Product and Company Identification: Safety Data Sheet

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Safety Data Sheet

Revision Number: 003.0 Issue date: 08/17/2017

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: LOCTITE 680 RETAIN CMPND 10ML IDH number: 1835205
Product type: Anaerobic Adhesive Item number: 1835205
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
Henkel Way One MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
SUSPECTED OF CAUSING CANCER.

HAZARD CLASS HAZARD CATEGORY


SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
CARCINOGENICITY 2

PICTOGRAM(S)

Precautionary Statements

Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Avoid breathing vapors, mist, or spray. Wash affected area thoroughly
after handling. Contaminated work clothing should not be allowed out of the workplace. Wear
protective gloves, clothing, eye and face protection.
Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or
concerned: Get medical attention. If skin irritation or rash occurs: Get medical attention. Take
off contaminated clothing.
Storage: Store locked up.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Component(s) CAS Number Percentage*
2-Propenoic acid, 2-methyl-, (1-
24448-20-2 30 - 40
methylethylidene)
3,3,5 Trimethylcyclohexyl methacrylate 7779-31-9 10 - 20
2-Hydroxyethyl methacrylate 868-77-9 10 - 20
Polyurethane methacrylate resin Unknown 5 - 10
Acrylic acid 79-10-7 1-5
Hydroxyalkyl methacrylate 27813-02-1 1-5
1-Acetyl-2-phenylhydrazine 114-83-0 0.1 - 1
Methacrylic acid 79-41-4 0.1 - 1
Cumene hydroperoxide 80-15-9 0.1 - 1

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES


Inhalation: Move to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.

Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
contaminated clothing and footwear. Wash clothing before reuse. Get medical
attention.

Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get medical attention.

Ingestion: DO NOT induce vomiting unless directed to do so by medical personnel.


Never give anything by mouth to an unconscious person. Get medical
attention.

Symptoms: See Section 11.

5. FIRE FIGHTING MEASURES


Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear. In case of fire, keep containers cool with water spray.

Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in
explosions or rupture of storage containers.

Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic
vapours.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected
personnel.

Environmental precautions: Do not allow product to enter sewer or waterways.

Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to
prevent entry into water system; wear full protective equipment during clean-
up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Scrape up as much material as possible. Store in a
partly filled, closed container until disposal. Refer to Section 8 "Exposure
Controls / Personal Protection" prior to clean up.

IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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7. HANDLING AND STORAGE
Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and
clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do
not taste or swallow. Refer to Section 8.

Storage: For safe storage, store at or below 38 °C (100.4 °F)


Keep in a cool, well ventilated area away from heat, sparks and open flame.
Keep container tightly closed until ready for use.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION


Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure
controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


2-Propenoic acid, 2-methyl-, (1-
None None None None
methylethylidene)
3,3,5 Trimethylcyclohexyl methacrylate None None None None
2-Hydroxyethyl methacrylate None None None 3 ppm Ceiling
Polyurethane methacrylate resin None None None None
1 ppm TWA
2 ppm TWA
Acrylic acid None None 3 ppm STEL
(SKIN)
(SKIN)
1 ppm TWA
Hydroxyalkyl methacrylate None None None
3 ppm STEL
1-Acetyl-2-phenylhydrazine None None None None
Methacrylic acid 20 ppm TWA None None None
1 ppm (6 mg/m3)
Cumene hydroperoxide None None TWA None
(SKIN)

Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below
exposure limits.

Respiratory protection: Use a NIOSH approved air-purifying respirator with an organic vapor cartridge.
If this material is handled at elevated temperatures or under mist forming
conditions, without engineering controls, a NIOSH approved respirator must
be used.

Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety
showers and eye wash stations should be available.

Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact. Neoprene gloves.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state: Liquid
Color: Green
Odor: Characteristic
Odor threshold: Not available.
pH: Not available.
Vapor pressure: Not available.
Boiling point/range: Not available.
Melting point/ range: Not available.
Specific gravity: 1.1
Vapor density: Not available.
Flash point: 93.3 °C (199.94 °F)
Flammable/Explosive limits - lower: Not available.
Flammable/Explosive limits - upper: Not available.
Autoignition temperature: Not available.

IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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Flammability: Not applicable
Evaporation rate: Not available.
Solubility in water: Not available.
Partition coefficient (n-octanol/water): Not available.
VOC content: 0.43 %; 4.74 g/l
Viscosity: Not available.
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY


Stability: Stable under normal conditions of storage and use.

Hazardous reactions: None under normal processing.

Hazardous decomposition Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours.
products:

Incompatible materials: Peroxides. Free radical initiators. Alkali metals

Reactivity: Not available.

Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from
incompatible materials.

11. TOXICOLOGICAL INFORMATION


Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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Potential Health Effects/Symptoms

Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system.
Skin contact: Causes skin irritation. May cause allergic skin reaction.
Eye contact: Causes serious eye damage.
Ingestion: May cause gastrointestinal tract irritation if swallowed.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
2-Propenoic acid, 2-methyl-, (1-
None Irritant, Allergen
methylethylidene)
3,3,5 Trimethylcyclohexyl methacrylate None No Records
Oral LD50 (Mouse) = 3,275 mg/kg
2-Hydroxyethyl methacrylate Oral LD50 (Rat) = 11.2 g/kg Irritant, Allergen
Oral LD50 (Rat) = 5,050 mg/kg
Polyurethane methacrylate resin None Irritant, Allergen
Oral LD50 (Rat) = 33.5 mg/kg
Oral LD50 (Mouse) = 2,400 mg/kg
Oral LD50 (Rat) = 2.5 g/kg
Acrylic acid Allergen, Corrosive, Irritant, Kidney, Liver
Oral LD50 (Rat) = 193 mg/kg
Oral LD50 (Rat) = 1,250 mg/kg
Inhalation LC50 (Rat, 4 h) = 1,200 mg/l
Hydroxyalkyl methacrylate None Irritant, Allergen
Allergen, Blood, Kidney, Mutagen, Some
1-Acetyl-2-phenylhydrazine Oral LD50 (Mouse) = 270 mg/kg
evidence of carcinogenicity
Oral LD50 (Mouse) = 1,332 mg/kg
Oral LD50 (Mouse) = 1,600 mg/kg
Oral LD50 (Mouse) = 1,250 mg/kg
Oral LD50 (Rabbit) = 1,200 mg/kg
Methacrylic acid Corrosive, Irritant, Allergen
Oral LD50 (Rat) = 1,060 mg/kg
Oral LD50 (Rat) = 2,224 mg/kg
Dermal LD50 (Rabbit) = 500 mg/kg
Inhalation LC50 (Rat, 4 h) = 7.1 mg/l
Allergen, Central nervous system, Corrosive,
Cumene hydroperoxide Inhalation LC50 (Mouse, 4 h) = 200 mg/l
Irritant, Mutagen

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
2-Propenoic acid, 2-methyl-, (1-
No No No
methylethylidene)
3,3,5 Trimethylcyclohexyl methacrylate No No No
2-Hydroxyethyl methacrylate No No No
Polyurethane methacrylate resin No No No
Acrylic acid No No No
Hydroxyalkyl methacrylate No No No
1-Acetyl-2-phenylhydrazine No No No
Methacrylic acid No No No
Cumene hydroperoxide No No No

12. ECOLOGICAL INFORMATION


Ecological information: Not available.

IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.

Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.

Hazardous waste number: Not a RCRA hazardous waste.

14. TRANSPORT INFORMATION


The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)


Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III
DOT Hazardous Substance(s): alpha,alpha-Dimethylbenzylhydroperoxide

International Air Transportation (ICAO/IATA)


Proper shipping name: RQ, Environmentally hazardous substance, liquid, n.o.s.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III

Water Transportation (IMO/IMDG)


Proper shipping name: RQ, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Hazard class or division: 9
Identification number: UN 3082
Packing group: III

15. REGULATORY INFORMATION


United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.


CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: This product contains the following toxic chemicals subject to the reporting requirements of
section 313 of the Emergency Planning and Community Right-To-Know Act of 1986 (40
CFR 372). Acrylic acid (CAS# 79-10-7).
CERCLA Reportable quantity: Cumene hydroperoxide (CAS# 80-15-9) 10 lbs. (4.54 kg)

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the
Domestic Substances List or the Non-Domestic Substances List.

16. OTHER INFORMATION


This safety data sheet contains changes from the previous version in sections: 2

IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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Prepared by: Product Safety and Regulatory Affairs

Issue date: 08/17/2017

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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