Structure of Atom Bounceback 2.0

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Consider the following pairs of electrons

A. Only A
B. Only B
C. Only C
D. (B) and (C)

The pairs of electron present in degenerate orbitals is/are


The energy of one mole of photons of radiation of wavelength
300 nm is
(given : h = 6.63 x 10-34 Js, NA = 6.02 x 1023 mol-1, c = 3 x 108 ms-1)

A. 235 kJ mol-1
B. 325 kJ mol-1
C. 399 kJ mol-1
D. 435 kJ mol-1
The pair, in which ions are isoelectronic with Al3+ is :-

A. Br- and Be2+


B. Cl- and Li+
C. S2- and K+
D. O2- and Mg2+
The minimum energy that must be possessed by photons in order to
produce the photoelectric effect with platinum metal is:
[Given: The threshold frequency of platinum is 1.3 x 1015 s-1 and h = 6.6 x
10-34 J s.]

A. 3.21 x 10-14 J
B. 6.24 x 10-16 J
C. 8.58 x 10-19 J
D. 9.76 x 10-20 J
If the radius of the 3rd Bohr’s orbit of hydrogen atom is r3 and the radius of
4th Bohr’s orbit is r4. Then :
The number of radial and angular nodes in 4d orbital are respectively

A. 1 and 2
B. 3 and 2
C. 1 and 0
D. 2 and 1
If the uncertainty in velocity and position of a minute particle in space are,
2.4 x 10-26 (ms-1) and 10-7 (m) respectively. The mass of the particle of g is_
(nearest integer)
(given : h = 6.626 x 10-34 Js)
Consider the following set of quantum numbers
If the work function of a metal is 6.63 x 10-19 J, the maximum wavelength
of the photon required to remove a photoelectron from the metal is_
nm . (Nearest integer)
[given : h = 6.63 x 10-34 J s, and c = 3 x 108 m s-1]
Consider the following statements:
A. The principal quantum number ‘n’ is a positive integer with values
‘n’ = 1, 2, 3, …
A. The azimuthal quantum number ‘l’ for a given ‘n’ (principal quantum
number) can have values as l’ = 0, 1, 2, … n
B. Magnetic orbital quantum number ‘mi’ for a particular ‘l’ (azimuthal
quantum number) has (2l + 1) values.
C. 土1/2 are the two possible orientations of electron spin.
D. For l = 5, there will be a total of 9 orbital.

Which of the above statements are correct ?

A. (A), (B) and (C)


B. (A) , (C) , (D) and (E)
C. (A) , (C) and (D)
D. (A) , (B) , (C) and (D)
Which of the following statements are correct ?
A. The electronic configuration of Cr is [Ar] 3d5 4s1.
B. The magnetic quantum number may have a negative value
C. In the ground state of an atom, the orbitals are filled in order of their
increasing energies.
D. The total number of nodes are given by n-2.

Choose the most appropriate answer from the options given below :

A. (A), (C) and (D) only


B. (A) and (B) only
C. (A) and (C) only
D. (A) , (B) and (C) only.
The electronic configuration of Pt (atomic number 78) is :

A. [xe] 4f14 5d9 6s1


B. [Kr] 4f14 5d10
C. [Xe] 4f14 5d10
D. [Xe] 4f14 5d8 6s2
Which of the following is the correct plot for the probability density ψ2 (r)
as a function of distance ‘r’ of the electron from the nucleus for 2s orbital ?
Which of the following sets of quantum is not allowed ?

A. n = 3, 1 = 2, m1 = 0, s = + 1/2
B. n = 3, 1 = 2, m1 = -2, s = + 1/2
C. n = 3, 1 = 3, m1 = 3, s = -1/2
D. n = 3, 1 = 0, m1 = 0, s = -1/2
When the excited electron of a H atom from n = 5 drops to the ground state,
the maximum number of emission lines observed are_
The wavelength of an electron and a neutron will become equal when the
velocity of the electron is x times the velocity of neutron. The value of x is_.
(nearest integer) (mass of electron is 9.1 x 10-31 kg and mass of neutron is
1.6 x 10-27 kg)
Consider an imaginary ion 4822X3-. The nucleus contains ‘a’ % more neutrons
than the number of electrons in the ion. The value of ‘a’ is_ [nearest integer]
Given below are two statements. One is labelled as
Assertion A and the other is labelled as Reason R.
Assertion A : Energy of 2s orbital of hydrogen atom is greater than that of 2s
orbital of lithium.
Reason R : Energies of the orbitals in the same subshell decrease with
increase in the atomic number.
In the light of the above statements choose the correct answer from the
options given below.

A. Both A and R are true and R is the correct explanation of A.


B. Both A and R are true but R is not the correct explanation of A.
C. A is true but R is false.
D. A is false but R is true.
The correct decreasing order of energy, for the orbitals having, following set
of quantum numbers :
(A) n = 3, 1 = 0, m = 0
(B) n = 4, 1 = 0, m = 0
(C) n = 3, 1 = 1, m = 0
(D) n = 3, 1 = 2, m = 1

A. (D) > (B) > (C) > (A)


B. (B) > (D) > (C) > (A)
C. (C) > (B) > (D) > (A)
D. (B) > (C) > (D) > (A)
Identify the incorrect statement from the following.

A. A circular path around the nucleus in which an electron moves is


proposed as Bohr’s orbit.
B. An orbital is the one electron wave function (Ψ) in an atom
C. The existence of Bohr’s orbits is supported by hydrogen spectrum.
D. Atomic orbital is characterised by the quantum numbers n and l only
If the wavelength for an electron emitted from H- atom is 3.3 x 10-10 m, then
energy absorbed by the electron in its ground state compared to minimum
energy required for its escape from the atom, is _ times. [given : h = 6.626 x
10-34 Js,
Mass of electron = 9.1 x 10-31]
The minimum uncertainty in the speed of an electron in an one dimensional
region of length 2ao (where a0 = Bohr radius 52.9 pm) is _ km s-1.
(Given : Mass of electron = 9.1 x 10-31 kg, Planck’s constant h = 6.63 x 10-34
Js
[Adv. 2019]
A. (III), (S)
[Adv. 2019]
B. (IV), (Q)

C. (III), (P)

D. (IV), (U)
Code: SAKSHI
Code: SAKSHI
Code: SAKSHI
SAKSHI SAKSHI
Thank You

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