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SAFETY DATA SHEET

Carboline Urethane Converter 811
According to Regulation (EC) No 1907/2006, Annex II, as amended by Regulation (EU) No 453/2010

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Carboline Urethane Converter 811

Product number 820UC811-B

1.2. Relevant identified uses of the substance or mixture and uses advised against
1.3. Details of the supplier of the safety data sheet
Supplier Akis Paint and Chemical Inc.
Ali Osman Sönmez Cad. No:4
DOSAB-BURSA/TURKEY
T: +902242610537
F:+902242610542
www.akisboya.com

Contact person Tolga Dıraz - Teknik Müdür,Resmiye Kovancı Savaş - Fabrika Müdürü,H.Tuğba Başkurt
Fildişi - Kalite Güvence Sorumlusu

1.4. Emergency telephone number

Emergency telephone Company Tel: +90 224 261 05 37 (office hours)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification
Physical hazards Flam. Liq. 3 - H226

Health hazards Acute Tox. 4 - H332 Skin Sens. 1 - H317 STOT SE 3 - H335

Environmental hazards Aquatic Chronic 3 - H412

Classification (67/548/EEC or Xn; R20. Xi; R37. R52/53, R10, R43

1999/45/EC)

2.2. Label elements

Pictogram

Signal word Warning

Hazard statements H226 Flammable liquid and vapour.

H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.

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Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P240 Ground/bond container and receiving equipment.
P241 Use explosion-proof electrical equipment.
P242 Use only non-sparking tools.
P243 Take precautionary measures against static discharge.
P261 Avoid breathing vapour/spray.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P312 Call a POISON CENTER/doctor if you feel unwell.
P321 Specific treatment (see medical advice on this label).
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362+P364 Take off contaminated clothing and wash it before reuse.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to extinguish.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container in accordance with national regulations.

Contains hexamethylene-1,6-diisocyanate homopolymer, Low boiling point naphtha - unspecified,

hexamethylene-di-isocyanate

2.3. Other hazards

No data available.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

hexamethylene-1,6-diisocyanate homopolymer 80-95%

CAS number: 28182-81-2 EC number: 500-060-2

Classification Classification (67/548/EEC or 1999/45/EC)

Acute Tox. 4 - H332 Xn; R20. Xi; R37. R43
Skin Sens. 1 - H317
STOT SE 3 - H335

n-butyl acetate 1-5%

CAS number: 123-86-4 EC number: 204-658-1

Classification Classification (67/548/EEC or 1999/45/EC)

Flam. Liq. 3 - H226 R10, R66, R67
STOT SE 3 - H336

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Low boiling point naphtha - unspecified 1-5%

CAS number: 64742-95-6 EC number: 265-199-0

Classification Classification (67/548/EEC or 1999/45/EC)

Flam. Liq. 3 - H226 Xn; R65. Xi; R37. N; R51/53. R10, R67
STOT SE 3 - H335, H336
Asp. Tox. 1 - H304
Aquatic Chronic 2 - H411

hexamethylene-di-isocyanate <1%
CAS number: 822-06-0 EC number: 212-485-8

Classification
Acute Tox. 4 - H302
Acute Tox. 1 - H330
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Resp. Sens. 1 - H334
Skin Sens. 1 - H317
STOT SE 3 - H335

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Remove affected person from source of contamination. Chemical burns must be treated by a
physician.

Inhalation If it is suspected that volatile contaminants are still present around the affected person, first
aid personnel should wear an appropriate respirator or self-contained breathing apparatus.
First aid personnel should wear appropriate protective equipment during any rescue. If
spray/mist has been inhaled, proceed as follows. Remove person to fresh air and keep
comfortable for breathing. Maintain an open airway. Rinse nose and mouth with water.
Consult a physician for specific advice. Keep affected person warm and at rest. Get medical
attention if symptoms are severe or persist.

Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Never give anything by mouth to
an unconscious person. Get medical attention.

Skin contact Remove affected person from source of contamination. Remove contaminated clothing
immediately and wash skin with soap and water. Get medical attention if any discomfort
continues.

Eye contact Remove affected person from source of contamination. Remove contact lenses, if present and
easy to do. Continue rinsing. Remove any contact lenses and open eyelids wide apart.
Continue to rinse for at least 15 minutes and get medical attention.

Protection of first aiders Wash contaminated clothing thoroughly with water before removing it from the affected
person, or wear gloves. First aid personnel should wear appropriate protective equipment
during any rescue.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation The product contains organic solvents. Toxic if inhaled.

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Ingestion This product is corrosive. Liquid irritates mucous membranes and may cause abdominal pain
if swallowed. May cause chemical burns in mouth and throat.

Skin contact Causes severe burns.

Eye contact Redness. Conjunctivitis, irritation, tearing. May cause chemical eye burns.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

Specific treatments No specific chemical antidote is known to be required after exposure to this product.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Use foam, carbon dioxide, dry powder or water fog to extinguish.

5.2. Special hazards arising from the substance or mixture

Specific hazards Not known. Thermal decomposition or combustion products may include the following
substances: Toxic gases or vapours.

Hazardous combustion None known.

products

5.3. Advice for firefighters

Protective actions during Move containers from fire area if it can be done without risk. Control run-off water by
firefighting containing and keeping it out of sewers and watercourses. Stop leak if safe to do so. Contain
and collect extinguishing water. Ventilate closed spaces before entering them. Cool
containers exposed to flames with water until well after the fire is out.

Special protective equipment Use air-supplied respirator, gloves and protective goggles.
for firefighters

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Ensure procedures and training for emergency decontamination and disposal are in place.
Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation
of vapours and contact with skin and eyes. Take care as floors and other surfaces may
become slippery. Ensure suitable respiratory protection is worn during removal of spillages in
confined areas.

6.2. Environmental precautions

Environmental precautions Avoid discharge into drains or watercourses or onto the ground. The product contains
substances which are toxic to aquatic organisms and which may cause long-term adverse
effects in the aquatic environment. May accumulate in soil and water systems.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Large Spillages: Collect spillage for reclamation or absorb in vermiculite, dry sand or similar
material. Flush contaminated area with plenty of water. Small Spillages: Absorb small
quantities with paper towels and evaporate in a safe place. Once evaporation is complete,
place paper in a suitable waste disposal container and seal securely. Leave small quantities
to evaporate, if safe to do so. Allow small quantities to evaporate to the atmosphere in a safe,
open place.

6.4. Reference to other sections

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Reference to other sections For personal protection, see Section 8. See Section 11 for additional information on health
hazards. See Section 12 for additional information on ecological hazards. For waste disposal,
see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Obtain special instructions before use. Avoid contact with skin, eyes and clothing. Read label
before use. Wear protective clothing as described in Section 8 of this safety data sheet. For
professional users only.

Advice on general Take off contaminated clothing. Promptly remove any clothing that becomes wet or
occupational hygiene contaminated. Remove contaminated clothing and wash the skin thoroughly with soap and
water after work. Contaminated clothing should be placed in a closed container for disposal or
decontamination. Good personal hygiene procedures should be implemented. Provide
eyewash station. Do not eat, drink or smoke when using this product.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in tightly-closed, original container in a dry and cool place. Protect from sunlight. Keep
away from food, drink and animal feeding stuffs. Keep containers upright.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

8.2. Exposure controls

Protective equipment

Appropriate engineering As this product contains ingredients with exposure limits, process enclosures, local exhaust
controls ventilation or other engineering controls should be used to keep worker exposure below any
statutory or recommended limits, if use generates dust, fumes, gas, vapour or mist.

Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible.

Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn if
a risk assessment indicates skin contact is possible.

Other skin and body Wear appropriate clothing to prevent any possibility of liquid contact and repeated or
protection prolonged vapour contact.

Hygiene measures Wash hands and any other contaminated areas of the body with soap and water before
leaving the work site. Clean equipment and the work area every day.

Respiratory protection Respiratory protection complying with an approved standard should be worn if a risk
assessment indicates inhalation of contaminants is possible.

Thermal hazards If there is a risk of contact with hot product, all protective equipment worn should be suitable
for use with high temperatures.

Environmental exposure Emissions from ventilation or work process equipment should be checked to ensure they
controls comply with the requirements of environmental protection legislation.

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SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Homogeneous

Colour Clear.

Flash point >23°C; <60°C

Relative density 1,08–1,13 gr/cm3 (20°C)

9.2. Other information

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

10.4. Conditions to avoid
Conditions to avoid Avoid exposure to high temperatures or direct sunlight.

10.5. Incompatible materials

10.6. Hazardous decomposition products
Hazardous decomposition Decomposition at ambient temperatures may generate the following substances: Carbon
products monoxide (CO). Carbon dioxide (CO2).

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Toxicological effects This product is toxic. Alergic skin reaction may be observerd in hypersensitive personel.
Harmful if swallowed.

Acute toxicity - inhalation

ATE inhalation (vapours mg/l) 1,222.0

Skin corrosion/irritation
Skin corrosion/irritation No information available.

Respiratory sensitisation
Respiratory sensitisation Sensitising.

Skin sensitisation
Skin sensitisation Sensitising.

Carcinogenicity
Carcinogenicity No information available.

Reproductive toxicity
Reproductive toxicity - fertility No information available.

Specific target organ toxicity - single exposure

STOT - single exposure May cause respiratory irritation.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure Data lacking.

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Inhalation The product contains organic solvents. May cause drowsiness or dizziness.

Ingestion May be harmful if swallowed. May cause stomach pain or vomiting.

Skin contact Liquid may irritate skin.

Eye contact May irritate eyes.

SECTION 12: Ecological Information

Ecotoxicity Dangerous for the environment. The product contains volatile organic compounds (VOCs)
which have a photochemical ozone creation potential. May cause long lasting harmful effects
to aquatic life. The product may have adverse effects on organisms in soil and water.

12.1. Toxicity
Toxicity No effects known.

12.2. Persistence and degradability

Persistence and degradability No data available.

12.3. Bioaccumulative potential

Bioaccumulative potential Not known.

12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects Not known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Disposal of this product, process solutions, residues and by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation and
any local authority requirements.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Confirm disposal procedures with environmental engineer and
local regulations. Product residues retained in emptied containers can be hazardous.

SECTION 14: Transport information

14.1. UN number
UN No. (ADR/RID) 1263

UN No. (IMDG) 1263

UN No. (ICAO) 1263

UN No. (ADN) 1263

14.2. UN proper shipping name

Proper shipping name PAINT RELATED MATERIAL
(ADR/RID)

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Proper shipping name PAINT RELATED MATERIAL

(IMDG)

Proper shipping name (ICAO) PAINT RELATED MATERIAL

Proper shipping name (ADN) PAINT RELATED MATERIAL

14.3. Transport hazard class(es)

ADR/RID class 3

ADR/RID classification code F1

ADR/RID label 3

IMDG class 3

ICAO class/division 3

ADN class 3

Transport labels

14.4. Packing group

ADR/RID packing group III

IMDG packing group III

ADN packing group III

ICAO packing group III

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

EmS F-E, S-E

ADR transport category 3

Emergency Action Code •3Y

Hazard Identification Number 30

(ADR/RID)

Tunnel restriction code (D/E)

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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EU legislation Commission Decision 2000/532/EC as amended by Decision 2001/118/EC establishing a list

of wastes and hazardous waste pursuant to Council Directive 75/442/EEC on waste and
Directive 91/689/EEC on hazardous waste with amendments.
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Key literature references and This SDS has been created as a result of observations, measurements on the product related
sources for data to the product and the data that raw material suppliers provide

Revision comments This is first issue.

Issued by Mr. Tolga DIRAZ - Certified SDS Author - Certificate No: 01.40.08/06.03.2015 /
[email protected] / +90 224 261 05 37

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Supersedes date 28/12/2015

SDS number 4923

Risk phrases in full R10 Flammable.

R20 Harmful by inhalation.
R23 Toxic by inhalation.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37 Irritating to respiratory system.
R42/43 May cause sensitisation by inhalation and skin contact.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

Hazard statements in full H226 Flammable liquid and vapour.

H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
EUH208 Contains hexamethylene-di-isocyanate. May produce an allergic reaction.

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This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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