MSDS Leoch Battery (Jiangsu) Corp. - 2022公章版

江苏理士电池有限公司
Leoch Battery(Jiangsu) Corp.

North of Shenhua Blvd. (West of Tongtai Road), Jinhu Industry Zone, Jinhu, Huaian, Jiangsu, china
MATERIAL SAFETY DATA SHEET
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SECTION 1: PRODUCT IDENTIFICATION

Product Name: Maintenance Free Valve Regulated Lead Acid Battery: DJW, DJM, DJ, FT, LHT,
LHR, PLH, LP, LPC, LPL, LPG, LPX, LPS, DGM, DG Series
Common Synonyms: Sealed Lead Acid Battery, Non-dangerous battery, VRLA Lead Acid Batteries, VRLA
Battery
DOT Description: Battery, wet, non-spillable, electric storage battery
Chemical Family: Electrical Battery Standby
Manufacturer’s Name: Leoch Battery(Jiangsu) Corp.
Address: North of Shenhua Blvd.(West of Tongtai Road), Jinhu Industry Zone, Jinhu, Huaian,
Jiangsu ,china
E-mail: [email protected]
Emergency Tel No.: (CHINA) Phone: 086-755-8603-6060
Date Issued: January 01,2022
SECTION 2: Hazards identification
HEALTH ENVIRONMENTAL PHYSICAL

Acute Toxicity Aquatic Chronic 1 Explosive Chemical, Division 1.3
(Oral/Dermal/Inhalation) Category 4 Aquatic Acute 1
Skin Corrosion/Irritation Category 1A
Eye Damage Category 1
Reproductive Category 1A
Carcinogenicity (lead compounds) Category 1B
Carcinogenicity (arsenic) Category 1A
Carcinogenicity (acid mist) Category 1A
Specific Target Organ Category 2
Toxicity (repeated exposure)
GHS LABEL:
HEALTH ENVIRONMENTAL PHYSICAL
Hazard Statements: DANGER! Precautionary Statements

Causes severe skin burns and serious eye damage. Wash thoroughly after handling.
May damage fertility or the unborn child if Do not eat, drink or smoke when using this product.
ingested or inhaled.
May cause cancer if ingested or inhaled. Wear protective gloves/protective clothing, eye
protection/face protection.
Causes damage to central nervous system, blood Avoid breathing dust/fume/gas/mist/vapors/spray.
and kidneys through prolonged or repeated
exposure.
May form explosive air/gas mixture during Use only outdoors or in a well-ventilated area.
charging.
Extremely flammable gas (hydrogen). Contact with internal components may cause irritation or
severe burns. Avoid contact with internal acid.
Explosive, fire, blast, or projection hazard. Irritating to eyes, respiratory system, and skin.
May cause harm to breast-fed children Harmful if Obtain special instructions before use.
swallowed, inhaled, or contact with skin Causes Do not handle until all safety precautions have been read
skin irritation, serious eye damage. and understood
Avoid contact during pregnancy/while nursing
Keep away from heat./sparks/open flames/hot surfaces. No
smoking
Other Hazards
Mechanical VRLA Batteries can be heavy. Correct manual handling techniques and/or mechanical lifting
aides (e.g. Fork Lift Truck) must be used.
Material name: Maintenance Free Valve Regulated Lead Acid Battery MSDS
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Electrical VRLA Batteries can contain large amounts of electrical energy which can give very high
discharge currents and severe electrical shock if the terminals are short circuited.
Chemical -The VRLA Battery presents no chemical hazards during the normal operation provided the
recommendations for handling, storage, transport and usage are observed.
-VRLA Batteries emit hydrogen gas which is highly flammable and will form explosive
mixtures in air from approx. 4% to 76%. This can be ignited by a spark at any voltage, naked
flames or other sources of ignition.
-If the battery is broken and the internal components exposed, hazards may exist which require
careful attention.
SECTION 3: HAZARDOUS INGREDIENTS/ IDENTITY INFORMATION
COMPONENTS Approx. % by CAS Number Air Exposure Limits (μg/m3) LD50

Wt. ACGIH TLV OSHA NIOSH ORAL
(mg/kg)
Inorganic Lead/Lead 65%-75% 7439-92-1 150 50 10 --
Compounds
Tin <0.5% 7440-31-5 2000 2000 -- --
Calcium <0.1% 7440-70-2 -- -- -- --
Dilute Sulfuric Acid ~20% 7664-93-9 1000 1000 1000 2.14
Fiberglass Separator ~5% -- -- -- -- --
Case Material: ~5% 9003-56-9 -- -- -- --
Acrylonitrile Butadiene
Styrene (ABS)
SECTION 4: HAZARDOUS INGREDIENTS/ IDENTITY INFORMATION
This information is of relevance only if the VRLA Battery has suffered damage, is broken and persons have
direct contact with the internal components.
Plate Grids Inhalation Remove the person from exposure to fresh air. Seek advice from a medical
and Active doctor
materials Ingestion Wash out mouth with water and give plenty of water to drink. Do not induce
vomiting. Seek advice from a medical doctor
Skin Contact Wash off with plenty of water and soap to prevent accidental ingestion or
inhalation. Seek medical advice if pain or rash does not reduce
Eye Contact Immediately irrigate with eyewash solution or clean water for at least 10
minutes, holding the eyelids apart. Then take the person to hospital without
further delay
Self-protection for Eye protection (safety glasses or face shield), and heavy-duty gloves are
the first aider required. In case of inhalation, a face mask or respirator may be required.
Battery SPEED IS ESSENTIAL - OBTAIN IMMEDIATE MEDICAL ATTENTION.
Electrolyte Inhalation Remove the person from exposure to fresh air. If the person continues to
feel unwell seek advice from a medical doctor.
Ingestion Wash out mouth with water and give plenty of water to drink. Do not induce
vomiting. If the person continues to feel unwell seek advice from a medical
doctor.
Skin Contact Drench with large quantities of water. Remove contaminated clothing and
place in water to dilute the acid. Continue to wash the affected area for at
least 10 minutes. Seek advice from a medical doctor
Eye Contact SPEED IS ESSENTIAL - OBTAIN IMMEDIATE MEDICAL
ATTENTION
Immediately irrigate with eyewash solution or clean water for at least 10
minutes, holding the eyelids apart. Then take the person to hospital without
further delay.
Self-protection for Eye protection (safety glasses or face shield), and heavy-duty gloves are
Case Inhalation Material can burn in a fire with toxic smoke and decomposition products.
Material Upon inhalation of decomposition products, keep patient calm, remove to
fresh air, and seek advice from a medical doctor. If a large quantity is
inhaled take the person to hospital.
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Note to physician: Treat according to symptoms (decontamination, vital
functions), no known specific antidote.
doctor.
Skin Contact Areas affected by molten material should be quickly placed under cold
running water and a sterile protective dressing applied. Seek advice from a
medical doctor.
Eye Contact May cause irritation or injury due to mechanical action and traces of Battery
Electrolyte. Immediately irrigate with eyewash solution or clean water for at
least 10 minutes, holding the eyelids apart. Then take the person to hospital
without further delay
Self-protection for Eye protection (safety glasses or face shield), and disposable gloves are
Separator Inhalation Remove patient from exposure to fresh air. If irritation persists, seek advice
Material from a medical doctor.
doctor.
Skin Contact After contact with skin, wash immediately with plenty of soap and water. If
irritation persists, seek advice from a medical doctor.
Eye Contact May cause irritation or injury due to mechanical action and traces of Battery
Electrolyte. Immediately irrigate with eyewash solution or clean water for at
least 10 minutes, holding the eyelids apart. Then take the person to hospital
without further delay
Self-protection for Eye protection (safety glasses or face shield), and disposable gloves are
SECTION 5: FIRE-FIGHTING AND EXPLOSION HAZARD MEASURES
VRLA batteries Flash Point: N/A

General Information: ➢ VRLA Batteries emit hydrogen gas which is highly
Explosion Hazard flammable and will form explosive mixtures in air from
approx. 4% to 76%. This can be ignited by a spark at any
voltage, naked flames or other sources of ignition.
➢ Batteries in use will be part of an electrical circuit and
must be isolated from the power source before
attempting to put out a fire. Switch the power OFF before
disconnecting the batteries from the power source.
➢ Damaged batteries may expose negative plates, grey in
colour, which may ignite if allowed to dry out. These
plates may be wetted down with water after the battery
has been removed from all electrical circuits.
Suitable Extinguisher types CO2; Foam; Dry Powder.
Unsuitable Extinguisher types Water extinguishers must never be used to put out an electrical
fire.
Hazardous combustion & Carbon monoxide, Sulphur Dioxide, Sulphur Trioxide, Lead
decomposition products fume and vapour, toxic fumes from decomposition of battery
case materials.
Advice for fire-fighters Full face visor or safety goggles; Respiratory equipment or
self-contained breathing apparatus (SCBA); Full acid resistant
protective clothing must be worn in fire-fighting conditions.
SECTION 6: ACCIDENTAL RELEASE MEASURES
This information is of relevance only if the VRLA Battery has suffered damage and is broken.
VRLA Battery VRLA batteries are designed to be safe to handle and not to leak battery
electrolyte under normal conditions.
In case of accidental damage heavy-duty gloves are required to pick-up the
battery to protect against unseen electrolyte leakage
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Plate Grids and Personal Eye protection (safety glasses or face shield), and heavy-duty gloves are
Active Precautions required. If the material is wet, a face mask or respirator is not required
Materials If the material is dry, a face mask or respirator is required
Clean-up Large, solid pieces may be picked up and bagged for recycling.
Methods Never use a brush to sweep up debris; it may create Lead-dust in the air.
Wet clean the spill area to remove all traces of debris. Battery debris and
cleaning materials must be collected and placed in an inert sealed container
(e.g. self-seal plastic bag or bucket) for disposal.
Environmental Do not allow material to enter a watercourse. Exposed Lead materials must
Precautions be placed in an inert sealed container (e.g. self-seal plastic bag or bucket)
for disposal,
Battery Personal Ensure suitable, acid resistant personal protective clothing (including
Electrolyte Precautions heavy-duty gloves, safety glasses and respiratory protection) is worn during
removal and clean-up of spillages.
Clean-up Neutralise and absorb the spillage using soda ash, sodium bicarbonate
Methods: (available from supermarkets), sodium carbonate or calcium carbonate
Small spillages powder.
Wet clean the spill area to remove all traces of debris. Battery debris and
cleaning materials must be collected and placed in an inert sealed container
Clean-up Large amounts of electrolyte spillage are unlikely with VRLA batteries
Methods: Large since the electrolyte is fully absorbed in the active materials and separator.
spillages Bund the spillage area using dry sand, earth, sawdust or other inert material.
Neutralise the electrolyte using soda ash, sodium bicarbonate (available
from supermarkets), sodium carbonate or calcium carbonate powder.
Wet clean the spill area to remove all traces of debris and electrolyte.
Cleaning materials must be collected and placed in an inert sealed container
Environmental Battery electrolyte must not be allowed to enter any drains or sewage
Precautions system or water course.
Case Material Clean-up Assume battery case material is contaminated and proceed as for Plate
Methods Grids and Active Materials above.
Separator Clean-up Assume battery case material is contaminated and proceed as for Plate
Material Methods Grids and Active Materials above.
SECTION 7: HANDLING AND STORAGE
Handling Unless involved in recycling operations, do not breach the casing or empty the contents of the
battery. Handle carefully and avoid tipping, which may allow electrolyte leakage. There may be
increasing risk of electric shock from strings of connected batteries.
Keep containers tightly closed when not in use. If battery case is broken, avoid contact with internal
components.
Keep vent caps on and cover terminals to prevent short circuits. Place cardboard between layers of
stacked automotive batteries to avoid damage and short circuits.
Keep away from combustible materials, organic chemicals, reducing substances, metals, strong
oxidizers and water. Use banding or stretch wrap to secure items for shipping.
Storage Store batteries in cool, dry, well-ventilated areas with impervious surfaces and adequate containment
in the event of spills. Batteries should also be stored under roof for protection against adverse
weather conditions. Separate from incompatible materials. Store and handle only in areas with
adequate water supply and spill control. Avoid damage to containers. Keep away from fire, sparks
and heat. Keep away from metallic objects could bridge the terminals on a battery and create a
dangerous short-circuit.
Charging There is a possible risk of electric shock from charging equipment and from strings of series
connected batteries, whether or not being charged. Shut-off power to chargers whenever not in use
and before detachment of any circuit connections. Batteries being charged will generate and release
flammable hydrogen gas.
Charging space should be ventilated. Keep battery vent caps in position. Prohibit smoking and avoid
creation of flames and sparks nearby.
Wear face and eye protection when near batteries being charged.
SECTION 8: HANDLING AND STORAGE

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VRLA Battery
Control Parameters There are no special control parameters for the handling, storage, installation of VRLA
Batteries.
VRLA Batteries emit hydrogen gas which is highly flammable and will form explosive
mixtures in air from approximately 4% to 76%. Never install VLRA Batteries in a gas-
tight enclosure during storage, transport or usage.
Exposure Control There are no special exposure controls for the handling, storage, installation or use of
VRLA Batteries.
Personal Protection When there is no evidence of damage or visible traces of liquid (electrolyte) or solid
deposits on the batteries they may be handled safely without extra personal protective
equipment.
Ensure electrical insulation equipment is used when installing batteries.
(e.g. insulated mats and covers; insulated tools)
Remove ALL metallic objects from the person when working with VRLA Batteries: e.g.
Jewellery (rings, watches, bracelets, necklaces), pens, torches, etc.
Where there are signs of damage or liquid (electrolyte) or solid deposits, rubber gloves
and acid resistant clothing must be worn when handling the batteries and affected
packaging to protect against the effects of any electrolyte that may be present.
If it is suspected that free electrolyte is present, then safety glasses must be worn, and if
large amounts are present, chemical goggles or face shield should be used.
UL CAUTIONARY “Warning: Risk of fire, explosion, or burns. Do not disassemble; heat above 50°C; or
STATEMENT incinerate”.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
VRLA Battery The main components are listed in SECTION 2 above

The undamaged product is a manufactured article in an inert plastic (ABS) case, which will burn
if subjected to high temperatures or sources of ignition. Some battery types are made with Flame
Retardant ABS cases, see technical specification. These batteries carry the suffix ‘FR’ after the
battery type.
The information below refers to the physical and chemical properties of the main VRLA Battery components and
substances. This information is published for reference only.
Plate Grids Appearance Safety-related data
and Form Solid Solidification point 327 °C
Active Colour Grey or Boiling point 1740 °C
materials brown
Odour Odourless Solubility in water Very low (0.15mg/l)
Solubility in acid or Yes, dependant on the strength of
alkaline solutions solution.
Density (at 20°C) 11.35 g/cm3
Vapour pressure (at 20°C) Undetectable
Battery Form Liquid Solidification point -35 to -60 °C
Electrolyte Colour Colourless Boiling point Approx. 108 to 114 °C
Odour Odourless Solubility in water Complete
Density (at 20°C) Variable up to 1.350 g/cm3
Vapour pressure (at 20°C) 10-20 mmHg
Case Material Appearance
Form Solid Softening point > 100 °C
Colour Grey or black Flash Point >330 °C
Odour Slight Odour Solubility in water Insoluble
Solubility in other solvents Soluble in polar solvents, aromatic
solvents, chlorinated
hydrocarbons.
Density (at 20°C) 1.07-1.4 g/cm3
Separator Form Fibrous Solidification point 820°C
Material: material
Colour White Boiling point >2500°C
Odour Odourless Solubility in water Insoluble
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Density (at 20°C) 2.23g/cm3
SECTION 10: STABILITY AND REACTIVITY
VRLA Battery Stability Within the operational temperature range -20 to +50 °C the
undamaged product is stable
Plate Grids and Materials & Conditions to Powdered Lead reacts violently with fused ammonium nitrate
Active materials Avoid and sodium acetylide. Reacts violently when in contact with
chlorine trifluoride.
Battery Possibility of Hazardous Dilution of the higher concentrated grades with water may
Electrolyte Reactions liberate excessive heat.
Highly reactive with metals and organic materials.
On contact with metals, may generate hydrogen which forms
explosive mixtures with air.
Destroys organic materials such as cardboard, wood, textiles,
etc.
Hazardous Decomposition Sulphur oxides
Product(s)
Case Material: Materials & Conditions to To avoid thermal decomposition, do not overheat.
Avoid Starts to decompose at temperatures >275°C
Powerful oxidising agents.
Hazardous decomposition Monomers, other degradation products, traces of hydrogen
products cyanide.
Separator Stability Stable material.
Material: Materials & Conditions to Incompatible with Hydrofluoric acid and concentrated Sodium
Avoid Hydroxide.
Hazardous decomposition No hazardous polymerisation expected.
products
SECTION 11: TOXICOLOGICAL INFORMATION
VRLA Battery This information does not apply to the undamaged VRLA
Battery. It is of relevance if the battery is broken and the
components are released to the environment
Exposure limits may vary according to national law and
regulations.
Plate Grids: Metallic Acute Toxicity Toxic by ingestion or inhalation
Lead, Lead alloys. Chronic poison
Lead is a poison that affects virtually every system in the body
Symptoms include fatigue, headaches, constipation, aching bones
and muscles, gastrointestinal tract disturbances and reduced
appetite
Symptoms include fatigue, headaches, constipation, aching bones
and muscles, gastrointestinal tract disturbances and reduced
appetite
Active materials: Acute Toxicity Toxic by ingestion or inhalation
Lead dioxide. Toxic by ingestion or inhalation
Chronic exposure to Lead compounds may lead to a build-up of
Lead in the body, giving rise to a variety of health problems,
including anaemia, kidney and liver damage, impaired eyesight,
memory loss and CNS2 damage
Battery Electrolyte: Corrosive Corrosive, the more concentrated solutions can cause serious
burns to the mouth, eyes and skin
Harmful by ingestion and through skin contact
7 / 11
Inhalation Mist is a severe irritant to the respiratory tract. Fluid build-up on
the lung (pulmonary oedema) may occur up to 48 hours after
exposure and could prove fatal
Ingestion Will immediately cause severe corrosion of and damage to the

gastrointestinal tract
Skin Contact Causes severe chemical burns
Eye Contact Risk of serious damage to eyes. Causes severe burns. May cause
prolonged or permanent damage or even total loss of sight. Mist
will cause irritation
Case Material: According to information available the product is not harmful to

health provided it is correctly handled and processed according to
the given recommendations.
Separator Material Based on animal implantation and epidemiologic studies glass

microfibers are thought to have some limited carcinogenic
potential and as such are designated as Group 2B materials
(IARC, US). The material should be treated as a category 3
carcinogen (Europe).
Limited evidence of carcinogenic effect.
SECTION 12: ECOLOGICAL INFORMATION
VRLA Battery This information does not apply to the undamaged VRLA
Battery. It is of relevance if the battery is broken and the
components are released to the environment.
Plate Grids and Metallic Lead, Lead Chemical and physical treatment is required for the elimination of
Active materials alloys and Lead dioxide Lead from water. Waste water containing Lead must not be
disposed of in an untreated condition.
Ecotoxicity Lead metal in massive form is not classified as hazardous to the

aquatic environment, due to its low solubility and rapid removal
from the water column. Inorganic lead compounds are considered
to be acutely toxic in the environment and also to present a long-
term hazard to aquatic organisms.
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Effect in the aquatic Toxicity for fish: 96 h LC 50 > 100 mg/l
environment Toxicity for daphnia: 48 h EC 50 > 100 mg/l
Toxicity for alga: 72 h IC 50 > 10 mg/l
Battery Ecotoxicity In order to avoid damage to the sewerage system, the acid has to
Electrolyte be neutralised by means of soda ash, sodium bicarbonate or
sodium carbonate before disposal.
Ecological damage is possible by change of pH. The electrolyte
solution reacts with water and organic substances, causing
damage to flora and fauna.
The electrolyte may also contain components of Lead that can be
toxic to aquatic environments.
Persistence and Remains indefinitely in the environment as sulphate.
Degradation
Case Material Elimination information: No data available: insoluble in water
Behaviour and Due to the consistency of the product, and its insolubility in
environmental fate water, it will apparently not be bio-available.
Separator No data available: insoluble in water
Material Not thought to pose any risk to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
VRLA Battery Europe Spent (used) VRLA Batteries are subject to the requirements of the Batteries
Directive 2006/66/EC on batteries and accumulators and waste batteries and
accumulators. Spent (used) VRLA Batteries MUST be sent for recycling
through an authorised contractor at the end-of-life.
The WEEE Directive 2002/96/EC (Waste Electrical and Electronic
Equipment) applies. Spent (used) VRLA Batteries MUST be removed from
electrical and electronic equipment at the end-of-life.
Worldwide VRLA batteries contain inorganic Lead compounds and Sulphuric Acid
which are damaging to the environment.
Spent (used) batteries must be disposed of in an environmentally friendly
manner in accordance with local national laws and regulations.
VRLA batteries must not be dismantled, burnt or incinerated as a means of
disposal.
At the end of life VRLA batteries may still be electrically ‘live’ and contain
a large amount of electrical energy. The same care and attention to safe
handling should be taken as when handling new batteries. Particular care
must be taken to avoid short-circuiting the battery terminals.
Plate Grids and Europe Metallic Lead and active materials (Lead Oxides) must be recycled.
Active materials Worldwide Disposal must be carried out in accordance with the European Hazardous
Waste Directive 2008/98/EC.
Battery Electrolyte Europe Disposal must be carried out in accordance with the European Hazardous
Waste Directive 2008/98/EC on the protection of the environment through
criminal law
Worldwide Disposal should be in accordance with local, state or national legislation.
General Battery electrolyte is dilute Sulphuric Acid, the strength of which depends on
the state of charge of the batteries. It must be neutralised before disposal. See
SECTION 6 for clean-up and disposal advice.
Case Material Do not dispose of this product into sewers, any ocean or water course in
order to prevent marine animals and birds from ingesting.
Recycling is encouraged.
Disposal by controlled incineration or source landfill in accordance with
local national laws and regulations may be acceptable.
Separator Material Constitutes a special waste by virtue of hazardous substance content.
Dispose of via approved landfill site. Disposal by controlled source landfill
in accordance with local national laws and regulations may be acceptable.
9 / 11
SECTION 14: TRANSPORT INFORMATION
Proper Shipping Name Batteries, wet, non-spillable

Wet, non-spillable batteries do not need to be shipped and transported as fully-regulated Class 8
Corrosive hazardous materials / dangerous goods when tested, packaged and marked in accordance
with the following regulations:
U.S. DOT: Our non-spillable lead acid batteries are under the U.S. Department of
Transportation’s (DOT) hazardous materials regulations but are excepted
from these regulations since they meet all of the following requirements
found at49 CFR 173.159(f) and 49 CFR 173.159a
The batteries are excepted from regulation if they have been tested in accordance
with the vibration and pressure differential tests found in 49 CFR 173.159(f) and
“rupture test” found at 49 CFR 173.159a;
When offered for transport, the batteries must be protected against short circuits and
securely packaged in accordance with 49 CFR 173.159a; and
The batteries and outer packaging must be marked NON-SPILLABLE BATTERY
or NON-SPILLABLE as required by 49 CFR 173.159a
ADR / RID Land Transport: Not applicable
IATA Dangerous Goods Excepted from the dangerous goods regulations because the batteries meet the
Regulations DGR requirements of Packing Instruction 872 and Special Provisions A67 of the
International Air Transportation Association (IATA) Dangerous goods Regulations
and International Civil Aviation Organization (ICAO) Technical Instructions.
Battery Terminals must be protected against short circuits.
The words “NOT RESTRICTED”, SPECIAL PROVISION A67" must be provided
on an airway bill when air waybill is issued.
IMDG Excepted from the dangerous goods regulations for transport by sea because the
batteries meet the requirements of Special Provision 238 of the International
Maritime Dangerous Goods (IMDG CODE). Battery terminals must be protected
against short circuits.
IMO Non-Hazardous for Sea Transport: Non-hazardous for sea transport.
If the regulations listed above are not met, then Batteries, wet, nonspillable (UN2800) are regulated as Class 8
Corrosive hazardous materials / dangerous goods by the U.S. Department of Transportation (DOT) and
international dangerous goods regulatory authorities pursuant to the IATA Dangerous Goods Regulations and
IMDG Code.
SECTION 15: REGULATORY INFORMATION
VRLA Battery Required Markings

Europe Crossed-out wheeled bin indicating “SEPARATE COLLECTION” for
all batteries and accumulators. Not to be disposed of with general
domestic, commercial or industrial waste.
Ref: The Batteries Directive 2006/66/EC
Europe The Pb symbol indicates the heavy metal content of the battery and
enables the Lead-Acid battery to be sorted for recycling.
Ref: The Batteries Directive 2006/66/EC.
Worldwide The International Recycling Symbol, required by law in many countries
world-wide to facilitate the identification of secondary batteries and
accumulators for recycling.
Ref: IEC 61429 : 1995, Marking of secondary cells and batteries with
the International Recycling Symbol ISO 7000-1135
U.S. Proposition 65 Warning: Battery posts, terminals and related accessories contain lead
and lead compounds, chemicals known to the State of California to
cause cancer and reproductive harm. Batteries also contain other
chemicals known to the State of California to cause cancer. Wash hands
after handling.
Europe EC Directives Directive 2006/66/EC, on batteries and accumulators and waste batteries
and accumulators.
Paragraph (Recital) 29 states:
10 / 11
“Directive 2002/95/EC of the European Parliament and of the Council
of 27 January 2003 on the restriction of the use of certain hazardous
substances in electrical and electronic equipment does not apply to
batteries and accumulators used in electrical and electronic equipment.”
Germany
VwVwS Annex reference Water hazard class (WGK) 2, hazard to waters (Classification
according to VwVwS, Annex 4)
12th Ordinance Implementing the Federal Is not subject of the 12. BlmSchV (Hazardous Incident
Immission Control Act - 12.BImSchV Ordinance)
Netherlands
SZW-lijst van kankerverwekkende stoffen None of the components are listed
SZW-lijst van mutagene stoffen None of the components are listed
NIET-limitatieve lijst van voor de voortplanting giftige stoffen – Lead is listed
Borstvoeding
Vruchtbaarheid
Ontwikkeling
Denmark
Classification remarks Emergency management guidelines for the storage of flammable liquids must be
followed
Recommendations Danish Young people below the age of 18 years are not allowed to use the product
Regulation Pregnant/breastfeeding women working with the product must not be in direct
contact with the product
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4) Lead (CAS 7439-92-1): Listed.
Sulphuric Acid (CAS 7664-93-9): Listed.
SARA 304 Emergency release notification Sulphuric Acid (CAS 7664-93-9): Listed.
OSHA Specifically Regulated Substances (29 CFR 1910.1001- Lead (CAS 7439-92-1):
1050) Reproductive toxicity
Central nervous system
Kidney
Blood
Acute toxicity
Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categories:
Immediate Hazard – No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance

Chemical name CAS Reportable Threshold Threshold Threshold planning
number Quantity planning quantity planning quantity, upper
(pounds) (pounds) quantity, lower value (pounds)
value (pounds)
Sulphuric Acid
7664-93-9 1000 1000 1000 1000
SARA 311/312 Hazardous chemical No
SARA 313 (TRI reporting)

Chemical name CAS number % by wt.
Lead 7439-92-1 65%-75%
Sulphuric Acid 7664-93-9 ~20%
11 / 11
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Lead (CAS 7439-92-1)
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 Sulphuric Acid (CAS 7664-93-9)
CFR 68.130)
Safe Drinking Water Act (SDWA) Not regulated.

Drug Enforcement Administration (DEA). List 2, Essential Sulphuric Acid (CAS 7664-93-9) : 6552
Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical
Code Number
Drug Enforcement Administration (DEA). List 1 & 2 Exempt Sulphuric Acid (CAS 7664-93-9):
Chemical Mixtures (21 CFR 1310.12(c)) 20%WV
DEA Exempt Chemical Mixtures Code Number Sulphuric Acid (CAS 7664-93-9): 6552
US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

Lead (CAS 7439-92-1) Listed: October 1, 1992
Sulphuric Acid (CAS 7664-93-9) Listed: March 14, 2003
US - California Proposition 65 - CRT: Listed date/Developmental toxin
Lead (CAS 7439-92-1) Listed: February 27, 1987
US - California Proposition 65 - CRT: Listed date/Female reproductive toxin
US - California Proposition 65 - CRT: Listed date/Male reproductive toxin
US. California. Candidate Chemicals List. Safer Lead (CAS 7439-92-1)
Consumer Products Regulations (Cal. Code Regs, tit. Tin (CAS 7440-31-5)
22, 69502.3, subd.(a)) Sulphuric Acid (CAS 7664-93-9)
SECTION 16: OTHER INFORMATION
HMIS®ratings Health: 0
Flammability: 1
Physical hazard: 0
Health: 0
NFPA ratings NFPA ratings
Flammability: 1
Instability: 0
Disclaimer The information in the sheet was written based on the best knowledge and experience
currently available.
Issue date 2022-01-01

MSDS Leoch Battery (Jiangsu) Corp. - 2022公章版

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江苏理士电池有限公司

Leoch Battery(Jiangsu) Corp.

SECTION 1: PRODUCT IDENTIFICATION

SECTION 2: Hazards identification

HEALTH ENVIRONMENTAL PHYSICAL

Hazard Statements: DANGER! Precautionary Statements

SECTION 3: HAZARDOUS INGREDIENTS/ IDENTITY INFORMATION

COMPONENTS Approx. % by CAS Number Air Exposure Limits (μg/m3) LD50

SECTION 4: HAZARDOUS INGREDIENTS/ IDENTITY INFORMATION

SECTION 5: FIRE-FIGHTING AND EXPLOSION HAZARD MEASURES

VRLA batteries Flash Point: N/A

SECTION 6: ACCIDENTAL RELEASE MEASURES

SECTION 7: HANDLING AND STORAGE

SECTION 8: HANDLING AND STORAGE

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

VRLA Battery The main components are listed in SECTION 2 above

SECTION 10: STABILITY AND REACTIVITY

SECTION 11: TOXICOLOGICAL INFORMATION

Harmful by ingestion and through skin contact

Ingestion Will immediately cause severe corrosion of and damage to the

Skin Contact Causes severe chemical burns

Case Material: According to information available the product is not harmful to

Separator Material Based on animal implantation and epidemiologic studies glass

SECTION 12: ECOLOGICAL INFORMATION

Ecotoxicity Lead metal in massive form is not classified as hazardous to the

SECTION 13: DISPOSAL CONSIDERATIONS

SECTION 14: TRANSPORT INFORMATION

Proper Shipping Name Batteries, wet, non-spillable

SECTION 15: REGULATORY INFORMATION

VRLA Battery Required Markings

SARA 302 Extremely hazardous substance

SARA 313 (TRI reporting)

Safe Drinking Water Act (SDWA) Not regulated.

US - California Proposition 65 - CRT: Listed date/Carcinogenic substance

SECTION 16: OTHER INFORMATION

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