Boric Acid
Boric Acid
Boric Acid
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses Reagent for analysis, Chemical production
In compliance with the conditions described in the annex to this safety
data sheet.
Signal word
Danger
Hazard statements
H360FD May damage fertility. May damage the unborn child.
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 1 of 20
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Precautionary statements
Prevention
P201 Obtain special instructions before use.
Response
P308 + P313 IF exposed or concerned: Get medical advice/ attention.
Index-No. 005-007-00-2
For the full text of the H-Statements mentioned in this Section, see Section 16.
Hazardous components (1999/45/EC)
Chemical Name (Concentration)
CAS-No. Classification
boric acid (<= 100 % )
10043-35-3 Repr.Cat.2; R60-61
For the full text of the R-phrases mentioned in this Section, see Section 16.
3.2 Mixture
not applicable
4.2 Most important symptoms and effects, both acute and delayed
drop in temperature, agitation, spasms, Diarrhoea, Nausea, Vomiting, Tiredness, ataxia
(impaired locomotor coordination)
4.3 Indication of any immediate medical attention and special treatment needed
No information available.
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 3 of 20
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Hygiene measures
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and
face after working with substance.
Worker DNEL, longterm Systemic effects dermal 392 mg/kg Body weight
Consumer DNEL, longterm Systemic effects dermal 196 mg/kg Body weight
Consumer DNEL, longterm Systemic effects oral 0.98 mg/kg Body weight
Consumer DNEL, acute Systemic effects oral 0.98 mg/kg Body weight
Engineering measures
Technical measures and appropriate working operations should be given priority over the use of
personal protective equipment.
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 4 of 20
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Hand protection
full contact:
Glove material: Nitrile rubber
Glove thickness: 0.11 mm
Break through time: > 480 min
splash contact:
Glove material: Nitrile rubber
Glove thickness: 0.11 mm
Break through time: > 480 min
The protective gloves to be used must comply with the specifications of EC Directive
89/686/EEC and the related standard EN374, for example KCL 741 Dermatril® L (full contact),
KCL 741 Dermatril® L (splash contact).
The breakthrough times stated above were determined by KCL in laboratory tests acc. to EN374
with samples of the recommended glove types.
This recommendation applies only to the product stated in the safety data sheet, supplied by us
and for the designated use. When dissolving in or mixing with other substances and under
conditions deviating from those stated in EN374 please contact the supplier of CE-approved
gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).
Other protective equipment
protective clothing
Respiratory protection
required when dusts are generated.
Recommended Filter type: Filter P 2 (acc. to DIN 3181) for solid and liquid particles of harmful
substances
The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective
devices are carried out according to the instructions of the producer. These measures have to be
properly documented.
Colour white
Odour odourless
pH 3.8 - 4.8
at 33 g/l
20 °C
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 5 of 20
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 6 of 20
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Genotoxicity in vitro
Ames test
Result: negative
Method: OECD Test Guideline 471
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 7 of 20
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
CMR effects
Teratogenicity:
May damage the unborn child.
Reproductive toxicity:
May damage fertility.
12.1 Toxicity
Toxicity to fish
LC50 Oncorhynchus mykiss (rainbow trout): 50 - 100 mg/l; 96 h (ECOTOX Database)
Toxicity to daphnia and other aquatic invertebrates
EC50 Daphnia magna (Water flea): 133 mg/l; 48 h (ECOTOX Database)
12.2 Persistence and degradability
Biodegradability
The methods for determining the biological degradability are not applicable to inorganic
substances.
12.3 Bioaccumulative potential
Partition coefficient: n-octanol/water
log Pow: -1.09 (22 °C)
OECD Test Guideline 107
Bioaccumulation is not expected.
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 8 of 20
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
See www.retrologistik.com for processes regarding the return of chemicals and containers, or
contact us there if you have further questions.
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not relevant
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 9 of 20
SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Substances of very high concern (SVHC) This product does contain substances of
very high concern according to Regulation
(EC) No 1907/2006 (REACH), Article 57
above the respective regulatory
concentration limit of ≥ 0.1 % (w/w).
Contains: boric acid
National legislation
Storage class 6.1 D
Training advice
Provide adequate information, instruction and training for operators.
R-phrase(s) 60-61 May impair fertility. May cause harm to the unborn child.
S-phrase(s) 53-45 Avoid exposure - obtain special instructions before use. In
case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
Further information
Restricted to professional users.
Key or legend to abbreviations and acronyms used in the safety data sheet
Used abbreviations and acronyms can be looked up at www.wikipedia.org.
The information contained herein is based on the present state of our knowledge. It characterises the product with
regard to the appropriate safety precautions. It does not represent a guarantee of any properties of the product.
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 10 of 20
SAFETY DATA SHEET – Annex
according to Regulation (EC) No. 1907/2006
Sectors of end-use
SU 3 Industrial uses: Uses of substances as such or in preparations at industrial sites
SU9 Manufacture of fine chemicals
SU 10 Formulation [mixing] of preparations and/ or re-packaging (excluding alloys)
Chemical product category
PC21 Laboratory chemicals
Process categories
PROC1 Use in closed process, no likelihood of exposure
PROC2 Use in closed, continuous process with occasional controlled exposure
PROC3 Use in closed batch process (synthesis or formulation)
PROC4 Use in batch and other process (synthesis) where opportunity for exposure arises
PROC5 Mixing or blending in batch processes for formulation of preparations and articles
(multistage and/ or significant contact)
PROC9 Transfer of substance or preparation into small containers (dedicated filling line, including
weighing)
PROC15 Use as laboratory reagent
PROC26 Handling of solid inorganic substances at ambient temperature
Environmental Release Categories
ERC1 Manufacture of substances
ERC2 Formulation of preparations
ERC4 Industrial use of processing aids in processes and products, not becoming part of articles
ERC6a Industrial use resulting in manufacture of another substance (use of intermediates)
ERC6b Industrial use of reactive processing aids
Amount used
Annual amount per site 55000 t
Remarks Expressed as, Boron
Amount used
Annual amount per site 950 kg
Remarks Expressed as, Boron
Amount used
Annual amount per site 14 t
Remarks Expressed as, Boron
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 12 of 20
SAFETY DATA SHEET – Annex
according to Regulation (EC) No. 1907/2006
Amount used
Annual amount per site 190 t
Remarks Expressed as, Boron
Product characteristics
Concentration of the Substance in Covers the percentage of the substance in the product up to
Mixture/Article 100 %.
Physical Form (at time of use) Solid, high dustiness, powder
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 13 of 20
SAFETY DATA SHEET – Annex
according to Regulation (EC) No. 1907/2006
Product characteristics
Concentration of the Substance in Covers the percentage of the substance in the product up to
Mixture/Article 100 %.
Physical Form (at time of use) Solid, high dustiness, powder
Conditions and measures related to personal protection, hygiene and health evaluation
In case of insufficient local exhaust ventilation, respiratory protection must be worn
Product characteristics
Concentration of the Substance in Covers the percentage of the substance in the product up to
Mixture/Article 100 %.
Physical Form (at time of use) Solid, high dustiness, powder
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 14 of 20
SAFETY DATA SHEET – Annex
according to Regulation (EC) No. 1907/2006
Conditions and measures related to personal protection, hygiene and health evaluation
Wear respiratory protection. Effectiveness (of a measure): 90 %
Product characteristics
Concentration of the Substance in Covers the percentage of the substance in the product up to
Mixture/Article 100 %.
Physical Form (at time of use) Solid, high dustiness
Physical Form (at time of use) Liquid mixture, paste
Conditions and measures related to personal protection, hygiene and health evaluation
Wear suitable gloves (tested to EN374), coverall and eye protection.
Safety shoes
Product characteristics
Concentration of the Substance in Covers the percentage of the substance in the product up to
Mixture/Article 100 %.
Physical Form (at time of use) Solid, high dustiness, powder
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 15 of 20
SAFETY DATA SHEET – Annex
according to Regulation (EC) No. 1907/2006
Avoid carrying out operation for more than 1 hour. Regular testing and maintenance of plant and
equipment
Conditions and measures related to personal protection, hygiene and health evaluation
Safety glasses
Lab coat
Safety shoes
Additional good practice advice beyond the REACH Chemical Safety Assessment
Additional good practice advice Wear suitable gloves tested to EN374.
Product characteristics
Concentration of the Substance in Covers the percentage of the substance in the product up to
Mixture/Article 100 %.
Physical Form (at time of use) Solid, high dustiness, powder
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 16 of 20
SAFETY DATA SHEET – Annex
according to Regulation (EC) No. 1907/2006
Workers
CS Use descriptor Exposure duration, route, effect RCR Exposure Assessment Method
2.5 PROC1 longterm, inhalative, systemic 0.007 MEASE
longterm, combined, systemic < 0.001 MEASE
longterm, dermal, systemic 0.007
2.5 PROC3 longterm, inhalative, systemic 0.690 MEASE
longterm, dermal, systemic < 0.001 MEASE
longterm, combined, systemic 0.690
2.6 PROC2 longterm, inhalative, systemic 0.33 MEASE
longterm, dermal, systemic < 0.001 MEASE
longterm, combined, systemic 0.33
2.7 PROC4 longterm, inhalative, systemic 0.276 MEASE
longterm, combined, systemic < 0.001 MEASE
longterm, dermal, systemic 0.276
2.7 PROC5 longterm, inhalative, systemic 0.276 MEASE
longterm, dermal, systemic < 0.001 MEASE
longterm, combined, systemic 0.276
2.8 PROC9 longterm, inhalative, systemic 0.276 Measured data
longterm, dermal, systemic < 0.001 MEASE
longterm, combined, systemic 0.276
2.9 PROC15 longterm, inhalative, systemic 0.110 Measured data
longterm, dermal, systemic < 0.001 MEASE
longterm, combined, systemic 0.110
2.10 PROC26 longterm, inhalative, systemic 0.662 MEASE
longterm, combined, systemic < 0.001 MEASE
longterm, dermal, systemic 0.662
The default parameters and -efficiencies of the applied exposure assessment model were used for
the calculation (unless stated differently).
4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure
Scenario
Please refer to the following documents: ECHA Guidance on information requirements and chemical
safety assessment Chapter R.12: Use descriptor system; ECHA Guidance for downstream users;
ECHA Guidance on information requirements and chemical safety assessment Part D: Exposure
Scenario Building, Part E: Risk Characterisation and Part G: Extending the SDS; VCI/Cefic REACH
Practical Guides on Exposure Assessment and Communications in the Supply Chain; CEFIC
Guidance Specific Environmental Release Categories (SPERCs).
For scaling of environmental exposure assessments, please refer to the ARCHE tool at www.arche-
consulting.be/Metal-CSA-toolbox/du-scaling-tool.
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 17 of 20
SAFETY DATA SHEET – Annex
according to Regulation (EC) No. 1907/2006
Sectors of end-use
SU 22 Professional uses: Public domain (administration, education, entertainment, services,
craftsmen)
Chemical product category
PC21 Laboratory chemicals
Process categories
PROC15 Use as laboratory reagent
Environmental Release Categories
ERC2 Formulation of preparations
ERC6a Industrial use resulting in manufacture of another substance (use of intermediates)
ERC6b Industrial use of reactive processing aids
Amount used
Annual amount per site 950 kg
Remarks Expressed as, Boron
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 18 of 20
SAFETY DATA SHEET – Annex
according to Regulation (EC) No. 1907/2006
Amount used
Annual amount per site 190 t
Remarks Expressed as, Boron
Product characteristics
Concentration of the Substance in Covers the percentage of the substance in the product up to
Mixture/Article 100 %.
Physical Form (at time of use) Solid, high dustiness, powder
Conditions and measures related to personal protection, hygiene and health evaluation
Safety glasses
Lab coat
Safety shoes
Additional good practice advice beyond the REACH Chemical Safety Assessment
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 19 of 20
SAFETY DATA SHEET – Annex
according to Regulation (EC) No. 1907/2006
Workers
CS Use descriptor Exposure duration, route, effect RCR Exposure Assessment Method
2.3 PROC15 longterm, inhalative, systemic 0.110 Measured data
longterm, dermal, systemic < 0.001 MEASE
longterm, combined, systemic 0.110
The default parameters and -efficiencies of the applied exposure assessment model were used for
the calculation (unless stated differently).
4. Guidance to Downstream User to evaluate whether he works inside the boundaries set by the Exposure
Scenario
Please refer to the following documents: ECHA Guidance on information requirements and chemical
safety assessment Chapter R.12: Use descriptor system; ECHA Guidance for downstream users;
ECHA Guidance on information requirements and chemical safety assessment Part D: Exposure
Scenario Building, Part E: Risk Characterisation and Part G: Extending the SDS; VCI/Cefic REACH
Practical Guides on Exposure Assessment and Communications in the Supply Chain; CEFIC
Guidance Specific Environmental Release Categories (SPERCs).
For scaling of environmental exposure assessments, please refer to the ARCHE tool at www.arche-
consulting.be/Metal-CSA-toolbox/du-scaling-tool.
The Safety Data Sheets for catalogue items are available at www.merck-chemicals.com
Page 20 of 20