Product and Company Identification: Safety Data Sheet
Product and Company Identification: Safety Data Sheet
Product and Company Identification: Safety Data Sheet
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
SUSPECTED OF CAUSING CANCER.
PICTOGRAM(S)
Precautionary Statements
Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Avoid breathing vapors, mist, or spray. Wash affected area thoroughly
after handling. Contaminated work clothing should not be allowed out of the workplace. Wear
protective gloves, clothing, eye and face protection.
Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or
concerned: Get medical attention. If skin irritation or rash occurs: Get medical attention. Take
off contaminated clothing.
Storage: Store locked up.
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.
Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Component(s) CAS Number Percentage*
2-Propenoic acid, 2-methyl-, (1-
24448-20-2 30 - 40
methylethylidene)
3,3,5 Trimethylcyclohexyl methacrylate 7779-31-9 10 - 20
2-Hydroxyethyl methacrylate 868-77-9 10 - 20
Polyurethane methacrylate resin Unknown 5 - 10
Acrylic acid 79-10-7 1-5
Hydroxyalkyl methacrylate 27813-02-1 1-5
1-Acetyl-2-phenylhydrazine 114-83-0 0.1 - 1
Methacrylic acid 79-41-4 0.1 - 1
Cumene hydroperoxide 80-15-9 0.1 - 1
* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.
Skin contact: Immediately flush skin with plenty of water (using soap, if available). Remove
contaminated clothing and footwear. Wash clothing before reuse. Get medical
attention.
Eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Get medical attention.
Special firefighting procedures: Wear self-contained breathing apparatus and full protective clothing, such as
turn-out gear. In case of fire, keep containers cool with water spray.
Unusual fire or explosion hazards: Uncontrolled polymerization may occur at high temperatures resulting in
explosions or rupture of storage containers.
Hazardous combustion products: Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic
vapours.
Clean-up methods: Remove all sources of ignition. Evacuate and ventilate spill area; dike spill to
prevent entry into water system; wear full protective equipment during clean-
up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust). Scrape up as much material as possible. Store in a
partly filled, closed container until disposal. Refer to Section 8 "Exposure
Controls / Personal Protection" prior to clean up.
IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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7. HANDLING AND STORAGE
Handling: Use only with adequate ventilation. Prevent contact with eyes, skin and
clothing. Do not breathe vapor and mist. Wash thoroughly after handling. Do
not taste or swallow. Refer to Section 8.
Engineering controls: Provide adequate local exhaust ventilation to maintain worker exposure below
exposure limits.
Respiratory protection: Use a NIOSH approved air-purifying respirator with an organic vapor cartridge.
If this material is handled at elevated temperatures or under mist forming
conditions, without engineering controls, a NIOSH approved respirator must
be used.
Eye/face protection: Safety goggles or safety glasses with side shields. Full face protection should
be used if the potential for splashing or spraying of product exists. Safety
showers and eye wash stations should be available.
Skin protection: Use chemical resistant, impermeable clothing including gloves and either an
apron or body suit to prevent skin contact. Neoprene gloves.
IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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Flammability: Not applicable
Evaporation rate: Not available.
Solubility in water: Not available.
Partition coefficient (n-octanol/water): Not available.
VOC content: 0.43 %; 4.74 g/l
Viscosity: Not available.
Decomposition temperature: Not available.
Hazardous decomposition Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Irritating organic vapours.
products:
Conditions to avoid: Elevated temperatures. Heat, flames, sparks and other sources of ignition. Store away from
incompatible materials.
IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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Potential Health Effects/Symptoms
Inhalation: Inhalation of vapors or mists of the product may be irritating to the respiratory system.
Skin contact: Causes skin irritation. May cause allergic skin reaction.
Eye contact: Causes serious eye damage.
Ingestion: May cause gastrointestinal tract irritation if swallowed.
Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
2-Propenoic acid, 2-methyl-, (1-
None Irritant, Allergen
methylethylidene)
3,3,5 Trimethylcyclohexyl methacrylate None No Records
Oral LD50 (Mouse) = 3,275 mg/kg
2-Hydroxyethyl methacrylate Oral LD50 (Rat) = 11.2 g/kg Irritant, Allergen
Oral LD50 (Rat) = 5,050 mg/kg
Polyurethane methacrylate resin None Irritant, Allergen
Oral LD50 (Rat) = 33.5 mg/kg
Oral LD50 (Mouse) = 2,400 mg/kg
Oral LD50 (Rat) = 2.5 g/kg
Acrylic acid Allergen, Corrosive, Irritant, Kidney, Liver
Oral LD50 (Rat) = 193 mg/kg
Oral LD50 (Rat) = 1,250 mg/kg
Inhalation LC50 (Rat, 4 h) = 1,200 mg/l
Hydroxyalkyl methacrylate None Irritant, Allergen
Allergen, Blood, Kidney, Mutagen, Some
1-Acetyl-2-phenylhydrazine Oral LD50 (Mouse) = 270 mg/kg
evidence of carcinogenicity
Oral LD50 (Mouse) = 1,332 mg/kg
Oral LD50 (Mouse) = 1,600 mg/kg
Oral LD50 (Mouse) = 1,250 mg/kg
Oral LD50 (Rabbit) = 1,200 mg/kg
Methacrylic acid Corrosive, Irritant, Allergen
Oral LD50 (Rat) = 1,060 mg/kg
Oral LD50 (Rat) = 2,224 mg/kg
Dermal LD50 (Rabbit) = 500 mg/kg
Inhalation LC50 (Rat, 4 h) = 7.1 mg/l
Allergen, Central nervous system, Corrosive,
Cumene hydroperoxide Inhalation LC50 (Mouse, 4 h) = 200 mg/l
Irritant, Mutagen
OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
2-Propenoic acid, 2-methyl-, (1-
No No No
methylethylidene)
3,3,5 Trimethylcyclohexyl methacrylate No No No
2-Hydroxyethyl methacrylate No No No
Polyurethane methacrylate resin No No No
Acrylic acid No No No
Hydroxyalkyl methacrylate No No No
1-Acetyl-2-phenylhydrazine No No No
Methacrylic acid No No No
Cumene hydroperoxide No No No
IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only.
Recommended method of disposal: Follow all local, state, federal and provincial regulations for disposal.
TSCA 8 (b) Inventory Status: All components are listed or are exempt from listing on the Toxic Substances Control Act
Inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis
California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.
CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the
Domestic Substances List or the Non-Domestic Substances List.
IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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Prepared by: Product Safety and Regulatory Affairs
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.
IDH number: 1835205 Product name: LOCTITE 680 RETAIN CMPND 10ML
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