Chemistry Practice Paper

CBSE
Class 11 Chemistry
Practice Paper 1
Chapter-2 Structure of Atom
General Instruction: All Questions are compulsory.
1 Mark Questions
1. Indicate the number of electrons, protons and neutrons in the clement U.
[Ans. e = 92, p =92, n = 146)

2. Name the experiment used in determination of the charge of an electron.
3. Arrange the electron (e), protons (p) and alpha particle (O) in the increasing order for the
values of earn (charge/mass).
[Ans. ∝<p < e]
4. Calculate the mass of one mole of electron. Given: me=9.11x 1031 kg)
[Ans. 0.55mg|
5. Write the dimensions of Planck's constant. Mention some other physical quantity, which
has the same dimension.
6. Name the element which was discovered in the sun by spectroscopic method.
Ans. Helium (He) |
7. Which of the following will not show deflection from the path on passing through an
electric field Proton, Cathode rays, Anode rays, Electron, Neutron.
Hint: Neutron (n) will not show deflection since it is electrically neutral.
8. Out of electron and proton, which one will have a higher velocity to produce matter
waves of the same wavelength
Hint: ,For same wavelength, m, is very small as compared to m.
Therefore ve. will be higher as compared to vp.
9. An anion A3- has 18 electrons. Write the atomic number of A.

[Ans. 15)
10. What is the value of orbital angular momentum of 6s orbital
11. What physical meaning is attributed to the square of the absolute value of wave function
?
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12. Name two physical quantities which can be estimated by principal quantum number (n).
13. Which shell would be the first to have g-subshell?
14. How many electrons in an atom can have n + 1 = 6
[Ans. 18)
15. Name three quantum numbers which arise as a result of the solution of Schrodinger
wave equation.
16. Write electronic configuration of the Cr3+ion. [Atomic number of Cr=24]

17. The ion of an element has configuration (Ar) 3din +3 oxidation state. Write the electronic
configuration of its atom.
18. State Pauli’s exclusion principle.
19. How many nodes are there in 3s orbital
Ans. 2 nodes
20. Why lp, 2d and 3s subshells are not possible
21. How many unpaired electrons are present in Fe3+ ion?

22. State Hunds rule of maximum multiplicity.
23. Using’s, p, d notations, describe the orbital with the following quantum numbers:
(a) = 4, = 2 (b) n = 1, 1 = 0
Ans. (a) 4d (b) 1s
24. Which quantum number determines the orientation of atomic orbital
25. Which orbital is non-directional
26. Write the correct set of four quantum numbers for the valence electron (outermost
electron) of potassium (Z= 19).
27. Which principle is not obeyed in writing of electronic configuration:
2 Mark Questions
1. Give examples of each of the following:

a. Isotope of Cl
b. Isobar of Ar
c. Isotone of N
d. Isoelectronic species of S2-

[Ans.
e. C1
f. Ca
g. O
h. K+ Ca2+, Ar, Cl-, S2-]

2. Describe the cathode ray experiment. How will you detect the spot where the rays stike?
3. Outline Rutherford's contribution to understand the nucleus of an atom.
4. Calculate the percentage of higher isotope of neon which has average atomic mass 20.2
and the isotopes have the mass numbers 20 and 22.
[Ans. 10% Ne]
5. Account for the following:

a. Cathode rays are produced only when the pressure of the gas inside the discharge
tube is very very low.
b. Canathin foil of aluminium be used in place of gold (Au) in Rutherford experiment?
Give suitable explanation.
(Hint: Lighter nuclei cannot exhibit proper deflection of ∝-particles.)
6. Distinguish between an atomic emission spectrum and an atomic absorption spectrum.
7. The energies of electrons are said to be quantized. Explain.
8. A laser used to read compact disc (CD) emits red light of wavelength 700 nm. How many
photons does it emit each second if its power is 1 W
[Ans. 3.5 x 1018S-1']

9. Electromagnetic radiation of wavelength 242 nm is just sufficient to ionise the sodium
atom, Calculate the ionisation energy of sodium in kJ mol-1.

10. Show that the circumference of Bohr orbit for the hydrogen atom is an integral multiple
of the de Broglie wavelength associated with the electron revolving around the nucleus.
11. Explain, giving reasons, which of the following sets of quantum numbers are not
possible:
(a) n =0 I=0 m1=0 ms=+ ½
(b) n = 1 I=0 m1=0 ms=- ½
(c) n= l I=1 m1=0 ms=+ ½

(d) n= 3 I=1 m1=0 ms=0
12. Calculate the energy required for the process He+ (g) →He2+ (g) + e- The ionisation energy
for the H atom in the ground state is 2.18 10'-18 J atom-1
[Ans. 8,72 10-18J|

13. a. Anatomic orbital has n = 3. Write the possible values of land m1?
b. List the quantum numbers (m1 and l) of electrons for 3d orbital.
14. Draw the boundary surface diagrams of d, and d, x2-y2orbitals.

15. What is meant by degenerate orbitals Illustrate with the help of one example,
16. How does a 1s orbital differ from a 2s orbital Mention two points in support of your
answer.
17. Calculate the wave number for the shortest wavelength transition in the Balmer series of
atomic hydrogen.
[Ans. 27419.25 cm-1]

18. Calculate (a) Wave number and (b) frequency of yellow radiation having wavelength 5
800 A
19. Calculate the energy associated with the first orbit of He. What is the radius of this orbit.
Ans.: E1=8.72 10-18 J, r= 0.02645 mn
20. Nitrogen laser produces a radiation at a wavelength of 337.1 nm. If the number of
photons emitted is 5.6 1024, calculated the power of this laser

Ans. (3.3 106 J)
21. 2 108 atoms of carbon are arranged side by side. Calculate the radius of carbon atom if
the length of this arrangement is 2.4 cm.
Ans. 0.06nm
22. In milikan's experiment, static electric charge on the oil drops has been obtained by
shining X-rays. If the static electric charge on the oil drop is -1.282 1018 C, calculate the
number of electrons present on it.
Ans. 8

3 Mark Questions
1. Differentiate between:
a. Photon and quantum
b. Orbit and orbital
c. de Broglie waves and electromagnetic waves
2. a. State Heisenberg uncertainly principle.
b. "Electron cannot exist within the atomic nucleus.' Justify the statement on the basis of
Heisenberg uncertainty principle.
Hint: Radius of nucleus = 10-15m

3. Calculate the wavelength of an electron that has been accelerated in a particle accelerator
through a potential difference of 1keV[1 eV = 1.6 10-19J)
Ans. 3.87 10-7 m
4. The kinetic energy of a subatomic particle is 5.86 10-25 J. Calculate the frequency of the
particle wave.
Ans. 1,76 109 s-1]

5. Calculate the energy required to excite the electron in the atom from n = 1 to n= 2. The
ionization enthalpy of hydrogen atom is 1.312 106 Jmol-1.

6. Calculate and compare the products of uncertainty in position and uncertainty in velocity
for a milligram-sized object and that of an electron (mc = 9.11 10-31 kg). What
conclusion would you draw from the result"?
7. The electron energy in hydrogen atom is given by En = (-2.18 10-18)/n2 J.

Calculate the energy required to remove an electron completely from the F = 2 orbit,
Calculate the longest wavelength of light in cm that can be used to cause this transition.
8. How many series are found in the spectrum of atomic hydrogen Mention their names
and the regions in which they appear.
9. a. Write the electronic configurations of the followings:
i. H- ii. Na+ iii. O2-
b. Symbols Brand "Br can be written, whereas symbols Brand 35Br are not
acceptable. Explain why?

c. An ion with mass number 37 possesses one unit of negative charge. If the ion contains

11.1% more neutrons than the electrons. Assign the symbol of this ion.
[Ans.: Cl-]
5 Mark Questions
1. a. Define photoelectric effect Mention its one practical application in daily life.
b. Electrons are emitted with zero velocity from a metal surface when it is exposed to
radiation of wavelength 6800 Á. Calculate threshold frequency (vo) and work function
(Wo) of the metal.
[Ans. 4.41 1014s-1 291 10-19J]

2. a. State de Broglie relation. Why it is not meaningful for a moving cricketball'?
b. Which out of (i) electron (e), (ii) proton (p) (iii) C, particle, has maximum de Broglie's
wavelength Assume that all are moving with the same velocity.
c. The wavelength associated with particle 'A' is 5 10-8 m. Calculate the wavelength
associated with particle B, if its momentum is half of A.
Ans. 1 10-7m
3. a. What is the significance of the statement "Product of uncertainty in position and
momentum is always constant if measured simultaneously"?
b. Why is uncertainty principle not applicable to macroscopic particles?
c. An electron has a speed of 40 ms-1 accurate upto 99.99%. What is the uncertainty in
locating its position (mc =9.11 10-31 kg)
[Ans. 145 10-2m]

4. a. State Aufbau principle.
b. What is the physical significance of the boundary surface diagrams in the following
depiction of atomic orbitals?
c. Explain the following with suitable reason:
i. In potassium, the 19th electron enters in 4s subshell instead of 3d Subshell.

ii. Chromium has configuration 4s1 3d5 and not 4s2 3d4.
iii. The three electrons present in 2p subshell of nitrogen (N) remain unpaired and
have the parallel spins.
5. The Work function for caesium atom is 1.9 eV. Calculate (i) the threshold wave length and
(ii) the threshold frequency of the radiation. If the caesium element is irradiated with a
radiation of wave length 500 nm, calculate the kinetic energy and the Velocity of the
ejected photo electron.
i) 652nm
ii) 4.598 1014 S-1
iii) 3.97 10-13 J, 9.33 108m S-1

Among the following pairs of orbitals, which orbital will experience the larger effective
nuclear charge
i) 2s and 3s
ii) 3d and 3p
Ans.:(i) 2s (ii) 3p

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CBSE

General Instruction: All Questions are compulsory.

1. Indicate the number of electrons, protons and neutrons in the clement U.

[Ans. e = 92, p =92, n = 146)

Hint: ,For same wavelength, m, is very small as compared to m.

Therefore ve. will be higher as compared to vp.

9. An anion A3- has 18 electrons. Write the atomic number of A.

Material downloaded from myCBSEguide.com. 1 / 7

16. Write electronic configuration of the Cr3+ion. [Atomic number of Cr=24]

21. How many unpaired electrons are present in Fe3+ ion?

1. Give examples of each of the following:

d. Isoelectronic species of S2-

Material downloaded from myCBSEguide.com. 2 / 7

h. K+ Ca2+, Ar, Cl-, S2-]

5. Account for the following:

[Ans. 3.5 x 1018S-1']

atom, Calculate the ionisation energy of sodium in kJ mol-1.

(a) n =0 I=0 m1=0 ms=+ ½

(b) n = 1 I=0 m1=0 ms=- ½

(c) n= l I=1 m1=0 ms=+ ½

Material downloaded from myCBSEguide.com. 3 / 7

for the H atom in the ground state is 2.18 10'-18 J atom-1

[Ans. 8,72 10-18J|

b. List the quantum numbers (m1 and l) of electrons for 3d orbital.

14. Draw the boundary surface diagrams of d, and d, x2-y2orbitals.

[Ans. 27419.25 cm-1]

Ans.: E1=8.72 ​ ​ 10-18 J, r= 0.02645 mn

photons emitted is 5.6 1024, calculated the power of this laser

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Hint: Radius of nucleus = 10-15m

through a potential difference of 1keV[1 eV = 1.6 10-19J)

Ans. 3.87 10-7 m

Ans. 1,76 109 s-1]

ionization enthalpy of hydrogen atom is 1.312 106 Jmol-1.

conclusion would you draw from the result"?

7. The electron energy in hydrogen atom is given by En = (-2.18 10-18)/n2 J.

i. H- ii. Na+ iii. O2-

acceptable. Explain why?

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(Wo) of the metal.

[Ans. 4.41 1014s-1 291 10-19J]

locating its position (mc =9.11 10-31 kg)

[Ans. 145 10-2m]

c. Explain the following with suitable reason:

i. In potassium, the 19th electron enters in 4s subshell instead of 3d Subshell.

Material downloaded from myCBSEguide.com. 6 / 7

ii) 4.598 1014 S-1

iii) 3.97 10-13 J, 9.33 108m S-1

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Ans.: E1=8.72 10-18 J, r= 0.02645 mn