Mollier Diagram Can Be Improved 1

MOLLIER DIAGRAM CAN BE IMPROVED!
IMPROVED BASIC COOLING CIRCUIT PERFORMANCE EFFICIENCY USING AN

ECONOMISER
Eng. Jonny Malachi, VP Operations,

Mashav Refrigeration and Air Conditioning Engineering Ltd.
IMPROVEMENT OF BASIC COOLING CIRCUIT EFFICIENCY

Improved cooling circuit efficiency is particularly important at the present time, when
equipment manufacturers seek every means to save energy and are constantly
improving the efficiency coefficient, we all know as the C.O.P (Coefficient Of
Performance).
The adoption of screw compressors to replace reciprocating compressors these days
enables chillers manufacturers to employ a technology common in the deep freeze
field, viz. medium pressure self-cooling of the liquid phase (warm fluid) in the
cooling circuit - Intermediate Cooling.
In this article I shall review the technologies for improving the basic cooling
circuit efficiency based on the Intermediate Cooling principle and currently
used by leading chiller manufacturers:
1. Flash Tank Economizer
2. DX (Direct Expansion) Economizer
PRESSURE ENTHALPY DIAGRAM
Pressure - Enthalpy Curve Pressure - Enthalpy Curve

(Pressure reduction)
Expansion Valve
Air Cooled Condenser

Pressure
Compressor
Temperature oC
Temperature oC
Water 12
7
Condenser
Subcooling Evaporator
Chilled Water Chilled Water Low Pressure
OUT IN Superheated
Vapour
Enthalpy (Total Heat) R22

High Pressure Liquid Low Pressure Liquid Low Pressure Saturated Vapour
Low Pressure Superheated Vapour High Pressure Superheated Vapour
Fig. 1: Mollier Diagram - Basic Cooling Circuit - Chiller

Why is it important to cool the liquid phase?
The basic cooling circuit is shown in Fig. 1, in which the cooling circuit is drawn
superimposed on the mollier diagram.
The ringed area is the liquid phase of the refrigerant at the evaporator output (warm
fluid).
Further cooling of the refrigerant at the evaporator output - Sub-Cooling, will improve
the performance of the cooling circuit, by increasing the evaporator cooling output,
hence improving the C.O.P.
Sub-cooling of the liquid phase (warm fluid) may also be achieved by other, albeit
restricted, methods, of which the most common are: additional cooling by external
media such as outside air, by increasing the condenser heat transfer area; and/or
additional cooling by the refrigerant itself, using the cold gaseous phase on the
suction side of the cooling circuit, by adding a liquid-suction heat exchanger.
This said, methods based on Intermediate Cooling are more effective (the fluid is
cooled by siphoning off and evaporating a small portion of the fluid itself for this
purpose) enabling improved C.O.P using the simplest means possible.
Improved Efficiency Using Flash Tank Economizer
Flash Tank Economizer (Open flash)
Fig. 2: Improved Efficiency by Adding Flash Tank Economizer
Under this method a Flash Tank Economizer is added at the condenser outlet.
The refrigerant expands in two steps, and sub-cooling is achieved by reduction of the
mixture vapour pressure in the Flash Tank Economizer to an intermediate value,
cooling the fluid in the tank by its partial evaporation.
The gaseous phase is sent back to the economizer-port at the top of the compressor
screw suction, at optimum intermediate pressure; the increased cooling output is
shown in the mollier diagram in Fig. 2.
Flash Tank Economizer
Fig. 3: Chiller with Flash Tank Type Economizer
Improved Efficiency Using Direct Expansion (DX) Economizer
Shell and Coil Economizer (Closed flash)

Direct Expansion Economizer (D.X.)
Fig. 4: Improved Efficiency Using Direct Expansion (DX) Economizer

Under this method a Direct Expansion (DX) Economizer is added to the cooling
circuit at the condenser outlet. Some of the refrigerant liquid phase is expelled via the
expansion nozzle and evaporates within the heat exchanger, resulting in cooling of the
warm fluid pumped through it; the expelled fluid undergoes a change of phase to the
gaseous state, which is then sent back to the economizer-port at the top of the
compressor screw suction, at optimum intermediate pressure; the increased cooling
output is shown in the mollier diagram in Fig. 4.
Direct Expansion Economizer
DX
Economizer
Fig. 5: Chiller with Direct Expansion (DX) Type Economizer
Performance Assessment
Performance is assessed with the aid of software belonging to the equipment
manufacturer, based on thermodynamic calculations derived from the mollier diagram
(see example of data entry page in Fig. 6). By running the software at multiple
different working points a performance graph may be plotted showing the percentage
improvement in efficiency resulting from introducing an economizer for each
refrigerant, as a function of the evaporation and condensation temperatures of the
refrigerant at the working point.
For example, the curves shown in Fig. 6 indicate that adding an economizer to a chiller
using the refrigerant R134a operating with an evaporation temperature of 3°c and a
condensation temperature of 35°c will lead to an energy saving of about 7% (the
greater the difference between evaporation and condensation temperatures, i.e. the
Lift, the greater the saving when operating with an economizer).
Flash Economizer Savings
Fig. 6: Percentage Improvement in Efficiency Resulting from Introducing an

Economizer in the Cooling Circuit
To sum up:
The advantages of introducing an economiser in the cooling circuit may be
summarised and depicted by superimposing diagrams of the processes on the mollier
diagram.
Mollier Diagram ? - Can be improved!

SUMMARY
Sub
Cooler
Flash
Cooler
De Super
Heater
Super
Heater
Fig. 7: Combined Depiction of Processes Superimposed on mollier diagram

Process with Flash Tank Economizer Added
This process improves the performance of the cooling circuit by combining an
intermediate cooling process - of both the warm fluid and the warm gas (which also
cools in the course of compression by mixing with cold gas returned via the
economizer port at the top of the screw, as shown in Fig.7- a combination of Flash
Cooler with De Super Heater).
Process with Direct Expansion (DX) Economizer Added

This process improves the performance of the cooling circuit by combining an
intermediate cooling process - of both the warm fluid and the warm gas (which also
cools in the course of compression by mixing with cold gas returned via the
economizer port at the top of the screw, as shown in Fig.7 - a combination of Sub
Cooler with De Super Heater).
Performance comparison- The efficiency improvement drops slightly (by one to two
percent) when using a Direct Expansion (DX) Economizer, compared to a Flash Tank
Economizer, due to the fact that heat exchange is never ideal. However use of a Direct
Expansion (DX) Economizer is preferable to a Flash Tank Economizer in cases where
it is important to maintain high pressure in the fluid line (for example, where the duct
work traverses a long route from the condenser output to the expansion nozzle port
input) to ensure a normal expansion process in the nozzle.

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MOLLIER DIAGRAM CAN BE IMPROVED!

IMPROVED BASIC COOLING CIRCUIT PERFORMANCE EFFICIENCY USING AN

Eng. Jonny Malachi, VP Operations,

IMPROVEMENT OF BASIC COOLING CIRCUIT EFFICIENCY

PRESSURE ENTHALPY DIAGRAM

Pressure - Enthalpy Curve Pressure - Enthalpy Curve

Air Cooled Condenser

Enthalpy (Total Heat) R22

Low Pressure Superheated Vapour High Pressure Superheated Vapour

Fig. 1: Mollier Diagram - Basic Cooling Circuit - Chiller

Improved Efficiency Using Flash Tank Economizer

Flash Tank Economizer (Open flash)

Fig. 2: Improved Efficiency by Adding Flash Tank Economizer

Fig. 3: Chiller with Flash Tank Type Economizer

Improved Efficiency Using Direct Expansion (DX) Economizer

Shell and Coil Economizer (Closed flash)

Fig. 4: Improved Efficiency Using Direct Expansion (DX) Economizer

Direct Expansion Economizer

Fig. 5: Chiller with Direct Expansion (DX) Type Economizer

Fig. 6: Percentage Improvement in Efficiency Resulting from Introducing an

Mollier Diagram ? - Can be improved!

Fig. 7: Combined Depiction of Processes Superimposed on mollier diagram

Process with Direct Expansion (DX) Economizer Added

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