing
water from contaminating surface water or the ground water system.
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Page 5 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see
sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation
of dusts.
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and
face after working with substance.
Tightly closed and away from sources of ignition and heat. Observe national regulations.
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Page 6 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Engineering measures
Technical measures and appropriate working operations should be given priority over the use of
personal protective equipment.
Eye/face protection
Safety glasses
Hand protection
full contact:
Glove material: Nitrile rubber
Glove thickness: 0,11 mm
Break through time: > 480 min
splash contact:
Glove material: Nitrile rubber
Glove thickness: 0,11 mm
Break through time: > 480 min
The protective gloves to be used must comply with the specifications of EC Directive
89/686/EEC and the related standard EN374, for example KCL 741 Dermatril® L (full contact),
KCL 741 Dermatril® L (splash contact).
The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374
with samples of the recommended glove types.
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Page 7 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
This recommendation applies only to the product stated in the safety data sheet<(>,<)> supplied
by us and for the designated use. When dissolving in or mixing with other substances and under
conditions deviating from those stated in EN374 please contact the supplier of CE-approved
gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Respiratory protection
required when dusts are generated.
Recommended Filter type: Filter P 2 (acc. to DIN 3181) for solid and liquid particles of harmful
substances
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective
devices are carried out according to the instructions of the producer. These measures have to be
properly documented.
Form solid
Colour white
Odour odourless
pH No information available.
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Page 8 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Flammability (solid, gas) The substance or mixture is a flammable solid with the
category 1.
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Page 9 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
none
10.1 Reactivity
The following applies in general to flammable organic substances and mixtures: in
correspondingly fine distribution, when whirled up a dust explosion potential may generally be
assumed.
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Page 10 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Skin irritation
Causes skin irritation.
Eye irritation
Causes serious eye irritation.
Sensitisation
This information is not available.
Carcinogenicity
This information is not available.
Reproductive toxicity
This information is not available.
Teratogenicity
This information is not available.
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Page 11 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Aspiration hazard
This information is not available.
12.1 Toxicity
No information available.
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Page 12 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Not relevant
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Page 13 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulations
Major Accident Hazard SEVESO III
Legislation Not applicable
Occupational restrictions Take note of Dir 94/33/EC on the protection of young people at
work.
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Page 14 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Substances of very high concern (SVHC) This product does not contain substances
of very high concern according to
Regulation (EC) No 1907/2006 (REACH),
Article 57 above the respective regulatory
concentration limit of ≥ 0.1 % (w/w).
National legislation
Storage class 4.1A
For this product a chemical safety assessment was not carried out.
Training advice
Provide adequate information, instruction and training for operators.
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Page 15 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Labelling
Hazard pictograms
Signal word
Danger
Hazard statements
H228 Flammable solid.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
Precautionary statements
Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking.
Response
P302 + P352 IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P313 Get medical advice/ attention.
P370 + P378 In case of fire: Use powder for extinction.
Key or legend to abbreviations and acronyms used in the safety data sheet
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Page 16 of 17
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Regional representation
This information is given on the authorised Safety Data Sheet for your country.
The information contained herein is based on the present state of our knowledge. It characterises the product with
regard to the appropriate safety precautions. It does not represent a guarantee of any properties of the product.
The Safety Data Sheets for catalogue items are available at www.merckgroup.com
Page 17 of 17